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By H. Jung

The microstructures and grain sizes of nanocrystalline Co and Co-1.1 wt % P alloys were characterized by X-ray diffraction. The corrosion properties of as-deposited and annealed Co-l.l wt % P alloys and pure nanocrystalline Co were studied in a deaerated 0.1M H2SO4 solution using electrochemical measurements and XPS surface analysis. Potentiodynamic polarization testing and impedance measurements revealed that an addition of P to pure nanocrystalline Co improved the anodic-corrosion resistance, however, this enhanced corrosion resistance was compromised by the heat treatment process at 350 and 800°C. The corroded surface of annealed nanocrystalline Co-1.1 wt % P at 350°C exhibited a more porous P-enriched layer compared with the as-deposited case. A sample annealed at 800°C corroded uniformly showing second-phase precipitates. The enhanced corrosion resistance of as-deposited nanocrystalline Co-1.1 wt % P was attributed to the elemental P on the surface that acted to hinder the anodic dissolution kinetics of surface Co following an initial selective dissolution of Co. However, at a higher anodic overpotential region, the superior corrosion resistance of Co-l.l wt% P alloys did not last because of the formation of a non-protective surface film consisting of mainly hypophosphite and phosphate as well as elemental P.

Jan 1, 2005

By Chris Doyle

From 1997-2000. PT INCO undertook the Fourth Line Expansion Project (FLEX) to increase annual production rates from 90-100 to 150 Mlbs Ni/year (68,000 MT Ni/yr). In 2003, PT INCO nickel production underwent a major sustainable step jump that finally exceeded the targeted rate. This paper presents the changes that led to this achievement. The focus of mining changed. Improving Ni grade was important but only if electric furnace feed met target chemistry so that on-specification slag could be produced. The intensity of diamond core drilling for exploration was dramatically upgraded, mine planning strategy was totally re- vamped and an ore chemistry quality assurance team was formed. In the processing plant, measurement systems were upgraded for better control. Teamwork between sections vastly improved. The final step jump in production occurred when the fifth hydro-electric power generator was added to the furnace grid to allow the power-starved furnaces to cruise in operation at 70+ MW. Keywords: Free cash flow, Ore Chemistry, Measure, Control, Improve

Jan 1, 2004

By Hermann Wotruba, Lars Weitkämper

"Dry coal dressing was popular during the 1950.s and 60.s in many parts of the world. The devices mainly used were air jigs and air tables.The increase in ash and moisture content of run-of-mine coals due to the wide advanced mechanisation of mining mechanisation during and after this period led to that pneumatic devices being unable to treat run-of-mine coals with the desired efficiency. Since the 1960.s almost all new coal preparation plants have been based on wet processes that are highly efficient in terms of coal recovery and their ability to handle damp and sticky run-of-mine coals. (Frankland, 1995)However, water is becoming increasingly costly and the disposal of fine products, containing most of the water, is an environmental concern. There would be significant cost savings and a lower total energy consumption if coal could be cleaned dry. Efficient dry coal treatment would be an interesting solution in desert, arid or cold areas.In Germany one dry coal dressing plant is in operation. The process and the advantages and disadvantages are presented below.Further on new developments in the field of dry density separation of coal are reviewed and analysed. Test results of new dry coal separation methods e.g. new developed air jig and magnetic separator are reported."

Jan 1, 2003

By Theodore L. Turner, Joseph H. Swift

A study on a small laboratory scale was made of the use of ammoniacalammonium carbonate for batch leaching Mn from low- grade manganiferous materials ( 6 to 16 pct Mn) obtained from deposits in the southern district of Aroostook County , Maine . These materials were partially reduced at 500 ° to 700 ° C with H₂ or CO and then leached with solutions of NH and CO₂ dissolved in water . Extraction of 80 to 90 pct of the Mn was obtained from some sample materials , but 10 to 34 pct of the iron was also extracted . Material from the Littleton Ridge deposit contained manganese intimately associated with Fe , a condition which contributed to difficulties in obtaining a commercially acceptable product . Extensive investigations of the leach and reduction processes with various mixtures of H₂ and water vapor , and CO and CO₂ , failed to disclose a set of conditions for selectively leaching the manganese . Finely divided metallic Fe was probably produced during the reduction steps so that Fe was leached with the Mn in the subsequent extractions .

