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By P. J. Harrington

The recovery and recycling of low concentration metal and other ions has traditionally been carried out using adsorption or ion exchange processes which, however, become uneconomical at higher concentrations, such as those that occur with many intermediate or waste streams where recycling is now being required. This paper describes the development of a process based on non-dispersive solvent extraction for the recovery of chromium (VI) from electroplating rinse water. During the chromium plating of steel, the concentration of chromium (VI) in the rinse bath rises to concentrations in the order of 100 mg/L when it becomes unusable and is then disposed of. The aim of this work was to investigate processes for recovery and recycling of the chromium in the rinse bath. The recovered chromium is required to be concentrated and purified before reuse. Tertiary amines have been shown capable of concentrating and purifying the chromium (VI) in solution. However, solvent extraction processes that have been applied to the recovery and reuse of metals from waste streams have had only limited success in the past, primarily because of the relatively high solvent losses when existing contacting equipment is used on low feed concentrations. Attempts to eliminate losses by immobilizing these complexing agents on substrates have not been successful. In order to control the losses and maintain specificity, a hollow fibre-contained liquid membrane has recently been trailed in a pilot plant to recover chromium from chromium plating waste streams. Details of the trial and modeling of the results are presented, and show that the level of losses is significantly reduced. However, issues relating to fouling still need to be addressed. This type of equipment has many applications in the recovery and recycling of a range of materials in the manufacturing processes.

Jan 1, 2003

By M. A. Vasina, I. A. Matveeva, E. A. Naumova, V. V. Doroshenko, N. A. Belov

"Using the calculated (Thermo-Calc software) and experimental methods (SEM, TEM, EMPA, DSC, XRD, etc.) the phase composition, structure and hardening of aluminium alloys of the Al-Ca-Zn-Mg system were studied in the following range: 2. 5%Mg, up to 10% Ca, and up to 14% Zn (wt%). Fragments of this quaternary phase diagram in the aluminium corner were constructed, including the liquidus surface, as well as some vertical sections. It was shown that the relatively large amount of zinc enters in the Ca-containing phase, which formula can be described as (Al,Zn)4Ca. An increase of Zn content leads to formation of Al4Ca primary crystals at lower concentrations of calcium. The eutectic (Al)+(Al,Zn)4Ca has a fine structure and aluminide particles are capable to spheroidization during the heat treatment at temperature 500 C. The maximal level of hardness observed on calcium containing alloys was higher than 200 HV, what gives the reason to expect good strength properties. With an example of an Al-9% Zn-2,5%Mg-3,5% Ca model experimental alloy based on the (Al)+(Al,Zn)4Ca eutectic, a principal possibility of manufacturing thin rolled sheets was demonstrated.INTRODUCTION Aluminum alloyed with calcium was first studied in 1970-80s by such authors as Piatti (1976), Moore (1978, 1980), Il'enko (1985), Swaminathan (1990), and Perez-Prado (1997) as superplastic materials. In particular, the alloy systems Al-Ca-Zn were studied (Il'enko, 1985, Swaminathan, 1990, Perez-Prado, 1997). For some time there was no new published works concerning the aluminum-calcium alloys. During the last years many works were published dedicated to the calcium alloying of magnesium alloys (Kim, 2011; Xu, 2011; Aljarrah, 2008; Bakhsheshi, 2014). This urged the authors (Belov, Naumova & Akopyan, 2016) to start studying cast and wrought aluminum-calcium alloys for construction (2008–2014). There is almost no information in the literature concerning triple and more complex diagrams of the aluminum-based system states with calcium and other elements. In recent work, parts of the state diagrams are plotted for the aluminum angle zone: Al-Ca-Mg-Sc (Belov, Naumova & Bazlova, 2016), Al-Ca-Ni-Sc (Belov, Naumova & Bazlova, 2017), Al-Ca-Si-Sc (Belov, Naumova & Akopyan, 2017) and others. Special attention was paid to the study of the system Al-Ca-Zn-Mg (Naumova, 2017). Based on this system creation of advanced extra-high tensile alloys is planned. Wrought extra-high tensile alloys series 7??? based on the system Al-Zn-Mg-Cu are well studied."

