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By R. C. Reed, L. T. Wu, H. C. Harada, K. Kawagish, R. T. Wu

Oxidation of pure metals is a chemical reaction in which the metal loses one or more electrons, such that the atom of the metal changes from the neutral state to a positively charge ion and reacts with oxygen to form an oxide of the metal. The oxide can form as a protective and adherent scale that slows down further oxidation, or may spall off repeatedly, exposing fresh metal surface to react with oxygen. In multi-component alloy systems such as typical high temperature NiCrAlY bond coats, more than one oxidation mechanism may take place at once and thus, complicates the study of oxidation. To better understand the competition between formations of oxides of different compositions, a thermodynamic assessment is carried out to study the oxidation mechanism of a Ni-27Cr-9Al (at %) ternary alloy. Based on the assessment, it is demonstrated that the layering of different oxides can be determined, with the most stable oxide (alumina) existing directly above the metal-oxide interface and the least stable oxide (nickel oxide) locating on the outer most layer. A comparison between the calculated results and previously published experimental observations shows excellent agreement.

Jan 1, 2010

By N. Ahmed

This paper is concerned with the drainage behaviour of gangue mineral in the froth phase. Experiments were carried out in a continuous laboratory flotation cell in which froth depth and bubble size could be changed independently. The fraction of solids returning from the froth to the pulp zone was expressed using a rate constant. A mixture of hydrophilic solids (silica) and floatable particles (glass ballotini) was used as a flotation feed. Samples of glass ballotini of different hydrophobicities were obtained, using controlled silanation. Three samples, with contact angles of 50, 66, 82 degrees, were used. The effect of the initial bubble size (pulp bubble size), concentration of gangue mineral in the froth zone, and froth depth on the drainage of silica, were investigated. The drainage rate of the entrained solids increases with an increase in the degree of hydrophobicity of the floatable particles. Concerning the effect of pulp bubble size on the drainage rate of entrained solids, larger bubbles always give higher drainage rates due to formation of relatively loose froth structures which allow gangue particles to easily move down to the pulp zone. Conversely, smaller bubbles exhibit lower drainage rate constants, in particular at shallow froth depths.

Jan 1, 2003

By J. B. Zadra, S. M. Shelton, M. M. Fine

"Ferrograde manganese ore or its equivalent is essential to the manufacture of every ton of steel produced; although it is well known that there are large deposits of low-grade ore in the United States, the production of substantial amounts of ferrograde material from domestic sources presents a problem that becomes more and more critical as the stockpiled ore is depleted through inability to procure adequate supplies from foreign sources. Consequently, a program of laboratory and pilot-plant investigation designed to solve the problem of obtaining a domestic supply of manganese has been undertaken by the Metallurgical Division, Bureau of Mines.This paper is one of a new series that will include reports of results obtained in the various investigations conducted under the manganese program. The scope of the program and the organization that woo set up to direct and supervise the work were discussed in the foreword of the first paper of this series, Report of Investigations 3606, Manganese Investigations. 1. Concentration of Manganese Ores from the Drum Mountain District, Utah, by S. R. Zimmerley, J. D. Vincent, and C. R. Schack. Other reports will be published as the work progresses."

Mar 1, 1942

By Roger Agnew

Sulphide ores mined by Inco Limited in the Sudbury District contain small quantities of cobalt. During beneficiation, cobalt distribution to various streams is similar to nickel. After smelting, nickel is selectively extracted by carbonyl refining and the cobalt remains in the carbonylation residue. This residue is processed in a specialized hydrometallurgical plant to produce precious metal residues, copper cathodes, and a nickel- cobalt carbonate intermediate product. The nickel-cobalt is shipped to Port Colborne where the cobalt is separated as cobaltic hydroxide and refined to metallic cobalt. This paper deals specifically with the recently constructed Electro Cobalt Refinery. The cobaltic hydroxide is dissolved and residual zinc, copper and nickel are removed by ion exchange and organics by a carbon column. The purified cobalt solution is fed to the electrowinning circuit where cobalt rounds are produced on stainless steel mandrels. In the design and construction of the refinery, special attention was directed to materials of construction both for the process equipment and the physical plant, operating control and flexibility, and the quality of the working environment. The end result is an efficient and clean operation which yields a product of excellent quality.

