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By Robert W. Curtis

Kaiser Aluminum & Chemical Corporation's (KACC) entrance into the alumina market began in 1946 with the purchase of a small plant in Baton Rouge. Louisiana. Since that time KACC has been involved with the design, construct; on, and operation of many alumina plants around the world. One of these plants is located in Gramercy, Louisiana. The Gramercy Works is a multiplant installation consisting of an alumina plant, a caustic-chlorine plant, a petroleum coke calciner and a fluorochemicals plant. Each of these plants require their own specific environmental control programs to abate pollution. Kaiser has made significant progress through the years on their own initiative in pollution control. But many new challenges have been and continue to be created with the enactment of environmental laws. The 1970 Clean Air Act Amendments, the resurrection of the old "Refuse Act" in 1970 and finally the 1972 Federal Water Pollution Control Act Amendments prompted the formulation of our current philosophy towards the abatement of pollution. Since the formulation of these complicated pieces of legislation, others equally complicated, have come to being. The Federal Insecticide, Fungicide and Rodenticide Act as amended by the Federal Environmental Pesticide Control Act of October, 1972, the Toxic Substances Control Act of 1976, the Solid Waste Disposal and Resource Recovery Act of 1976 and the Safe Drinking Water Act sighed in December of 1974 have all contributed to the challenge for an alumina plant to meet regulatory constraints. However, this paper will only discuss the alumina plant?s environmental programs designed to meet compliance with air and water pollution legislation. At the Gramercy Alumina Plant, over $25 million has been spent for pollution control since 1969. The Gramercy Plant is a prime example of KACC's commitment to meeting the environmental challenge.

Jan 1, 1978

By D. Krawczykowski, D. Saramak, T. Gawenda

"Annual world zinc consumption is as high as nearly 14 millions of tonnes. Approximately 50% share of zinc is used for corrosion protection in processes of continuous galvanization and the hot dip processes. In the latter, two zinc containing residues are produced: zinc ash and hard zinc, which constitute around 10% each. Paper concerns the method of possible separation of metallic zinc from the non-metallic zinc compounds from the zinc ashes – the waste product of hot dip galvanization process. The investigative programme covered the comminution tests of the feed (zinc ash) in selected crushers: jaw crusher, roller crusher and impactor. Results of investigations show that application of individual crushing device results in various breakage of the feed sample. Impact force caused the highest increase in finest particles size fractions of the product, while metallic and non-metallic fractions were comminuted differently. The compression force, in turn, caused the selective comminution, i.e. the breakage of metallic zinc was observed in a higher degree. The presented approach appears to be an economical supplementary method of initial recovery of metallic zinc from metallurgical zinc waste. For the high demands for the zinc in the world and the need of corrosion protection, the method presented in the paper helps in more effective zinc recovery and environmental protection.INTRODUCTION AND METHODOLOGY World production of metallic zinc during last decade shows a slight increase and in recent years its consumptions reach 14 millions of tonnes. Figure 1 shows world production of zinc in the time period 2009 – 2016. Main directions of zinc utilization include: - Galvanization - Production of zinc alloys - Brass and bronze production - Semi-manufactures of zinc - Chemicals The major share in global zinc consumption constitute galvanization process (Bright 2007). Two main types of zinc galvanization are: hot-dip galvanizing (HDG) and electro-galvanizing."

Jan 1, 2018

By AIME AIME

THE following paragraphs comprise such information as the Secretary has been able to obtain concerning the members and associates whose deaths have been reported. Further particulars or corrections of errors, and biographical data concerning deceased members or associates not already noticed in this way, are solicited. Pat Doyle was born in 1849. At the age of fifteen he entered the Civil Engineering College of Madras, India, and left it at seventeen, having achieved special distinction in mathematics, chemistry,. and geology. Before be was eighteen years old he was in charge of two of the most important Sub-Divisions in the Madras Presidency, where he had ample opportunities for acquiring a preliminary knowledge of his profession, which was his chief object in joining the Public Works Department. In 1867, his energetic measures saved the island of Seringham from disastrous inundation. At this period he began contributing to the press ; and after a varied practical experience he came into public notice again in 1876, with an article in the Colliery Guardian on Indian Mines and Mining. In 1877 he became a Fellow of the Statistical Society of London. He was a founder of the Straits Branch of the Royal Asiatic Society and a life member of the parent Society of Great- Britain and- Ireland, as well as a member of the Independent Asiatic Society of Bengal. In 1878-9 he was Chief Superintendent of the Public Works of Perak; was active in having the Associate Member Class added to the Institution of Civil Engineers; and became a member of the Society of Engineers of London and of the North of England Institute of Mining and Mechanical Engineers. In 1880 he went to the Southern Colonies and held several appointments in Australia, where he became a member of the Johnsonian Club, Brisbane, and the Queensland Philo-

