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Surface Plasmon Resonance (SPR) spectroscopy, combined with cyclovoltammetry, has been successfully used to study the interactions between ethyl xanthate, heptyl xanthate, dithio-phosphate and propyl trithiocarbonate flotation collectors and a gold surface. Large, easily measurable responses have been obtained in the potential areas where the thiol collectors are known to interact with gold. The four collector types lead to differing SPR maximum values, with longer alkyl chains resulting in higher SPR responses, and the trithiocarbonate leading to the highest response values. The SPR responses differ considerably from the current density response at very anodic and cathodic potentials. There are indications that thiols might still be adsorbed at potentials as low as-300 mV (vs SHE). Keywords: flotation collectors; thiol collectors; cyclovoltammetry; surface plasmon resonance spectroscopy.

Jan 1, 2005

By Barbara J. Arnold

Combat Infantrymen’s Badge and Bronze Star Medal. Following his discharge from the Army, he re-entered SDSM&T in 1946 and earned a B.S. degree in Metallurgical Engineering in 1948. He then received an M.S. from Montana Tech (MT), worked several years in industry and then as an Assistant Professor at the University of Washington (Seattle). He joined his Montana Tech colleague, Douglas W. Fuerstenau, at The Massachusetts Institute of Technology (MIT), receiving his doctorate in 1957. While at MIT, he married Clare M. Donaghue of Dorchester, Massachusetts, in 1955

Jan 3, 2022

By Kevin Michael, David C. Byrne

In previous issue of Spectrum (October 1999, 16/4), a system of measuring the attenuation provided by insert-type hearing protectors was described, That report described experiences using the FitCheck (Michael & Associates, Inc.) system in a pilot project involving the steel industry during 1998.[ ]

This paper describes some experiences in the design of flotation reagent schemes for the efficient flotation of complex gold ores containing free gold and/or gold associated with easily flotable sulphide minerals such as chalcopyrite and bornite. Historically, the design of gold flotation reagent schemes has been based primarily on experiences using high dosage levels of water soluble charged collectors such as xanthates and dithiophosphates and carefully controlled regions of pH. This approach has been effective with gold associated with complex sulphide minerals, in particular gold associated with iron sulphides such as pyrite. An alternative two-stage reagent approach is presented that is applicable to certain types of gold ores. This approach involves using very small dosages of uncharged water insoluble collectors at natural ore pH followed by a modified bulk flotation reagent approach for the second stage. The reasons for utilising this approach, when applicable, are discussed and illustrated with examples.

Jan 1, 1997

By Binns RA, Murao S

The PACMANUS and Jade deposits are two active hydrothermal fields that are forming massive sulfide deposits at the Pacific rim margin. Both are associated with felsic submarine volcanic rocks and both occur in back-arc settings. However, PACMANUS is associated with almost sediment-free dacites and lies on the crest of a volcanic ridge, whereas Jade occurs in a heavily-sedimented tectonic depression associated with a basement of pumiceous rhyolite. The PACMANUS deposit is richer in Cu and Au, and Jade in Pb. Zinc, Ag, As and Sb contents are similar. Sulfide textures at PACMANUS suggest formation of Cu and Zn sulfides by simultaneous double-diffusion involving inwards-moving seawater mixing with outwards-moving hydrothermal fluid. By contrast, at Jade there is a more complex history of formation where initial growth of barite on the sediment surface, probably associated with microbial activity, formed an impervious cap which trapped higher temperature hydrothermal solutions.

Jan 1, 1995

By Sarkis G. Ampian

Published optical microscopic and X- ray diffraction characteristics of the following compounds are critically evaluated and compared with Bureau of Mines data : Tricalcium aluminate , calcium monoa luminate , dodecacalcium heptaluminate , dicalcium silicate , tricalcium silicate , and sodium aluminate . A recommended set of definitive optical and X- ray diffraction characteristics is presented . These values are used to identify products of the lime soda sinter process for production of alumina . Polymorphism of gamma- , beta- , and alpha prime - dicalcium silicate is reexamined , and new data are presented on polymorphism of tricalcium silicate and sodium aluminate by high- temperature X- ray diffractometry . Polymorphism is not observed for tricalcium aluminate , calcium monoaluminate , and dodecacalcium heptaluminate . Bureau of Mines data indicating a stoichiometry of 12Ca0.7A10 for the phase 5Ca0.3A1 0₂ are discussed . A critical review of the literature concerning calcium dia luminate and sodium undecaluminate ( 8 -A10 ) is also included .

