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By M. Karmis

mining factors and representative ground movement parameters. Based on this analysis, the previously developed prediction methods were modified and tested for their applicability in the Appalachian coalfield. Finally, in order to facilitate the implementation of the prediction methods, as well as the data processing of the monitoring program, a number of computer software were developed and will be discussed in the paper. Surface deformations above underground mines and their prediction and control have been the topics of an extensive research effort by Virginia Polytechnic Institute and State University over the past few years. During the initial stages of this research, a number of case studies were collected from the literature, the mining industry and various government and state agencies and, based on the analysis of this information, appropriate prediction methods were proposed (Goodman, 1980; Webb, 1982; Hasenfus, 1984; Karmis et al., 1984). Although the prediction methods were based on sound concepts, it became evident that their accuracy and implementation were a reflection of the size and quality of the collected case studies. In this respect, the data bank was rather insufficient and posed certain questions regarding the development of subsidence information due to inappropriate length and spacing of monuments used in subsidence surveys, density and accuracy of such surveys, lack of monitoring horizontal movements, etc. In an effort to alleviate these problems, a comprehensive monitoring program was initiated in the coal mines of southwest Virginia, which included: - Two longwall and five room and pillar mines. - In total, seven longwall and sixteen room and pillar panels. - Monitoring lines in excess of 35,000 feet. - Vertical as well as horizontal measurements. A high accuracy digital computer tacheometer was used in all surveys and the type and spacing of all monuments were in accordance with well accepted guidelines. The data from this monitoring program completed the initially collected data bank and, thus, enabled a much needed statistical analysis between

Jan 1, 1987

During 1995 a catastrophic accident took place at the No 2 Vaal Reefs shaft in South Africa, when a locomotive fell onto a cage, causing the death of 104 people. The subsequent Commission of Enquiry found that the safety detaching hook had opened when hit by parts of the falling locomotive, detaching the cage from the rope and allowing the cage to drop 400 m down the shaft. It was believed that had the hook not detached, the rope would have been sufficiently elastic not to have failed, implying that many fatalities may have been avoided. In addition, the risk of accidental opening of hooks due to impact with smaller falling objects in shafts became a concern. This paper deals with a comprehensive statistical investigation that was performed to quantify this risk, establish acceptable levels of such risks and to derive criteria for the resistance of detachment hooks against accidental opening caused by impacts. The investigation involved a survey, dynamic finite element analyses and Monte Carlo simulations.

Jan 1, 2005

By O. Laitinen, M. Rudolph, J. A. Sirviö, H. Liimatainen, R. Hartmann, University of Oulu

The increasing complexity of the ores composition worldwide calls for suitable collectors with specific properties, such as selectivity, wettability, and in regard to current regulations, environmental sustainability. Therefore, collectors have to satisfy many features to improve the efficiency of flotation processes. Cellulose nanocrystals gain more and more interest due to the versatile synthesis routes which enable the integration of specific functional groups and components with different degrees of hydrophobicity within the molecular structure. Consequently, cellulose nanocrystals can be employed in flotation processes as depressant or collector molecules, respectively. Nonetheless, the usage of cellulose nanocrystals is still limited due to a lack of the characterization of nanocrystal-mineral interactions and the change of the surface wetting properties of minerals after adsorption phenomena between nanocrystals and minerals. In these studies, butyl-amine cellulose nanocrystal (BAC) and quartz are used as model system to investigate physicochemical properties of both, BAC and quartz, and examine the applicability of BAC in flotation processes. Therefore, the surface charge distribution and electrophoretic mobility of BAC and quartz are investigated and compared to understand the effect of electrostatic interactions between BACs, and BAC and quartz. Based on this, the adsorption of BAC on quartz is examined. Finally, microflotation experiments test the efficiency of BAC to be used in flotation processes. The flotation response is correlated to the specific surface charge of BAC revealing the dominant effect of surface charges on effective particle-bubble adhesions.

