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By L. C. Clare

In a meeting of this kind where everyone present is connected with or engaged in coal mining, and where each one is present with the set purpose of learning new thoughts or ideas, the subject of the saving of life by any method in the industry is a vitally interesting and important one. On the cost per ton basis, it mounts to a formidable figure especially so during these days of depression and stagnant, or no business. But entirely outside of the human side of the question, to lose lives would cost more than saving them. Your insurance under haphazard safety measures would mount, loss of time due to accidents would impair efficiency among employees and the breaking of the morale of the staff, due to criticism of lax methods would cost more than an efficient safety program. Taking it for granted that most of you are looking at the question from the viewpoint of a yearly or five-year cost sheet, and that at this time you are doing all that can be done without bringing a ruinous cost upon your companies, I can offer only one suggestion: Raise the quality of your safety, or lower the cost. In this meeting, there should be no question of standing still or retreating in the quality of safety, so I will amend the suggestion with "Raise the quality and lower the cost." We have learned that when the coal beds were forming, nature sealed them in with a strata of mud that the ages have turned to shale, sealing them effectively against the deteriorating influences of the air. Mudite is carrying out nature's plan of coal preservation to the inside of the coal mine. Text books teach us that a large proportion of the vegetation that forms our present coal beds grow on what might be termed mud, later falling and being buried practically where it grew by mud, then on being subjected to heat, pressure and time, was changed to coal. The mud being subjected to the same three forces forms our present shale stratas. Now if nature saw fit to use this solidified mud as a preservative through countless centuries, isn't it reasonable to expect that occasional coatings on the ribs and roofs of entries and rooms will aid materially in preserving our coal and coal dust? Nature took mud and formed it into shale; mudite takes the shale, reduces it into dust, adds water and makes a mud, applies it to the ribs, roofs and floors of the mine in a thin coating

Jan 1, 1925

By J. A. Clum, R. W. Heins, T. D. Tiemann

The use of Na-montmorillonite clay hinders (Western Bentonite) in the pelletizing of iron ore concentrates is well established as is the idea that alternative binders must be found. 1-6 This note summarizes work done7 in evaluating a Wisconsin montmorillonite clay binder. The clay occurs in irregualr beds overlying the Prairie du Chien Dolomite and the St. Peters Sandstone near Hersey, St. Croix County. The raw Wisconsin clay contained 65% quartz and 35% clay minerals. The Na20to CaO ratio was 0.234. Suspension viscosity tests of the raw clay gave results only slightly better than water alone, even after treatment with activator materials. Sedimentation treatment reduced the quartz in the decantate to 5% after 240 min (four hours). Twenty minutes of sedimentation produced a decantate with 27.5% quartz which was found as effective as the 5% quartz decantate in pelletizing behavior. The 20 min decantate was used in subsequent tests. The decantate was filtered and dried at 110°(230°F). The minus 200 mesh portion of this was added directly to the magnetite concentrate. Pellets were made in a laboratory sized disc pelletizer from pastes consisting of ore concentrate, balling water (9%) and binder (clay, or clay + resins, or resins). The pastes were premixed in a Waring blender. The binders were: (1) 1% of a commercially used Western Bentonite; (2) 1 % or 3% of the Wisconsin clay (raw, or 20 min decantate); (3) 20 min decantate washed with activator solutions, (to exchange Na for Ca in the clay); (4) decantate with activator added in the balling water; (5) decantate with organic resins; (6) organic resins. Measurements of the 0.46 m (18 in.) Green Drop Number, the Dry Strength and the Fired Strength (fired at 1260°C (2300°F) for 30 min) were made. The dry and fired compressive strengths were determined on an Instron testing machine using a C-load cell and a F-load cell, respectively. The cross-head speed was 0.004 m/sec (0.1 in./min) for both. The results of each measurement were averaged for 15 pellets. A summary of those results is presented in [Table 1]. More detailed results and procedures are presented in another report.7 In addition to the effects on pellet strength due to various binders the effect of varying magnetite concentrate characteristics is noted in [Table l]. There, a few comparative data are shown for Cornwall, PA Magnetite, which has a generally liner particle size than the Black River Falls magnetite which was used for most of the tests.

Jan 1, 1979

By R. H. Swallow, George Hess

C. G. BALL*—These maps are obvi-~,usly quite helpful in many types of mining engineering, but I want to find out if the prints which you obtain in the first step toward making any aerial contour map have already been corrected for tilt. Is that done afterwards only if you are going into the process of making a contour map ? GEORGE HESS (authors' reply)— The tilt correction is the first step in either compiling the mosaic or compiling the total map. They must be corrected. C. G. BALL—But are the contact prints themselves corrected for tilt? GEORGE HESS—They are not corrected. E. R. KAISER†—I enjoyed this paper very much, and am glad to learn that the methods have a high degree of accuracy and are in use in the coal industry. Accuracy in dimensions is understandable from the paper. Would you tell us how accuracy can be obtained in the vertical dimensions by means of the photographs so as to permit drawing contour lines? GEORGE HESS—To explain our process, even in a limited way, is quite a large order. However, the basic principle involved is the measurement of parallax by viewing two overlapping photographs stereoscopically. It would almost be necessary to have the various instruments here on view to adequately explain their operation. E. R. KAISER—Are the elevations for reference obtained at more than four points ? GEORGE HESS—The pattern of control is four points obtained in the corners. Primarily. that is to restitute the picture and horizontalize it. The vertical control points are read ill on the stereometer and a direct comparison is made while draw- ing the contour lines. You do have to have those four points. But one stereoscopic pair of 5 ft contours has some 340 acres on it, consequently for every four points picked up 340 acres are contoured. E. R. KAISER—How does your method compare with that used by the military reconnaissance during World War II? GEORGE HESS—The Army did not get into this refined mapping. Most of their work has been reconnaissance mapping by taking one vertical and two oblique views. Basically, the same principle is used. Our maps are for engineering purposes. The Army was primarily interested in reconnaissance. E. R. KAISER—You could take more than 48 pictures in one flight? GEORGE HESS—Yes, the Brock camera accomodates 48 pictures per magazine. We are limited by the hours of greatest light, though, 2 hr before high noon, and 2 hr after high noon. Shadows do affect the picture. The shadows can-