Jan 1, 1988

AlfreD H. Cowles, Cleveland, Ohio (commuaication to the Secretary*):—Mr.Gillette's paper and his deductions seem to me of the very greatest importance, if the validity of his conclusions and figures can be confirmed. His work seems to solve an unfinished problem that I attempted to solve on the same lines about two years ago, at a time when I was preparing a paper' on another subject for the American Electrochemical Society. The following paragraph is quoted from the paper referred to: "I feel convinced that a further study of the heats of combination now known for so many compounds, which merely express in other terms their voltages of disruption, will show us the allowance that must be made as a departure from unity in the case of each element, for the intrinsic charge of its elementary molecule, and thereby render possible the creation of a table of apparent relative atomic capacities for electricity, similar to the table of atomic weights. With the numerals of this table known, thermal reaction or energy-transformations will be read with the same ease that we now read and trace the shifting of mass

Jan 1, 1904

By Gennaro G. Marino

This paper summarizes and evaluates data on mine subsidence ground movements and associated damage for houses in Illinois. Based on the data collected, the response of homes to subsidence ground movements is expressed in terms of repair costs. A damage criteria is then proposed that relates the ground movements and damage levels. The data were collected as part of a comprehen¬sive study performed for the Illinois Abandoned ?Lined Lands Reclamation Council, A -M-RC, by the Civil Engineering Department at the University of Illinois, and probably will be published in late 1934 by the council. The study concentrated its efforts on surface ground movements and the effects to houses over abandoned room and pillar mines. The resultant surface subsidences are commonly dish or bowl shaped and are termed sags. Method of Analysis The steps in analysis used to arrive at the proposed damage criteria are: 1. Canvas and rap subsidence damage in houses, 2. Assess the associated ground movements, 3. Estimate the damage repair cost, 4. Develop a damage/repair level classifica¬tion, 5. Correlate the associated ground movement, damage/repair level and home construction type, 6. Propose a damage criteria.

Jan 1, 1984

By S. P. Singh

In order to simulate the operation of coal extraction machines, a portable workability instrument has been designed. Initially, the tests were performed with the instrument on modeling material, which were followed by in situ tests on coal in underground mines. The peak and mean cutting resistance and work done to cut a unit length of coal were determined for coal as well as modeling material. In addition, rebound strength and dynamic penetration tests were also performed in situ. On the basis of the cutting characteristics of coal, a "Workability Index" has been developed and its role in the judicious selection of coal cutting machines has been discussed. With reference to prior works and the strength characteristics of coal, it was found that the coal plow may not be suitable for the seams under investigation and the shearer seems to be the only choice. It has been observed that peak cutting resistance and the "Workability Index" in the case of coal as well as modeling material depend upon compressive strength. The peak cutting resistance exhibited certain dependence upon the Schmidt rebound hardness and dynamic penetration strength of coal in situ.

Jan 1, 1984

By T Walsh, S R. Mudnuru

The development of lithium-ion batteries, coupled with the global trend towards electrification of transportation, has led to a dramatic increase in the demand for lithium. The production of lithium from hard rock ores is increasing, and flotation has proved to be an effective means for the beneficiation of many pegmatitic lithium ores. Clariant Mining Solutions has developed a range of novel collectors for the flotation of spodumene and other lithium ores, and this paper presents examples of some of the most recent developments. Fatty acids are the typical collectors for lithium flotation, however the grade and recovery achieved with these collectors is often below the desired level. There are also some significant drawbacks associated with the use of fatty acid collectors, such as the formation of calcium soaps which give rise to filtration problems and the need for acid washing. Several FLOTINOR products have been developed as alternatives to fatty acids. These products offer equivalent or better metallurgical performance at significantly lower dosages than fatty acids. This offers benefits to the flotation circuit as well as potentially reducing the issues associated with downstream processing of the concentrate.

