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By Bruce W. Wessels

"Metal-organic chemical vapor deposition has been shown to be a highly versatile technique for the synthesis of complex oxides. High dielectric constant oxide thin films of SrTiO3, BaTiO3, Ba1-xSrxTiO3 and SrxBa1-xNb2O6 can be be be deposited at 800 ºC with this technique. The fluorine substituted B-diketonate precursors have been shown to be well-suited for the deposition of high quality, epitaxial thin films of these materials.IntroductionThere has been a resurgence of interest in thin film ferroelectric oxides as a result of the development of techniques to deposit high quality material. Both physical and chemical vapor deposition techniques have been realized. Of the chemical vapor deposition techniques, metal-organic chemical vapor deposition (MOCVD) has received the most interest for the deposition of ferroelectric oxide thin films. This results, in part, from the availability of a number of volatile metal-organic precursors.(l) Moreover, MOCVD offers the advantages of high growth rates, uniform coverage over large areas, conformability, abrupt interfaces and excellent epitaxial crystallinity. Of the metalorganic precursors, the B-diketonate complexes have played an important role especially in the deposition of ferroelectric oxides containing alkaline-earth metals such as BaTi03 and Ba1•XSrxTi03. For example, barium tetramethylheptanedionate Ba(thd)2 has been used in the preparation of BaTi03 by MOCVD.(2) These compounds, however, are not without their problems. Ba(dpm)2 has a relatively low volatility; and as a consequence, temperatures in excess of 180·C are required for volatilization. This leads to the necessity of a complex precursor delivery system to insure that the precursor does not condense before the reaction zone. Moreover, the Ba precursor tends to oligomerize leading to a decrease in vapor pressure as well as a problem with reproducibility. To counter these problems, novel liquid source and solid source precursor delivery systems have been developed. (3)(4)"

Jan 1, 1994

By Simon C. Dominy, Alwyn E. Annels, Paul Wheeler, Suzanne P. Barr, G. Simon Camm

Abstract-Narrow veins are an important world-wide source of silver, tin, uranium and particularly gold. To potential financiers, this style of mineralization is viewed as high risk because of the often relatively small resource involved and high cost of estimation. In many cases diamond core drilling will not enable resource estimation beyond the inferred and indicated categories. Exploratory underground development is required to define measured resources. The definition of geological and grade continuity are major factors in narrow vein assessment. A measured resource must be based on strong geological and grade continuities. Narrow veins, generally less than 3 m wide, are complex geological phenomena, which commonly display unpredictable geometry and grade distribution. Variations in structural continuity, dip, strike, width, mineralogy and specific gravity are common. Veins may be composite, with ore-grade mineralization restricted to a specific structural domain. Branches, intersections and braided zones are common features. Potentially high-grade zones are often localized within ore shoots, which are surrounded by barren/low-grade regions. Resources must be determined as closely as possible to reality and reflect the distribution of the commodity in the rock. Estimation has three main requirements: (1) geological study to determine orebody nature; (2) estimation of tonnage and grade, and (3) the presentation of this information using a classification that is clear, unambiguous and bankable. Estimation methods employed are either classical or geostatistical; however, classical methods are often used because of the difficulties in applying geostatistics. Grades generally show a strong positively skewed distribution testifying the presence of high-grade values. Problems exist in the applicability of cutting outlier values risking over- or underestimation of grade. It is generally believed that where resource estimates are in error, poor geological control is usually the cause. Overestimation can lead to the closure of a mine through lost revenue and capital. An understated estimate can result in an opportunity missed for profit and/or greater economies of scale. Definition of reserves involves the consideration of economic and engineering data, to decide which part of the resource is economically mineable. Geology plays a similarly important role at this stage in the assessment of likely mining method, dilution, recovery etc. Throughout resource/reserve estimation, it is crucial that the amount and quality of the data and the geologist’s experience are relevant. The impact of geological understanding on estimation is often undervalued or assumed to be of lesser importance than finding grades and tonnages. This paper discusses the geology of narrow vein deposits and the importance of geology in their evaluation.