Jan 1, 1964

By S. J. Gasior

A method for destroying the caking properties of bituminous coal was developed by the Bureau of Mines. Coal is treated in a fixed bed by heating through its plastic range under controlled temperatures in mildly oxidative atmospheres composed of inert gas and/or steam containing about 1 volume-percent oxygen. High-volatile A (hvab) and high-volatile B (hvbb) and low-volatile bituminous (lvb) coals in the size range 1/8 to 1-1/2 inches were successfully treated at 0 (atmospheric pressure) to 300 psig in static beds 6 to 18 inches deep. Conditions of treatment depended on the coal and ranged from 80 to 200 minutes at 350° to 510° C. Char produced in this manner from hvab coal was gasified with steam at 800° C and 100 psig in a fixed bed in one series of tests and in other tests was exposed to hydrogen in a dilute co current free-falling-bed system at 750° C and 3,000 psig without agglomerating.

Jan 1, 1965

By Trevor Yeomans

"NVI Mining’s Myra Falls Operation is a forty year old underground mining operation feeding a 4000 mtpd concentrator.The current Mill, built in 1985, was designed to process a large massive sulphide ore-body. This ore-body, known as the “HW”, contains about 50% pyrite. Value minerals are chalcopyrite, and sphalerite, with precious metals occurring in all mineral types.By 1997, mining of a new ore-body, known as “Battle-Gap” commenced. Mineralogically complex, the new orebody contains about 15% pyrite, copper minerals including primary chalcopyrite, secondary bornite, chalcocite and tennantite, combined with increased galena and sphalerite.Flotation performance generally decreased with increasing amounts of Battle-Gap ore types, with both copper concentrate quality (increased lead and zinc content) and copper recoveries being affected.Following significant metallurgical testwork, a new fully sequential copper-lead-zinc flotation flowsheet and reagent scheme was developed.This sequential flowsheet was progressively installed and commissioned during 2006.Copper concentrate lead and zinc smelter penalty contents have been reduced by some 40%, whilst increasing copper recovery by 10%.INTRODUCTIONNVI Mining operates the Myra Falls Operation near Campbell River on Vancouver Island, BC. The complex has been in operation since 1966 with mining being predominantly underground. One unique feature of Myra Falls is that the mine operates within a BC Provincial Park.In 1985, a new large massive sulphide ore-body (HW) had been defined, and metallurgically tested. A new concentrator was built based upon this massive pyrite, chalcopyrite, and sphalerite mineralization producing copper and zinc concentrates by conventional flotation methods."

Jan 1, 2008

By A. D. Pelton, Y. -B. Kang, S. A. Decterov

Computerized thermodynamic databases for solid and liquid metal, slag and solid oxide phases in the Al2O3-CaO-CoO-CrO-Cr2O3-FeO-Fe2O3-MgO-MnO-NiO-SiO2-S system have been developed by critical evaluation/optimization of all available phase equilibrium and thermodynamic data. The databases contain parameters of models specifically developed for molten slags, liquid steel and solid oxide solutions such as spinels, pyroxenes, olivine, monoxide (wustite, periclase, lime), corundum, etc. By means of the optimization process, model parameters are found which reproduce all thermodynamic and phase equilibrium data within experimental error limits. Furthermore, the models permit extrapolation into regions of temperature and composition where data are not available. The databases are automatically accessed by user-friendly software that calculates complex equilibria involving simultaneously slag, metal, refractories and gases, for systems with many components, over wide ranges of temperature, oxygen potential and pressure. A short review of the available databases is presented. The critical evaluation/optimization procedure is outlined using the Al2O3-CaO-FeO-Fe2O3-SiO2and Al2O3-CaO-MnO-SiO2systemsas examples. Several applications of the databases to deoxidation of iron and to inclusion control in steel are discussed. Keywords: thermodynamics, phase equilibrium, phase diagrams, databases, ferrous metallurgy, steelmaking, inclusion control, slags, oxide systems.