Jan 5, 1908

By R Peiffer, L van Wyk

The Port of Port Hedland is the largest bulk export terminal in the world and is one of Australia’s most important pieces of economic infrastructure. BHP is the largest Port user to support the export of iron ore products from mines located within the Pilbara region of Western Australia (WA). BHP’s priority is the safety and well-being of its workforce and the communities where it operates. In a recent regulatory application to increase export capacity, BHP committed to the deployment of wind fences to reduce wind erosion from stockpiled ore. Wind erosion from stockpiles was identified through inverse modelling as the most significant dust source compared to other sources such as stackers, reclaimers, shiploaders and transfer stations. The primary cause of dust emissions from stockpiles is dust lift-off during high wind conditions. BHP proposed the installation of wind fences across its Port Hedland operations, targeted at reducing emissions from wind dependent sources, primarily stockpiles, by reducing the wind speed downwind of the wind fence. Modelling predicts that installation of the wind fence will significantly reduce emissions from stockpiles, particularly at BHP’s western operations (Finucane Island). To be effective in shielding stockyards and reducing wind speeds, the wind fences are located upwind and as close as practical to the open stockyards. BHP’s wind fence design incorporates learnings from other existing installations and has been tailored for Port Hedland’s cyclonic conditions. The wind fence will be higher than the stockpile height, with a mesh porosity of approximately 50 per cent. The mesh porosity allows some of the wind to pass through the mesh. This reduces the wind turbulence downstream of the wind fence, as opposed to a solid wind fence, which increases downwind turbulence, resulting in increased dust.

Sep 18, 2023

By W. R. Reed

This study evaluates the roof-bolter canopy air curtain (CAC) system in an exhausting face ventilation system, demonstrating its effectiveness and illustrating the CAC protection zones. Two scenarios are considered: (1) a roof-bolting machine in the center of the entry for installation of the fifth row of bolts from the face, and (2) a roof-bolting machine positioned close to the face for the installation of the last row of bolts. In both scenarios, the bolting machine is placed in an environment that contains 6.0 mg/m3 of respirable dust and is ventilated by an exhaust curtain with 9,000 cfm (4.25 m3/s) of air to simulate the roof-bolter machine operating downstream of a continuous mining machine. Two operation positions are simulated at the same bolting location: dual drill heads in the inward position for two inside bolts and in the outward position for two outside bolts. The influence of the CAC on airflows and dust dispersion is evaluated with the CAC operating at 250 cfm (0.12 m3/s) with dust reductions ranging from 39.5 to 82.8 percent. When the roof bolter is operated close to the face, increasing CAC airflow was required for adequate protection, as the dust reductions can be as low as 39.5 percent. Increasing CAC airflows to 350 cfm (0.17 m3/s) and 450 cfm (0.21 m3/s) were evaluated, demonstrating that dust reductions increased to 59.7 percent (350 cfm) and 72.0 percent (450 cfm). These results revealed improvement in respirable dust reductions compared to the CAC airflows at 250 cfm when the bolter is operated close to the face, showing the CAC can provide protection against high respirable dust concentrations for roof-bolter operators.

By D. S. DeLong, A. Giza, D. G. Fraser, V. A. Robinson, T. B. Whitmoyer, J. E. Sneckenberger

"A cotton dust animal exposure system has been modified to incorporate a microcomputer feedback loop to monitor particle concentrations. The loop's major components are a minature real-time aerosol monitor (miniram) to estimate concentrations and a microcomputer to read the miniram's data and to control a stepper motor that adjusts the amount of dilutant air mixing with respirable cotton dust. Ninety minute trials of this system indicate that the standard deviation of particle concentrations is within 0.68 Mg/m3 of the average concentration, insuring a near constant concentration of respirable dust throughout the exposure.INTRODUCTION Previous workWeyel et al. (1984) have determined that respirable cotton dust can be shaken from bulk cotton samples using acoustical energy. The particle generator designed to utilize this fact operates like a commercially available sonic sifter, but on a much larger scale.While this generator successfully resuspended trapped respirable cotton dust, the generator output concentration decreased exponentially with time. This disadvantage was solved by Frazer et al. (1986) by operating the generator with a sinusoidal voltage near the minimum resonance frequency of the generator. This adjustment enabled the generator to produce respirable cotton dust for six hours or longer.Frazer et al. (1987) utilized the modified acoustical generator to produce a cotton dust animal exposure system. The cotton dust concentrations were estimated by a miniram, a light scattering aerosol Monitor. The system operator used the miniram values to adjust the system's parameters to maintain the desired concentration level.PurposeThe objective of this study was to introduce a computerized feedback loop to the operator controlled cotton dust animal exposure system. The miniram's estimates were analyzed by a microcomputer to determine what adjustments in the flow of dilutant air were necessary to maintain the desired cotton dust concentration. These modifications were intended to improve system performance and ease the system operator's work burden."

