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By D Liu, M Edraki, L Berry

The presence of clay minerals slows down the settling rate and mitigates compact consolidation efficiency in tailings dewatering. The increasing use of saline water in many plants, affects the dewatering performance and presents the mining industry with new concerns. Efficient tailings dewatering is a great challenge due to the complexity character of tailings, especially clay mineralogy, clay content, and water chemistry. In this study, existing studies of the effect of different affecting parameters, such as pH, ionic strength and polymer flocculants, on clay aggregation behaviours are reviewed. The settling behaviours of three types of commonly observed clay minerals in tailings, kaolinite, bentonite, and illite, are also investigated in saline water with different water salinity as a case study. The settling rates of clay minerals are found to be affected by water salinity, clay type, clay content and polymer dosage levels. High salinity water hinders the settling of kaolinite but assists the settling of bentonite and illite through formation of different aggregation structures.The current work has indicated that strategies to promote more rapid dewatering could include adjusting flocculant type or level, water salinity and salt balance, and tailings solid content levels. Implementing dewatering strategies may require a more detailed knowledge of the effect of surface chemistry on the nature and strength of the clay inter-particle forces. This study discusses the research gaps on how to better manage clay-rich tailings in saline water and identifies new research directions. The development of a water management model, supported through in-line monitoring data to predict and manipulate of the surface chemistry of the clay component of the tailings could be a new direction to manage the issues associated with clay minerals in the process of dewatering and tailings management. Mine planning (water use requirements, operating costs) could benefit from more detailed studies on dewatering of clay-rich tailings in saline water. CITATION:Liu, D, Edraki, M and Berry, L, 2018. Improving the dewatering efficiency of clay-rich tailings in saline water, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 476–484 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018

By William A. Beck

Bauxite was discovered in the Springvale district in 1916. About 16, 000 tons was mined in the period 1916 to 1922, but no bauxite mining has been done since that time. The Bureau of Mines explored for bauxite in the district from September 5 to November 18, 1943. During the life of the project, the Bureau of Mines obtained mineral exploration agreements covering a total of 11,330 acres from 50 property owners. A total of 388 holes were drilled on five of these properties and 164 samples were taken and analyzed. The Springvale bauxite district includes an area of about 30 square miles in the northwestern part of Randolph County, Ga. The village of Springvale is in the west central part of the district, and Cuthbert is 8 miles southeast of it (fig. 1).

Jan 1, 1949

By Lu-ming Zhao, Li Zhao, Yu Wang

In this paper, the change of crystallization rate, dendrite arm spacing and dendrite width of mold flux with various magnetic field conditions were studied by experiment. Having found that the crystallization ratio of mold flux increased from 33 to 96.6%, the dendrite arm spacing decreased from 72.47 to 38.02 lm, the dendrite width decreased from 48.47 to 27.02 lm while the magnetic field frequency (f) equaled to 8 Hz and its strength (B) increased from 0 to 30 mT. The crystallization ratio of the mold flux increased from 91.9 to 96.1%, the dendrite arm spacing decreased from 60.53 to 28.08 lm,the dendrite width decreased from 42.53 to 24.08 lm when B equaled to 20 mT and f increased from 6 to 12 Hz. However, the XRD analysis indicated that the phase types of the mold flux under the experimental conditions did not transform. Results showed that an alternating magnetic field can promote the crystallization of mold flux and refine grain structure.

Mar 1, 2018

By Wilson Blake

A mathematical model based on the finite element method of stress analysis has been used to describe the behavior of the western wall of the Kimbley Pit as its slope was steepened from 45 degrees to 57 degrees. Theoretical stress changes because of slope modification are slight except at the toe of the modified slope. Magnitudes of stress created are small when compared with the strength of a competent rock. Resulting displacement patterns point out the need for determining the in situ state of stress at a site prior to excavation or modification. A comparison of model results with field measurements shows that, in general, the model has described the measured behavior of the west wall of the Kimbley Pit remarkably well.

