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By A. R. Taylor

Using solution calorimetry, the following heats of reaction were determined: (1) NaCN(c) + 1/Cu20(c) + 129H20(l) ? CuCN(c) + NaOH?128.5H2O ?H = -13.44±0.10 kcal/mole, (2) HCN(2) + NaOH?128.5H20 ? NaCN(c) + 129.5H20(l) ? = -2.52±0.02 kcal/mole. From these reactions, the heats of formation for CuCN(c) and HCN(2) were calculated to be 22.7±0.4 kcal/mole and 24.9±0.4 kcal/mole, respectively. Reaction 2 was made to check the consistency of literature values for heats of formation of HCN and NaCN. Adiabatic calorimetric measurements between 10° and 400° K showed the entropy and heat capacity of CuCN(c) to be 21.51±0.06 eu and 14.58±0.04 cal/mole deg, respectively, at 298° K. A broad anomaly in the heat capacity was found in the temperature range 285°-320° K. The heat of transition associated with this anomaly was less than 1 cal/mole, the sensitivity of the measurements.

Jan 1, 1971

By Jack G. Pippenger

The Coteau Properties Co.'s Freedom mine is a surface operation near Beulah, ND that produces more than 13.6 Mt/a (15 million stpy) of lignite. Coteau, a subsidiary of North American Coal Corp., ranks among the largest mines in North America. In 1994, Coteau ranked eighth in annual coal sales, becoming the largest mine outside the Powder River Basin of northeastern Wyoming. However, for the Freedom mine to stand alongside the Powder River Basin heavyweights, Coteau had to overcome several obstacles. These included a coal seam with three-quarters the heating value and overburden-to-coal ratios three times higher than Powder River Basin mines. Coteau's ability to compete has been built around a program of continuous improvements in productivity, cost efficiency and innovation.

Jan 1, 1995

By J. Drelich, M. Pawlik

An improved experimental procedure to measure contact angle has been consolidated with coal surface preparation involving polishing with abrasive paper, alumina powder, and a cloth, followed by ultrasonic and mechanical cleaning. Specifically, the captive-bubble measuring technique has been compared with the sessile-drop technique and the former has been recommended for the examination of the hydrophobic properties of coal surfaces. Results of the research program, which is currently under way, on the examination of the effect of the nature, amount, size, and distribution of mineral inclusions in coal, on its wettability are briefly reviewed.

Jan 1, 1999

By Jerry L. Purswell

INTRODUCTION The principal OSHA standards dealing with tunneling activities are found in 29 CFR Part 1926. A reference for the applicable subparts which apply to tunneling is included as Appendix A. In addition, some standards from 29 CFR Part 1910 have been identified as applicable to construction and are included in the recent printing of an interim vertical standard for construction (1910/1926 Project). The remainder of this presentation will be focused on past OSHA activities to revise Subpart S of 1926, the principal subpart dealing with tunnel construction.

Jan 1, 1979

By D. F. Sherwin

"THE AREA which is described in this paper (Fig. 1) includes the continental margin of eastern Canada extending from the Gulf of Maine to the north edge of the Grand Banks, which, including the continental shelf, slope and rise, comprises an area of about 600,000 square miles. The paper is intended to give a background of the geological setting of this region in the context of its ultimate potential for oil and gas reserves in close proximity to the Nova Scotia energy market.HISTORY OF EXPLORATIONThe history of geological exploration of this area really began in 1878, when U.S. fishing boats brought back samples of rock recovered in trawls from their expeditions to the long-famous fishing banks off Canada's East Coast. Tertiary and Cretaceous fossils recovered from these samples indicated that the eastern Canadian continental shelf was actually the submerged northern extension of the Atlantic Coastal Plain."

Jan 1, 1972

By B. N. Thompson

The main industrial minerals produced are non-metallic - clay, dolomite, limestone, pumice, salt, serpentine, and silica sand. The other minerals, some with minor production, include diatomite, feldspar, magnesite, sulphur, asbestos, and perlite. Energy and metallic minerals and aggregate are excluded from this account. These industrial minerals occur in a wide range of rock types and geological ages. For example clays are known from the weathering products of Cretaceous rhyolite and leaching of Eocene coal measures; from Quaternary weathering of contemporary loess and shallow marine sediments, and of greywacke of Triassic-Jurassic age; and from the hydrothermal alteration of Late Cenozoic acidic volcanic rocks.

