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By Harry Seltz

INTERMETALLIC compounds are formed in many binary metal systems. Some compounds are stable to their melting points, and others decompose at lower transition temperatures. Even those of the first class are dis-sociated in the liquid state, as indicated by the continuous for in of their solubility curves at their melting points1. While the lattice structures of some of these compounds have been determined, their thermodynamic properties have not been investigated. In this paper is described the determination of the free energy and heat of formation of the compound CdSb, which is of the first class mentioned above, melting congruently at 455° C. This compound shows a rhombic structure, and the lengths of the edges of the elementary cell containing four molecules are: a =6.52, b = 8.60, c = 4.16 A.2 There are three possible methods of determining the free energy of formation of a compound of this type. The first method, applying the third law of thermodynamics, requires the measurement of its heat capacity preferably to liquid hydrogen temperatures, and a calorimetric determination of its heat of formation. The second method involves the study of the equilibrium of the compound in some gas reaction, such as: CdSb + CO2 = CdO + CO + Sb From the known free energies of formation of CdO, CO2 and CO the free energy of formation of CdSb could be calculated. The third method measures the electromotive force of a galvanic cell in which the cell

Jan 1, 1935

By S. M. Shelton, W. A. Calhoun

"INTRODUCTION Discovery and development of a southwestern Arkansas quicksilver district are recent history. In July 1930 4/, a specimen was discovered near the Little Missouri River in sec. 1, T. 7S. R. 26 W., which was identified as cinnabar. In the summer of 1931, Leo Yount began prospecting for cinnabar near the Little Missouri River. In the fall of that year he operated a small three-tube retort near the present Parker Hill mines and produced several flasks of quicksilver. Yount optioned a considerable block of ground containing the best showings in the Little Missouri River area, and on February 19, 1932, he and W. C. McBride, Inc., of St. Louis, Mo., formed the Southwestern Quicksilver Co., which was the largest producer in the district until operations ceased in September 1934.The Southwestern Quicksilver Co. installed a rotary furnace on Parker Hill in April 1932, which treated ore from the three principal mines Gap Ridge, Parker Hill, and Parnell Hill. In 1934 production was entirely from the Gap Ridge and Parker Hill mines. Nothing was done at Parnell Hill except a little small-scale work on a share basis.Mercury Producers, Inc., later took an option on the holdings of the Southwestern Quicksilver Co. and in June 1935 began operations. The company produced considerable quicksilver before the lease and option were surrendered in the summer of 1936. Most of the work of Mercury Producers, Inc., was on Parnell Hill, but some work was done on Parker Hill and at the Bell prospect on ground not controlled by the Southwestern Quicksilver Co."

Mar 1, 1942

By C. E. Reistle

The generation of steam for drilling operations has visually been accomplished in the past by the use of portable locomotive-type boilers without the aid of auxiliary equipment or advanced for economizing fuel or water consumption. This has been due primarily to the fact that the steam-generating plant of a drilling well must necessarily be of temporary and portable design, and the amount of steam generated has not been considered sufficient to justify the additional expense necessary to obtain more economical operation. However, with the constantly increasing depth to which oil wells are being drilled and the use of larger and heavier equipment, the steam requirements have reached a point where equipment and methods that were previously considered as applicable only to permanent plant installation can be and are being used to a decided advantage by the more progressive operators. As an example of the present-day requirements and the rapidly increasing steam consumption in rotary drilling, a comparison between the requirements during the intensive drilling period in the Seminole end Oklahoma City fields of Oklahoma is of interest. In the Seminole field. There the approximate depth of rotary drilling was 3,500 feet, the general practice was to use three 85 to 90 or 100 horsepower A. P. I. code boilers operating at a working pressure of 175 to 200 pounds per square inch. The fuel end water consumption was approximately 450 to 500 thousand cubic feet of gas and 700 to 750 barrels of water per day. In the Oklahoma City field, where the average drilling depth is approximately 6,500 feet, the general practice is to use either four 100 or 116 horsepower or three 123 horsepower A.P.I. code boilers, operating at a pressure of 250 pounds per square inch. The fuel and water consumption varies from 550 to 750 thousand cubic feet of gas and from 1,000 to 1,500 barrels of water per day.