Jan 1, 2016

By Paul Torrey

IN his recent article, Stanley C. Herold described some of the principles involved in oil-field rejuvenation. The purpose of this paper is to present certain facts, based upon observations of systematic water flooding of oil sands in the Bradford and Allegany fields of northwestern Pennsylvania and southwestern New York, which, it is believed, will partially substantiate Mr. Herold's opinions. The writer gratefully acknowledges his obligation to the Forest Oil Corpn., the Kendall Refining Co., the Petroleum Reclamation Co., W. J. Healey, of Bradford, Pa., and the Producers Oil Corpn., of Olean, N. Y., for information included in this article; and he is especially indebted to Jerry B. Newby, of the Petroleum Reclamation Co., for helpful suggestions and criticism in the preparation of the paper. It is obvious that, in the calculation of mathematical formulas for the prediction of oil recovery, uniform conditions must be assumed; otherwise, the applicability of the results of such work will be, by necessity, restricted to the area or individual property for which they were designed. Geologic and physical conditions are so variable throughout the fields where water flooding is practiced that it is difficult to devise methods that can be universally applicable. However, it is believed that there are certain fundamental principles which, when applied with specific modifications designed to meet the conditions existing in local areas or individual properties, may yield considerably greater recoveries of oil.

Jan 1, 1927

By J. Murray Riddell, Grover J. Holt, Arthur E. Anderson

Out of the depths of each business cycle we emerge with a stimulus for greater efficiency and a realization of progress in industrial technique. The recent years have not been an exception to this rule, and in retrospect we sense that significant advances have been made in mining practices on the Mesabi Range, with emphasis on speed of production and economy of operation. A survey of such changes does not reveal anything that is fundamentally or basically new, but it is apparent that ideas and machines that have found wide application in industry elsewhere, with necessary modifications, are being put to productive use in mining iron ore. Innovations in transporting and conveying ore from the open pits stand out with greatest prominence, so that, in the main, it will be with these features that this paper will treat, in the review of progress made to this date. The late years have witnessed the development of small deposits for open-pit operation, the cleaning up of pits nearing exhaustion, and in two large operations the approach to the limit for haulage by steam locomotives, owing to grades, making it necessary to recover the ore in slopes, track benches and below the power-shovel limit by a milling and scram operation. For several years small standard-type dump trucks have been used in clean-up or scram operations within the pits, but during the season of 1936 the first effort was made to use heavy truck haulage in the transportation of stripping and iron ore. The new units in use today vary from 15 to 20 tons in capacity, and are equipped with powerful gasoline or Diesel engines and supplemented by trailers or wagons on rubber or crawler treads. The Diesel engine finds favor with most operators because of fuel economy. These units develop upward of 125 hp. in the 15-ton trucks. The speed of these trucks varies from 2 miles per hour in Pow gear to 35 in high gear. The transmission affords 12 speeds forward and 3 speeds in reverse.

Jan 1, 1940

By J. Murray Riddell, Arthur E. Anderson, Grover J. Holt

Out of the depths of each business cycle we emerge with a stimulus for greater efficiency and a realization of progress in industrial technique. The recent years have not been an exception to this rule, and in retrospect we sense that significant advances have been made in mining practices on the Mesabi Range, with emphasis on speed of production and economy of operation. A survey of such changes does not reveal anything that is fundamentally or basically new, but it is apparent that ideas and machines that have found wide application in industry elsewhere, with necessary modifications, are being put to productive use in mining iron ore. Innovations in transporting and conveying ore from the open pits stand out with greatest prominence, so that, in the main, it will be with these features that this paper will treat, in the review of progress made to this date. The late years have witnessed the development of small deposits for open-pit operation, the cleaning up of pits nearing exhaustion, and in two large operations the approach to the limit for haulage by steam locomotives, owing to grades, making it necessary to recover the ore in slopes, track benches and below the power-shovel limit by a milling and scram operation. For several years small standard-type dump trucks have been used in clean-up or scram operations within the pits, but during the season of 1936 the first effort was made to use heavy truck haulage in the transportation of stripping and iron ore. The new units in use today vary from 15 to 20 tons in capacity, and are equipped with powerful gasoline or Diesel engines and supplemented by trailers or wagons on rubber or crawler treads. The Diesel engine finds favor with most operators because of fuel economy. These units develop upward of 125 hp. in the 15-ton trucks. The speed of these trucks varies from 2 miles per hour in Pow gear to 35 in high gear. The transmission affords 12 speeds forward and 3 speeds in reverse.

