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By William A. Apel

Several different strains of bacteria have been shown capable of reducing hexavalent chromium, Cr(VI), to Cr(III), a less toxic, .. more readily recoverable form of Cr. This paper examined the Cr(VI) reduction efficacies of 3 different Cr(VI) reducing bacteria: Pseudomonas f1uorescens LB300., Pseudomonas aeruginosa PAOI, and Pseudomonas aeruginosa PAOI (pCROI) It was demonstrated that all three bacterial stratns reduced Cr(VI) primarily during their exponential growth phases while using glucose as their carbon and energy source. Significant differences in the three organisms' Cr(Vl) reduction capabilities depending on initial Cr(VI) concentrations were also demonstrated. P. aeruginosa PAOI showed superior Cr(VI) reducing capabilities over the. entire range of Cr(VI) concentrations tested while the Cr(VI) reduction capabilities of the other two strains were increasingly inhibited as Cr(VI) concentrations increased.

Jan 1, 1991

By S. Chander

The formation of surface films on pyrite has been studied through electrochemical techniques of cyclic voltametry and AC impedance measurements. The characteristics of the surface films depend upon the conditions of oxidation and the source of pyrite. At potentials near 0.0 V, some pyrites have large values of polarization resistance showing a certain degree of passivity. Some pyrites show more passivation than the others, however. On oxidation, metastable phases of Fe(OH2) and Fe(OH3) form which transform to more stable 3 phases on aging. The growth of surface films near the corrosion potential of pyrite follows a linear kinetics which is attributed to a chemical (or an electrochemical) reaction as the rate determining step. The surface film is considered to be a hydroxide or an oxide rather than sulfur because the later is expected to be limited to a monolayer in alkaline solutions. This study has also demonstrated that AC impedance measurements can be used to study the growth characteristics of films at mineral/ solution interfaces.

Jan 1, 1987

By K. I. Savage, S. C. Sun

This paper describes a process developed to recover coal, clays and pyrite from coal wastes. The process consists of fine grinding followed by coal and pyrite flotation which leaves the clays in the flotation pulp. A bituminous coal refuse containing 10% sulfur and 30% carbonaceous material was treated by this method to yield a coal product containing 4% sulfur, 10% ash; a pyrite product containing 45% sulfur (84% FeS2), 1% carbonaceous material; and a clay product containing 2% sulfur (3.5% FeS2). The coal yield was about 89%. The pyrite yield was about 77%. The process steps may be entirely flotation, or gravity separation (hydrocycloning) may be used to increase the pyrite : coal ratio in the flotation feed. Cost estimates for the process show a profit of $2.28 per ton of low pyrite grade refuse, but these do not include labor, maintenance, overhead and plant depreciation. The development of this process consisted of three parts: (1) exploratory tests, (2) op-timazation tests and (3) confirmatory tests. The objectionable qualities that sulfur imparts to coal have been commented upon from early times, and they have become more objectionable as the uses of coal have grown. In whatever form coal takes — raw, carbonized or gasified —the sulfur content remains objectionable, and therefore its compounds are removed as completely as possible. It has long been known that sulfur occurs in coal in different forms. In 1861, sulfur was said to exist in the state of sulfuric acid in combination with a base; in combination with iron as iron pyrites; as bisulfides of iron; and in combination with the organic elements of coal.' Pyritic sulfur is a term loosely used to cover the sulfur associated with iron in its various forms. The mineralogically recognized forms are pyrite (FeS2), pyrrhotite (Fe 1-x S) and marcasite (FeS2). The particle sizes of pyrites vary widely. Isolated grains of marcasite smaller than 15 microns have been found disseminated through coal.2 Hair-like "veins" of pyrite filling cracks in vitrain have been found. At the other extreme, lumps or nodules of pyrites large enough for removal by hand picking have been encountered. Organic sulfur, unlike pyritic sulfur, does not exist as discrete particles, but is instead intimately associated with the coal structure and thus it is impossible to remove it or reduce its concentration by physical or mechanical means.2 In the preparation of coal for its various markets, the pyrite minerals (pyrites) are separated from the raw coal feed. This separation process concentrates the pyrites in the tailings or other waste products. It would be desirable to recover these pyrites for three reasons: (1) Pyrites are potential sources of sulfur and iron. In 1967, for the fifth consecutive year, Free World consumption of sulfur exceeded production.3 Propelled by the shortage, the domestic price of sulfur has risen from $24 to $38 per long ton (bright). (2) The refuse, when placed in piles, becomes ignited. The pyrites (FeS2) bum, giving off SO,. Thus, the pyrites are a cause of air pollution. (3) Also, the pyrites undergo chemical reaction when exposed to air. The refuse is leached by waters which result in stream pollution due to the water-soluble iron and acidic reaction products. Coal refuse also contains coal minerals and clay minerals. Therefore, any process for recovering the pyrites must successfully separate them from the coal and clay minerals. In the study discussed here, ten different bituminous coal refuse samples were successfully upgraded in pyrite content. These samples represented a wide variety of coal waste materials from Pennsylvania and other states. The variabilities of the sulfur and coal contents are shown in Table I. The extremes are Sample J, a high sulfur-low coal, and Sample B, a low sulfur-high coal. Definitions of some of the symbols or terms used in this report are given below: Mesh size—Tyler standard mesh screen sieves with an opening based on the square root of two. Fe —Indicates iron, as determined by a stannous reduction-dichromatic oxidation method. S—Indicates sulfur, as determined by the ASTM "Eschka" method for sulfur in coal.