Jan 1, 1950

By Ernest R. Darby

WHEN bronze is melted in open-flame furnaces a considerable amount of slag is formed during the melting operation. This slag maybe incidental to the melting practice or it may be formed intentionally by slag-forming constituents added to the furnace charge to provide a covering for the melted metal. When this slag is removed from the furnace, it contains, in addition to the free metal carried with it by the skimming operation, a considerable amount of metal as oxide either combined or mechanically mixed with it. By the usual crushing and washing methods this metallic oxide generally goes to the tailings pile, so diluted by other foundry waste that its recovery is economically impossible. If this furnace slag is not mixed with other foundry waste, practically all of the metal oxide as well as the free metal may be recovered by some form of smelting operation. The first side of the problem to be considered is the amount of slag produced. It may not be true that the majority of foundries have no record of the amount of slag made, but it is certainly true that a very great many either have no record or pay little attention to it. Usually the collection of furnace slag for one normal week's run will be sufficient to determine the advisability of its being handled in a different manner from the crushing and concentrating generally employed. If a large representative sample of the accumulation is crushed and concentrated and the recovery compared with the results of a careful assay, it will be found that a large percentage of the total metal content was lost in the washing process. The percentage of loss will be greater than the metallic oxide content, as some free metal in extremely fine particles always is carried away in grains of slag. From such a comparison, it may be determined whether or not the slag should be melted, sold or treated as before. An example of an actual test of this kind is given below. In a foundry melting 50,000 to 80,000 lb. of bronze per day, a week's accumulation of furnace slag and ladle skimmings amounted to 16,500 lb.-over three times as much as the foundry superintendent estimated before the accumulation was made. Two tons of this material was taken as representative of the lot. This was ground through a thoroughly cleaned ball-mill and concentrated over a Wilfley table. The

Jan 1, 1928

ROBERT WOOLSTON HUNT, who joined the Institute in 1874, served twice as its President, was made Honorary member in 1919, in whose honor the Hunt prize and medal were established, and who, within a month, had received the Washington Award, died at his home in Chicago on July 11, 1923. Robert Woolston Hunt was born Dec. 9, 1838, in Fallsington, Buck County, Pa., His father, Dr. Robert A. Hunt, of Trenton, N. J., graduated from Princeton College in the class of 1824, and later from the Uni-versity of Pennsylvania. His mother was Martha Lancaster Woolston. Mr. Hunt spent several years learning the practical side of iron making in the roll-ing mills of John Burnish & Co. at Pottsville, Pa. Later he took a course in analytical chemistry in the laboratory of Booth, Gar-rett & Blair, upon the completion of which he entered the employ of the Cambria Iron Co. at Johns-town, and for them, on Aug. 1, 1860, established the first laboratory in Amer-ica forming an integral part of an iron or steel organization. In the fall of 1861 he en-tered the United States military service, and was in command of Camp Curtin at Harrisburg, serving as mustering officer for the State of Pennsylvania, with the rank of Captain. In 1864 he assisted in recruiting Lambert's Independent Mounted Company, and was mustered into active ser-vice as a sergeant, having tossed up with a friend who had also participated in recruiting the company, as to which one should receive a Lieutenant's commission. Upon being mustered out of service, Mr. Hunt returned to the employ of the Cambria Iron Co. which sent him to the works at Wyandotte, Mich., where experiments with the new Bessemer process of making steel were being conducted. He was placed in charge of those works in July, 1865, and so continued until May, 1866, when the Cambria company called him back to Johnstown to take charge of their steel business, intending at once to begin the erection of a Bessemer steel plant. The plant, however, was not built for several years, and in the meantime the Cambria company began the rolling of steel rails for the Pennsylvania Railroad, using ingots of Bessemer steel produced by the Pennsylvania Steel Co. at their Steelton works. Mr. Hunt had charge of the steel for these operations; and in August, 1867, the first steel rails made in America on a commercial order were rolled.