Jan 1, 1940

By Armin C. Supp

Since 1975, about a dozen high capacity flotation plants have been installed in the Ruhr district. Depending on the size of the preparation plants, the design capacity of the flotation section is between 100 - 150 t/h. The flotation units generally comprise rougher and cleaner stages in which 5 to 6 or 4 to 5 agitators respectively are arranged in line. The unit volume allocated to each agitator is up to 16 m3. The type of flotation machines, the design of these plants and their instrumen¬tation and control equipment are described in detail. The run of mine coal in the Ruhr district is characterized by a wide variety of the volatile matter. Generally, a distinction must be made between coals with more than 30 - 35% V.M., which are preferably used in power station, and coal with lower V.M. content, which are preferably used as coke-oven feed. The difference between these coals in respect to grain-size distribution, ash cotent and flotation properties will also be described in detail.

Jan 1, 1985

By J. Murray Riddell, Arthur E. Anderson, Grover J. Holt

OUT of the depths of each business cycle we emerge with a stimulus for greater efficiency and a realization of progress in industrial technique. The recent years have not been an exception to this rule, and in retrospect we sense that significant advances have been made in mining practices on the Mesabi Range, with emphasis on speed of production and economy of operation. A survey of such changes does not reveal anything that is fundamentally or basically new, but it is apparent that ideas and machines that have found wide application in industry elsewhere, with necessary modifications, are being put to productive use in mining iron ore. Innovations in transporting and conveying ore from the open pits stand out with greatest prominence, so that, in the main, it will be with these features that this paper will treat, in the review of progress made to this date. The late years have witnessed the development of small deposits for open-pit operation, the cleaning up of pits nearing exhaustion, and in two large operations the approach to the limit for haulage by steam locomotives, owing to grades, making it necessary to recover the ore in slopes, track benches and below the power-shovel limit by a milling and scram operation. For several years small standard-type dump trucks have been used in clean-up or scram operations within the pits, but during the seasor1 of 1936 the first effort was made to use heavy truck haulage in the transportation of stripping and iron ore. The new units in use today vary from 15 to 20 tons in capacity, and are equipped with powerful gasoline or Diesel engines and supplemented by trailers or wagons on rubber or crawler treads. The Diesel engine finds favor with most operators because of fuel economy. These units develop upward of 125 hp. in the 15-ton trucks. The speed of these trucks varies from 2 miles per hour in low gear to 35 in high gear. The transmission affords 12 speeds forward and 3 speeds in reverse.

Jan 1, 1938

By P. T. Perdue, F. F. Haywood

INTRODUCTION Monitoring devices used for detecting and measuring airborne radon in mines are limited due to the rugged environment in which they must operate. Personnel monitors now available are either passive or require filters and an air pump. Area air monitors usually have bulky batteries or require electric power service to the instrument. Thus, there are few instruments presently in use in mines capable of discriminating between the various radon isotopes and their daughters. Occasionally it is desirable to determine which radon daughters are the principal dose contributors in mine air. In some areas, such as the Elliot Lake mine in Canada, there exist sizable quantities of 220Rn in the mine air due to 232Th in the ore (Cote and Townsend, 1981). Since there has been recent interest in radon daughters in homes and factories, as well as caves and mines, methods and instrumentation are being developed to address these cases. Some of these methods can be employed in uranium mines. Although there have been very few determinations of the three radon isotopes (222Rn, 220Rn, and 219Rn) and their daughters made in uranium mines, these isotopes have been measured in process buildings and in private homes under circumstances that suggest these isotopes could also be present in uranium mine air (Perdue, Leggett, and Haywood, 1980; Yarborough, 1980) METHODS Cryogenic air sampling was developed about 15 years ago (Rasmussen, 1972) to concentrate various airborne chemicals for later fractional distillation and measurement of various organics using gas chromatography. A version of this technique has been developed to measure tritium, krypton, and other radioactive gases in nuclear power station buildings (Anon, 1980). In this method, fractional distillation is used in conjunction with various detectors to identify the radionuclides present. The cryogenic method to be discussed here was developed at Oak Ridge National Laboratory (ORNL). It uses the liquid air accumulated in a sampling device for a direct analysis of all gamma-ray emitters present. The air sampler (Fig. 1) could be employed in a mine to liquefy air, using the difference between the point of liquefaction of air (~80 deg. Kelvin) and the boiling point of liquid nitrogen (77 deg. Kelvin) to liquefy an air sample. By using a proper orifice at the entry to the sampling vessel, air of any dust concentration and relative humidity [ ] may be sampled. The energy for sampling is provided by the slow evaporation of the liquid nitrogen; no other power source is required. This type of sampler could be used to augment the usual filter and pump, or passive system presently employed to estimate personnel dose from radon daughters. It would also allow measurement of any combination of daughters from the three radon isotopes. Upon completion of sampling, the sampler is closed and removed from the mine. This sampler, with its liquid air contents maintained by the slow evaporation of liquid nitrogen, is taken to the place of measurement. There, the sampler is opened, the accumulation of water and ice in the neck is chiseled down into the liquid air, and the sample is transferred quickly to a precooled counting dewar (Fig. 2). This counting dewar is then placed upon a gamma radiation detector; we recommend a high purity germanium detector. A determination of all the radon daughters can be made in 1 to 4 hours after the sample is taken.

