Search Documents

By A. W. Schlechten

The proposition is advanced that edutcation specifically for exlractive metallurgy is desirable not because the course content is cmique but rather as a means of indoctrinating the student with a backgrocmd that will give him an interest and pride in the profession. Factors that have caused the decline in enrollment in metallurgical engineering courses emphasizing extractive processes are being overcome. There is a need to distinguish between the sciences of metallurgy and the engineering applications to avoid confusion both in and out of the profession. AS a first step in preparing the 1967 EMD Lecture I searched the literature to determine what my predecessors had done hoping thereby to gain some clues for my own performance. The Transactions of the Metallurgical Society show that the first EMD Lec- turer in 1959 was Dr. W. J. Kroll, known chiefly today for his pioneering work on the production of titanium and zirconium, but equally respected by an earlier generation for his contributions to lead refining. He has been followed by a series of well-known and competent metallurgists all possessing specialized knowledge that has served as a basis for their lectures. The EMD Lectures have in general been a review of the development of a certain aspect of the extractive metallurgical industry or a preview of a particular area of science or technology that has applications in extractive metallurgy. The usual format is to describe developments of the past, summarize the present state of knowledge, and make predictions for the future. There has been great variation in the relative amount of time devoted to these three subdivisions, the past, the present, and the future. For example, Professor Gaudin, the 1961 EMD Lecturer, in speaking of Separation Engineering on the Moon, did not have too many examples of past practice and so had to emphasize the future. It is cheering to observe that all of these authorities were optimistic in their predictions. Despite the fact that four of the previous EMD Lecturers have been educators, Professors Gaudin, Pidgeon, Schuhmann, and Kellogg, none of them discussed the subject of education for extractive metallurgists. I might say parenthetically that lecturers in other divisions, such as B. M. Larsen, J. B. Austin, F. D. Richardson, John Chipman, and R. F. Mehl, have commented with concern on the present state of training for extractive metallurgy. What can you say that is new about extractive metallurgy education? Certainly nothing new can be said about the educational process itself. Professional educators do have new approaches to teaching and learn-

Jan 1, 1968

By Eugene H. Cowles

The German silver industry of the United States amounts in value to upwards of $6,000,000 or $8,000,000 annually. Several thousands of people earn a livelihood pursuing it, and the beautiful goods and articles manufactured from this time-honored and valued alloy are everywhere visible. German silver enters largely into our street signs, harness and house hardware, and all manner of table-ware, solid or plated. There is scarcely an hour in the day that German or nickel-silver is not before our eyes. The composition of this alloy is a very uncertain thing, and depends largely on the honesty of the manufacturer and the price the purchaser is willing to pay. It is composed of copper, zinc and nickel in varying proportions. The best varieties contain from 18 to 25 per cent. of nickel, and from 20 to 30 per cent. of zinc, the remainder being copper. The more expensive nickel-silver contains from 25 to 33 per cent. of nickel, and from 75 to 66 per cent. of copper. The nickel is used as a whitening element; it also strengthens the alloy and renders it harder and more non-corrodible than the brass made without it, of copper and zinc. Moreover, it reduces the odor emanating from brass, which is so disagreeable if it occurs about the dining-table. Of all troublesome alloys to handle in the foundry or rollingmill, German silver is the worst. It is unmanageable and refractory at every step in its transition from the crude elements into rods, sheets or wire. As a white-headed furnace-man recently said to the writer, in one of our large mills, " you can put eight crucibles into the fire, each containing exactly the same mixture of German silver, and when you take them out and pour them into slabs for rolling, seven will be a mass of scum or slag, or the stuff will swell up like rising bread and overflow the moulds, and be so full of blow-holes that it will look like a sponge. The eighth crucible will contain perfectly good metal. On remelting the next day, the bad stuff will, in nine chances out of ten, come out just as good metal as the eighth pot the day before, and under apparently the same conditions." With nickel at seventy or eighty cents per pound, German silver