Aug 24, 2022

To Americans, Alaska occupies a unique position, both geographically and historically. The only integral portion of the United States lying in the sub-Arctic and Arctic regions of the Earth, the early remoteness and climatic conditions effectively combined to impede the economic development of this area. Although Alaska has been a part of our Nation since 1867, its mining industry is still at that stage of development which characterized the West 100 years ago when miners concentrated on high-grade lodes and rich placer deposits. Since World War II, however, there has been a noticeable increase of interest in the raw materials of the North. This concern has been most noticeable in Canada, Scandinavia and Russia, but it has been, and is being shown in Alaska. To the American mining industry, the potential importance of this State can be summed up by the question, "Can Alaskan mining compete successfully with those of other states and countries?" The answer revolves about the vital factors of geography, economics, and the political turmoil of the World. These aspects are among those discussed on the following pages in a series of articles by Alaskans and non-Alaskans alike. We invite you to read "Alaska: Regional Report."

Jan 12, 1961

By Chas. E. Shumate

There is assembled here this morning in Chicago the heartland of America, what is undoubtedly the greatest concentration of Technical, Scientific and "CAN DO" knowledge ever assembled in America. The participation in this Conference by the representatives of so many nations is particularly impressive and is a further indication of the importance of the subject matter of this conference which you will be discussing in much detail during the next few days. Another impressive feature of this Conference is the participation of a large segment of the construction industry in whose hands fall the job of building what others design. Also strongly represented is the manufacturing industry whose capability is well known throughout the world. They have the resources to design, develop and manufacture the machines and specialized equipment needed to do any job which the world requires. You should not expect to gain any knowledge from my few remarks this morning as I am undoubtedly the least qualified individual in this room on the highly technical and scientific subjects you will be discussing during these next few days. However, I shall offer a few broad suggestions on subject matter which I trust may generate serious thought during your discussions.

Jan 1, 1997

By Richard A. Thomas, Isaac A. Zlochower, Gregory M. Green, Kenneth L. Cashdollar, Martin Hertzberg

This paper reports the results of flammability studies for methane, propane. hydrogen, and deuterium gases in air conducted by the Pittsburgh Research Laboratory. Knowledge of the explosion hazards of these gases is important to the coal mining industry and to other industries that produce or use flammable gases. The experimental research was conducted in 20 L and 120 L closed explosion chambers under both quiescent and turbulent conditions, using both electric spark and pyrotechnic ignition sources. The data reported here generally confirm the data of previous investigators, but they are more comprehensive than those reported previously. The results illustrate the complications associated with buoyancy, turbulence, selective diffusion, and ignitor strength versus chamber size. Although the lower flammable limits (LFLs) are well defined for methane (CH,) and Propane (CA), the LFLs for hydrogen (HZ) and its heavier isotope deuterium (D2) are much more dependent on the limit criterion chosen. A similar behavior is observed for the upper flammable limit of propane. The data presented include lower and upper flammable limits, maximum pressures, and maximum rates of pressure rise. The rates of pressure rise, even when normalized by the cube root of the chamber volume (V 1/3), are shown to be sensitive to chamber size.

By R. S. Mateer

Linear programming on desktop computers is commonly used to optimize coal blending proportions. The objective function is usually the cost of the blend. The constraints consist of materials and heat balances as expressed as linear functions of the blend. This is illustrated in Example 1. Inclusion of a sulfur compliance constraint in more complex because the maximum permitted sulfur percentage is not a pre-specified constant. Rather, it is a function of the calorific power of the blend itself. The current limit of 1.2 pounds of sulfur dioxide per million Btu may be expressed as: [Sulfur Max%= 0.6 . Hl10,OOO with H in Btu/lb.] A proper constraint equation may be formed by defining for each coal a function that is the difference between the actual sulfur percentage and the maximum sulfur percentage. This may be regarded us an excess sulfur percentage. For Coal A of Example 1. this would be: [ Sulfur Excess%=0.5-0.6 13,000/10,000=-0.28] This value would be used as the coefficient of the weight proportions of this coal in the blend. The complete constraint equation would then be the sum of such terms for each coal set less than or equal to zero. This is illustrated in Example II. [ ]