Jan 1, 2018

By R. P. Jewett

The object of this investigation was to correlate the crushing strength of green pellets prepared from magnetite, specular and earthy hematite with the particle size of these respective raw materials. In this study no attempt was made to correlate the strength of fired pellets and particle size. The effect of particle size upon a number of fine ores and concentrates was studied. Much of the low-grade ore reserves in the Lake Superior Region must be finely ground before concentration and then agglomerated for iron and steelmaking processes. Fine natural ores also must be agglomerated. Pellets constitute an important type of agglomerate. Considerable handling occurs during screening to remove undersize and oversize pellets, and in transfering green unfired pellets from the balling machines to the heat-hardening equipment. As a result the strength of the green pellets is a factor of great importance.

Jan 1, 1961

By Gavin K. W. Freeman

The efficient separation of cobalt from nickel is a fundamental objective in the refining of cobalt. Based on recent experience at the Corefco refinery in Fort Saskatchewan, the identification of a novel process for the selective precipitation of cobalt from aqueous ammonia leach liquors is described. The addition of calcium sulphate, CaSO4.2H2O (gypsum), to an aqueous solution containing cobalt(III) hexammine sulphate, [Co(NH3)6]2(SO4)3, will result in the precipitation of a sparingly soluble double salt having the stoichiometry, [Co(NH3)6]2(SO4)3.2CaSO4.xH2O, where x = 4 or 6. Leach residues, which may contain a significant quantity of cobalt associated with the cobalt calcium double salt, can be washed with process solutions that contain ammonium carbonate. After contact with ammonium carbonate, the cobalt is recovered into solution, while the calcium is re-precipitated as the insoluble carbonate. The simplicity of this elemental separation and its high selectivity for cobalt, as well as the demonstrated usefulness in improving cobalt recoveries, are the basis for the potential applications of this process.

Jan 1, 2003

By C. W. Kovach, A. Moskowitz

Studies were undertaken to investigate the effects of manganese content on the machinability and other Properties of a free machining martensitic stainless steel (AISI Type 416). Machinability was found to be significantly improved in steels of high manganese content, and a direct relationship was obtained between machinability and steel Mn:S ratio. As the manganese content of the steel increases, the sulfide Phase present changes from CrS to (FeMn)Cr2S4 to (MnFeCr)S, and finally to MnS. The average sulfide inclusion hardness decreases through the same range of increasing manganese content. The mechanism for machinability improvement is discussed in terms of a soft ductile sulfide affecting deformation in the secondary shear zone. Type 416 containing relatively high manganese for improved machinability shows good general properties. The effects of increasing manganese content on mechanical properties, cold formability, and corrosion resistance are described. THE addition of sulfur is commonly used to improve the machinability of stainless steels. However, little attention has been paid in the past to the composition and characteristics of the sulfur-containing phase or phases present in these resulfurized steels. Recent information on the properties of sulfide phases, and their role in metal cutting, suggests that variations in these phases could have critical effects on machin-ability, as well as important effects on formability and other properties such as corrosion resistance. Manganese, chromium, and iron are strong sulfide forming elements present in stainless steels! of these, manganese has the greatest sulfide forming tendency and iron the least.1"1 The manganese content of resul-furized 13 pct Cr steels, often about 0.5 pct, can be insufficient or only barely sufficient to combine with the sulfur that is present; thus, the precise level of manganese can strongly influence the nature of the sulfide phase. Sulfide phases which may be present in stainless steels have been reported to include CrS, a spinel-type sulfide, chromium-rich manganese sul-fide, and manganese Sulfide.5,6 Detailed phase relationships for the Fel3Cr-Mn-S system have been reported by the present investigators,7 and a portion of this work will be referred to subsequently in this paper. Recent work by Kiessling6 and Chao et a1.8 has shown that sulfide phases can display wide variations in hardness, and may undergo considerable plastic deformation under isostatic loading.9-12 Early theories of metal cutting attributed the influence of sulfur to a lubricating effect. It is now apparent that the influence of the nonmetallic inclusions and their properties on crack initiation, deformation in the shear zones, and boundary films must also be considered in relation to the machining process. This paper presents the results of studies conducted to relate machinability to the various sulfide phases which occur in stainless steels. This work has led to the development of alloys with improved machinability, and has generated information on the effects of inclusions on metal cutting processes. Effects of sulfide inclusions and steel composition on other important metallurgical properties are also discussed. MATERIALS For drill machinability and inclusion studies, 10 lb laboratory heats were melted in an air induction furnace. These heats were made with sulfur contents be tween 0.10 and 0.50 pct and manganese contents be tween 0.05 and 3.0 pct. Residual elements were added to the heats in amounts typical for commercial steels. The typical compositional range covered by the heats is shown below: C Mn P S Si Ni Cr Mo Cu N 0.10 0.05 0.007 (M0 0.40 0.40 13.0 0.20 0.10 0.03 3.0 0750 The laboratory ingots were forged in the temperature range of 1800" to 2100°F to 3/4-in. sq bars, and all bars tempered to a hardness aim of 200 Bhn prior to testing. Because of differences in composition and tempering response, the tempered bars showed some variation in hardness (175 to 275 Bhn) as well as variations in delta ferrite content (0 to 50 pct). Composition, hardness, and delta ferrite content were considered in the analysis of the machinability data. Additional tests involving tool-life evaluation and determination of other properties were conducted on materials from commercially melted and processed 15-ton electric furnace heats. TESTS AND PROCEDURES Machinability of the laboratory heats was evaluated in a drill test. In this test, 1/4-in. diam holes, 0.4 in. deep, were drilled alternately in a test bar and in a standard bar for a total of four holes in each. This sequence was repeated three times using a freshly sharpened drill each time. The average time required to drill a hole in the test bar was compared to that for the standard bar. A drill machinability rating was assigned to the test bar relative to a rating of 100

