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By R. L. Player

"The Copper Isasmelt process has been developed over the past 15 years by Mount Isa Mines Limited (MIM) and the Commonwealth Scientific and Industrial Research Organisation (CSIRO). The first two commercial plants were commissioned in mid 1992.The results of four heat balances on the Mount Isa plant are presented. At a smelting rate of 98 t/hr of chalcopyrite concentrate plus 14 t/hr reverts, the total heat generated was -91MW. Approximately 39% of this energy came from coal, while 50% of the energy reported to the process waste gas. To a first approximation the furnace is near chemical equilibrium.The impurity distribution in the Mount Isa plant was presented. Approximately 91 % As, 85% Cd, 75% Bi, 68% Zn, 60% Sb and Tl, 45% Pb and 30% Te in concentrate was eliminated from the matte.The ""bubble"" frequency of the gas cavity below the foot of the lance was measured at -2. 1Hz. Side bands displaced by -l.lHz modulated the bubble frequency. This was consistent with radial gravity wave motion in the slag bath. The two processes, gas bubbling and wave motion appeared to be coupled together; the bubble frequency was twice the slop wave frequency. IntroductionCopper Isasmelt has been developed over the past 15 years by Mount Isa Mines Limited and the Commonwealth Scientific and Industrial Research Organisation. The process is based on the Sirosmelt lance, invented by researchers at the then Division of Mineral"" and ProcessEngineering ofCSIRO in 1973.The first two commercial scale copper furnaces were commissioned at Mount Isa and the Cyprus Miami Mining Corporation smelter at Miami, Arizona in August and June 1992 respectively.The process concept, the history of the development, and the Mount Isa plant have been described (1, 2, 3).This paper sununarises heat balances obtained on the furnace, the impurity distribution among the output streams and lance injection characteristics."

Jan 1, 1996

By E. Gybbon Spilsbury

(Pittsburg meeting, March, 1910.) THE recovery of gold and silver from their ores by means of the cyanide process has been so successful in the last few years that any radical improvement would seem impossible; yet the appliance to which I wish to call attention in this paper is really a radical departure from the methods now in general use. The most modern and approved of these, known as the all-sliming method, depends for its success on the grinding of the. ore so fine that practically 90 per cent. of it will pass through a 200-mesh screen. The slimes thus produced are then agitated and aerated in tanks of various types. The main object of this treatment is to insure such a thorough admixture of the pulp and solution that every particle of the ore is surrounded by a volume of solution sufficient to insure the dissolving of the whole of the gold- and silver-content. In addition, in order to expedite the action of the cyanide, and to oxidize such elements as would, if left in their active state, become cyanicides, air is blown in under pressure. In the Pachuca tank, this air is the active and sole means of agitation. The chief objections to all the methods off agitation used heretofore are the expense of operating and maintaining the mechanical devices for keeping the pulp in suspension, and the length of time required to obtain a fairly complete extraction. of the values. These objections are inherent to any method of agitation effecting a circulation of the pulp and the solution together, by giving the whole mass a circular movement, as in the low-tank system, or a vertical circulation, as in the Pachuca-tank system. In both methods, the particles of ore are kept traveling in the same direction as the solution, and with very little difference of speed; so that, while the whole mass is in

May 1, 1910

By Milton T. Pana

Computer techniques now have been applied to the solution of a wide variety of scientific and engineering problems in the mining industry, but generally not in great depth in any one area. In mining, the area covered in greatest depth and with the greatest success has probably been mine planning and to a lesser degree production scheduling. A rather comprehensive review of the literature related to mine planning and production scheduling indicates that contributions in these areas have been geographically, as well as organizationally, widespread. Of twenty-six papers reviewed, eleven were from industry, eight from educational institutions, four from computer vendors, two from the Bureau of Mines, and one from a private consultant. The conclusions that can be derived from the literature are: First, the-state-of-the art has advanced to the point that computing ore reserves and developing mining plans with the aid of the computer is now a routine practice; second, the application of the computer to mine planning problems has markedly improved our ability to estimate ore reserves, more accurately define pit limits, and determine an optimum mining sequence. MINE PLANNING The papers in this section deal essentially with the problem of determining the final pit limits of an orebody and the ore reserves associated with a given pit limit. The problem is probably best described by Soderberg25 and more recently by Reibell. 23. There are two techniques currently being applied to this problem by several mining companies: 1) the multiple-cone technique and 2) the Lerch-Grossman algorithm. The multiple-cone technique is the older of the two techniques and has the advantage of being more flexible, allowing an engineer to easily vary pit slopes in different sectors of the design. The technique can also be used to define intermediate pit contours. The Lerch-Grossman algorithm is appealing in that the final solution is given in the form of a true mathematical optimum. The technique is limited, however, in that the size of the blocks in the orebody model are a function of the desired

Jan 1, 1969

By Venda Oliveira P. J., Correia A. A. S., Danisi C. M.