Jan 1, 1969

By Maleki. Hamid

The U.S. Bureau of Mines implemented an inte¬grated static and geophysical monitoring program in a southern Wyoming mine to study changes in seismic wave propagation properties in roof strata. The purpose was to develop techniques to assess roof stability problems. The work consisted of record¬ing deformation and stress histories and calcu¬lating seismic velocity profiles. In addition. geology and roof conditions were mapped; the in¬struments were initially installed at the develop¬ment face; monitoring continued until the mecha¬nized retreat face retreated within 60 m of the instruments. Mining geometry consisted of a three-¬entry gate system using 5.2-m-wide pillars at depths of 426 m. Results were analyzed using stan¬dard history plots, velocity tomographs, and numer¬ical modeling techniques. Changes in velocity. frequency, amplitude, dynamic elastic modulus, and dynamic Poisson's ratio were related to roof defor¬mation, fracturing, and support requirements. A reduction in seismic velocity of 17 pct occurred after 60 mm of roof deformation following installa¬tion of supplementary support. Static measurements revealed significant dilation in the mine floor, spreading to the pillar and the mine roof. Failure was initiated in the floor as a result of uniform pillar penetration.

Jan 1, 1993

By Michael P. Hardy

The report described improvements and applications of the Hybrid Computer facility. Improvements implemented under U.S.B.M. Contract H0252035 included expansion of the capability to model nonlinear seam behavior, installation of a color video output display monitor, and further development of software capabilities. To demonstrate the capability of the system, firstly, the influence of nonlinear seam behavior response to the occurrence of coal mine bumps was fully investigated and secondly, the effect of improper mining sequence on bump occurrence was demonstrated. In addition, the system was applied to the analysis of a series of practical coal mine problems. Mines in three coal seams were analysed to investigate the parameters which contribute to the occurrence of coal mine bumps.

Jan 1, 1977

By Margaret Armstrong, Chris Roth

Abstract -Estimating ore reserves for vein type deposits is a two-stage procedure: first, calculate the geometry of the vein system, and second, estimate the grades within this system. The grade estimation can only be consistently performed if the vein geometry - its size, shape and orientation - has been correctly characterized. Getting the size and shape of the different veins right means that the ore tonnages will not be artificially inflated, e.g., by falsely classifying host rock as veins. Similarly, correctly estimating their orientation and location helps mine management decide on the appropriate mining technique, selective or not. When applying geostatistics to estimate the vein geometry all available information needs to be used and not just the standard lithologic indicator of being or not being in a vein.

Jan 1, 1998

By Don W. Dotson

In 1962, Kondner prepared several papers dealing with hyperbolic stress-strain response of cohesive soils. The following year, Brinch Hansen proposed 80% and 90% failure criteria for stress-strain behavior of cohesive soils. Fellenius was instrumental in popularizing these failure criteria for pile load tests and offered a direct solution equation for the failure load according to the 80% failure criterion. Since the 90% Criterion has been incorporated into the International Building Code, equations for the direct solution of the failure load at the 90% Criterion would be useful to practicing engineers. This Technical Note supplies the derivation methodology for the 80% Criterion and provides expressions to determine the load and deflection at failure for the 90% Criterion.