Jan 1, 1970

By J. C. Bradley

THE relation of annealing temperature to conductivity of copper wire has been determined. Conductivity hard was 98.26 per cent. After a 10-min. heating at 200°C. it was 98.69. By annealing 10 min. at 300° C. a large increase, to 100.93, occurred. Maximum conductivity, 101.15, was attained after a 500° C. anneal; thereafter it decreased to 100.53 after a 950° C. anneal. If copper is gassed the decrease is much more than this. Materials and Methods The work was done on high grade electrolytic copper, 99.942 per cent. copper plus silver, silver 0.0008 per cent. It was hot-rolled to >/4 in., then cold drawn to 0.080 in. The wire was cut into 25 5-ft. lengths and numbered 1 to 25 as cut. Four samples were tested hard. The others were wound into 5-in. diameter coils. For the 100° C. heating a coil was put into water, the water brought to boiling, and the wire kept at this temperature for 10 min. For the higher temperatures the coils were placed in envelopes of sheet copper, a little water added, and the envelopes sealed by folding over the edges twice, and hammering them together. This kept the air out very well. The envelope and wire 'were brought to the desired temperature; this was maintained for 10 min., then the whole was water-quenched.

Jan 1, 1927

By K. M. Parida

The kinetics of dissolution of manganese dioxide in dilute sulphuric acid solution have been investigated using iron pyrites as a reductant. The dissolution rate of manganese is independent of the speed stirring but depends upon temperature, particle size, specific surface area of manganese ore, acid concentration, Fe(II) concentration and amount of pyrite. The activation energy is 43.6 KJ/mol and the linear relationship between the rate of dissolution and lido indicates that the reaction is chemically-controlled. The redox reactions of MnO2 with iron pyrites and Fe(II) are the rate-controlling reactions.

Jan 1, 1990

By Felicia F. Peng

The computer graphic routines and digital simulation program of coal cleaning circuits have been developed in the Mineral Processing Engineering Department, West Virginia University. The functions of the program include computing, tabulation and graphing of 1) washability characteristics of raw coals, 2) blending, 3) Tromp distribution curves for two washer types-- water only and dense medium, 4) predicting the functional relationship of yield and qualities of clean coal product in individual and overall coal cleaning circuits in coal preparation plant, and 5) determining the optimal clean coal yield based on the market and environmental specifications. Amdahl 470 V/7A digital computer, Tektronic 4025 graphic terminal and Tektronix 4663 digital plotter with Fortran IV are used to achieve the goals. The simulation with the aid of graphic routine program of coal cleaning circuits is a useful tool for coal preparation engineers in evaluating the feasibility of proposed flowsheets, in investigating the effect of a modification in a unit operation of an existing plant, in analyzing the off-line optimization, and in comparing the alternative circuit control strategies. The coal cleaning process simulation with graphic routine can contribute greatly to the decision making processes of preparation plant design.

