Search Documents

Effective strata control, utilising fully encapsulated roof bolts, is dependent on the installed quality of the reinforcement elements. One mechanism by which fully encapsulated roof bolts may become less than fully effective is by gloving (glove fingering) and un-mixing of the resin. Following some small roof failures containing gloved bolts, investigations have been undertaken in some New Zealand coal mines to determine the extent of, and mechanisms involved in, the gloving of fully encapsulated roof bolts for a range of roof types and installation methods. Gloving, in this context, refers to the resin cartridge partially or completely enveloping a length of the bolt, typically with unmixed resin filler and catalyst/hardener remaining within the cartridge. Results have shown that gloving and un-mixing is a systematic and widespread phenomena, occurring across a range of resin and/or bolt manufacturers, and across a variety of roof types. Gloving was found in bolts installed using: hand held pneumatic and continuous miner mounted hydraulic methods, under run of mine (ROM) conditions by mine workers, and under controlled "best practice" conditions. The roofs bolts investigated are all 1800mm (6ft) long, and have shown that, on average, 485mm (-19") of the bolt length is gloved and/or unmixed. This equates to a 27 percent reduction in effective bolt length. The effected length of bolt is sufficient to impact on the load transfer/reinforcement capabilities of the bolt system, and hence impacts on the design assumptions and subsequent stability assessments. Furthermore, there is a direct relationship between the mechanism for the gloving of bolts and an increased occurrence of resin loss and reduction in encapsulations length in soft (less than 10 MPa) and/or highly fractured rock. Investigations have concentrated on developing an understanding of the mechanisms involved. This has been undertaken using both field installations and recovered bolts, as well as test bench trials. The mechanisms involved have been confirmed as being: the development of a pressure front as the bolt encounters the resin and is spun up the hole, which, in turn, leads to over-pressurisation and radial expansion of the resin cartridge, resulting in an increase in diameter of the plastic resin cartridge, which allows the bolt to be spun up into the cartridge without making sufficient contact to shred the cartridge or the hardener tube, resulting in an unmixed portion of resin.

Jan 1, 2003

By D. Jamróz, A. Surowiak, T. Niedoba, P. Pieta

"The separation of coal material of three types of coals originating from three various Polish hard coal mines (types 31, 34.2 and 35, according to Polish nomenclature, which were steam coal, semi-coking coal and coking coal) into particle size fractions and then into particle density fractions was done and then the following parameters were measured for each particle size-density fraction: combustion heat, ash contents, sulfur contents, volatile parts contents, analytic moisture. In this way a 7-dimensional vector of data was created. Using methods of factor analysis the important features of coal were selected, which decide about their membership to individual types. To evaluate the appropriateness of the applied method the Bartlett’s sphericity test as well coefficient of Kaiser-Mayer-Olkin (KMO) were used. To select important factors the Kaiser criterion and Cattell’s scree test were used. The obtained results were compared with the results obtained in previous works by means of observation tunnels method. The results showed which particular features are crucial to define the type of coal what is also important to select appropriate method of its enrichment.INTRODUCTION Coal extracted from the mine is often a mixture of coals of various quality originating, for example, from various coal layers. One of the most important issues is to determine its quality, what means to verify if it fulfills certain requirements. Usually, such parameters as combustion heat, ash contents, sulfur contents, volatile parts contents and analytic moisture decide what the coal quality is (Drzymala, 2009). Such investigations are expensive and time consuming. That is why it seems to be important to determine the mutual connections and interactions between them what would make possible to reduce the amount of the necessary parameters. This issue was already investigated with successes in several works [Jamróz and Niedoba, 2013; 2014; Niedoba, 2015]. This work is another approach to this problem. Here, the investigation of possible reduction of researched parameters was done on the basis of the factor analysis. The obtained results confirm the earlier observations."

