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By H. R. Wells

The Blackbird district, Lemhi County, Idaho, has long been recognized as a potential source of cobalt and copper. However, the comparatively low grade and small size of the known ore bodies, the small demand for cobalt, and. the lack of adequate roads throughout the region precluded extensive exploration of the early discoveries in the area. Recent advances in alloy metallurgy, accentuated by wartime activities, greatly increased the demand for sources of domestic cobalt. Beginning In 1941, engineers of the Bureau of Mines conducted an examination and exploration program in the Blackbird district. This work was supplemented by an exploration program by engineers of the Howe Sound Mining Co., 730 Fifth Ave., New York 19, N.Y.

Jan 1, 1948

By Hee-suk Yun, Dae-jin Hwang, Jeong-woo Seok, Myoung-mo Kim

"In this paper, the accuracy of the data measured by a newly developed displacement measuring system, DPRMs (Digital Pile Penetration and Rebound Monitoring system) and its applicability as a quality control tool were verified by field measurements of pile penetration and rebound for pile driving performed at 3 construction sites and 1 test site. The DPRMs data were found to be much better than handwork data. A new dynamic formula for pile capacities is proposed uses the results of a pilot dynamic load test and the final pile penetration. The ratios of pile capacities obtained by the new formula to those by the dynamic load test were 94%±7.4% in the contrast with 123±28.3% by the 5S formula and 68±24.0% by Hiley's formula. This result shows the superiority of the new formula. The ratios of the maximum compressive stresses calculated by using DPRMs to those calculated by using PDA (Pile Driving Analyzer) were about 90-110±10%. This result confirms the applicability of DPRMs as an overdriving monitoring tool. Two sets of DPRMs were used to measure the 3-D displacement behavior of a pile head at the test site. The more the pile head moves laterally, the less the final set values were expected because of the loss of driving energy, but this trend was not obvious within the limited data obtained at the test site.INTRODUCTIONPile construction monitoring consists of two parts. In the first part, enough capacity of the pile is secured to stand the design load. In the other part, pile damage during driving is prevented. Although several methods can be applied to achieve the first part, PDA is nearly the only tool for measuring pile stress.Several methods such as a static load test, a dynamic load test, an Osterberg cell, and numerous driving equations can determine the pile capacity. Among them, the static load test and the dynamic load test are most widely used. The static load test is advantageous because it has the highest reliability. The disadvantages are as follows: it is costly and time-consuming. Also, the capacity of the pile under construction cannot be evaluated. The dynamic load test has lower reliability than the static load test, but it is cheaper than the static load test, is reliable enough to determine the pile capacity, can evaluate the capacity of a pile during construction, and can offer information about construction conditions such as the pile integrity and the pi le stress during driving. The dynamic load test takes a relatively short time and is low cost compared with the static load test. However, it is still costly, time-consuming, and unnecessary to apply to all piles in the field as a construction measurement tool. Therefore, driving resistance (blowcounts) is commonly measured to confirm the pile capacity at construction sites."

Jan 1, 2005

By Zbigniew Lubosik, Andrzej Walentek, Stanislaw Prusek, Sylwester Rajwa, Aleksander Wrana

"Underground coal gasification (UCG) provides a solution to supply electricity from high ash coal or deep deposited seams. The coal is consumed in situ, and, accordingly, the ash is left underground. UCG could play a major role in the future of coal, which is expected to fuel 44% of the world’s energy in 2030, in a more environmentally friendly and commercially viable manner. Nevertheless, it is known that the UCG can impact the environment. One of the most important factors in safe UCG process should be the evaluation of rock mass quality and the monitoring of its behaviour. The changes of rock mass parameters and quality have an influence on numerous aspects, such as subsidence and the stability of underground workings in georeactor vicinity, however, they also increase the possibility of pollutant migration through fractures and pores. These issues are especially important in cases of gasification conducted in an operating mine or on areas of high ecological vulnerability. This paper details observations made in two underground trials of UCG performed in Poland recently. The first of which is the Experimental Mine Barbara (under the project entitled HUGE-2 Hydrogen oriented underground coal gasification for Europe – Environmental and Safety aspects, (Wiatowski et al., 2015). The other trial has been conducted at an operating mine, Wieczorek, which is in the framework of a research project on the development of coal gasification technology for highly efficient fuel and electricity production (Czaplicka-Kolarz et al., 2013). During these trials, investigations were carried out aimed at assessing geomechanical parameters of rock mass and support behaviour in surroundings of UCG geaoreactors. Investigation comprises assessment of geomechanical parameters of coal, floor and roof strata, roof displacements, and concrete support strength parameters variation, as well as standing steel support load. Hydraulic penetrometer, endoscopic camera, Schmidt hammer, pull-out method, telltale, and ground penetration radar (GPR) were used in the investigation. Research conducted at both EM Barbara and Wieczorek Collieries revealed that the UCG process did not adversely affected the competency of rock mass (expressed by number of fissures and strength parameters of rocks), the stability of roadways and the support performance in the areas located in the vicinity of the georeactors."

