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By E. F. Johnson, F. H. Brinkman, H. J. Welge, S. P. Ewing

This paper presents a method for predicting the manrler in which oil will be displaced from a porous body by enriched gas. The calculations apply to a gas rich enough to give a partially, but not a completely, misci-ble displacement. The method — a three-component, two-phase analysis — takes into account condensation of some of the intermediate hydrocarbons from the injected gas into the oil, as well as enhanced volatility of heavier hydrocarbons at elevated pressures and temperatures. The condensation swells the oil and decreases its viscosity, thus aiding in its recovery. The calculations have been extended to apply to actual crude oil-natural gas systems by arranging the components into three groups according to their volatility. As an approximation, each group is then treated as a single component in the analysis. The influence of an angle of dip for an inclined displacement is also taken into account. The recovery predictions are corroborated by experiments which used both consolidated sand cores and un-consolidated glass beads. In some of these tests, actual live crude oil was displaced by a multicomponent gas typical of enriched gases used in oil fields. INTRODUCTION This paper presents a method for predicting the amount of oil that can be displaced from a homogeneous, linear, porous body at various stages during the injection of enriched, or "wet", gas. The porous body can be in either a horizontal or an inclined position. 'This type of displacement is sometimes known as condensing gas drive The method is developed especially for the case in which the injected gas is enriched enough to be partially, but not completely, miscible with the reservoir oil. The need for a calcula-tive procedure for this type of operation is emphasized by the number of field projects where completely miscible drives are not practical, but where near-miscible conditions are feasible. The factors taken into account in the predictive calculations include: (1) the condensation of gas components into the oil, with a resulting increase in oil volume; (2) the lowering of oil viscosity by the addition of lighter ends from the gas; (3) the increase in oil volatility at high temperatures and pressures; and (4) the physical displacement of the oil by the gas. The techniques developed in the paper can be extended to other nonequilibrium displacement processes. Other such processes that we have analyzed include a displacement by lean gas which stripped intermediates from the oil, and a water flood in which the water con. tained in solution a substance somewhat soluble in the oil. ANALYSIS OF ENRICHED-GAS DRIVE GENERAL PRINCIPLES Our method for predicting the amount of oil that can be displaced by an enriched gas uses an analogy between a three-component and a multicomponent system.' The predictive method is based on these assumptions: (1) constant, or nearly constant, pressure; (2) complete equilibrium by diffusion perpendicular to the main direction of flow, but no significant mixing along the direction of flow; (3) constant injection velocity; and (4) flow in a linear porous body. The composition of a liquid or a vapor with respect to three components can be plotted on a three-component, or ternary, diagram like that in Fig. 1. Let Point A represent the composition of the oil originally in place. In this case, Oil A is undersaturated with gas. If Point A lay on the equilibrium Curve BF, the oil would be saturated. In the extreme case where the original oil contained no intermediates or dissolved gas, Point A would lie at the lower left-hand corner of the ternary diagram. In a displacement of Oil A by Gas D, there will be a progressive change in the composition of the oil phase as more and more gas is brought into equilibrium with the oil. The end result of this progressive change is an oil having the composition represented by Point F. This oil is richer in intermediate hydrocarbon and methane than the original oil and, therefore, has a greater forma-

By Jack Washburn

The c axis indentations in zinc crystals were shown to undergo 100 pct strain recovery on heating. The mode of deformation and the details of the polygonization and collapse of indentations were found to be consistent with a number of predictions of dislocation theory. IT has been observed that indentations of the type made by Jillson in zinc crystals can, under certain conditions, be macle to shrink in size and even completely disappear on heating the crystal, Fig. 1. The details of the process are interesting in that they afford a simple experimental illustration of several predictions of dislocation theory. The indentations were made as shown in Fig. 2 by dropping a 0.2 g indenter with a hemispherical point on a cleavage face of a. zinc crystal. Such indentations can be made through relatively great thicknesses in the c-axis direction. The material close to the struck surface, where mechanical twinning and complex distortion occurred, was removed by cleavage. The remaining crystal, which was about 1 cm thick, contained a dent that was accurately round and almost the same size on both top and bottom surfaces. The indentation had the form of a flat cone of half angle approximately 89°, having a rounded apex and a rounded intersection with the unde-formed part of the crystal. The mode of deformation was primarily slip on the three equivalent systems in the basal plane. Six types of dislocation loop (plus and minus in each of the three directions) as shown in Fig. 3 are required by the geometry of the indentation. The maximum shear strain in the radial direction amounted to approximately 2.5 pct. Slip was distributed in the usual, microscopically nonuniform, manner among the possible parallel slip planes. When an indentation was made close to a (2110) surface, three separate sets of interpenetrating slip bands appeared as shown schematically in Fig. 3. A small biaxial tension strain in the plane of (0001) is also a geometrical necessity for the formation of an indentation. If the sides of the dent are tilted l° with respect to the undeformed surrounding crystal, and the surround-