Jan 1, 1964

By Luís Marcelo Tavares, Henrique Dias Gatti Turrer, Luciana Pereira Alves

Desliming is a method of classifying mineral particles, which aims at removal of slimes so as to prepare the slurry to downstream concentration processes. It is a common item in mineral processing flowsheets, being mostly carried out in hydrocyclones, in which separation is result of complex fluid flow and its interaction with the mineral particles. When dealing with particles contained in size ranges relevant to desliming, the challenge in describing the process is even greater. The work deals with the fitting of the Narasimha-Mainza model of classification in hydrocyclones to data from desliming an itabirite iron ore, for prediction of feed slurry flowrate, corrected cut size and short-circuit to the underflow. As such, tests were conducted at both pilot and industrial plants in KREBS 2.7” and 4” cyclones operating under a variety of conditions. In the validation of the model, deviations between the predicted and measured values were lower than 34% for feed slurry flowrate, less than 22% for corrected cut size and less than 18% for short-circuit for underflow.

Oct 3, 2019

By Susanna G. de Jager, Francis W. Petersen

"To enable the prediction of reagents suitable for fine coal flotation, it is necessary to develop a methodology applicable to different South African coal types. Statistical confirmation of the applicability of this methodology is important to avoid recommendation of reagents on a trial and error basis.The study included 5 coal samples from different collieries and included Highveld seam 3 and 4 coal (as one sample), Waterberg coal (zone 10 -11), Highveld seam 5 upper coal and Witbank seam 2 and seam 4 coal. Seam 3 and 4 (mixture) coal, Waterberg and the seam 5 upper coal were all found to be vitrinite rich coals. The coal characterisation study included petrographic analysis, proximate analysis, float-sink analysis, oxygen-containing functional groups, surface extraction, flotation release analysis and contact angle measurements. Flotation tests were used to validate expectations from the characterisation of the coal samples.RESULTSThe flotation data indicated that all of the coal samples were amendable to froth flotation. The best results were obtained with the Witbank seam 2 coal and the poorest flotation with Syferfontein seam 5 coal. The flotation tests showed that the best reagents to float all of the coal samples studied were iso-decanol and dodecene. These reagents produced flotation products that were near to the release curve, which are the optimum flotation results (obtained when using iso-paraffin as collector). Dodecene resulted in low ash products and iso-decanol in high yield products."

Jan 1, 2003

By Charles E. Reed

With the increasing importance of clay in drilling operations which demand more precise and exacting control over its behavior, there has come the realization that most of our present methods of control over many of its important properties still represent more of an art than a science. Such a situation with respect to a material of such industrial significance is unfortunate, and naturally many investigations have been conducted to improve our knowledge. In general, these investigations have revealed the complex nature of clay behavior and while sometimes they may not have seemed to contribute directly to a solution of the field operator's problems they have been of inestimable importance in bringing to light the broad fundamental scientific principles upon which must be based any effective working theory correlating the known facts of clay behavior and predicting profitable new lines of attack for its improvement. Major Facts Concerning Behavior of Clays In the study of clays, as in that of most other colloidal materials, it has been impossible to make progress by the study of isolated facts. On the other hand, analysis of large groups of facts, many of which seem at first completely unrelated, can lead to a deeper insight into the structure of clays and the mechanism of their behavior. It will be well to list the major facts on which the analysis here presented is based, starting with those that have emerged repeatedly from past investigations and which thereby constitute an impregnable foundation upon which must rest any comprehensive theory of clay behavior: 1. Clays consist of hydrated aluminosilicates of extremely fine and variable particle size. 2. Suspended in water, clays exhibit variable degrees of swelling, depending upon their origin and upon the chemical and colloidal nature of any other substances present. The magnitude of the swelling is a direct indication of the extent to which the clay has become dispersed.