Jan 1, 1930

By G. Fuentes, J. Viñals

"The nature and basic kinetics of the hydrothermal reactions of bornite, covellite pyrite and enargite with copper sulfate solutions were investigated, as a previous study on the behavior of the bulk Chilean copper concentrates. The reaction of bornite produced digenite at 160 °C and djurleite above this temperature. Covellite was transformed to digenite at < 200 °C and to chalcocite (Q and M) at > 200 °C. The pyrite reaction was significant at > 200 °C and extensive at 240 °C, enargite reacts only above 240°C and produces digenite. The hydrothermal treatment of Chilean Codelco-type copper concentrates with hydrothermal reactions was similar to those obtained from pure mineral samples.INTRODUCTIONStudies on the hydrothermal enrichment of chalcopyrite concentrates were begun by MacGauley and Roberts (1951), Roberts et al. (1953) and MacGauley and Schaufelberger (1956). In the 1970's these processes were reexamined by McKay et al. (1972), and Johnson and Coltrinari (1976), but it not was until the 1990s when the kinetics, mechanisms and full engineering aspects were studied by Barlett, (1992), Jang and Wadsworth, (1994) and Peterson and Wadsworth (1994). The main objectives were to solve some important problems in the copper pyrometallurgy: The increase of the smelting capacity, the reduction of the iron slag – and associated copper losses – as well as the reduction of sulfur emissions. The present rise in copper demand and price implies the production and subsequent treatment of very impure concentrates. Thus, a significant increase of environmental problems can be expected in the copper pyrometallurgy. The previous purification of concentrates can reduce the processing of wastes containing hazardous heavy metals in the copper refineries and the hydrothermal treatment can be an alternative which combines both enrichment and purification. On the other hand, Chuquicamatatype concentrates (Viñals et al., 2004a) contains digenite (Cu1.8S), pyrite (FeS2), chalcopyrite(CuFeS2), b ornite (Cu5FeS4), covellite (CuS) and sphalerite (ZnS) as the main mineral components, with minor amounts of enargite (Cu3AsS4), galena (PbS) and molybdenite (MoS2)."

Jan 1, 2012

By Laurentiu Nastac

"This paper describes the development and validation of a comprehensive multiscale modeling approach capable of predicting at the mesoscopic scale level the ingot solidification structure and solidification-related defects commonly occurring during the vacuum arc remelting (VAR) process. The approach consists of a coupling between a fully transient macroscopic code and a mesoscopic solidification structure code. The predictions from the multiscale model, including grain morphology and size, primary and secondary dendrite arm spacings, Laves and NbC phases, tendency for freckling and columnar-to-equiaxed transition, were validated against experimental measurements for a 20-inch diameter VAR alloy 718 ingots. The validated model was then used to investigate the effects of melting rate and ingot diameter on the solidification structure of VAR processed 718 ingots.IntroductionThe objective of this work was to develop a fully transient multiscale modeling approach to get an insight into the effect of processing parameters on the cast micro- and macro-structure during VAR processing. The developed model assists in achieving better control of the ingot solidification structure and to determine trends in the macrosegregation in these ingots. Another objective of this work was to analyze the transient effects of production rate and ingot size on the resultant ingot microstructures. This objective was met by first understanding the effects of the full range of processing parameters typically used in the VAR process. Processing parameters such as power input and heat extraction rate significantly influence the ingot liquid pool size and shape as well as the ingot structure, which in turn will greatly impacts the final ingot quality."

Jan 1, 2012

By William Metcalf

One of the first questions that naturally occurs to one who handles steel is, " Why does steel harden?" To answer this question the chemist and physicist have devoted much thought and experiment, and while they have enriched our store of knowledge of the nature and composition of steel, it cannot be said that they have yet solved the problem involved in its hardening. In this communication I desire to direct attention to a line of investigation yet new, in the hope that it may receive the attention. of those who have the time and ability to pursue it. I refer to magnetism. There are so many parallels between the action of magnetism on iron and steel and their behavior under different processes of manipulation that it would seem. as if there must be some connection between tile forces at work in the different cases, if, indeed, there be not an identify of force in all of these cases. Magnetism, as me know it, may be merely the visible manifestation of forces, which may serve as a guide to lead us to an exact knowledge of the structure, tile strains, and the resistances with which me have to deal in iron and steel. If a magnet be brought close to a pile of iron filings, the little pieces of iron will fly to the maguet and attach themselves to it, with their longer axes lying in the direction of the force. If molten cast iron be poured into an iron mould,—a chill,—the iron upon crystallizing will form needlelike crystals, with their long axes normal to the surfaces of the mould. • If the iron is at the proper temperatare and the quantity small, compared to the mass of the mould, the whole of it, will be chilled, or set, in &apos;the hard needlelike crystals