Jan 8, 1923

By C. S. Smith, Chih-Chung Wang

D. Turnbull—In the opinion of the writer the most interesting result described in this paper is that the distribution of tin with respect to solidification temperature has several fairly well-defined maxima. It appears that each peak may be associated with a catalytic impurity of some rather specific composition. Recently we have obtained some additional evidence in favor of this viewpoint in experiments on the supercooling of lead droplets coated with different surface films. The distribution of lead droplets, ostensibly coated with lead sulphate, with respect to solidification temperature exhibited two distinct and reproducible maxima, one at 20" supercooling and the other at 47". On the other hand, when the droplets were ostensibly coated with halide films, no solidification was perceptible until the aggregate was supercooled more than 55". Upon further cooling a single well-defined peak centering at 60" supercooling was observed. Since the particle size distribution was the same in these two sets of experiments it appears that the most reasonable interpretation of the results is that the sulphate surface film or its reaction products with lead are much more effective in catalyzing the nucleation of lead crystals than are lead halide films. C. S. Smith (authors' reply)—Dr. Turnbull's experiments with lead drops coated with various surface films are most interesting. However, before drawing conclusions from the cooling curves described in the paper as to the existence of a few nucleus types effective at a few different temperatures, one must consider the state of subdivision of the liquid metal. In the A1-Sn alloy used, the tin was not in uniform droplets but tended to collect in three distinct shapes—in long interconnecting prisms along grain edges, in somewhat elongated interdendritic branching pools. and in isolated droplets. A single nucleus will solidify only the metal in contact with it, and the heat evolved will be proportional to the connected volume. A uniform distribution of nuclei of random effectiveness in such an alloy will cause peaks on the specific heat curve on cooling, which correspond to the volume distribution of tin and tell nothing about the nucleus type. In any real alloy both effects will be combined, and it seems impossible at present to distinguish between them. M. B. Bever—The thesis of this interesting paper is supported by a combination of positive and negative evidence. The authors have shown that under certain conditions a liquid phase may undercool, if it is dispersed in a thoroughly discontinuous manner throughout a solid matrix. They also found that undercooling

Jan 1, 1951

By Klaus Schwerdtfeger, Leo Zwell

The equilibrium between Ir-Fe or Rh-Fe alloys, iron oxide (wüstite or magnetite), and CO2-CO atmospheres has been determined at 1200°C. The data are used to derive the activities in these binary solid solutions. Both systems show negative deviations from Raoult's law. The lattice parameters are given for the investigated Ir-Fe and Rh-Fe alloys. IRIDIUM and iron form a continuous series of fcc solid solutions at elevated temperatures.' Rhodium-rich Rh- Fe alloys have fcc structure.' In the medium concentration range an ordered bcc phase is stable at temperatures up to about 1300°C. Phase relations in iron-rich alloys are not well-known. No thermody-namic data are available for these alloys. EXPERIMENTAL METHOD The experimental method used was to measure the equilibria between a gas phase of known CO2/C0 ratio, the alloy, and iron oxide (wüstite or magnetite). In one series of experiments the alloys of known composition were heated in CO 2-CO gas mixtures. After treatment (usually 1 day) the sample was quenched to room temperature and its surface examined visually to determine whether an oxide tarnish had formed. The procedure was repeated at slightly higher CO 2/CO ratios until the CO 2/CO ratio of incipient oxidation was found. Subsequently, the CO 2/C0 ratio was lowered again in small increments until the tarnish was reduced. In other experiments mixtures of alloy and iron oxide powders were pressed into pellets and equilibrated with the CO2-CO gas phase. In order to ensure that equilibrium was attained, two specimens with different starting iron content were heated side by side; in most cases, equilibrium was approached in one pellet by reduction of iron oxide and in the other pellet by oxidation of metallic iron. The sample was quenched to room temperature, and the composition of the equilibrated alloy was determined by X-ray measurements of lattice parameters and comparison of these values with calibration curves obtained from alloys of known composition. The oxides present in the specimens were identified by comparison of their diffraction patterns with those in the ASTM Card File. It may be expected from the noble character of iridium and rhodium that no appreciable amount of iridium or rhodium is dissolved in wiistite and magnetite under the present experimental conditions. The activity of iron in the alloy is then equal to that established in the iron oxide by the COrCO atmosphere. The activities of iron in wüstite and magnetite, as a function of oxygen pressure, were taken from the work of Darken and Gurry,

Jan 1, 1969

By R. W. Raymond

ChaRles William HenRy Kirchhoff was born March 28, 1853, at San Francisco, Cal., where his father, Charles Kirchhoff, was at that time consul for his native country, Germany. A few years later, the family moved' to Hoboken, K. J., in which city the son received his preliminary education at the Hoboken Academy, proceeding later to Germany, where he was graduated in 1874 as mining engineer and metallurgist at the Prussian Royal Mining Academy of Clausthal, in the Harz. Upon his return to the United States, he became chemist of the Delaware Lead Refinery at Philadelphia, and retained that position for three years. But in 1877 he began what was to be an almost uninterrupted life-long association with David Williams, the publisher of The Iron Age, of New York, who established in that year, and continued for a brief period, a journal entitled the Metallurgical Review, on the editorial staff of which Mr. Kirchhoff received a place. The enterprise was doubtless an attempt to cover a wide metallurgical field outside of that which properly belonged to The Iron Age. But it was soon abandoned, and Mr. Williams wisely concentrated his energies upon the older journal, which, under his vigorous and skillful management, and the labors of the able editors and correspondents whom he selected, became one of the greatest institutions of its class in the world. From 1878 to 1881, Mr. Kirchhoff was assistant editor of The Iron Age. From 1881 to 1884, he was managing editor of the Engineering and Mining Journal; in 1884 he returned to The Iron Age, to become for five years its associate editor, and in 1889, on the retirement of James C. Bayles, editor-in-chief. This list of dates and employments, without further comment, sufficiently indicates, at least to the eye of an expert, that Mr. Kirchhoff had found his congenial career in trade journalism. His qualifications for this profession were somewhat exceptional. He possessed the scientific training, the knowledge of foreign languages and literatures, and the power of making and keeping friends, which enabled him to get early notice of technical novelties; he had the taste for statistics which made him both industrious and intelligent in their collection and use; and to these traits he added a mastery of the meaning of such accumulated data, and a sane, critical judgment of the situations which they represented, as well as of the sources and the figures themselves, which made his opinion weighty