Jan 1, 1938

By R. Karl Zipf, David Newman

The objective of this is paper is to review the current state of knowledge and practice in highwall mining (HWM). HWM has become a widely-applied method in surface mining, commonly used alone or in conjunction with contour or slot mining. It provides 800-feet to 1,200-feet of additional recovery when the economic stripping ratio is reached in contour mining or in slot mining when surface access to a reserve is limited. A significant attribute of the highwall miner is its versatility. HWM has been used successfully to mine abandoned pre-reclamation law highwalls, points or ridges uneconomic to mine by underground or other surface methods, outcrop barriers left adjacent to underground mines, separate benches of the same seam where the parting thickness or quality differences between benches render complete extraction uneconomic, previously augered areas containing otherwise inaccessible additional reserves and close or widely spaced multiple seams. The theory and design methods to assess roof, pillar, and floor stability are presented followed by three case histories. Simple design charts for sizing HWM web and barrier pillars are also presented. A recommended web pillar width may be obtained from the design charts given the overburden depth, the HWM cut width, and the mining height. Given the depth and panel width for a set of HWM cuts, another set of charts gives a suggested barrier pillar width. The case histories, from Northern and Southern Appalachia are used to illustrate the application of rock mechanics to quantify the stability of the highwall, roof, web pillars, and floor. The case histories involve 1) mining through a previously augered highwall, 2) mining under back-stacked spoil and 3) selective mining of closely spaced benches of the same seam. Because each site is unique, the appropriate pre-mining geotechnical analyses range from the calculation of roof, web pillar, and floor bearing capacity stability factors to detailed numerical modeling of the auger and underground mine workings. When operating in the vicinity of existing underground mine or auger workings, the determination of ground deformation and strains resulting from highwall mining is a necessary facet of a ground control investigation.

By John G. Parker

Many of the so-called minor metals are derived as byproducts from the processing of lead and zinc concentrates in which they occur as minor constituents. Concentrates from some lead-zinc mineral deposits are more enriched in metals such as cadmium, arsenic, bismuth, silver, and selenium than are others, and these sources offer a continuing, assured supply of certain of these metals. Despite the age of the data collected, the Bureau of Mines feels it to be highly desirable to publish due to its relevance to the objective of the study which was to ascertain the flow of minor metals from certain smelter feeds Efforts to trace these metals through the complicated lead and zinc processing steps included trying to ascertain losses and mode of loss of these metals. Losses of some metals in processing may be surmised as occurring in gaseous and other emissions, or possibly in slags and residues.

Jan 1, 1979

By Somerville M, Muray A, Bocking M

Australia has an extremely large total hot dry rock (HDR) resource above a depth of 5 km, equivalent to 7500 times its present annual energy consumption, of which 80 per cent underlies the Great Artesian Basin. The resources most likely to be exploited first are those residing in homogeneous granitic bodies beneath sedimentary basins containing insulating rocks such as shales and coal measures. In the Sydney Basin south of Muswellbrook, an area of high geothermal gradient corresponds to a gravity low thought to be a buried granite body at a temperature of possibly 250¦C. This locality is suspected to have the ideal geological characteristics for Australia's first hot rock test facility. Australia's high HDR potential is possibly unique in the world, in that the potential sites satisfy four independent, geological conditions, each considered as favourable for the creation of a resource, and for the ease of extracting that resource. They are: ò Higher crustal heat generating capacity than that of normal continental crust. ò Much of the Australian continent is covered by sedimentary basins which contain a high proportion of shales and coal measures that have low thermal conductivities, thus providing an insulating blanket for the heat being generated beneath. ò The sedimentary basins are in many places underlain by large untectonised granitic bodies that are not only a major contributor to heat generation, but also ideally suited to the establishment of HDR reservoirs. ò The crustal shortening stress field that is found in the majority of the Australian continental crust results in a vertical minimum principal stress orientation which should result in the development of favourably oriented horizontal stimulation cells necessary for maximising an HDR resource.

Jan 1, 1995

By Anthony (Sam) J. S. Spearing

Backfilling using coal waste is not a novel means for waste disposal throughout the world; yet, backfilling using a high density (paste) backfill is relatively new, except in Germany and Poland. One of the main benefits of a high density backfill, as opposed to a low density (slurry) backfill, is that, if placed at a low permeability and low moisture content, the risk of water table contamination can be relatively low. In addition, if paste backfill can be placed cost effectively, environmental benefits are huge because the surface impoundment footprint can be greatly reduced or even eliminated. This is especially true in room-and-pillar applications. In its current state, backfilling is considerably more costly than surface disposal. This is mainly because paste, as opposed to slurry, significantly increases backfill placement costs; however, this could be offset by increasing the achievable extraction rate. Overall, such a system could potentially improve the public?s image of coal mining in the US for a myriad of reasons. This paper discusses a proposed backfill system for a typical room-and-pillar coal mine in the Illinois Basin of the US and clearly shows the technical advantages, although costs are still higher with fill. The cost differential will likely reduce over time, in favor of the backfill option, as costs of traditional surface disposal increase, due mainly to ever-restrictive disposal regulations.