Jan 1, 1957

By V. C. P. Morfopoulos, N. Arbiter

Theoretical and experimental studies of the interactions of mineral particles with electrical fields of cylindrical symmetry have been made. Theoretically, an expression relating field gradient and intensity to the force experienced by a dielectric particle was derived in a manner paralleling the magnetic analog. Pauthenier's and Cohen's expressions were considered in the evaluation of coulombic forces. Comparison of dielectric and coulombic interactions of minerals exhibiting a wide difference in dielectric susceptibility revealed the potential significance of dielectric forces in a field of appropriate characteristics. Experimentally, apparatus was designed for the study of forces experienced by a single stationary particle in an electrostatic field. This permitted the separate and precise measurement of dielectric interactions in the field. The experimental results were in good agreement with the theory and with relevant published data. Dielectric forces were found of comparable magnitude with coulombic in the presence of an adequate field gradient. Prolonged exposure of minerals to an inhomogeneous field was found to enhance the dielectric response. Dielectric inter- actions properly employed may thus be important in electrostatic concentration techniques. Conventional electrostatic separation techniques employ forces between charged particles and field electrodes to establish the trajectories which effect separation. Uncharged mineral aggregates, although unaffected by homogeneous electrical fields, should respond to fields exhibiting appropriate orientation and electrical gradients. The purpose of this paper is to establish the theoretical and experimental base for the comparison of the forces due to dielectric-field interactions with those of electrostatic origin. Apparatus and techniques developed for the determination of dielectric interactions are described and data on the dielectric forces experienced by stationary particles in cylindrical fields are reported. Finally, a quantitative comparison of dielectric and electrostatic forces is given. THEORY Dielectric Forces: When dielectric particles, minerals for example, are placed in an inhomogeneous field they experience interactions that give rise to substantial dielectric forces.' The latter were shown proportional to the intensity of the field, the potential gradient, the size of the particles and the dielectric permittivity difference between the particles and the medium. The properties of the inhomogeneous field, E, and the magnitude of the gradient, dE/dl, depend on the geometry of the system in question.

Jan 1, 1965

By D. Rankin, H. J. Stucke, W. K. B. Loftus

Discussion: H. J. Wright (Member): The authors are to be congratulated on presenting such a comprehensive and lucid account of bringing a large diamond mine into efficient production from the grass roots. When one considers the vast amount of planning and hard work that had to be put into the project the authors have done a praiseworthy job in condensing the story, so as to present all the important technical aspects, the logic behind the major decisions and the future thinking on the operations, in a concise and readable form. This was the first experience of De Beers personnel in starting a large diamond mine as an opencast project and nor do they employ a large planning staff, most of the planning being carried out by the executive staff themselves. It is operating most efficiently on a large tonnage and it is neatly and very well laid out. In fact, with its model townships, both for European and Coloured employees, tarred roads, recreation club and its grass golf course, it is like an oasis in the arid climate of the North-Western Cape. The key operation of opencast mining is, of course, the planning of the geometry of the pit. This has been adequately dealt with by the authors. It is of interest to consider some of the consequences arising from complete lack of open pit planning, based on actual operating mines. I refer of course to the present, four producing mines in Kimberley. The Kimberlite pipes were all discovered in a short span of time from the year 1870, onwards. They soon became a hive of activity with diggers industriously working their claims at varying rates. The country rock comprises from the surface downwards, some 90 ft of decomposed dolerite followed by approximately 260 ft of soft Karroo shales, which in turn is underlain by a hard competent Ventersdorp lava, known locally as melaphyre. The average water table was just below the dolerite at a depth of approximately 90 to 100 ft. Only the blue ground was mined leaving the waste rock sides almost vertical, and as the depth increased beyond 100 ft, large falls of sidewall started to take place. The shale was unstable and the falls covered

Jan 3, 1969

By W. C. Holliman

This report describes apparatus and procedure used for determining the vapor pressure of aviation gasoline in surveys of commercial aviation-gasoline characteristics made by the Bureau of Mines in cooperation with the Coordinating Fuel and Equipment Committee of the Coordinating Research Council, Inc. (CFR-CRC). The method is a modification of the Reid method, in which a mercury manor is substituted for the Bourdon-type gage of the Reid method. The method was used in earlier surveys made by the National Bureau of Standards in cooperation with the CFR-CRC, and was used in the Bureau of Mines surveys at the request of the cooperating organizations. It is designed for special research problems? particularly in vapor-lock studies, which require a precision greater than obtainable by the Reid vapor pressure method. A repeatability of + 0.01 p.s.i. average deviation from the mean may be obtained by method.