Jan 1, 1968

By K. D. Card, K. Howard Poulsen

Abstract - The Archean Superior Province craton and the Paleoproterozoic Penokean Orogen are major geological sub-divisions of the southern Canadian Shield and account for much of the metallic mineral production of North America. The Superior Province experienced a mainly Archean history involving several cycles of volcanism, plutonism, and tectonism, primarily in the Neo-archean but also including Meso-archean and Paleo-archean cycles as well. Superior Province consists of northern and southern high-grade gneiss sub-provinces and a broad central region of alternating greenstone-granite and metasedimentary belts. The sub-provinces may represent tectonic terranes assembled in the Archean by accretion processes similar to those of some Phanerozoic orogens. Most of the mineral deposits, including VMS, intrusion-related, and lode gold deposits occur in the greenstone- granite sub-provinces where they were formed in an interval of 100 million years or less around 2.7 Ga. The Paleoproterozoic Penokean Orogen comprises supracrustal sequences deposited in fault-controlled epicratonic and rifted margin settings developed on and about the Superior craton. Deposition of the ~2.4 Ga Huronian Supergroup and its paleoplacer uranium deposits in the eastern Penokean Orogen, and their pre-2.2 Ga deformation, were probably unrelated to the deposition of the ~2.1 Ga Marquette Range and Animikie groups and their major taconite iron formations in the west. However, these sequences were deformed together during the ~1.85 Ga Penokean Orogeny which resulted when an assembly of island arcs containing VMS deposits, the Wisconsin magmatic terrane, collided with the Superior block and its Paleoproterozoic cover. The Sudbury structure with its world class Ni-Cu-PGE ores was also formed at this time, possibly triggered by meteorite impact. Metallogenic patterns in the Paleoproterozoic rocks were controlled by a complex interplay of factors including tectonically controlled variations in deposition and deformation, distribution of mineralization in the Archean basement, and oxyatmoversion, the transition from anoxic to oxygenic atmospheric conditions that occurred during the deposition of these sequences.

Jan 1, 1998

By Pamela Paradis-Sokoloski, Deni Thibodeau, J. Denis, Samantha J. Espley, P. O’Donnell

"During the previous decade, the role of spray-on liners within the mining industry was limited to providing a corrosion resistant coating to screen and bolts; however, increasingly, liners are being used as ground support products. Expanding use and testing of liners have demonstrated their ground support function, yet the definitive support mechanism is still under debate. The most promising theory is the retain/hold/reinforcement concept (Kaiser et al.,1992). This conceptual theory has been the basis for the recent underground trials at INCO where, specifically, shotcrete and MIROC Mineguard were tested in two trials to further define limitations and applications of each liner.In a cursory overview, shotcrete is becoming accepted as a support product, while Mineguard is only slowly gaining acceptance.This discrepancy is the result of the corresponding life-spans within the industry, whereby shotcrete has had wide-spread use for decades, yet Mineguard has only recently been introduced. Currently at INCO, shotcrete is primarily used: to provide support in poor ground conditions, to add stability when developing through backfill, and to provide damage control in seismically active mines. It is also used to protect production headings and secondary-blasting chambers from fly-rock damage during blasting. Despite an obvious support function of the liner, shotcrete has always been used in addition to bolts and screen. Comparatively, Mineguard is still in the testing stage, where the greatest potential is increased productivity for applications in multi-tasking development headings. In this scenario, Mineguard provides instant support to replace screen, and bolts temporarily. When the heading has advanced, the drill and support crews work in tandem, drilling off the next round and installing bolts for long-term radial support, respectively. Other potential applications of Mineguard are within production headings to replace screen in the back, and screen and bolts in walls. The potential for both liners to replace conventional support is clearly war-ranted, such that defining the support role was the primary goal of the two underground trials."