Jan 1, 1881

By Persifor Frazer

It was my intention to have directed the attention of the members of the Institute to a complete series of rocks representing the older and middle formations represented in Pennsylvania, but time has been insufficient for the purpose, and 1 have been unable, in the first attempts to reduce the sections of those rocks, which I have brought with me to this meeting, to the requisite thinness necessary for exhibiting the peculiarities of their constituent minerals. The rocks represented here belong to the various horizons already mentioned, and include gneiss, ferruginous gneiss, chlorite slate, quartzites, and hydro-mica slates, limestones, dolomites, ferruginous conglomerates, quartz conglomerates, " Potomac marble" (nether member of the Mesozoic series), dolerites, and a syenite. The order in which these are named is, roughly, the order .of geographical position in a section line from southeast to northwest, commencing at the intersection of the Northern Central Railroad with the Maryland line, and ending a few miles from the town of York, and a short distance within the marginal outcrop of Mesozoic red sandstone. In such a geographical section all the rocks above mentioned would be encountered in the given order except syenite, about which a few words are to be said in a moment. (But this is far from representing the rocks in their geological sequence.) There is nothing of unusual interest to present to your notice in these slates and quarteites. The limestones were carefully searched tinder 450 diameters microscopic power, but they show no signs of organic remaius. One section of a fine-grained Triassic sandstone contains a very beau- . tifully banded plate of quartz. But the objects of greatest interest at present are the specimens of trap. The more fine-grained and compact traps were collected from

By Willard L. Cumings, Benjamin L. Miller

The Camaguey brown iron-ore deposit covers the top of Sari Felipe hill, the nearest point of which lies 14 miles NW. of the city of Camaguey. While there are several low flat-topped hills in the vicinity covered with a more or less continuous mantle of brown iron-ore, the deposit of San Felipe hill is the only one of any size and importance, and the name " San Belipe district" is proposed for the region. The deposit extends in a NW-SE. direction for a distance of about 10 miles, with an average width of 5 miles. The location is shown in Fig. 1, a sketch-map of the eastern part of Cuba. Fig. 2 is a map of the San Felipe district. 2. Description. The district is mentioned by Spencer,&apos; who says: " The Cubitas iron-ore fields are situated from 12 to 15 miles north of Camagueg City, in the province of Camagueg.....Within an area measuring roughly 10 miles east and west and 4 miles north and south, there are several flat-topped mesas rising 300 to 400 ft. above the level of an almost featureless plain which extends for many miles in all directions except toward the north." With the exception of the discrepancy in his statements .as to the distance from Camaguey and the area of the hill, which is over 50 sq. miles, his description is a very good one. Kemp2 has the following to say of ores in Camaguey Province:

Jan 1, 1912

By G. S. Farnham, D. A. Scott

Partition of certain elements, particularly nickel, was determined for slowly cooled steels, the greater number containing from 0.30 to 0.35 pct C. Approximately 3 pct of the nickel, 18 pct of the manganese, 33 pct of the molybdenum, and 35 pct of the chromium occur in the carbide phase. Partition of one element is not much affected by the presence of another. THE object of this investigation was: 1—to determine the partition of nickel between cemen-tite and ferrite in a medium and high carbon series of annealed steels; 2—to evaluate the effect of chromium and/or molybdenum or both on the partition of nickel in medium carbon annealed steels; 3— to determine the partition of chromium between ferrite and carbide in a series of medium carbon annealed steels; and 4—to study the chemistry of the carbides formed in an AISI 2330 steel during both isothermal transformation, and quench and draw experiments at 1150°F (620°C). The partition of alloying elements between ce-mentite and ferrite in annealed steels has been the subject of many investigations, a summary of which has been given by Austin1. However, there is no satisfactory data available concerning the partition of nickel. It has generally been assumed that virtu- ally all of the nickel concentrates in the ferrite phase in annealed steels. Two investigators"." have reported the finding of nickel in extracted carbide residues. Recently, it has been shown4 that nickel substitutes up to 40 pct for iron in the lattice of cementite produced by the low temperature carburization of iron-nickel powders. In addition to the lack of data on nickel partition, the literature also fails to make reference to the effect of other elements on the nickel content of the carbide in nickel-bearing steels. The partition of molybdenum between ferrite and carbide has been reported"-&apos; for hypoeutectoid steels, isothermally transformed at 1300°F (705°C) and

Jan 1, 1954

W. L. Saunders, New York, N. Y. (communication to the Secretary*):—The Laramie tunnel, though a small one, compares very favorably in the speed of driving with the great Alpine tunnels which have the record so far. I think it safe to say that, taking all things into consideration, the record made at Laramie is the best American record, though it still falls short of the long-tunnel records abroad. In discussing tunnel-records it must always be borne in mind that there are conditions peculiar to each individual tunnel job, so that no comparisons are complete, fair and conclusive. At Laramie there is one point which stands out prominently, and which distinguishes this from any of the recently-built Alpine tunnels, and that is that here we have great progress in an American driven tunnel without the use of a carriage for mounting the drills. At the Arlberg and Loetschberg tunnels, the carriage was an essential condition for progress. All the heading-drills were mounted upon a bar which rested upon a small carriage. This carriage was withdrawn after the drilling and run into the heading after the blast without much disturbance of the drills, and with very little adjustment except that required in jacking the horizontal bar across the tunnel. The carriage was so small in its track-area that it required little mucking to run it in to the face; and as the rock-drills used were heavy machines 38 in. in diameter, progress in setting up and drilling was very much accelerated by the use of the carriage. At the Laramie tunnel hammer-drills were used instead of piston-drills, and here we have an important distinction which

Jan 1, 1913

By Alan R. Buehler

A mineral survey of the 20,792-acre Sand Butte WSA (Wilderness study Area), ID-57-8, was conducted by U.S. Bureau of Mines personnel in 1985, at the request of the Bureau of Land Management. The WSA is in Lincoln County, south-central Idaho, about 15 miles south-southeast of Carey. There are no mines, prospects, or claims within the WSA. Basaltic lava is the only rock type exposed within the WSA. The only mineral resource is a few tons of a platy variety of lava (slab pahoehoe) which is suitable for use as decorative stone. Similar slab pahoehoe, produced from other lava fields in southern Idaho, retails for approximately $125/ton. The deposit in the WSA is too small to be mined commercially but may have value to consumers who gather their own decorative stone. INTRODUCTION A mineral survey of the Sand Butte WSA (Wilderness Study Area) 1/ was conducted in June 1985 by the USBM (U.S. Bureau of Mines) and the USGS (U.S. Geological Survey) at the request of the BLM (U.S. Bureau of Land Management). The USBM examines individual mines, prospects, claims, and mineralized zones, and evaluates identified mineral and energy resources. The USGS evaluates potential for undiscovered resources based on areal geological, geochemical, and geophysical surveys. Results of the investigations will he used to help determine the suitability of the WSA for inclusion into the National Wilderness Preservation System. The immediate goal of this and other USBM mineral surveys is to provide data to the President, Congress, government agencies, and the public for land-use decisions. The long-term objective is to ensure the Nation has an adequate and dependable supply of minerals at a reasonable cost.