Jan 1, 1917

Edmund Gybbon SpilsbURy, mining and metallurgical engineer of international reputation, died suddenly of heart failure on May 28, 1920, in the New York Eye and Ear Infirmary, following an operation for cataract, which had been successfully performed a few days before. Mr. Spilsbury was one of the early members of the American Institute of Mining Engineers, which he joined in 1873. During all this time he contributed freely of his time and ability. He was manager of the Institute from 1885 to 1887, vice-president, 1893 and 1894, and president in 1896. He was also a member of the Engineers Club, of which he was president in 1916 and 1917, American Society of Civil Engineers, American Society of Mechanical Engineers, Institution of Mining and Metallurgy, Mining and Metallurgical Society of America, American Electrochemical Society and the Rocky Mountain Club of New York. He was a trustee of the United Engineering Society from 1916 to his death; a member of United Engineering Society Library Board from its organization in 1913 until his death, being its chairman from 1918 to January, 1920; a trustee of Engineering Foundation Board from 1916 until his death; and member of the John Fritz Medal Board of Award. He was also a member of the Division of Engineering of the National Research Council. Born in London, England, in 1845, Mr. Spilsbury went to Liege, Belgium, at an early age, where he received his preliminary education. For his technical education he attended the University of Louvain, Belgium, graduating in 1862, and later he took a practical course at Clausthal, Germany. In 1864 he became assistant engineer for the Eschweiler Zinc Co., of Stolberg, one of the largest miners and smelters of lead and zinc in the world at that time, and the next year he took charge of that company's mines and works on the Island of Sardinia. From Sardinia he went to the Atlas Mountains in Morocco. In 1867 he entered the service of McClean & Stilman, of London, and had charge of the construction of the iron gates for the Surrey Commercial Docks. In 1868 he was designing engineer with J. Casper Harkort, and had charge of most of the detail work of the Keulenberg Bridge in Holland, the Danube Bridge in Vienna, and the Rhine Bridge at Düsseldorf. In 1870 Mr. Spilsbury came to the United States to investigate the lead and zinc resources for the Austro-Belgian Metallurgical Co. After spending two years in this work, he resigned in order to practice in the United States, and he was the first to introduce the Harz system of ore

Jan 1, 1922

Geostatistics originated as an application of a classical statistical concept, multivariate linear regression, to the solution of a practical problem, estimation of reserves in the South African gold mines. In this respect, geostatistics should only be considered as one statistical method among many that can be used to evaluate mineral deposits. R.F. Shurtz has studied possible applications of power spectrum analysis to the same problem, and these studies may result in future improvements over the presently accepted geostatistical methodology. The intention of R.F. Shurtz's paper, as stated by the author, is to "relate geostatistical doctrine to classical statistical and mathematical concepts." However, in this comparison the "geostatistical doctrine" appears to include only the simplest among the geostatistical concepts advocated by G. Matheron, while "classical statistical and mathematical concepts" are limited nearly exclusively to power spectrum analysis. The author attempts to compare the two methods, and to prove the theoretical superiority of power spectrum analysis. Unfortunately, a number of errors and incorrect statements are made concerning both the theory and application of geostatistics, which invalidate the comparison and the conclusions drawn from it. The errors made in this comparison are understandable since few scientists can claim to have expertise in two theories as diverse as those compared here. In many respects, this paper is reminiscent of polemics which occurred 15 to 20 years ago when geostatistics and trend surface analysis were compared. Each method has its own merit and limitations, and none can claim absolute superiority. The most misleading statements found in R.F. Shurtz's paper are: The definition of the semivariogram given on page 1923 is incorrect. If the maximum difference between two assays is 1, the maximum value of the semivariogram is not 1, as stated, but 0.5. The comparison of geostatistics and linear regression made in the section entitled "Insufficiency of Classical Statistics?" is not valid. The semivariogram of the sample values given in Table 1 (page 1919) has a parabolic shape indicative of a linear drift. When such a semivariogram is observed, the simplest method of geostatistical estimation (linear kriging with unknown mean) is not applicable. Universal kriging must be used that takes trends into account. On page 1921 it is stated that the use of trends "is officially disparaged in geostatistics." Again on page 1924 mention is made to "Matheron's commitment to random process (intrinsic) models and his present categorical rejection of deterministic (trend) models for mineral deposit evaluation." Indeed, from articles published by geostatisticians in the 1960s one could infer that geostatistical methods are not compatible with the presence of trends. However, even the simplest