Jan 1, 1981

By Otto L. Schumacher

The Overthrust Belt in portions of Montana, Idaho, Utah, and Wyoming, an area that has contributed generously to the Nation's mineral supply, is one of the few remaining oil and gas frontiers on the North American continent. Determination of the oil and gas potential and development of mineral resources of the area have been affected by a variety of land withdrawals and other restrictions, The purpose of this study is to determine the extent of these withdrawals and restrictions and to discuss the mineral resource potential within the study area. Statistics in this report refer to land status on January 1, 1979. At that time, of the 27.3 million acres of Federal mineral lands within the study area, applications tor Federal oil and gas leases for more than 4,4 million acres (about 16 percent) were pending; the average length of time was 2 years. Federal oil and gas leases covering 8.8 million acres were also on record. Although drilling has occurred on some of these leases, others are subject to restrictions that discourage or prevent development. Some in fact contain stipulations disallowing any development.

Jan 1, 1981

By J. Mattern

Performance monitoring, operational practices and ongoing collection of geologic data in open pit slopes all provide valuable information for quantifying potential steepening of subsequent slopes. Mining at the Goldstrike open pit has been ongoing since the early 1980’s, with its share of slope instabilities. In areas where slopes have remained stable, consideration has been made for potential slope steepening of final walls. With the proper available equipment, steepening of bench face angles via pre-split blasting is not an uncommon method for steepening of inter-ramp slope angles. As an alternative at Goldstrike, the commonly used Modified Ritchie Criteria for empirical catch bench width has been adjusted resulting in quantified, rock specific formulas for bench width and rock fall berm placement. The result is an inter-ramp slope angle increase of 2 degrees on a 300m high slope, without the necessary purchases and procedural changes that would be required for pre-split drilling and blasting. The result has shown significant net benefits through reduction in mined waste tons and an increase in gold reserves. Location The Goldstrike open pit is located on the Carlin Trend gold belt in northeastern Nevada USA (Figure 1). The mine has produced over 43 million ounces (1.2M kg) of gold during the past 30 years. Engineering Geology Stratigraphy Figure 2 is a stratigraphic section of the rocks in the Goldstrike open pit. Quaternary alluvium and Miocene materials typically are poorly indurated stiff soils and are not present in all locations. Bedrock units consist of siltstones, mudstones, sandstones and cherts. From top down the major units exposed in the open pit are the Vinini Formation, the Rodeo Creek Unit, and the Popovich Formation. In general, rock mass strength increases with depth.