Jan 1, 1983

By David Hopkins, Steve Klein, Bradford Townsend, Ed Sum, Derek Penrice

INTRODUCTION The Transbay-Caltrain Downtown Extension (DTX) Project involves the construction of an approximately 1.5-mile rail line that will extend Caltrain commuter service and the future California High Speed Rail system into downtown San Francisco. The underground rail extension will be constructed by mined tunnel and cut-and-cover methods. Tunneling challenges include difficult ground conditions, low rock cover, the presence of historic buildings along the alignment, and the large tunnel span, ranging from approximately 50 to 65 feet. Three mined tunnel construction methods were evaluated: the Stacked Drift Method, the New Austrian Tunneling Method/Sequential Excavation Method (NATM/SEM), and Tunnel Boring Machines (TBM). This paper describes the challenges presented within the mined tunnel section, and summarizes the evaluation of tunneling methods that led to the selection of NATM/SEM. PROJECT OVERVIEW The existing Transbay Terminal opened in downtown San Francisco in 1939. This facility is antiquated, and does not meet current building seismic safety standards or the transportation needs of the Bay Area. For these reasons, San Francisco voters approved Proposition H in 1999, which proposed to construct a new or rebuilt regional transit center at the site of the existing terminal and extend Caltrain commuter rail ser-vice to the new transit center. The new transit center is the hub of the Transbay Transit Center (TTC) Program, which will greatly enhance regional transit service by providing connectivity for six Bay Area transit providers at one facility. The program will be the largest inter-modal centerwest of New York City. The TTC Program is comprised of two major projects, the Transit

Jan 1, 2007

If an orebody has been drilled to achieve some level of regulatory compliance, then a number of associated geological databases will exist, representing 10 000 to 100 000 m plus of core intervals. The databases usually contain data about assays, lithology, mineralisation and geophysical attributes. They will also include location information such as collar positions and downhole surveys. Obviously this data is collected by geologists for, predominantly, geologists and mining engineers. However, from a process design viewpoint process engineers usually ignore the geology where possible and rely on a small number of metallurgical test samples. Typically these test samples are sourced from convenient and available cores or from a small number of specially drilled metallurgical holes. One of the worst instances known to the author was the design of a SAG mill using only two SAG specific test results (one for each of the major ore types) while, geologically, the orebody was defined by more than 30 000 m of drilling. This paper sets out a philosophy to maximise the use of the geological data, both for process design and in preparation for the commissioning phase of projects. Geological data is used in the identification of preferred locations for metallurgical test samples, for checking the metallurgical validity of the geological ore-type definitions, where necessary developing new ore-type definitions (geometallurgical domains) and developing mathematical relationships for the estimation of important metallurgical factors across the geological database. If the estimation of factors (for example ore competence) is considered reliable enough then there is also the possibility of feeding calculated data back into the block modelling process to allow the generation of metallurgically relevant outputs in the mine plans.

Jan 1, 2007

By T. Bartnitzki, N. Fietz

"INTRODUCTION For a long time now automation has been state of the art in production engineering and chemical engineering. The advantages of automation are, for instance, higher reliabilities of production processes, higher product qualities as well as capacities and improved safety conditions for the personnel. In contrast, many operations in mining are still conducted manually by machine operators instead of autonomous control units. One example for this is the excavation of underground hard coal which is still executed with aid of human perception. The Institute for Mining and Metallurgical Machinery (IMR) has been working on possibilities for sensor-based automation of mining machinery for many years now. Thereto the focus is set on the implementation of common material analysis techniques into ruggedized conditions as a basis for automation. Laser-induced breakdown spectroscopy (LIBS) for instance is an atom emission technique which enables the determination of the elemental composition of a sample. After introducing LIBS this paper will give an overview on dust formation during the cutting process. With the illustration of a few examples the challenges in determining dust concentrations specifically such of cutting processes are explained in further detail. The final chapter will outlay the possibilities and challenges in utilizing cutting-induced dust for the automation of shearer loaders. LASER-INDUCED BREAKDOWN SPECTROSCOPY LIBS Fundamentals LIBS (laser-induced breakdown spectroscopy) is a contact-free method for analyzing materials in any state of aggregate. It pertains the atom emission techniques and is based on the generation of plasma, inducing avalanche ionization on the surface of a solid material or any spot in a gas or aqueous solution. With sufficient background information on the expected elements and an additional calibration, this method can determine all present elements not only qualitatively but also quantitatively. However, this method cannot be utilized for determining the molecular composition of materials – if this feature is required a complementary method such as Raman analysis needs to be added. (1, 2)"