Jan 1, 1988

By D. A. Reynolds, J. D. Davis

"This work was begun in l928, with the cooperation of the American, Gas Association, and the Association contributed financial aid for that year and for the 4 years following. In 1933 financial aid was discontinued, but the Advisory Committee, under the able, Chairmanship of J. S. Haug, has continued to function through the years to the present date. Mr. Haug's annual reports have been published in the Proceedings of the American Gas Association. The purpose of this paper is to bring the index of coals tested by the Bureau of Mines-American Gas Association (EM-AGA) method up to date, to discuss development of auxiliary tests, and to outiline the uses to which the methods have been put in promoting the war effort.COALS TESTEDThe test methods developed with the advice of the Advisory Committee had been applied to 66 coals up to 1942, and an index giving the serial number, origin, and analyses of these coals was published as Bureau of Mines Technical Paper 637. Since this paper was published, 20 additional coals have been tested; the source and analyses of these coals are given in table 1. The table also refers to publications that have been issued. Complete series of tests at high, medium, and low temperatures,have been made on most of these coals, and blending tests with 20 and 30 30 percent of low-volatile coals have also been made at 900°C.; however a few low- and medium-volatile coals (60, 70, 74, 79, and 80) were bested,at high temperatures only. Those coals were mined in eastern Oklahoma and western Arkansas. The test work included low- and high-temperature assay tests, petrorraphic analyses, and plasticity tests since its inception; and for the last 20 coals of the series, expansion and oxidation tests have been made where applicable."

Jun 1, 1944

By JOHN BIRKNBINE

MR. NEILSON was born Aug. 12, 1842, at Philadelphia, Pa., where he died Dec. 30, 1906. His business career began with his graduation, in the class of 1862, from the Polytechnic College of the State of Pennsylvania. For a short time after graduation he was instructor in mathematics at the college, and then became associated with Messrs. Booth & Garrett, chemists, of his native city: In 1867 he was sent to the Adirondack mountains to care for mining interests of the late Jay Cooke, and spent about three years there, operating the forges at Elizabethtown, Essex county, N. Y. He also prepared an interesting monograph on Catalan forges and their operations. In 1868 he published a chart showing the material progress of the United States, and the cost of certain staple products during a series of years, which is believed to be the first of its kind issued in this country. In 1870 he made a trip to the Pacific Coast, prior to entering the service of the Pennsylvania Steel Company. In 1871, when the Logan Iron & Steel Co., of Burnham, Pa., failed, Mr. Neilson was appointed receiver, re-organized the company, became' its General Manager, and spent more than four years in this work. In the meantime, he became interested in the Freedom forge of the same place, and, with Mr. Wm. Burnham and Mr. Milton Brosius, laid the foundations for what is now the Standard Steel Works. From Jan. 1, 1877, to April 1, 1890, he was General Manager of these works, and closely associated with the Baldwin Locomotive Works. In 1878 he was in charge of the first consignment of Baldwin locomotives to Europe, which, with a picked crew of men from Baldwin's, he took to Eydtkennen, Russia, and placed in service. In 1890 he resigned from the Standard Steel Works and ac-

Jul 1, 1907

By R. D. Hutchinson

I consider it an honour to be the opening speaker in this afternoon's session on "Canadian Exploration". I also think it most appropriate that this joint meeting of the MMIJ and AIME should consider this subject, because Canada is a major exporter of mineral products and Japan and the United States are our two largest customers. Clearly, therefore, both countries have a valid interest in developments on the Canadian minerals scene. I represent the Mineral Development Sector of the Canadian Department of Energy, Mines and Resources. I will therefore speak from the point of view of the Federal Government. At this point I would like to acknowledge the help and constructive criticism I have received from several of my colleagues in Mineral Development Sector in the preparation of this paper. In any discussion of exploration in Canada, it is essential to emphasize at the outset that Canada has a federal system of government, with powers shared between Ottawa and the provinces. Under our constitution, the federal government has jurisdiction over the north, and over offshore areas, while the provinces own the natural resources within their boundaries. They control the systems of land acquisition for exploration and the terns under which mining titles are issued, and are therefore able to determine the rate and conditions of exploration and development of these resources. It follows that the Federal Government can influence the exploration and development of the provincial resources only indirectly by consultation with provincial authorities. However, once the resources are developed and begin to flow to market, the Federal Government can exert a much stronger influence because of its constitutional right to control both inter-provincial and international trade, as well as through its general fiscal and tax powers.

