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An atomic force microscopy (AFM) has been applied to study the adsorption of potassium amyl xanthate (PAX) and potassium ethyl xanthate (KEX) on arsenopyrite surface in solutions. AFM images show that the collectors adsorb on arsenopyrite surface in patches at pH 6. Increasing the chemical dosage will increase the adsorption density of the patches on mineral surface. The increased probe-arsenopyrite adhesion measured in PAX solutions at pH 6 is attributed to the adsorption of the patches, suggesting the hydrophobic nature of the patches, which is likely the oily dixanthogen. It is also found that arsenopyrite is reactive in water in the presence of air. At a high pH with the addition of Ca(OH)2 the adsorption of collectors on arsenopyrite is greatly retarded or depressed because the mineral surface is coated by a lot of precipitates, which is hydrophilic in nature as shown by the measured strong repulsive probe-arsenopyrite detachment force. The findings confirm that the flotation behavior of arsenopyrite in xanthate solutions is very similar to that of pyrite.

Feb 27, 2013

By L. Douglass Anderson

For some years past the annual reviews of the metallurgy of lead have almost uniformly stated that there have been no great changes, such as there were being more particularly noticeable in the refinement of details. While this is quite true, nevertheless these changes in details are gradually bringing about a condition that, taken as a whole, constitutes a considerable advance in the art. Local circumstances have often compelled metallurgists to adopt certain peculiarities of practice which upon trial have been found advantageously applicable to more than the restricted district of origin. This paper will deal with some of the more novel features developed in recent years at the United States smelter, Midvale, Utah, particularly with reference to the influence of the bag house. The plant is equipped with six blast furnaces, 48 by 160 in., mechanically fed; four Wedge furnaces for roasting matte and sulphide ores; four Dwight-Lloyd sintering machines; 20 converter boxes for blast roasting; storage bins for ore, fuel, and fluxes; "oxide" and "sulphide" sampling mills; bag house taking all the gases of the plant; arsenic plant for treating the dust gathered there; laboratory, shops, etc. The most marked feature of the plant is its complete bag-house system. Of the many schemes thus far tried for preventing damage to surrounding agricultural interests the writer is aware of none as yet quite as efficient as the bag house. A common remark of visitors upon approaching the plant and viewing the clear stacks is that it appears to be shut down, whereas once inside all the evidences of industry are found. Bag-housing blast-furnace gases presents no peculiar difficulties. The gases from properly run furnaces are comparatively cool, contain scarcely a trace of acid and do not burn the filtering medium. All that is required is a proper mechanical design of the bag house and its accessories, the provision of ample filtering area, and of convenient means for handling and treating the product. While cotton or duck bags have been used, on the whole woolen bags woven of the raw wool appear to give sufficiently longer life to warrant their heavier expense. As for the filtering

Jan 1, 1915

"Classification is an important aspect of mineral processing plants and if not operated efficiently can compromise both the throughput and recovery of the circuit. This paper discusses the benefits that can be obtained by operating the classification section efficiently. Since classification in most of the mineral processing plants is carried out using either hydrocyclones or screens the case studies involving the two classifiers were used in the discussion. Studies where optimising the classification circuit lead to improvements in the performance of the overall plant were included to show the benefits of paying attention to this area that is usually neglected. The data from the mill-float mill float, SABC, and Single Stage SAG mill circuit case studies have shown that the circuit throughput can be increased throughputs without compromising recoveries by optimising the classification circuit. On plants where the ore can be liberated at coarser sizes the experimental results have shown that replacing hydrocyclones with high frequency screens can lead to improved plant throughput with no detrimental effect on recovery. The discussion has included information on design and operational considerations for plants that have or intend to use hydrocyclones or screens that could make the classification circuit more efficient.INTRODUCTIONComminution is the process in which particles are reduced in size mainly by crushing and grinding. In most mineral processing circuits comminution is carried out to liberate the valuable minerals prior to subjecting the ore to a recovery process were values are concentrated or extracted (Mainza, Evertsson, Benzer, Tavares, Powell, Rule, Plint, …, 2013). Comminution is an energy intensive process and is usually achieved in stages. It is common to have a classifier after each comminution stage. The process is carried out in stages to minimize energy usage and to improve the efficiency of the process in meeting product specifications. Although comminution circuits have been advancing classification has remained a key component of the comminution circuit design (Mainza et al., 2013). Mainza et al. (2013) summarised the role of classification in mineral processing circuit as: to allow material in the equipment that can promote high operational efficiency, to improve material handling in the circuit, to minimize overgrinding of material to reduce energy consumption, and to provide the best quality product to enter the next stage of processing. Classification stages are employed in comminution circuits to ensure that high throughputs are processed without compromising the product quality or to produce a fine product at relatively low energy. If neglected classification can have detrimental effects on plant performance."