Aug 1, 2013

By W Medina, G Angulo, A Anani

A current challenge faced by the mining industry is solving the integrated transition mine problem (TMP) that maximizes the net present value (NPV). This study aims to develop an optimization framework capable of solving the TMP. The problem is NP-hard and therefore computationally intractable. Three ad hoc approaches – Exact solution, Benders’ decomposition, and Benders’ decomposition with Bienstock-Zuckerberg (BZ) algorithm – are compared for different scheduling periods. The TMP is formulated as a mixed integer linear programming model, implemented in Python, and solved with the Gurobi optimizer. The results showed that Bender's decomposition with the BZ algorithm outperforms the other approaches in execution time, computational cost, and feasibility to address large problems in exchange for a marginal cost in the quality of the NPV obtained. In addition, the probability of finding the optimal point of transition is higher regardless of the number of feasible crown pillar locations evaluated. This is achieved through the optimality cuts proposed in the algorithm.

Jun 25, 2023

By S C. Dominy

The grade of ore at Marvel Loch mine is directly related to the presence or absence of shear zones and quartz-sulfide-rich hornblende (¦ diopside) veining within areas of plagioclase alteration. An experienced geologist can identify these features in hand specimen. Practical rules have been developed to assist this visual identification. The structural sites and styles of alteration and veining most conducive to gold mineralisation have also been determined. The work has enabled a better understanding of the geological controls on mineralisation at Marvel Loch, and has clarified geological understanding for optimisation of grade control modeling, ore block mark-ups, and minimisation of ore loss and dilution during excavation. In addition to this, it has enabled a detailed understanding of mine scale structural controls, geometry and relative grade relationships.

Jan 1, 2003

By Ramdane Bahar

"Abstract The design foundations can be performed using Menard pressuremeter rules that require a limit pressure and a pressuremeter modulus. In recent years, another trend of interpretation of this test is appeared. It consists of identifying the rheological soil parameters using analytical or numerical methods and then used to evaluate the bearing capacity and settlement of soil foundations using numerical software. This paper deals with the bearing capacity and settlement predictions of bored piles using two approaches. The first one is the method called ""Pressident"" which is a numerical program developed to analyse pressuremeter tests taking into account the Duncan and Chang model. The second approach is the method developed by Bahar and Olivari based on the generalised elastoplastic Prager’s model with the Von Mises criterion which is suitable to describe the behaviour of saturated clays under undrained conditions. The pressuremeter data, collected on various research and consulting projects are used to explore the relationship between limit pressure and undrained shear strength obtained by the two methods. Numerical calculations, by FLAC2D software taking into account the rheological parameters derived from these two methods, are performed in order to predict the behaviour of a single bored pile subjected to an axial vertical load. The predictions are comparedto the measured data.IntroductionThe Menard Pressuremeter test has been used extensively to measure in situ soil properties and for the design deep foundations in Algeria. These tests are an useful and economical way for obtaining reliable in situ properties of soils and provide the measurement of in situ stress-strain response of soils. From this test, the design foundations can be performed using pressuremeter rules that require a limit pressure, pl, and a pressuremeter modulus, EM. These two parameters are derived from the pressuremeter curve or deduced from existing correlations with undrained cohesion and internal angle friction (Ménard, 1957; Amar and Jézéquel, 1972), and are used to evaluate the bearing capacity of soil foundations and the expected settlements. But, they can also help to identify usual soil parameters required by simple constitutive models for soils in numerical calculations."