Jan 1, 1890

By A. Abadías Llamas, N. Bartie, M. Stelter

Evaluating the economic viability as well as the sustainability of the Circular Economy (CE) system requires a deep understanding of the distribution of all elements, compounds, alloys, materials etc. in flows. In this paper, the circularity of the copper value chain, including primary and secondary processing, is rigorously evaluated. The studied system comprises the metallic copper production from primary sources (from mineral to metal), copper-containing commodity production (copper is mixed with other metals) and copper recycling through secondary smelting to close the loop. This is linked to photovoltaic (PV) panels and battery storage. A simulation model of this system is created using HSC Sim, considering more than 30 elements (and its various compounds), 180 unit operations and 800 flows. From the mass and energy balances obtained through the simulation, an exergy analysis is conducted to evaluate the resource consumption from a second law (entropy) perspective. Additionally, these results are complemented through a Life Cycle Assessment (LCA), the recovery of technology elements and by-products is discussed, while quantifying the losses through the value chain. Through the digitalization of the complete system, a better CAPEX and OPEX understanding of the metal recovery and losses can be obtained, as well as the associated resource consumption and environmental impacts. New flowsheets and technologies can be evaluated. Several scenarios show how the resource consumption and the environmental impacts are affected by the recovery of different materials to produce different products. INTRODUCTION A key challenge of the circular economy (CE) is the linkage and optimization of both resource and energy efficiency of the (renewable) energy infrastructure and the resource cycle depicted by Figure 1 simultaneously. In addition, the CE requires the linkage of all stakeholders as shown by Figure 1. This has been discussed in some detail by Reuter and Bartie (2019) and Reuter et al. (2019). Copper and all its associated technology elements is one of the key enabling metals that is an economical copper colored thread through CE society (Reuter & Kojo, 2014). The Metal Wheel (Figure 2) shows the linkage of and recovery of various elements associated with copper and other carrier metals. This reveals that copper acts as an important carrier metal because of its properties i.e. the wealth of technology elements it carries from geological ores, but also its capacity to act as solvent of valuable elements and thence a key closer of various complexly connected element and material cycles when these technology elements are released during copper refining. The same applies to all other carrier metals of modern CE society as shown for example recently in a lead policy brief (Blanpain, Reuter & Malfliet, 2019).

Jan 1, 2019

By J B Tucker, A T. McGrath

Situated in north-west Queensland, Australia, the Ernest Henry Mine (EHM) has been producing copper and gold since 1996. Owned and operated by Glencore Xstrata, ore is currently sourced from a newly developed underground sublevel cave (SLC) mine below the old EHM open pit (the pit). Ore feed to the concentrator is supplemented by satellite open pits comprising the Mount Margaret operation.The transition from open pit to a producing underground mine involved a complex extraction sequence for the first two production sublevels on RL1650 and RL1625. Underground mining during cave initiation was further complicated when south wall instability prevented completion of the final open pit shell. The transition mining phase included mass firing of an inclined crown pillar between the initial SLC void and the pit followed by a combination of transverse and longitudinal SLC mining.The inclined crown pillar mass firing was the first significant milestone in the extraction of the transition ore block. Comprising approximately 890 000 t of in situ material; 70 000 m of drilling was charged with 351 t of emulsion and 6026 electronic detonators to initiate the single mass firing. The firing contained five direction changes over 19 seconds making it one of the largest and most complex underground blasts ever conducted in Australia.Risk management was integrated into every facet of the technical and operational planning and execution of the transition mining phase, whilst maintaining daily mine construction and production commitments. This paper provides a detailed overview of the transition objectives and constraints, mining method selection, post mass blast outcomes and the journey ahead.CITATION:McGrath, A T, Campbell, A D and Tucker, J B, 2014. Transition of the Ernest Henry Mine from open pit to an underground sublevel cave, in Proceedings 12th AusIMM Underground Operators’ Conference 2014 , pp 297–308 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Mar 24, 2014