Jan 1, 1982

By Dennis N. Poffenroth

One concern of the Mine Safety and Health Administration is the structural integrity of steel wire ropes used on mine personnel hoists and elevators. Failure of such ropes has resulted in loss of life and property. Although thorough and regular visual examinations are performed, hoist ropes may still fail from undetected internal wear, corrosion, and broken wires. To complement visual examinations, nondestructive rope inspection techniques have been developed to determine deterioration and removal criteria. The techniques use electromagnetic and permanent-magnet test instruments designed by a Canadian firm. This paper describes the operating principles, field and laboratory testing of these nondestructive testing instruments, and discusses the feasibility of using this type of testing as a supplement to visual examination and destructive tests.

Jan 1, 1982

By D. Doyle, T. Cienski

"This paper presents and discusses the results of a detailed study conducted on the subject of energy consumption in the comminution of industrial minerals. The study was based on pilot circuit testing, plant operating data collection, detailed equipment data and literature research. The areas covered by investigations include: high efficiency classification; air classifiers for cement grinding circuits; grinding aids in dry grinding; and dry grinding circuit control based on particle size measurement. Results obtained indicate a large potential for the reduction of energy consumption, in particular in the cement clinker grinding circuits. Better classification techniques and correct application of grinding additives can significantly reduce power used per tonne of product and also substantially increase grinding circuit output."

Jan 1, 1992

By P. T. Brooks

Mineral nodules from the ocean floor represent a vast potential source of manganese, nickel, cobalt, and copper. Process development studies to devise methods for recovering these metals were conducted by the Bureau of Mines using two types of nodules--relatively low-grade calcareous nodules from the Atlantic Ocean and higher grade siliceous nodules from the Pacific Ocean. Ammoniacal carbonate leaching of reduced nodules appeared to have the best potential for processing the calcareous nodules, but the method proved to be impractical for recovering manganese. Extraction of 90 percent or better of the nickel, cobalt, and copper showed the technique to be attractive for recovery of these metals. The siliceous nodules appeared amenable to a process that starts with either a sulfur dioxide leach or a sulfation roast followed by a water leach to dissolve the soluble sulfates.

Jan 1, 1971

By Hernando Labarthe

El presente trabajo señala los posibles soluciones a problemas encontrados en el diseño de una planta de beneficio en nuestro país. Para ello, es necesario considerar cuáles son los factores que ocasionarían esta dificultad como el costo de producción, economía de espacio, almacenamiento de minerales, etc.y en el que tanto la ingeniosidad y experiencia del diseñador son relevantes, para que el mejor diseño del proyecto no altere la economía del proyecto en sí mismo.

Jun 20, 1954

By Lon Santis, David Leidel, John Tatom, Meredith Hardwick

This paper describes the development and methodology of the Institute of Makers of Explosives’ Safety Analysis for Risk (IMESAFR), a risk analysis software program for commercial explosives operations. IME is a nonprofit safety and security association devoted to the safe and secure manufacture, transportation, storage, and use or disposal of commercial explosives in the US and Canada since 1913. The software methodology’s basis is the U.S. Department of Defense Risk Based Explosives Safety Criteria Team’s Safety Assessment for Explosives Risk (SAFER) software. A diverse group of industry and government experts contributed to modifications to SAFER that reflect commercial operations. IMESAFR is intended to supplement the American Table of Distances (ATD) and offer standardized methods of managing risk from a wide variety of commercial explosives operations where the ATD does not apply. The modifications made to SAFER primarily involved the addition of commercial activities and potential explosives sites (PES). A review of commercial explosives accidents and operations over the last 20 years served as the basis for establishing probability of event values. An industry survey of commercial PES types in the U.S. and Canada was conducted to identify and address critical differences in commercial structures as compared to the military structures in SAFER. The paper concludes with discussion of the potential uses for quantitative risk analysis (QRA) and a description of other explosion effects software

Jan 1, 2007

By Richard L. Jenkins

Systematic sampling, in reconnaissance fashion, of the continental shelves of the United States to define favorable areas of offshore mineral deposits, is one of the long-range marine mineral; programs of the U.S. Department of the Interior. In mid-1966 the Department of the Interior launched its Heavy Metals Program to stimulate domestic output of gold which is in serious short supply. The program is jointly conducted by the Geological Survey and the Bureau of Mines.