Jan 1, 2019

In a ætypicalÆ gold deposit each tonne of ore will contain tens of millions of very fine gold particles, whereas; at Bendigo the majority of gold in each tonne of ore is present in just five to 15 very coarse gold particles, a distribution more akin to diamond deposits. At Bendigo the minimum sample size required for good assay repeatability is estimated at 4.5 t for each assay. Drill core samples are several orders of magnitude too small to generate representative assays.The drilling data are characterised by a nugget effect approaching 90 per cent, a very skewed distribution and, on average, under-report in situ grade by 50 per cent to 75 per cent. Since 2002 Bendigo Mining NL has completed 47 000 m of diamond drilling, 1200 m of on reef development, collected and processed 100 bulk samples (150 t each), 800 mini bulk samples (50 kg each) and processed in excess of 25 000 t of ore through a pilot plant. The results of this work have provided the information required to develop and verify a robust grade estimation procedure. No standard geostatistical manipulation of the drilling assay data can generate an accurate grade estimate as the samples and associated assays are not representative of the ore being sampled. The recognition of this fact was critical as a radical transformation of the raw drill assay data was required to develop a workable methodology for grade estimation in such a high nugget environment. The aim of the transformation was to reduce the nugget effect and high variance and so approach a lognormal assay distribution. Ideally the average drill grade would approximate actual in situ grade and the assay distribution would reflect actual grade distribution within the reefs. Following the data transformation simple block modeling within the defined resources allows grade estimates to be made that can be used in the estimation of Indicated Resources and hence Probable Reserves. The grade estimates have been checked by extensive bulk sampling and processing of 25 000 t of ore (three per cent of total resource) through a pilot plant with planned full scale mining to provide the ultimate verification.

Jan 1, 2004

By R. R. Brandenthaler

The development of the Seminole area into one of the major oil-producing sections of the country has been accompanied by many innovations and departures from former methods of development. On July 1, 1929, two years and nine months from the date of discovery, 20,490 acres were considered proved, and additional acreage is constantly being developed. Because of its peculiar conditions, extent, and rapid rate of development, the Seminole area provided numerous problems, the solution of which necessitated research in connection with practical field operation; as a result, there was a radical departure from methods usually employed in the development of a new field in the Mid-Continent area.

Jan 1, 1930

The reduced need for traditionally trained and educated personnel in the mining industry is systemic to the changing mining industry. Our universities and other training institutions are doing just fine meeting the traditional skill needs required by the industry. But are the skill needs going to be the same in the near future? The answer may be NO!! Mining is changing: increased liabilities and costs of environmental and safety issues; lower grades of minerals in traditional mining activities; the advent of new bio-chemical processes and robotic equipment as more productive and economic alternatives; and, larger more sophisticated and automatic equipment. Engineering is more specific, accurate, precise and expensive. Measurement is more thorough and timely of progress, production, costs, and productivity. And we will be engaging in more undersea mining, possibly space bases processing, less human interaction, and more remote control of events than was ever thought possible in the past. This paper presents several of the systemic changes that are presently and will continue to change the face of mining. It will identify area where education and management will have to address these changes.

Jan 1, 2011

By Daniel D. Pollock

The il'lott and Jones theory of thermoelectricity predicts that the absolute thermoelectric power of alloys of transition and noble metals should be a maximum when the concentration of the noble metal is approximately 55 to 60 at. pct. An examination of the emf of a series of relatively pure alloys of copper and nickel shows that the predicted maximum occurs at about 57 at. pct Cu. This excellent agreement with the theory is considered to substantiate the Mott and Jones theory of thermoelectricity for binary alloys of transition elements. This theory is extended to show that the emf behavior of dilute, ternary copper-nickel base alloys, which contain approsimately 60 pct Cu and 40 pct Ni, may be described in terms of a scattering mechanism. The scattering effect of a third element is demonstrated to be a function of its valence and its period in the periodic table. Small amounts of solute elements have additive scattering effects upon the emf of the Cu-Ni base. The Mott and Jones equation is modified to include this scattering parameter. This adaptation accurately describes the thermoelectric behavior of ternary and quaternary CLL-Ni base alloys. An empirical form of the modified Mott and Jones equation is derived which permits the calculation of thermoelectric power with an average error of less than 0.4 pct at 500 "C. CONSTANTAN has long been used as a thermocouple element. Its approximate composition varies from 50 pct Cu, 50 pct Ni to 65 pct Cu, 35 pct Ni. Small amounts of manganese, iron, and other elements have been used to modify the composition in order that the resultant emf vs platinum conforms to nationally accepted table. Adjustments of this type are made on a purely empirical basis. Constantan was originally made in Germany and was imported into this country for thermoelectric and electrical resistance purposes. During World War I, the supply of this material became seriously depleted. The work of Bash4 was done in this period in order to develop a satisfactory substitute for the imported material. Bash's empirical work on Cu-Ni alloys is still the basis for all commercial constantans made in this country. No reexamination of the electrical properties of this system has been made, despite the fact that it is now well known that Bash's alloys contained impurities which strongly affected their thermoelectric behavior.

