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By M. A. Mahtab, A. S. Burgess, R. G. Charlwood, P. O. Sandstrom, J. L. Ratigan

"Addressing a current operating and environmental concern, this paper first presents an overview of the design program for an underground radioactive waste storage vault. It then reviews the construction, operational and thermal-mechanical aspects of such a project. The relevant experience from major underground construction projects is reviewed and the paper concludes with brief comments on the design-oriented research and development requirements . 1. IntroductionA program to develop techniques for the ultimate disposal of high-level radioactive waste into geologic formations was announced by AECL in 1975 (Tamrnernagi, 1976), and is discussed more fully in a later document (Boulton, 1978). Our paper summarizes the studies caried out, as part of the AECL waste management program, by the authors and associates on the development of design concepts for a vault situated in crystalline rocks of the type present in the Canadian Shield.The design studies have been carried out in three phases, the elements of which are described in Section 2.1 (also see Fig. 1). The general vault designs are presented in Section 2.2. These provide for emplacement of either immobilized fuel or solidified reprocessing wastes in a room-and-pillar facility at a depth of 1,000 m.Section 3 reviews the principal design considerations from the construction, operation and thermal-mechanical response aspects. The concepts have been studied in both temporal and spatial domains, and the requirements and responses assessed in each as appropriate.Section 4 briefly reviews the availability of relevant experience from previous major underground construction projects. Finally, in Section 5, brief comments are given regarding design-oriented research and development requirements."

Jan 1, 1980

Despite the claims of energy efficiency and the considerable development that has gone into dramatically extending rolls’ life and facilitating rolls’ change-out, in the six years since the last SAG conference, only a few HPGR operations have entered the realm of mineral processing. Risk barriers to the take-up of new equipment or processes are: a massive increase in materials handling issues as well as in the number of pieces of equipment required, low total circuit potential energy savings, and similar or higher capital costs. An alternative route is to make use of the complementary strengths of the HPGR and SAG in hybrid circuits. Minimising materials handling issues, providing an ideal balanced feed to the AG or SAG mill, and improving controllability through shifting grinding load as the RoM feed changes, are all potential major advantages to this approach. Conceptual circuit layouts, based on real measured ore and equipment data, are presented here to illustrate the potential production upside, the reduction in operating costs and the reduction in the physical and energy footprints.

Jan 1, 2012

By Jennifer Riefenberg

A family of personal computer programs that calculate the Coal Mine Roof Rating (CMRR) has been developed by the U.S. Bureau of Mines. The CMRR rock mass classification system provides a link between the qualitative geologists' description of coal mine roof and the quantitive mine engineers' needs for mine design roof support selection, and hazard detection. The program CMRR is a user-friendly, interactive program into which raw field data are input. A CMRR is calculated and output along with two graphic displays. The first graphic display is a plan view trap with the CMRR's displayed on a color-coded scale. The second display shows a stratigraphic section of the bolted roof interval and its resultant CMRR. In addition, a Lotus 1-2-3 worksheet, computer file BOM-CMRR.WK3, has been developed for easy storage of field data. The worksheet includes four macros that automatically calculate CMRR's, store field test data in a database format, and print a two-page report of the field data and CMRR parameters. Production of summary port; for analysis of site-specific information are readily generated using Lotus 1-2-3 software. These programs help to facilitate the engineer in utilizing the CMRR in ground control studies.

Jan 1, 1994

By H. L. Barr

THE following report covers the history of the development of the mine, present equipment, methods and costs of mining and milling. In addition, a description of the ore deposit is given with emphasis on the origin of the fractures, mode and types of ore occurrence, and mechanics of granite emplacement. An endeavor has been made to present a complete and accurate statement of the San Mauricio mine, the highest grade gold mine in the Philippine Islands. Credit is gratefully acknowledged to the mine staff for descriptions and details regarding their particular field of work. All analyses were made by Mr. T. A. DeVore, head chemist, San Mauricio Mining Co. Messrs. Edward Wisser, J. E. Fyfe, A. F. Skerl and W. B. Meek, geol-ogists, have contributed geologic information and ideas, for which thanks are extended. The Executive Committee of Marsman and Co., Inc., Managers of the Company, has kindly given permission for publication. Mr. J. B. Stapler, Division Manager, Marsman and Co., has had the courtesy to read the manuscript and to give critical and helpful suggestions.