"AbstractA laboratory study has been undertaken to establish common understanding of the creep phenomenon of a Portuguese soft soil chemically stabilised with binders. In order to study the effect of different stress levels on the strength and on the creep behavior of the stabilised soil, oedometer creep tests and unconfined compressive tests were performed at different curing times. Results show that the creep stress level does not influence the unconfined compressive strength. In addition, the creep phenomenon increases the unconfined compressive strength of the treated soil. Two different secondary compression indexes were recognized from the one-dimensional compression curve which increase with an exponential trend with the creep stress level.IntroductionConstruction on soft soils requires a mandatory soil stabilization work to improve mechanical characteristics of the natural soil. Deep mixing method is a worldwide employed ground improvement method, nevertheless the creep phenomenon hasn’t been yet thoroughly analyzed. Most of the published papers have focused on the analysis of the compressibility and the strength of the soil-binder mixtures without considering the creep phenomenon. However, numerical results (Venda Oliveira et al. 2009) have shown that although settlements that occur during the creep stage (namely creep strains) are less in case of treated columns, they are still important especially due to the high loads applied to the stabilised soil. The few published studies about creep behavior of soil-binder mixtures reveal that the stabilization of an organic soil with cement induces a reduction of creep deformations, which is related to the amount of cement used and that the increase of the organic matter of the soil has a negative impact on soil stabilization, further inducing a slight increase in the creep deformations (Venda Oliveira et al. 2012).As part of the current research the effect of different stress levels on the creep behavior of a soft clayey-silt soil was studied. The binder mixture used to enhance the properties of the soil had a specific composition and quantity. Unconfined compressive strength tests (UCS) and UCS creep tests were carried out at pre-set curing times in order to analyze the creep behavior of the soil-binder mixture. In particular five different creep stress levels were studied to understand its influence on the strength and on the compressibility of the stabilised soil. In addition, considerations about the secondary consolidation index are also presented."

Jan 1, 2014

By A. E. Wells

"When the United States entered the World War, the heavy requirements for sulphuric acid in the manufacture of explosives made necessary a definite knowledge of the sulphuric acid capacity of the country. The Bureau of Mines, under the authority conferred by the explosives regulation act, made a thorough survey of the sulphuric acid situation. In this work, which was personally directed by the writer, comprehensive data were collected on the situation and capacities of the various acid plants, sources of supply of raw materials (brimstone, pyrite, pyrrohotite, zinc ores and concentrates, waste sulphur dioxide gases from copper smelting, and spent oxide from gas works), the principal points in regard to manufacturing processes (chamber and contact) and the uses of the acid. The results of this investigaion have recently been published by the Bureau of Mines, as Bulletin 184, entitled ""The Manufacture of Sulphuric Acid in the United States"" by A. E. Wells and D. E. Fogg. The following paragraphs on the uses of sulphuric acid are abstracted from this bulletin.Sulphuric acid is one of the most important of all chemicals, not only because of the large quantities manufactured but also because of the wide use of the acid in many different industrial works. Sulphuric acid is to the chemical industry what iron is to metallurgy. The general public, however, does not realize this fact, for sulphuric acid does not appear in the finished product as does iron and steel, but is only a means to an end. It is essential in many industries, such for example as in the manufacture of phosphate fertilizers, explosives, dyes and petroleum products. In recent years in the United States, especially in the East, the demand for sulphuric acid for chemical and metallurgical industries has been an accurate and sensitive barometer of the general business conditions. This demand for acid responds much more quickly to a general slump or boom in the industrial world than does the demand for iron and steel."

Oct 1, 1920

By Karl Hoover, Cassandra Spence, Brent Bachewich, Jaakko Levanaho

"Since year 2000 the gold recovery into copper concentrate at Hudson Bay Mining and Smelting has reduced considerably during the summer months. This initiated a testwork program in the fall 2003 to find reasons and solutions for such change. During the testwork mineralogical factors, water quality effects and different reagents were evaluated. The reason for the lower recovery appeared to be the sensitivity of some collectors to pulp temperature. As a result of the work different collectors are being used in the mill in the summer than in the winter. A modification to the water system was also made to provide cooler water to the mill in the summer months.INTRODUCTIONHudson Bay Mining and Smelting (HBMS) is located in Northern Manitoba, just on the border of Manitoba and Saskatchewan. The complex consist of four different mines, Callinan, Trout Lake, Konuto Lake and 777 mine including copper smelter and zinc hydrometallurgical plants producing metallic copper and zinc. Gold is a very important byproduct providing about 30% of the mine revenue. In early 1990s when the company was facing declining ore reserves and was starting to gradually close down the operations, the 777’th exploration drill hole discovered a new orebody, which initiated a $0.5 billion expansion program. The main projects were a new 777 hoist with underground development and a new zinc cell house. About $30 million was used to increase the mill throughput to the present 2.27 million tonnes or 2.5 million short tons per year. The expansion programs were finished by the end of the year 2003.Historically the gold recovery at HBMS has varied between 60 and 70%. The recovery has been somewhat lower during the summer months. Gold recovery improvement projects were conducted throughout the 1990s, but were not focused on the seasonal gold recovery variance. However, since 2000, when the water system modifications to meet the increased water demand were completed, the gold recovery during the summer has been much lower than in the past. In August 2003 gold recovery fell below 30%, which initiated a metallurgical research program to discover the reasons behind the low gold recovery in the summer."