Jan 1, 2015

By K. C. Dean

During the investigations of the occurrence of manganese in the Western United States, a Bureau of Mines examining engineer collected samples frame two properties in Beaver County, Utah. As the ores were too low in grade to be acceptable by manufacturers of ferromanganese, beneficiation studies were made to determine the amenability of the ores to concentration. The Steelville property is about 37 miles southwest of Frisco, Utah. The deposit is an example of manganese occurring as a replacement of limestone in a bedded vein or as layers in limestone associated with shale and rock decomposition products. The Susie Q deposit, about 33 miles southwest of Milford, Utah, is also a tabular replacement deposit in limestone, apparently of limited extent. Test work was done on representative samples of 2-ton lots obtained by the examining 'engineer from each of the properties mentioned.

Jan 1, 1951

By Caroline B. Chapleau, Mélanie Proulx, Claude Bazin, Gaétan Lavoie

"Quebec Cartier Mining operates a pelletizing plant in Port-Cartier, QC. Grinding, agglomeration and pellets induration are the three main steps in the preparation of iron oxide pellets. In 1998, following different recommendations, the company increased the speed of one of its ball mill in order to increase the grinding efficiency of the machine. As expected, the increased speed lead to an increase of the power draught, which did not produce the expected increase of fineness of grind, neither its allows to increase the mill throughput. The change of behaviour of the mill could hardly be understood by comparison of discharge size distribution at initial and modified mill rotation speed. On the other hand, the use of the selection function from a population balance model provides an insight of the changes that occurred in the mill. This paper reviews the various steps required for the estimation of a grinding mill selection function. Results of the calibration to Quebec Cartier grinding mills show that the increase in the mill speed leads to higher rate of breakage of coarse particles, at the expenses of less efficient breakage of medium and fine size particles. In the case of the studied mill, breakage of coarse particles was probably not the critical step of the mill operation. INTRODUCTIONOre size reduction is the major energy consumption step in any mineral processing operations (Austin et al., 1984). Size reduction is required to either liberate valuable minerals from the gangue minerals in which they are imbedded, or to increase the specific surface of the ground material. Plant engineers continuously face the challenge to find grinding machines, operating conditions or grinding circuit flowsheet configurations that could improve the size reduction process at lower energy or m6dia consumption."

Jan 1, 2000

By M. Muskat, R. D. Wyckoff, H. G. Botset

The flow of liquids through porous media is known to follow Darcy's law which states that the velocity of flow is proportional to the pressure gradient. This law is but a statement of the facts obtained from experimental studies and is, therefore, uncontroversial. It should be men-tioned, however, that it applies only when the flow is viscous in nature and that at excessive velocities which tend to produce turbulence, the velocity is proportional to some power of the pressure gradient, the exponent ranging from 1 to 0.5 as the degree of turbulence increases. However., experiments with media having permeabilities corresponding to those of actual producing horizons show conclusively that the actual flow of liquids in a producing horizon must be viscous except perhaps in the immediate vicinity of a well producing at a high rate. Therefore, one is justified in assuming Darcy's law to hold for cases of practical interest, as will be implicitly assumed in this discussion Given this basic law of flow it is possible, theoretically to obtain solutions to any problem of viscous flow of dead liquids1 by the usual methods of potential theory. However, problems of practical interest often present such complex geometrical configurations of sources and sinks (driving sources and output wells) as to make the analytical solutions extremely difficult or even impossible. It is useful, therefore, to note that Darcy's law is precisely equivalent to the law of electrical conduction, so that the pressure distribution in steady state porous flow of liquids is exactly the same as the potential distribution in an electrical conducting medium.2 This analogy permits the use of electrical models wherein the potential distributions may be measured with far greater facility and accuracy than is possible in actual fluid-sand models. Such electrical models were used in determining the pressure distribution about complex arrays of wells, an example of which will be shown later in the discussion of the 5-spot flood. One phase of the porous flow problems which is of considerable practical interest involves the tracing of an advancing fluid front. Thus,

Jan 1, 1933

Many of the large refrigeration plants used in, the cooling systems on deep South African gold mines are situated on surface where they are exposed to seasonally and diurnally varying climatic conditions, and to a diurnally varying demand for cooling made by the mine. It has been traditional to accommodate the seasonal variation in climate by manual control applied to the plants at appropriate times of the year, and the plants have normally been specified to conform passively to the diurnal variations. This paper introduces new strategies for the active automatic control of the plants on a diurnal cycle, and shows that attractive benefits in energy and chilled water resource management can be accrued through the use of these strategies. The results have been derived through the modelling and simulation of a representative refrigeration plant.