Jan 1, 1950

By J. Moore Samuel

Before the year 1909, no measurements of dust losses and flue gases had been made at the Copper Queen Reduction Works, at Douglas, Ariz. At that time the "unaccounted" loss of the smelter had reached a figure that drew attention to the possibility of large stack losses. The measurement of dust losses had not been studied much at that time, and estimates of dust losses, with a few exceptions, were the results of tests by what has been termed '(chemical methods," that is, the aspiration and filtration through cotton, wool or some similar medium of a few liters of gas, the dust being weighed on a chemical balance, and the volume of gas computed from the volume of aspirator water. The possible error of this method is enormous, and the probable error much too large for reliable results. Since the object of these tests was to discover not only the extent of the dust losses, but also the possibility of profitably reducing them, it was decided that the method adopted must have the following characteristics: 1. The sample of gas taken for filtration must be representative of the whole volume of gas, that is to say, it must have the same dust content. This condition will be fulfilled in all cases if the gas sample is drawn off without change of rate of flow. Then it will contain the same proportion of entrained or suspended particles of dust as the original gas. In the case of flue gases which contain only fume, at a temperature above or near the sublimation point, this condition need not be adhered to since the fume will not behave as entrained particles, but more nearly as a true gas. Consequently the gas sample in this case only may be drawn off at any rate of flow. 2. The gas sample taken must be large enough (a) to yield sufficient dust to permit of accurate chemical and physical examination; (b) so that the ratio of the total volume of gas passing through the flue to the volume of gas sample taken shall not be too large.

Jan 1, 1917

By Jens Kempken

A competitive landscape pressurizes the steel producers business, zero defect requirements from customers forces the operators for additional efforts in process control and quality management. The so called quality related cost, which include also rework, cost for downgrading or even scabbing of material is already a remarkable lever in a plants profitability breakdown. The introduction of advanced state of the art grades in the product portfolio requires already a budgeting for the expenses for R&D and quality management. PQA has been developed as a process and quality management software solution next to existing level 2 or level 3 automation systems. It is focusing on the analysis of process data, equipment information, in line quality measurement devices and trend analysis to obtain an answer whether the process is according to definition and expectation and whether the intermediate or final product can be shipped for further processing as prime material. Advanced analytics which are linked to an expert know how based configuration identifies deficiencies in the production and processing process. An intelligent, state of the art quality rating system evaluates tolerable deviations. PQA comprises the software platform including the database, data configurator and collector from the different sources in the production process and units. The core element of the platform is the knowledge based expert know how package defining process and quality determining fundamentals. The paper describes the structure of the software package, it gives insights on the expert know how package, process and quality evaluation and points out the customer benefits, cost reduction, improvement yield, customer satisfaction increase. The link to recent operational references is given.

Oct 30, 2017

By R-H Yoon

The thin film pressure balance (TFPB) technique was used to measure the kinetics of thinning of single foam films and disjoining pressures in the presence of sodium dodecyl sulfate (SDS) and electrolyte (NaCl). The results were analysed in view of the Reynolds equation to determine the role of surface forces in film thinning. It was found that film thinning is controlled by surface forces at thicknesses below approximately 200 nm. It was also found that hydrophobic force plays an important role particularly at low SDS and NaCl concentrations. The values of the hydrophobic force constant (K232) estimated from the film thinning experiments were used to predict the disjoining pressure isotherm using the extended DLVO theory, which were found to be in excellent agreement with experiment. The TFPB technique was also used to measure the equilibrium thicknesses (He) of the foam films stabilised by a non-ionic surfactant, n-octanol, in the presence of NaCl. At a given ionic strength, He increased noticeably with increasing octanol concentration at very low concentrations. This observation suggests that hydrophobic force is at its maximum level in the absence of surfactant and decreases with increasing surfactant concentration. The results obtained with the single foam films were used to explain the stability of the three-dimensional foams.

Jan 1, 2005

By D. Crone, T. Watts

"The Lindsley project was a program of deep drilling to test the contact down-dip from two nickel-copper deposits, one uneconomical and the other mined out. The role of Borehole Pulse EM(PEM) was to detect the higher grade, more massive sulphide zones if they were missed by a drillhole, and to help determine geometry if the zones were intersected. Two problems appeared as the PEM survey progressed: (1) conductivity-thickness as measured by the PEM did not always relate to economic sulphides as determined by the market; (2) a pattern of unusual PEM anomalies was obtained that indicated something odd and big, but the cause was unknown. A large fold structure subsequently was indicated by a program of deepening previous holes, the third of which intersected high-grade mineralization below 1280 m. Falconbridge is in the process of shaft sinking and underground exploration.IntroductionThe Falconbridge Lindsley property is on the south rim of the Sudbury basin, 8 Ian north of downtown Sudbury. The original property was acquired by a prospector named James Stobie, who, in early August 1885, staked a showing that later became the Mount Nickel mine (Fig. I). On August 10 Stobie staked another property that would become the Little Stobie mine, and at the end of the same month he staked the main Stobie orebody.In 1888, the ground immediately west of the MOlU1t Nickel find was staked. This ground contained the Blezard deposit (Fig. 1) which was put into production in 1889 and was eventually acquired by Inco. Down-dip from the Blezard workings, on Falconbridge ground, is located the upper Lindsley No. 1 deposit which was drilled off by Falconbridge in the 1940s to 1950s. A decision to go underground on the Lindsley No.1 mineralization was made in 1969, but the project was cancelled in 1971 because of declining nickel prices. The shaft was stopped at 95 m, and the headframe and hoist were sold. Further surface exploration drilling in the 1970s discovered the deeper Lindsley No. 2 zone, but as it had grades similar to those of the No. 1 zone, it too was considered uneconomic."