Jan 1, 1984

By Clarence Zener

THE internal friction of nonferrous metals vibrating at low stress amplitudes has so far always been successfully interpreted in terms of inhomogeneities of one sort or another. Examples are the fluctuation of stress across a specimen vibrating transversely,1,2,3 the stress inhomogeneities due to the elastic anisotropy and partial random orientation of the individual crystallites,4,5 localized weak regions introduced by cold-working,6,7 grain boundaries and possibly twinning planes.8,9 Perfect single crystals are, by definition, homogeneous. Actual single crystals usually, perhaps always, contains some imperfections. The present investigation. was undertaken to determine whether the internal friction of single crystals may likewise be attributed to inhomogeneities. This study was made possible through the gift of a large single crystal of 70-30 alpha brass by H. L. Burghoff, of the Chase Brass and Copper Co. The specimen, ½ in. in diameter and 10 in. long, was similar to samples previously described by Mr. Burghoff.10 EXPERIMENTAL METHOD The experimental method used has previously been described in Institute papers.5,6,9 The measure of internal friction adopted here, 1/Q, is (1/p) X the logarithmic decrement, a measure used by some writers, and is also (1/2p) X the specific damping capacity, a measure used by other writers. In all measurements the stress level was kept so low that the measurements were independent of stress level. In all measurements in which the temperature was varied, observations were made as the specimen slowly cooled from its highest temperature. The specimen was vibrated transversely. Observations were made at the funda¬mental frequency and at the first overtone, of about 620 and 1710 cycles per second, respectively. No attempt was made to avoid acoustical losses. EXPERIMENTAL RESULTS The specimen was annealed for several hours at 450°C. The temperature dependence of the internal friction was then determined from room temperature to 400°C. As shown in Fig. 1, the internal friction increased by only a factor of 2 from room temperature to 300°C., then by a factor of l00 during the next 100° interval. These measurements are consistent with the view that the observed internal friction is the superposition of two distinct parts. One, dominant at room temperature, is nearly independent of temperature. This part may be accounted for by acoustical losses and by transverse thermal currents. It was not further investigated. The second part, when plotted in the manner of Fig. I, lies upon a straight line. Therefore it has a heat of activation H; i.e., it varies with temperature as Internal friction e~H/RT [I]

Jan 1, 1942

By D. A. Woodford

A number of observations have now been reported where the steady-state creep rate is apparently linearly dependent on the applied stress at high temperature and low stresses. This results in a creep rate greater than that predicted by extrapolation of high-stress data and has obvious practical implications. However, some of these observations are open to question. For example, the analysis by Harris and Partridge17 of the data of Greenfield et a1.18 was dependent on strain rates which, according to the original authors, were too low to be measured. Dr. Bernstein appears to have demonstrated a linear stress dependence at low stresses in two zirconium alloys. There are, however, a number of discrepancies in his treatment of the data and the subsequent theoretical analysis which require clarification. 1) It is incorrectly stated that steady-state conditions are revealed by a slope of unity on a plot of log i vs log (time). This objection is trivial if the author meant to say a slope of zero, although it is unclear how subsequent extrapolation was made to determine the steady-state creep rates at low stresses for the zircaloy-2. If the plot used was actually log c vs log (time), it is unlikely that a slope of unity would represent a constant creep rate. A plot of log (c - co) vs log (time), where c0 is the extrapolated intercept sf the steady-state creep rate on the strain axis, would have a slope of unity during steady-state creep. However, eo cannot be determined unless is is already known. 2) The author chooses to interpret his results based on the equation: where A, and B, are structure-sensitive parameters, Ql and Q, are the activation energies for the particular creep process, and n describes the sensitivity of the creep rate on stress. The first term represents a slip creep process and the second a diffusion creep process. However, it is stated later that "two distinct processes acting in parallel are involved". Eq. [I] surely represents two processes in series since each reacts to the total applied stress and t, is the sum of the individual creep rates. If the processes are acting in parallel, then the effective stress in each would be less than the applied stress. The component stresses would be given by sl + s2 = a but it is not clear how the magnitude of either, or the corresponding stress exponent, could be determined.

Jan 1, 1969

By Clarence Zener

THE internal friction of nonferrous metals vibrating at low stress amplitudes has so far always been successfully interpreted in terms of inhomogeneities of one sort or another. Examples are the fluctuation of stress across a specimen vibrating transversely,1,2,3 the stress inhomogeneities due to the elastic anisotropy and partial random orientation of the individual crystallites,4,5 localized weak regions introduced by cold-working,6,7 grain boundaries and possibly twinning planes.8.9 Perfect single crystals are, by definition, homogeneous. Actual single crystals usually, perhaps always, contains some imperfections. The present investigation was undertaken to determine whether the internal friction of single crystals may likewise be attributed to inhomogeneities. This study was made possible through the gift of a large single crystal of 70-30 alpha brass by H. L. Burghoff, of the Chase Brass and Copper Co. The specimen, 3-s in. in diameter and 10 in. long, was similar to samples previously described by Mr. Burghoff.10 EXPERIMENTAL METHOD The experimental method used has previously been described in Institute papers.5,6.9 The measure of internal friction adopted here, I/Q, is (p) X the logarithmic decrement, a measure used by some writers, and is also (I/2p) X the specific damping capacity, a measure used by other writers. In all measurements the stress level was kept so low that the measurements were independent of stress level. In all measurements in which the temperature was varied, observations were made as the specimen slowly cooled from its highest temperature. The specimen was vibrated transversely. Observations were made at the fundamental frequency and at the first overtone, of about 620 and 1710 cycles per second, respectively. No attempt was made to avoid acoustical losses. EXPERIMENTAL RESULTS The specimen was annealed for several hours at 450°C. The temperature dependence of the internal friction was then determined from room temperature to 400°°C. As shown in Fig. i, the internal friction increased by only a factor of 2 from room temperature to 300°°C., then by a factor of 100 during the next :too' interval. These measurements are consistent with the view that the observed internal friction is the superposition of two distinct parts. One, dominant at room temperature, is nearly independent of temperature. This part may be accounted for by acoustical losses and by transverse thermal currents. It was not further investigated. The second part, when plotted in the manner of Fig. I, lies upon a straight line. Therefore it has a heat of activation H; i.e., it varies with temperature as Internal friction ~ e-HI/RT [I]