Jan 1, 1996

By K. Lagnese, C. Robinson, S. Muddasani

"Mine water generated from underground coal mining operations contains both dissolved and particulate solids. Dissolved solids primarily consist of sodium, calcium, magnesium, potassium, chlorides and sulfates. When discharged to a receiving stream without treatment, these constituents create a potentially toxic environment for aquatic life. A case study is presented to discuss how a centralized treatment plant treats mine water from six locations to meet discharge limitations for chlorides. Located in West Virginia, this facility consistently achieves less than the NPDES permit limitation of 218 mg/L chlorides in the discharge while generating almost zero liquid waste. The dissolved solids concentration in the influent ranges between 5,000 and 10,000 mg/L, with chloride concentrations of 1,000 to 2,000 mg/L and sulfate concentrations of 2,000 to 6,000 mg/L. The mine water is treated using advanced treatment technology to produce clean water for discharge or reuse. The treatment process comprises aeration, softening, filtration, reverse osmosis, RO reject softening, evaporation, crystallization, final effluent remineralization and sludge dewatering. The solid waste generated in the treatment process is landfilled on site. The leachate is sent back to the facility’s thermal treatment process. Because no liquid waste leaves the property, this plant is termed a “Zero Liquid Waste” (ZLW) facility. INTRODUCTION The advanced water treatment system was built to meet a new 218 mg/l regulatory limitation imposed by the West Virginia Department of Environmental Protection for chlorides discharged to surface waters. The system is designed to treat a maximum flow of approximately 5 million gallons per day (795 m3/h) of mine water. The treatment process utilizes reverse osmosis (RO) membrane treatment to achieve the effluent criteria, and evaporation and crystallization technology to manage the RO concentrate from the water treatment process. As a result, the system produces clean water for discharge while generating zero liquid waste. The effluent water can be used for industrial purposes or discharged to a receiving stream. A Water Impact Index (WIIx) study indicated that discharge of this high-quality water into the Monongahela River watershed may improve the water quality for downstream water users. The waste produced in the treatment process, including softening sludge and salt, is disposed of in an on-site landfill."

Jan 1, 2015

By Robert H. Bedford

The Rogan-Mallery tin property is in the foothills on the south slope of the Tehachapi Mountains, Kern County, Calif. It was first visited by the senior author in August 1942, and exploration by means of trenching and diamond drilling began in May 1944 and was concluded in August of the same year. Cassiterite, associated with iron-rich gossan, occurs in a limestone roof pendant at places near or at its contact with the underlying granitic rocks. The cassiterite grain sizes range from 20 mesh to 150 mesh. Surface and diamond-drill samples showed tin ranging from traces up to 122.6 pounds per ton. Exploration by the Bureau of Mines included 2,100 cubic yards of trenching and the drilling of 11 diamond drill holes totaling 1,000 feet. Dana Hogan, president of the Rogan Petroleum Co. of Los Angeles, Calif.) brought these projects to the attention of the Bureau of Mines in July 1942, and the following month a Bureau engineer made a preliminary examination in company with Hillard Mallery, of 408 Ruby Street, Redondo Beach, Calif., the man who discovered them.

Jan 1, 1949

By Vladko Panayotov, Marinela Panayotova

"Recently, in order to extract metals, the industry is trying to process old metallurgical slag. The material requires very fine grinding that results in enhanced slime-formation. This in turn leads to problems in the course of the flotation process and to a loss of metal. In addition, it causes difficulties in the wastewater treatment aimed at water reuse. The aggregation and separation of the fine particles and their further subjecting to mineral processing would result in more efficient use of raw materials. Closing the water cycle also would be facilitated. The paper presents results from studying sixteen flocculation reagents, commercially available for treating municipal wastewater, including products based on nanotechnology, for their ability to rend the production wastewater in suitable for reuse in the flotation. It turned out that, from all studied reagents, the cationic C-587 is suitable for the purpose. Some of reagents were studied for their ability to flocculate selectively, in presence of coke fines, rich in copper fines which are produced at grinding of a slag from lead-zinc metallurgy. Most promising reagents are chosen, based on the chemical analysis of the flocculated materials. Open-cycle rough copper flotation experiments with the flocculated fines and recycled wastewater gave encouraging results."

Jan 1, 2014

By B Belle, M Biffi

Cooling of coal mines in the Bowen Basin, characterised by steep geothermal gradient, is presently achieved mostly through rental surface bulk air cooling in summer months. This paper argues that future mines will be required to focus their cooling resources more intensively to manage a challenging thermal environment where virgin coal temperatures of over 50¦C at a depth of 500 m are expected. Currently, mine cooling systems are employed to maintain the wet bulb temperatures (WBT) to below 27¦C at which point the risks of heat stroke or other heat-related issues are manageable. The capacities of these systems are in the range of 6 MWR to 10 MWR. The relationship between high working temperature environments and injury frequency rates is well established. Therefore, provision of appropriate cooling strategies and understanding their optimum performance and suitability are important to Australian coal mines of the future. This paper evaluates the underground temperature profiles of deep, gassy coal mines with propensity for spontaneous combustion and proposes the long-term cooling pathways to effectively manage thermal hazards. Thermodynamic modelling is performed on a longwall face and includes air leakage effects from goaf streams at various locations along the longwall face. The strategy summarises the application of underground bulk air cooling, chilled water sprays on the shearer and the resulting temperature profiles. Considering the new mining projects planned for the Bowen Basin region, a review of implementable cooling strategies such as mid-gate mobile bulk air coolers (BACs), spot coolers, underground bulk air cooling and the use of chilled water to enhance the positional efficiency of cooling plants, are discussed in this paper. Finally, the comparison of ærentalÆ versus æownershipÆ of cooling plants is analysed as part of long-term cooling strategies.CITATION:Belle, B and Biffi, M, 2013. Cooling pathways for deep Australian longwall coal mines of the future, in Proceedings The Australian Mine Ventilation Conference , pp 223-236 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 1, 2013