Jan 1, 2017

By Nobuyuki Masuda

In Japan, the municipal solid waste, which amounts to 50 million tons, is generated every year and most of it is incinerated. The fly ash from the municipal waste incineration (the primary fly ash) contains heavy metals, such as lead and zinc, etc., and dioxins. In case of melting, the fly ash from the process (the secondary fly ash) contains high concentration of heavy metals (e.g., Zn; 1-20%, Pb, 1-10%). Metal Mining Agency of Japan launched a four-year project in 1999 to establish the integrated technologies to recover the valuable metals from, and to decontaminate, the primary and secondary fly-ashes in the practical scale by utilizing the existing metallurgical processes and facilities, along with the energy saving. The segregation, flotation and chemical treatment are applied to the treatment of the primary fly ash. The secondary fly ash is treated with MY (Mitsui-type blast furnace) Process after the chlorine removal to recover the heavy metals in the ash, In this paper, the segregation and flotation process for primary fly ash and MF process for secondary fly ash are explained. The main results of experiments done from 1999 to the mid of 2001 to design the pilot plants and to optimize the operating conditions are described. The main results of the experiments are as follows: - The segregation reaction of Cu was confirmed by the experiment on the treatment condition of 800 and 900`C with adding oil cokes and water to the primary fly ash, and 99.98% (toxicity equivalent) of the dioxins were decomposed by the treatment. - Washing tests of secondary fly ash to feed MF resulted that more than 70% of chloride were removed, but still lower than expected, and agglomeration tests were successful by the results of the sufficient strength of briquettes produced though a little more binder for the agglomeration is required than usual operation. - Smelting experiment by downsized MF showed that valuable metals, such as zinc and lead, are recoverable in the furnace dust. Recovery ratios, Zn: 58% and 67%, Pb: 74% and 83%, are accomplished.

Jan 1, 2002

By T. Krumins, L. Zunti, R. Frischmuth

"Titanium and titanium alloys are commonly selected for pressure oxidation autoclave vent piping and pressure control valve components, as well as autoclave internals and other process piping. In the autoclave vent application, titanium ignition risk is controlled by limiting oxygen concentration, and preventing high gas velocity gas impingement on surfaces. Oxygen concentration is dependent on the autoclave pressure and temperature operating conditions and therefore oxygen concentration and the associated titanium ignition risk is dependent on standard operating procedures, process control interlocks and permissive conditions. It is not uncommon for these standard controls to be deficient during atypical operating conditions, or for operations to deviate from the operating procedures, increasing the potential for a titanium ignition incident. Titanium ignition risk caused by elevated oxygen concentration in autoclave vent systems can be reduced with the introduction of an online autoclave overpressure calculation and the configuration of associated interlocks and permissive conditions. INTRODUCTION High temperature pressure oxidation (>190°C) is a well recognized and versatile metallurgical oxidative pre-treatment process commonly used to liberate gold from refractory sulphide ores and concentrates before conventional leaching with cyanide. Titanium and titanium alloys are highly corrosion resistant in pressure oxidation process conditions and are therefore commonly selected as materials of construction for many components including: autoclave internals, agitators, process piping, and components in autoclave vent systems. Operations that anticipate or have experienced aggressive corrosion in the vent system often have little choice in material selection other than the use of titanium (Krag & Henson, 1992). Titanium is not suitable for use with elevated oxygen concentrations and is considered a restricted material because of its high pyrophoricity and combustion propagation properties (Beeson, Smith, Stewart, 2007). Several serious incidents have occurred in which titanium materials have ignited in autoclave applications (Zawierucha, McIllroy, Million, 1995). In autoclave vent applications, titanium ignition risk is reduced by preventing elevated oxygen concentrations, maintaining low gas velocities, and minimizing the potential for gas impingement on surfaces. Oxygen concentration in the autoclave vapour phase and vent system is dependent on the autoclave operating pressure and temperature conditions and therefore titanium ignition prevention controls typically include process interlocks and operating procedures based on the selected nominal design operating conditions. However, it is not uncommon for these controls to be deficient or for operations to deviate from the nominal operating conditions over time, increasing the risk of titanium ignition. The introduction of an online calculation of autoclave overpressure and a maximum target autoclave pressure as well as associated process control interlocks and permissive conditions can alert the autoclave control room operator and prevent an elevated oxygen concentration from developing, and therefore reduce titanium ignition risk in autoclave vent systems."

