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By Brady Butler

Many high capacity metal hydrides exhibit a high degree of stability in the hydrogenated state. This stability leads to a number of significant design problems with regard to the low temperature kinetics and thermodynamics of dehydrogenation. Nanometric metal hydride materials provide a promising route for increasing the reaction kinetics while altering the thermodynamic stability of the material. The use of nanometric metal hydride materials for hydrogen storage has largely been absent because of the difficulties associated with the synthesis of these materials. In this paper, research results on the synthesis of lithium based metal hydrides by vapor phase reactions are presented. The lithium based compounds that have been made in our lab include nanosized powders of metallic Li, Li₃N, LiNH₂ and LiH. The vapor phase process has also been used to custom engineer Li-based materials with other alloying elements or doping elements. The dependence of the characteristics of these materials on synthesis process parameters is studied. The effects of nanoscaled particle sizes on the kinetics of dehydrogenation and hydrogenation reactions are also explored.

Jan 1, 2006

At the office of the Chief of Engineers, Washington, there is a unique collection of engineering material used and developed in the present war. It. is a most interesting group of war devices, from the special trench shovel that excavates both gas and water, to the standard gage locomotives that were sent to France so complete that they were lifted from the ships by cranes, placed on the-rails on shore, filled with water, fired up, and moved out from underneath the cranes under their own steam. Everything is exhibited either by models, or by photograph where the original samples are too large to admit of demonstration in an ordinary office. The forestry section has an interesting exhibit of the wonderful work clone in France; where, owing to the shortage of coal and the necessity for burning wood, the Forestry Unit of the A. E. F. in one month stacked up 60 mi. of cord wood (80,000 cords); also cut 6.6 mi. of timber, stacked 12 ft. long, and 10 ft. high, containing 50,000,000 hoard feet of sawed timber.

Jan 3, 1919

Meeting of April 24, 1914.-President Thayer announced the appointment of the Committee on Safety and Sanitation. The Committee on Nominations for officers for 1915 was appointed, as follows: William J. Cox, Chairman; H. Poster Bain, Joseph Daniels, Charles E. Mills, R. V. Norris, E. Gybbon Spilsbury, and Herbert A. Wheeler. The request of twenty residents of Salt Lake City and vicinity for permission to establish the Utah-Nevada Local Section was granted and R. C. Gemmell was appointed Chairman of the Committee on Organization. The following resolution was adopted: Resolved: That under authority of Article V, Section 7, of the Constitution, a special Committee be and hereby is appointed, to consist of the President and six other members of the Institute, to be named by him, Who shall be authorized to appear before the proper authorities at Washington and urge that Mining Engineers be appointed upon the proposed Commission for revision of the Federal Mining Laws. Further Resolved: That the activities of this special Committee be restricted to the authority given in this resolution.

Jan 6, 1914

By Yuting Xue, Danqing Gao, Brijes Mishra

Heterogeneity and discontinuity significantly affect rockmass strength. Past studies have largely used arbitrary scaling approaches to produce rockmass strength from laboratory rock tests. This paper proposes a stochastic approach to produce rockmass strength from laboratory rock tests. Based on the laboratory data, MATLAB with an extreme value stochastic model generated a database for each physico-mechanical property of the rock. Then finite-difference software FLAC2D simulated laboratory-sized rock specimens. Random material properties in MATLAB were generated using the grids developed in the numerical model. The random properties were then applied to the final FLAC2D model. Model runs simulated the approach performed in the laboratory. The results from the model indicate that a stochastic approach produced compressive strengths that were lower than those from the deterministic approach. Failure modes for each specimen were different from those observed in the laboratory. In addition, random density also influenced the failure mode, highlighting the importance of stochastic analysis in rocks.