Jan 1, 2013

By A. T. Iannacchione

Underground limestone mines typically use the room-and-pillar method of mining in the generally flat-lying limestone formations. In some cases the dip may exceed 5° which can result in unique roof instability problems. Stability may be further exacerbated by the presence of horizontal tectonic stresses. Field studies and numerical model analyses are combined to assess the affect of the dip in various stress conditions. The results showed that where the horizontal tectonic stresses are sufficient to cause intact rock failure, increasing dip results in increased failure potential. The effect of the dip is greater when the maximum horizontal stress is parallel to the dip. Two case studies are presented and evaluated against the findings of stress analysis results. The study showed that the empirical rules of orienting headings parallel to the maximum stress are generally applicable to dipping excavations, except when mining in the up-dip direction. The importance of accurately determining the orientation of the maximum horizontal stress is emphasized because the window of favorable orientations relative to the stress is small.

By Harumasa Kurokawa

Since the initial start-up, the Toyo Smelter & Refinery has been operating in harmony with the ambient environment, and improvements have been implemented with technologies specifically developed for further protecting the environment. Toyo Smelter & Refinery is now planning to increase the copper production capacity from 280,000 tpy to 450,000 tpy, over a period of several years. In 2003, the first step of this smelter expansion and modernization plan was implemented. The production capacity of the P-S converter was increased dramatically, as it became possible to operate under a ?2 hot-2 blowing? schedule. In 2005, an additional converter will be installed, in order to allow operation under a ?3 hot-2 blowing? schedule. This report will describe the technical improvements on the P-S converters, as well as describe the Toyo expansion program and discuss the technologies applied to the fugitive gas collecting system.

Jan 1, 2005

By W. Hume-Rothery

IN recent interesting papers,1,2 Bardos et al. have described ternary Laves phases of the type A2(BsSi) and A4(B5Si3) where A = titanium vanadium, niobium, and so forth, and B = manganese, iron, cobalt, or nickel; other more complex formulae have also been established. In these phases, silicon plays the part of the smaller B atom of a Laves phase AB2, and the interatomic distances show that the effec- tive silicon radii lie between 1.16 and 1.21Å, and are thus very much smaller than the metallic radius of silicon for CN = 12. It does not seem to have been pointed out that these small atomic radii are almost the sape as the normal covalent radius of silicon (1.174Å). If, therefore, silicon acts as an acceptor of electrons as suggested by Bardos et al.,1 it appears to do so, not by the building up of a negatively charged silicon ion which would be large, but by the formation of what are very nearly or may be actually normal covalent bonds. Since a covalent bond contains two electrons, its formation would reduce the number of electrons available for bonding in other parts of the structure, and in this way the effect of silicon in stabilizing the o phase at high electron concentrations might be understood.

Jan 1, 1965

By Nicholas Adrian Barcza

"What affects and influences one’s perspective of the mining and metallurgical industries?One’s perspective of the industry we work in changes over time as a function of our experience as well as from the interaction we have with colleagues locally and probably even more so with those internationally. Furthermore, the ever-changing environment continues to impact the context in which one sees things. Living mostly in South Africa through its changes in the past fi fty years but also having the opportunity to travel extensively and work on projects abroad adds an invaluable richness to this more global perspective. One of the greatest challenges is how best to use this experience to endeavour to support the many potential opportunities in southern as well as sub-Saharan Africa. However, one has also to face the realities of how the best interests of the country and its peoples are sadly often not well served for various unfortunate reasons. Investment, education, regional stability, and good governance are some of the most critical considerations for the prosperity and survival of the region.The mining and metallurgical industry in southern and sub-Saharan Africa changed significantly during the post-colonial and apartheid eras as a result of global and regional developments that have impacted the ownership of businesses, the technologies used, and products produced in a manner that was not envisaged even fi fty years ago. Southern Africa’s mining and metallurgical industry has progressed from one based mostly on diamonds and gold in the late 19th century to a much more diverse one that involves the production of a variety of other precious, base, and ferrous metals and minerals as well as coal and industrial minerals. The infrastructure and manufacturing capacity was largely developed to meet the needs of this industry during its growth phases, but even though the dynamics have changed there is still a need for more efficient and effective support systems in the region."