Jan 1, 2016

By Henry S. Washington

I. INTRODUCTION. DURING the last twenty years or so the chemical investigation of rocks has made great advances, and it is now generally recognized that a knowledge of the chemical composition is as essential as that of the texture or mineral composition-if not more so-for the proper classification of rocks and study of their origin and relationships. Rock-analyses have vastly increased in numbers and, what is of greater importance, in quality. New and improved methods permit of greater accuracy than was possible in the early days, and the list of chemical constituents frequently determined has risen from the seven or eight of the greater part of the nineteenth century to twenty or more. Indeed, rock-analyses with determinations of so many constituents are now commonly made by the chemists of the United States and Australia, while in Germany, Great Britain, France, and Italy the rarer constituents are determined more frequently than formerly. As a consequence of this modern, accurate work, it has been discovered that some elements which were formerly supposed to be rare are of wide-spread occurrence and are often present in considerable amount. The fact is further being developed that the elements tend to show certain relations of occurrence or abundance in connection with each other. This is a fact which is applicable to the rarer elements, and which also finds a broad geological and petrological expression in the recognition of petrographic provinces. We are beginning to obtain some definite, though as yet rudimentary, knowledge of the distribution of the elements among igneous rocks. Some of the results along these lines obtained by study of the vast accumulation of analytical data now available are well known to petrologists, while others do not seem to be so gener-

Sep 1, 1908

By Chuanshun Li, Haitao Zhang, Xuefa Shi, Quanshu Yan, Zhiwei Zhu

In Expeditions 22 and 26 of China Ocean Survey (COS), Chinese and Russian scientists have Carried out a lot of work to search for hydrothermal sulfide in Southern Mid-Atlantic ridge (SMAR) 19°S, but come back empty-handed at last. The sulfide formation is closely related with the water-rock reactions which are controlled by the heat source. Melt inclusions are considered to have a unique compositions in melt to reflect the deep magma processes. Fortunately, we have found a large number of plagioclase hosted melt inclusions in SMAR19°S MORB. We have done experiments by re-homogenization and re-crystallization of these melt inclusions. During the re-homogenization experiments, the forming and melting processes of the olivine crystal inside the melt inclusions indicate that the homogeneous temperature of melt inclusions is 1190-1200??. During the recrystallization experiments, the different mineral phase assemblages show H2O inside the melt inclusions has hardly ever been loss, in addition Cr element and H2O molecule in SMAR19°S magma are heterogeneity at the time of melt inclusions trapping, and then the re-crystallization experiments provide a method to prove the microheterogeneity of basaltic magma system. Combining with the bulk rock data, this study shows that the melt inclusions are formed at a low-temperature and high-pressure condition. Eventually, this paper speculates that a low temperature heat source generated by a lower mantle potential temperature or/and a thick lithosphere indicated by the melt inclusions that not experienced the H2O loss process are beneath the SMAR19°S. The low temperature heat source transmits its heat to lithosphere through the cooling thermal boundary layer (CTBL), and the thick lithosphere can sufficiently absorb and consume the heat. Under the interaction between the heat source and lithosphere, the residue heat at the infiltration depth of sea water might have been no ability to satisfy the water-rock reactions temperature, therefore, the water-rock reaction should hardly ever appear, so the theoretical reaction zone would not exist beneath the SMAR19°S. Eventually, the interaction between thick lithosphere and the low-temperature heat source should be the dominant factor that makes SMAR19°S area have no condition to form the seafloor sulfide. However, this paper is based on melt inclusions only, in fact, melt inclusions are potential to have melt compositions produced by mineral dissolution, reaction and assimilation, and the volumes of melt inclusions are exceedingly small compared to the overall size of the magmatic systems, therefore, the extrapolation across many orders of magnitude is implicit when applying petrologic information obtained from inclusions to entire magmatic systems. Therefore, there should have other more research to verify the reliability of this conclusion.