By F. C. Bond

B. H. Bergstrom (Allis-Chalmers Mfg. Co., Milwaukee)—In reading this article, it was difficult to follow through the example given as a starting point in the derivation of the theoretical equation which relates ball size to feed size. A discussion with F. C. Bond led to the following clarification: Bond postulates that "the breaking force exerted by a ball varies ... as the cube of its diameter . . ." and that the force in pounds per square inch required to break a particle varies ... as its diameter squared." He concludes: "It follows that when a l-in. ball breaks a 1-mm particle, a 2-in. ball will break a 4-mm particle, and a 3-in. ball a 9-mm particle." The above example can be true only for a different set of assumptions. Since the first assumption is apparently true, it is the second that must be revised. The second assumption should read that the breaking force required to break a particle varies as its diameter to the 3/2 power. This relationship was derived in the next paragraph of the article.

Jan 1, 1960

By Stubbs B

In conjunction with Charles Copeman, we have arranged the presentation of a paper by Charles with a support paper by myself presenting alternatives to currentaccepted legal concepts involving the ownership of minerals by the Crown and the absence of ownership in any minerals or entitlement to benefit therefrom by the owner of the land on or under which the minerals occur.2. The current situation has its historical route in the concept of gold and silver being royal metals and belonging wherever situated in the Kingdom to the King and it is submitted it can be'seen as being archaic in nature perhaps even feudal and perhaps worthy in this day and age of reconsideration.Our purpose in these papers is to present an alternative view supported by argument challenging the present system and hopefully, creating room for comment and interchange amongst those involved in the industry. My solutions are not Charles Copeman's solutions and vice-versa. However, we do share a common belief that the present system may not be the best system.

Jan 1, 1990

By Robert H. Richards

In the latter part of December a batch of amalgam was retorted and the tin in the retort uncovered while at a low red heat, and allowed to cool slowly to a temperature more suitable for ladling into moulds. It was then ladled and made what appeared to be nice, white, malleable block tin. On February 15th our attention is called to the fact that the tin is brittle, and on examination we find that the molecular condition of the pigs has changed to the extent of one-half its material. The change shows itself by an enlargement appearing on the surface something like crystallization, and comes in spots. The condition of the metal in these spots is very peculiar. It has changed from a malleable metal to a brittle one, with a structure somewhat resembling stibnite, and a color very considerably darker gray than tin. The analyses of the two parts of this tin pig showed the following results: Mercury. Tin. Specific Gravity. Crystalline part,.....2.62 97.24 6.175 Malleable part,.....2.38 97.50 7.387

Jan 1, 1883

By T Smith

The evaluation of a new mineral resource and its economic viability is critically dependant on the quality of the assay data as it is this data that defines the grade of the resource. However, all too often the procedures of sampling and chemical analyses used to generate such data are neglected or given little consideration until final modelling and evaluation are under way. This approach frequently requires large reassay and/or re-sampling programs to be undertaken to validate or to improve the integrity of the data base. This paper outlines a step by step approach to ensure quality data is achieved and then maintained throughout the entire exploration and resource development program. This involves the use of correct field sampling methods, assay methods designed to give the required levels of accuracy and precision and quality procedures in place to monitor the effectiveness of the overall process. Thorough documentation is an overriding and necessary part of the entire process. Practical examples are given to demonstrate the use and value of these methods.

Jan 1, 1998

By Houghton BF

Ruapehu is an extremely active andesitic composite volcano, built in at least four cone- building episodes over the last 250 ka. The volcano was constructed by a variety of extrusive and subplinian, strombolian, phreatomagmatic and dome-related explosive eruptions from summit, flank, and satellite vents. The volcano may be subdivided into the cone itself, of volume 110 km3, and a surround- ing epiclastic ring plain of similar size. Four facies associations can be recognised at Ruapehu,-two each on the cone and on the ring plain. Neither cone nor ring plain provides a complete record of the history of the volcano. The cone is dominated by the products of extrusive eruption, as primary pyroclastic deposits are seldom preserved, being rapidly removed by erosion from the steep water- saturated and/or snow-covered flanks of the cone. The ring plain consists of the products of mostly explosive activity forming an alter- nation of primary pyroclastic fall deposits and material transported from the cone by lahars, floods and debris avalanches and then rapidly reworked in sediment-choked hyperconcentrated Streams.