Jan 1, 2014

By P. G. Flood

A simplified conceptual model shows how the arc flank to arc fringe areas adjacent to ignimbritic centres form a prospective zone for natural zeolites. Large alkaline lakes that serve as the repository of voluminous ash-fall tuffaceous material provide the ideal chemical setting for pervasive alteration of silicic glass to zeolites. The unusually old age of the Escott deposit demonstrates that any silicic volcanic province that contains low-temperature, unmetamorphosed sequences is a potential zeolite exploration target and that age should not be used as a criterion to exclude potential areas. It has also been demonstrated that heulandite and mordenite, formed by diagenetic alteration of silicic glass, do not always change to analcite and albite through the ageing process

Jan 1, 1991

By Knevitt L. T

PART 1Details of Kiewa Scheme.Introduction.Topography.Preliminary Investigations.Geology.Description of Project.Details of Main Works.Main Transmission of Power.Construction Facilities.PART 2Underground Works.Summary of Projected Works.Administration.Labour.Surveying.Safety and Accident Prevention.Medical Attention and First Aid.PART 3No. 4 Head Race Tunnel.Summary.Geology.

Jan 1, 1950

Silver is one of the three major metals produced from the Broken Hill mines. The accurate determination of the silver in these ores, therefore, is of economic importance.With due appreciation of the divergence of opinion of many who are interested in the subject of the determination of silver, the writer has been prompted to present the results of some recent experiments on silver losses during cupellation and conclusions from these experiments in the present paper. The losses of silver in the fire assay for this metal are due to silver retained in the slag during the fusion or scorification of the ore, and to silver volatilized from, and absorbed by the cupel during the process of cupellation.The literature describing the results of experimental work on silver losses due to the above causes is extensive, and the general conclusion of these experiments is that the silver lost in the slag is small, but that lost by cupellation is larger and more variable.The term cupellation loss in this paper refers to the total cupellation loss, no distinction being made between the absorption and volatilization losses.Volatilization loss is shown by King to be 0.5% of the total cupellation loss and, as it is generally accepted among assayers as being only a small fraction of the cupellation loss (3) (5), it will not receive further consideration in this paper.The factors causing the loss of silver by cupellation and the precautions to be obs~rved to reduce the loss in this operation are described in (1), (2), (3), (4) and (5). The...

Jan 1, 1940

By W. T. Lankford, Low J. R., Gensamer M.

The problem of sheet metal formability is one which has received a vast amount of attention during recent years. In spite of the great amount of study and experimental work which has been devoted to this problem, many of its fundamental aspects are still not well understood. No generally satisfactory test has been developed which is capable of providing a reasonably adequate evaluation of sheet metal formability, particularly in borderline cases. Anomalies persistently arise in which a lot of supposedly satisfactory material exhibits excessive breakage when formed. This lack of suitable technological tests greatly hinders the design of new parts and the substitution of new materials in parts of existing design, frequently necessitating considerable costly trial and error experimentation on an actual production basis. When, at the beginning of World War 11, it became apparent that mass production methods of forming would bc required in the aircraft industry if the large numbers of military aircraft needed were to be supplied, renewed attention was focussed on the problem of sheet metal formability. It was widely recognized that the formability requirements placed on sheet metals had been steadily increasing in severity through the years, especially as greater and greater emphasis was placed on streamlined designs with the resultant freer application of doubly curved surfaces. The recent advent of several new high strength aluminum alloys of more limited formability than some of the older alloys also served to emphasize the need for new approaches to the problem. It seemed evident that progress in the technology of sheet metal forming would depend to a great extent on the development of more reliable criteria for the evaluation of formability. Although the problem is admittedly very complex, the most logical approach appeared to be through studies of the fundamental material properties of sheet metals, especially under complex stress conditions simulating those prevailing in actual forming operations. Most previous investigations have failed to make full use of existing knowledge of fundamental material properties, and in many instances have attempted correlations with properties which are now recognized as being ambiguous in nature. This investigation was undertaken, therefore, with the aim of developing methods for the study of the flow and fracture of sheet meta1s under combined stresses, and of making use of such methods as might be developed in