By P. D. Gorsuch, D. L. Newhouse, Irvin R. Kramer

ALTHOUGH many methods have been suggested for the calculation of tensile strength and yield point from chemical composition, their usefulness has been limited to a particular cooling rate or section size. Further limitations have been imposed by failure to take into account many of the alloying elements that exert a considerable influence on the tensile strength or yield point. These systems, nevertheless, have filled an important need in many instances. The value of a system for the calculation of the tensile properties from the chemical composition and cooling rate is that it permits the prediction of the effect of alloying elements and heat-treatment on the mechanical, properties, so that more efficient use of alloying elements may be made. Furthermore, it aids in the choice of steel for a given application and tends to decrease the number of steels that otherwise would have to be tested. It is the purpose of this work to present a method of calculating tensile strength and yield point from the chemical composition and to suggest a method of correlating the tensile-strength and yield-point factors and cooling rate. Steelmakers have been interested for many years in the calculation of the tensile strength of hot-rolled steels. Quest and Washburn' summarize several of the attempts that have been made to devise formulas. They show the inadequacy of each of these formulas and present one of their own. It is apparent from their work that a simple additive equation of the type TS = A + BX + Cy + DZ + ? ? ? , where A, B, C, D, etc. are experimentally determined constants and x, y, z, etc., are the percentages of alloying elements present in the steel, is not adequate to analyze fully the situation encountered in the calculation of tensile strength. For example, it was found that the difference between the calculated and observed values became progressively greater as the carbon and manganese contents were increased. Therefore, the effect of manganese was given as a function of the carbon content. Grossmann,2 in his work on the hardenability of quenched steels, and Walters,3 in his method of calculation of tensile strength of normalized steels, present two cases in which multiplying factors were successfully used to express the combined effect of alloying elements. The factors in both cases were obtained from the fractional increase in hardenability or tensile strength with increase of alloy content. Yield point often is more important in design than tensile strength. For quenched and tempered steels a linear correlation exists between yield and tensile strength .4 This is not true, however, for normalized

Jan 1, 1946

By A. R. Jr. Amos

LOG washers have been used for many years in the washing of clay iron ores, phosphate rock and manganese ores, but not until the past 15 years have they been employed to any extent in the preparation of aggregate materials and fluxing stone. For a machine of such importance where tenacious clay or soft rock must be eliminated, there are few data generally available. The purpose of this paper is to set forth the results obtained from several operations, together with a few suggestions for planning a specific installation. Where the material to be washed out consists of loose surface soil, silt, or small amounts of quickly soluble clay, there is little competition with other forms of washers, because greater power and maintenance are required for the operation of log washers, but where the foreign matter is a stiff clay, such as occurs with high-calcium limestones and in marginal gravel deposits, the ability of other kinds of washers to eliminate com-pletely the hard clay balls is at least uncertain. Then the log washer comes into its own field, for with the breaking and churning action of the logs it will clean out the toughest clay. Even with material from the hydraulic dredge, if it contains tough clay, the log washer is desirable unless the gravel is subjected to a costly soaking and rehandling process. Recently there has been a considerable development in other types of machines to accomplish these results but it is not within the scope of this paper to make comparisons between competitive types, but to present the best obtainable data on log washers only. From the primitive design that gave it its name, a long log hewn from a tree, with paddles forged to shape from strap iron and attached by lag screws, the log washer has gradually been developed to the present all-steel type. As now manufactured, the log washer consists essentially of two built-up logs on which are mounted a series of paddles, carried by shafts fitted at the ends of the logs on bearings fastened outside the enclosing steel box, or trough, which is set at an angle of about 5° to 10° and into which the material is fed. Stuffing boxes at the places where the shafts pass through the box at the lower end are equipped with water-

Jan 1, 1936

By H. Seguin, J. A. Le Gac, S. Bernhard, P. R. ZETTWOOG

The "Service de Protection Technique"of the "Institut de Protection et de Sûreté Nucléaire" was asked by the Commission of European Communities to conduct measurement campaigns which would make it possible to evaluate, on an experimental basis, the collective risk to miners exposed to radon in underground, non-uranium mines located in countries within the European Community. 1. METHODOLOGY USED TO CONDUCT THE CAMPAIGNS This campaign is original in that direct measurements of the individual monthly exposure to potential [a]-energy from short-lived radon daughters are made using personal [a]-dosimeters described previously (1). We call this type of dosimetry "personal dosimetry". The workers who wear the personal [a]-dosimeters were selected taking into account the various categories of workers and their work assignments in the various areas of the mine. Another way of finding out the occupational exposure of these miners consists in making numerous measurements of the radon concentration at the various work places, taking into account the time spent at each place by each worker. This procedure is too complex for an evaluation of the collective risk as requested by the Commission of European Communities and was therefore rejected. Additional data was gathered during these measurements campaigns using the following techniques (table 1). [ ] (1) Current [a]-dosimetry as practiced in France - SPT international report N° 234 - February, 1981 - P. ZETTWOOG The mines were chosen to include a larger variety of types of ore, of geological situations, and of mining methods. 2. RESULTS OF THE RADON DATA-GATHERING CAMPAIGNS 2.1 – [Uranium content of the surrounding rocks and ore] The samples taken during the campaigns make it possible to establish the U content in the rocks of the mines selected. These values, from 2 to 15 ppm, are slightly higher than those usually found (2 to 5 ppm) (table 2). [ ]