Jan 1, 2017

By Nancy E. Wilk

In 2015, more than 1.2 million deaths annually were estimated to be caused by occupational risks (WHO, 2018). In 2021, this estimate increased with the publishing of the World Health Organization (WHO) and the International Labour Office (ILO) Joint Estimates of the Work-related Burden of Disease and Injury based on data from 2000 to 2016 (WHO/ILO, 2021). These global estimates reported that each year 1.9 million people die from exposure to occupational risk factors, 81% of these fatalities resulting from non-communicable, occupational diseases. WHO/ILO notes that the health-related risk factors with the largest number of attributable deaths were exposures to long working hours followed by workplace exposures to particulate matter, gases, and fumes. The health outcome with the greatest work-related burden of deaths was chronic obstructive pulmonary disease, followed by stroke and ischaemic heart disease. In considering the 2021 data published by WHO/ILO, it is likely that the estimates are low and underestimate the true burden of occupational disease and injury. In support of that position, more recently the ILO estimated that “2.3 million women and men around the world succumb to work-related accidents or diseases every year; this corresponds to over 6000 deaths every single day” (ILO, 2022).

Jan 1, 2023

The control of AG mills fed by ores with harder and softer components can be challenging due to the sensitivity of the mill to the ratio of hard to soft components. The mills at LKAB?s iron ore operations are generally well controlled, but there are periods when the throughput falls off dramatically, due to a loss of mill filling. As the ore is upgraded in the sorting plant through magnetic separation prior to milling, this presents an opportunity to manipulate the feed blend in advance. In order to assess this opportunity, a fullscale mill charge was dumped and assayed by size to quantify the build-up of competent waste in the mills. This was supplemented by pilot and locked-cycle laboratory tests at a wide range of feed blends in order to facilitate the development of an appropriate multi-component AG mill model. This paper reports the experimental campaign requirements and methodologies, as well as the major outcomes from analysis and modelling exercises using the industrial, pilot and laboratory multi-component data.

Jan 1, 2012

By T A. J Hopper, S Mukkisa, M L. Johns, K T. O’Neill

Technological advances the sensor design and performance for logging while drilling (LWD) instrumentation offer considerable opportunities in iron ore exploration. Here we focus on the development of a nuclear magnetic resonance (NMR) LWD tool. NMR is an advanced geotechnical logging technology capable of providing in situ measurements of the porosity, pore size and permeability of the formation of interest. The ability to provide real-time characterisation of iron-ore systems is beneficial to both drilling operations as well as real-time formation evaluation. The development of an NMR LWD tool for mineral exploration drilling has previously not been achieved due to the significant technical and environmental challenges associated with the design and operation of such a tool. The tool outlined in this work is designed to work in reverse-circulation (RC) drilling systems. As such, the tool needs to be compatible with the RC drill-string, as well as being highly robust to survive the shocks and vibrations experienced during RC drilling operations. The magnetic physics of the probe must be capable of measuring at the appropriate depth into formation whilst being subject to the array of motions experienced during drilling operations. Furthermore, conducting accurate NMR measurements in an iron ore formation is challenging and the measurement methodology must be tailored to characterise the magnetic environment. The tool also requires high-powered electronics capable of operating the necessary pulse sequences for excitation and acquisition. The resultant tool design must therefore optimise the inherent trade-offs which exist between the physical components (ie mechanical structure, magnetic components and electronic hardware) in order to operate appropriately whilst not hindering RC drilling operations. Current experimental analysis of the prototype indicates that the current probe design exhibits the required measurement specifications and is nearing field testing. Future work will look towards commercialisation of the instrument.