Jan 1, 1992

By Henry M. Howe

This paper gives the results of an investigation of the beha vior of the argentiferous cobalt-nickel arsenides of Temiskam-ing, Ontario, in roasting, made in the metallurgical laboratories of the School of Mines of Columbia University in the City of New York. The ore was kindly given by the owners of the La Rose and Trethewey properties at Cobalt, Ontario, and Mr E. J. Hall, Tutor in Assaying in Columbia University, has helped us much. I. Object of the Investigation. The object of the investigation was to learn: 1. The temperature at which the arsenic is most rapidly expelled ; 2. The thoroughness with which it is expelled by prolonged roasting at this temperature; 3. The effect of adding charcoal (a) near the end of the roast and (b) at. the beginning of the roast. II. Nature of the ORe. The important ores mined in the Temiskaming deposits are: native silver—with small amounts of dyscrasite (Ag,Sb), ar-gentite (Ag,S), pyrargyrite (Ag,SbS,)—smaltite (CoAs,), chlo-anthite (NiAs,) and niccolite (NiAs). Mispickel (FeAsS) and cobaltite (CoAsS) also occur in smaller quantities. The average composition of the ore shipped from this district for the first six months of 1905 was: silver, from 4.1 to 4.8 per cent.; cobalt, from 6.9 to 8.2 per cent.; nickel, from 3 to 4.7 per cent.; and arsenic, from 30.9 to 34.6 per cent. The ore which we treated consists chiefly of smaltite. In our 1aboratory-work

Jan 1, 1908

By Qin Hua, Xiangru Chen, Qijie Zhai, Yongsheng Yan, Liang Chang

"In this paper, pure bainite ductile iron and their alloying form of 0.2wt% niobium were prepared by a controlled cooling heat-treatment. The effect of niobium alloying on the microstructure, hardness and impact toughness of bainite ductile iron was studied. The results show that adding niobium effectively improves the hardness and toughness of bainite ductile iron. The hardness and the impact toughness of niobium-alloyed bainite ductile iron were investigated by varying the temperature at which samples were fed to the incubator.IntroductionThere are two essential methods to prepare the bainite ductile iron: isothermal quenching [I-31, and alloying [4• 51• Isothermal quenching process is very time and energy consumable, concerned as a high cost technique for mass production. Besides, there are certain limitations on the size and shape of castings in this process. In addition, it potentially harms the environment. As for the alloying, Ni, Mo, and Cu have to be utilized to obtain bainite. However, the large demand and high cost of Ni makes it not feasible in practice.It is well known that niobium can promote the formation of carbon compound, and improves the stability ofundercooled austenite, which is preferred to the increase of the hardenability. Previous studies showed that niobium could refine the grain and improve the mechanical properties of gray cast iron [6-81 • Therefore, in the present work, the effects of niobium and the temperature at which samples were fed to the incubator on the microstructures and properties of niobium alloyed bainite ductile iron were investigated."

Jan 1, 2014

By W. P. DYKEMA

This report gins the results of a study conducted hy the Ilnreau of Mines for the purpose of informing the petroleum industry on the recent progress in the de,·elopment nncl application of the absorption process for recO\·ering gasoline from natural gas. The work has been undertaken entirely with regard to plant practice and for the purpose of describing the features and the operation of units of the plants now in use, the improvements that have been made, and the reasons for any ehanges eontemplated by the engineers in eharge· of the plants studied. Throughout the United States the impro,·ements in the absorption process that are under consideration by engineers not only widen practice so as to include gases at all pressures and percentages of gasoline content, but seem to be dewloping definite standards as to dimensions of towers, l"elocities of flow, saturation of oi~ areas of eooling surfaces, and quantities of menstruum to be circulated. Although perfect practice has by no means been attained, the writer belie,·es thnt a description of the current practice at ,·arious plants, including those ob,'iously more efficient features that each plant hns <le\"eloped and uses at one or another stage of treatment, will intere;; t and possibly help all persons operating or designing absorption plants.