Jan 1, 2016

By Roswell Johnson

WHAT becomes of the water which must have filled the oil and gas sands at the time of deposition, has long puzzled students of oil and gas and has found expression in Munn's well known article on the hydraulic theory. Both Munn and Clapp have pointed out that in the Appalachian field the deeper sands carry increasingly less proportionate amounts of water. It seems to me probable that the principal source of oil and gas has been in the shales in proximity to the sands which now contain these products. The sand spits which mark off the lagoons from the sea comply particularly with the requirements of a limited sand imbedded in shales rich in organic matter. Cunningham Craig has objected to this view that the rich organic muds of lagoons are found only at the surface. That such muds do extend to considerable depth 1 am assured by Prof. Douglas W. Johnson, who has made an extensive study of the Atlantic Coast marshes. As any particular sand body becomes weighted by a heavier and heavier overburden, the result of increasing deposition, a part of the very large percentage of water in the uncompacted sand and mud is forced pout. The water percentage of freshly settled mud is vastly higher than that of the resultant shales, or even of a very porous sand. If beds of less compressible material meet or underlie the shales in question, there will. frequently be a lateral motion along such beds to some point where the upward movement will be resumed. We find in our laboratory work here that oil, gas, and water have extremely slight capacity for gravitational sorting while in a state of rest but when moving the gravitational sorting is readily accomplished. As the oil, gas, and water pass a body of larger pores, the gas, owing to its lack of capillary attraction, is retained in .the large pores.

Jan 2, 1915

By Denise Y. Dizon

The objectives of this study were to document the hydrologic impacts of longwall mining on streams, identify the factors affecting the extent of stream dewatering, and develop empirical trends to predict the extent of dewatering and recovery of streams in advance of mining. This study on stream impacts is a companion to a stud; conducted on ground water impacts from longwall mining, which was done as part of the same research project at the' same locations and times. The study areas are three mine sites in north- central West Virginia. Mine A, located in Upshur County, has relatively thin mine overburden under the valley streams (105-115 feet). Stream monitoring there continued the earlier work of Cifelli and Rauch (1). Stream dewatering was severe with streams often going dry over the longwall panels during baseflow conditions. The lost water was probably flowing to the mine. Dewatering began in streams over the mine entry areas adjacent to the panels and as much as 380 feet from the nearest panel edge. The angles of dewatering influence ranged 22 to 72 degrees with respect to the nearest mined panel edge. Discharge then typically increased as the streams- flowed across the panel edge, but then decreased again over the panels. These streams were often ponded by local reversals in hydraulic gradient caused by land subsidence, and often dried up after flowing a few hundred feet across the panels. This occurred over panels that were previously mined up to eight months before. Mine B, located in Monongalia County, has relatively thick mine overburden (475-485 - feet) under the major stream. Stream dewatering was severe there during warm season baseflows, with complete dewatering occurring then over the longwall panels. This dewatering occurred over mined panels up to five years old, probably in response to a major anticlinal axis lineament and fracture zone in the stream valley. Mine C. located on the West Virginia -Pennsylvania border, has relatively thick mine overburden (about 585-630 feet) under the monitored streams there. stream dewatering was only partial, and these streams typically recovered their lost discharge downstream of the mine, indicating that lost water was not recharging to the mine. Only longwall panels less than one year old were associated with stream dewatering.

Jan 1, 1990

By Frank Firmstone

Since the blast Fired August 15th, 1878, which was described by Mr. Clark," and up to November, 1881, we have fired three smaller blasts, one in the southwest corner of the quarry and two in the buttress of rock left standing by the first blast near the mouth of the main gangway. We intended to keep an exact account of the stone thrown down by each blast, but the large quantity required by the furnaces since the beginning of 1879, and the time taken up by more important matters, have caused this to he neglected, so that it is not possible to separate exactly the cost and quantity of stone obtained during this time by the old method from that furnished by the large blasts; yet as the latter quantity has been much greater than the former, some notion of the value of the large-blast plan may be reached by comparing the figures from September, 1878, to November, 1881, with those for times when the old system was exclusively used. Since 1878 wages have been raised, lowered, and again raised, and to get a year of sufficiently large production for fair comparison it is necessary to go back to that ending April, 1872, when wage? and supplies were different from present prices and from those of 1878,.

