Search Documents

By Malcolm T. Hepworth

RECENT interest in thermoelectric devices has been directed toward studies of the properties of thermoelectric materials of semiconducting solid compounds with little attention given to ionic and semiconducting liquids such as aqueous solutions, fused salts, and mattes. One type of thermoelectric system is the thermocell: a nonisothermal galvanic cell with two identical electrodes at different temperatures connected by an electrolyte bridge. An electromotive force, v, is generated which is a function of the electrode reactions and the properties of the electrolyte according to the Eastman' equation: where S* is the entropy change of the system arising from the electrode reactions and by heat transferred by ion migration and by thermal conduction. The quantity nF is the product of equivalents passed and Faraday's constant. A value of S* of 23.06 cal per "C is equivalent to 1 mv-Faraday per "C. The symbol, a, is used for dV/dT in analog to the See-beck coefficient of solid-state thermoelements. de Bethune2 has calculated the temperature coefficients of the electromotive force of a large number of nonisothermal aqueous cells from measurements on the nonisothermal temperature coefficients of the standard hydrogen electrode, combined with data on the isothermal temperature coefficients of half-cells tabulated in the literature. Values of these coefficients (a) in de Bethune's compilation ranged up to 3 mv per C. In particular he reported a value of +2.059 mv per "C at 25'C for the cell: Fe (aqueous, unit activity) (aqueous, unit activity) written for the hot-electrode reaction. The positive sign indicates that the hot electrode is positive (an "n-type thermocell"). In analog to a solid-state p-n system, it would be possible to couple two thermocells together to form a system in which the figure of merit could be calculated by adding the temperature coefficients according to the relationship described by offee:' where a is the Seebeck coefficient in volts per "C, p is the specific resistivity in ohm-cm, and K is the thermal conductivity in watts per cm "C. Even though ionic systems have rather high electrical resistivities compared with semiconducting and metallic systems, it was felt that a preliminary study of one ionic system should be made to establish some basis for evaluating the possibility of a p-n thermocell for energy conversion. Accordingly the Fe", Fe"' system was studied as a possible component for a p-n system. A glass system was constructed consisting of two vertical water-jacketed tubes connected by a horizontal tube, Fig. 1. Platinum-black electrodes 1 cm by 1 cm in dimension were inserted in each vertical tube with thermometers to register the electrode-compartment temperatures. The temperature of the electrode compartments was controlled by circulating water from thermostatted baths around the electrode compartments. The electromotive force of the cell was then read by a potentiometer for zero current as a function of the temperature of the hotter electrode. Current output of the cell for varying external loads was also measured. The cell resistance was measured by means of a bridge circuit with 10,000 cps signal and oscilloscope. Resistance measurements were converted to specific resistivity by calibrating the cell with a solution of known conductivity.

Jan 1, 1965

By John Lindsay

"Although diamond mining is a relative newcomer to the Canadian mining industry, with the first diamond mine coming on stream in 1998, Canada is already a significant producer of high quality diamonds. This paper will review diamond production trends and highlight some of the projects currently under development, which have the potential to enhance Canada’s role as a significant diamond producer.Diamond recovery plants generally incorporate well-established mineral processing and recovery techniques, with issues such as product security, cut-off sizes, and diamond preservation becoming important considerations when developing process flowsheets. A diamond processing plant must achieve three key objectives, namely:• Liberation of the diamonds from the host rock;• Separation of the heavy minerals, which include the diamonds, from the host rock;• Recovery of the diamonds from the heavy mineral concentrates.Processing technologies and equipment commonly utilized in diamond processing plants will be reviewed and some of the significant issues associated with each option briefly discussed.Typical process flowsheets will be presented.Finally, an overview of De Beers’ Victor diamond project, located in northern Ontario, will be provided. This potentially significant diamond producer is currently at a pre-feasibility stage of development.DIAMONDS IN CANADAWorld Diamond ProductionCommercial diamond mining commenced in earnest with the discovery of the Kimberley diamondfields in South Africa in the late 1800s, and this resulted in a dramatic increase in the supply of diamonds. As can be seen from figure 1, world diamond production, mainly from South Africa, Angola, Congo, and Namibia, remained relatively constant through the early 1900s until the development of the large Russian kimberlite pipes in the 1950s. Production increased again in the 1960s and 70s with the development of the Botswana mines, but the most significant increase in global production came from the Argyle mine in Australia, which came on stream in 1983 and produced a peak of almost 43 million carats in 1994, representing approximately 40% of the world market. Production from Argyle has since fallen-off as grades have declined and the strip ratio has increased with the deepening of the open pit."