Jan 1, 1942

Edmund Gybbon SpilsbURy, mining and metallurgical engineer of international reputation, died suddenly of heart failure on May 28, 1920, in the New York Eye and Ear Infirmary, following an operation for cataract, which had been successfully performed a few days before. Mr. Spilsbury was one of the early members of the American Institute of Mining Engineers, which he joined in 1873. During all this time he contributed freely of his time and ability. He was manager of the Institute from 1885 to 1887, vice-president, 1893 and 1894, and president in 1896. He was also a member of the Engineers Club, of which he was president in 1916 and 1917, American Society of Civil Engineers, American Society of Mechanical Engineers, Institution of Mining and Metallurgy, Mining and Metallurgical Society of America, American Electrochemical Society and the Rocky Mountain Club of New York. He was a trustee of the United Engineering Society from 1916 to his death; a member of United Engineering Society Library Board from its organization in 1913 until his death, being its chairman from 1918 to January, 1920; a trustee of Engineering Foundation Board from 1916 until his death; and member of the John Fritz Medal Board of Award. He was also a member of the Division of Engineering of the National Research Council. Born in London, England, in 1845, Mr. Spilsbury went to Liege, Belgium, at an early age, where he received his preliminary education. For his technical education he attended the University of Louvain, Belgium, graduating in 1862, and later he took a practical course at Clausthal, Germany. In 1864 he became assistant engineer for the Eschweiler Zinc Co., of Stolberg, one of the largest miners and smelters of lead and zinc in the world at that time, and the next year he took charge of that company's mines and works on the Island of Sardinia. From Sardinia he went to the Atlas Mountains in Morocco. In 1867 he entered the service of McClean & Stilman, of London, and had charge of the construction of the iron gates for the Surrey Commercial Docks. In 1868 he was designing engineer with J. Casper Harkort, and had charge of most of the detail work of the Keulenberg Bridge in Holland, the Danube Bridge in Vienna, and the Rhine Bridge at Düsseldorf. In 1870 Mr. Spilsbury came to the United States to investigate the lead and zinc resources for the Austro-Belgian Metallurgical Co. After spending two years in this work, he resigned in order to practice in the United States, and he was the first to introduce the Harz system of ore

Jan 1, 1922

By Michael B. Bever, Carl F. Floe

The solubility of hydrogen in molten copper-tin alloys is of both practical and theoretical interest. From a practical standpoint, data on the equilibrium solubility as a function of temperature, pressure and alloy composition are valuable for a better understanding of porosity problems in bronze castings. From the theoretical point of view the determination of the hydrogen-copper-tin equilibrium is of interest since it extends the laws governing the solution of gases in metals. This paper presents the results of an investigation of the solubility of hydrogen in representative compositions of the copper-tin system at temperatures ranging from above the liquidus to I300°C. and at pressures from less than 50 mm. of mercury to about atmospheric. Review of Previous Work The solubility of hydrogen in copper was determined by Sieverts and Krumbhaarl in 1910 and by Roentgen and Moeller2 in 1934. Their values are in fair agreement. In 1926 Iwasé3 reported results that were very much higher. The published data on the solubility of hydrogen in tin do not agree. Smithells4 states that no reliable data are available According to Sieverts and Krumbhaar,5 hydrogen is insoluble in tin. Bircumshaw,6 on the other hand, found a definite solubility at 800°C. The latter's experimental procedure did not provide for stirring of the metal and in his opinion he failed to reach equilibrium. Iwasé3 again reported large solubility values. For copper alloys, Sieverts and Krumbhaar5 distinguished between alloying elements that do not markedly affect the solubility of hydrogen, elements that increase the solubility, and elements that reduce it. They named gold, tin, and aluminum as examples of this last group and reported hydrogen solubility data at 1225°C. for the copper-rich side of these alloy systems at atmospheric pressure. Without giving experimental results, they stated that the amount of hydrogen dissolved by liquid copper alloys is proportional to the square root of the pressure as in pure metals. These authors suggested that in a limited way the effect of an alloying element on the solubility of a gas is related to the constitution diagram for the alloy system. Sieverts7 also called attention to the fact that the curve of hydrogen solubility versus composition of copper-tin alloys shows a sharp change of direction at the composition of Cu3Sn and suggested that this compound persists at least to some extent in the molten state. Iwasé3 reported large hydrogen solubility values for several compositions of copper-tin alloys, which appear to be in error.