Jan 1, 1882

By P. B. Liebermann

1. Haulage Tests on Coal-mine Cars THE haulage of coal from the face to the tipple is an important enough link in the production of coal to deserve its full share of study and care. In order to obtain a better understanding of mine haulage conditions, a series of tests and investigations has been made which promises to hasten the improvement of present conditions. For hauling coal through the mine and on the surface, locomotives are required, the size and power consumption of which depend on the resistance to motion offered by the mine cars. This resistance is principally caused by gravity and hearing friction. The effect of gravity can be reduced to a minimum by a suitable layout of the haulageways; that is, by arranging the grades in favor of the loaded trips, and by fixing the percentage of grade to that value which gives the lowest power consumption for loaded and empty trains. The bearing friction, which is considerably greater than is generally realized, can be easily reduced to a negligible quantity by the installation of a suitable anti-friction bearing that will stand the rough use and abuse of coal-mine service. The present investigation will deal with flexible roller bearings in comparison with ordinary plain bearings.

Jan 7, 1917

By M. H. HARRINOTON

THE Transactions of the Institute afford abundant evidence of the general recognition by mining engineers of the importance of a safety-lamp which will not only give warning of the presence of fire-damp, but will also indicate the proportion in which it is present.' Mining-men are only too familiar with the frequent and sudden changes that constantly occur at the working-face of a gaseous mine. Nothing illustrates more forcibly the pregnant condition of the strata enfolding the seam and the seam itself, than the fact that a circulation of perhaps 150,000 cu. ft. of air may contain 2 or even 3 per cent. of marsh-gas, representing a volume of from 3,000 to 4,000 cu. ft. of this gas pouring-out each minute from the natural strata into the mine-workings. It would, indeed, be strange if this great outflow of gas were always constant, and it creates no surprise that such earth-breathings, as they may be called, are spasmodic and irregular in their wane and flow. There are other causes that act to vary the gaseous condition of mine-air. Gas has a tendency, often very manifest in mine-workings and airways, to stratify and, at times, to travel long distances in veins or streams. It is common to catch and lose the gas in the lamp when making a test. At times two lamps, held side by side in an air current, will indicate different gaseous conditions of the passing air. When testing for gas, the lamp may suddenly fill with flame, in a mine-chamber, where a moment before a careful test showed the presence of but 1 per cent. of gas. It is sometimes remarked that there is little need of detecting a smaller percentage of gas than is revealed by the common

Jan 1, 1906

By E. J. Parkins, H. L. Shergold

The paper is divided into two parts. The first part describes an investigation of the effect of temperature on the conditioning and flotation of an ilmenite ore with a 1:l oleic acid-fuel oil mixture as collector. During conditioning the pulp underwent characteristic changes of flocculation, deflocculation and dispersion which were monitored by measuring the power consumption of the conditioner motor. Optimum flotation results were obtained at the end of the deflocculation period. High ilmenite recoveries were obtained at high temperatures and high concentrate grades at low temperatures. The second part of the paper describes a study of the effect of temperature on the adsorption of oleic acid at the ilmenite/water interface. At high adsorption densities it was chemical and exothermic. Contact angles showed that the hydrophobicity of the collector-coated minerals increased with an increase in temperature.

Jan 1, 1976

By J. M. King

A crucial step in the acquisition by one company of the assets of another, the acquisition of the stock of another company, or the merger of two com-ponies, is the legal due diligence which needs to be performed in order for the acquirer to ascertain or confirm the obligations, liabilities and exposures to risk that are being assumed along with the assets or corporate stock being acquired. Where the obligations, liabilities, or exposures to risk arise from existing contracts, or from pending lawsuits, administrative proceedings, or threats of these actions, those matters are relatively straightforward to discover by careful review of the files of the party whose assets or stock is being acquired. However, where a company is engaged in ongoing mining or processing operations and has operated or owned mining proper-. ties, there are many sources of liability and exposure to risk which could have major adverse economic consequences to the acquiring party and which are not revealed, or at least are not clearly delineated, by the records of the company whose stock or assets are being acquired.