Jan 1, 1940

By N Kojola, A Vickerfält, J Huss

The possibility of using an acidic autogenous hydrogen direct reduced iron (H-DRI) slag as a basis for vanadium extraction is investigated. For a raw material to be suitable for producing high-quality FeV, the vanadium oxide content should be sufficiently high and the phosphorus oxide content in a tolerable range. Therefore, the feasibility for vanadium extraction relies on fulfilling two demands: the predominate partitioning of phosphorus to the metal and vanadium to the slag. Correspondingly, the behaviours of phosphorus and vanadium in the Al2O3-SiO2-FeOx-VyOz-P2O5-Fe system were studied experimentally. Slag, 10 g, was put in contact with liquid iron, 30 g, for different durations (2–24 hrs) in closed alumina crucibles at 1873 K. The slag composition was varied between 33.1– 49.3 wt per cent Al2O3, 27.1–46.7 wt per cent SiO2, 16.6–30.1 wt per cent FeOx, and 2.5– 8.8 wt per cent V2O3. The equilibrium phosphorus distribution was 0.42, while the vanadium distribution ranged from 7.6 to 43.4, increasing with the Al2O3- and the FeOx-content.

Jun 19, 2024

By Kenzo Ikeda

The Kosaka smelter is situated in the extreme northern end of Hondo (the main island of Japan) 15 mi. east of Odate, on the government railroad, to which it is connected by a private railway. It contains ten blast furnaces having a maximum daily capacity of 1600 short tons of ore, conducting a slow pyritic smelting entirely without coke or limestone, and with a charge carrying over 50 per cent. of briquetted and agglomerated fines. The matte (35 per cent. Cu) is blown in two basic-lined barrel converters, the blister copper (98.8 per cent. Cu) being cast at once into anodes. The adjoining refinery contains 600 tanks with a maximum capacity of 1300 tons of cathodes per month, the byproducts being gold, silver, and bismuth. At present, working at about half capacity, the whole plant consumes 2000 kw. of hydro-electric power, and employs 850 men and women. The ores are derived from two principal sources: The relatively new Hanaoka mine, 20 mi. from the smelter, yielding copper pyrites by underground mining, and the old Kosaka open-cut mine, 1 1/2 mi. from the smelter, yielding three different ores: (a) kuromono, a compact finegrained mixture of barite (32 per cent.), zinc blende, galena, and pyrite, the whole carrying about 2.5 per cent. Cu; (6) cupriferous pyrites with 2.4 per cent. Cu; (c) siliceous ore with 2 per cent. Cu. The Hanaoka ore now constitutes approximately one-half of the charge, almost replacing the Kosaka kuromono which was the ore chiefly smelted until 1913.'

Jan 1, 1923

By Yu-ren Jiang

Novel compounds of hydroxycarbamoyl carboxylic acids, including 2-hydroxycarbamoyl -3-methlcyclohexane carboxylic acid (HCMC), 2-hydroxycarbamoylmethyl decylen-4-yl carboxylic acid (HCDC) and 2-hydroxycar-bamoylmethyl tridecylen-4-yl carboxylic acid (HCTC) were synthesized. The flotation behaviors of diaspore, kaolinite and illite using these compounds as collectors were investigated. The flotation results revealed that the floatability of the minerals was, in descending order, diaspore and kaolinite, followed by illite, and the ability to collect the minerals was, in ascending order, HCMC and HCDC, followed by HCTC. At a dosage of 2×10-4 mol/L, both HCDC and HCTC show a strong ability to collect diaspore and a weak ability to float kaolinite and illite. The flotation recovery of diaspore is over 90% and that of kaolinite and illite less than 30%. Moreover, Fourier transform infrared spectroscopy (FTIR) spectrum and zeta potential, as well as the adsorption amount, indicated that the adsorption interaction between HCTC and diaspore was primarily a kind of chemisorption in the form of chelate rings, while the interaction between the collector and aluminosilicate mineral was dominated by physisorption. It was concluded that the novel hydroxycarbamoyl carboxylic acid compounds are highly selective collectors for the flotation of diaspore vs. aluminosilicate minerals.

