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By Chang Wei, Zhigan Deng, Minting Li, Cunxiong Li, Gang Fan, Xingbin Li

Molybdenum and nickel in black shale ore exists as amorphous sulfides which has highly active, and easily oxide to sulfuric acid and sulfate at low temperature in the presence of excess oxygen. Take advantage of the characteristic to leach molybdenum and nickel from black shale. Oxidation, conversion and dissolution behavior of amorphous colloidal molybdenum and nickel sulfide in pressure leaching process was studied. The effects of stirring speed, temperature, concentration of sulphuric acid, oxygen process and mineral granularity on molybdenum and nickel leaching were investigated. The results showed that dissolution rate increased with increasing temperature and stirring speed, but decreased with increasing concentration of sulphuric acid. And dissolution of molybdenum and nickel from ore only need oxygen without any other reagent.

Mar 1, 2017

By Z. Zhang, X. -G. Chen, F. Breton, A. Arici

"The microstructure of Al-10Si-0.3Mg-0.5Mn alloy with 0.27% Zr and 0.19% V addition was quantitatively analysed and compared to the base material. The addition of Zr and V in the AlSi10Mg alloy exhibit a beneficial effect on the Si modification, resulting in the reduction of the size of eutectic Si particles on both as-cast and T6 conditions. The quantitative image analysis results show that the Zr and V addition and T6 treatment can reduce the size of the intermetallic phases. In addition, the presence of Zr and V is favour to the partial dissolution of the intermetallic phases during the T6 treatment. Different heat treatment procedures were tested to optimize treatment parameters. The mechanical properties of the alloys were evaluated using hardness measurements and tensile tests. The results show that the addition of Zr and V can remarkably improve the mechanical properties on as-cast and T6-treated conditions. The correlation between the microstructure and mechanical properties of the alloys is discussed.INTRODUCTION Al-Si-Mg foundry alloys have been widely used in automotive and aerospace industries due to their high strength-to-weight ratio, heat-treatable capability and excellent castability. The alloying elements such as Cu, Mn, Fe are traditionally added into Al-Si-Mg alloys to improve their mechanical properties (Mohamed, Samuel, Samuel & Doty, 2009). In recent years, the attention has been paid to the effect of the transition elements such as Zr, V, Ti, etc, as minor alloying additives, on the properties of aluminum alloys (Elhadari, Patel, Chen, & Kasprzak, 2011; Kasprzak, Amirkhiz & Niewczas, 2014; Shaha, Czerwinski, Kasprzak, Friedman & Chen, 2015; Shaha, Czerwinski, Kasprzak & Chen, 2014; Mahmudi, Sepehrband, Ghasemi & 2006; Meng, Cui, Zhao & Zuo, 2013). Kasprzak et al., (2014) and Shaha et al., (2015) reported that additions of Zr, V, and Ti in Al-Si-Cu-Mg cast alloys can improve the alloy mechanical properties at high temperature by forming stable intermetallics and precipitates on as-cast and heat treatment conditions. On the other hand, the mechanical properties of near-eutectic and eutectic Al–Si cast alloys depend not only on the chemical composition but also, even more importantly, on microstructural features such as the morphology and size of eutectic silicon and intermetallic particles, which are present on both as-cast and heat treatment conditions (Mohamed et al., 2009). However, there is rather limited information on the effect of Zr and V on the microstructure features and mechanical properties of near-eutectic Al-Si-Mg cast alloys."

Jan 1, 2018

Samples weighing O· 2 g are digested with 2 ml of 72 per cent perchloric acid for 2 hr at 180°C, and then diluted to 10 ml. with water. After settling, an aliquot of clear solution is reduced with ascorbic-citric acid, and then a zinc dithiol solution is added to form a coloured molybdenum complex which is extracted with petroleum spirit for comparison with standards.Concentrations down to 2 p.p.m. may be analysed at rates up to 150 determinations per day.

Jan 1, 1970

By K-H. Frohne

This report presents a study of the Cooper sand of the Fork Run pool of Warren and McKean Counties, Pa., and a prediction of the secondary oil recovery by gasflooding the reservoir. A computer program employing a modification of the Craig, Geffen, and Morse secondary recovery calculation was used to make the gas flood performance forecast and is presented in the appendix. The Cooper sand reservoir in the Fork Run pool lies at a depth of about 1,900 feet and covers an area 1/2 mile wide by 2-1/4 miles long. Original oil in place is estimated to have been 8,266,000 STB. The primary recovery mechanism is solution gas drive, and ultimate primary recovery may reach 20 percent over a well life of 90 years. Two computer predictions were made for gas flooding the Cooper reservoir. The first was for a 25-acre pilot five-spot utilizing existing wells, but project economics were poor since only 25 percent of injection gas is utilized for pilot oil recovery. Recovery was 71,000 STB, or 22 percent of oil in place at flood initiation, but required 25,700 scf gas injected per STB of oil recovered. In the second prediction, pilot area performance was projected for the entire Fork Run pool, and economics became good. Recovery was 1,753,000 STB from 25 five-spots after the injection of only 6,400 scf per STB of oil recovered.