Jan 1, 1919

By C. G. Dunn

The measurement of interfacial teusions or grain boundary energies in metals is an important metallurgical problem, especially since it bears on growth and nucleation processes. Statistical methods of measuring equilibrium grain boundary angles, which relate interfacial tensions, have been used by some investigators1&apos;2 but more direct methods would be preferred. A direct way, based on a simple extension of a successful method of growing single crystals of silicon ferrite to predetermined orientations in flat specimens,3 is to produce three-grain specimens in such a way that the equilibrium common grain boundary will be perpendicular to the surface of the specimen. The angles to be measured then appear as the grain boundary angles in the surface of the specimen. The method of producing a single crystal specimen with a predetermined orientation is basically the same as that employed by Yoshida and Fuji-wara4 in their work on aluminum wires. The specimen, prior to any single crystal transformation, must have a matrix which will support the growth of a crystal of the desired orientation. Growth may occur through exaggerated grain growth or, if the matrix is strained a critical amount. by normal recrystallization. In either case the matrix must have stability at the temperature used to effect the transformation, this stability appearing as a long induction period for exaggerated grain growth or for the formation of recrystallization nuclei. Additional control is gained by using a high temperature gradient through which the specimen is moved at a suitable rate. To obtain the desired orientation, the specimen is fed a short way into the furnace producing one or more crystals in the hot end. After the specimen is removed from the furnace, the orientation of a crystal is determined, so that this crystal may be reoriented by properly deforming a narrow piece of the matrix between the end crystal and the rest of the specimen. This part of the specimen in the case of silicon ferrite is preferably held at red heat during the reorienting process. Fig 1 shows a specimen which is ready to be transformed into a single crystal through growth of a reoriented "seed" crystal. When the method just described is applied to the production of a three-grain specimen two crystals are grown first side by side in one end, the specimen is then reversed and the third grain grown from the opposite end. A suitable group of grains each of different orientation is one where all three grains have the same crystallo-graphic plane in the plane of the specimen. Fig 2 shows a photograph of a three-grain group prepared as described. The notches are introduced in the open ends of the grain boundaries to anchor them during the final annealing operations which ultimately should bring the grain boundaries to the lowest energy configuration. Two-grain groups with different crystallographic planes in the plane of the specimen can be similarly prepared and treated. If the two grains have different surface (gas to metal) energies per unit area, the equilibrium condition leads to a curved grain boundary.* * This feature of the problem was pointed out by J. c. Fisher. References 1. Cyril Stanley Smith: Grains. Phases and Interfaces: An Interpretation of Microstructure. Trans. AIME 175, 15. Met. Tech. TP 2387, June 1948. 2. D. Harker and E. Parker: Grain Shape and Grain Growth. Trans. A.S.M. (194,5) 34, 156-195. 3. C. G. Dunn, A. Seddon, and R. Wylie: Unpublished Work, 1946-1947. 4. Takeo Fujiwara: A Method of Producing A Long Single-Crystal Wire of Aluminum with any Desired Crystallographic Axis. Jnl. of Sci. Horoshima Univ. A, (1939) 9, No. 3, 227.

Jan 1, 1950

By J. A. Sanchidrián, P. Segarra, S. Gómez

Blasting is a common activity in mining that can cause significant damage in the remaining rock mass. The most commonly used method for predicting vibrations is the Swedish or Holmberg-Persson approach. It is a simple and fast method that uses empirical formulation to estimate the vibration levels based on the explosive charge weight, distance to the source, and other parameters. However, it has limited accuracy and does not consider the effect of free surfaces or other boundary conditions. On the other hand, recently developed methods as the full-field solution (FFS) can provide more accurate predictions of vibrations due to excitations provoked by cylindrical columns of explosive, but the inclusion of free surfaces in analytical methods is a challenging problem. This paper presents a new approach that includes free surfaces in the FFS to predict vibrations analytically in the near-field. The main obstacle to including free surfaces in the FFS was the belief that the solution was non-decoupleable in P- and SV-waves separately. The Heelan's approach was previously used to decouple them, but it only provides valid radiation patterns in the far-field and does not account for intrinsic attenuation. In this paper, we address this problem successfully, allowing for the inclusion of free surfaces in the FFS.