Jan 1, 1985

By Donald P. Schlick

Respirable dust provisions of the Federal Coal Mine Health and Safety Act of 1969 are designed to protect the most important resource of the coal mining industry--its workers. The Act imposes two respirable dust standards of 3.0 milligrams per cubic meter of air after June 30, 1970; and 2.0 milligrams per cubic meter of air after December 30, 1972. Under Federal regulations, each operator is required to carry out a dust sampling program established by the Secretary of the Interior and the Secretary of Health, Education, and Welfare, This program features the sampling of "high risk" face workers to establish that the exposure of each miner is below the dust standard, Mining sect ions, continuously in compliance with the regulations, may sample at less frequent intervals. In addition to requiring the mining company to take respirable dust samples, the Bureau of Mines will perform in-depth dust inspections twice a year, as well as frequent "spot inspections." The Bureau has established a semiautomatic computerized operation capable of processing over 1 million samples per year. This facility will be linked to various Bureau offices by a telecommunications system to provide automatic data printouts within hours after samples have been weighed.

Jan 1, 1970

By van Eck M, Orr T, Eggleton R. A, Taylor G

The Charters Towers locality has been a historically renowned gold producing region and discovery of new ore deposits during the past decade have renewed exploration interests in the area. Further mineral exploration with conventional techniques is hindered by the presence of Cainozoic sedimentary deposits and volcanic flows overlying a major portion of the basement geology. Mineral exploration thus warrants new, innovative and cost-effective methods to probe beneath the Cainozoic cover in an attempt to discover new orebodies. There is growing awareness of the role of weathering as an agent of chemical dispersion into the cover sediments as well as a producer of supergene deposits in tectonically stable cratons (Butt and Zeegers, 1992). Consequently, landscape evolution coupled with regolith geochemistry is one of the methods increasingly being used to identify relevant sampling media to explore beneath weathered cover sediments and deeply weathered bedrock terrain (Anand, 1993). The aim of this paper is to describe and elucidate the regolith - landscape features of the region and combine geochemistry to assess the pertinence of the same on mineral exploration strategies in the Charters Towers area.

Jan 1, 1997

By H Allday

The mining industry’s attention has shifted over the last decade with the recovery from the downturn resulting in greater development of innovation and new work methods in a bid to remain competitive and deliver higher productivity. The emphasis on cost reduction to improve profit margins has primarily been the focus of the “work smarter” campaigns embraced within the industry. But is this strategy holistically the best-for-business, or does it place a ceiling on revenue opportunities and inhibit mining companies from truly maximising value? Businesses need to maintain a balance between active cost management and revenue generation often resulting in cost reduction strategies at site level. These strategies have merit, assessing areas of cost wastage across operations and creating space for opportunity. However, this potentially can create distractions from the goal of enabling growth and lead to the sacrifice of quality and delivery. Focusing too heavily on cost reductions without addressing revenue generation is an unprofitable lens to look through, and the relationships between cost, revenue, quality and profit margin can often be overlooked resulting in missed opportunity to maximise value. How these relationships are effectively employed by mining companies to reap the rewards from an overarching corporate perspective down to site level remains a fluid concept depending on the nature, operating market and strategy of the business. A common directive from businesses to their operations is to strive for greater profitability and productivity. The quantification of these requirements, and the nature of the cascading message delivered, impacts the methods employed by the operational team to meet the expectations of the business. Cascaded strategies, if not delivered with appropriate participation and buy-in can often be perceived to be knee-jerk and create frustration for operations who are squeezed to deliver on expectations by slashing site costs. This squeezing is not only felt by the mining operation but at the individual level and can result in increased team stresses. In some cases, this may also steer behaviours towards activities that result in corner cutting and an elevation of operational risk, potentially increasing associated incidents and injury. Driving down costs by any means can create an unhealthy tunnel vision where value is no-longer assessed for best-forbusiness results. By flipping the viewpoint to a value-based approach revenue opportunity may be realised and potentially exceeded, however this opportunity may be missed if value is over shadowed by a cost heavy focus. By analysing a selection of real operational cases (ranging from mining contractors through to in-house mining giants), it becomes apparent that practical revenue maximisation strategies are not only key to an increase in value and cash flow but to a stronger understanding of business drivers for sites and operators alike. In the cases evaluated additional revenue opportunities are foregone in favour of cost reduction strategies resulting in negative impacts on the associated operations and wider businesses. Alignment towards value generation is king. If strategies are not implemented focusing towards value and revenue maximisation, the opportunity loss experienced by mining operations could continue be great and the question should be posed; when the next up-turn hits will operations be ready to reap the rewards or still have a glass ceiling above their heads?