Jan 1, 2003

By Oliver Zach

To know as much as possible about the condition of the refractory material (lining thickness, slag layer, build ups, ...) in an high temperature furnace is very important due to the safety and economic impacts. The new CONSCAN system offers the possibility to measure the inner surface of an furnace, and based on this results to calculate the thickness of the refractory lining, slag layer, build ups,.... The CONSCAN System provides this results as figures and graphics. This system is also working under hot conditions so it is not necessary to cool down the furnace. Based on these results the process control and the refractory lining concept could be optimized for maximum campaign life of the furnace.

Jan 1, 2006

By David P. Reddick

"Suncor Inc. Oilsands Group mining operation in Northern Alberta, Canada, has been blasting to loosen the oilsands to increase production and decrease maintenance of the bucketwheel excavators for over twenty years. In 1991 an area of the mine was encountered which had a working face of 130 feet rather than the usual 20 to 57. In order to maintain production objectives, the planning and blasting departments of the mine took on the task of blasting as much of the working face as possible. McGinnis Rathole Drilling Company provided the drilling for the project and Mining Services International (MSI) delivered the bulk explosives to the boreholes. It is believed the resultingblasts exceeded several known records in production blasting."

Jan 1, 1992

By D. S. van Vuuren

Over the last 60 years many different processes were conceived to reduce the cost of titanium produced by the Kroll process. However, success eluded all previous efforts, which were consequently terminated in periods of economic downturn. Recently, the grow thin demand for titanium and the high cost of producing the metal again sparked renewed attempts in various parts of the world to replace the antiquated Kroll process with a more efficient route. The different options to produce titanium are reviewed, classified and evaluated in terms of the fundamentals underlying the technologies, and it is shown that the options considered to be the most likely to replace the Kroll process, are continuous processes to reduce TiCl4 metallo-thermically to titanium powder. Of these, continuous magnesio-thermic reduction of TiCl4 would conceptually result in the lowest-cost and highest-value product. However, when considering by-product salt removal from the titanium product and recycling of the salt as well, sodio-thermic reduction of TiCl4 is better.

Jan 1, 2009

By R. J. E. Stewart

Another very successful evening meeting was organized by the Johannesburg Branch of The South African Institute of Mining and Metallurgy on 20th November, 1990, when Mr R.D. MacPherson, General Manager of Richards Bay Minerals, gave a presentation on the Richards Bay operations. The function was held in the Ballroom of the Johannesburg Country Club, and the very high attendance (some 250 people) was indeed a reflection of the high profile of the subject mater. It was also a fitting reward for the efforts of Mr MacPherson and his team, who spent a considerable amount of time and effort traveling the country to present 'the other side of the story'.

Jan 1, 1991

Four engineering products and three consumer products have received awards in the 1978 Shell Design Awards competition organized by the Design Institute of the South African Bureau of Standards. Norman Hanson Visiting Fellowship The Norman Hanson Visiting Fellowship, supported jointly by the National Development Fund for the Building Industry (inaugurated by the Building Industries Federation (8.A.)), the Institute of S.A. Architects, the Association of S.A. Quantity Surveyors, and the National Building Research Institute of the CSIR exists to finance fully or wholly visits by eminent authorities from overseas to South Africa for the purposes of seminars, informed discussions, consultation, and possible active participation in scientific, technological, and development projects of importance to the building industry.