Jul 1, 2019

Leaving the relatively simple life on a uni student and venturing off in to the outside working world is a big step. There are two paths to follow, the æContikiÆ style graduate program where you pick up your new lease vehicle and set forth on two to three years of planned activities, or can pack everything into one bag, stick a copy of æthe rough guideÆ in your pocket, and set off on your own graduate adventure. I took the path less travelled.The less followed method of developing yourself isnÆt for everybody. Parts of the journey are difficult and sometimes it feels hopeless, but itÆs all a learning experience. Along the way you might not get to all the graduate ætourist stopsÆ like dragline, truck-shovel, or drill and blast. But youÆll see most of them and pick up a lot more of the local culture such as people management, operational knowledge, quality control, and the black arts of project financial management.

Jan 1, 2004

By A. Kapoor, L. Morin, S. Mortazavi, P. Béedard, Gould. W. D., A. Kuiper

The degradation of thiocyanate in a simulated gold mill effluent was studied using a laboratory scale rotating biological contactor (RBC). Complete SCN- removal was obtained at temperatures of 8 and 12°C, and a hydraulic retention time of approximately 3.3 h. The NH4+ produced by thiocyanate hydrolysis was oxidized by nitrifying bacteria to NO2 and NO3-. The HS- produced by thiocyanate hydrolysis was chemically and biologically oxidized to elemental S, which was subsequently biologically oxidized to sulfate. Incomplete sulfur oxidation occurred in the RBC, particularly at 8°C and elemental sulfur deposition was observed on the RBC disks. The RBC feed exhibited toxicity to rainbow trout but the RBC was effective in removing the acute toxicity of thiocyanate.

Jan 1, 2005

By W. L. Korbee, P. Hazebroek, M. Prats, E. E. Allen, C. A. 225-000-000-017 Verbraak, H. C. van Elst

In a recent paper,' one of us has presented some experimental evidence on the relationship between twinning and brittle fracture in steel. From metallographic examinations of brittle fracture it could be derived that mechanical twins and microcracks are formed already in front of a running brittle fracture. A tentative explanation based on the evaluation of the statistical distribution of mechanical twins vs various angles to the fracture was given in the above mentioned paper. It was suggested that these twins are caused by stress waves emitted by a running brittle fracture. With the aid of high-speed photography and the use of photo-stress sheet we are now able to study in more detail the propagation of a brittle fracture and the emittance of stress waves connected with fracture. A typical example is given in Fig. 1. In this figure a running brittle fracture in an ordinary Thomas steel is shown. The experiment was performed on a Robertson apparatus and the stress waves caused by the fracture were made visible with photo-stress

Jan 1, 1962

By N. F. Dawson

Recovery of a chromite concentrate from UG2 flotation tailings streams, of a grade suitable for further pyrometallurgical treatment for the production of ferrochrome, has certain specific challenges not only by virtue of the decoupled nature of the primary PGM recovery process and secondary gravity based chromite recovery circuits, but also because of intrinsic variations in the nature of the ore and its mineral composition. Variability in the ore, together with upstream process dynamics, creates a challenging environment in which to achieve optimal recovery of a gravity concentrate with accurate grade control. This paper examines certain inter-relational aspects between the ore gangue and chromite mineral types, the influence of the primary PGM extraction circuit and secondary chromite extraction activity as applied specifically to UG2 ore against a background of actual plant experiences and circuit configurations applied in order achieve a suitable quality of chromite concentrate.

Jan 1, 2010

By L. Shevenell

Nevada now has, or will have, 35 pit lakes resulting from open-pit mining below the water table. State regulators are requiring that the ultimate pit lake water quality be predicted as part of the permit application process. Water balances/pit lake filling rates must be esti¬mated in support of the geochemical modeling. In Nevada, analytical and numerical methods have been employed for the study of pit lakes. In the current work, analytical solutions are investigated for one pit lake, the Getchell south pit lake, which previously filled be¬tween 1968 and 1982 during a hiatus in mining. Water levels vs. time are available for this lake and these data have been fitted with a hyperbolic curve. This water-level-vs.-time curve was used in simple water-balance computations to find the net inflow rates by forcing computed water levels and volumes to match those of the known water levels and volumes through time. The model described here provides realistic volume fluxes into and out of the lake on a monthly basis as the pit lake filled.

Jan 1, 2000