By Simon N. Lekakh, D. G. C. Robertson

A new integrated CFD-combined reactors approach is proposed for the description of processes in metallurgical vessels. CFD simulations were used to obtain the melt flow pattern in the vessels (ladle, tundish, and continuous caster mold). From these simulations, the characteristic curves were derived: (i) the residence time distribution curves (RTD) for flow-through systems (at tundish exit or at dendrite coherency surface in the mold) and (ii) the mixing curves for closed systems (ladle). In the next step, the melt flow was represented in a “combined reactors” system consisting of a combination of unit reactors (Plug Flow, Mixer, and Recirculated Volume). An inverse simulation was used to define the volumes of the reactor units and the melt flow rates between them by fitting to the characteristic curves from both methods (CFD and combined reactors). The suggested approach is demonstrated for multiple designs of Ar-stirred ladles, tundish, and SEN. This methodology can be used to enhance traditional post-processing CFD analysis and also as a tool for on-line process control.

Jan 1, 2014

An intensely sheared and mineralisedIzone occurs in the Quartz Dolerite Greenstone (or Younger Greenstone) mass on, the western limb of the Kalgoorlie Syncline. This zone comprises the western part of the Golden Mile and has produced the greater part of the 33,000,000 ounces of gold produced to date from the main mining belts. A study of.th e general geological and structural features gives rise to the expectation that the lode shear system,will continue southward on a pitch similar to that of the maln syncline whose axial plane may be referred to as the "Boulder Dyke". Although payable ore has recently been found further south than previously, the expectation of large quantities extending southward from the present mining areas is Problematical.'

Jan 1, 1964

By Boshou Bian

Air quantity is the primary parameter governing the working condition of a mine fan. In order to improve the fan performance and efficiency, reduce its energy consumption, and guarantee mine safety, it is very important to obtain an accurate value. However, generally speaking, the fan ducting or drift on surface is very short in distance and contains sharp bends. The air quantity of the mine is so concentrated in this way that the air velocity becomes very high, and the airflow, either in the fan drift before the fan impeller or at the downstream diffuser, is very turbulent. Therefore, no anemometer is satisfactory because there is too much difference between the measured value and the actual value of air quantity at the mine fan.

Jan 1, 1989

By V Novoselov, R Sabirov

Flotation processing technology of water-soluble minerals has made it possible to realise, since the 1960s, the wide scale industrial processing of potash and potassium-magnesium ores (about 200 million tonnes per year) as well as to create the multi-tonnage worldwide production of sylvite (KCl) for industrial and agricultural application. In this paper the particularities of the effect of reagents (blinders, collectors and frothers) during cation flotation in saturated saline solutions are outlined. New reagent modes for activating the effects of alkylamines during the flotation of KCl and the perfecting of technological flow sheets for processing potassium ore have been developed. The results of research on the reverse flotation of carnallite ore, with the help of alkylmorpholine û a new developing technology for benefication carnallite as raw material for the production of metal magnesium and fertilisers are listed. Examples are given of the industrial applications of processed reagent modes at potash flotation factories in Russia.