Jan 1, 1976

By Steve Kral

"Each January, tunneling and underground professionals gather in New York City for the George A. Fox Conference. The one-day event offers attendees the opportunity to listen to their peers outline what’s new in the underground construction industry, get updates on major projects in North America and have a chance to catch up of old friends.The conference is put on by the Underground Construction Association of SME. This latest conference attracted about 370 specialists in the industry. The theme for this year’s event was “Water Tunnels, Past, Present and Future.”The technical session included talks focused on major tunneling projects, including the massive California Water Fix program and the Massachusetts Water Resources Authority (MWRA) Metropolitan tunnel redundance program in Boston. The conference also included an update on the Gateway Project from Phil Rice from WSP and Mahammed Nasim of Amtrak as well as a Tunnel Industry update.The following is a sample of a few of the presentations. Technical presentationsDEP’s Tunneling Program Evolution. James Mueller is the agency chief engineer of New York City’s Department of Environmental Protection (DEP). Its mission is to plan sustainable infrastructure investments for the future of clean water and the environment in the city and its watersheds, he said. The agency’s goals are to synthesize information across bureaus within DEP to allow data-driven decision-making. It is also to optimize internal agency processes and systems related to the implmenation of engineering programs within a structured assessment process. The agency also prioritizes projects and funding within a structured integrated planning process. And it standardizes project performance and delivery to meet the needs of the agency in alignment with industry standards and market capabilities."

Mar 1, 2019

By R. K. Franklin, S. T. Reese, J. J. Forbes

"INTRODUCTION It is a recognized fact that in the coal-mining industry coal dust must be allayed to promote the safety and health of underground workers. The Bureau of Mines has been cognizant of the hazards of coal dust for many years, and the necessity of controlling such dust was acknowledged when the Federal Mine Safety Code was formulated. Accumulations of coal dust increase the explosion hazard in a bituminous-coal mine and facilitate the propagation of an explosion. Some of the coal dust produced in mining is inhaled by the workers and contributes to respiratory infection. Impairment of vision and personal discomfort resulting from working in dense clouds of coal dust reflect unfavorably on the efficiency of workmen. Considerable coal dust, originating at the working face, is carried in the ventilating current and deposited elsewhere in the mine, thereby increasing the explosion hazard. It is apparent, therefore, that if coal dust could be allayed effectively at its points of origin, the dust-explosion hazard in bituminous-coal mines would be reduced greatly.Although dust control is practiced in many bituminous-coal and lignite mines, the extent and effectiveness of control for the, entire industry-is not generally known. The purpose of this circular is to present such information clearly, and to encourage coal-mine operators to install dust- allaying equipment.Factual data on dust-allaying practices at working faces in a large number of the bituminous-coal and lignite mines in the United States were .compiled from reports on recent Federal inspections of these mines, The information is presented in tabular form to permit review of the dust-allaying practices of a substantial part of the industry, by States, and also according to employment, and loading practice."

May 1, 1950

By Sunil S. Gandhi

"The Mountain Lake deposit is a tabular sandstone-type uranium deposit, hosted by the basal unit of Middle Proterozoic Dismal Lakes Group. Uranium occurs mainly as sooty pitchblende disseminated in stratiform lenses within gently dipping quartzose sandstone. It is associated with copper sulphides, pyrite, hematite, and traces of nickel and cobalt arsenides and of silver.Exploration HistoryUranium showings on the PEC claim group were discovered during 1969 by an airborne radiometric survey carried out over the Dismal Lakes-Great Bear Lake area by Aquitaine of Canada Limited (Bizard and Salat, 1969). Some drilling was done in the vicinity of the showings in 1975 by the company under a joint venture with Eldorado Nuclear Limited but the results were not encouraging (Hassard and Woollett, 1975). During 1972, Trigg, Woollett and Associates Limited conducting surveys for Imperial Oil Limited, discovered numerous high-grade radioactive boulders scattered over a distance of several kilometres north and west of the showings, and the area north of the PEC claims was staked as the YUK claims (Ahuja, 1974). A systematic study of the boulder distribution and Pleistocene geology suggested a source additional to the showings. More intensive exploration followed, and in 1976 drilling just north of the PEC claim group boundary intersected the main deposit at a depth of 75 m to 150 m, beneath overburden up to 60 m thick. Part of the deposit extends into the PEC claim group which is under exploration by the Aquitaine-Cominco Joint Venture.The following brief description is based on the presentations in 1978 by F. Hassard of Trigg, Woollett and Associates Limited at the Geoscience Forum in Yellowknife, and by S.S. Gandhi of the Geological Survey of Canada at the Mineralogical Association of Canada Uranium Short Course in Toronto."