Jan 1, 1969

By H. V. Makar

The Bureau of Mines successfully demonstrated, on a pilot plant scale, a sodium sulfate (Na2S04) refining process for removal of copper from molten ferrous scrap. Previous tests established technical feasibility on a bench scale for achieving low copper concentrations and determining the principal factors controlling process efficiency. The pilot plant study involved a 1-ton arc furnace for melting ferrous scrap and a 1-1/2-ton treatment ladle. Results of these tests showed that copper removals obtained in laboratory tests (approximately 40 relative percent copper removal with 10 weight-percent surface addition of sodium sulfate) could be achieved on the pilot plant scale when excess carbon was added with the sodium sulfate compacts. Data were obtained on temperature losses and carbon consumption related to Na2SO4 treatment.

Jan 1, 1974

By T. Xue, A. Singhal, D. Wrana, I. Mihaylov

"At Vale's Thompson Nickel Refinery, the copper and arsenic in the nickel electrolyte are removed by precipitation using H2S, generating a sulphide precipitate containing about 40% Cu, 8% Ni, 2 to 4% As and 30% S. This residue has been typically stored in impoundment ponds within the plant site. Various options for reprocessing it have been investigated over the years. One of the options involved oxidative pressure acid leach, whereby over 95% Cu, Ni and As were extracted. More recently, an atmospheric alkaline sulphide leaching process for selective removal of 70 to 90% As was developed and mini-plant tested. After alkaline sulphide leaching, the dissolved arsenic is precipitated as stable basic ferric arsenate (BFA) with the addition of ferric sulfate, while the low-arsenic Cu/Ni sulfide is suitable for processing in Vale's operations elsewhere in Canada.INTRODUCTIONVale’s Thompson Nickel Refinery was commissioned in 1961 and currently it has the capacity to produce about 56,700 tonnes per year of electrolytic nickel as cathode slab and rounds products. A sulphate and chloride mixed electrolyte is used in the Thompson refining process and it typically contains 75 to 85 g/L Ni, 50 to 60 g/L Cl, 90 to 120 g/L SO4 2-, 25 to 30 g/L Na and 8 to 9 g/L boric acid. The main impurities in the Thompson anolyte are copper, cobalt, arsenic, iron and lead.The simplified Thompson electrolyte purification flowsheet is shown in Figure 1 (Oliver & Wrana, 2009, Goble & Chapman, 1986); it consists of precipitation of copper, arsenic and lead with H2S, followed by nickel replenishment with ground matte and acid and removal of cobalt and iron with Cl2 and NiCO3."

Jan 1, 2012

By K H. Esbensen

The critical role of representative sampling is featured and illustrated by selected examples from the geosciences and beyond. As there already are many demonstrations of the potential (and potentially large) economic consequences of ignoring proper standards with respect to representativity, eg for mining and minerals processing companies, which æstand to lose millions of dollars by failing to optimise exploitation of their mineral resourcesÆ, such need no further iteration here.This keynote lecture, rather, takes a point of departure from the opposite perspective: what is to be gained by a scrupulous stand for representativity? Honesty, reputation, credibility, market advantage - is what!CITATION:Esbensen, K H, 2012. The critical role of representative sampling, in Proceedings Sampling 2012 , pp 9-12 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 21, 2012

The War Department is appealing to skilled workmen and scientifically or technically trained men to enlist in any one of a large number of engineering troops needed for immediate action in France. Any registrant under the selective service law, who has not actually been called to service, may be immediately inducted into an engineer organization at his own request. Application for induction should be made to the Chief of Engineers, giving a complete statement of the applicant's qualifications. Any man who is physically qualified, between the ages of 18 and 21, or between 31 and 40, may voluntarily enlist for an engineer organization, provided he proves to the recruiting officer that he is experienced or skilled in any engineering trade, or is a handy main who is' especially suited for engineering work. There are about 600 recruiting stations in the United States, and an officer at any one of these will enlist a candidate for an engineer organization if he is suitable. Enlistment is in the grade of private. Subsequent promotion to the rank of non-commissioned officer is secured by merit. It is intended to fill many of the vacancies which will occur from time to time among the commissioned officers by selection from the ranks. A few of the special services, of most interest to mining and metallurgical workmen, urgently needed by the army, are as follows: Crane Operating and Maintenance Regiments; Depot Detachments; Electrical and Mechanical Regiments; General Construction Battalions; Mining Regiments; Quarry Regiments; Battalions for the construction, maintenance, and operation of railways; Road Building Battalions; Sapper Regiments; Supply and Shop Battalions; Surveying, Ranging and Map Reproduction Regiments; Water Supply Companies; and many others. All of these organizations will be assigned to such duties as competent