Jan 1, 1997

By Phillip J. Maddex, Ole Skaarup

The quite diverse backgrounds of the authors and their mutual interest in reducing transportation costs has produced some interesting innovations. A few words about their background will tell the reason for this joint paper. . . One is a shipping executive with a background of shipowning, ship management, ship and cargo brokerage and chartering, and most facets of the steamship industry, both American and International. The other is a chemical engineer, thoroughly brought up in the American chemical and mineral industries, with several top managerial positions behind him. They began cooperating when U.S. Borax was contemplating a change in its export shipping program and studying the freight cost for shipping borax from The mines in the Californian desert to Europe, and eastern U. S. markets. In the 20 Mule Team days, borax was exported in 50 pound bags. In 1960 it was still shipped in 50 pound hags. Three main products were shipped: two were anhydrous, and all three were sensitive to impurities. The products were bagged at the plant in the Mohave Desert, and shipped about 150 miles by rail to the port in Los Angeles. From Los Angeles, shipment was made by Conference steamship lines at Conference rates. Anyone who has shipped bagged material to Europe by steamer knows that the tab is anywhere from $20 to $30 or more per ton.

Jan 1, 1970

By Robert A. Kinzie

PAGE Introduction.............334 Climate.............335 History............335 Geology.............341 Mining..............343 Shafts............343 Stations and Ore-Bins....345 Levels. Drifts. Cross-Cuts, Winzes. etc........347 Stoping Surface-Pits,......... 351 Underground Stoping........... 332 Chutes. Drilling. etc.....354 Tramming............. 358 Sampling. Maps and Assaying.........360 Labor.............361 Machinery.............362 Milling,..............362 Crushers.............366 Battery-Foundations...........368 Power (Water—Coal)...........373 Methods of Catching the Free Gold...374 Screens..............376 Apron-Plates,.......376 Concentration..........378 Clean-Up,.............378 Labor..............382 Costs..............382 Introduction. The Treadwell Group comprises five mines. four of which are situated on the northeast side of Douglas island. directly opposite the town of Juneau, and one about four miles back of Juneau. These mines are owned by four separate companies. but are all under the same general management. Those situated on Douglas island are : The Treadwell mine. owned by the Alaska Treadwell Gold Mining Co.. the Mexican mine. owned by the Alaska Mexican Gold Mining Co.; and the Ready Bullion and Seven-Hundred-Foot mines. owned by the Alaska United Gold Mining Co. The Juneau mine. owned by the

Jan 1, 1904

By Leonard Obert

THE CRACKING AND POPPING of rock, often heard by men working underground, for years has been interpreted as a warning of danger and unstable ground. However, not until 1939 was it discovered that rock under stress generates subaudible and sometimes audible seismic disturbances (referred to as "micro-seismims" 4), which can be detected with the use of a suitable seismic apparatus. Since that date laboratory and field investigations have been in progress to ascertain to what extent this phenomenon can be utilized to detect, localize, and determine the magnitude of areas of instability in and around mine openings and to predict if and when failure will occur. These investigations have included a determination of the types of problems to which the method is applicable and the effect of rock type, geological defects, such as joints, fractures, faults, and other uncontrollable factors, on the reliability of results. Six reports have been prepared covering the investigations conducted between 1940 and 1952 (4-9). 5 These reports describe some of the characteristics of micro-seismims, as determined from both laboratory and field tests; the equipment used to pick up and record micro-seismims; the general test procedure and method of analyzing results; and applications of the method to specific mining problems.

Jan 1, 1957

By von Wielligh. L., D. G. Hattingh, M. N. James, W. Thomas

"SynopsisThe process of joining materials by friction is based on generating the heat necessary to create a solid-state mechanical bond between two faying surfaces to be joined. In simple terms, the components to be joined are subjected to frictional heating between rubbing surfaces, causing an increase in interface temperature and leading to localized softening of interface material, creating what is described as a ’third body’ plasticized layer. This plasticized zone reduces the energy input rate from frictional heating and hence prevents macroscopic melting. The plasticized layer can no longer transmit sufficient stress as it effectively behaves as a lubricant (Boldyrev and Voinov, 1980; Godet, 1984; Singer, 1998; Suery, Blandin, and Dendievel, 1994). The potential for this solid-state frictional joining process to create high-performance joints between, for example, dissimilar materials with limited detrimental metallurgical impact, and reduced defect population and residual stress level, has had a very significant impact on fabrication and repair in industrial sectors such as transport. This paper presents a brief overview of the advances made within the family of friction processing technologies that could potentially be exploited in the nuclear industry as alternative joining and repair techniques to fusion welding.Modern friction processing technologies can be placed into two main categories: those that make use of a consumable tool to achieve the intended repair or joint (friction stud and friction hydro-pillar processing) and those making use of a non-consumable tool (friction stir welding). The most mature friction joining technology is friction rotary welding, where a joint is formed between original parent materials only. A new addition in this category is linear friction welding, which opens the potential for joining complex near-net-shape geometries by friction heating. The continuous innovation in friction processing over the last 25 years has led to the development of a number of unique processes and applications, highlighting the adaptability of friction processes for specialized applications for high-value engineering components.IntroductionAssessing the potential for using alternative joining and repair techniques for specific applications in a given industrial sector is informed by an appreciation of the current size and potential growth in that sector. Power generation by nuclear fission has been out of favour over the past few years, due to several high-profile nuclear incidents, e.g. the Fukushima Daiichi nuclear disaster, as well as concerns over disposal of nuclear waste and spent fuel rods. However, due to rapid increases in the demand for electricity, coupled with many fossil-fuel fired plants reaching end-of-life, there is renewed interest in installing additional nuclear capacity."