Jan 1, 1986

By D. A. Reynolds, L. P. Rockenbach

"The method of analyzing light oil for benzene is fully described by Fieldner and others 4/ and Kester and Kolmes 5/. In this procedure, benzene is determined by shaking 20 cc. of the 79º to 81º C. boiling point cut from the fractionation of the refined light oil with 3 volumes of 98—percent sulfuric acid in an A. S. T. M. separator funnel of the type used for determining water in bitumi¬nous materials. After the mixture has been shaken 5 minutes it is allowed to settle at least half an hour and the acid is drawn off; the residual oil is reported as paraffins and the decrease in volume as benzene. The method has been found satisfactory for light oils from coals carbonized at 5000, 600°, and 7000 C. but does not give accurate, reproducible results for oils from the 800° C. tests.The content of benzene of the 790 to 81° C. cut is high, 90 to 95 percent, for 800° C. light oils, whereas for lower—temperature light oils it is considerably less. Benzene is the most difficult of the aromatics to sulfonate, hence the acid concentration must be maintained above 95 percent to insure complete sulfonation. Sulfuric acid (98 percent) reacts with benzene, but its reaction with paraffins at ordinary temperatures is negligible; however, more concentrated acid will attack paraffins and give erroneous yields of benzene. The reaction between benzene and sulfuric acid forms water that will dilute the acid. The effect of this dilution may be overcome by increasing the acid-to-oil ratio or increasing the strength of the acid. The latter, however, must not be used, because the stronger acid reacts with paraffins."

Mar 1, 1942

By V. Rajaram

V. Rajaram's paper does not accurately reflect the status of Eastern oil shale development as it stands today. Today, there are numerous firms and research organizations pursuing development of the Eastern oil shale resource. Details of the current projects can be found in the symposium proceedings for the 1985 Eastern Oil Shale Symposium held in Lexington, KY, in November 1985. Additionally, the comparison of the Paraho and HYTORT processes is invalid because the HYTORT process design used it not an accurate representation of the HYTORT process. I will briefly address this point. It is disconcerting to see the author reference hydroretorting work conducted at the Institute of Gas Technology (IGT) (circa 1978) in the introduction, which indicates hydroretorting (the HYTORT process concept) yields of up to 250% of the Fischer Assay oil yield, and then turn around and base the remainder of the paper on the 1981 "Synthetic Fuels From Eastern Oil Shale Report," which depicts the HYTORT process as yielding only 115% of Fischer Assay. Indeed, work conducted at IGT to 1981 indicates commercial oil yields for the HYTORT process would be in the range of 200% to 210% of Fischer Assay. A more thorough literature search by the author would have yielded a 1981 publication by Schora et al., entitled "Update on the HYTORT Process" presented at the Symposium on Synthetic Fuels From Oil Shale in Nashville, TN, October 1981. This paper thoroughly discusses the shortcomings of the referenced study with respect to the HYTORT process. For the interested reader, I can also recommend a June 1984 report entitled "An Economic Comparison of Five Process Concepts for Using Eastern Oil Shale," published by Los Alomos National Laboratory (LA-10106-MS, Parkinson et al., NTIS No. DE84-015981). This study applies a realistic HYTORT design (circa 1982) and indicates that HYTORT is the most econom¬ical method of processing Eastern oil shales (about $20/bbl less than Paraho). Additionally, completion of the HYTORT feasibility study in June 1983 by Phillips Petroleum Co., Bechtel Group Inc., HYCRUDE Corp., and IGT has resulted in development of designs that will make the use of HYTORT on Eastern oil shales even more economic. HYCRUDE Corp., a second-tier subsidiary of IGT, is involved in commercialization and licensing of the HYTORT process and is active in efforts to develop the Eastern oil shale resource. As such, I am disappointed to see outdated material that has the potential for adversely affecting development of Eastern oil shale resources published in MINING ENGINEERING. I can only hope that this response will serve to mitigate any negative opinions that may have been formed. Today, activity in commercializing Eastern oil shales dominates the oil shale scene in the US and indicates a realization of the potential for these shales. Reply by V. Rajaram I appreciate the updates on the HYTORT process provided by R.C. Rex, Jr. I hope that Hycrude's work will lead to the funding of a pilot plant to demonstrate that yields of greater than 200% of Fischer Assay can be achieved in a commercial plant using eastern US oil shales.