Jan 1, 2005

By W. G. Pfann

A simple method of obtaining multistage batch separations by crystallization was described recently. Known as zone-refining, it comprises passing short molten zones through a long solid charge. This technique can now be used on a continuous basis by means of the zone-void method described in this paper. Feed enters, at an intermediate point, a column down which molten zones travel, and waste and product leave at the ends. Materials move in the column through the agency of voids, which are introduced at the ends and travel toward the feed inlet. The voids and molten zones are moved by external heaters in a simple manner, and the principle of reflux is utilized. ANEW method of obtaining multistage separations by crystallization was described recently.' Named zone-refinina.,-, the method comwrises slowly passing a series of molten zones through a long solid charge. Solute becomes concentrated at one or the other end of the charge, depending on whether it raises or lowers the freezing point of the solvent. The separation increases with the number, P, of zone-passes, approaching a limit as P approaches infinity. Zone-refining has been highly effective in purifying germanium and other substances.2,3 and new applications are steadily increasing. Zone-refining is a batch method and as such it has certain limitations inherent in batch operation. If it could be made continuous, its scope and utility would be greatly broadened. This end has been achieved by the zone-void method described in this paper. In the zone-void method feed is introduced continuously at an intermediate point in a column down which molten zones travel, while impure waste and purified product leave at the ends. Both the flows of feed, waste and product, and also the travels of the zones, are actuated by external moving heaters in a simple manner; and the system utilizes the principle of reflux. The method provides, in the field of crystallization, the counterpart of the continuous fractiona-tion column in the field of distillation. The following will be discussed: apparatus and mode of operation, fundamental nature of the separation, design theory, and practical considerations. The method will be described in terms of a binary solute-solvent system in which the solute is an impurity to be removed and the solvent is the desired product. The distribution coefficient, k, defined as the ratio of solute concentration in the solid freezing out of a molten zone to that in the liquid in the zone, is assumed to be constant and less than one. The process is equally effective for k's greater than one and for ternary or higher order systems. Method and Apparatus The essential features of a continuous zone-refining process are represented in highly generalized form in Fig. 1. A series of molten zones, produced by moving heaters, travels slowly down the column or charge (to the left in Fig. 1). If there were no flows of feed, waste, or product, the process would simply be batch zone-refining, the action of the molten zones being to sweep solute down the column, solvent up the column. For the process to be con- tinuous, with stripping and enriching sections in the column, feed must enter, and waste and product must leave, as indicated. The zone-void process accomplishes both objectives, namely, the indicated movements of zones and the indicated flows of material. Zones are moved by moving heaters, just as in batch zone-refining. Materials are made to flow by creating voids at the waste and product exits and causing these voids to move to the feed inlet. Since there must be a net flow of material from the feed inlet to each of the outlets, the indicated movements of voids are in the desired directions, because movement of a void in a given direction corresponds to flow of material in an opposite direction. In order to produce the desired movements of voids, the column is folded into two vertical sections having the feed inlet in common at their upper ends. Voids are displaced upward by the liquids in the molten zones and their travel is actuated by the motions of the zones. Voids travel with the zones in the enriching section and move continuously. Voids travel opposite to the zones in the stripping section and move intermittently. Creation and travel of voids will now be examined in detail. The enriching section of a column in operation, with its void generator, is shown in Fig. 2. The column section is a vertical tube around which a series of closely fitting, regularly spaced heaters travel slowly upward. Each heater produces a molten region, the temperatures of the heaters and the cooling between heaters being controlled so as to maintain the molten zones approximately constant in size. A void is normally present atop the molten zone in each heater. As the heater rises, it continuously melts solid above it, which drips through the void into the molten zone and continuously freezes out solid below it, of concentration k times that of the liquid in the zone. When a molten zone and void reach the feed inlet, which is kept molten, the void is displaced by an equal volume of feed liquid. Generation of voids of controlled size in the enriching section is shown in Fig. 3. The void generator is a tube of small cross-section, provided with lateral heat-conducting fins which sense the position of the heater. Liquid can escape only when the entire outlet tube is within the heater. If any part of the outlet tube is outside the heater, liquid cannot escape,