Jan 1, 2015

By A. N. Brown

The Hendrik van der Bijl Memorial Lecture is arranged annually under the auspices of the Pretoria Engineers Liaison Committee. This is a multidisciplinary Committee with representatives from eleven societies and associations, and serves the interests of engineers resident in the Pretoria area. Coal preparation The Japanese Organizing Committee of the 11th International Coal Preparation Congress is now busy making the necessary arrangements for the Congress, which is to be held in Tokyo from 22nd to 26th October, 1990.

Jan 1, 1989

By J. K. Brimacombe

Since the Peirce-Smith converter was introduced to the non-ferrous industry in the early part of this century, there has been a paucity of research on process-engineering aspects of the reactor such as gas injection. This paper reviews studies conducted at UBC over the last decade on gas discharge dynamics, high-pressure injection, bath slopping, oxygen/bath reaction kinetics and out-of-stack heat transfer within the converter. The ultimate objectives of this work have been to extend refractory life and to increase converter productivity.

Jan 1, 1985

By K. V. Konigsmann

"Concentrate dewatering operations have a significant influence on the economics of base metal beneficiation. The expenditures f or energy and labour per tonne of product are high. The relatively low efficiencies of standard techniques present inducements for process modifications. Development efforts at several Noranda concentrators led to process changes which improved productivity, namely, agitated pulp storage in large vessels, process automation and pressure filtration.IntroductionA program was initiated in 1968 with the aim of improving utilization of manpower and equipment in dewatering operations. The following considerations motivated us in this effort: Firstly, filters and dryers had traditionally been operated continuously and in step with grinding and flotation circuits. The demand for labour and equipment operating time was fixed and was not determined by the rate of concentrate production.Secondly, dewatering equipment had usually been designed to handle the concentrate tonnages which were produced when mill feed grades were high; therefore the equipment operated at less than capacity when treating ores of average metal content. The first goal was the separation of the flotation process from concentrate dewatering by development of a practical storage system for concentrate pulps . A second objective was the gradual introduction of dependable automatic controls. The steep increase in energy costs after 1973 added urgency to the search for dewatering processes which were highly energy efficient."

Jan 1, 1984

By W. J. McGee

Most nations and states have conducted geological surveys, generally with the view of discovering and developing natural resources, sometimes with the aim of promoting science. In some cases, as in the first survey of Pennsylvania, the official geologist so far preceded the prospector and miner as to guide the discovery and exploitation of the commoner ores, mineral fuels and structural materials; but in most instances statesmen have only been awakened to the need of such a survey by the successful extraction of minerals;

Jan 1, 1893

When I wrote the Railroad portion of "Mining Engineering" magazines 94 Powder River Basin (PRB) Coal Article I described to you some definite destinations the Railroads had in mind. As with many destinations, the ones I wrote of turned out to be merely stops on the way to places that we have yet to reach. Somewhere along the way we discovered that making it better is a continuous process not just something that you can do in phases I, II, III, & IV. We always knew this I suspect, but perhaps not at the awareness level that exists in RR environments in 1997. The purpose of this article is to update the 94 article, which I could do very quickly. Everything I told you we were going to do in 94 is done, end of story! But in addition to making it a very short article it would not be telling you the things RR has done beyond what we were planning in 94 and for the future.

Jan 1, 1998

By Stephen C. Moore

The Grossschloppen vein-uranium deposit, Bavaria, West Germany, was examined utilizing underground workings during 1980-82 by Esso Erz GMbH, an affiliate of Exxon Minerals Company (EMC). Geologic evaluation entailed dense drilling of a portion of the deposit from workings constructed specifically for the program. Discovered in 1977, the deposit was initially explored by surface diamond drillholes which allowed definition of a 30-60 m wide vein system discontinuously mineralized along a 1000 m strike length and to at least a 450 m depth. The underground program was conceived as a cost effective procedure to answer questions on vein correlation, grade continuity and variability. A 1200 m decline allowed access for detailed sampling of approximately 10% of the known area of mineralization. Fanned drillholes, logged by gaga probe, were spaced to provide intersections of veins at 10 to 20 m intervals. Six cross cuts also penetrate the pitchblende and uranophane mineralization which occurs in 0.1 to 2.5 as thick quartz veins. Detailed cross-sections and level plans were constructed for resource estimates of the intensively studied portion of the vein system. The program resulted in the discovery of local, high grade areas and an average grade in the evaluated area nearly double that expected from surface drilling.