Jan 1, 1986

By P B. Hills, R J. Walton

Narrow vein tabular orebodies are prone to mining induced seismicity. The Tasmania Mine is a complex example of a seismically active tabular orebody, where the contrasting material properties of the host strata and of the orebody itself, serve to exacerbate the seismic response. Analysis of a continuous record of seismicity over a period of seven years has provided significant insight into the fundamental mechanics of the rock mass. Understanding seismicity to permit safe extraction of the orebody has been enhanced by instrumentation of rock mass behaviour in response to mining and mining induced seismicity. It is the purpose of this paper to explore that understanding in respect to the adoption of an alternative down-hole Avoca stoping method for use in particular circumstances.Intensive instrumentation of the Tasmania Mine over a period of four years has provided insight into the behaviour of the rock mass in response to extraction of the narrow vein orebody it encompasses. A range of instruments have been installed in clusters or single installations in order to measure changing stress conditions and the impact of those changes on the rock mass and the reinforcement system.Instruments are often installed in very close proximity to active production stoping. While it has been possible to observe the impact of the mining and mining induced seismicity at very close quarters, instruments installed in these locations are vulnerable to damage and consequently, the level of instrumentation is high. Instruments are continuously logged, typically on a six hourly basis coinciding with the end of regular blasting times. The response of the instrumentation to changed rock mass conditions is considered against the background of development and production blasting and against the seismic record to assess the viability of downhole Avoca stoping.CITATION:Hills, P B and Walton, R J, 2012. Continued observations of rock mass behaviour in response to stoping at the Tasmania mine, Beaconsfield, Tasmania, in Proceedings Narrow Vein Mining 2012 , pp 169-178 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Mar 26, 2012

By Claude Hubert, Alex C. Brown, Michel Richard, Rejean Sirois

"The Pierre Beauchemin gold deposit, situated 15 km NW of Rouyn-Noranda, produces an average of 1050 tonnes of ore a day. Reserves are 1.2 Mt grading 5.6 g/t Au. The deposit, located in a shear zone within the Flavrianpluton, in the Blake River Group, is hosted by four major rock types: meta-trondhjemite, meta-tonalite, hybrid rocks and meta-diorite (the prefu; ""meta-"" is omitted thereafter). The trondhjemite, tonalite, and metamorphic hybrid rocks are spatially distributed as a series of sub-horizontal tabular sills that form a genetically related group. Early fractures that permitted either the emplacement of pre-diorite felsic dikes or the formation of a visible alteration caused by early fluid circulation might have been developed in response to initial strain created during regional deformation. These fractures were precursors to the emplacement of diorite and the development of major shear planes. Sub-horizontal north-trending en échelon diorite lenses are observed at the mine. Together, these diorite lenses constitute larger scale diorite zones which are observed at the scale of the pluton. The diorite zones are interpreted as evidence of an episode of sub-vertical extension sustained by the layered trondhjemite, tonalite and hybrid system. The anisotropy created by the less competent sub-horizontal en échelon diorite was an important factor. In shear zone development and subsequent mineralization. The tonalite and diorite accommodated further defomation and developed the main N030°/40° ESE shears along with the spatially associated N060°/50°-60° SSE, and the N000°/10°-40° E shear zones. The N000° shears are interpreted as refracted or deflected equivalents of the N030° shears. The combined shears compose the Eldrich shear system which trends approximately N030°/40° ESE and has had a general reverse movement with a minor sinistral component.Gold mineralization occurs in all four major rock types as en échelon sigmoidal shaped lenses associated with the major N030° deformation system. The distribution of ore lenses can be divided into two categories: The first category occupies sub-horizontal diorite zones. The lenses trend N-S, dip 100 40° E, and are associated with shear zones, sub-horizontal fractures or tonalite-diorite contact planes. The second category of lenses is found in felsic granitic rocks; the lenses trend either N0300!40°ESE or N060°/50°-60° SSE. Local hydraulic breccia zones are observed near ore zones occupying felsic granitic rocks. These breccias may have resulted from high fluid pressures brought upon by confinement as a result of impermeable zones in an anisotropic tonalite-diorite system."