Jan 1, 1956

By R. Webeler

In order to study the role of work hardening in the fatigue process, use was made of the great sensitivty of the resistivity of AuCu to cold work. A change of the resistivity of AuCu of the order of 1 to 2 pct at the temperature of liquid nitrogen was found to occur as a consequence of severe fatigue. ACCORDING to Orowan's theory,' the process of fatigue In metals 1s associated with the production of a number of small regions which have undergone strain hardening. This phenomenon is supposed to occilr even if the stress applied during fatiguing is always smaller than the yield stress. In an attempt to verity the existence of such regions, Welber and Webeler' undertook to detect the stored energy associated with severe fatigue in copper. Previous experiments" had shown that the energy stored in a sample of copper which has been cold worked by torsion is released in the temperature range between 150" and 250°C when the sample is heated from room temperature and that no more energy is released (or absorbed) between 250" and 450°C. In particular the stored energy amounted to 0.41 cal per g for a case in which the mechanical energy expended in twisting the sample was 11.9 cal per g. In the case of fatigued copper, however, no release of stored energy could be detected between 150" and 250°C, so that the experimental error of &0.02 cal per g represents an upper limit for the amount of energy stored in strain hardening., It seemed desirable to attack the problem in a new fashion. For this purpose, it was decided to make use of the fact that, if an alloy capable of undergoing the order-disorder transition is ordered and then cold worked, the resistivity, p, increases very greatly above the value for the ordered state even if the deformation is very small. Some insight into the nature of the fatigue process may be obtained then by measuring the resistivity of an ordered sample before and after subjecting it to fatigue. For reasons which will become apparent from the following remarks, considerably more can be learned by carrying out the resistivity measurements at two different temperatures. In the case of a material containing impurities, vacancies, dislocations, or other imperfections of essentially atomic dimensions, the resistivity, p, according to Matthiessen's rule, can be represented as a sum of two terms p = p, + p, where p, is the (temperature dependent) resistivity of the pure metal, and p, is the temperature independent contribution of the imperfections. Briefly, the physical basis for this rule is the following: The main contribution of the impurities in question to the resistivity results from the fact that they interrupt the periodicity of the lattice and thus scatter the conduction electrons with a probability which is almost independent of temperature. In order that this be the case, it is necessary that the' extension of the impurities be small enough—roughly less than one electron mean free path—so that their main effect on the resistivity occurs for the foregoing reason. If an alloy like AuCu is partly or completely disordered by quenching from an appropriate temperature, Matthiessen's rule also applies to a very good approximation* with p, representing in this case the resistivity po of the ordered sample and p, the additional (temperature independent) resistivity due to the disorder. In general, the disorder can be represented in terms of atoms which are displaced from their "proper" positions in the superlattice and which thus qualitatively represent the imperfections in the superlattice responsible for the term p,. Since the misplaced atoms are distributed at random throughout the super-lattice, their contribution to the resistivity still can be considered in terms of the scattering of conduction electrons by lattice defects. The situation is somewhat more complex in the case of an alloy disordered by cold work because the process of disordering here does not involve a random redistribution of the atoms; however, Matthiessen's rule also holds in this case. Whenever Matthiessen's rule does apply, the values of the quantity /3 = (p? — /(T, — T,), where p, and p, are the values of the resistivity at two fixed temperatures, T, and T,, respectively, is constant (independent of p,) for a given alloy or metal. In particular, if a sample of AuCu is subjected to ordinary cold work, the value of /3 remains equal to Po, the value for the ordered material. According to Orowan's theory,' as remarked before, a fatigued sample contains a large number of isolated severely cold-worked regions, which make up only a small proportion of the metal. Thus, if a sample of AuCu initially in the ordered state is fatigued, more or less disordered regions will be produced within the ordered material. If these regions are small enough so that Matthiessen's rule applies, then it follows from the previous discussion that /3 again will remain equal to Po. If the effect of fatigue is to produce cold-worked regions which are macroscopic—of the order of at least several electron mean free paths—the effective resistivity, p, has to be computed by use of the ordinary laws of large-scale electrodynamics. For the sake of simplicity, it will be assumed here that the cold-worked regions are completely disordered and have a resistivity, p,. For a given proportion A of disordered regions the effective resistivity, p, for the current in a given direction depends on the geometrical configuration of these regions. In any case, the value of p for such