Mar 15, 2021

By L. Wilfley, G. A. Calboreanu

"Wear resistant 25% Cr hard cast iron is a heterogeneous material containing 1,600 HV hard chromium carbides embedded into martensitic matrix. It is the most used cast alloy in wear operations of mining industry, chemical industry, fracking, etc. During the last decade the hard iron manufacturers increased wear resistance in the following ways: • Reduce / eliminate harmful retained austenite and chromium + carbon depleted areas especially within eutectic carbide cells. In Max5A the improved 25% Cr alloy brittle carbide eutectic cells are removed which increases toughness. • Delay delamination between chromium carbides and matrix particularly during sliding abrasion wear. Delamination commences at the weakest chromium carbide – matrix contact lines exposing chromium carbide to localized bending stresses which gradually chip carbides away. Once the chromium carbide base is removed accelerated wear degradation occurs. • Evenly randomize and avoid discontinuities in the chromium carbide network. When chromium carbides are perpendicularly positioned to the wear surface wear rate is minimized. On the contrary the highest wear rate takes place when 3D oriented chromium carbides are parallel with the wear surface. In this case chromium carbides cover top network discontinuities being just matrix supported which leads to rapid carbide cracking. The new hard iron discussed in this paper fulfils and exceeds the above requirements increasing the casting service life around 250% in various wear operations. Physical and mechanical properties of Max5A are compared with well manufactured Industry Standard 25% Cr hard iron. The paper presents practical accomplishments obtained in the USA, South America and India. INTRODUCTION The chemical composition of Max5A and Industry Standard 25% Cr are identical like specified by ASTM A532 Class III Type A requesting C = 2.0-3.3% and Cr = 23.0-30.0%. Manganese, silicon, nickel, molybdenum and copper contents are limited by maximum accepted quantities.[1] According to published data the eutectic chromium carbides chemical composition of 25% Cr hard iron is Cr = 54% and C = 8% which indicates strong depletion of chromium and carbon along chromium carbide - matrix interfaces. [2] The optimized Max5A microstructure has minimized retained austenite, is devoid of harmful carbide eutectic cells and has the most advantageous chromium carbide and secondary chromium carbide morphology. This favorable microstructure increases wear resistance, mechanical properties and corrosion resistance. The paper compares the Max5A microscopic features and mechanical – physical properties with similar properties of high quality Industry Standard 25% Cr."

Jan 1, 2017

By T. Takayama Filho

Votorantim Metais Zinco is a smelting facility which produces SHG zinc, zinc alloys, sulfuric acid, liquid SO2, copper sulfate, cadmium metal and silver concentrate. It is located at Juiz de Fora, Minas Gerais State, Brazil. This facility has been operating since 1980 and its current capacity is 95,000 tonnes of zinc per year, using mostly imported sulfide concentrates.The plant uses the conventional roast-leach electrowinning (RLE) process, in which iron is removed from the circuit as jarosite. The residues generated by the RLE process, which amount to about 200 t/day (dry weight), were until 10 years ago, deposited in tailing ponds having no impervious lining. More recently, jarosite and other wastes have been deposited in a properly built reservoir, but this is reaching its maximum capacity. In order to decommission these disposal operations and to reclaim the sites in an environmentally acceptable manner, Votorantim Metais concluded in 2004 a rehabilitation project for the old tailings pond and prepared detailed plans for managing the current and future disposal of jarosite-bearing residues. This paper describes the procedure for removing iron from the hydrometallurgical circuit and discusses the past and current status of the residue disposal sites, as well as the future challenges related to the environmentally acceptable handling of iron residues.

Jan 1, 2006