Jan 1, 1983

By Atinuke Oladoye, David Esezobor

"Particulate Copper Silicon carbide (Cu-SiCp) composites find application as wear and heat resistant materials in electrical sliding contacts such as in homopolar machines, railway overhead current collector systems where high electrical/thermal conductivity combined with good wear properties is required. However, challenges occur during machining due to the presence of hard reinforcement in the matrix. This may lead to high turnover of tool wear and poor surface finish. The adoption of near-net shape technology to produce such hard-to-machine metal matrix composites and subsequent finish machining with its attendant cost has reported limited success. This paper critically appraises the challenges and opportunities in the improvement of tribological characteristics of particulate Cu-SiC composites and identifies low cost reinforcement material that could be used to improve its tribological characteristics.IntroductionTribology consideration is increasingly becoming a decisive factor in the design and selection of materials for applications involving interacting surfaces in relative motion. The consideration is mainly on the combined effects of friction and lubrication on material's wear integrity and performance amongst other. Annual losses due to tribology in the US industries are estimated at between 1-2% of the Gross National Income [1], in Russia it is about 1-4% of the GDP [2]. Thus, the attributes of tribology has become imperative in modem machinery especially those applications involving sliding and rolling surfaces, and electrical contacts [3- 8].These are readily found in homopolar machines, internal combustion engines, aircraft engines, gears, cams, seals and railway overhead current collector systems [9-12]. In these systems, the dissipation of frictional heat arising from the interacting surfaces as quickly as possible imposes constraints on the choice of materials for such application to prevent softening, plastic and shear flow and the transfer of metal as wear debris onto the interacting surfaces. If these possibilities occur, system performance is compromised and premature failure may result. Materials for these systems are expected to possess high electrical and thermal conductivities, low coefficient of thermal expansion, good corrosion resistance and high melting point [3-8, 13]."

Jan 1, 2011

By Alan G. Fricker

Cyprus Gold NZ Ltd will be recovering residual free cyanide in barren gold pulp by air stripping. Laboratory investigations by DSIR have indicated additional advantages by recovering the cyanide from pregnant pulp. These are a lower leach pH, a greater cyanide recovery and less carbon consumption. They have a net economic advantage of $1.20/tonne over recovery from barren pulp. The realisation of these advantages is dependent on three crucial technical aspects -optimum pH for dissolution, the absolute loss of cyanide and the stability of the aurocyanide ion. The laboratory investigations described herein address these aspects. Earlier work had indicated that the rate of dissolution of freely revolving gold discs at constant cyanide ion concentration increased with decreasing pH from 11 to 8. Attempts to repeat the work in a more controlled manner by measuring the corrosion potential and current density have, to date, not been reproducible, but do not contradict the earlier observations. Cyanide recoveries and balances were obtained on leaches at pH 10.5 and 9 at the same cyanide ion concentration -the lower pH requiring three times as much total cyanide. Unaccounted-for losses, unfortunately, exceed the accounted-for losses, making interpretation of the balances difficult. Nevertheless, it appears that the additional amount of cyanide at the lower pH of 9 may not be fully recoverable. It may not, however, prove necessary in practice to use more cyanide at a lower pH. Both the gold and silver cyanide complexes remain available for carbon adsorption, as do mercury, copper and iron. Zinc, and probably cadmium, nickel and lead, may precipitate during stripping, which is an environmental advantage.

Jan 1, 1991

By Dina Aloi

The need to be seen as responsible neighbours and good corporate citizens is a critical success criteria for mining companies. To be seen as responsible requires both achieving responsible performance, and making that good performance visible to the community, legislators, investors, and other stakeholders. This has broadened the skills required for the successful operation of a mining company to include social sciences, public affairs, communications, and environmental sciences. Mining companies still look to technical specialists to achieve the core of that good performance - broadly characterized as a sustainable operation. However, the degree of understanding that those specialists have of the requirements for sustainability and overall Corporate Social Responsibility has a tremendous impact on the overall performance of the project and company. In her keynote address to the Sustainability for Profit session, Dina will outline some of the key areas in which technical employees and consultants can contribute to achieving successful sustainable mining operations.