Jan 1, 1956

By Fred N. Kissell, George H. Jr. Schnakenberg

INTRODUCTION A variety of instruments are available for measuring or monitoring the performance of underground mine-ventilation systems. In general terms, the instruments may be classified as those that measure air velocity and those that measure gaseous concentrations. All costs herein are in terms of 1978 US dollars. The mention of a specific manufacturer or device is not intended to be an endorsement by the US Bureau of Mines. AIR-VELOCITY INSTRUMENTS The basic instruments used for measuring the air velocity in mines are the vane anemometer and the smoke tube. Vane Anemometer Of the air-velocity instruments, the 102-mm (4.0¬in.) vane anemometer is the most common and is available as either a low- or high-speed type. The low-speed anemometer generally is the most suitable for measuring the velocities in ordinary airways. For a rough check of the velocity in an airway, it usually is satisfactory to hold the anemometer by hand, positioning it in the center of the airway for 30 sec. However, the resultant error may be as high as 25% , and such a hand-held approach is unsuitable when accurate or reliable measurements are required. To obtain more accurate measurements, the proper procedure is as follows: 1) Since holding the anemometer by hand generally causes the instrument to read about 15% high, it is mounted on a 0.6-m (2-ft) extension rod. 2) The airway is divided into equal right and left halves. A 1-min traverse is used in each half, moving the anemometer smoothly up and down in a zigzag pattern so that the entire half is covered within the allotted minute. 3) The manufacturer's correction table is applied to the readings to adjust the velocity calculation as necessary. Whenever possible, anemometer readings should be obtained in a long straight section of airway that has a constant cross-sectional area. Bends and obstructions should be avoided, since they cause turbulence and other discontinuities in the airflow and can degrade the accuracy of the velocity measurements. Although a series of velocity measurements at one location usually corresponds to within a few percent, this is not an indication that the airflows calculated from those readings are completely accurate. One reason is that the correction table provided with the instrument generally is not for that specific instrument; instead, it represents the average correction for all such instru¬ments made by the particular manufacturer. Most cor¬rection tables specify a correction factor of from 0 to 15%, depending upon the velocity. However, even after correction, the instrument error still may range from 3 to 5%. At low velocities such as those below 0.76 m/s (150 fpm), the instrument error can be two or three times greater than this, ranging from 6 to 15%. The new ball-bearing anemometers generally perform somewhat better at low velocities than did the older conventional anemometers. Another source of error is introduced when measur¬ing the cross-sectional area of the airway or entry. Under the best of circumstances, measurement errors, instrument errors, and a host of other minor errors all combine to cause a total error of at least 10% in the velocity calculation. The vane anemometer also can be used with reason¬able accuracy to measure airflows in mine-ventilation ducts. In this application, the anemometer is mounted on a rod and is held at the center of the duct end. For a duct that is discharging air, the average velocity in the duct is 85% of the centerline reading (Northover, 1957). For a duct that is taking in air, the average velocity is 70% of the centerline reading (Haney and Hlavsa, 1976). To measure the airflow discharged from a regulator or from a small hole in a stopping or bulk¬head, a correction factor for the area is necessary. A good approach in this situation is to traverse the area of the regulator or hole, holding the anemometer with an extension rod. This provides an average velocity that is multiplied by 85% of the measured area of the regulator or hole. In all cases, the manufacturer's instrument cor¬rection table must be used and applied properly. For accurate results, the anemometer should be returned to the manufacturer for periodic cleaning and checking. If it is in daily use, the anemometer should be returned about once per year, and proportionally less frequently if the usage is less frequent than on a daily basis. Smoke Tube The smoke tube may not appeal to individuals who believe that good measurement results can be obtained only with expensive, complicated, and fragile instru¬mentation. Nevertheless, smoke works about as well as anything for the routine measurement of low air velocities in mines. The following procedure yields reasonably good results: 1) Two marks are scratched 7.6 m (25 ft) apart on the floor of the airway. 2) The smoke tube is used to release a cloud of smoke in the center of the airway, about 0.9 m (3 ft) upstream of the first mark on the floor. 3) A timed interval begins when the leading edge of the smoke cloud passes over the first mark, and the interval stops when the leading edge of the cloud passes over the second mark. 4) A factor of 20% is subtracted from the cal¬culated velocity to determine the true average velocity, providing a correction for the centerline and for the spreading effect at the front of the cloud. Velocities calculated with the preceding method generally are accurate to within 10 to 15%. In some instances, the cloud from a conventional smoke tube

Jan 1, 1982

By L C. Taylor, H U. Lesiste

This paper describes a method for estimating the density distribution in the soil cap as a function of distance from its top at the time of impact with the target. It provides an estimate of the density distribution in the soil on the center line of the soil cap at the time of target impact for a single depth of burial of the charge and two heights of target and shows that, for the heights of target and the depth of burial considered, the thickness of the soil cap first increases from the in situ value and then decreases. The distribution of soil density along the centerline of the soil cap changes significantly with distance from its original position. These results can be used for validating hydro-code computations and the soil models used in the computations.

Jan 1, 2011

By Lei Pan, Roe-Hoan Yoon

"Sea water flotation is becoming a reality due to shortages of fresh water. To better understand the mechanisms involved in sea water flotation, we have studied the effects of KCl and MgCl2 on the surface forces present in the wetting films of water formed on hydrophobic surfaces. The measurements have been conducted using the force apparatus for deformable surface (FADS), which is capable of measuring both the surface and hydrodynamic forces responsible for bubble-particle interactions. The results obtained with the gold surfaces hydrophobized with butanethiol (C4SH) show that the wetting films of Ultrapure water do not rupture despite the relatively high water contact angle (??= 80o) and the presence of a long-range hydrophobic force with a decay length (D) of 25 nm in the film. The film is metastable with its equilibrium thickness (he) at 140 nm, where the repulsive double-layer force is equal in magnitude to the capillary force as shown in Figure 1. The film loses its metastability and ruptures in a 10-2 M KCl solution, in which the double-layer force decreases substantially due to the decrease in Debye length (?-1) while the decay length of the hydrophobic force remains as large as 23 nm.The effects of MgCl2 has also been studied using a C4SH-coated gold surface with a water contact angle of 87o. It has been found that in a 10-4 M solution double-layer force decreases due to the decrease in the negative ?-potentials and Debye length, which should help destabilize the wetting film. However, the film remains stable due to the decrease in the decay length of the long-range hydrophobic force from 45 nm in Ultrapure water to 14 nm in the MgCl2 solution. Thus, the results obtained in the present investigation support the view that the difficulties in sea water flotation may be due to the presence of MgCl2 rather than the presence of NaCl in sea water (Ramos, et al., 2013)."