Jan 1, 2024

By J. S. Billheimer, B. H. Sage, W. N. Lacey

A restricted ternary system made up of n-pentane, tetralin, and a purified bitumen was investigated at 70, 160, and 220 °F. Most of the experimental observations were at atmospheric pressure or at 200 psi." However, some experimental measurements were carried out at a pressure of approximately 8000 psi. It was found that the purified bitumen was precipitated from its solution or dispersion in tetralin by the addition of n-pentane and that the separation occurred at lower weight fractions of n-pentane at the lower temperatures. The bitumen-tetralin solutions show some colloidal characteristics at temperatures below 160 °F when near compositions at which the bitumen separates as a solid phase. At states remote from the phase boundaries and at temperatures above 160 °F these characteristics become less evident. Under these latter circumstances the mixtures tend to follow the behavior of true solutions, particularly in regard to the approach to heterogeneous equilibrium. An increase in pressure appears to increase the solubility of bitumen in tet-ralin-n-pentane solutions. This effect is more pronounced at temperatures above 160 °F than at lower temperatures. INTRODUCTION Asphaltic phases of plastic or solid nature have appeared in numerous instances during the recovery of petroleum from underground reservoirs. Such depositions occurring underground appear to have caused adverse production histories for particular wells or zones. Because of this field experience, it is desirable to understand the factors which influence the formation or separation of the asphaltic phases from petroleum. The problem is unusually complex because the number of true components involved is very large and the details of the phase behavior encountered are difficult to ascertain experimentally. The literature relating to asphalts, asphaltines, and bitumen is voluminous and widespread.&apos; Only those references which are directly pertinent to the work at hand are cited. The separation of an asphaltic phase, hereinafter called bitumen? from naturally occurring hydrocarbon mixtures has been the subject of several investigations.2&apos;3&apos;4&apos;5&apos;6 It has been found that as many as four phases4 may be produced from a crude oil by the solution of a natural gas and propane at a pressure of 1500 psi and a temperature of 70 °F. The separation of bitumen from such naturally occurring mixtures results in at least one liquid phase which is substantially free of high molecular weight components.³ The influence of the solution of lighter hydrocarbons on the separation of bitumen from a Santa Fe Springs crude oil has been investigated. The results indicate that in the case of the methane-crude oil system, the quantity of plastic or solid phase separated reaches a maximum between 0.14 and 0.19 weight fraction methane and then decreases until negligible at higher weight fractions of methane. Similiar behavior was encountered in the case of mixtures of ethane and crude oil. The decrease in the quantity of the solid phase with an increase in the weight fraction of the lighter component appears to result from the formation of an additional liquid phase6 in which the bitumen is relatively soluble. The formation of this additional phase probably occurs at a weight fraction of methane close to that at which the quantity of separated solid reaches a maximum. A comparison of the deposition of bitumen in the field with the separation of asphalts from lubrication oil has been made&apos; and apparently the phenomena are similar. The phase behavior of bitumen also appears to be comparable to that of coal tar."&apos; The chemical and physical characteristics of asphalts and bitumen have been the subject of extended investigations which have been reviewed in some detail by Katz.¹º The conclusion was reached that the dispersion of bitumen in a number of organic liquids was not entirely colloidal since it was impossible to isolate individual dispersed particles even with the electron microscope. However, the evidence appeared to indicate that at states close to phase boundaries the extent of the dispersion of the phases influenced the equilibrium to a greater extent than is encountered in many simpler systems. From earlier study of field samples it became apparent that the phase behavior of bitumen-hydrocarbon systems was unusually complex. It was difficult to characterize in detail the phase behavior involved in naturally occurring hydrocarbon systems, even after a relatively extended investigation. For this reason, the study of a somewhat simpler system which still behaved in a similar manner became desirable. Three major constituents were necessary as-follows: a bituminous solid, a liquid constituent which was a reasonably good solvent, and a constituent in which bitumen was largely insoluble. A sam-

Jan 1, 1949

By Harrison Schmitt

The definitions of the terms commonly used in connection with metamorphism at elevated temperature near igneous contacts are re-examined. As the study of tactite zones associated with igneous contacts progresses, more and more emphasis is put on the localization of the ore by structural forms. The generally early age of the silicates and late age of the sulphides is well established. Postsilicate structural deformation is likely to localize ore bodies. The silicates are often replaced by the ore minerals. we may not be far from proving that the elements involved in the formation of silicate aureoles are merely normal "volcanic" emanations, that silica, lime, magnesia, and alumina, and probably soda and potash, are likely to undergo local transfers only. The work of Newhouse suggests the agents of the formation of sulphides in deposits of various classifications are the volcanic emanations. Introduction The purpose of this paper is to define the terms commonly used in connection with the subject, to briefly review and discuss the broad features of the aureoles, to indicate some of the features lately recognized: to discuss the genesis, and to suggest how the associated ore deposits can best be studied and developed. When developing a subject in mining geology one is soon conscious of the vast amount of pertinent literature and that most relevant ideas, no matter how obscure, have been considered. One can only hope to make some small contribution in point of view, a few confirmatory observations, or, perhaps, suggest a small new idea indebted to the most recent data. It is nearly impossible, also, to give specific credit, and adequate credit, to all the contributors to a given subject. This study, furthermore, was not intended to cover the field exhaustively, nor is the bibliography complete. Definition OF Terms There is much confusion in the use of the broad terms concerned. Needless to say, metamorphism means change of form; metasomatism, change of substance. The term contact metamorphism, however, has been widely misused possibly by a majority of economic geologists and engineers. As originally adopted by European investigators it meant changes effected largely by heat (thermal effects) in the rocks invaded by plutonic intrusives, but did not include those local changes usually at the immediate contact brought about by the addition of substance, i.e., by metasomatism. The term has become clouded. In Europe it has