Jan 1, 1947

By Low J. R., Gensamer M., W. T. Lankford

The problem of sheet metal formability is one which has received a vast amount of attention during recent years. In spite of the great amount of study and experimental work which has been devoted to this problem, many of its fundamental aspects are still not well understood. No generally satisfactory test has been developed which is capable of providing a reasonably adequate evaluation of sheet metal formability, particularly in borderline cases. Anomalies persistently arise in which a lot of supposedly satisfactory material exhibits excessive breakage when formed. This lack of suitable technological tests greatly hinders the design of new parts and the substitution of new materials in parts of existing design, frequently necessitating considerable costly trial and error experimentation on an actual production basis. When, at the beginning of World War 11, it became apparent that mass production methods of forming would bc required in the aircraft industry if the large numbers of military aircraft needed were to be supplied, renewed attention was focussed on the problem of sheet metal formability. It was widely recognized that the formability requirements placed on sheet metals had been steadily increasing in severity through the years, especially as greater and greater emphasis was placed on streamlined designs with the resultant freer application of doubly curved surfaces. The recent advent of several new high strength aluminum alloys of more limited formability than some of the older alloys also served to emphasize the need for new approaches to the problem. It seemed evident that progress in the technology of sheet metal forming would depend to a great extent on the development of more reliable criteria for the evaluation of formability. Although the problem is admittedly very complex, the most logical approach appeared to be through studies of the fundamental material properties of sheet metals, especially under complex stress conditions simulating those prevailing in actual forming operations. Most previous investigations have failed to make full use of existing knowledge of fundamental material properties, and in many instances have attempted correlations with properties which are now recognized as being ambiguous in nature. This investigation was undertaken, therefore, with the aim of developing methods for the study of the flow and fracture of sheet meta1s under combined stresses, and of making use of such methods as might be developed in

Jan 1, 1947

By Mutton B. K

Hilton Mine is being developed as an integrated component of the Mount Isa operation, to achieve continuity of silver/lead/zinc production well into the next century. The mine has a chequered history from its discovery in 1947 through several periods of intense development activity, each of which has been curtailed due to the further development of the Isa Mine operation. This era has now passed; to sustain increased production rates at Mount Isa, there is a requirement for Hilton ore in 1989. The decision was made in 1983 to accelerate the programme of Hilton development by installing skip hoisting facilities in the main service shaft (P49), to facilitate the development of the mine to pre-production status. The Hilton development plan provides for the mining of selected orebodies, a broadening of the underground exploration drilling programme, and the establishment of significant mine infrastructure. Several technical challenges have been identified as important. The Hilton orebodies, although occurring in the same rock type as Isa Mine, are more faulted, jointed and intersected by intrusive dykes. The ore is more variable in terms of ore continuity, boundaries, grade and metal distribution and the mineralogy more complex. As a consequence the development of this project consists of a co-ordinated programme of mine exploration and development, rock mechanics investigations and metallurgical research and development work. Production will commence in 1986 at a rate of 1000 t/day using mechanized cut and fill techniques. It is planned to introduce sublevel open stoping and by 1996/97 the production rate will be 2.5 million t/yr.

Jan 1, 1986

By F. Mucciardi

While flash smelting and converting are capturing a greater share of the market, injection through circular injectors will remain with us for the foreseeable future. The use of top lances for injection is a key feature in several processes (e.g. Mitsubishi, Ausmelt). Tuyeres, on the other hand, are incorporated into a number of processes (e.g. Noranda, Peirce-Smith). To date no lances or tuyeres are cooled by an external source. The reagent provides the bulk of the cooling. With limited cooling, it is normal to have substantial wear on the nozzles - especially in the case of lances. To overcome the issue of wear, a new patented injector (lance or tuyere) has been developed by Noranda and McGill University. This novel unit is based on heat pipe technology. It can operate for an extended period of time without wearing. Enhanced lance/tuyere life is achieved by operating the injector at a low enough temperature that promotes the formation of a thin frozen layer on the outer body of the unit. The vaporizing and condensing substance within the unit acts to cool' the high heat flux portions and dissipate the heat to areas of low heat flux outside the vessel. A fairly large number of tests have been conducted with a prototype unit. The tests have shown that the heat pipe lance is a viable unit. In this paper is detailed a test which illustrates how the lance functions when pure oxygen is injected into copper matte. In addition, the findings from a basic study of a heat pipe in high heat flux environments are also presented.

Jan 1, 1999

By B. Sereda

As it is known the creation and development of new titanic alloys has been problematic up to now. They can be used in aircraft and vehicle construction, shipbuilding and as materials for keeping static loadings in high-temperature environments. In this work the synthesis of various titan aluminides is investigated. Mathematical model of structurization process was done. On the base of retrieved model the mechanisms of structurization in systems Ti + Al and Ti + 3Al was determined. Experimental researches were done at two different modes: burning and thermal spontaneous ignition. The method of retrieving compacted products combusted in SHS conditions (SHS-compacting) was used to gain these intermetallic compounds. The physical and thermal characteristics of technological process and their influence on structurization, homogeneity of structure and porosity of titan aluminides have been simulated and researched. It is established that the SHS-compactizing technology is fully capable of supervising the process of structurizations with the whole complex of advantages and can be applied for receiving qualitative titan aluminides with the set of chemical-physical properties.