Jan 1, 2011

By Kenzo Ikeda

The Kosaka smelter is situated in the extreme northern end of Hondo (the main island of Japan) 15 mi. east of Odate, on the government railroad, to which it is connected by a private railway. It contains ten blast furnaces having a maximum daily capacity of 1600 short tons of ore, conducting a slow pyritic smelting entirely without coke or limestone, and with a charge carrying over 50 per cent. of briquetted and agglomerated fines. The matte (35 per cent. Cu) is blown in two basic-lined barrel converters, the blister copper (98.8 per cent. Cu) being cast at once into anodes. The adjoining refinery contains 600 tanks with a maximum capacity of 1300 tons of cathodes per month, the byproducts being gold, silver, and bismuth. At present, working at about half capacity, the whole plant consumes 2000 kw. of hydro-electric power, and employs 850 men and women. The ores are derived from two principal sources: The relatively new Hanaoka mine, 20 mi. from the smelter, yielding copper pyrites by underground mining, and the old Kosaka open-cut mine, 1 1/2 mi. from the smelter, yielding three different ores: (a) kuromono, a compact finegrained mixture of barite (32 per cent.), zinc blende, galena, and pyrite, the whole carrying about 2.5 per cent. Cu; (6) cupriferous pyrites with 2.4 per cent. Cu; (c) siliceous ore with 2 per cent. Cu. The Hanaoka ore now constitutes approximately one-half of the charge, almost replacing the Kosaka kuromono which was the ore chiefly smelted until 1913.'

Jan 1, 1923

By Ian M. Loomis, Malcolm J. McPherson

A fuel-rich fire exists when the quantity of fuel exceeds the oxygen available to support complete combustion. The transition of a mine fire from Oxygen- rich to Fuel-rich combustion, at this time, represents a point-of-no-return in the fire fighting efforts. Once the transition has been made to fuel-rich the fire can spread at a rate 6 to 10 times as fast as in the oxygen-rich state. Utilizing available technology the fire fighters are left to seal the fuel-rich fie as the only technique to extinguish it. In order to minimize the devastating effects of a fuel- rich fire it is important to understand the means by which the fire becomes fuel-rich and by what means the fire may be returned to an oxygen-rich state. This paper covers: the development mechanism of a fuel- rich fire in a coal mine entry and the physical and chemical effects of applying water to a fire. Experiments concerning these matters have been conducted in a 30 cm square wind tunnel constructed at the Virginia Polytechnic Institute and State University as a model coal mine entry. This paper also addresses the results obtained in testing application of a water mist to fuel-rich fires in this model. These tests have centered on the development profile of a fuel-rich fire in a duct and demonstrate a means of regaining control of a fuel-rich fire by returning it to an oxygen-rich state.

Jan 1, 1995

By R. W. Raymond

R. W. Raymond, New York City: In his paper at the New York meeting (Trans., xix., 28), Mr. Ledyard described, among other mines, the Belmont, in the county of Peterboro, Ontario, the developments of which at that time indicated, though they did not, perhaps, completely demonstrate, a deposit of high-grade Bessemer magnetite of very great extent. Mr. Ledpard said that experts estimated the quantity of ore within 100 feet of the surface at 1,000,000 tons. But the precise data upon which this estimate was based were not furnished. We are all interested in the development of fresh supplies of Bessemer ores. I think nobody who knows how enormous is the demand can seriously fear that such deposits will be exploited too rapidly. On the other hand, I need not here enlarge on the fact that a considerable number of enterprises, in which American ironmasters have been more or less interested, for the development of Canadian iron-ore deposits, have been unsuccessful, more by reason of disappointment as to the quantity of the ore and the facilities for cheaply mining it on a large scale, than as to its quality. Of course, a Canadian nine supplying the American market is handicapped at present, to the extent of 75 cents per ton, by the duty on foreign iron-ore; but this would certainly not be prohibitory in the case of a deposit sufficiently large, rich, and accessible. Or, to put it otherwise, there might easily be, somewhere in Canada, near our borders, a mine so favored that its product could be profitably