Jan 1, 1944

By W. M. Rust, W. D, D. W. Mounce

The almost universal acceptance of electrical logging by the petroleum industry calls for a critical examination of the physical bases of the common methods. This is particularly needed for the natural potential log. The conventional explanations are based on the phenomena of electrofiltration and electro-osmosis. However, experimental data show that they fail to give a basis that is quantitatively sound. Moreover, they lead to interpretations of details of electrical logs that are erroneous. It was found experimentally that when a plug of shale is placed in a chain of dissimilar electrolytes, a current flow results. Experiments on oil-well cores and fluids similar to those existing in wells show that potentials are set up which are in reasonable agreement with those encountered in electrical logging. Doubtless other sources of potential are important but this explanation not only accounts for much of the potential but also clarifies some fairly familiar examples of misinterpretations. Introduction The extraordinary value of electrical well logging as a tool for petroleum engineers and geologists is now so uni- versally recognized that it is not necessary to point out the ways in which it can be useful. It is sufficient to mention only the saving that has resulted from the elimination of much coring that would have been necessary under former practices and the considerable additions to reserves resulting from the discovery of sands missed in coring. Paradoxically, the very remarkable success that has resulted from the application of electrical logging to correlation and completion problems has cost some of its most consistent users dearly.' The fact that some operators have placed unwarranted faith in erroneous interpretations of electrical logs does not reduce the value of the logs. It should, however, make one pause long enough to ask why experienced users should be misled. The answer to this question is not hard to find. In nearly every case, the fault has been oversimplification. This is illustrated very aptly by the familiar interpretation and theory of the natural potential log. Recording and Interpreting Logs The natural potential log is extremely simple to record precisely enough for all present-day uses. One needs only an electrode, a cable to lower the electrode through the drilling mud, a recording meter and a surface ground connection. The electrode can be elaborate but need not be. A simple brass rod 2 in, in diameter and 2 or 3 in. long is quite satisfactory. The cable need not be particularly well insulated, nor need it have a very low resistance. The recorder can be a vacuum-tube 1 References are at the end of the paper.

Jan 1, 1944

By F. M. Lewis, J. F. Meyers

This second progress report of grinding presents comments regarding ball consumption and data pertaining to the hydroscillator, which is closed circuited with the tricone mill. A study and postulate of how balls function is presented. The paper summarizes cost reduction obtained by the method of "grinding for the tail race" rather than for "mesh tons." AT the Regional meeting in Columbus, Ohio, in September 1949, the authors presented a progress report of the first year's operation with a Hardinge tricone mill in closed circuit with a Dorr hydroscillator. The present report covers our findings on this grinding circuit to January, 1950. In order to clarify our position, the authors wish to state that no invention or discovery is claimed. The Tennessee grinding circuit is simply an engineered arrangement of known equipment arranged to incorporate all of the recognized efficiency factors of comminution as they are known today. As we concluded our first report, it was not clear how effective the Tennessee mode of operation would be on harder ores. The only information we had at that time was that the Bond grindability test at 48-mesh gave 6.04 g of undersize per revolution. A later test on the same sample at 100-mesh reduced this to 2.04 g, which is definitely in the harder ore class, and which makes the reported 8.80 kw-hr per ton of —200-mesh produced a very creditable figure. Hydroscillator Operation The machine as now developed has proved dependable and easy to operate. It starts easily under full load and responds quickly to operating adjustments. The hydraulic holes in the oscillating plate do not plug when shut down under full load. Absolutely clean hydraulic water is essential. An Elliott water screen or similar device should be an essential part of the machine to keep all scale and trash of all kinds from the hydraulic compartment. The shift operators have expressed approval of the machine. In table I we show a typical screen analysis of the hydroscillator rake sand as compared to conventional classifier rake sand on our ore. We have previously reported that of the 28.7 pct reduction in power, the hydroscillator contributed 6 pct, on a —200-mesh basis. This is a conservative figure. Some of our test runs indicated that the saving was as high as 10 pct. Laboratory studies by the Dorr Co. engineers indicate that still greater efficiency is possible. Nevertheless, the 10-ft plate is overflowing 2100 tons per day at 3 to 4 pct + 65-mesh, which is a very creditable performance by