Nov 8, 2021

By J. Wiedenroth

Since the end of the 1970s Pipe Conveyors have become increasingly important for conveying bulk materials because they have some specific advantages over conventional troughed belt conveyors. FLSmidth KOCH Pipe Conveyor represent the marked-leading know how of the former KOCH Transporttechnik GmbH, which belongs to the FLSmidth Group since January 2007. Pipe Conveyors from FLSmidth KOCH are already being used successfully at more than 260 locations around the world. Their special properties, their extreme flexibility, the horizontal and vertical changes in direction without transfer points, the small space requirement, the low-noise running and their optimum protection of environment and material without any additional casing mean that Pipe Conveyors can provide transport solutions that are often far superior to other conveying systems. The utilization of these many advantages will be illustrated in the following example of the world?s longest Pipe Conveyor at Cementos Lima, the Peruvian cement producer.

Jan 1, 2010

By Leslie H. Sharp, Martin J. Gavin

Those of the oil-shale operators in this country who are sincerely attempting to make a real industry out of oil-shale developments, are anxious to obtain fundamental data on the retorting of oil-shale; particularly as regards the effect of certain variable factors in the process of retorting on the quantity and quality of products yielded from oil shales when they are subjected to destructive distillation. From careful examination of a con siderable number of suggested processes for treating oil shales and the con flicting ideas on which they are designed, it seems probable that accurate information of a fundamental nature is highly essential to the successful establishment of an oil-shale industry in this country. . Accordingly, the United States Bureau of Mines, in cooperation with the State of Colorado, is undertaking to furnish some definite and impartial information of this type through investigations now under way at the University of Colorado, Boulder, Colo. A retort for the distillation of oil from oil shale has been designed and installed, together with the necessary auxiliary equipment for controlling and determining variable factors of distillation, and for recovering and de termining the quantity and quality of the products yielded from the shales. The retort is of such a nature that conditions of retorting can be accurately . and completely controlled, and varied at will. It is not designed as a com mercial retort, but only for research purposes. A testing laboratory with equipment necessary for the examination of the shales, physically and chemic ally, and the products yielded by them, has also been fitted up . The material used in the investigations is oil shale obtained from the DeBeque, Colorado, shale field. It yields on distillation in the Bureau of Mines testing apparatus, about 42 gallons of oil to the ton, and is there fore a fairly representative sample of the shales that probably will be first worked in Colorado. The shale used will be as uniform as possible in character and oil yield and will all be obtained from the same seam at the same point, in order to avoid the introduction of unnecessary variable factors in the tests and to render results strictly comparable •

Jul 1, 1920

By Christophe Bragard, Marte Gutierrez, Haotian Zheng, Michael Mooney

This paper proposes a framework for applying surrogate-based approaches to evaluate SEM construction, which can both benefit the uncertainty analysis in the design stage and real-time calibration during the construction process. The performances of four surrogate modeling approaches, namely back-propagation neural network (BPNN), support vector regression (SVR), random forest (RF), and polynomial chaos expansions combined with Kriging (PCK), were evaluated and compared. A variance-based global sensitivity analysis (GSA) was performed on the surrogate predictor to quantify the impacts of geotechnical parameters on the deformation responses induced by SEM tunneling. The Regional Connector Crossover Cavern project constructed in Downtown Los Angeles was set as the benchmark problem to demonstrate the efficiency and reliability of the proposed procedure.

Jun 13, 2021

By N. B. Aughenbaugh

The People's Republic of China has 582 Gt (641 billion tons) of proven coal reserves. At present, 576.5 Mt (635.5 million tons) of coal are mined a year which makes China the third largest producer of coal in the world. Underground mining accounts for 95% of the total production. This paper will discuss the coal districts, coal types, jurisdiction of coal mining, and methods of underground mining. The article also will outline China's objectives in future planning and development of its coal reserves.