Jan 1, 2004

By B. W. Gandrud

This is the third report published by the Bureau of Mines concerning the washability of Black Creek coal. Both of the former reports.5/6/ dealt with the Black Creek coal at the Bradford mine, Dixiana, Ala., near the northeastern extremity of the Warrior field, whereas the present report is based on float-and-sink tests of coal from what is presumably the Black Creek bed near the southern extremity of the field. Although the Yolande Coal & Coke Co., owners of the property at Yolande No. 6 slope, consider this opening to be on the Black Creek bed, the authors do not feel that there is as yet positive proof that this correlation is correct. There has been little or no development of the Black Creek bed in the Yolande Basin in the past, and a positive identification of the bed at Yolande No. 6 will have to await further exploration and development. The Yolande No. 6 is an exploration slope 3/4 mile north of Rockcastle, Ala. The slope is approximately 400 feet from top to bottom on a dip of 180. As far as the authors can ascertain, coal has never been produced commercially from the Black Creek bed in the southwestern part of the Warrior field. Exploration work in the past has indicated that the Black Creek coal in this area is extremely friable and high in sulfur. Extreme friability would naturally discourage its use as a domestic and railroad fuel, and high sulfur content would be a disasvantage in its use for coking coal. The present study of this coal has been made with particular reference to sulfur elimination on the assumption that it would make a good coking coal provided enough of the sulfur could be eliminated by washing.

Jan 1, 1939

By W Newns

This paper describes laboratory and in situ tests and determines a set of parameters for stiffness and strength properties for a weak sedimentary rock mass, the East Coast Bays Formation of Auckland. The parameters derived are discussed in relation to peak strength and in respect of deformation limits associated with sequential excavate and support (SEM) or conventional tunnelling.

Mar 8, 2011

By M. A. Reyes, L. Yan

Heat and humidity buildup withn refuge alternatives (RAs) may expose occupants to physiological hazards such as heat stress. The Mine Safety and Health Administration (MSHA) regulations require RAs in underground coal mines to provide a lifesustaining environment for miners trapped underground when escape is impossible. RAs are required to sustain life for 96 h while maintaining an apparent temperature (AT) below 95 °F (35 °C). The National Institute for Occupational Safety and Health (NIOSH) tested a 10-person tent-type RA, a 23-person tent-type RA, and a 6-person metal-type RA in its underground coal mine facilities to investigate the thermal environment over a 96-h period. The test results showed that mine air and mine strata temperatures surrounding an RA occupied by simulated miners (SMs) increased over the 96-h test period. The test results suggest that RA manufacturers should consider this increase in temperatures when calculating and evaluating RA components during surface and laboratory tests. The findings can equip stakeholders with additional considerations for calculating the interior heat and humidity temperature profiles for occupied RAs not tested in situ.

By M. S. Miller, R. H. Mullennex

The growing need for development of thinner, more erratic, or less easily-mined coals in the Appalachian region requires more detailed analysis of conditions and factors controlling or influencing deposition of these seams. The value of depositional modeling in evaluation of such coals has been demonstrated in many recent studies and publications. Such modeling may be applied to allow prediction of factors varying from regional coal occurrence trends to very local areas of seam discontinuities but requires thorough we of all available types of data. Mapping of general depositional energies, as derived from basic geophysical and driller's logs, can be applied to specific prediction of coal occurrence, and projection of particular facies as representative of unique depositional features or conditions may prove more applicable to coal character delineation than mapping of the coal itself. Depositional modeling and trend projection may also serve as a guideline in reserve classification and confidence levels in reserve estimations.

Jan 1, 1983

The common approach of designing blasts on a trial and error basis is quickly coming to an end. When utilizing the full scale blast environment, trial and error can quickly become cost prohibitive and leaves much to be desired in terms of true blast diagnostics. In these situations testing is usually only continued until a perceived improvement is achieved and when the gross undesirables in blast results are removed. This does does not preclude, however, that further improvements of up to 100% or more can not be obtained.