Jan 1, 1990

By W. W. Adams

The metal and nonmetallic mineral mines (excluding coal mines) of the United States had a more favorable safety record in 1935 than in any year except 1931 and 1932 since annual statistics of accidents first became available in 1911. The accident rate was even lower than that for 1911, when the recorded rate probably did not reflect all of the accidents that actually occurred because many companies had not yet begun to keep complete records of accidents, especially those causing only minor injuries, and when, therefore, the number of accidents revealed by the companies' reports to the Bureau of Mines was probably not as complete as that reported for later years. Compared. with 1911, the accident rate covering fatal and nonfatal injuries in. 1935 decreased 13 percent. Compared with 1925, when the rate was the highest ever reported, the rate for 1935 decreased 47 percent and compared with 1934, 7 percent. The progress in safety which the mines of the country made in 1935 was not confined to any section or mining region; it was shared by a majority of the mining States and applied to underground mining operations, to open-pit mining, and to work at surface shops and yards. The rate for underground mining declined 8 percent from 1934; the rate for open-pit mining declined 14 percent, and that for surface shops and yards 12 percent.

Jan 1, 1938

By C. W. JEFFERS

At its annual meeting on March 5, 1928, in Washington, D. C., the Joseph A. Holmes Safety Association gave to the Ford Collieries Co., Curtisville, Pa., a certificate of honor for "having worked 922,628 underground man-shifts from August 14, 1920, to December 31, 1926, producing 5,755,669 short tons of coal without a fatality." This remarkable record certainly deserved recognition. It developed that this company's freedom from fatalities continued until October 2, 1929, hence the full period during which no underground fatalities occurred was from August 14, 1920, to October 2, 1929, or 9 years, 1 month, and 18 days, the total tonnage being over 7,700,000. Table 1, shows the complete safety record of the Ford Collieries Co. since 1920 as given by the officials of the company. The first item in Table 1 shows a remarkable performance. This company since 1920 has mined 15 times more coal per fatal accident than the average pro- duction per fatal accident for the State of Pennsylvania in 1928 (255,257 tons). Excluding the two fatalities (one in 1922 and one in 1929) the severity rate for the same period has been 1.259 per thousand hours worked, a record of which the company may justly be proud. However, including the fatal accidents the rate is 2.407. This compares favorably with an average of 12.4 in 1928 for 66 mines in the National Safety Competition. The Ford Collieries Co. operates three mines located in the vicinity of Curtisville, Allegheny County, Pa. One of these mines, Benjamin No. 1, is idle at the present time. The officials are: A. R. Pollock, general manager, Curtisville, Pa., and C. W. Pollock, assistant general manager in charge of safety and operation.

Sep 1, 1930

By Edward Martinez

Due to its unique properties, chrysotile asbestos is used in many diversified applications. In recent years, a better understanding of the structure and properties of chrysotile has evolved due to the research efforts of many investigators. A summary of the results of some of these investigations is given. An attempt is made to show the relationships between the properties of chrysotile and its crystal structure. Examples taken from the literature are cited in which methods have been developed for modifying the properties to improve the performance of asbestos in some applications. These include the effect of pH on the positive zeta potential and the addition of sodium silicate to improve filtration characteristics. The dehydroxylation and formation of forsterite when chrysotile is heated are also discussed.

Jan 1, 1966

By D. P. Caplice

On behalf of the Ontario Water Resources Commission, I would like to express my sincere appreciation to your Institute for presenting us with this opportunity to outline the regulatory control programme as it relates to the mining industry in the Province of Ontario. In Canada, and particularly in Ontario, we are blessed with an abundance of natural resources. Fresh water in the form of lakes and rivers covers nearly 17 per cent of the area of the Province. (Total area of the Province of Ontario is 412,582 square miles.) The mining industry, which had its beginning in the early 1800's with a small iron ore plant, has progressed with the major discoveries of nickel and copper in 1883, silver in 1903, gold in 1908, iron in 1939 and uranium in 1953, to the point where, in 1966, almost one billion dollars in mineral wealth was mined in Ontario. Water, in spite of its great abundance and with due respects that it may become a natural resource worthy of export in the foreseeable future, has become increasingly precious in Ontario, particularly in the more urban areas in the southern part of the Province.