Jan 1, 1987

By Walter Bonsack

THE CHAIRMAN.-This is the third and last session of the Institute of Metals Division's Symposium on Secondary Metals, and certainly the best of those that I have attended in the last few years. I would say that the increase in interest in secondary metals is quite noticeable by the steadily increasing attendance at these meetings. We have heard about the necessity of utilizing salvaged materials, but we still speak about them as low-grade, or down-graded materials. We still have the wrong perspective. We must willingly admit that these materials are valuable; we cannot go on using the choicest primary metals as morsels for our economic diet in a war of such unbelievable dimensions. This brings up the question-why are we so selective. The answer certainly is not that we know nothing else will do, but rather that we do not know what else will do. To be honest, we should admit our lack of knowledge concerning our complex alloys. Compared to the organic chemists, we metallurgists are very conservative, and the sooner we realize this and start to overcome it the better, because if we do not eliminate this difference, many customers of the metals business will go over to the plastics. If we take for example the development of aluminum alloys, you will see what I mean. From the binary aluminum alloys of 1920, we have progressed to ternary and quarternary alloys in the 1930's. We are only now beginning to use more complex alloys as we are forced to learn more about the effect of various elements on existing alloys. The effects of these elements should be studied now. They can be studied by two methods of approach. The usual method is to start from the base alloy and add various elements one by one in increasing amounts and study the resultant changes in properties. This is a tedious, long way. The other method which the smelters frequently use is to take the off-grade heats and study their characteristics. While the producer of primary alloys often has difficulties in alloying certain elements with the alloy under investigation, the smelter often finds them well alloyed in his raw materials and has no difficulties at all. Elements such as lead are difficult to alloy with aluminum and they tend to segregate severely. However, the amount which will remain alloyed in the metal is usually found in some "secondary" aluminum alloys. If one considers such concentration as the saturation, then by dilution with the same type of alloy, but free of such element, one can produce numerous intermediary alloys for investigation. In this fashion one is fairly certain to get uniformly spaced concentrations of the element under investigation. Similar cases probably exist with other metals. Nevertheless, the amount of work necessary to study all possible combinations is still tremendous. Necessity forces us now to utilize alloys which contain more elements than we are accustomed to. It is, therefore, necessary to study carefully the more complicated alloys. In secondary aluminum we are working and using the alloys which contain as many as 6 to 10 elements and we have learned over a period of several decades to balance

Jan 1, 1943

By P. K. Foh, C. G. Dunn

IN an investigation of the rolling and recrystalliz-ing textures obtained from single crystals of Si-Fe, Koh and Dunn included specimens in the (111) [lie] orientation.1,2 This note reports some additional results obtained on samples of this orientation set aside for further study. After, primary recrystallization longer annealing treatments at 980°C produced only normal grain growth; after 16 hr at 980°C the largest grains were approximately 0.010 to 0.020 in. in diam. The orientations of 13 of the larger grains were found by the transmission Laue method. The unidentified (110) poles of these grains have been added to the (110) pole figure obtained after primary recrystallization2 to give the plot shown in Fig. 1. When grain identifications are also included, such a plot reveals the following. Two orientations agree almost exactly with the peak pole ,density positions of component B of the primary recrystallization texture, one with component A, and one with component C. All the remaining orientations except one have (110) poles near weaker and unidentified pole density peaks. In fact, the correlation is good enough for an identification of eight components. Previously only components A, B, and C were certain. The results are perhaps even more informative when combined with the (110) pole figure of the cold-rolled crystal to give the plot shown in Fig. 2. Each of the 13 orientations is identified and uniquely determined by selecting two (110) poles per crystal, which are 90" apart. The plot shows that every grain of the 13, except grain 6, has a (110) pole in common with a (110) pole concentration of the cold-rolled crystal. The orientation relationship with the cold-rolled orientation may be expressed as approximately 25" rotations about <110> axes, which is in agreement with the results found for coarse-grained primary recrystallization.2 If primary recrystallization had occurred according to the <110> rule without preference, there would have been 12 components. Actually our limited data reveals nine of the possible 12. The integrated pole figure also shows preferences among them, since three are considerably stronger than the rest. In addition to the above direct information, the following conclusions may be drawn. Primary recrystallization of the (111) [110] cold-rolled crystal produces a limited number of weak and strong components with the larger than average primary grains from these components related to the cold-rolled crystal by 25° <110> relationships. In arriving at this conclusion of limited orientations the (111) [110] orientation has to be ruled out as a source of large primaries for two reasons. First, growth in this orientation was not observed, despite an expected high grain boundary mobility (due to its 25" <110> relationship with every component of the texture). Secondly, primary recrystallization usually produces grains in new orientations, particularly in a single orientation matrix; but (111) [110] is not new. Other orientations besides those of the <110> type may be considered unlikely, of course, because the <110> relationship holds quite well for primary recrystallization2 and should produce the large primaries. There are exceptions to this rule, but probably not enough to provide large