Jan 1, 1990

By E. L. Bruce

GOLD occurs ill many mineral deposits in the rocks of the Canadian Shield. It is present in the ores of many base metals and a considerable quantity is recovered as a by-product from the production of copper at Noranda, of nickel and copper at Sudbury and of copper and zinc at Flinflon. But the greater part of the gold production of Canada is from deposits in which gold is the only metal of value. No gold is obtained from placer deposits within the borders of the Canadian Shield. A brief review of the geological relations of some of the gold deposits of the Canadian Shield will be presented in an attempt to explain certain associations. Only those which are being worked for their gold content will be considered and descriptions will be confined to representative types of deposits, chiefly those of major importance; a few others, differing in certain features from those of the older and larger mines, will be included in order to illustrate the general conditions in which gold occurs in these ancient rocks. Brief summaries will be given of the geological relations of the Beattie and Siscoe mines of northern Quebec, of the mines of the Porcupine and Kirkland Lake areas of northeastern Ontario and of the Howey, Central Patricia and Little Long Lac mines of northwestern Ontario. Genetic relations to igneous rocks of granitic composition, outcropping in the vicinity, have been assumed for many of these deposits. Undoubtedly the ore minerals have been derived from igneous sources and, for some occurrences, there is evidence suggestive of genetic relationship between the ore bodies and neighbouring intrusive rocks. During the past few years, however, many investigators have expressed doubt of the genetic relationship of certain ore bodies to igneous masses near which they occur. As will be seen from references in the following descriptions the importance of the structural conditions in localizing deposition has been realized. This is pointed out for Canadian pre-Cambrian gold deposits by E. T. Dougherty, who also refers to the

Jan 1, 1937

By E. G. Joe

Introduction Uranium mining has been actively carried on in Canada for over twenty-five years mainly in Ontario at Elliot Lake in Bancroft, and in Northern Saskatchewan at the operations of Eldorado Nuclear Ltd. During this period, approximately one hundred million tons of mill tailings have been created and lie mainly on the surface close to the mining and milling installations. If all of the present reserves of uranium ores in Canada are mined, a further eight hundred million tons of mine tailings could be created in Ontario, Saskatchewan, the Northwest Territories, Labrador and British Columbia. The present control of effluents from existing tailings is managed by the operating mines under the regulations of both federal and provincial control agencies. It is the long-term effect of these tailings on the environment that has not been clearly defined or measured. Several years ago, the Canada Centre for Mineral and Energy Technology of the Department of Energy, Mines and Resources, embarked upon a program of research directed at the long-term effects of uranium mine tailings. Much of the research to date has been on tailings in the Elliot Lake, Ontario area where some tailings piles have existed for over twenty years. The program consists of two projects, one to address the problem of existing tailings and the other to examine alternatives in the management of current and future tailings. TAILINGS CHARACTERISTICS Uranium tailings are generally the result of sulphuric acid leaching in which the uranium and alkaline minerals such as carbonates and chlorites are leached out. If the ore contains sulphides, these minerals potentially present an additional hazard of acid generation over time and could increase the mobility of heavy metals and some radionuclides such as thorium-230. Except for the extracted uranium, most of the radionuclides from the ore remain in the tailings pile. Uranium ores in Canada span a wide variety of mineralization and associated gangue composition. Uranium minerals include pitchblende, uraninite, uranothorite, brannerite and the phosphate uranium minerals autunite and saleeite. Gangue minerals vary from acid consuming carbonates, and chlorites to acid producing sulphides and inert silicates. With such a wide variety in ore composition, the characteristics of the resultant tailings in Canada are in many cases site specific and the solutions to the long-term effects of these tailings may also be site specific.