Jan 1, 1982

Significant advances have been made in the design of centrifugal slurry pumps that are used for pumping high-density viscous and paste slurries. This paper presents the results of a series of centrifugal pump performance tests that were conducted using an FLSmidth 6 x 4 Krebs millMAX centrifugal pump. The pump was fitted with a dry mechanical seal to prevent dilution of the slurry from gland service water, as the theology of the slurry is sensitive to small changes in slurry density. Tests were done using paste kaolin slurry with Bingham yield stress values between 578-1 120 Pa and plastic viscosities between 728 and 1491 mPa.s. The viscous properties of the paste during each pump test were measured using a rotational viscometer. Pump head and efficiency de-rating were measured and compared to the correlations of Walker and Goulas (1984). The test data shows the pump's best-efficiency point (BEP) changes and shifts to the left of the performance curve. The pump efficiency decreases as the slurry yield stress increases. The head de-rating data shows more head de-rating at the low flow rates compared to the high flow rates for the high viscosity slurry, which is in line with the findings of Walker and Goulas (1984). This paper demonstrates that it is possible to pump very viscous, high yield stress slurries with limited head and efficiency de-rating using centrifugal pumps, provided that positive suction conditions are maintained at all times.

Jan 1, 2012

By Paul Queneau

FEW of us who waded ashore on the Norman beaches realized the importance of coal to a successful invasion. General Eisenhower and his staff had been aware of the essential need for coal and an able Solid Fuels Section had been set up under the direction of Colonel Robert P. Koenig, of Indiana. This organization met the requirements of the invading armies on their march to the Rhine. East of the Siegfried Line enemy territory, the Army Engineers were called upon for assistance. When the Engineers were advised that, in addition to their normal duties, they were to occupy and place in operation the coal mines in the Twelfth Army group area, plans were drawn up overnight and action was initiated immediately. The Sixth Engineer Special Brigade, a versatile outfit which made a notable record D-Day on Omaha Beach, was selected to handle the operation. Within 48 hours of the new assignment an advance command post was set up cm the west bank of the Rhine at Homberg, just below German-held Duisburg. The 368th Engineer General Service Regiment was assigned to the Brigade, and the British 44th Pioneer Group, including specialist personnel, was also attached. This large British unit was added because most of the mines would shortly come within the British zone of

Jan 1, 1946

THE John Fritz Medal Board of Award, at its regu¬lar annual meeting Oct. 19, awarded its gold medal to Herbert Clark Hoover. Thus ended a process of selection begun a few years ago. The award was tentatively made a year ago by the Board, which is composed of sixteen recent past-presidents of the four national societies of Civil, Mining and Metallurgical, Mechanical, and Electrical Engineers, having together a membership of nearly 60,000. The sixteen members of the Board are: American Society of Civil Engineers : C. E. Grunsky, Robert Ridgway, George S. Davison and John F. Stevens ; American Institute of Mining and Metallurgical Engineers: William Kelly, J. V. W. Reynders, Samuel A. Taylor and E. DeGolyer; American Society of Mechanical Engineers: Fred R. Low, D. S. Jacobus, Dexter S. Kimball and Charles M. Schwab; American Institute of Electrical Engineers: Farley Osgood, M. I. Pupin, C. C. Chesney and Bancroft Gherardi.