Jan 1, 1981

By James M. Tantalla, Roderic A. Ellman, W. Allen Marr, Scott R. Bamford

"Construction of the powerhouse for the Willow Island Hydroelectric Project required a 100-ft deep excavation inside the limits of a cofferdam and embankment-seepage cut-off wall through soil and rock adjacent to the Ohio River. Portions of the rock had preexisting weak plans and slickensided surfaces with low frictional strength. Stability analyses were performed for critical sections of the excavation to evaluate the stability of the soil slopes and rock cuts using buckling, tension crack, and limit equilibrium analysis techniques. Loading conditions included the 100-yr and intermediate floods, normal pool, sudden drawdown, and seismic design conditions.Stability analyses indicated adequate factors of safety for soil slopes and for rock cuts through the landside embankment sections. However, the results of deep-seated stability analyses through the rock supporting the riverside cellular cofferdam indicated unacceptable factors of safety. Consequently, the riverside portion of the excavation required measures to increase stability. Long, high-capacity rock anchors and deep dewatering wells to lower the site piezometric head were chosen for this purpose.Thirty high-capacity rock anchors were installed on the upstream, riverside, and downstream sides of the cofferdam rock cut. Required rock anchor loads varied from 1,968 to 2,074 kips. The designed anchors consisted of multiple, seven–wire strands with up to 59 strands per anchor. Bond lengths used an allowable bond stress of 100 psi based on the rock bond measured with pull-out tests. Maximum bond and anchor lengths were 50 ft and 140 ft, respectively. Measurements of forces in selected strands and displacements of the excavation showed excellent performance."

Jan 1, 2017

By C. E. Abbott

The Birmingham district, Alabama, is distinctive in the proximity to one another of its deposits of iron ore, coal and flux. These three basic requisites for the making of iron and steel are found within a radius of 10 miles. Both dolomite and limestone are produced, the former for blast-furnace flux and the latter for basic open-hearth operations. The Tennessee Coal, Iron and Railroad Co., a subsidiary of the United States Steel Corporation, operates a limestone mine at Muscoda, near Bessemer, 12 miles southwest of Birmingham, served by its own railroad transportation system. The mine has a capacity of 130 tons per hour. Average analyses of a recent month's production arc as follows: Fe²zO³ SiO² Al²O³ CaCO³ MgCO³ Lump, percent............................. 0.51 0.22 98.63 0.14 Crushed and washed, per cent,................ 0.70 0.26 98.36 0.18 Lump stone, 2 1/2 to 755 in., is used in open-hearth operations at Fairfield Steel Works. Fine crushed and washed stone, 1% to 0.063 in., is calcined at the lime-burning plant and used for lime charges at the Ensley open hearths. Geology The district's deposits of hematite ore occur in the Clinton formation, and the limestone beds mined are stratigraphically 330 ft. above the ore beds worked. A cross section on the center line of the mine is shown in Fig. 1. This limestone formation, 130 ft. thick, is in the Warsaw horizon of the Lower Mississippian. It lies above 100 ft. of Fort Payne chert, which is immediately above the Clinton formation, and is composcd of layers of chert and cherty limestone, approximately 50 per cent of the material being pure chert. The chert is extremely hard, and the cost of driving raises through it is very high. Both iron ore and limestone deposits lie on the southwest limb of the Jones Valley anticline, the formations dipping from 15' to 32' to the southeast. The iron-ore seam outcrops along the crest of Red Mountain, a ridge with northeast-southwest trend rising 200 to 300 ft. above Jones and Shades valleys at the

Jan 1, 1938

By Shufeng Yang, Anping Dong, Yongfeng Chen, Jingshe Li, Lifeng Zhang, Liyuan Sun