Jan 1, 1962

By L. F. Stutzman, George Thodos

The friction factor plot presented by Cornell and Katz4 and developed for the flow of fluids through consolidated formations has been directly adapted for handling fluid flow problems involvitrg both linear and radial flow. In this adaptation the friction factor plot is used directly for the solution of problems and thereby eliminates the use of conventional equations which are specific to laminar (Darcy) or turbutent flow. This upproach overcomes the disadvantages inherent in the use of these conventional equations. It eliminates the necessity of checking the type of flow occurring in order to identify the specific equation which must be used. In radial flow problems, because of the increasing mass velocity of the fluids as they approach the wellbore. the type of flow may no longer remain laminar. Consequently, it is necessary to use more than one equation in a problem and to identify the range over which each equation should be applied. Finally, in practice it has been found that much of the flow of gases through consolidated media occurs in a range that is neither laminar or turbulent. For this transitional region, no convenient equations are available. The method and presented friction factor plot are appficahle to both liquids and gases. INTRODUCTION The flow of fluids through unconsolidated media in packed beds has been treated extensively by a number of investigatorsl,2,3,5,7,8 Most of these studies present friction factors as a function of modified Reynolds number similar to those developed for conventional fluid flow through pipes. These friction factor plots are presented for linear flow; however, Elenbaas and Katz have extended these concepts to apply to radial flow. All of these studies on unconsolidated materials require a knowledge of packing properties such as sphericity. porosity, and particle diameter. Sphericity and particle diameter cannot be defined at the present time for consolidated formations such as those commonly found in gas or oil reservoirs. As a result many investigators have not utilized friction factors and Reynolds number in the study of fluid flow through consolidated media. However, Cornell and Katz4 present a plot (Fig. 1) for the flow of fluids through consolidated porous media, in which the friction factor defined as: The turbulence coefficient, P, is related to the formation permeability, K, as presented in Fig. 2. Three different types of flow may exist in the flow ot

Jan 1, 1957

By D. J. Carney, J. Chipman, N. J. Grant

G. Derge—With the development of this last weapon, there is not much of a chance for hydrogen. It is certainly a very interesting paper, and it gives us more confidence in sampling liquid steel for hydrogen than we have ever had before. This satisfactory work gives considerable confidence to all of the chilled methods of sampling which should be more or less successful depending upon the degree of chilling obtained. J. T. MacKenzie—How do you handle a nonmagnetic specimen in that device? D. J. Carney (authors' reply)—I left that out in going over the analytical procedure. For the 18-8 steel, what was done was to get some iron wire which was degassed. One turn of wire was made around the sample; it was inserted into the analytical apparatus, and that was enough to allow the magnet to pull the sample and drop it in the furnace. Other methods could be devised for this apparatus to do the same thing. This was just a quick method. C. E. Sims—This method of sampling and analysis is very ingenious, and the results obtained attest to a satisfactory degree of accuracy. It was noted in the paper that the samples are satisfactory only when there is a complete absence of pipe. This should be empha- sized, particularly in view of the fact that they are cut off under water. Some reservations are held in regard to the adequacy of the method of sample storage prior to analysis. Cooling on dry ice undoubtedly slows down the rate of diffusion to a marked degree, and it obviously suffices when the analysis is made within a few hours. All of the samples, except some of high-nickel steels, were analyzed within 12 hr. It is still unknown how long this method would be safe. In the work at Battelle Institute, it was impracticable always to start analysis within 12 hr for various reasons. Some samples did not reach the laboratory for several days, and some were held as long as a month before analysis. During this period, they were held over mercury, and the gas evolved at room temperature was collected and analyzed. It should be mentioned that both the mercury and the container must be kept very clean.