Jan 1, 1892

By Leslie Thompson, Randy Hiebert, Marietta Canty

A paper is presented in which an innovative biological process is described for the treatment of cyanide-, metals-, and nitrate-contaminated mine process water. The technology is capable of detoxifying cyanide and nitrate and immobilizing metals in wastewater from agitation cyanide leaching as well as heap leaching. A pilot-scale demonstration is described in which a pilot plant was constructed to detoxify cyanide and immobilize several metals from a mine process wastestream at a mine in Nevada. The demonstration was performed jointly under the Mine Waste Technology Program (MWTP), which is funded by the U.S. Environmental Protection Agency (EPA) and is jointly administered by the U.S. Department of Energy's (DOE) Western Environmental Technology Office (WETO) and the Superfund Innovative Technology Evaluation (SITE) Demonstration Program under Interagency Agreement Number DW89938513-01-0. MSE Technology Applications, Inc. (MSE) located in Butte, Montana, was the contractor responsible for conducting the project, and Pintail Systems Inc. of Aurora, Colorado, was the technology provider. The pilot-scale unit was field tested at the Echo Bay McCoy/Cove Mine southwest of Battle Mountain, Nevada. The biotreatment process was con­sidered to be very successful in detoxifying cyanide from the mine process water. The process was also determined to be very effective in removing metals. The pH was consistently neutral­ized and nitrates were successfully removed in the mine process water. As a result of conducting these pilot-scale tests, the biotreatment process was concluded to offer an innovative, cost­effective alternative for the treatment of mining wastewaters.

Jan 1, 1998

By Takashi Katsura, Avnulf Muan

Equilibrium relations in the system FeO-Fe2O3 Cr2O3 have been determined at 1300°C at oxygen pressures ranging from that of air (0.21 atm) to 1.5 x 10-11 atm. The following oxide phases have stable equilibrium existence under these conditions : a sesquioxide solid solution with corundum-type structure (approximate composition Fe2O3-Cr2O3); a ternary solid solution with spinel-type structure (approximate composition FeO Fe2O3-FeO Cr2O3) and a ternary wüstite solid solution with periclase-type structure and compositions approaching FeO. The metal phase occurring in equilibrium with oxide phase(s) at the lowest oxygen pressures used in the present investigation is almost pure iron. The extent of solid-solution areas and the location of oxygen isobars have been determined. ThE system Fe-Cr-O has attracted a great deal of interest among metallurgists as well as ceramists and geochemists. Metallurgists have studied the system because of its importance in deoxidation equilibria, ceramists because of its importance in basic brick technology, and geochemists because of its importance for an understanding of natural chromite deposits. Chen and chipman1 investigated the Cr-O equilibrium in liquid iron at 1595°C in atmospheres of known oxygen pressures (controlled H2O/H2 ratios). The main purpose of their work was to determine the stability range of the iron-chromite phase. Hilty et al.2 studied oxide phases in equilibrium with liquid Fe-Cr alloys at 1550°, 1600°, and 1650°C. They reported the existence of two previously unknown oxide phases, one a distorted spinel with composition intermediate between FeO Cr203 and Cr3O4, the other Cr3O4 with tetragonal structure. They also sketched diagrams showing the inferred liqui-dus surface and the inferred 1600°C isothermal section for the system Fe-Cr-O. Koch et al3 studied oxide inclusions in Fe-Cr alloys and also observed the distorted spinel phase reported by Hilty et al. Richards and white4 as well as Woodhouse and White5 investigated spinel-sesquioxide equilibria in the system Fe-Cr-O in air in the temperature range of 1420" to 1650°C, and Muan and Somiya6 delineated approximate phase relations in the system in air from 1400" to 2050°C. The present study was carried out at a constant temperature of 1300° C and at oxygen pressures ranging from 0.21 atm (air) to 1.5 x 10-11 atm. The chosen temperature is high enough to permit equilibrium to be attained within a reasonable period of time within most composition areas of the system, and still low enough to permit use of experimental methods which give highly accurate and reliable results. These methods are described in detail in the following. I) EXPERIMENTAL METHODS 1) General Procedures. Two different experimental methods were used in the present investigation: quenching and thermogravimetry. In the quenching method, oxide samples were heated at chosen temperature and chosen oxygen pressure until equilibrium was attained among gas and condensed phases. The samples were then quenched rapidly to room temperature and the phases present determined by X-ray and microscopic examination. Total compositions were determined by chemical analysis after quenching. In the thermogravimetric method, pellets of oxide mixtures were suspended by a thin platinum wire from one beam of an analytical balance, and the weight changes were recorded as a function of oxygen pressure at constant temperature. The data thus obtained were used to locate oxygen isobars. The courses of the latter curves reflect changes in phase assemblages and serve to supplement the observations made by the quenching technique. 2) Materials. Analytical-grade Fe2O3 and Cr2O3 were used as starting materials. Each oxide was first heated separately in air at 1000°C for several hours. Mixtures of desired ratios of the two oxides were then prepared. Each mixture was finely ground and mixed, and heated at 1250" to 1300°C in air for 2 hr, ground and mixed again and heated at the same temperature for 5 to 24 hr, depending on the Cr2O3 content of the mixture. A homogeneous sesquioxide solid solution between the two end members resulted from this treatment. A Part of some of the sesquioxide samples thus prepared was heated for 2 to 3 hr at 1300°C and oxygen pressures of 10-7 or 1.5 x 10-11 atm. Reduced samples (either iron chromite