Jan 1, 2018

By D McB Martin, A Piechocka, M Jessell, M Lindsay, E Ramanaidou

The Hamersley Basin of Western Australia, approximately 500 km long by 200 km wide, is recognised globally for its rich endowment of iron ore resources. Two types of bedded iron ore mineralisation are recognised: the Proterozoic hypogene martite-microplaty hematite ores; and the more recent Cenozoic supergene martite-goethite ores. Exploration strategies depend on the style of mineralisation being targeted; however, stratigraphy and structure are fundamental controls on both ore types. Therefore, the ability to visualise the 3D geology of the entire basin is critical for the understanding of iron ore occurrences and their relationship to ore genesis of bedded iron ore mineralisation. However, due to the large size of the basin, generating a 3D geological model of the regional stratigraphy and structure has not been possible, or prioritised, primarily due to software limitations. Recent advances in implicit automated geological modelling presents an ideal opportunity to develop a 3D model of the entire Hamersley Basin. The innovative Loop software was used to model open source geological data (ie geological mapping, outcrop orientation data, and fault data) sourced from the Geological Survey of Western Australia. In addition to generating a 3D geological model, information such as stratigraphic thickness and fault offset information was extracted using the map2loop module and demonstrated its application to exploration targeting. This study demonstrates how a basin-wide 3D geological model was used to conduct a regional structural analysis of the Hamersley Basin. The results of this study provide opportunities for other prospective regions to be rapidly modelled in order to enhance the understanding of the geology and improve exploration targeting.

Nov 8, 2021

NIOSH is conducting research to reduce the silica dust exposure of workers at surface coal mines. One goal of this research is to evaluate the relationship between drilling parameters, rock strata and silica dust generation. This study involved measuring blast hole emission dust from a rotary drill rig which required sampling high concentration dust (>400 mg/m3) for silica content in a high velocity airstream. To measure dust initially, traditional sampling methods using personal sampling instruments were attempted in and around the shroud area of the drill with no success. Variations in the dust cloud concentrations under the shroud, the condition of the shroud and its orientation over the hole, and ambient air conditions prevented consistent and accurate dust measurements from being obtained. Amore consistent dust cloud is necessary for accurate measurements. An area of the drill’s dust collector system that consistently draws the emitted airborne dust from the hole is the collector tube. This tube connects the drill collector’s vacuum and dust filtration system to the shroud area. Assuming the collector system is working as designed, sampling from the collector tube would enable more consistent and accurate samples to be taken. However, current personal samplers are unable to sample in the concentrations and velocities experienced in the collector tube, so another method had to be devised. To achieve the desired results, an in-stack cascade cyclone was used. Preliminary field testing shows positive results.

Jan 1, 2003

By M. Karmis

For several centuries surface subsidence has been recognized as an inevitable consequence of most underground mining. In fact, British court records of disputes and litigations related to property damage due to mining subsidence can be traced to the early fifteenth century (Shadbolt, 1978). The first systematic investigations of the mechanisms involved in mining subsidence can be credited to Belgian Mining Engineers. The re- search effort was initiated after the widespread movements and the resulting structural damages suffered by the City of Liege in the 1920's. The publication of Gonot's 1871 treatise "Loie de la NomZ" (normal theory) was one of the most not- able achievements of the Belgian school of that era (Gonot, 1871). During the past 100 years the phenomenon of mining subsidence has been the subject of intensive research, particularly in Europe where long- wall is the most common method of underground coal mining. Many theories have been advanced to explain the mechanism of ground movement as it develops from the excavation, through the superincumbent strata, to the surface. Such theories include the original concepts of beams, arches, domes and the contemporary mathematical modeling principles of strata movement assuming two extreme concepts-- a continuous elastic medium and a stochastic medium for the superincumbent strata. An excellent review of the development of these theories ?-s given by Shadbolt (Shadbolt, 1978). In conjunction with the theories of mass strata movement in the vicinity of mine workings, the subject of surface subsidence predictions has also been the subject of extensive research. The development of reliable and rational techniques of subsidence prediction is imperative, if this phenomenon is to be recognized and controlled within acceptable environmental levels. Empirical as well as mathematical methods have been proposed to fulfill this objective and a comprehensive analysis of these methods has been presented in the literature (Bramer, 1973; Shad- bolt, 1978; Virginia Polytechnic Institute and State University, 1980). As a result of this intensive research effort, it is now accepted in many )coal fields-- mainly in Europe-- that the state of art in subsidence prediction and control has approached a level where mining induced surface displacements can be predicted to a suggested accuracy of less than + 20 percent. Furthermore, such movements can be translated into anticipated structural failures using established damage criteria, thus enabling appropriate precautionary measures to be implemented. In this country, subsidence is rapidly gaining emphasis as an important environmental problem of underground coal mining. Damage resulting from this phenomenon ranges from land settlement to severe structural damage and has been witnessed in rural (Illinois, Colorado, West Virginia, Virginia, Pennsylvania) as well as in urban areas (Pennsylvania, West Virginia, Illinois, Wyoming). Yet, the art of subsidence prediction and hence control in this country, for both longwall and room-and-pillar coal mining, is far from approaching the maturity reached by the Europeans. In this paper, field measurments and computer modeling techniques have been used to develop some basic relationships of longwall subsidence and its related parameters. Because the objective of this study was to develop regional subsidence trends, all processed information pertains to the Appalachian coal region.