Jan 1, 1980

By G. Morin, F. Chiesa, B. Tougas, B. Duchesne, Jocelyn Baril, N. Giguère

"An aluminum A356 compressor impeller was sand cast using the Low Pressure technique. The casting was limited in size (170 mm in diameter, 1.2 kg in weight) and very intricate in shape thus making 3D mold printing particularly favorable; indeed, producing this part by the traditional pattern-core box route would involve mounting 12 cores inside the mold while stringent dimensional tolerances are required as the impeller blades are only 2 mm thick. Consequently the molds were produce on the X-One MFlex printer of Quebec Metallurgy Center - CMQ. A dozen castings were produced with different casting temperatures and filling times so that it was possible to assess under which conditions complete filling of the mold cavity would be achieved. Filling and solidification modeling allowed predicting misruns and metallurgical properties inside the A356 (AlSi7Mg04) casting.INTRODUCTION Recent advancements in additive manufacturing enable foundries to produce molds without the tooling (pattern and core boxes) necessary when conventional technology is used (Eyad, 2016). This is particularly advantageous when dealing with intricate shapes and/or when a limited number of parts must be produced within a few days rather than in 5 weeks. An additional advantage is gained when producing prototypes (Johnson, 2016) as changes are much less costly and time consuming when made on a numerical 3D drawing rather than on patterns and core boxes. 3D printing is normally economical for a small number of parts; however, if the part is not too big and very intricate in shape such as the part that will be studied in the present work, 3D printing can be economical even for an important number of castings to be produced. On the other hand, low pressure casting is a high integrity casting process in which the mold cavity is filled from the bottom via a transfer tube in which the liquid aluminum rises under the pressure applied at the surface of the melt as illustrated in Figure 1. The filling can thus be precisely controlled, eliminating the turbulence created when the mold is filled from the top (gravity casting). Also, the pressure applied on the melt during solidification results in excellent feeding of the casting when conditions of directional solidification are met. In the present work, the compressor impeller shown in Figure 2 will be sand cast by low pressure."

Jan 1, 2018

By A. M. Gaudin

Of the various reagents employed in the flotation of zinc-bearing ores none have attained the wide popularity that is enjoyed at present by xanthates, copper sulfate and cyanides. This situation suggests the existence of an unusual dependence in the reactions of these chemicals and of sphalerite. A study of the flotative characteristics of sphalerite when using xanthates as collectors, as related to the chemical properties of copper salts and cyanides, has therefore been conducted at the University of Utah by the writer and his associates1 during the period of 1926 to 1929. In perusing the technical literature concerning the flotation of zinc ores and of zinc-bearing lead and copper ores, a striking and general lack of agreement as to the floatability of sphalerite was observed. The underlying cause for the erratic behavior of sphalerite has not been definitely ascertained but the presence in various proportions of iron sulfide in solid solution in the sphalerite has frequently been implicitly regarded as a major factor in this respect. Although the effect of iron sulfide in solid solution in sphalerite has not been investigated in relation to the behavior of sphalerite in flotation, it is likely that it is not as important a factor as was thought at one time. The variable float-ability of sphalerite has led to the use of fairly large amounts of cyanide to prevent its flotation in the case of certain ores, whereas mere fractions of that amount of cyanide, or even none at all, have been sufficient to achieve the same result for other ores2 Similarly, the amount of copper sulfate used to promote the flotation of sphalerite has been found to vary widely. Effect of Copper Salts in Distilled Water on Sphalerite In the work at the University of Utah, over a year was spent in futile attempts at duplicating experiments until it was discovered that the

Jan 1, 1930

By C. D. King

The key to maximum production of ingots for the war effort is maximum production of pig iron. For any given furnace and ore, the most important single influence on blast-furnace production is the quality of the furnace coke. It is generally recognized that undoubtedly deterioration of Pittsburgh coking coals will be accelerated by the depletion of some of the better grades of coal; the extension of mine mechanization, with attendant degradation of coal quality; and the opening of new coal fields, some of which are known to be fairly high in sulphur. All of these factors, contributing as they do to higher ash and sulphur, and not infrequently to inferior quality of coke, made it desirable that an extensive study be undertaken to determine the effect of washing some coals that closely approximate the average chemical composition of coking coals to be expected in the future by the subsidiaries of the United States Steel Corporation in the Pittsburgh district. It was deemed advisable to study the improvement obtained by washing such coals and to determine the need for supplementing the existing coal washery at Clairton to assure continued maximum production of pig iron from presently available furnace stacks. The existence of the coal washer at Clairton made it possible to conduct tests on coals used in raw form and on similar coals after washing. This study covers an investigation of the quality of furnace coke as affected by washing coking coals, and is confined to the use of 100 per cent high-volatile Pittsburgh seam coals from Fayette and Greene Counties in the manufacture of furnace coke. It covers the improvement in chemical and physical properties as well as the degree of uniformity in coke obtained by washing these coals, and includes the effect on blast-furnace production and practice. The test period involved is four months; the plants, Clairton by-product coke plant, and the Carrie No. 1 and No. 2 blast furnaces at Rankin, Pa., Carnegie-Illinois Steel Corporation. Clairton By-product Coke Plant and Coal Washer The Clairton by-product coke plant carbonizes 30,800 net tons of coal daily in 22 batteries containing 1482 ovens. Three oven sizes are used, commonly known as wide, medium, and narrow types, recognizing the difference in oven width, These ovens also differ in height and length. The present coal washer has a daily capacity of approximately 14,000 tons, leaving 16,800 tans to be carbonized in raw form. Washed coal is used on all the narrow ovens and on three of the six batteries with ovens of medium width, raw coals being used on all the remaining ovens. The customary arrangement is