Jan 1, 2016

By Akram Alfantzai, Farzad Mohammadi, Maysam Mohammadi

"Degradation of lead anodes has always been a major concern among the electrowinning industries. In this study, the effect of agitation of the zinc electrowinning solution on the integrity of lead anodes was investigated. Galvanostatic experiments were performed at 37±0.5°C using 0,600 and l000rpm magnetic stirring rates for 24 hours. The Pb02 layer formed on the anode surface was reduced to PbS04 (discharged). The discharge information was used to calculate the amount of Pb02 present on the surface. Weight loss measurements along with the discharge calculations revealed that the degradation rate of the lead anode increased as the solution was stirred more vigorously. Furthermore, the amount of remaining Pb02 on the surfaces was decreased as a function of solution velocity. Therefore, it may be concluded that, degradation rate oflead anodes is controlled by detachment of the corrosion products from the surface rather than by electrochemical reactions. IntroductionElectrowinning is one of the extraction stages of zinc, in which pure zinc is deposited from acidic solution after froth flotation, roasting and leaching processes. The anode electrode materials play important roles in the electrowinning process. Their electrocatalytical capacities determine the oxygen evolution overpotential, and consequently the cell potential and energy efficiency of the zinc electrodeposition [l]. Purity of the zinc deposited on the cathode is affected by the solubility and corrosion resistance of the anode materials. Using insoluble materials as anode in the electrowinning leads to the higher purity of the deposited metal on the cathode[2]. Lead (Pb) and its alloys have been used as the anode in the zinc electrowinning because of its special properties such as relatively low cost, low melting point, insolubility in solutions containing sulphuric acid and high conductivity in both states of metallic and oxidized [3, 4]. In zinc electrowinnig, zinc reduction occurs on the cathode (reaction 1) and the oxygen evolution reaction (OER) (reaction 2) is the main anodic reaction [5, 6]."

Jan 1, 2013

Executive Committee. GEORGE F. KUNZ, Chairman. E. GIBBON SPILSBURY, Vice-Chairman. THOMAS ROBINS, H. J. SEAMAN. Louis D. HUNTOON, Secretary-Treasurer. Meeting, Apr. 4, 1913. A joint meeting of the New York Section of the American Institute of Mining Engineers, the American Society of Mechanical Engineers, and the American Institute of Electrical Engineers was held in the large auditorium of the Engineering Societies Building, 29 West 39th Street, on Friday evening, Apr. 4, 1913, and an exhibition of the Edison Talking Moving Pictures was presented before the Societies, together with exhibitions of the work which is being done by the Edison Co. in making moving pictures to illustrate lectures on natural science and the useful arts for school and college work. Introductory remarks were made by Mr. J. W. Lieb, Jr., and followed by an exhibition of moving pictures illustrating the formation of crystals, the operation of different types of pumps, magnetic forces, electro-magnetic separation of iron ore, the evolution of the fly, and many other most interesting studies. One of the films, entitled The Formation of Crystals, showed a moving picture of a boy, whose laboratory was the kitchen, dissolving salt in a test tube filled with hot water. The boy then poured the solution of hot salt into a watch glass and placed it under the microscope to watch the crystals form. This film was immediately followed by another showing what the boy saw through the microscope. The solution at first was free from crystals. Gradually the crystals commenced to form and increased very rapidly after once starting, shooting across the screen with lightning speed. The film illustrating the separation of iron ores by the Edison electro-magnet showed an ore bin with an electro-magnet set at one side and below the bin. As the ore was dropped from the bin the magnetite was drawn into the. electric field and deposited in a separate rile from the sand.

Jan 5, 1913

Arrangements have been completed in New York whereby the re- sources of The Engineering Foundation, under the auspices of the four principal national engineering societies, are placed at the disposal of the National Research Council, which was appointed by the National Academy of Sciences* at the request of President Wilson. The object of the Council is to coordinate the scientific research work of the country in order to secure efficiency in the solution of the problems of war and peace. The Council was without funds until The Engineering Foundation, established to further scientific and engineering research, offered to place its resources at the Council's disposal, including the services of its secretary, Dr. Cary T. Hutchinson, to act as-secretary of the Council. The offer was accepted and plans for immediate activities have been placed in the hands of an executive committee. In indicating how thoroughly, every branch bf science and engineering is represented, Dr. George E. Hale, Director of the Mt. Wilson Solar Observatory, and Chairman of the Council, when he was in New York attending to the details of the arrangement, called attention to the personnel of the body, saying that it is the purpose to enlist the cooperation, in the solution of our industrial and military problems of a scientific character, of every possible established agency. Medicine, for example, is represented on the Council by Dr. William H. Welch, President of the National Academy of Sciences, Brigadier General William C. Gorgas, , Surgeon Crenera.1 of the United States Army, Dr. Simon Flexner, Director of the Rockefeller Medical Institute, and Dr. Victor C. Vaughan, Past President of the American Medical Society; biological science by Dr. Edwin G. Conklin, Professor of Zoology, Princeton University; chemistry by Dr. A. A. Noyes of Massachusetts Institute of Technology and Dr. L. H. Baekeland; physics by Dr. A. A. Michelson of the University of Chicago; and electricity by Professor M. I. Pupin, of Columbia University.