Jan 1, 1981

By Mohammad Ranjbar Hamghavandi, Mohammad Ranjbar, Zahra Manafi, Mohammad Hassan Fazaelipoor, Mahin Schaffie

The present study introduces a new approach to understand the copper dissolution rate and to find an adapted mathematical statement for particle shrinkage rate in a batch bioleaching system. Four size classes of a chalcopyrite concentrate, namely [D1 : (−54 + 44)μm, D2 : (−44 + 38)μm, D3 : (−38 + 25)μm and D4 : (−25)μm], were used in the batch bioleaching tests by applying a mixed culture of moderately thermophilic microorganisms. The pulp density and temperature were 8 (%w/v) and 50 °C, respectively. Findings delineated that the bioleaching time can be divided into two specific time intervals: first, the surface reactions were the prevailing controlling step; second, the prevailing mechanism was diffusion through the product layer, whereas the overall rate of the process may be related to both through a Q factor using a mixed model. A mathematical model was developed based on particle size distribution (PSD) and a kinetic model. Experimental validation of the mixed model was accomplished by the representative sample with d80 = 54 microns. Results showed that the PSD of the specific sample was in good agreement with Rosin–Rammler function. Besides, the simulation result of the conversion fraction had the best conformity with the experimental data (with a maximum error of approximately 7%). This paper should be considered as an initial part of a larger, global model for chalcopyrite concentrate bioleaching.

By Eric Toh, Michel David

"Geo-statistics was born from mining problems: grades not being what was expected; more tons of waste than expected; in other words, dilution. Geo-statisticians now claim to have solved many of these problems, but the solutions seem to have a hard time being picked up by practitionners. One of the reasons may be the jargon which geo-statisticians are using. The reason for jargon is that obtaining solutions required a strict formulation in a statistical framework. Practicing mining engineers and geologists are not used to such a framework, and they are not familiar with the jargon. In this paper, the authors re-examine dilution in operating mines and answer two extremely practical problems, using practical language as much as possible. Can dilution be reduced by improving the quality of blast hole samples? How many samples are needed to obtain a good ore-waste discrimination, i.e. to reduce dilution to acceptable levels? Citing real situations, this paper will try to show how fairly simple concepts can be used to answer both problems. It will try to present the solut ions using a minimum of jargon, even if the theoretical solution could be obtained in a few precisely worded paragraphs.The two problems considered are the following: the first one was encountered in the Panguna deposit of Bougainville Copper Limited, P.N .G., but it occurs in every open pit operation where selective mining is required. As the cut-off is lowered, more and more mining occurs in marginal areas. Grade control is mostly based on the grades obtained from blast holes, hence, it is essential that the quality of the blast hole samples be as good as possible in order to reduce dilution, waste being sent to the mill and ore being sent to the waste dump.The second example stemmed from the grade control technique used in many gold open-pit operations in Western Australia: channels are cut on lines 5 m apart and assays are taken every metre. The pattern in the same regardless of rock type, whether one is in the oxidized zone or not. The number of samples to be treated is enormous, hence, the question arises how to find an acceptable sampling grid, and whether changing it can reduce dilution at an acceptable cost.A solution will be given to each problem separately, although in fact it could be seen that the formal framework is the same in both situations."