"Instead of nickel-based stainless steel, a nitrogen-bearing stainless steel was produced to reduce the production cost stemming from the shortage of nickel recourses. Thermodynamic model to calculate the saturation nitrogen content in the stainless steel were developed and the model was validated by experimental measurement. The experiments were performed with a high temperature induction furnace. Nitrogen gas under constant pressure was injected into the crucible with a top lance by which the nitrogen was transferred to the molten stainless steel. The effects of chemical composition, temperature, superficial active elements and nitrogen-flow rate on transferring nitrogen to the steel were investigated and discussed.IntroductionWith the rapid production growth of stainless steels, nitrogen-bearing stainless steel has recently attracted more and more attention for their high strength and excellent corrosion resistance imparted by interstitial nitrogen without decreasing its toughness and ductility. Moreover, the addition of nitrogen to the stainless steel as a substitute for nickel leads a lower consumption of nickel, so significantly lowers the high production cost stemming from the shortage of nickel recourses. However, production of the nitrogen-bearing steel is difficult since nitrogen is a gas element and has a low solubility in the steel. So efficiently increasing the amount of nitrogen in steel continues to be one of the main concerns for the production of nitrogen-bearing steels.Currently there are some special processes to produce austenitic stainless steels with a very high N content, including pressurized electroslag remelting, counter-pressure casting, special induction melting and powder metallurgy, etc [1]. Special expensive vacuum system was required for these processes. Alloying nitrogen at a normal pressure can be performed by alloy addition or gas injection. Blowing nitrogen gas is a more economic and advisable method since the nitrogen-bearing alloy is quite expensive and contains high content of impurities. A number of investigations have been reported on the solubility of nitrogen gas in pure iron [2] but few in iron-based multi-component alloys such as stainless steel.In the current study, the effects of steel chemical composition, temperature, superficial active elements and nitrogen-flow rate on transferring nitrogen to the steel were experimentally investigated with a high temperature induction furnace."

Jan 1, 2011

By A. Singh

"The flotation of fine minerals less than 10 µm in size is an age old challenge spanning both the precious metal and industrial mineral sectors across a range of commodities. This problem has been brought into sharper focus by the emergence of the practice of fine grinding of flotation feed to effect better liberation of the targeted minerals. However, the ability of conventional flotation cells to effectively float the liberated fines remains questionable. In order to overcome this problem, Gold Ore postulates the “Bringing the Mountain to Mohamed” hypothesis which comprises the steps of gas nucleation on particle surfaces, aggregation of particles and levitation of aggregates. Testing of this hypothesis at Mintek, South Africa, showed a ~180% increase in the Kelsall kfast factor coupled with a projected recovery improvement of ~4 % for the Mach Reactor case coupled with a final concentrate grade of ~2 times that of conventional flotation. These fundamentals were then extrapolated to plant scale with Mach Reactors installed on the flotation feed at Platmin’s Tailings Scavenger Plant (TSP) with the objective of scavenging the fine minerals lost to tailings by the main plant. This paper details the theory, pilot plant results as well as key aspects of the full scale plant design supplemented by operational plant observations after commissioning. This game changing application is regarded as being pivotal to future flotation plant design whilst providing the technology leverage required for the survival of mineral operations in an economically unfriendly environment.INTRODUCTION - THE CONUNDRUM OF FINE PARTICLE FLOTATION“If the mountain won't come to Mohamed then Mohamed must go to the mountain” is an age old saying written into the book of proverbs in 1670. Legend has it that Mohamed promised his people that he would summon a mountain to come over to him so that he could offer up his prayers from its summit. After numerous attempts at moving the mountain went in vain, Mohamed, quite unabashed, said “Well if the mountain will not come to Mohamed, then Mohamed will go to the Mountain.” In this analogy, Mohamed is a fine particle <10 µm and the mountain is a bubble within a flotation system. The age old challenge is how to bring these two together to achieve attachment?"