Jan 1, 1979

By J. Jeremy Burden, Bruce S. Brown

A major question in the design and permitting of a tailings storage facility is the quality and quantity of seepage which will occur from the base of the tailings facility into the underlying foundation and groundwater regime. A corollary to this is what liner system, if any, is necessary to protect the groundwater regime from unacceptable contamination. Modern tailings storage facilities are generally designed as drained tailings deposits whereby all free water is removed from the facility by decant, drainage and evaporation. This removes the source of on­going seepage and allows for efficient and timely reclamation of the facilities. Quantifying the residual seepage from the base of the tailings deposit is complicated due to the following factors:

Jan 1, 1992

By R. J. Wahrer

In 1996, the Office of Surface Mining (OSM) and the U.S. Fish and Wildlife Service (FWS) completed an Endangered Species Act (ESA) programmatic Section 7 consultation. From the resultant Biological Opinion, it was found that coal mining operations conducted under federally approved state regulatory programs would not likely jeopardize the continuation of federally listed species nor result in the destruction or adverse modification of critical habitats. The requirements of the ESA and their integration into the SMCRA permitting process and the responsibilities of the regulatory agency, the FWS and the coal operator will be discussed. Guidance on the development of protection and enhancement plans will be provided and site-specific examples given.

Jan 1, 2003

By Dewey W. Marino

Conventional remote sensing applications for the exploration of natural resources has largely been the domain of low resolu­tion Earth orbiting systems such as Landsat™ which can sample a broad range of the spectrum. As the classic application of remote sensing, it has proven its worth through the discovery of numerous mineral deposits worldwide. Often this technique relies more on the spectral content of the imagery for narrowing potential sites on the ground, but often cannot reveal the detailed context of the observed response. As the dawn of the new era in remote sensing grows closer, high-resolution imagery is proving its worth for the definition of mineral potential and its cost sav­ing advantages for mine management.

Jan 1, 1998

The design of drawpoints in caving and stoping mines has a significant impact on the productivity of the operation. Drawpoints must be designed to provide uniform drawdown and maximum recovery of the broken ore within the limits imposed by the dimensions of the stope, the stability of the pillars, the method of draw, material flow characteristics, etc. The design of drawpoints historically relied on the mining engineerÆs experience and intuition. However, in many operations, empirical analyses have also produced important information regarding design geometry. Factors that affect the sizing and spacing of drawpoints are discussed and guidelines are provided for their design in order to obtain maximum recovery of broken ore and reduce hang-ups.

Jan 1, 2000

By Hoerger Steve

Minera Yanacocha S.R.L. (MYsrl) operates the largest gold mine in South America near Cajamarca in Northern Peru. In 2002, the minera set the goal of being the world’s best heap leach gold operation in terms of efficiency, safety and environmental performance. In support of this goal, the long term planning function seeks to maximize the value of MYsrl’s resources. This includes not only the value of the orebody, but also the value of all past and future investments and the value of the company’s relationships with its employees, the environment and the local communities. All of these components will be critical to MYsrl’s continued long-term success.

Aug 25, 2002

Senator Smoot recently introduced his bill providing for the leasing of oil and coal lands. This bill provides only for the leasing of these lands from the Government and advocates government ownership of all government coal and oil lands. Under the provision of the bill as now proposed, 50 per cent. of all money received under the measure is to be paid to the state in which the land is located. The money must be used, however, for the construction and maintenance of roads and for schools. The last leasing bill was defeated when it was about to become law largely because of the fact that it allowed the sale of coal lands.

Jan 9, 1919

By P. Pages, J. Lombard, F. Fagnant, G. Bresson

This study is devoted to the improvement of the decision-making process in occupational protection of uranium miners in France. Its purpose is to apply the principles which are recommended by the I.C.R.P. in the field of radiation hazards. These principles, which have introduced the notion of "optimization" in standard setting, suggest the importance of applying cost-benefit and cost-effectiveness analysis to this sector. The objectives here are twofold : to evaluate the present organization of radiation protection on the basis of a simulation model of polluted air flow in the mine (due to the decay of a radioactive gas, radon) and to develop cost-effectiveness analysis of the various radiation protection policies.