Jan 1, 1989

By Thomas J. Peters

In 1987, at the request of the U.S. Bureau of Land Management, the U.S. Bureau of Mines studied the 15,174-acre Sleeping Giant study area, including the 6,112-acre Wilderness Study Area (MT-075-111), in order to evaluate its identified mineral resources. The study area is located in Lewis and Clark County, MT, about 30 miles north of Helena. Sleeping Giant Mountain trends west-northwest from the Missouri to the eastern crest of Little Prickly Pear Canyon (the route of Interstate 15), and has several summits over 6,000 ft. Geologically, the area is in the Disturbed Belt, and a large block of Middle Precambrian metasedimentary siltstone and underlying shale has been thrust northeast over younger, sedimentdry volcanic and intrusive rocks.

Jan 1, 1988

By Kazuki Morita

A new route to produce solar grade silicon (SOG-Si 6N) from metallurgical grade (MG-Si 98%) has been developed in Japan, which may satisfy the increasing demand for solar cells in the near future. Since some elements such as P and B have very large segregation coefficients, solidification refining is not effective for their removal and costly processes, such as electron beam vacuum melting and oxidation plasma refining, are required. According to our previous results which showed the effectiveness of leaching procedure with Ca addition for Fe and Ti removal, possibility of P and B removal by acid leaching was focused expecting that their affinities for Ca in molten silicon might be considerable. Hence, the effects of Ca addition on the thennodynamic properties of P and B in molten silicon alloys have been investigated for overall control and optimization of the SOG-Si production process in the present study. The interaction parameters between Ca and P, and Ca and B were determined by chemical equilibration techniques at 1723 K. Although the interaction parameter between Ca and B was slightly negative, that between Ca and P showed a large negative value. Also, the results for the leaching test with various amount of Ca addition revealed that the removal fractions of both elements, especially P, drastically increased with increase in the Ca content, which showed very good agreement with the prediction from the interaction parameters derived in the present work. The present results suggest that the preliminary leaching procedure can reduce the processing time and energy for SOG-Si refining. Keywords: Silicon, Solar Cell, Refining, Acid Leaching, Thennodynamics. Interaction, Phosphorus, Boron, Calcium

Jan 1, 2003

By A. J. Russell

"This paper investigates why it is critical for a mine to accurately determine thermal rock properties and virgin rock temperatures. Theoretical simulations of deep mining production zones have demonstrated that thermal conductivity (k), virgin rock temperatures and specific heat (cp) significantly impact rock heat predictions which can be the dominant component of a mine’s heat load. Natural variability in these factors showed that realistic errors can have a significant effect on mine heat loads. This can ultimately affect miner safety and introduces risk to the viability and sustainability of a project. INTRODUCTION Accurate heat load determinations are critical to ensure that underground working conditions are maintained within legislated and mine specific parameters to safeguard the safety and productivity of employees. Underpredicting mine heat loads will result in hot underground conditions, which risk the health and safety of employees, reduce the productivity of employees or stop production if legislated temperatures in working areas are exceeded. Overestimating mine heat loads will result in increased capital and operating costs reducing the viability of the project. Over- or under- predicting the heat load for a project will increase the project risk. Heat sources in a mine can broadly be broken into two categories. These two categories are defined by Hemp and Rawlins (2014) as natural and artificial heat sources. Those sources which depend on the size, location and depth of the mining areas are defined as natural heat sources, whereas those heat sources which are a result of the actual mining activities are defined as artificial heat sources. Autocompression, or the conversion of potential energy, to enthalpy is an important consideration when determining the air temperature in the mine and its interaction with natural and artificial heat sources. It is documented by Jones (1985) and Hemp and Rawlins (2014), that the heat flow from rock in deep mines can dominate other heat sources; information from BBE’s archives show that this is between 40% and 60% of the total heat load. They also point out the importance of accurately measuring both the thermal rock properties and virgin rock temperatures (VRTs) for determining and planning the ventilation and refrigeration requirements for a mine. Both of these texts cite multiple methods for calculating the heat-flux and ultimately the heat load for the different working areas in a mine. All of these methods demonstrate that the heat flux and heat load will increase proportionally with increased thermal conductivity (k), specific heat (cp) of the rock or mineral, and VRT depending the area of the mine or mining method."