Jan 1, 1991

By Russo S

Metals Refining Operations Pty Ltd (MRO) began refining gold in PNG in 1991 and has undergone continuing growth since then in servicing an everchanging and growing market. MRO's ownership combines PNG Government interests and Golden West Refining Corporation Limited as operator.Features include a very diverse range of suppliers, a full range of technical methods and challenges and the financing and marketing responses unique to a developing country. These areas are examined and documented with special emphasis upon the service needs for the gold industry and future trends and challenges are discussed.

Jan 1, 1997

By M. C. Mound, E. Gallestey, C. Colbert

Continuous operating performance and high profit is one of the major concerns in the mining industry. Information systems are expected to reinforce and enable conformance to these requirements. The companion efforts of business management and production information systems press for tighter integration to avoid over-laps, multiple instances of similar data, and expensive maintenance of databases. Implementation of advanced intelligent systems throughout a mine operation can reduce costs, optimize investment and create a shorter payback via conversion of the data accumulated by field and process devices into information, and subsequently, into decisions. However, in order to harness the potential power inherent in these intelligent devices, adequate and flexible modular knowledge-based solutions are required. Fortunately, there has been at least one such practical response to this challenge, namely the ABB IndustrialIT portfolio. With these tools in place, production efficiency is reached via integration of process, production, and quality information. Moreover, they permit immediate detection and remedial action to changes to process and boundary condition variables. Finally, using advanced optimization techniques supported by dedicated mathematical models, they allow for economic process optimization (process set points and coordination thereof, energy management, production planning, energy supply contract optimization, etc) of the plant as a whole.

Jan 1, 2004

By A. D. Fowler, M. T. Anderson

A phenomenological model is presented that relates Pb-Zn mineralisation to proximal geopressure zones. Typically, geopressure zones (GPZ) consist of masses of undercompacted sediment encapsulated within impermeable shales and are characterised by high formation fluid pressures. Heat flow is perturbed in some GPZ on account of their insulating properties. Geothermal gradients as high as 150 degrees C/km have been observed over short distances in the sediments of the US coast of the Gulf of Mexico. Some modern geopressure zones are known to reach temperatures of 120-150 degrees C at depths of 2.5-3.5 km. It is demonstrated that the zones may act as proximal sources of hydrothermal fluids, thus explaining the high temperatures of mineralisation observed in the deposits, which are hosted in basins characterised by thick, rapidly deposited, shale-rich clastic sequences

Jan 1, 1991

By F Hancock

A rainfall simulator was developed to assist with hydrogeomorphic research into the stability of engineered landforms associated with rehabilitated uranium mines in the Top End of Australia. It can be used in rough terrain with slope gradients up to 30o. The rainfall simulator is modular, utilises upward jetting nozzles, has a multiple head arrangement and is capable of delivering rainfall intensities between 60 and 300 mmh-1 over areas up to 1000 m2 and could be easily modified for larger areas. Rainfall uniformity is commonly in excess of 80 per cent and the kinetic energy approaches that of natural rainfall (The modular design utilises an equilateral triangular array of rainfall stands, constructed from galvanised steel water pipes and flexible plastic hoses. Total construction costs are low. The water supply reservoir is mobile and easily constructed. An example of its use at Ranger Uranium Mine, investigating the effect of cover on rainsplash and rainwash dominated processes shows that vegetation cover is likely to reduce the erosion rate by these processes by at least four times below that experienced on bare areas.

Jan 1, 1997

By L. F. Heising

Ten composite samples of Mesabi Range nonmagnetic taconite from the Hibbing, Minn., area were evaluated by flotation and by reduction roasting-magnetic separation to determine their potential as a future source of iron are. Only one of the composites yielded concentrates that could be considered marketable, using as a criterion a 10-to-1 iron-to-silica ratio. Cursory petrographic examinations of all 10 composited samples and a detailed mineralogical study on 1 sample suggest that unfavorable mineralogical associations between iron and gangue minerals are responsible for their poor beneficiation characteristics.

Jan 1, 1967

By Liu Y, Campbell K. R

The paper shows how breakage parameters may he extracted from laboratory batch grinding results and how they may used with reference full-scale hall mill circuit data to estimate the likely size distributions of values and gangue in a full-sca

Jan 1, 1997