Jan 1, 1995

[ ] ST. JOSEPH Lead Co., is entering the oil business. Andrew Fletcher, St. Joseph president, stated that plans call for a contract with the Continental Oil Co., to drill 11 exploratory wells. Six will be in Texas, one in southern Louisiana, one in northern Louisiana, and one each in California, Oklahoma, and Montana. St. Joseph is also negotiating a contract with the Zephyr Drilling Co., for wells in Wyoming and Colorado. St. Joseph is planning to drill another well on a 6000 acre plot in southern Illinois. Proxies issued before a special meeting of the board, said the new venture is not intended to change the general character of the company's business, or to involve a significant part of its resources. If gas, oil, or minerals are discovered in paying quantities, the company will develop and operate the deposits and dispose of the products for the joint account of Continental Oil and St. Joseph Lead. The mining company will contribute a proportionate share of the cost, but will have definite limitation of its obligation. The amendment to St. Joseph's certificate of corporation, passed by the board meeting, also extended the power of the company to include mining operations of all kinds.

Jan 1, 1952

By Jeaneth S. Benedetto

The physical and chemical processes developed for recovery of uranium and phosphor from phosphoro-uraniferous ore bodies consists of three basic steps: concentration of the phosphate bearing uranium by flotation, chemical dissolution of the concentrate by wet phosphoric acid and extraction of uranium by solvent. In this process two products are obtained: 1) uranium and 2) phosphoric acid. The purpose of this work was to develop technological know-how of phosphoric acid purification though an extraction of P2O5 by solvents. It was investigated by two lines of research. In the first one the uranium was extracted before the phosphoric acid purification. In the second, the phosphoric acid was extracted before uranium recovery. The comparison of the two processes is shown in this paper. Experimental work was developed on a laboratory scale to select and optimize the process variables. After the laboratory study, the research of extraction and stripping was continued on a pilot scale in pulsed perforated-plate columns in order to investigate the main operational and process conditions. The first phosphoric acid extraction experiments showed good results using a raffinate sample obtained from the uranium extraction process. It was possible to obtain a high purity phosphoric acid.

Jan 1, 2003

The United States Civil Service Commission announces open competitive examinations for the positions of valuation engineer, assistant valuation engineer, and valuation aid for the Income-tax Unit of the Internal Revenue Bureau. The duties of these positions will involve the estimating of: (1) The quantity of mineral, oil, and gas or timber; (2) the theoretical and market values of mineral, or oil and gas in place, standing timber, and their products; (3) the value of equipment ordinarily used in discovery, exploitation, and utilization of such natural resources; (4) the cost of development, exploitation, and utilization of such natural resources. The entrance salary for each grade, within the range stated, depending on the qualifications of the appointee, is: Valuation engineer, $3600 to $4800 a year, though in exceptional cases higher salaries may be paid; assistant valuation engineer, $2500 to $3600 a year; valuation aid, $1200 to $2500 a year. Applications for valuation aid must have had a bachelor's degree from a college of recognized standing, graduation from a four years' high-school course, or education equivalent to that required for such graduation, and at least four years' experience in the technical branches of one of the industries mentioned in positions tending to qualify them for the duties outlined above.

Jan 6, 1919

By M. Sabau

The Electrowinning Plant at INCO's Copper Cliff Nickel Refinery is a precious metals upgrading plant. The feed to the plant contains copper, nickel, cobalt, iron, significant amounts of precious metals and some impurities. Copper is the most abundant element in the feed. This paper describes the major equipment and process changes over the last twenty years, geared to improve the tankhouse operation, workroom environment and recovery of copper from the acidic solution. Copper is plated on to titanium blanks using explosion-bonded crossrods, animal glue as a levelling agent, and an organic surfactant for mist control. The installation of the stripping machine in 2001 required a number of changes: cathode and anode contacts were redesigned, flat bus bars were replaced with dog-bone type, spacer boards for cathodes and anodes were installed, longer anodes started to be used, and the plating cycle was extended from seven to fourteen days. A number of initiatives for improvement are being carried out. Explosion-bonded crossrods are being replaced with titanium-clad crossrods. The plan for the near future is to increase copper production by increasing current efficiency and current density. The possibility of lowering the iron concentration in electrolyte and changing the acid mist control method is being investigated.