Jan 1, 1964

THE CHAIRMAN (G. H. CLEVENGER, Stanford University, Cal.).¬I would like to ask Mr. Pyne if he has had any experience inn the use of chromite as refractory under conditions that are highly reducing? I am reminded of an experience I once had with an electric furnace. I imagined that chromite would form a splendid lining, but it soon disappeared; hence it seems probable that, under highly reducing conditions at a high temperature, chromite is a very poor refractory. F. R. PYNE.-In copper smelting the atmosphere is generally neutral, or slightly oxidizing; we do not use highly reducing atmospheres at all, not even in the matting furnace. You can take the chromite brick and treat it as you would an iron ore, obtaining ferro-chrome very readily, from which the copper will separate. We have done this; in fact, at one time we considered installing a small electric furnace for the production of ferro-chrome. FOREST RUTHERFORD, New York, N. Y.-During the time I was general superintendent at the smelter of the Copper Queen Consolidated Mining Co., at Douglas, Ariz., a great many experiments were made on the furnaces and settlers with different kinds of brick, and I agree with Mr. Pyne's statements about chrome brick. Their power to absorb metals is very great, and as they cannot be smelted at any temperatures obtainable in a copper furnace, to get rid of the bats and extract the metal from them is quite a problem. We finally got down to using chrome brick only for lining the settlers, out of which we often got a life of upwards of 2 years, and for lining the blast-furnace bottoms, for the reason that chrome brick can be heated and wet, or wet after being heated, without going to pieces, whereas under these conditions magnesite brick will break down very rapidly. We also used a layer of chrome brick above and below an 18-in. band of magnesite brick put on the slag line of the reverberatories, in order to separate the magnesite from the silica brick, fearing that they would slag each other and let the wall drop. The idea worked, but became unnecessary on account of a change made in the method of feeding the furnaces. Chronic brick will not stand up under pressure so well as a good Grecian or Austrian magnesite brick, on account of the poorer bonding properties of the materials from which the chrome brick is made.

Jan 4, 1918

By Manqiu Xu, Joe Holmes, Peter Wells, Peter Langlois, Germain Labonté, Jim Barrett

"The flowsheet for the Voisey’s Bay mill had to meet the challenge of processing an ore containing high pentlandite and chalcopyrite values in a largely pyrrhotite/troilite matrix. In the 1994-97 period, circuit development focused on making a high-grade copper concentrate and a relatively low-grade nickel concentrate. However, in 1998 a circuit with copper concentrate, high-grade nickel concentrate and a Ni/Cu middlings concentrate was specified. Following a three year project delay, work resumed on the flowsheet in 2001, and the target for the overall grade of the nickel concentrate was raised from 14% to 20% nickel. To achieve this target triethylamine tetramine (TETA) and sulfite pyrrhotite depressants were used in an all lime circuit. It later became evident that, with appropriate selection of collector and adjustment of the circuit by the addition of a scavenger on the scavenger cleaner, it would be possible to approach the grade of concentrate required without the use of pyrrhotite depressants. The recycle of water and the contained thiosalts was also proven to be instrumental in raising the grade.Construction and commissioning of the mill were fast-tracked with start-up of the mill in September 2005 some six months ahead of the original schedule. Ramp-up of both throughput and metallurgy was faster than any other recent nickel installations with tonnage being limited mainly by concentrate dewatering due to the higher than initially planned ore grades.INTRODUCTIONNickel was discovered in the vicinity of Voisey’s Bay by Chislett and Verbiski working for Diamond Field Resources in 1993 and the Ovoid deposit was delineated in the winter of 1994/95. By the end of 1995 the Ovoid had been well explored and at that time was thought to have a reserve of at least 30 million tonnes with an average grade of 2.83% Ni and 2.0% Cu. Drilling to the east of the Ovoid had indicated the presence of significant mineralization. In June of 1995, Inco Limited bought a 25% share in the Voisey’s Bay Nickel Company (VBNC) which was a subsidiary holding company set up by Diamond Fields. Inco also bought 8% of Diamond Fields and negotiated the right to sell all the nickel produced from VBNC for twenty years as part of this agreement. In April 1996, Inco bought the 75% of VBNC shares that it did not own."