Jan 4, 1918

By P. Schilizzi, A. Jarosz, M. Karmis

This paper is concerned with subsidence prediction methods and in particular with two techniques, one based on profile functions and the other on influence functions. Profile function methods provide a tool for a fast calculation of subsidence on a line across a mine panel. Influence function methods, on the other hand, allow for a more detailed calculation of ground movements, in any mode and at any depth, on a grid or at any specific point. In more detail, the hyperbolic tangent profile function, as developed by VPI&SU from field data pertaining to the eastern U.S. coalfields, and an influence function method currently being adapted for the same region, are presented and discussed. The applicability, advantages and limitations of these techniques are examined and comparisons are presented with field measurements. Computer software developed for the application of these prediction methods, for two widely used personal computer systems, are also discussed and a number of examples are presented demonstrating the potential of such programs.

Jan 1, 1986

Of late there have been various papers published on this subject by various authorities, in which certain definite factors influencing slime settlement have been brought forward. As the principles set forth by these writers are of great interest, and have, in most cases, been generally accepted, the author will review them in the hope that by discussion some more knowledge may be brought to bear on many points connected with the subject.The definition of slime at the present time is not a standard one, and varies according to different authorities, some defining slime as ore crushed to such a fineness that it will pass through a screen of standard size, say 150 or 200-mesh, in water (1, 2);others as that part of the finely-crushed material which is in the physical condition which causes it to remain in. suspension in water, and possesses pr?perties which render it almost unleachable (3). Authorities seem divided on this point, but of late American writers seem to prefer the former definition. On the contrary, B L Gardiner describes slime as a mixture of small particles of crushed ore of varying sizes which, when mixed with water, tend...

Jan 1, 1912

By R. H. Migliaccio, M. B. Kahle

The railroad haulage system was started at Kennecott's Bingham Mine in 1906 and has remained a prime mover of ore and waste for the succeeding sixty years. As the stripping ratios increased contract stripping on the upper levels of the mine was introduced employing truck and shovel methods. The ore production then was 90,000 tpd. Analysis of expanding the ore production to 108,000 tpd revealed that the increased ore production and continually rising stripping ratio would result in waste production requirements that exceeded the capacity of the rail haulage system above 6290 level. The advent of larger haulage trucks (65-100 tons) in the early 1960's made available to the Bing- ham Mine economic and operating factors which showed truck haul- age to be the best replacement for rail haulage on the upper levels of the mine. As part of that analysis it was concluded that company stripping would replace the contractor stripping in the top area of the mine.

Jan 7, 1973

Late Palaeozoic and Late Mesozoic phases of widespread overprinting have obliterated most of the primary magnetization signature of the Tasman Fold Belt. Palaeomagnetic programs of a regional extent offer best prospects for identification and interpretation of such secondary magnetizations and for isolation of any remaining primary magnetization. In 1983 the BMR initiated a regionally oriented palaeomagnetic study of the Tasman Fold Belt to obtain palaeomagnetic constraints on the tectogenesis of the fold belt. Particular attention is being paid to the analysis of possible differential movements between suspect or- tectonostratigraphic terranes within the Tasman Fold Belt and the respect to cratonic Australia. Work has concentrated so far on the Cowra Trough-Molong High region of the Lachlan Fold Belt and the New England region. Pilot sampling has been carried out in the Gympie region. In addition Palaeozoic sequences are being studied from the Amadeus Basin and the Ngalia Basin to refine the palaeomagnetic reference frame of cratonic Australia.