Jan 1, 1958

By Oliver Bowles

AMONG mining men as well as in the popular mind the conviction has held sway that mining is pre-eminently a western industry. True it is that gold, silver, copper and other metals have made the States of California, Colorado, Montana, Utah. Nevada and Arizona famous. The prominence attained by these States as mineral producers is, however, not measured alone by the money value of the products of their mines. While the metals are without doubt indispensable in industry, the glamour of the precious metals, and the lure of copper, lead and zinc have given to their ore deposits a sentimental interest that often quite out-weighs their commercial importance. Today a great group of more commonplace minerals are finding a place in commerce and industry rivaling that of the metals, but there is little sentiment attached to them, and,. therefore, they attain relatively little publicity. This is the great group of the non-metallic minerals, exclusive of fuels and oils, including stone, sand and gravel, cement, lime, gypsum, asbestos, mica, phos-phate rock and many others. Almost unnoticed they have grown in production to almost unbelievable pro-portions. The estimated value of metal production for 1925 is given as $1,380,000,000, of the non-metals (ex-cluding fuels) $1,294,000,000. The non-metallic industries are not new, many of them date back almost to pre-historic times; but, as the greatest of them (on a tonnage basis) provides raw materials for the construction industries, it required the activities of the present age of construction to bring about their enormous development. Many of them enter manufacturing as well as con-struction. Non-metallic minerals constitute the back-bone of our great chemical industries. While construction and manufacture reach to all parts of the country their widest development has been in the great industrial centers of the eastern Seaboard and the middle West. Consequently the raw materials of mineral origin required for these great industries have attained a remarkable growth in the eastern half of the- United States. In compiling figures of mineral production for 1924, for which more complete data are available than for later years, the surprising fact is brought to light that the non-metallic mineral produc-tion alone of some of the eastern and middle-western States exceeds by a substantial margin the total min-eral production of some of the western States that have been classed as essentially mining States. Thus the non-metallic mineral production, exclusive of coal and petroleum, of the State of Ohio, was approximately $150,000,000; of Pennsylvania $175,000,000; and of New York $107,000,000. For the same year, 1924, the total mineral production of Utah was $84,357,000; of Montana $70,632,000; of Colorado $61,488,000; and of Nevada only $26,226,000. Even Minnesota, with its enormous iron ore production, reached only $107,845,-000, or a sum about equivalent to the non-metallic min-eral production of the State of New York.

Jan 8, 1927

By J. W. Hickman

INTRODUCTION RECENT work by the authors1 on the oxide films formed on alloys of titanium and zirconium with nickel and copper indicated that an investigation of the oxides which form on alloys of copper and nickel might permit the relative rates of formation and diffusion of the ions of. these metals to be determined. This binary system is of further interest since the alloys which form are of the solid solution-type over-the entire range. In addition nickel is much more oxidation resistant than copper. A comparison of the free energies of formation of the simple oxides which may occur on these alloys indicates that nickel oxide should be observed over the entire time and temperature ranges of oxidation for all alloy compositions.1 In. order for nickel oxide to predominate on the surface, it is necessary that nickel ions form and diffuse to the surface. Two factors which may influence the formation of nickel oxide may be the ionic sizes, where Cu+ is 0.96Å and Ni-++ is 0.70Å, and the charges on the ions. On the basis of size, Ni++ should diffuse more readily than Cu+ while on the basis of charge, Cu+ should form more readily than Ni++. According to Uhlig2 passivity to corrosion in an alloy appears at a critical composition which for copper-nickel alloys is related to the tendency of the d band of electronic energy states to fill with electrons. This composition in the copper-nickel alloys corresponds to 40 at. Pct nickel at which composition Uhlig2 (quoting La Que&apos;s data) states that the alloy system becomes passive. Magnetic and specific heat data indicate that the d band of copper-nickel alloys is filled at 6o at. pct copper or 4o at. pct nickel. Mott and Jones3 have shown that if, on alloying nickel with copper, one considers a copper atom to be identical with a nickel atom except for an extra electron (nickel -has the-configuration: 3d8 4s2 and copper: 3 d10 4s) then at 60 at. pct copper or 4o at. pct nickel enough electrons are contributed by copper to fill the d band of the alloy. At this composition the magnetic susceptibility approximates zero according to Grew.4 Although the electron diffraction data will not determine the rates of the several reactions which may occur during oxidation, yet a determination of the structures of the surface oxides may yield information concerning the relationships, if any, which may&apos; exist between the oxide structures which form and that composition where the magnetic susceptibility approximates zero. It is quite possible, of course, that the mechanisms of the oxidation and corrosion reactions may be so widely different that no correlations between them may be possible. SURVEY OF LITERATURE The metals, copper and nickel, which are face-centered cubic, form solid solution alloys which are face-centered cubic with no superstructure for all compositions. Three oxides of nickel have been investigated structurally by X ray diffraction. Of