Jan 1, 2007

Contribution by W.D. Ortlepp? The authors are to be commended for publishing their interesting view of an aspect of deep-level mining technology that is becoming increasingly topical and vitally important. This is the second paper in the journal within four months to deal with the crucial needs of highly stressed tunnel construction, the other being the paper on the design and testing of rockburst support in the February 1994 issue. Both papers re-examine important innovative ideas that are more than a quarter of a century old, but that have not yet been implemented by the industry. It is to be hoped that they will now, taken together, serve as a new starting point for a definitive examination of what constitutes proper tunnel-support design. There can be no question that the need to develop a design approach that will solve the problems of tunnelling at depths of 4000 m or more has now become crucial. Contribution by A.M.J. Vervoort* Although the overall paper is very interesting and the future research (comparison between numerical simulations and underground measurements) will be very challenging, I would like to make some remarks regarding the set-up of the numerical model and the interpretation of the elastic results.

Jan 1, 1995

In order to formulate appropriate and useful education and training policies and practices, it is crucial to firstly consider the demographic environment of our workforce-and the direction in which it is (known to be) heading. We can predict with a degree of certainty, that the role and influence of training on the future survivability of organisations will- become increasingly critical. This will be particularly relevant for those industries and organisations which are technologically based. The ad-hoc use of training is and, will no longer be appropriate. Organisations must move toward the on-going use of a dynamic education and training strategy based on an effective staff development programme, which meets the short and medium term needs of the organisation. The Technisearch approach is based on maximizing the efficacy of training and learning. The package provides.a total service to meet clients training needs using educational techniques geared to adult learning. it stresses the importance of ongoing research into industrial adult training and its effectiveness in improving skills and productivity. Current research on roles of supervisors in the Australian workplace and the development of the Supervisory Behaviour Questionnaire. (SBQ) indicates the need for a proper framework within which the objectives of training can be addressed.

Jan 1, 1986

On Feb. 16, 1948, the Board of Directors of AIME authorized the publishing of "Technical Notes" in METALS TECHNOLOGY. The purpose is to provide prompt publication of very short items of the following general types: I. Results of short investigations which do not warrant a paper. 2. The conclusions of extensive investigations of insufficient general interest to justify a regular paper. 3. Conclusions arising in the course of an investigation, which, because of interest to others in the field, the author wishes to present prior to completion of the investigation. 4. Pertinent factual comment (not mere argument) on the subject matter of previous "Notes." Such Notes will be subject to the approval of the Auxiliary and AIME Publications Committees, but can be handled more promptly than regular papers because they need not be referred to readers. The recommended maximum length is 500 words; notes in excess of 1,000 words will not be considered for this type of publication. A graph or photograph may be included as part of the note when particularly illustrative. As with regular papers, contributions to the new section should be submitted to the Secretarv of the AIME. Please furnish two copies, each complete with illustrations.

Jan 1, 1948

By Aalbers J. P A

The State Electricity Commission of Victoria (SECV) operates 13 excavators, 3 travelling stackers and 4 mobile slew conveyors in their three open cuts in the Latrobe Valley. The majority of these machines have been designed and constructed to a German design code current at the date of order. The SECV has always ensured that the machines were manufactured and erected to the appropriate standards. The SECV has a policy of having all machines inspected by an independent inspector every two years. These inspections are based on those carried out in Germany. The inspections have been carried out by inspectors from Germany who have the necessary experience to do similar work in German open cuts. Major faults found during the inspections have been repaired, however,the gradual breakdown of corrosion protection system has continued. The structures on some machines have areas of bad corrosion. This, coupled with wear on major mechanical equipment, would require an extensive outage to overhaul the machines. Refurbishment of Hazelwood Power Station will result in higher levels of production and extended life for the station. This will require improvement in the total output from Morwell Open Cut (MOC). To meet this increased coal demand, the open cut equipment will need to operate more efficiently and for a longer period of life.

Jan 1, 1989