Jan 1, 1987

By Frank A. Wilder

The most important process in a gypsum mill is calcining the crude mineral. There seems, however, to be little progress or change in calcining methods. This would not be surprising if the industry was not, in other ways, developing. The demand for gypsum in its various forms, however, is growing rapidly. The output has more than doubled in six years, while the value of gypsum products, through the introduction of higher priced. specialties like wall board, has nearly trebled in the same period. In other industries, under somewhat similar conditions, calcining in rotating cylinders, either by direct or indirect heat, has replaced the method that still prevails in gypsum mills. Efforts were made to use rotary calciners in manufacturing plaster of Paris in the early days of the industry in America; 25 years ago rotary calciners were in use in Germany. At that time there was great diversity of opinion in regard to their merit. In 1923, the output of calcined gypsum in the United States was 3,101,378 tons. About nine-tenths of this material was calcined in kettles, the remainder in rotary calciners. The ratio was about the same 10 years ago. During these 10 years, rotary calcining made relatively no gains, and there were no important changes in the construction of kettles. In their manipulation, the only change of consequence was in connection with the length of time that the gypsum is left in the kettle. For wall-plaster purposes, all producers who had not previously done so changed from second-settled to first-settled calcined gypsum, thereby reducing production costs and improving the plasticity and sand-carrying capacity of their plaster. Nevertheless, in the few mills in which they were installed, rotary calciners continue to operate, with possibly one or two exceptions, and to be highly successful. In these 10 years, the Cummer type of rotary calciner has disappeared. All rotaries now used are of the cement-mill type with a diameter of 6 or 7 ft. and length of 80 to 120 feet.

Jan 1, 1925

By P. C. Thakur

Mine productivity, measured by the output of minerals per manshift, depends on a number of factors including physical conditions of the minable seam, type of mining equipment, management techniques, worker attitudes and governing jaws and regulations. The greatest scope of improving productivity lies, perhaps, in modifying physical conditions to an advantage and using highly productive equipment. In the case of coal mines, increased productivity can be achieved by (i) obtaining prior knowledge of the mineable property, e.g., the grade and thickness of, the coal seam, presence of sand channels, faults, etc., (ii) eliminating conditions that hamper production, e.g., high emissions of methane and water, and (iii) using more productive mining techniques. Conoco/Consol's (Conoco Inc. and Consolidation! bal Company, a fully-owned subsidiary) horizontal drilling system was developed with the hove objectives in mind. It can drill 75 to 1001 in diameter boreholes to depths of more than 600 1 and maintain the borehole in a preselected horizon. Such boreholes can be utilized for premining exploration of the coal seam, for removing methane and water and in devising mining techniques with high productivity. The purpose of this paper is to describe the horizontal drilling system briefly and to discuss its applications in the above-mentioned- areas.

Jan 1, 1980

By L. W. Beckstead

The use of acid ferric sulfate solution as a lixiviant for chalcopyrite concentrates has been of little interest from a practical standpoint due to the formation of a tenacious layer of elemental sulfur which severely impedes the reaction progress. CuFeS2 + 4Fe+3 ?Cu+2 + 5Fe+2 +2s° For example, an acid ferric sulfate leach of chalcopyrite concentrate results in only 12% copper extraction in a three hour leach at 93°C. Experimental results suggest that particle size is the only controllable variable which has a significant effect on the rate of acid ferric sulfate leaching at ambient pressure. Size reduction of the concentrate prior to leaching was exam¬ined using various methods of grinding. Of the grinding methods considered, attrition grinding was found to be the most effective. Leaching of an attritor-ground product (median particle size 0.5 microns) resulted in approximately 90% copper extraction in a three hour leach at 93°C. Energy measurements suggest that the costs associated with attrition mill¬ing are not unreasonable. Evidence indicates that "activation" or stored strain energy is not responsibile for the enhanced reaction kinetics of the finely ground concentrate, but rather the experimental results can be explained simply in terms of the increased surface area due to size reduction. Leaching reaction mech¬anisms operative in the acid ferric sulfate system are discussed and the application of ultra-fine grinding technology to other systems is considered.

Jan 1, 1976

By Basil B. Zavoico

ALTHOUGH the American petroleum industry was affected by the Second World War from its early beginning it was not until Dec. 7, 1941- that the industry was placed on full war footing. Even throughout most of 1942 the American overseas operations were limited and not until late in the year did expansion of military activities, more particularly the offensive in North Africa, affect the domestic supplies to such an extent that critical deficiencies developed locally in this country, particularly along the East Coast. The definite outlook for greatly expanded offensive operations by the United States on both Atlantic and Pacific fronts makes certain that during 1943 the domestic situation will. not be alleviated; rather it may become even more critical even though additional transportation facilities, now being built and planned. will be completed from the southwestern producing states to the East Coast.