Jan 1, 1948

By E. A. Gulbransen, J. W. Hickman

Recent work by the authors1 on the oxide films formed on alloys of titanium and zirconium with nickel and copper indicated that an investigation of the oxides which form on alloys of copper and nickel might permit the relative rates of formation and diffusion of the ions of these metals to be determined. This binary system is of further interest since the alloys which form are of the solid solution type over the entire range. In addition nickel is much more oxidation resistant than copper. A comparison of the free energies of formation of the simple oxides which may occur on these alloys indicates that nickel oxide should be observed over the entire time and temperature ranges of oxidation for all alloy compositions~i In order for nickel oxide to predominate on the surface, it is necessary that nickel ions form and diffuse to the surface. Two factors which may influence the formation of nickel oxide may be the ionic sizes, where cu+ is o.,,6-,4 and ~i++ is o.,oh;, and the charges on the ions. On the basis of size, Ni++ should diffuse more readily than Cu+ while on the basis of charge, Cu+ should form more readily than Ni++. According to Uhlig2 passivity to corrosion in an alloy appears at a critical composition which for copper-nickel alloys is related to the tendency of the d band of electronic energy states to fill with elec-trans. This in in the copper- nickel alloys corresponds to 40 at. pct nickel at which composition Uhlig2 (quoting La Que&apos;s data) states that the alloy system becomes passive. Magnetic and specific heat data indicate that the d band of copper-nickel alloys is flied at 60 at. Pet Or or 4O at. pct nickel. Matt and Jones3 have shown that if, on alloying nickel with copper, one considers a copper atom to be identical with a nickel atom except for an extra electron (nickel has the configuration: 3ds 4s2 and copper: 3 dl0 4s) then at 60 at. pct copper or 40 at. pct nickel enough electrons are contributed by copper to fill the d band of the alloy. At this composition the magnetic susceptibility approximates zero according to Grew.4 Although the electron diffraction data will not determine the rates of the several reactions which may occur during oxidation, yet a determination of the structures of the surface oxides may yield information concerning the relationships, if any, which may exist between the oxide structures which form and that composition where the magnetic susceptibility approximates zero. It is quite possible, of course, that the mechanisms of the oxidation and corrosion reactions may be so widely different that no correlations between them may be possible. Survey OF Literature The metals, copper and nickel, which are face-centered cubic, form solid solution alloys which are face-centered cubic with no superstructure for all compositions. Three oxides of nickel have been investigated structurally by X ray diffraction. Of

Jan 1, 1949

By d&apos, John C. Entremont

Pure iron was inductively melted in small refractory crucibles and optical pyrometer and immersion thermocouple readings were simultmzeously taken. The resulting emissivities of the liquid iron surface obtained were found to be greatly affected by both the gaseous atmosphere and geometrical changes in the physical setup. Quantitative values for these effects are indicated. FOR many applications in both the laboratory and plant, optical pyrometry is still the best means of measuring temperatures in the incandescent range. A prerequisite in evaluating the correct temperature is a good value of the emissivity of the surface. To obtain the emissivity from the tabulated values of the literature can be very confusing and often far from correct. There are many reasons for these difficulties, and it is not within the scope of this paper either to enumerate or to discuss them all. Its purpose is to show quantitatively how several factors affect the apparent emissivities obtained from experimental measurements on liquid iron surfaces. The black body is the reference state for the quantitative values of emissivities and is defined1 as a body which absorbs all radiation incident on it, reflecting none; such a surface emits more radiation per unit area per unit time than any surface which reflects any radiation, and is given a value of unit emissivity. All bodies having reflective power thus have emissivities less than unity and are considered nonblack or grey bodies. The ratio of the radiant energy emitted by the flat, nonblack surface to that of a perfectly black surface of equal area and temperature is the emissivity of the surface. The above definitions are applied to flat, polished, opaque surfaces, very seldom encountered in actual measurements, and for this reason many authors have suggested that the word "emittance" be used for real bodies rather than emissivity. The emittance has reference to the material and its configuration rather than to its properties in the idealized state. Recent observations of molten iron in a small refractory crucible indicate that not only the configuration of its surface but the geometrical arrangement of its surrounding and the nature of the surrounding atmosphere have a pronounced effect on the emittance. Neglect of changes in such conditions may lead to errors as large as 40°C at 1600°C. Thus it is suggested that the term "apparent emissivity" be used and that it be recognized that its value pertains to a particular experimental arrangement only. As a result of not recognizing these differences in emissivities, which are obtainable from changes in the physical setup of an observation, many investigators have incorrectly quoted their values as those of the emissivities of particular materials rather than as an apparent emissivity for their particular arrangements. As a consequence, values of the emissivity of liquid iron ranging from 0.3 up to 0.55 are found in the literature. In an effort to establish an accurate optical temperature scale for liquid iron solutions in which de-oxidation studies were to be carried out, it was observed that the temperature relationship, obtained by simultaneously taking immersion thermocouple

Jan 1, 1963