Jan 10, 1916

COLUMBIA SECTION STANLY A. EASTON, Chairman, FREDERIC KEFFER, Vice-Chairman, L. K. ARMSTRONG, Secretary-Treasurer, P. 0. Drawer 2154, Spokane, Wash. D. C. LIVINGSTON FRANK A. Ross The first meeting of the Columbia Section was held on March 24, as a part of the 1916 Northwest Mining Convention which was held under the -auspices of the Spokane Mining Men's Club assisted by the Spokane Chamber of Commerce, the technical program being in charge of the Spokane Engineering and Technical Association assisted by the local sections of the A. I. E. E., A. S. C. E., and A. I. M. E. The program of the successive sessions was carefully arranged with view to its application to mining, and in addition to the technical program there were exhibits of ores, minerals, devices, etc., of interest to the delegates, who numbered over 500. A portion of the program was also arranged with special reference to the requirements of the prospector and miner. A reception, a banquet, a complimentary luncheon, a regular daily call' of the Stock Exchange, a visit to the High Schools and to one of the substations of the Washington Water Power Company and to the Union Iron Works kept the visitors entertained, the ladies being looked after by a special committee of ladies who held open house during the entire week. Several important resolutions were passed by the Convention and one by the Columbia Section, A. 1. M. E. With Stanly A. Easton, chairman, presiding, the Columbia Section, American Institute of Mining Engineers, occupied the time between 2.00 and 5.30 p.m., March 24th, the Moorish room of the Spokane hotel being filled with members and their guests. "The Apex Law and the Mineral Surveyor" was a paper presented by F. W. Callaway and generally dis-cussed because of its local application in the Coeur d'Alenes, the conclusions being reached after expensive litigation between two of the large mining operators in that district.

Jan 6, 1916

By Guy Jordan

HIGH-IRON cements have a number of advantages over cements carrying little or no iron. The presence of iron in, Portland cement aids in the manufacture of the cement and also imparts certain advantageous physical properties to the finished product. In manufacture, the presence of iron lowers the fuel consumption, increases the ease of proper burning, and lessens the destructive action of the charge on the kiln refractories. In the finished cement the presence of iron reduces the expansion and contraction, adds strength, adds increased resistance to freezing and thawing, and increases the resistance of the cement to sea or sulphate waters. During the past few years the construction of numerous dams through-out the Southeast by the Tennessee Valley Authority has stimulated the production of high-iron cements. At present a great number of specifica-tions call for an iron cement, and the industry is supplying this demand with a Portland cement carrying approximately 5 per cent iron oxide. Several manufacturers are now making practically all of their cement of this type and a number of others manufacture it as a special cement over short periods to meet demands from the Tennessee Valley Authority and other buyers. The recent increase in the use of iron in Portland cement has created a market for iron products that previously was nonexistent. The chief sources of supply for the cement manufacturers at present are iron sand, iron sinter and slag, and ocher. The Copperhill mining district, Ten-nessee, supplies both iron sinter and slag for use in cement. The Carters-ville district supplies iron sand, ocher, and some iron resulting from the magnetic separation of iron from barite. The advantages of these products vary according to the chemical properties of the raw materials and the methods of handling used by the different manufacturers. Where the iron is to be handled by conveying belts and in hopper cars, the iron

Jan 1, 1939

By Courtenay DeKalb

The accompanying illustrations, Figs. 1 to 6, from plans drawn by Mr. T. L. Knapp, a student in the Missouri School of Mines, show a type of furnace designed by the writer, which possesses some peculiarities intended to meet the necessities of laboratory-instruction in that institution. The object aimed at was the construction of a simple, inexpensive furnace, suitable for the distillation of zinc from its ores, and using only a single retort. This limitation imposed the chief difficulty, owing to the necessity of obtaining a high degree of heat concentra ted upon the retort. This is accomplished by the peculiar curve of the arch, which consists of arcs of seven distinct ellipses, one focus of each of which lies within the area occupied by the retort. Thus the reflected heat would necessarily be thrown mainly where most needed, namely, on the retort. Conservation of heat is provided for by a return-flue through the hollow arch, and by a sand bottom under the fire-brick hearth. Four openings lead back from the laboratory, or heating-chamber in this instance, to the arch-flue; and three openings lead from the arch-flue to a large horizontal flue, from which a down-take conducts the gases to the stack. The fire box, it dl be observed, is deep, thus producing much CO during the combustion of the coal. The further combustion of this CO may be accomplished by the admission of air through the hollow fire-bridge, thus producing a higher flametemperature surrounding the retort. Provision is also made for removing the retort and the portion of the wall supporting it and the condenser, leaving a high arch, into which a door-frame may be inserted; the space above being temporarily bricked in. By this alteration, which may be quickly and easily made, the furnace may be converted into a reverberatory, suitable for treating small charges such as