Jan 1, 2019

By William P. Blake

In view of the present exposition at Atlanta, and the timely meeting of the Institute in that city, and the expressed desire of the Council for contributions to the knowledge of the mineral resources of the Southern States, I may be permitted to offer some desultory notes upon the subject, chiefly in the form

Jan 1, 1896

By Richard L. Rains

The 15,770-acre Worm Creek Roadless Study Area is in southeastern Idaho about 8 miles (mi) west of the northern portion of Bear Lake. U.S. Bureau of Mines personnel examined the roadless, area during the summer of 1984. No mineral resources were identified within the study area. There were no mines or mining claims in the study area in 1984. However, the study area is blanketed with oil and gas leases, but no known productive horizons have been identified within nor nearby. The roadless area is in the Cordilleran fold-thrust belt and is underlain by Paleozoic and Mesozoic marine strata more than 50,000 feet thick. The trace of the Paris thrust fault is 2 to 3 mi east of the study area and has an eastward displacement of about 4 to 7 mi.

Jan 1, 1985

By Vi-Duong Dang

Lithium requirements in the next few decades for batteries and controlled thermonuclear fusion reactors (CTR) may exceed the availability of the current mineral and brine reserves. It is thus prudent to search for new reserves and resources to satisfy these and future lithium applications. The lithium content of the waters from the Smackover oil field. located in the Gulf Coast region of the United States, ranges from 100 to 500 mp/l and could represent a substantial new reserve. Experimental evidence described in the literature indicates that a specific chelating agent dipivaloylmethane (DPM), of the diketone type, has a specific selectivity toward lithium in the presence of other metal ions in aqueous solutions. Based in part on this unique property of dipivaloylmethane, a conceptual design of a full-size plant to extract lithium from the Smackover brine is presented in this paper. This study includes alternate flow-sheet development, design information on the major units of the process, energy requirements, and an economic analysis of a facility capable of producing 106 kg of lithium per year. The economics of three different process concepts depend primarily on the amount of water needing to be evaporated from the initial oil-field feed waters in concentrating the brine. The results, as a function of production rates, are indicated only in a general manner.

Jan 1, 1978

By Adriana de Aquino Soeiro da Silva, Joao Alves Sampaioa, Luiz Carlos Bertolino, Francisco Manoel Garrido, Marta Eloisa Medeiros

"Brazil has a large agricultural potential and its production success is related to the chemicaland physical soil characteristics. Therefore, the demand in the use of a great quantity offertilizers to compensate the low amount of nutrients in the soil includes about 40% of foodproduction costs. In order to develop economical alternatives to traditional fertilizers, rockswith potential use in agriculture will be studied. In this work the potassium rock, a greensandslate, will be chemically and structurally characterized for the development of a potassiumthermophosphate. This alternative fertilizer will be obtained based on a fusion of a ponderedmixture of potassium, magnesium and phosphate rocks to be applied in the Brazilianagriculture. Preliminary characterization results indicate that the greensand slate presents ahigh percentage of glauconite, quartz and micas.Keywords: Potassium thermophosphate, alternative fertilizers, greensand slate.IntroductionBrazil has a great agricultural potential and its production success is closely related to thesoil's chemical and physical characteristics. However, the country's soils present lownutrients content and high acidity due to weather conditions. Thus, the use of a high amountof fertilizers makes up for the soils' lack of nutrients and accounts for 40% of food productioncosts. Therefore, research on obtaining new alternative fertilizers is a constant worry due tothe increase on food demand [ 1].The lack of raw material for the preparation of NPK fertilizers in Brazil is a concern and theissue of potassium fertilizers a priority. Such a fact is because in 2008 only 608.000 tons ofKCl were produced, corresponding to just 10% of the Brazilian necessity. Thus, the use ofrocks as agricultural nutrients can contribute to reduce the need for industrial fertilizers.This way, the development of a new agricultural raw material originated from a rock thatalready exists in the country's soil is of great importance for the mineral and agriculturalsectors."