Jan 1, 1949

By Y. Y. Li, Q. Chen, Y. X. Cai, Q. Zhang, S. Mao

"Due to the influence of combustion conditions, the fly ash produced by some power plants has the problem of high-carbon content. The unburned carbon in fly ash can be removed by flotation, and the decarbon tailings should reach the national standard level I fly ash. The fineness of the requirement is one of the important indicators and is also an important factor affecting the tail ash activity. In this paper,adopting two methods investigate the effect of particle size on the flotation index: one is direct flotation of fly ash, and the other way is wet grinding + flotation of fly ash, comparing the two methods and selecting the appropriate process,which provides a way for the effective utilization of fly ash. INTRODUCTION Fly ash is a solid waste discharged from coal-fired power plants. The annual amount of emissions of fly ash are very large in China. The amount of fly ash were discharged from coal-fired power plants are increasing gradually, and the amount of fly ash stored has exceeded 2.5 billion tons, but the comprehensive utilization of fly ash is not high, which brings about a huge environmental problems( Lu et al.,2011). Carbon is a harmful component of fly ash in cement and concrete application (Zhang et al.,2008). Fly ash decarburization is an essential link to improve the utilization efficiency of fly ash and the reduce pollution ( Yang et al.,2012). Carbon is selected from fly ash to make full use of fly ash resources and improve utilization of fly ash (Li et al.,2008). In this paper, the flotation decarburization of high-carbon fly ash is studied, through comparing the grinding and not-grinding processes, optimizing the separation process of fly ash, which provides a way for the effective utilization of fly ash."

Jan 1, 2018

By L. S. Birks

The bainite transformation in a 3.5 pct Ni-1.25 pct Cr steel was studied under various conditions of cooling and stress. Several characteristics may be specified: 1) transformation in the bainite region (925° to 575°F) is very little affected by the manner of cooling from the austenitizing temperature at 1600°F to 575°F)tothe upper limit of bainite transformation at 925°F; 2) starting time for the bainite transformation is the same order of magnitude for either isothermal transformation or continuous cooling, but the rate of transformation is somewhat greater for isothermal transformation; 3) tensile stress accelerates both isothermal and continuous cooling transformation, and 32,000 psi stress changes the form of the isothermal transformation diagram to correspond in appearance to the continuous cooling diagram; 4) transformation for nonlinear, continuous cooling may not be determined directly from the linear, continuous cooling transformation diagram, but may be predicted by assuming first that the fractional amount of austenite transformed in a given small temperature interval depends on the approximate linear cooling rate during that temperature interval and then by summing stepwise over the whole temperature range. IN a previous publication&apos; an X-ray spectrometer was described with which the X-ray diffraction from a specimen could be observed continuously under controlled temperature and tensile stress. This instrument has now been applied to a study of the austenite-bainite transformation in a Ni-Cr steel for both isothermal and continuous cooling conditions, with and without stress. Certain characteristics of the transformation lead to a method of predicting the amount of transformation to be expected at a given temperature for any type of cooling curve. Material and Specimen Preparation The steel chosen for the investigation was a Ni-Cr steel having the composition in the following percentages: 0.30 C, 0.27 Mn, 0.019 P and S, 3.50 Ni, and 1.25 Cr. In order to fabricate specimens suitable for the X-ray spectrometer, a 1/4 in. plate was ground down to 0.060 in. and then cold rolled to about 0.035 in. Next it was heat treated by quenching in oil from 1650°F and tempering at 1200°F for 1 hr. Then it was etched in dilute nitric acid to reduce its thickness to 0.014 in. and cut into blanks in the shape of flat tensile specimens 3 1/4 Vi in. long, 7/16 in. wide, with a notch % in. long and 7/32 in. wide; see Fig. 1. X-Ray Technique Since the X-ray spectrometer has been described in detail elsewhere,&apos; only a brief outline of the principles will be repeated here. A focusing, pow- der-diffraction arrangement&apos; was used, as shown schematically in Fig. 1, and the specimen was mounted vertically in a vacuum furnace (not shown in the figure). The X-rays, moving in a horizontal plane, enter and leave the furnace through beryllium windows. As shown in the figure, X-rays diverging from the line source A are diffracted by the specimen B and converge at the detector slit C. The detector D and the slit C may be set at the proper angle in the horizontal plane to receive X-rays diffracted by either the face-centered phase (austenite) or the body-centered form (ferrite, bainite, martensite). The specimen is heated by electrical conduction between connectors E, and E,, and a Pt—Pt-10 pct Rh thermocouple spot-welded to the center of the notched region on the side away from the X-ray beam indicates the temperature continuously on a Brown recorder. Temperature control is exercised manually with a variable transformer on the input to E,-E,. Any desired time-temperature relationship is easily obtained by first drawing the desired curve on the temperature recorder chart and then adjusting the variable transformer during the run so that the thermocouple