Jan 1, 1951

By O. N. Carlson, A. L. Eustice

The tensile properties of iodide vanadium were determined as a function of hydrogen concentration. It was shown that the presence of 10 ppm H is sufficient to cause embrittlement of vanadzum over a limited temperature range. The temperature of the observed ductility mininlum is approximately -l00°C, this being a function of strain rate and hydrogen concentration. The yield stress of hydrogenated vanadium is raised sharply in the brittle temperature range. THE present investigation was initiated to determine the effect of hydrogen on the tensile properties of high-purity vanadium as a function of temperature and the role of hydrogen in the brittle-ductile transition. Loomis and Carlson&apos; reported a change from ductile to brittle behavior in iodide vanadium at -110°C with a return of ductility at temperatures below -140°C. Vanadium wire containing 270 pprn of hydrogen was brittle at room temperature while wire containing 100 ppm was ductile under the same conditions. Roberts and Rogers&apos; reported a ductile-brittle-ductile fracture sequence in vanadium containing 400 to 600 ppm of hydrogen. Their data show that hydrogenated vanadium is ductile at 150"C, brittle at room temperature and ductile again at -196°C. Magnusson and Baldwin found a minimum in ductility in vanadium containing 80 ppm hydrogen from tensile tests performed at several strain rates. Information available on the vanadium-hydrogen equilibrium system4 is somewhat incomplete. The absorption of hydrogen is exothermic in accordance with the decline in solubility with rising temperature. The limit of solid solubility at temperatures below 400°C has not been determined due to the difficulties in obtaining equilibrium at these temperatures. Data on the hydrides of vanadium are rather limited. Roberts6 studied the structure of VD,., by neutron diffraction, and observed the ordering of the deuterium atoms below -65°C into a primitive cubic cell with a lattice constant about twice that of the disordered bcc vanadium solid solution. EXPERIMENTAL PROCEDURE Vanadium of 99.9 pct purity was prepared by the iodide refining process6 for use in this investigation. This vanadium contained the following analyzed impurities; <20 pprn calcium, 150 ppm carbon, 200 ppm chromium, 30 ppm copper, 10 ppm hydrogen, 200 ppm iron, <20 ppm magnesium, <20 ppm nickel, <5 ppm nitrogen, 150 ppm oxygen, <50 ppm silicon, and <20 ppm titanium. specimen Preparation—Tensile specimens were machined from swaged rods of iodide vanadium. The

Jan 1, 1962

By R. H. Murray

The Kamyr countercurrent tower leach process consists of a true countercurrent leach ?with a flocculated ore and fibre mixture entering the top of the tower and a cyanide solution or alternative lixiviant as well as a barren wash solution entering the bottom of the tower. It offers the possibility of including the entire leaching, solid-liquid separation and clarification processes into one unit or tower as opposed to the multiple leach tanks, filtration and clarification sections required in a conventional leach and precipitation plant. The tower process has been demonstrated in the laboratory and found to be effective for leaching gold, silver and other amenable ores. Based on laboratory results, Gencor and Kamyr have jointly constructed a 200 ton per day pilot plant in order to prove the process on a larger semi-production plant scale.

Jan 1, 1989

By J. W. Perez

Raw coal will often break intragranularly in either a completely random way or in a differential mode where one species will have a different rate of breakage than another. Locked coal-ash and coal-pyrite particles can also break by the preferential detachment of one species from another along zones of inherent weakness in locked particle assemblages. The mode. cf breakage is largely a function of the nature of the feed, but it is also influenced by the comminution device and the operating variables. Evidence of breakage of particles in the various modes is seen in the crushing of raw coal and middlings particles with a rotary beaker, jaw crusher, rolls, hammer mill and rod mill. Evidence from the literature indicates the detachment mode is often important for coal, ores and metallurgical products. Further confirmation comes from the crushing of a specially prepared &apos;ore&apos; of sized magnetite in plaster of Paris.

Jan 1, 1988