Jan 1, 1968

By N. F. Schulz

The purpose of this investigation was to evaluate the effects of variables in equipment and procedure on tube test results. This information was then to be used to formulate specifications, preferably within the practical ranges of existing machines, for test procedures capable of yielding precise and meaningful data concerning the magnetic separation of any magnetite ore, regardless of its origin. A survey of current practice was conducted among laboratories using the Davis tube test. Many tube tests were performed to experimentally evaluate the variables most likely to affect test results. A simple method was then sought for adequately interpreting tube test results. The Davis magnetic tube concentrator is a laboratory machine designed to separate a small sample of pulverized magnetic iron ore into magnetic and non-magnetic fractions. It was developed in 1921 by mechanization of a test previously performed manually No significant changes have been made in the design of the apparatus since that time. The Davis magnetic tube test continues to serve as a practical basis for judging the amenability of an ore to magnetic separation and for controlling magnetic separation plant operations. The apparatus consists of an inclined cylindrical glass tube supported adjacent to closely spaced pointed poles of a powerful C-magnet. (Fig. 1). To conduct a tube test, a sample of suitably prepared ore is poured into the water-filled tube. With wash water flowing through, the tube is oscillated to gradually reject the non-magnetic and weakly magnetic ore particles until the desired degree of separation is attained. Both the magnetic concentrate and the tailings may be recovered for examination. MAGNETIC SEPARATION BY THE DAVIS TUBE Mechanical separation of a specified mineral component from an ore usually requires comminution to fine sizes for sufficient liberation. Some distinguish- ing property of the mineral is then exploited to sort the desired mineral particles from the gangue particles. The magnetic separation of iron ores is based on the fact that magnetite, Fe3O4, is strongly attracted by a magnetic field while the gangue minerals are not. Maghemite, ?-Fe2O3, which may occur in certain chemically processed ores, responds similarly to magnetite. The magnetic process is practical only when the loss of iron in the form of relatively nonmagnetic hematite, Fe2O3, goethite, Fe2O3.nH2O, or other iron mineral can be tolerated. In the Davis magnetic tube concentrator, magnetic attraction holds magnetically susceptible particles in a magnetic field. Forces due to gravity, inertia, and fluid-solid friction tend to remove the less susceptible particles from the field. The probability that a given middling particle will be rejected from the tube in a given period of time is an inverse function of its magnetite content, with some modification due to particle size and mineral specific gravities. The net result is that ore particles tend to be rejected in their order of increasing magnetite content, while the retained portion or magnetic concentrate increases in grade continuously during the process. MAGNETIC SEPARATION CHARACTERISTIC The magnetic separation characteristic or MSC of a magnetite ore is the correlation between concentrate

Jan 1, 1964

By D. A. Temple, G. O. John

Until recently, the approach to the problem of treating complex ores bas been to produce, insofar as is possible, mono-metal concentrates which are treated in traditional zinc, lead and copper smelting circuits, with the residues and by-products from some of these circuits being retreated for the recovery of contained values either by a separate residue treatment process or along with the primary feed to the appropriate circuit. The continued development of the Imperial Smelting Process, with its ability to treat poly-metal concentrates, calls for a re-examination of the traditional approach to this problem, and this the paper attempts to do. A survey of recent progress in the technical development of the process is made and a summary of current operational performance is included.

Jan 1, 1971

By W. W. Adams

The year 1937 was signalized by increased employment in the metal-and nonmetal-mining 4 industry of the United States. Measured by the number of men working, there was a 17-percent gain in employment compared with 1936. In total number of man-hours worked at all mines, the gain was slightly over 18 percent. Hazards connected with mining resulted in more accidents to the workers than in 1936, but the increase in number of accidents caused only a slight rise in the accident rate because of the much larger increase in the number of man-hours worked. In fact, the fatality rate per million man-hours of exposure was lower in 1937 than in 1936, but the rate for nonfatal injuries increased slightly.