Jan 1, 1951

By John Chipman, Eric R. Jette, O. B. Ellis

IN the study of the chemical reactions occurring in the open-hearth furnace, it is frequently assumed that a condition of equilibrium between slag and metal is attained. In order to test this assumption it is necessary to have dependable operating data as well as an exact knowledge of the equilibrium state. Considerable progress has already been made in the study of slag-metal equilibria, notably in the earlier work of Herty1 and of Oberhoffer and Schenck2 and in the more recent researches of Krings and Schackmann3 and of Koerber and Oelsen.4 None of these investigators, however, have employed basic slags comparable to those encountered in basic open-hearth practice, so that up to the present time our only information regarding the equilibria of these slags is based upon observations drawn from steelmaking practice in which there is little assurance that actual equilibrium was attained. The original plan of this investigation was to secure simultaneous slag and metal samples at intervals during the making of an open-hearth heat, recording the heat history in detail and obtaining complete analyses of slag and metal, then to bring these slag samples into equilibrium with liquid iron in the laboratory induction furnace and thus to determine directly whether or not the observed relationships in the open hearth represent conditions approaching equilibrium. This plan was only partly successful. While slags were obtained from the open hearth under satisfactorily recorded conditions and these were remelted in the laboratory under equilibrium conditions, changes in slag composition, which accompanied the remelting operation, were so great that the final slag from the induction furnace bore little resemblance to its open-hearth parent and the direct comparison was therefore abandoned. The results, however, lie within a range of slag composition that is of interest in the making of low-carbon steel. As far as we are aware, they represent the first published laboratory study of equilibria involving slags that contain all the constituents of basic open-hearth slag. EXPERIMENTAL HEATS The first set of measurements on slagmetal equilibrium was made in the Research Laboratories of the American Rolling Mill Co. at Middletown, Ohio. This will be known as series A. The second set was made in the Metallurgical Research Laboratories at Massachusetts Institute of Technology, and will be referred to as series B. Series A.-The induction furnace used has been described.5 Approximately I kg. of a special ingot iron containing less than

Jan 1, 1941

By Carl F. Floe, Michael B. Bever

The solubility of hydrogen in molten copper-tin alloys is of both practical and theoretical interest. From a practical standpoint, data on the equilibrium solubility as a function of temperature, pressure and alloy composition are valuable for a better understanding of porosity problems in bronze castings. From the theoretical point of view the determination of the hydrogen-copper-tin equilibrium is of interest since it extends the laws governing the solution of gases in metals. This paper presents the results of an investigation of the solubility of hydrogen in representative compositions of the copper-tin system at temperatures ranging from above the liquidus to I300°C. and at pressures from less than 50 mm. of mercury to about atmospheric. Review of Previous Work The solubility of hydrogen in copper was determined by Sieverts and Krumbhaarl in 1910 and by Roentgen and Moeller2 in 1934. Their values are in fair agreement. In 1926 Iwasé3 reported results that were very much higher. The published data on the solubility of hydrogen in tin do not agree. Smithells4 states that no reliable data are available According to Sieverts and Krumbhaar,5 hydrogen is insoluble in tin. Bircumshaw,6 on the other hand, found a definite solubility at 800°C. The latter's experimental procedure did not provide for stirring of the metal and in his opinion he failed to reach equilibrium. Iwasé3 again reported large solubility values. For copper alloys, Sieverts and Krumbhaar5 distinguished between alloying elements that do not markedly affect the solubility of hydrogen, elements that increase the solubility, and elements that reduce it. They named gold, tin, and aluminum as examples of this last group and reported hydrogen solubility data at 1225°C. for the copper-rich side of these alloy systems at atmospheric pressure. Without giving experimental results, they stated that the amount of hydrogen dissolved by liquid copper alloys is proportional to the square root of the pressure as in pure metals. These authors suggested that in a limited way the effect of an alloying element on the solubility of a gas is related to the constitution diagram for the alloy system. Sieverts7 also called attention to the fact that the curve of hydrogen solubility versus composition of copper-tin alloys shows a sharp change of direction at the composition of Cu3Sn and suggested that this compound persists at least to some extent in the molten state. Iwasé3 reported large hydrogen solubility values for several compositions of copper-tin alloys, which appear to be in error.

Jan 1, 1944

By E. H. Rose

THE present symposium on flotation machines provides a unique opportunity for group reappraisal of standard or habitual viewpoints. A symposium is by definition a trading post for observations that might prove complementary when put together, thus leading to useful thoughts that might not have been evident from the original observations individually. The present paper, pertaining to power consumption in flotation, is deliberately an experiment of that kind. Data were solicited from the operating superintendents of several of the major flotation plants on this continent. The information received, covering a total of 14 separate operations in seven plants, has been collated in terms of power intensity; that is, the total power input per cubic foot of cell volume. This departs somewhat from the conventional expression of power per ton of ore treated, though the latter figure is also given for the plants concerned. Because of wartime restrictions, particularly in Canada, identifying names of plants and machines are withheld. Not as a firm conclusion, but as a tender for symposium discussion, the following points are made: I. That flotation is a power operation in much the same sense as ball milling. 2. That contact time is the complement of power intensity and may be decreased as the latter is increased. 3. That a decrease in flotation power per ton of ore can result from an increase in power intensity. ANALOGY WITH GRINDING In grinding, it has become axiomatic that the more the power put into a given operation, the greater the work performance. The analogous view is now proposed that the effectiveness of any flotation operation will be related to the mechanical energy usefully applied to that operation. Under this view, each increment of properly directed input energy should give either an increase in unit tonnage or an improvement in the metallurgical separation (concentrate grade or tailing grade), until either the theoretical limit imposed by mineral constitution or surface condition is reached, or until further increments of power become uneconomic under the law of diminishing returns. Thus, as in grinding, there are two forms of output that greater power input or improved utilization of power can produce. As for the law of diminishing returns, lower unit cost of power through improved generating efficiency in the past decade has pushed the limit back. Over and above this, however, there is strong indication in the operationg data herein presented that higher power intensity results in an actual economy of over-all power consumption. Like crushing and grinding, flotation accomplishes a rupture of the forces of molecular attraction, by taking particles from the common environment and placing them in the two separate environments of

Jan 1, 1944