Jan 1, 1968

The Waste Isolation Pilot Plant (WIPP) is a geologic repository for disposal of transuranic waste and is operated by the US Department of Energy. The repository is located at a depth of 655 min the Permian age salt beds of the Salado Formation. The exhaust air from the facility is independently monitored by the Environmental Evaluation Group to verify compliance with regulatory release limits for radioactive materials. A May 1995 video inspection of the exhaust shaft identified fluid migration into the uppermost 25 m of the shaft. Since then, water has been observed flowing in from cracks in the shaft lining between 16and 25 m below surface level at an estimated rate of between 5 and15 m3/d. This water inflow has not only negatively impacted the equipment in the shaft, associated duct-work and monitoring equipment located at the top of the shaft, but also challenged efforts to verify compliance at the WIPP. This paper provides an analysis of these effects.

Jan 1, 2004

By E. L. Frueh

AMAX Base Metals Research & Development, Inc. has developed a process for treating copper-nickel mattes to produce copper cathodes and a pure nickel sulfate solution. In this process, the input matte is preleached in a copper sulfate electrolyte bleed solution so as to dissolve nickel from the matte and cement copper from solution. The preleach leaves a substantially pure nickel sulfate solution. The residue from the preleach is roasted to less than about one percent sulfur. A portion of the calcine is leached with sulfuric acid to make a copper sulfate solution for input to the tank house. The residue from this leach and the remaining calcine are smelted to form a bimetallic (copper/nickel.) anode. The anodes are electrolytically refined and copper is preferentially deposited on the cathode while the nickel reports to the electrolyte, A bleed stream is taken from the electrolyte and used in the preleaching of the input matte. This process produces high purity metal streams while consuming less energy and smaller amounts of reagents as compared with other matte processes.

Jan 1, 1983

By J. K. Neathery, T. X. Li, H. Ban, J. L. Schaefer, J. M. Stencel, X. K. Jiang

Pneumatic, triboelectrostatic processing of physical mixtures containing fine (-200 mesh) particulate may have significant application potential in the mining and energy industries. Such dry processing methods, especially for finely comminuted materials, have not been examined in as much detail as wet processing methods nor have been part of the training or education of mining and process engineers. We have examined fundamental and applied physical and engineering factors controlling triboelectrostatic beneficiation of fine-sized physical mixtures, one of which - combustion fly ash - has size, heterogeneity and mineral concentrations typical of those expected in mined minerals. The applicability of dry processing, however, cannot be readily evaluated because of the unavailability of standard procedures for process assessment.

Jan 1, 1999

By Jackson de Brito Simões

As Ligas com efeito de Memória de Forma (LMF) são metais funcionais que podem recuperar grandes deformações, superiores a 5%, quando submetidos a carregamento mecânico e/ou aquecidos. Este fenômeno ainda surpreende pesquisadores e engenheiros de projetos, materiais e processos. Esses metais possibilitam o desenvolvimento de atuadores termomecânicos capazes de gerar esforço mecânico com o bloqueio da recuperação de forma. Inúmeros são os processos para obtenção dessas LMF, cada um com sua particularidade e limitação específica. Nesse contexto, este trabalho avalia o efeito do reprocessamento pela técnica Plasma Skul Push-Pull (PSPP) e do tratamento térmico de solubilização nas propriedades térmicas de transformação de fase de uma LMF 55,1Ni-44,9Ti (% em peso) obtida originalmente pelo processo de fusão por indução a vácuo (VIM). Para isso, a LMF foi refundida com uma tocha de plasma e vazada sob pressão em quatro moldes metálicos distintos (aço, bronze, alumínio e cobre). As técnicas de caracterização térmica Calorimetria Diferencial de Varredura (DSC) e Resistência Elétrica em função da Temperatura (RET) foram utilizadas para avaliar o efeito desse reprocessamento e do subsequente tratamento térmico de solubilização a 850°C em diferentes tempos. Verificou-se que a injeção em molde metálico proporciona uma significativa redução nas temperaturas de transformação de fase, da ordem de 30°C em relação ao material bruto obtido por VIM. Por fim, foi possível concluir que a LMF NiTi reprocessada mantém a transformação de fase mesmo após tratamentos de solubilização a 850°C em tempos mais longos (8 h), contrariamente ao material originalmente obtido por VIM.

Aug 16, 2017

By L. B. Pankratz

The Bureau of Mines conducted heat-content measurements above 298.15° K for dehydrated analcite (NaAISi2O6) to 1,000°K, kaliophilite (KA1Si04) to 1,800° K, and leucite (KAlSi206) to 1,800° K. Heat content and entropy increments were tabulated, and the heat content data, were given in equation form. A first order transition was noted for kaliophilite near 810° K with a heat absorption of 160 cal/mole. Leucite had a second order transition which became complete near 955° K. In this transition a crystal change occurred from tetragonal (low-temperature form) to cubic (high-temperature form).