Jan 1, 1940

By S. F. Guo, B. W. Zheng, X. L. Huang, S. W. Qi

"The study of mechanical characteristics of rock discontinuities under different shear deformation velocities is an important premise of rock slope dynamic response analysis. According to disposing and calculating the experimental results of previous research about peak shear strength of rock discontinuities under different shear deformation velocity of constant normal loading, the law of influence of shear velocity on the total friction angle is studied. Based on the research results, it can be found that the total friction angle of rock joint specimens varies in the form of negative logarithm with the variation of shear deformation velocity. It’s also indicated that the total friction angle of rock joints decreases with the increase of shear deformation velocity for rock joints of relative strong homogeneity and isotropy. However, the total friction angle of rock joints increases with the increase of shear deformation velocity for rock joints of relative strong heterogeneity and anisotropy and the latter amplitude of increase is less than the former amplitude of decrease. The physical property and microscopic geometry of rock joints play an important effect on the increase or decrease tendency and amplitude variation of total friction angle with the increase of shear deformation velocity.INTRODUCTIONThe rock slope dynamic response is largely restricted by rock discontinuities. Hence the study of dynamic characteristics of rock discontinuities, especially the dynamic shear characteristics is an important premise of rock slope dynamic response analysis (Qi et al., 2007). Seismic load is both dynamic load and cyclic load (Liu et al., 2011). Under the dynamic and cyclic shearing actions of seismic load, the rock slope which is stable under the condition of static load may slide along the rock discontinuities whose shear strength reduce and then the earthquake landslides occur. The strength degradation and deformation mechanism of rock discontinuities under the dynamic and cyclic shearing actions is one of the key problems to be solved in the work of earthquake prevention and control of engineering slope. Based on the above understanding, predecessors conduct some researches which focus on the shear behavior mechanical characteristics of rock joints under cyclic shearing actions (Plesha, 1987; Hutson & Dowding, 1990; Jing et al., 1992, 1993; Huang et al., 1993; Qiu et al., 1993; Homand et al., 2001; Lee et al., 2001; Jafari et al., 2003; Liu et al., 2011, 2013). However, there are a few researches about the mechanical characteristics of rock joints under different shear deformation velocities because of the restriction of shear apparatus. Crawford and Curran (1981) conducted a series of one-way cyclic direct shear tests on four kinds of natural rock joints under different shear deformation velocities varying from 0 to 200 mm/s. The tests showed that at low normal stresses the peak shear strength of soft rock joints exhibited an increase up to a certain velocity, after which it remained essentially constant. For rock joints of intermediate hardness, the peak shear strength was essentially independent of shear deformation velocity; whereas for hard rock joints, the peak shear strength of which showed a significant variation with the shear deformation velocity. Jafari et al. (2003) carried out a series of conventional triaxial tests on artificial rock joints of regular saw-tooth shape with axial loading rate from 0.05 mm/s to 0.4 mm/s."

Jan 1, 2015

The dissolution behavior of gold and silver from Au/Ag alloys in aerated cyanide solutions has been investigated using rotating disc electrodes. The variables studied included concentration of cyanide, oxygen partial pressure and rotating speed of the disc. The dissolution potential and the rate of dissolution were obtained in view of the anodic and cathodic current-potential relationships. The results were discussed in terms of a mixed potential theory. The results showed that the dissolution rate of gold and silver from the alloys was partially controlled by chemical reaction, but largely by transport of either oxygen or cyanide, depending on their relative concentration under the experimental conditions employed in this study.

Jan 1, 1995

By M. C. Fuerstenau, J. D. Miller

The response of calcite to flotation with saturated fatty acids and alkyl sulfonates of various chain lengths is presented. The amount of collector re-quired for flotation is shown to decrease systemati-cally with increasing carbon content from 8 to 12-carbon atoms per molecule. This systematic flotation response is correlated with the solubilities of the calcium-collector salts, which were established with a nephelometer. The 14-carbon collectors deviate from this systematic behavior, and no flotation is possible with the 16-carbon homologs. As determined by infrared analysis, the mechanism of collector adsorption involves a specific chemical reaction be-tween the collector and the surface. A reaction of the form CaCO3(s)+ 2 RCOO"=*=Ca(RCOO)2(s) + C03= is suggested. The pH of the system is also shown to be a most important parameter as it controls the carbonate, calcium, and collector ion concentrations in solution and thus controls flotation response. The importance of hydrocarbon chain length of collectors was recognized early, and various studies have been made on this aspect of flotation. Wilkinson, ' for example, noted that as the chain length of alkyl xanthates is increased, the amount of collector required for flotation of sphalerite is decreased. The same effect has been shown in the flotation of galena.2 Similar results were obtained when malachite3 and calcite4 were floated with various fatty acids. DeBruyn5 has shown that a similar phenomenon occurs when quartz is floated with amines at constant pH. Recently, Fuerstenau, Healy, and Somasundaran6 correlated this phenomenon with the van der Waals cohesive free energy of association of the hydrocarbon chains. It seems unlikely, however, that chain association could be involved in the sulfide and carbonate systems with the collector additions employed, especially with the short-chain xanthates. Rather, it would seem that the decrease in collector concentration with increase in chain length noted for flotation is related to the solubility of the metal-collector salt. The purpose of this investigation is to verify this premise and also quantify this phenomenon if possible. Calcite was selected for study with both alkyl sulfonates and saturated fatty acids as collectors. EXPERIMENTAL MATERIALS AND METHODS The collectors used in this investigation ranged from 8 through 14 carbon atoms per molecule. The fatty acids had a reported purity of greater than 99%. The sodium alkyl sulfonates were provided by the Marathon Oil Cot, Littleton, Colorado, and had the

Jan 1, 1968