Jan 1, 2005

By Gerald Sherman

MINING asbestos ore by caving at Thetford Mines, Quebec, has been described in the Transactions of the Canadian Institute of Mining and Metallurgy in papers presented by the staffs of The Asbestos Corp. Ltd., in 1934, and Johnson's Co. Ltd., in 1941. The production by caving prior to 1949, in round figures, has been 14,500,000 tons of ore by The Asbestos Corp. and 5,500,000 by Johnson's Co. They are the only caving operations in asbestos at the present time. The Jeffrey mine of the Canadian Johns-Manville Co. at Asbestos, 40 miles southwest of Thetford, is well along in preparations for caving, and The Bell Asbestos Mines Ltd. at Thetford Mines, will follow their examples later. GERALD SHERMAN, Member AIME, is Consulting Engineer, Johnson's Co. and Canadian Johns-Manville Co., New York, N. Y. AIME San Francisco Meeting, Feb. 1949, and New York Meeting, Feb. 1950. TP 2828 A. Discussion (2 copies) may be sent to Transactions AIME before May 31, 1950. Manuscript received Nov. 2, 1949. Nearly all of the asbestos produced by the western hemisphere is mined in those districts of Canada. Since it has been the subject of a number of technical papers, this contribution is offered as a review of progress. Some introductory information seems appropriate, for few members of the American Institute of Mining and Metallurgical Engineers are familiar with the mineral, or how asbestos deposits differ from others in caving characteristics. Asbestos is found in peridotite, a basic intrusive rock irregularly altered to serpentine and erratically fractured, well enough to cave in bulk, but leaving many blocks of solid ore of all sizes scattered through the deposit. Chrysotile is the variety of asbestos produced in Canada. Its fibers are the most valuable commercially, having a good proportion of long fibers, strong, silky, flexible, and suitable for spinning. The fibers occur in all lengths, from the microscopic to 3 in., or more, the shorter are more abundant. Their values depend on length combined with other qualities noted above. They occur as veinlets filling fissures in the peridotite, with crystals compactly arranged in parallel across the cracks. They are sometimes lightly frozen to the walls but the partings are distinct, often marked by particles of magnetite adhering to the fiber ends. Sometimes they break away from the rock in slabs an inch or more in thickness. In wide fissures the fibers are not always continuous, the "broken fibers" being separated by lines of parting with occasional scattered grains of magnetite, which is an injurious mineral to be elirninated when possible. In addition to the chrysotile ''Cross fiber," some "slip fiber" is found in fault fractures in limited quantities of less valuable character. With the exception of the Asbestos Corp, ore, in which the content is said to be more uniform, asbestos is eccentrically distributed through the peridotite. It is the general impression that the higher grades are more often found in hard rock. There are rich pockets and leaner areas which range down through various grades to minor barren sections. Wholesale mining is necessary to make sure of recovering all the high grade for there are no reliable indications of its existence. Ore selection only appears in constructing assay-grade limits for caving. The mill yield of the Thetford ore body in 1934 was 6 to 10 pct of the ore milled, made up of all classes, with occasional runs up to 15 pct or so. Quotations for Canadian asbestos* are as follows: Per Ton No. 1 Crude (% in. and longer) $896 @ $960 No. 2 Crude (Y8 to % in.) 350 @ 545 Spinning (less than % in.) 204 @ 378 Other classes, price diminishing with length. Shorts or "refuse" 24 @ 46 • From Eng. and Min. Jnl., Nov. 1948. Asbestos of even superior quality for electric insulation is found in Arizona limestone. It is white, containing very little combined iron, but occurs only in small quantities.

Jan 1, 1951

By N. Kubo

Sumitomo Toyo Copper Smelter and Refinery was commenced in 1971, and its production capacity of sulfuric acid was 550tpd at the beginning. In 2001 Toyo Copper Smelter and Refinery projected to expand its copper production capacity to 450,000tpy, and now the project is still in progress. To achieve this expansion project, 4,000tpd of sulfuric acid production capacity is necessary to the acid plant. So as a part of this project, the construction of the new converting and absorbing line and the improvement of the existing converting and absorbing line were carried out from 2001 until 2005. Then the production capacity of these 2 lines has already reached the target, 4,000tpd of sulfuric acid. Moreover, at the design of the new line, we adopted several latest technologies and materials in order to construct the world's leading acid plant. Basing on the operation performance of the new line, we have improved the existing line in 2005. Both of these 2 converting and absorbing lines are working quite well and contribute to big energy saving and excellently stable operation. Cu2007