Jan 1, 2010

By A. Haghighat

The Missouri University of Science and Technology?s (Missouri S&T) Experimental Mine is a teaching and research facility which has been excavated in limestone by mining engineering students over almost 100 years. The mine is currently being extended to a second level. Available fans for ventilation are two surface fans of 24 kW and two underground booster fans of 12 kW. The design of a ventilation network in conjunction with multi surface fans and booster fans entails a complex procedure. Ventsim Visual software modeling has been used for network analysis to determine the optimum surface and booster fans locations, blade settings, and speeds. Both natural and mechanical induced ventilation pressures have been taken into account. Three working faces on each level have been designated as target points that minimum air quantities are required. The model has been calibrated against a pressure and quantity survey. Design of ductwork, door/stopping positions and different fans characteristics have been examined. The optimum flow rate at identified working faces, efficiency and minimum energy losses and annual network power cost determine the best scenario. The optimum design has been determined for the ventilation network for the next 100 years. The optimum flow rate across working faces is the key criterion selected.

Feb 23, 2014

During the life of a mining project in Papua New Guinea (PNG), the greatest impact is on the people of the project area and the most intense, day-to-day contact is between these people and the project's field staff. Yet formal structures at present emphasise contact between much higher levels of national government and company personnel. Whilst understandable, this is unfortunate particularly since, given the nature of PNG politics, villagers do have a powerful influence on project success, as recent dramatic events on Bougainville have indicated. A greater role for local views and greater attention to such views by other parties is clearly required. But to achieve a successful marriage between informal village politics and the formal structures of investment procedures will require considerable patience and adjustment. This should be reflected in the cost of project development and be regarded as being as of a significance equal to that currently accorded to the technical aspects of project development.

Jan 1, 1990

By S. L. Zekovic

This paper analysis the medium and long-term perspectives, framework and considered possibilities of sustainable development of RTB "Bor" (Copper mines in East Serbia) after consolidation in the period of transition. The copper mine was opened in 1903. and today is the best quality copper producer on Balcan. This paper are elaborates the problems of privatization, debt, investment, growth of copper production from own mines (and imported raw), opening of new mines, economical efficiency of production, markets, environmental problems and impacts of the recent industry consolidation. The RTB "Bor" is a serious hot spot in Serbia. Unsustainable trends and processes are identified, as follows: open-pit waste dumps, flotation tailings, mining and processing waste waters, air pollution; no efficiency (excessive) using nonrenewal resource in the copper production; inefficiency in the use of energy, water and other inputs in copper complex; transboundary character of emissions of dust; environmental degradation and quality of wide area and ecologically highly risk, etc. Analysing some trends and planning-developmental perspectives and development strategies of company, it might be assumed that in the forth coming period, in parts of the Serbia, the borders areas of Bulgaria and Romania, there is an anticipated increase of ecological risk.

Jan 1, 2007

By François Tremblay

It is well known that removal of organic material such ,as Jacquer, paint, plastic prior to melting improves aluminum recovery. In addition to being an important economically, decoating of aluminum scrap has a positive impact on the environment, through better control of gaseous emissions. Most of the existing thermal decoaters for aluminum have been designed to operate with scrap containing a level of organic material lower than 10%. The main field of their present application is for recycling of used aluminum can, where levels of organic material are lower than 4%. Alcan has recently developed a new thermal decoating system in order to extend applications of this process to a much wider variety of aluminum scrap. The new decoater efficiently processes aluminum scrap with a level of organic material up to 50%. This new technology features the use of fluidized bed technology to thermally control the process. This innovative feature improves both performance and control over conventional delacquering systems based on hot air convection. This paper describes the basic principles of the technology and the design of the? first industrial unit commissioned by the Alcan Recycling plant in Shelbyville (TN) at the beginning of 1994. Typical applications and operating advantages are discussed.

Jan 1, 1995

By D. J. Wang

Based on the thermodynamic arid kinectic aspects, the vaccum distillation processes for the separation and recovery of metals from wastes are analyzed. As to the separation criteria, The separation coefficient and equilibrium composition relation between vapor phase and liquid phase are the bases of recovery of metals by vacuum distillation, The vaporization rates and condensation mechanisms are also discussed. Some experimental results which deal with metals-containing wastes are described and the performances of a new kind of horizontal vacuum furnace are introduced, which demonstrate that , vacuum distillation may be a prospective technique for circulation and regeneration of some non-ferrous metals from industrial wastes.

Jan 1, 1996