Jan 1, 2011

By B. C. Craft, T. J. Johnson, H. L. Kirkpatrick

Petroleum engineers are displaying considerable interest in the problems of cementing oil wells, especially in the Gulf Coast and California areas, where steep temperature gradients are encountered and where wells are being drilled to greater depths. Deep drilling, that is, at depths in excess of 7000 ft., has been undertaken in these areas only in the last few years and with this trend oil-well cementing requires more technical treatment. It is not the purpose of this paper to describe the scope and application of cement operations in the oil industry or to give the standard specifications, methods of sampling and testing of portland cement. The various testing methods have been described by the American Society for Testing Materials1, Uren2, Tickell and Wankowski3 and Rakestraw and Parsons4. The latter authors (pp. 50-58) have also described in detail the methods of cementing. The authors realize that it is impossible to reproduce in the laboratory the scale of forces and dimensions that exist at great depths, but an attempt has been made to scale down these dimensions proportionally. The selection of problems to be studied was based largely upon the practical questions asked by several of the largest operators in these fields. All cements used in these experiments met the specifications of the American Society for Testing Materials.

Jan 1, 1935

By Roy A. Koski

INTRODUCTION Cleveland-Cliffs Iron Company, and its subsidiary companies, operate and manage mining, beneficiation, and pelletizing operations in the Upper Peninsula of Michigan, the province of Ontario, Canada, and the State of Western Australia, Australia. The concentrates and natural ores vary mineralogically, physically and chemically. This paper describes the techniques employed in pelletizing the various concentrates and ore fines. The plant operations described are the Republic, Humboldt, Tilden, Empire and Pioneer in Michigan, the Adams and Sherman in Ontario, and the Robe River in Western Australia. Table 1 contains further details regarding design and operating capacities, commissioning dates, and participant ownerships. Allis-Chalmers grate-kiln systems are utilized in Michigan and Ontario, and Dravo straight-grate systems in Western Australia. Currently, the Empire and Tilden operations are being expanded. At Empire the additional pelletizing unit, identified as Unit IV, will have a design capacity of 8 996 metric tonne/d and is scheduled for startup May 1, 1979. The Tilden operation is being doubled with the additional pelletizing unit, identified as Unit 11, having a de- sign capacity of 12 599 metric tonne/d. Startup is scheduled for January 1, 1980. MINERALOGY OF CONCENTRATES AND NATURAL ORES In the Upper Peninsula of Michigan, the operations process ores from the Negaunee iron formation of the Marquette Range. The