Jan 1, 2007

By Gerald Sherman

MINING asbestos ore by caving at Thetford Mines, Quebec, has been described in the Transactions of the Canadian Institute of Mining and Metallurgy in papers presented by the staffs of The Asbestos Corp. Ltd., in 1934, and Johnson's Co. Ltd., in 1941. The production by caving prior to 1949, in round figures, has been 14,500,000 tons of ore by The Asbestos Corp. and 5,500,000 by Johnson's Co. They are the only caving operations in asbestos at the present time. The Jeffrey mine of the Canadian Johns-Manville Co. at Asbestos, 40 miles southwest of Thetford, is well along in preparations for caving, and The Bell Asbestos Mines Ltd. at Thetford Mines, will follow their examples later. GERALD SHERMAN, Member AIME, is Consulting Engineer, Johnson's Co. and Canadian Johns-Manville Co., New York, N. Y. AIME San Francisco Meeting, Feb. 1949, and New York Meeting, Feb. 1950. TP 2828 A. Discussion (2 copies) may be sent to Transactions AIME before May 31, 1950. Manuscript received Nov. 2, 1949. Nearly all of the asbestos produced by the western hemisphere is mined in those districts of Canada. Since it has been the subject of a number of technical papers, this contribution is offered as a review of progress. Some introductory information seems appropriate, for few members of the American Institute of Mining and Metallurgical Engineers are familiar with the mineral, or how asbestos deposits differ from others in caving characteristics. Asbestos is found in peridotite, a basic intrusive rock irregularly altered to serpentine and erratically fractured, well enough to cave in bulk, but leaving many blocks of solid ore of all sizes scattered through the deposit. Chrysotile is the variety of asbestos produced in Canada. Its fibers are the most valuable commercially, having a good proportion of long fibers, strong, silky, flexible, and suitable for spinning. The fibers occur in all lengths, from the microscopic to 3 in., or more, the shorter are more abundant. Their values depend on length combined with other qualities noted above. They occur as veinlets filling fissures in the peridotite, with crystals compactly arranged in parallel across the cracks. They are sometimes lightly frozen to the walls but the partings are distinct, often marked by particles of magnetite adhering to the fiber ends. Sometimes they break away from the rock in slabs an inch or more in thickness. In wide fissures the fibers are not always continuous, the "broken fibers" being separated by lines of parting with occasional scattered grains of magnetite, which is an injurious mineral to be elirninated when possible. In addition to the chrysotile ''Cross fiber," some "slip fiber" is found in fault fractures in limited quantities of less valuable character. With the exception of the Asbestos Corp, ore, in which the content is said to be more uniform, asbestos is eccentrically distributed through the peridotite. It is the general impression that the higher grades are more often found in hard rock. There are rich pockets and leaner areas which range down through various grades to minor barren sections. Wholesale mining is necessary to make sure of recovering all the high grade for there are no reliable indications of its existence. Ore selection only appears in constructing assay-grade limits for caving. The mill yield of the Thetford ore body in 1934 was 6 to 10 pct of the ore milled, made up of all classes, with occasional runs up to 15 pct or so. Quotations for Canadian asbestos* are as follows: Per Ton No. 1 Crude (% in. and longer) $896 @ $960 No. 2 Crude (Y8 to % in.) 350 @ 545 Spinning (less than % in.) 204 @ 378 Other classes, price diminishing with length. Shorts or "refuse" 24 @ 46 • From Eng. and Min. Jnl., Nov. 1948. Asbestos of even superior quality for electric insulation is found in Arizona limestone. It is white, containing very little combined iron, but occurs only in small quantities.