Jan 1, 2007

By Howard J. Pincus

The purpose of the study is to investigate the effects of fracture filling and associated alteration on the mechanical behavior of rocks. Results are presented for specimens from the Climax and Henderson mines in Colorado and the San Manuel mine in Arizona. The rock types studied from each location are from 1) Climax, medium-grained - granite, fine-grained granite, granite porphyry, schist, and gneiss; 2. Henderson, rhyolite porphyry; 3. San Manuel, quartz monzonite and quartz monzonite porphyry. A description of the rocks was made including: color, texture, mineral composition, composition and fabric of fracture fillings, density and porosity. Unconfined and triaxial compression tests were run on the Climax and San Manuel specimens. Sonic relocities were measured during the compression tests; Shore sceleroscope hardness was measured before the compression tests. Tentative conclusions are that some relation appears to exist between compressive strength and the following properties and features for all the specimens: dynamic Young's modulus, sonic velocity, density, rock composition, and composition and fabric of fracture fillings - veinlets. There appears to be some relation between compressive strength and Shore scleroscope hardness and porosity for quartz monzonite (San Manuel). A relation appears to exist between compressive strength and texture for schist and between com¬pressive strength and extent of failure on fracture fillings for fine-grained granite, schist, and gneiss (Climax). We plan to perform additional analyses of data collected so far and data yet to be collected in the next few months, with emphasis placed on devising a practical index of alter¬ation that can be used in the field. Limitations on interpretations arise from such factors as heterogeneity of the rocks studied, the small range of confining pressures used, and other factors presented in the text.

Jan 1, 1973

By M. Imani, A. Fahimifar, A. H. Javid

"Current studies of bearing capacity for shallow foundations tend to rely on the hypothesis of an isolated footing. In practice a footing is never isolated; it is mostly in interaction with other footings. This paper focuses on a numerical study to evaluate the ultimate bearing capacity for two interfering strip footings resting on a rock mass in which the strength can be described by the generalised Hoek–Brown failure criterion. This criterion is applicable to intact rock or heavily jointed rock masses that can be considered homogeneous and isotropic.The material is assumed to exhibit perfect plasticity and obeys an associated flow rule. The effects of Hoek–Brown parameters including GSI, mi, and sci were studied and the corresponding results are presented. For different clear spacing (S) between the footings, values of the efficiency factor (?) were determined; where ? is defined as the ratio of the failure load for an interfering new footing of a given width (B) to that of a single isolated footing having the same width. The maximum value of (?) occurs at spaced between S/B = 0.5 to 1.0. The results have been compared with those available in the literature.INTRODUCTIONEvaluating the ultimate bearing capacity of rock masses is essential for important projects like dams and bridges. Closely spaced footings may occur on rock masses in the form of pier foundation and grillage footing. Close spacing lead to permit higher loads than can be bore by similar isolated footings. The ultimate bearing capacity of two interfering strip footings resting on cohesionless soil have been studied theoretically (Kumar, & Gosh, 2007; Kumar, & Kouzer, 2008; Stuart, 1962). Results revealed when two strip footings approached closely enough, failure zones affect each other and ultimate bearing capacity significantly increased."

Jan 1, 2015

By P. C. Rath, K. Srinivasa Rao, T. Subbaiah

A process for the recovery of nickel from ammoniacal leach liquor through an integrated solvent extraction-electrowinning (SX-EW) flowsheet was tested on a pilot-plant scale. The objectives of the test run were to assess the reproducibility of laboratory-scale data in a large-scale continuous operation and to study the build up of impurities in the system. The pilot-plant test was conducted under operating conditions that were established from the laboratory-scale experiments. Efficiencies of nickel extraction, nickel stripping and ammonia scrubbing were comparable to the laboratory-scale values, whereas the current efficiency during nickel electrolysis was observed to be less than the laboratory-scale values. The electrodeposited nickel contained some cobalt and iron impurities.