Jan 1, 1977

By Fazel G. Jahromi, Ahmad Ghahreman

"Several studies were performed on the atmospheric leaching of copper sulfide minerals in the presence of activated carbon and a new catalyst, AF 5. AF 5 is a carbon based catalyst with similar properties to those of activated carbon however much better mechanical properties. The activated carbon surface chemistry has been investigated in various studies; however the connection of the surface chemistry of activated carbon and AF 5 with the sulfide minerals during the atmospheric leaching process is not well-understood yet. Based on the surface analysis, AF 5 showed higher surface area than activated carbon (AC). Adsorption and oxidation of copper, arsenic and iron ions in the presence of different activated carbon were investigated. Adsorption properties of both catalysts were similar and 18-24% of iron, 12-18% of copper and 10% of arsenic adsorbed on the catalysts surface form 5 g/L Fe(III) and Cu(II) and 2 g/L As(III) at 80°C. In oxidation experiments, both catalysts reduced Fe(III) and Cu(II) ions and re-oxidized the reduced species in the presence of oxygen and oxidized As(III) ions. The addition of oxidizing ions can enhance the oxidation process kinetics and increase the catalytic capability of carbon.INTRODUCTION Hydrometallurgical processes of copper sulfide concentrates are under development and various different methods have been proposed to increase the atmospheric leaching rate of copper sulfide minerals. These methods include using different media, reagents, and catalysts. Among different methods, leaching of the copper sulfide minerals in the chloride media has some advantages over sulfate media. Smaller scale of operation, increased leaching rates, and lower sulfate formation are some of the benefits of the chloride leaching media over other similar media. Moreover, using ferric and cupric ions as oxidants and utilizing activated carbon as a catalyst has been proven to enhance the leaching rate of copper sulfide minerals effectively. Activated carbon (AC) and AF 5 (micro porous carbon based catalyst) are two of the most efficient and practical catalysts in copper sulfide leaching processes. AC can enhance the copper recovery of enargite in chloride media from 69% to 92% after 96 hours of leaching under the similar conditions (Jahromi & Ghahreman, 2016). It has been shown that AC at acidic pH can generate hydrogen peroxide in the presence of oxygen which can leach copper minerals (Ahmumada et al., 2002)."

Jan 1, 2017

By D. H. Turner, F. A. Crossley

The titanium-rich corner of the system Ti-Al-Si has been studied to determine the phase relationships in the temperature interval 600° to 1200°C. Metallographic examination of long time isothermally annealed specimens was the means of investigation. PART of a program on phase relations and transformation processes of titanium alloy systems included the study of the titanium-rich corner of the Ti-Al-Si system. The investigation covered ternary compositions in the range 2 to 8 pet A1 and 0.1 to 2 pet Si and binary compositions in the range 0.2 to 2 pet Si. Temperatures were in the range of 600" to 1200°C. Alloys containing 6 pet A1-0.1 to 0.5 pet Si were investigated down to 400°C. Partial vertical sections are presented for 2, 4, 6, and 8 pet Al. The Ti-Si system has been reported by Hansen et al.' It is characterized by a eutectoid decomposition, ß = ± a + Ti3Si3, at 860°C. The maximum solubility of silicon in a is reported to be about 0.5 pet at the eutectoid temperature. The solubility of silicon in 0 increases from 0.9 pet at the eutectoid temperature to approximately 3 pet at the eutectic temperature, 1330°C. Several investigations in the composition range of interest have been reported for the Ti-A1 system."' These investigations are in agreement on the phase fields, but differ to small extents on boundary positions. However, very recent, and as yet unpublished, findings" " indicate that there are perhaps two phases which occur at lower aluminum contents than the ? (TiA1) phase, and that the solubility of aluminum in a titanium is less than 6 pet. In the present investigation phase relations found are in agreement with the published literature exemplified by the work of Bumps et al.3 Therefore, it is probable that the partial system reported herein is metastable and does not represent true equilibrium. Experimental Procedure High purity Bureau of Mines titanium sponge of 103 Bhn hardness, granulated aluminum shot of 99.7 pet purity, and silicon powder of 99.8 pet purity were used in making the alloys. For the work in the range from 600" to 1200°C, 100 g ingots were prepared by arc melting. Melting losses were negligible and spot checks by chemical analysis showed good agreement between nominal and analyzed results. Nominal compositions are used throughout this paper. Ingots were forged to 3/8 in. rounds and cut into specimens for heat treatment. Isothermal anneals in the range from 600" to 900°C were preceded by solution treatment at 1000°C for 1 hr, followed by furnace cooling to the annealing temperature. Samples were sealed in evacuated Vycor bulbs for heat treatments up to 1000°C. Higher temperature anneals were done with the samples sealed in quartz bulbs under a partial pressure of argon.