Jan 1, 1944

By W. N. Poundstone, W. M. Merritts, B. A. Light

A joint investigation by the Bureau of Mines and the Christopher Coal Co. at the Humphrey No. 7 mine, operating in the Pittsburgh coalbed in northern West Virginia, was undertaken to gain more insight concerning the hazardous emission of methane gas in mining. This report describes the equipment, procedure, and results. Horizontal bleeder holes drilled in the faces drained large quantities of methane, eliminating downtime of mining equipment. Also, larger quantities of methane were removed by forcing 14 to 25 g,.p.m. water at 25 to 200 p.s.i. 5 pressure into the bleeder holes. In one infusion test a fluorescein dye was added to the infusion water; in later mining operations, the infusion water was traced for a distance of 1,500 feet. With vacuum pump applied to the horizontal hole the gas-flow rate increased, and the methane content decreased. Tests indicated that methane and water infused in bleeder holes traveled along the bedding planes of the Pittsburgh coalbed at a faster rate than across the planes. Methane associated with coalbeds is produced by the slow decomposition of carbonaceous material in the absence of air and the presence of water. It is lighter than air and, depending on its concentration, forms an inflammable or explosive mixture with air. It is believed that methane is entrapped in and around the pores of the coal and adjacent strata--often under great pressure. In many cases where the strata have been disturbed by geologic movements the

Jan 1, 1962

By Aydin Shaterpour Mamaghani, Bilgin. Nuh, Engin Dogan, Tayfun Erdogan

"Improved safety and more environmentally friendly operation are basic advantages of mechanical excavation over the drill and blast method. Raise Boring Machines (RBMs) are one of the types of these machines which have recently been increased use in Turkey. The excavated hole with RBM is more stable than other methods and has better air flow, making it ideal for ventilation shafts. This paper is a summary of the performance of a RBM in the Balya PB-Zn Mine in Turkey. Length and diameter of the ventilation shaft are 200 m and 2.4 m, respectively. The geological and geotechnical characteristics of the strata excavated in the mine are first given and later the validity of a model developed to predict the machine performance is discussed. It is believed that the results of this study and the model given to estimate the performance of the RBM will be useful guide for future applications. INTRODUCTION Raise boring technology was developed to meet the demands of the mining industry, but has also found numerous applications in tunneling or infrastructure projects for ventilation purposes. Raise boring machine uses a small diameter drill rod, around 230-350 mm to drill a pilot hole down to the required depth up to around 2000 m. Once the pilot hole has been drilled to the desired depth, a reamer of up to 9 m diameter is attached to the drill rod. The reamer is then pulled back up to the upper level, creating a round shape. Continues operation provides a faster advance rate than other methods. RBMs are suitable both in hard and soft rock. The flexibility in different angles and diameters is a great advantage compared to drill and blast excavation method. RBM creates a shaft with smooth walls which usually does not require lining. The hole is more stable than a drilled and blasted method and has better air flow, making it ideal for ventilation shafts. Raise boring is convenient method in competent rock; however several problems are faced in geological formations where geological discontinuities are dominant. Moreover, assembly and disassembly time may be long in some cases. The performance and operational parameters of the excavating machine should be predicted prior to starting the excavation operations in order to fulfill the economic requirements of the project. In the light of this fact, the main objective of this investigation is to summarize a case study on raise boring machine performance and suggest a new model based on laboratory test results. First, general description of the mine and project are provided. Then, the physical and mechanical characteristics of the samples taken from project area are discussed. In the third section, performance and operational parameters of RBM are investigated to understand the machine behavior in different rock characteristics and also to collect a useful database for further investigation. In the fourth section, a new model for performance estimation of RBM are recommended."

Jan 1, 2016