Jan 1, 1898

By J. Yvon, Inna V. Filippova

"The aim of this work is to seek the inhibitors of the meteoric and bacterial dissolution of sulphides and gangue minerals to stop the undesirable chemical reactions during conservation of the flotation wastes. The approach of passivation of surfaces by chemical treatment of the solid phase is applied for this objective.The samples taken from different depths of an old French waste dump revealed the capacity of the flotation tailings to produce acid waters (pH 1.8-2.4) and to release heavy metals. Mineralogical studies show not only the product of sulphide oxidation, i.e. sulphates, but also the complex transformations of aluminosilicates in acidic liquid phase. The detection by XRD of aluminium hydroxides (gibbsite, boehmite) allows supposing the recrystallisation phenomena during tailings conservation.Comparative tests of the passivation of the surface of sulphide minerals and waste of flotation with using of conventional reagents (CaO, NaOH, phosphates) and original reagents for this purpose (alkyl dithiocarbamates) allow to identify the optimal treatment conditions and the efficient chemicals.Leach tests were carried out in percolation columns during 68 weeks. The normalised leaching tests according to French legislation were run to confirm the selected treatment conditions. The results obtained show that a single treatment with carbamate inhibits the oxidation of the pyrite and the other sulphides, and totally prevents the formation of acid waters (the stabilised pH was 5.3-5.8). Treatment of in situ drainage water allows to obtaining a total precipitation of heavy metals: the residual concentrations of Fe, Cu and Zn are lower than 0,1 mg/l.The passivation of sulphides is the result of the formation with carbamate (studied by IR spectroscopy and XPS) of organometallic compounds, which are stable in acid medium. The presence of thiuramdisulphide (product of alkylcarbamate oxidation) at the mineral surface stabilises the mixed adsorption layer and leads to a considerable reduction in the hydratation rate of surface by avoiding the corrosion of the pyrite. No aluminium was detected in leach solution with this treatment."

Jan 1, 2003

By David P. Hale, Guy W. Jordan

HIGH-IRON cements have a number of advantages over cements carrying little or no iron. The presence of iron in Portland cement aids in the manufacture of the cement and also imparts certain advantageous physical properties to the finished product. In manufacture, the presence of iron lowers the fuel consumption, increases the ease of proper burning, and lessens the destructive action of the charge on the kiln refractories. In the finished cement the presence of iron reduces the expansion and contraction, adds strength, adds increased resistance to freezing and thawing, and increases the resistance of the cement to sea or sulphate waters. During the past few years the construction of numerous dams throughout the Southeast by the Tennessee Valley Authority has stimulated the production of high-iron cements. At present a great number of specifications call for an iron cement, and the industry is supplying this demand with a Portland cement carrying approximately 5 per cent iron oxide. Several manufacturers are now making practically all of their cement of this type and a number of others manufacture it as a special cement over short periods to meet demands from the Tennessee Valley Authority and other buyers. The recent increase in the use of iron in Portland cement has created a market for iron products that previously was nonexistent. The chief sources of supply for the cement manufacturers at present are iron sand, iron sinter and slag, and ocher. The Copperhill mining district, Tennessee, supplies both iron sinter and slag for use in cement. The Cartersville district supplies iron sand, ocher, and some iron resulting from the magnetic separation of iron from barite. The advantages of these products vary according to the chemical properties of the raw materials and the methods of handling used by the different manufacturers. Where the iron is to be handled by conveying belts and in hopper cars, the iron

Jan 1, 1939

By Maurice Ewing, L. Don Leet

The most important quantitative method in seismic prospecting by refraction shooting is the method of profiles. A profile is established by firing a series of charges at various points along a straight line which terminates at the seismograph. The same data are obtained by repeatedly firing charges at one place and recording at a series of stations along the line of the profile. The quantities which are measured are the distance x from each firing position to the seismograph and the time t required for the first disturbance from each explosion to travel to the seismograph. These data are used in plotting the familiar time-distance graph. The only time-distance graphs that will be considered here are those obtained in localities where the velocity of propagation depends solely on the depth beneath the surface; that is, where there is no slope in the subsurface. The essential calculation to be made from such a time-distance graph is the determination of P(x), the maximum depth of penetration of a disturbance coming to the seismograph from a firing point at the distance x from the instrument. If the time-distance graph consists of a series of straight lines, as is often the case, the penetration P(x) can be calculated by means of formulas which appear in almost every description of seismic prospecting.' Until the present, however, the only formula that has been available for calculating P(x) for time-distance graphs which are smooth curves is one which requires an arbitrary assumption regarding the law of velocity increase with depth.2 The practice in these cases has been to approximate the curve by means of a number of straight lines and then to apply the ordinary straight-line formulas. This method clearly can yield accurate results only when a sufficiently large number of straight lines is used. The labor of computation increases rapidly when the number of lines is increased, so too few lines often are used. Further than that, there is a strong tendency to overlook the approximate nature

Jan 1, 1932