Jan 1, 1981

By M. R. Moharam

The well-known formulae of screening efficiency and circulating load calculations in closed crushing circuits were exploited to achieve graphical estimation of these parameters. Three basic charts were proposed and constructed. The first one is for the regular closed circuits where the new feed goes to the crusher. The second is for the reverse closed circuits in which the new feed reported to the screen is free of screen undersize particles. The third chart controls the reverse circuits when they are receiving new incoming feeds containing undersize material. Compound circuits were also reanalyzed and a concept of equivalent simple circuit was introduced to enable graphical manipulation of these complex circuits with the help of the aforementioned charts

Jan 1, 1982

By P. Somasundaran, A. Sivakumar

Surfactants and polymers are used in a number of processes such as flotation and flocculation. The structure of the adsorbed surfactant and polymer layers control the interfacial properties of the solid and hence an understanding of the structure of the adsorbed layers at the molecular level is essential. In this paper, a review of different spectroscopic techniques (fluorescence, electron spin resonance and Raman) used to characterize the adsorbed layers [in-situ] is presented. Information on the micropolarity, microfluidity and size of the surfactant aggregates was obtained and the growth of the adsorbed layer was followed. [In-situ] conformational states of polymers at the solid/liquid interface were determined for different pH values.

Jan 1, 1989

By Yu-Jun Z

According to site measurement and labora- tory experiment, the authors suggest a new mathematical model of grouted rock bolts. The rock bolt is taken as an elastic bar, and the grout is substituted by a set of springs the rigidity of which is given as K. Based on certain assumptions, a simplified formula is deduced. When the category of rock, depth of tunnel, the spacing of rock bolts and the rigidity of springs K values are given, so that we can calculate the radius of plastic zone, and subsequently the convergence of rock at the tunnel inner surface u, and the resis- tance exerted by the rock bolt p. Finally, the length of rock bolt can be determined.

Jan 1, 1987

By E. M. Alcântara

This paper describes some aspects about the relationship between copper electrorefining addition reagents and the hydrogen in the cathode. The conditions of electrorefining were studied by factorial design methods. The advantages of this technique are reduction in the number of tests, well organized experiments; improvement in productivity and reliability of results. The dosage of the two main addition agents, glue and thiourea, were varied simultaneously and compared with the hydrogen content in the cathode. The influence of these factors, as well their interactions were analyzed by statistical methods denominated ANOVA (Analysis of Variance). The increase of thiourea quantities, within of levels studied, influenced significantly at 95% confidence in the hydrogen content in copper cathode.

Jan 1, 1999

By W. Dalmijn, H. de Ruiter

"The decline in students for mining and metallurgical engineering in the last few years has lead to the closure of many university departments in all first world countries around the world. Three independent studies carried out in Europe, Australia and North America indicate that during the next decade the demand for mining, minerals processing and metallurgical engineers will be significantly higher than the supply. Demand for engineers will increase even more because many of the professionals in industry are about to retire within the next 5 years. Meanwhile mining is a growth industry, minerals demand continues to increase in line with the growth in World GDP, as illustrated in the Graph at the end of the paper."

Jan 1, 2005

The Board of Directors on April 18, 1940, adopted a resolution providing that "no person who has been awarded any one of the four medals-Douglas, Saunders, Lucas, and Rand-is eligible for consideration for any other of the four medals " Later in the year the rules for the award of these four medals were revised and, so far as practicable, made uniform The medalists are elected by the Board of Directors, on recommendation of special standing committees of award, appointees on which serve four-year terms and are engaged in the branch of industry represented by the respective awards Under the rules only members of the committees of award are eligible to propose candidates\ for the nomination

Jan 1, 1952