Jan 1, 1957

By W. N. Lacey, B. H. Sage, J. S. Billheimer

A restricted ternary system made up of n-pentane, tetralin, and a purified bitumen was investigated at 70, 160, and 220 °F. Most of the experimental observations were at atmospheric pressure or at 200 psi." However, some experimental measurements were carried out at a pressure of approximately 8000 psi. It was found that the purified bitumen was precipitated from its solution or dispersion in tetralin by the addition of n-pentane and that the separation occurred at lower weight fractions of n-pentane at the lower temperatures. The bitumen-tetralin solutions show some colloidal characteristics at temperatures below 160 °F when near compositions at which the bitumen separates as a solid phase. At states remote from the phase boundaries and at temperatures above 160 °F these characteristics become less evident. Under these latter circumstances the mixtures tend to follow the behavior of true solutions, particularly in regard to the approach to heterogeneous equilibrium. An increase in pressure appears to increase the solubility of bitumen in tet-ralin-n-pentane solutions. This effect is more pronounced at temperatures above 160 °F than at lower temperatures. INTRODUCTION Asphaltic phases of plastic or solid nature have appeared in numerous instances during the recovery of petroleum from underground reservoirs. Such depositions occurring underground appear to have caused adverse production histories for particular wells or zones. Because of this field experience, it is desirable to understand the factors which influence the formation or separation of the asphaltic phases from petroleum. The problem is unusually complex because the number of true components involved is very large and the details of the phase behavior encountered are difficult to ascertain experimentally. The literature relating to asphalts, asphaltines, and bitumen is voluminous and widespread.&apos; Only those references which are directly pertinent to the work at hand are cited. The separation of an asphaltic phase, hereinafter called bitumen? from naturally occurring hydrocarbon mixtures has been the subject of several investigations.2&apos;3&apos;4&apos;5&apos;6 It has been found that as many as four phases4 may be produced from a crude oil by the solution of a natural gas and propane at a pressure of 1500 psi and a temperature of 70 °F. The separation of bitumen from such naturally occurring mixtures results in at least one liquid phase which is substantially free of high molecular weight components.³ The influence of the solution of lighter hydrocarbons on the separation of bitumen from a Santa Fe Springs crude oil has been investigated. The results indicate that in the case of the methane-crude oil system, the quantity of plastic or solid phase separated reaches a maximum between 0.14 and 0.19 weight fraction methane and then decreases until negligible at higher weight fractions of methane. Similiar behavior was encountered in the case of mixtures of ethane and crude oil. The decrease in the quantity of the solid phase with an increase in the weight fraction of the lighter component appears to result from the formation of an additional liquid phase6 in which the bitumen is relatively soluble. The formation of this additional phase probably occurs at a weight fraction of methane close to that at which the quantity of separated solid reaches a maximum. A comparison of the deposition of bitumen in the field with the separation of asphalts from lubrication oil has been made&apos; and apparently the phenomena are similar. The phase behavior of bitumen also appears to be comparable to that of coal tar."&apos; The chemical and physical characteristics of asphalts and bitumen have been the subject of extended investigations which have been reviewed in some detail by Katz.¹º The conclusion was reached that the dispersion of bitumen in a number of organic liquids was not entirely colloidal since it was impossible to isolate individual dispersed particles even with the electron microscope. However, the evidence appeared to indicate that at states close to phase boundaries the extent of the dispersion of the phases influenced the equilibrium to a greater extent than is encountered in many simpler systems. From earlier study of field samples it became apparent that the phase behavior of bitumen-hydrocarbon systems was unusually complex. It was difficult to characterize in detail the phase behavior involved in naturally occurring hydrocarbon systems, even after a relatively extended investigation. For this reason, the study of a somewhat simpler system which still behaved in a similar manner became desirable. Three major constituents were necessary as-follows: a bituminous solid, a liquid constituent which was a reasonably good solvent, and a constituent in which bitumen was largely insoluble. A sam-

Jan 1, 1949

By Harrison Schmitt

The definitions of the terms commonly used in connection with metamorphism at elevated temperature near igneous contacts are re-examined. As the study of tactite zones associated with igneous contacts progresses, more and more emphasis is put on the localization of the ore by structural forms. The generally early age of the silicates and late age of the sulphides is well established. Postsilicate structural deformation is likely to localize ore bodies. The silicates are often replaced by the ore minerals. we may not be far from proving that the elements involved in the formation of silicate aureoles are merely normal "volcanic" emanations, that silica, lime, magnesia, and alumina, and probably soda and potash, are likely to undergo local transfers only. The work of Newhouse suggests the agents of the formation of sulphides in deposits of various classifications are the volcanic emanations. Introduction The purpose of this paper is to define the terms commonly used in connection with the subject, to briefly review and discuss the broad features of the aureoles, to indicate some of the features lately recognized: to discuss the genesis, and to suggest how the associated ore deposits can best be studied and developed. When developing a subject in mining geology one is soon conscious of the vast amount of pertinent literature and that most relevant ideas, no matter how obscure, have been considered. One can only hope to make some small contribution in point of view, a few confirmatory observations, or, perhaps, suggest a small new idea indebted to the most recent data. It is nearly impossible, also, to give specific credit, and adequate credit, to all the contributors to a given subject. This study, furthermore, was not intended to cover the field exhaustively, nor is the bibliography complete. Definition OF Terms There is much confusion in the use of the broad terms concerned. Needless to say, metamorphism means change of form; metasomatism, change of substance. The term contact metamorphism, however, has been widely misused possibly by a majority of economic geologists and engineers. As originally adopted by European investigators it meant changes effected largely by heat (thermal effects) in the rocks invaded by plutonic intrusives, but did not include those local changes usually at the immediate contact brought about by the addition of substance, i.e., by metasomatism. The term has become clouded. In Europe it has

Jan 1, 1949