Jan 1, 1943

By Justus Deen, Paul Sterk

Overbreak into the wall rock of a development drift leads to the inevitable need to rehabilitate a drift. Moreover, overbreak in a production heading can lead to external dilution and lower ore grades. Both of these factors are critical to bottom line costs of underground operations today. The geology of the Homestake orebody makes this an even more complex problem. For over fifteen years the Homestake Mine has attempted to implement perimeter blasting techniques that are both safe and cost effective. Many practical perimeter methods and products have been tested including air decking; low density emulsions; various types of stick powder; various decoupling media including rope, low density ANFO, polystyrene ANFO, salt based ANFO, and various grain detonating cords up to 200 grain.

Jan 1, 1997

By Julyana G. Santana, Esperidiana A. B. Moura, Vijay K. Rangari, Olgun Güven, Angel Ortiz, Rene R. Oliveira

Ethylene-vinyl alcohol (EVOH) copolymers are widely used in the food packaging industry as gas barrier properties to oxygen, organic solvents, and food aromas. EVOH is very sensitive to moisture and its gas barrier ability deteriorates in high relative humidity conditions.This work aims to prepare flexible films based on melt-blending high density polyethylene (HDPE) and ethylene-vinyl alcohol (HDPE/EVOH/EVA blend) reinforced with graphene oxide (GO). The HDPE/ EVOH/EVA/GO flexible films were prepared by twin-screw extrusion and blown film extrusion processing. The flexible films samples were characterized by tensile tests, TG, DSC and FE-SEM analysis and the correlation between properties was discussed. In addition, the oxygen permeability tests were performed at 23 °C, 0 and 90% relative humidity using an OX-TRAN (MOCON Inc.).

Mar 1, 2017

Pese a tener cajas sólidas en su estructura, algunas vetas desarrollan un relleno frágil, ocasionando problemas futuros de sostenimiento para el "corte y relleno" de los mismos. Por ello, se utilizó el método de los "Square Sets", donde además de ser costoso, implicaba eliminar una proporción de la roca encajonante y diluía el contenido metálico de los filones. En ese sentido, el objetivo del texto es señalar la viabilidad del "método Cornish"como método alternativo, económico, de rendimiento óptimo y que no presenta riesgos para el personal o la labor realizada. Este método es aplicable en aquellas vetas uniformes no falladas, que tengan desde una potencia pequeña hasta aquella que sea posible apuntalar, así como en aquellas que requieran sostenimiento del techo en la veta mima o donde se realizen Shrinkages. El proceso del método se basa en la preparación de los tajeos, luego en la explotación(perforación y disparos), enmaderado, relleno del tajeo, recuperación de madera, las variantes en la preparación del tajeo y la recuperación del mineral. La única desventaja que ofrece este método es su peligrosidad, dado que si se aplica en zonas inadecuadas o sin la supervisión que garantice el cumplimiento de las normas preventivas, es preferible el uso de los "Square Sets". Sin embargo, la aplicación del método resulta mucho más productiva en rendimiento teórico puesto que alcanza de 7 a 10 toneladas por tarea de 8 horas y responde satisfactoriamente siempre y cuando las condiciones de las vetas lo permita.

Jul 20, 1957

By S Matos Camacho, K G. van den Boogaart, R Tolosana Delgado, U Mueller

"The precise formulation of a geometallurgical optimisation problem is by necessity a simplification of reality. It includes implicit choices such as data availability or mining block geometry. Additional data can be orebody data, production data or market data. Often these choices are predetermined by the software, the workflow or the corporate culture, and as such are not even queried. There are several aspects that might play a role in the optimisation. They include not only the spatial model on which the selection of mining blocks and the potential mining sequence are based, but also the complexity of the processing model, the way in which uncertainty is treated, the scope of responsibility and the complexity of the model. In addition the timing of the optimisation and the availability (or lack thereof) of information will influence the outcome of any optimisation.We show that different modelling choices and different model formulations for the same mine can lead to very different processing choices, substantially different net present values (NPV), opposite investment decisions and so to overall different values for the entire operation. The selection of adequate simplifications and corresponding formulations for the optimisation problem is thus an important task in itself.For this purpose we introduce a method for quantifying the impact of certain simplifications prior to the optimisation. For example, the effect of mining block choices depends mainly on the spatial structure and the structure of the processing gain function. Both can be quantified beforehand. Based on the outcome, appropriate simplifications can be selected for the geometallurgical optimisation.CITATION:van den Boogaart, K G, Tolosana Delgado, R, Mueller, U and Matos Camacho, S, 2016. How Details of the Geometallurgical Optimisation Influence Overall Value, in Proceedings The Third AusIMM International Geometallurgy Conference (GeoMet) 2016, pp 303–312 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Jun 15, 2016