Jan 1, 2016

By C. E. Abbott

The Birmingham district, Alabama, is distinctive in the proximity to one another of its deposits of iron ore, coal and flux. These three basic requisites for the making of iron and steel are found within a radius of 10 miles. Both dolomite and limestone are produced, the former for blast-furnace flux and the latter for basic open-hearth operations. The Tennessee Coal, Iron and Railroad Co., a subsidiary of the United States Steel Corporation, operates a limestone mine at Muscoda, near Bessemer, 12 miles southwest of Birmingham, served by its own railroad transportation system. The mine has a capacity of 130 tons per hour. Average analyses of a recent month&apos;s production arc as follows: Fe²zO³ SiO² Al²O³ CaCO³ MgCO³ Lump, percent............................. 0.51 0.22 98.63 0.14 Crushed and washed, per cent,................ 0.70 0.26 98.36 0.18 Lump stone, 2 1/2 to 755 in., is used in open-hearth operations at Fairfield Steel Works. Fine crushed and washed stone, 1% to 0.063 in., is calcined at the lime-burning plant and used for lime charges at the Ensley open hearths. Geology The district&apos;s deposits of hematite ore occur in the Clinton formation, and the limestone beds mined are stratigraphically 330 ft. above the ore beds worked. A cross section on the center line of the mine is shown in Fig. 1. This limestone formation, 130 ft. thick, is in the Warsaw horizon of the Lower Mississippian. It lies above 100 ft. of Fort Payne chert, which is immediately above the Clinton formation, and is composcd of layers of chert and cherty limestone, approximately 50 per cent of the material being pure chert. The chert is extremely hard, and the cost of driving raises through it is very high. Both iron ore and limestone deposits lie on the southwest limb of the Jones Valley anticline, the formations dipping from 15&apos; to 32&apos; to the southeast. The iron-ore seam outcrops along the crest of Red Mountain, a ridge with northeast-southwest trend rising 200 to 300 ft. above Jones and Shades valleys at the

Jan 1, 1938

By Harrison Schmitt

IN the practice of ore finding the geologist is continually confronted with the question of oreshoot extension, so that the general problem seems worthy of systematic investigation. This problem appears when the reserves are estimated and when the advisability of deepening the shaft comes up. Moreover, there is need for lower development cost to keep pace with cost reductions in other departments, or even to offset a rising cost of ore finding or ore following. This can be gained by close geologic control of the development; and much of the geology involved is that bearing on the downward, upward, and horizontal extensions of shoots. Furthermore, the purchase of a mine or prospect often depends directly on the question of shoot extension; because it is seldom that the ore is fully developed and the purchase price is almost invariably based largely on "possible" and geologically prospective ore. Most current methods for estimating &apos;(possible" and the more nebulous classes of ore are crude and indecisive. In the following pages the extension of oreshoots is the major theme, although the more basic subject, the general art of ore finding, is given some space. (A) Direct Methods of Extension Prediction (I) Extrapolation and Interpolation of Shoots by Use of Conventional Geologic and Assay Plans, Projections and Cross-sections There is little need for stressing the desirability of detailed geologic plans, assay plans, projections, and cross-sections as a basis for the study and extension prediction of shoots. Underground and surface mapping, in most cases, ought to be done in exhaustive detail. All features of obvious bearing should be mapped and it is good practice to record all possible details, some of which may become significant when studied in the ensemble. It should be emphasized that the mapping should be done with an impartial mind, with interpretation reduced to the minimum. The symbols of the map can be made to distinguish observed facts from interpretation.

Jan 1, 1929

By F. F. Hintze

Petroleum production in the Rocky Mountain district during 1929 registered a small decline from that of the previous year, conforming with a gradual decrease in the amount of oil produced during the last few years. A number of causes may be mentioned to account for this result, chiefly overproduction in other regions and the apparent desire of operators in this territory to conform to the policy of proration and retrenchment adopted by special agreement among operators in many of the fields. Unit operation has been adopted to control oil production from the Sundance sands in the Salt Creek field, Wyoming, in line with the general effort to stabilize this phase of the industry and prevent excessive drilling of new wells. Another factor which greatly retarded development in the Rocky Mountain region was the executive order of President Hoover issued in March refusing the award of new prospecting permits to future applicants and threatening cancellation of all existing permits upon which actual drilling had not been done as specified by law. Only four states in the Rocky Mountain region are important oil producers. In 1929 Wyoming led with an average daily output of 52,600 bbl., followed by Montana, with 10,730 bbl.; Colorado, with 6500 bbl., and New Mexico with 2700 bbl. daily average. These states bear the following percentage relation to total production in the Rocky Mountain district: Wyoming, 72; Montana, 15; Colorado, 9; New Mexico, 4., (Table 1.) The total average daily production was approximately 73,000 bbl. and the total production of all four states during the year was 26,534,606 bbl. This is 2.7 per cent. of the total oil production of the United States during this period. Colorado Although Colorado is not a large producer of oil and natural gas, its oil operations are widely distributed over the state. The Florence field is one of the oldest oil fields in the country, and there are good reasons for believing that the state will retain its place for many years to