Jan 1, 1928

By G. D. Oxx, L. F. Coffin

The concept of using a phase that is liquid at service temperatures as a component of coatings for refractory metals has been described. The liquid, an alloy of gold and silicon, is retained on a molybdemum surface by a capillary system made of molybdenum disilicide. The coating has the advantage of good thermal shock and has a self-henling chracteristic. In order for highly stressed structures to exceed a service temperature of 2000°F, it has become apparent that a development that does not depend on the traditional iron, cobalt, or nickel-base alloy is needed. Alloys of the refractory metals, i.e., molybdenum, tungsten, tantalum. niobium (colum-bium), and rhenium are potentially useful at extremely high temperatures that more conventional alloys would never be expected to achieve. A new alloy of molybdenum has become available that has a 100-hr rupture strength of 35,000 psi at 2200°F.1 As a result of this work, it may be assumed that a material with adequate mechanical properties at 2200?F is now available. Unfortunately, this alloy and all other known alloys of the refractory metals suffer from not being; serviceable in an oxidizing atmosphere for a very long time. In order to permit general use of refractory metals at high temperatures, it is necessary to prevent destructive oxidation by appropriate alloying or by protective coatings. The liquid phase coating reported here is representative of a concept for the protection of metals that permits higher service temperatures and introduces a new group of materials for selection as coatings. Coating Requirements—Service conditions that represent potential applications for refractory metals vary considerably: however, it is possible to consider two conditions that are usually present. The refractory metal1 component must be heated to the service temperature at least once and usually frequently. When a solid coating is used, usually the coating and basis metal do not have the same coefficient of expansion. This difference causes thermal stress in the coating that is aggravated by rapid heating and cooling and eventually causes coating failure. The second consideration is the probability that there will be damage to the coating by some environmental condition. In jet engines, for example, it is expected that large particles, stones, metal parts, and so forth, will strike a bucket at high speed and cut a hole in the coating. In addition to the above considerations, the coating must also have other fundamental properties. Obviously, it must be oxidation resistant. In addi- tion, it must prevent permeation of oxygen and subsequent oxidation of the basis metal at the interface. Also, diffusion of the basis metal to the outside surface and subsequent oxidation there must be prevented. Finally, the coating must not react with the basis metal to form a weak bond at the interface. It should be noted that the coating need not support a load: it must only remain intact. Liquid Phase Coating Design Factors—In the use of a liquid as a principal coating constituent, it would be expected that the two service conditions mentioned above would be satisfied. A liquid would flow under the influence of the thermal strain developed by coating-basis metal expansion mismatch such that failure from this source would not be expected to occur. It is also probable that the ability of a liquid to flow would provide a self-healing effect. Thus, damage caused by particles in the atmosphere would be repaired. A third advantage is evident in that vapor pressure rather than melting point limits the service temperature. This latter advantage permits use of low melting but oxidation resistant metals such as gold or copper that would be quite useless if the solid state was required. A low viscosity liquid alone. however, is a totally unsuitable coating because it will simply flow off a component, particularly under the influence of a high acceleration field. A method of preventing liquid loss must be devised. In this case, it is desired that the liquid have a low viscosity so that it may easily flow into flaws; thus, raising the viscosity is not a satisfactory solution. One other inherent difficulty is caused by the high mobility of atoms in the liquid state as compared to the solid state. Because of this mobility, it would be expected that gases would diffuse more rapidly through a liquid. It is also probable that the solubility of oxygen in the liquid would be comparatively high. These factors would tend toward rapid permeation of oxygen and oxidation of the substrate. It is most reasonable that this problem could be solved by incorporating a solid phase, which is impermeable to gases, as a component of the coating. To overcome the tendency of a liquid to flow easily, it is possible to use surface tension to advantage. If the surface were made up of a large number of capillary tubes of sufficiently small diameter, then surface tension would hold the liquid even against the acceleration of a centrifugal field.

Jan 1, 1961

By W. H. Oppelt

A lignite from west-central North Dakota (Mercer County) was dried by the Bureau of Mines by the Fleissner process at saturated steam pressures to 1,500 pounds per square inch absolute (p.s.i.a.). Normally, the process is operated at pressures of 200 to 370 p.s.i.a. At the highest pressure the temperature of the saturated stearn is 596° F. The purpose of the investigation was to evaluate the influence of very high stearn pressure and temperature on moisture removal, steam consumption, and physical and chemical characteristics of the dried lignite. Two drying cycles were used: A normal cycle, corresponding to previously established standard time requirements, and an accelerated cycle, wherein time requirements were determined by boiler capacity and handling speed. Blank tests to determine stearn requirements for heating the empty autoclave were performed for each cycle and each test condition. Moisture removal, final moisture content, net steam consumption, and size stability of the dried lignite were determined.

Jan 1, 1959

By F. San Martin, Y. Lefevre, F. Tamargo

The San Juan de Nieva smelter was commissioned in 1960 with an electrolytic zinc capacity of 15,000 t/y. After a number of minor expansions, the capacity was increased to 320,000 t/y in 1991 and will reach 440,000 t/y by August 2001. The expansion involves the construction of a 900 t/day Lurgi roaster and a new acid plant. The leaching will be fully revamped and modernised, including the construction of a new building for residue treatment and for j arosite precipitation with a separate circuit for silver-containing concentrates. The project also includes the construction of a fully automated 137,000 t/y zinc cathode tankhouse fitted with 3.4 m2 cathodes designed by Asturiana de Zinc, and based on the existing tankhouse and introducing some improvements. New melting and casting facilities, also designed by Asturiana, will be constructed.

Jan 1, 2000