Jan 1, 1959

By R. W. Snyder, W. H. Guilinger, B. S. Gottfried

Two numerical methods are presented JOT solving the equations Jor one-dimensional, multiphase /low in porous media. The case oF variable physical properties is included in the Formulation, although gravity and capillarity are ignored. Both methods are analyzed mathematically, resulting in upper and lower bounds for the ratio of time step to mesh spacing. The methods are applied to two- and three-phase waterflooding problems in laboratory-size cores, and resulting saturation and pressure distributions and production histories are presented graphically. Results oJ the tuo-phase flow problem are in agreement with the predictions of the Buckley-Leuerett theory. Several three-phase flow problems are presented which consider variations in the water injection rate and changes in the initial oil-and ujater-saturation distributions. The results are different physically from the two- phase case; however, it is shown that the Buckley-Lez~erett theory can accurately predict fluid interlace velocities and displacing-fluid frontal snturations for three-phase flow, providing the correct assumptions are made. The above solutions are used as a basis JOT et~aluuting the numerical methods with respect to machine time requirements and allowable time step for a fixed mesh spacing. INTRODUCTION Considerable progress has been made in recent years in obtaining numerical solutions of the equations for two-phase flow in porous media. Douglas, Blair and Wagner2and McEwenll present different methods for solving the one-dimensional case for incompressible fluids with capillarity (the former using finite differences, the latter with an approach based upon characteristics). Fayers and Sheldon4 and Hovanesian and Fayers8 have extended these studies to include the effects of gravity. West, Garvin and Sheldon, l4 in a pioneer paper, treat linear and radial systems with both capillarity and gravity and they also include the effects of compressibility. Douglas, Peaceman and Rachford3 consider two-dimensional, two-phase, in compressible flow with gravity and capillarity and Blair and Peaceman1 have extended this method to allow for compressible fluids. No one, however, has examined the case of three-phase flow, even for the relatively simple case of one-dimensional flow of incompressible fluids in the absence of gravity and capillarity. In obtaining a numerical technique for simulating forward in situ combustion laboratory experiments, Gottfried5 has developed a method for solving the one-dimensional, compressible flow equations with any number of flowing phases. Gravity and capillarity are not included in the formulation. The method has been used successfully, however, for two- and three-phase problems in a variable-temperature field with sources and sinks. This paper examines the algorithm of Gottfried more critically. Two numerical methods are presented for solving the one-dimensional, multi-phase flow equations with variable physical properties. Both methods are analyzed mathematically, and are used to simulate two- and three-phase waterflooding problems. The numerical solutions are then taken as a basis for comparing the utility of the methods.

Jan 1, 1967

By S. Rajendran

Gas Hydrates (Methane Hydrates) are solid, ice ? like substances composed of water and natural gas. They occur naturally in areas of the world where methane and water can combine at appropriate conditions of temperature and pressure and are found in the ocean bottom sediments and in some permafrost areas. Besides temperature and pressure, factors like bathymetry, sediment thickness, sedimentation rates, and total organic carbon content (TOC) also control gas hydrate formation in the sea. The stability of gas hydrates depends on the critical high pressure ? low temperature combination (0 - 17 bars, 0 - 25°C), which in turn dependent on the mix of gases from which the mineral is formed. As the critical parameters can be altered by deposition, erosion or slumping of sediments, formation or melting of ice cover, rise and fall of sea level and sudden temperature changes induced by tectonic activities, current flows or volcanisms, the gas hydrates tend to be very unstable. The Indian offshore is promising with the occurrence of gas hydrates in a total of about 80,000 km2 area in the bathymetry range of 700 to 3000 m as reported in the earlier surveys. A gas hydrate stability zone thickness map was prepared using bathymetry and sea bottom temperatures along the continental margins of India. This map is expected to provide the depth window while searching for the ?Bottom Simulating Reflectors? (BSR). The study indicates that a minimum water depth of 750 m is required for the formation of gas hydrates, and above which the chances for gas hydrates occurrences appear minimal despite other favourable conditions like presence of sediment rich organic content etc. Single channel seismic analog records (Gupta et al., 1998) suggests that Western Continental Margin of India (WCMI) offers greater promise with to gas hydrate occurrences, particularly with regard to the number of BSRs traced on the analog records as compared to the earlier surveys.

Jan 1, 2002