Jan 1, 1930

By J. W. van der Merwe, K. G. Moloko

Furnace wall tubes from 600 MW subcritical boilers at three coal-fired power stations were sampled and the fireside deposits examined to determine the mechanism of fireside corrosion. This involved an indepth investigation into the morphology and composition of the fireside deposits and the conditions of the furnace that enable this type of attack. SEM-EDS analysis revealed high concentrations of oxygen, iron, and sulphur, QEMSCAN and XRD analyses identified the presence of Fe3O4, Fe2O3, FeS, and FeS2. Differential thermal analysis showed thermal activities at temperatures of 500–600°C, 900–1100°C, and 1100–1250°C, which are associated, respectively, with FeS2 oxidation to FeS and Fe2O3, at 475–525°C, formation of aluminosilicates at 925–1100°C, and melting of FeS around 1190°C. The absence of sodium and potassium eliminates the contribution of molten alkali sulphates to the corrosion. The consistent coexistence of iron sulphide and iron oxide is indicative of the substoichiometric conditions in the furnace, while the detection of pyrite suggests that the coal is not completely combusted, which points to a poor combustion process. These observations were affirmed by gas analysis at one of the stations, where very high levels of carbon monoxide were measured at the furnace wall (≥ 14 000 ppm) and furnace exit (≥ 3500 ppm). The high CO concentrations are indicative of limited combustion caused by limited O2. These reducing conditions promote the formation of FeS-rich deposit, which is the corrosive species responsible for degradation.

Jun 1, 2021

By Justyna Swolkień, Nikodem Szlązak, Dariusz Obracaj

Polish coal mines are characterized by severe geological conditions and the co-occurrence of natural hazards. These hazards are associated with methane and dust emissions during mining processes which can provide methane, dust or methane-dust explosions. Besides, there are such natural hazards as gas and rock outbursts, rock bursts, spontaneous combustion of coal and environmental heat load. The mutual influences of various geological conditions, as well as the natural hazards, intensify the increase of the methane explosion hazard. The occurrence of methane explosions in the Polish mining industry between 2013 and 2108 are analyzed. Fatal accidents are compared with similar events in the global mining industry. The methods of preventing the explosion hazard as well as methane emission control in the Polish coal mining sector are presented. Methane hazard prevention should be adapted to levels and other natural hazards, especially those related to ventilation of underground mine. The methods of preventing methane emissions into mine excavations are often contrary to the means of preventing other ventilation-related hazards in the underground mine, e.g. the prevention of spontaneous combustion of coal in the goaf of longwall panel. Therefore, the design of longwall panels should be preceded by a detailed analysis of the results of both methane emission prediction and forecast of other ventilation-related hazards.

By Morandini AF, Occella E, Clerici C, Mancini R

This contribution presents the first results of an experimental research aimed at finding an unified description of the first stages of a rock comminution process. With reference to the case of the jaw crushers and to the specific subject of the comminution law, the tests reviewed and analysed in this contribution have been carried out, at a laboratory scale, on five different materials (limestones, quartzite, serpentinite) at different reduction ratios and feed rates, and accurately recording both total power and idle running power. The analysis of the results has shown that: ò the grain size distribution of the products complies with a modified form of the Rosin-Rammler equation, already found to be well suited to representing the grain size distribution of blasted rock in previous works by the authors; ò observed trends of the consumed power at increasing reduction ratios is steeper than predicted by the classical Rittinger, Kick and Bond laws, Rittinger law representing however a closer approximation of the experimental results; and ò a more accurate description of the experimental results is provided by a modified form of the Rittinger law. Accuracy of the semi-empirical expression has been found to be usually better than ten per cent by comparing actual results with expected Results.