Jan 1, 1968

By Paul A. Rittenhouse

Its a pleasure to be with you this afternoon and to talk briefly on one of my favorite subjects -- the U.S. sulphur industry. As our Chairman mentioned, I have been associated with the sulphur industry either directly or indirectly for the last twenty years, both on the production side and as a consumer. Sulphur, while unseen and relatively unknown to most people, is like margarine ... that ubiquitous spread ... that is yellow and nearly omnipresent in the industrial world. It is because sulphur, in some form, is required in nearly all aspects of our economy that makes its study so interesting to me as a researcher. An analysis of the sulphur outlook requires examination of such industries as fertilizer, paints and pigments, copper and zinc, uranium, petroleum, chemicals, pulp and paper and textiles - just to name a few. Of course, because its use is so widespread and ever-changing it is difficult to develop and maintain a good understanding of the sulphur industry. It is also a problem to cover the industry in a short discussion and to project its really dynamic nature. Hut, if you will bear with me, I will attempt the task. First of all, let me say that sulphur today is a world commodity and to a large extent moves freely in world trade; nearly a third of the world's sulphur or something over 15 million tons in 1974 entered international trade. However, today our interest is in the current changing sulphur picture in the U.S., with particular emphasis on the western part of the country.

Jan 1, 1975

By Robert H. Richards

Tuns truly remarkable machine was built on a preliminary scale in May, 1895. The first full-sized table was built by Mr. A. R. Wilfley, and was used in his own mill in Kokomo in May, 1896. The first table sold for installation was placed' in the Puzzle mill, Breckinridge county, in August, 1896. The mill enthusiasts at first hailed it as the cure for all the ills that flesh is heir to in the milling line. A little later it was found to make losses which were serious, and on this account the table succeeded only to a limited extent in displacing the vanners of the gold-mills. Still later, mill-men in a number of districts throughout the country made special studies of the faults of the machine, and devised a number of ways of grouping supplementary machines to overcome as far as possible the losses, and at the same time retain the benefit of the extraordinarily large capacity accompanied by the production of clean concentrates for which the machine has become so justly famous. I hope to make an exhibit of some of these methods in an appendix to my book on ore-dressing which is now in preparation. These experimenters have not written up the subject, and if they possess all the facts they have not given them out for the benefit of the mining profession at large. The object of this paper is to obtain the facts and to pre¬sent them so clearly that their bearing can be seen by all. To this end two complete series-'of tests have been planned. One (the present paper), to study concentration of galena in presence of quartz; the other (to follow shortly), to study concentration of chalcopyrite in presence of quartz. Some authorities claim that the table does its best work when treating natural products; by this phrase I mean products which have been crushed to pass through a limiting

Jul 1, 1907

By William C. Brice

Minnesota is involved in planning controversies related to taconite and potential copper-nickel mining. Mine facility planning includes the Reserve dining on-land tailings disposal issue and the potential for a new copper-nickel mining district. Both provide a unique opportunity for innovative planning in the attempt to be responsive to public and private interests. Concerns that emanate as a result of mineral resource activities include environmental protection, land use competition, land exchanges, highway and utility extensions, and legal constraints on public or private lands. The purpose of this newly-developed planning approach is to anticipate such issues and provide a rational information base for dealing with them. The result will be a framework plan for guiding public planning, and an impact assessment for reviewing the implications of industrial project proposals. The approach uses a computer-stored resource inventory of natural and cultural information. Geographic data is mapped and entered into a computer storage and retrieval system. This enables systematic analysis of mineral resources along with environmental and land use considerations. Computer mapping describes the relationship of each activity and allows identification of potential conflicts; it also shows geographical extent in the form of statistical compilations. Resource data is being collected and compiled using a standard metric grid (Universal Transverse Mercator). Individual cells are 100 m. squares and represent areas of about 2.5 acres. The study area contains about 145,000 cells. Data inventories are being compiled in 25 natural and cultural resource categories. Geologic variables include Bedrock Geology, Taconite Reserves and Potential Resources, Depth to the Duluth Complex Contact and two soil inventories. Topographic and hydrologic variables include elevation, slope, slope orientation, surface hydrology, and watersheds. There are also 6 biological data variables and 7 land use inventories.

Jan 1, 1977