Jan 1, 1951

By Milton E. Wadsworth, W. Martin Fassell, William H. Dresher

A study of the rate of dissolution of molybdenite (MoS2) in alkaline solution was carried out under carefully controlled conditions. Effects of temperature, oxygen over-pressure, and KOH concentration were evaluated. Studies were made in the temperature range 100°C to 175°C and in the pressure range 0 to 700 psia of oxygen. Under these conditions molybdenite was found to leach according to a linear mechanism. Both oxygen over-pressure and KOH concentration were found to control the rate of leaching. The mechanism has been explained in terms of adsorption of oxygen at the molybdenite surface followed by configurational rearrangement of the adsorbed molecules. The hydroxyl ion dependency is believed to be diffusion-controlled. Laboratory batch studies have shown that molybdenite can be readily dissolved in alkaline solutions under moderate conditions of temperature and pressure. Commercial application of this process to the production of ferro-molybdenum and molybdenum chemicals is promising in view of the ease of dissolution of molybdenite and the relatively noncorrosive conditions involved in the process. HIGH temperature-high pressure techniques have long been used to great advantage in the organic chemical industry, the petroleum industry, and the paper industry. Only recently, however, have these methods been used to extract metals from their ores on a commercial scale. The Chemical Construction Corp., together with interested producers of nickel and cobalt, has done much to develop methods of producing nickel and cobalt powders by the use of high temperature-high pressure techniques.' The Howe Sound Co. is currently operating a plant near Salt Lake City in which the new Chemical Construction Corp. technique is applied to cobalt-arsenic sulfide concentrates. In this method the concentrates are leached in a dilute solution of sulfuric acid under air pressure at a high temperature. Near Edmonton, in Alberta, Canada, the Sherritt Gordon Co. is also using the new method in conjunction with its ammoniacal leach process.' National Lead Co., at Fredricktown, Mo., is operating a process similar to that of Howe Sound. In spite of the rapid growth of high temperature-high pressure hydrometallurgical processes, there has been very little work done on fundamental principles involved in this type of process. Conse- quently the literature lacks any significant data in this field. Oxidation of pyrite,3 phalerite,4 galena,5 and recently molybdenite" in alkaline solutions has been reported to some extent. This investigation was initiated, therefore, to broaden the application of high temperature-high pressure hydrometallurgy and also to contribute some insight into the basic mechanisms of oxidation in an aqueous medium under these conditions. In addition to the immediate consequences of these processes much valuable information remains to be learned about fundamental reactions when they are carried out at temperatures and pressures slightly higher than those normally encountered. Leaching of molybdenite by alkaline solutions under oxygen pressure has recently been reported in the Russian literature by E. S. Usataya,8 who found that leaching rate increased with an increase in the pH of the solution—the strongest effects being observed at a pH of 10—and also with an increase in temperature. Usataya also has reported the formation of a protective film on the surface of the molybdenite when the leaching solution was weakly alkaline, neutral, or acidic. He believes that this oxidation process explains the migration of Mo+ + in the oxidation zones of molybdenite ore deposits and the subsequent impoverishment of the ores. Equipment: The high temperature-high pressure reaction unit used in this work was especially designed for kinetic studies of this nature, emphasis being placed on accuracy of measurement and precision of control. As details of the unit's construction and operation have been discussed elsewhere,7 Only basic features and principles of operation will be discussed at this point.

Jan 1, 1957

By Borje Hjortzberg-Nordlund

THE great Swedish export iron ore mines are Kiruna and Malmberget in the north above the Arctic circle and Grängesberg in Central Sweden, see Figs. 1 to 3. These mines exported in 1951 about 13 million metric tons of high grade iron ore and concentrates. The origin of these three ore fields seems to be the same. They are of pre-Cambrian age and are regarded as typical instances of primary eruptive ore that has thrust up as glowing masses of lava flow between two somewhat older beds of porphyry. Apparently the ore and the porphyry became segregated from common parent magmas by a process of differentiation. Despite the fact that the Kiruna orebody belongs to the earliest pre-Cambrian formation, it has been influenced to an unusually small extent by later metamorphosisms, apart from its having been set on edge through folding and wrenching off by a number of later faults. The Kiruna ore occurs along a stretch of more than 4 miles as a series of slabs or lenses sloping steeply toward the east and sandwiched between two beds of porphyry. The main orebody has a length of about 3 miles and an average width of 300 ft with a maximum of 600 ft. The dip varies from 65° to 45° toward the east and the known depth is 3000 ft, although magnetic surveys indicate it may be at least 6000 ft. Malmberget has undergone a more thorough transformation, having been pressed and crumpled into a meandering band of disconnected layers and lenses. The largest of the more connected bodies of ore, the Great Ore Layer, outcrops on a low mountain ridge and has a total length of about 4 miles and a maximum width of about 300 ft. The dip varies from 30° to 70° towards the north. The main orebody in Grängesberg, the so-called

Jan 1, 1952

By S. A. R. Keneti

Predicting the geomechanical response of the shale gas material during hydraulic fracturing operation in the field needs better understanding of their geomechanical behaviour under laboratory testing. Anisotropy is considered as a critical factor during investigation and analysis of deviated boreholes, borehole stability, stress-strain and strength behaviour, generation and propagation of fracture and fluid flow. In this study, compressive elastic modulus (Ec) of the Montney shale has been investigated in two perpendicular directions: unconfined compressive strengths test was conducted on the Montney sample to measure its Ec in the vertical direction. This value then was compared to the Ec value in the horizontal plane (i.e. foliation plane) which was previously measured throughout a Brazilian test by Keneti and Wong (2011). From the results, the representative values of Ec in the vertical and in the horizontal directions were found as 25 GPa and 40 GPa, respectively. Computer tomography technique was also employed for the experimental data interpretation.

Jun 1, 2012