Jan 1, 2010

By Craig T. Jones, Zachary Q. Maassen

"Jet grouting is a method of ground improvement that relies on the erosive capacity of high-speed jets to cut and mix the ground in place with a cementitious grout. A continuous return flow of cuttings, called jet grout backflow or spoils, is expelled to the surface during the grouting process. Data from projects completed in Toronto and Ottawa is presented where BOS Solutions’ services provided significant savings compared to the traditional spoils treatment utilizing vacuum trucks for spoils disposal. These traditional treatment methods are cumbersome and expensive by nature. BOS Solutions provided an alternative solution that is environmentally friendly and capable of handling full flow to process these jet grout spoils utilizing a tank system paired with centrifuges and flocculation additives to remove the ground soils and grout product from the spoils slurry. BOS’ process produced a clean water for reuse in the project while reducing the overall waste volume by producing a dry, stackable solid that could be hauled to a landfill. Benefits observed by using the BOS process were disposal waste volumes decreased over 30% and at least a 19% reduction on disposal costs.SCOPE OF WORKJet grouting is a method of ground improvement that relies on the erosive capacity of high-speed jets to cut and mix the ground in place with a cementitious grout. A continuous return flow of cuttings, called jet grout backflow or spoils, is expelled to the surface during the grouting process. The backflow, or spoils, is a mixture of grout, water and soils. Traditionally, the spoil would be collected in in-ground pits and allowed to solidify for a few days prior to hauling to a final disposal site. For the projects completed in Toronto and Ottawa, the jet grouting work was performed at street level, in high traffic congested areas, presenting the challenge of insufficient space for the contractors to process the jet grout spoils in the traditional way. At first, attempts were made of using vacuum trucks to collect and haul the wet spoils to an off-site location where the spoils would be allowed to solidify. However, this method proved cumbersome and expensive due to the high volumes of spoils generated daily and the high number of vacuum trucks required to support the jet grouting operations, respectively."

Jan 1, 2017

By E. R. Weltevreden, C. Klauber, C. Vernon

"In this paper a review of the current status in recycling technologies for cathode ray tubes is given for both the glass and phosphors. Particular emphasis is placed on the opportunities for the recovery of the rare earth elements (REE) from the phosphor coatings. This is placed in the market context of alternative virgin sources and some of the advantages and disadvantages for REE waste recovery. Future opportunities are explored and also some experimental detail on a low cost leach system is presented. INTRODUCTIONThe disposal of cathode ray tube (CRT) based colour televisions has accelerated world-wide with the development of high definition flat screen panels. The total number of colour CRT televisions that have been sold in the United States in the mid-20th century is estimated to have been over 2 billion (U.S. Environmental Protection Agency, 2007), with high current rates of disposal. It is estimated that of the 20 million televisions annually discarded, 78% are send to landfill (Nnorom, Osibanjo & Ogwuegbu, 2011). However, this easily accessible item of electronics cannot only be turned into a valuable resource using the right recovery procedures, it can also prevent the substantial environmental contamination arising from improper disposal. In this review we focus on previous and current work performed on the recycling of CRT based televisions. Due to the increasing demand for rare earth metals, the main focus will be on the possibilities and challenges of recycling the fluorescent phosphor powders on the CRT’s panel glass.CATHODE RAY TUBE’S GLASS RECYCLINGConventional cathode ray tubes consist of three main parts, the panel, the funnel and the neck (Figure 1). To produce the different colours on the screen, the inside of the panel is coated with a matrix of hundreds of thousands of small phosphor dots. Each dot is one of three types of coloured phosphors, emitting either red, green or blue light. These emit light when excited by a beam of electrons generated by electron guns located in the neck of the CRT. These beams pass through holes in the shadow mask and excite the phosphor coating on the inside of the panel, to give light of variable RGB composition, see Figure 1."

Jan 1, 2012