Jan 1, 1993

By P. H. Brace, N. A. Ziegler

THE study of the relations between gases and metals is one of perennial interest to all who are connected with the production of high-grade metallurgical products. The data reported here are the outcome of work of which the object is to determine the effects of dissolved gases upon the properties of metals and to gain a more detailed knowledge of the reactions between gases and molten metals, particularly iron, under definitely controlled conditions. We have attempted to reduce our margin of error by dealing with relatively large quantities of metal, from 4 to 13 lb. (2 to 6 kg.), and keeping the ratio of refractories to metal as small as practicable. The ingots produced are large enough to provide adequate material for making determinations of magnetic and other physical properties. In choosing the bell-jar type of furnace we were influenced by the results of considerable experimentation along the same general line which indicated that, for the scale on which we were to work, it was important to have the furnace structure independent of the vacuum enclosure. The use of a bell-jar surrounding the entire furnace accomplishes this and also gives great freedom of observation during operation and ready accessibility for the replacements which are necessary after each run. Our choice of analytical method was made in the light of the results secured by H. M. Ryder, who used a method similar in principle for the analysis of very small quantities of gas extracted from strips of metal heated electrically in high vacuum. We have presented some selected preliminary experimental data as being illustrative of the quantity and nature of the gases which occur in iron of different origins, but do not urge any hypothesis at this time. THE FURNACE Our furnace may be described as "a high-frequency induction furnace of the bell-jar type." It is similar in a general way to that described by Cain and Peterson&apos; though we have introduced certain refinements of

Jan 1, 1928

By Cristiän Vargas, Jaime Simpson, Gerardo Cifuentes

"This paper presents a new process for the precipitation of Sb and Bi present in copper refinery electrolytes in the presence of Pb02 (Chilean Patent No. 45,037). To establish the conditions under which the precipitating compounds form, it was necessary to evaluate the amount of PbCh consumed, antimony extraction efficiency, precipitate stability, reaction kinetics, diffraction analysis and X-ray fluorescence, separation of size, plus observation of the precipitates in the electron microscope. Preliminary tests were carried with synthetic copper refinery electrolyte, and then the final testing was done with electrolytes from Chilean refineries. This process provides a real alternative for the treatment of copper refinery electrolytes for the control of Sb and Bi in solution; it is very simple to operate and is low cost compared with competing processes.Introduction.A high quality copper cathode implies a cathode free of impurities. The electrorefining process seeks to eliminate these impurities from the copper anode (99.5% purity) by its dissolution in an acid electrolyte using chemical and electrochemical reactions. As a result of this process, a cathode (99.99% purity) is obtained. If the concentration of impurities in the electrolyte, from the dissolved anodes, begins to increase; particularly if the antimony concentration in the electrolyte increases up 500 ppm, the formation of floating slimes which are a major cause of contamination of the cathode is favoured. The most important impurities from the point of view of their effect on the quality of the cathode copper, are Ag, As, Sb, Bi, Pb, Se and Te. Silver is necessary for the control of Se and Te. To control all of these impurities, it is necessary to establish different methods or parameters of control in copper electrorefining. These parameters are anode composition, additives, purification of the electrolyte, current density, acidity, etc."

Jan 1, 2012

By Murat Budakoglu

Albite (NaA1Si308) is one of the important raw materials for the rapidly developing Turkish ceramic and glass industry. Prior to 1980, development of the ceramic industry in terms of raw material was dependent upon small-scale mining operations; in the last decade, these efforts have increased substantially. The aim of this study is to investigate the geochemical properties and distribution of albite occurrences in the Kocayayla district, which is about 12 km northeast of the town of Milas, about 50 km west of the city of Mugla in southwestern Anatolia. Kocayayla is also well known for its famous ancient city, Labranda. The field area is located in the Menderes Massif, which was formed by major tectonic events during the Late Proterozoic and subsequent periods. The target area was studied to prepare a detailed geological map (scale, 1:10,000), and to determine the formation of albite-mica-schist-quartzite borders in the host rock gneiss. To do this, systematic sampling of albite was done in the two main areas, the Sarikaya and Yumruta? regions. In the study area, albite zones are scattered within an area of about 20 km2, and they extend in a northeast-southwest direction; mica-schists and quartzite veins accompany these units. Mineralogical observations show that quartz is the main mineral associated with albite. In the ceramic industry, the albite + quartz assemblage is well known and is classified as "standard" or "super type," depending upon the content of TiO2 and Fe203. In this study, the Sarikaya albites (profile I) exhibit remarkably lower TiO2 (0.15% on the average) values contrasted to that of Yumruta? (profile 11; 0.24% on the average), whereas Fe203 values vary slightly from 0.076% to 0.085% in both regions.

Jan 1, 1999