Jan 1, 1998

By V. ?. Chanturiya, I. Zh. Bunin, M. V. Ryazantseva

"Surface changes in naturally occurring metal sulfides (pyrite, arsenopyrite, sphalerite, chalcopyrite, galena, and molybdenite) due to treatments from high-power electromagnetic pulses (HPEMP) at varying times were studied using X-ray photoelectron spectroscopy. Analysis of the obtained results revealed common patterns and differences in surface transformations. The transformations were found to include two main stages. The first stage was observed at low treatment intensities (up to n ~103 pulses). At this stage, formation and accumulation in the surface layer of the nonstoichiometric sulfide phase, oxides and hydroxides, as well as elemental (polysulfide) sulfur and/or metastable sulfur species (thiosulfate, sulfite) was observed. The second stage (N = 3·103 pulses) is characterized by thermal removal of sulfur species and renewal of the mineral surface (sulfidization).It was found that the chemical changes of the sulfur on the surface layer of pyrite, arsenopyrite, chalcopyrite included accumulation/formation of S0 (Sn 2-) at the first stage of the transformation, followed by its removal. An increase in the surface concentration of elemental sulfur for pyrite and chalcopyrite was 10–12% while arsenopyrite was approximately 5%. A more complicated chemical change was observed for sphalerite and galena, that included formation/accumulation of metastable sulfur species (thiosulfate, sulfate) at the initial stage (up to 103 pulses) and during longer treatment times, the sulphur is reduced back to its initial state (sulfide or disulfide). The increased concentration of S0 sulfur, compared to the original sample, was only 3% in galena and sphalerite.The application of HPEMP treatment to improve flotation selectivity is supported by singlemineral flotation tests. Changes in flotability as a result of HPEMP treatment are principally explained by surface phase changes that resulted in higher adsorption activity."

Jan 1, 2016

By B. E. Thompson, H. B. Fuqua

For a very brief description of the North Texas area, and the general geological features with which it is associated, the reader is referred to the opening paragraph of last year's summary1. A more complete discussion of the structure of the area, together with other interesting data concerning it, has been published recently by the Bureau of Economic Geology at the University of Texas2. It has been impossible for the authors to isolate the statistics for production for each of the many small pools of this district, as such statistics are not kept by operators except by counties or arbitrary divisions of counties. The total number of wells drilled in Archer, Wichita and Clay counties also has been subject to some estimate, as many of the shallower holes are not reported. While both routine development in proven or semiproven areas and exploratory drilling during 1935 showed an increase over the year 1934, the discovery of new producing areas of importance did not show improvement over that period. Several extremely local productive spots within semiproven areas were found in Archer, Cooke and Wilbarger counties; and extensions to older producing areas were developed in Archer, Baylor, Cooke, Montague, Wichita and Wilbarger counties. In Archer County, the Grace and Woods No. 1 Archer County (Fee), 4 miles northwest of Archer City, in the Thomas Glass survey, encountered a sand from 2836 to 2845 ft. of Pennsylvanian (lower Canyon) age, which showed an initial yield of 75 bbl. daily. While its production is of negligible importance, it is given special mention in this review because of the fact that it is producing from a new and deeper horizon than has been previously exploited in the county. Little deep development occurred in the district during the year. The Walter Gant No. 2 C. M. Worsham in J. M. Swisher survey, about 14 miles east of Henrietta, in Clay County, was abandoned at 5127 ft. in

Jan 1, 1936

H. 0. HOFMAN, Boston, Mass (written discussion*).-The paper by Mr.. Pyne gives clear evidence of the difficulties the metallurgist is likely to encounter when he tries to recover in the blast furnace the metal from old chromite lining used as a refractory material in the copper reverberatory furnace. It appears that chromite cannot be fluxed at temperatures which usually prevail in copper blast furnaces. This calls to mind the freezing-point curve drawn by M. Simonis1 of mixtures of chromite and kaolinite. The chromite used in the experiments contained 52.9 per cent. Cr203, 22.6 FeO, 4.8 AI203, 9.6 Si02, .10.1-MgO; FIG. 1. the kaolinite was clay from Zettlitz with 98.5 per cent. clay-substance: The accompanying curve shows that the eutectic mixture with 35 per cent. kaolinite and 65 per cent. chromite freezes at Seger cone No. 15 (1435° C.), while kaolinite fuses at cone No. 35 (1770° C.) and chromite at cone No. 42 (2000° C.). The curve indicates that the difficulty in the blast furnace can be overcome by having at the smelting zone a temperature much higher than is usual in copper smelting; a charge composition similar to that prevailing at the Mansfeld copper smeltery -which gives with 23 per cent. coke a, slag of the composition Si02, .49.09; .(FeMg)0, 5.58; (CaMg)0, 16.02; A1203,-16.02-might flux and fuse chromite.

Jan 3, 1918