Jan 1, 1987

Conceptually coal reserve assessment is simple but in practice it presents many problems. These arise from the origin and geological history of coal seams and from the diverse nature of the coal itself. The suitability of a coal for a particular use depends upon its type and so sheer quantity of reserves does not guarantee the adequacy of coal reserves for all requirements. Codes have been formulated to counteract the effects of subjectivity in reserve assessment. The code for calculating and reporting coal reserves published by the Standing Committee on Coalfield Geology of New South Wales has wide acceptance but the Committee itself recognises that it has shortcomings. Currently the Committee is engaged on the commendable but difficult endeavour of formulating a code that will meet the needs of scientific rigour and professional and commercial ethics and that will allow the specification of an assessment method without constraining it. It is generally agreed in the coal industry that the assessment of coal reserves can not conveniently be incorporated into codes formulated for other resources.

Jan 1, 1979

SOUTHERN CALIFORNIA LOCAL SECTION Executive Committee THEODORE B. COMSTOCK, Chairman SEELEY W. MUDD, Vice-Chairman FREDERICK J. H. MERRILL, Secretary-Treasurer, 631 Higgins Bldg., Los Angeles, Cal. A. B. CARPENTER C. COLCOCK JONES A meeting of the Southern California Local Section, in honor of the presence of Secretary Bradley Stoughton, was held at luncheon in a private dining room of the Sierra Madre Club on Friday, May 21, 1915, 27 members and guests being present. In the absence, through illness, of the Chairman, Dr. Comstock, the vice-Chairman, Seeley W. Mudd, presided. After the luncheon, Secretary Stoughton made a short address on the activities of the Institute. George S. Rice, of the U. S. Bureau of Mines, who was present, then spoke on the activities of his Bureau. Local Secretary F. J. H. Merrill gave a description of the activities of the Southern California Section and its progress, and reported the latter as substantial and its condition as very good. After some informal remarks by other members present the meeting adjourned. F. J. H. MERRILL, Secretary.

Jan 7, 1915

Canadian owned Lake are carriers will be used again this year in an attempt to make up the deficit caused by the two months steel-strike. Buffalo mills need between 5 million and 6 million tons of ore before the Lakes navigation season ends. Mutual Security Program aid will help reactivate Austria's largest iron ore mine. The Erzberg development is one of the moat important in Europe. MSA announced approval of $500,000 in supplemental financing of equipment. Following the war, the Russians stripped the Erzberg and Radmar deposits of equipment. The he Carborundum Corp. is going to build a $2.44 million plant at Akron, NO.. TOP near Niagara Falls for production of rare metals used by the Atomic Energy Commission. A subsidiary, the Carborundum Metals Co., Inc.,, will produce zirconium, hafnium sponge metals. The pyrochlore rich Sukulu Hills in Eastern Uganda will be mined under a pool arrangement including Tinto Mines, Monsanto Chemicals and Frobisher Mines. The combine will be known as the Uganda Development Corp., Pyrochlore is used in the manufacture of heat-resisting. alloys for Jet engines.

Jan 1, 1952

HENRY M. Howe, Bedford Hills, N. Y (written discussion*).¬Mr. Foley's explanation of this interesting occurrence is perfectly reasonable. Possibly a word explaining the phenomenon more in detail may not be amiss. In the act of solidification each drop as it starts to solidify splits up into a half drop poorer in carbon and another half drop richer in carbon than the drop itself. The half drop poorer in carbon solidifies and attaches itself to-the already solid walls, whereas the half drop richer in carbon remains molten for the excellent reason that it is richer and hence is more fusible than the original drop, and hence in turn is wholly fusible at the existing temperature. Under usual conditions, as when the steel solidifies in a mold of any form, the successive molten half drops thus enriched in carbon remain present and by their enrichment progressively raise the carbon con-tent of the remaining molten mass, out of which successive half drops are continuously solidifying and attaching themselves to the already solid walls. Because the molten mass thus. becomes progressively richer

Jan 10, 1919

By Anthony J. Peach

With the new generation of so called "Super TBM", we would all expect to witness the implied super-performance. In some instances this is occurring, but one must ask why is it not occurring in the majority of applications? For hard rock TBM related projects, we are observing a decrease in the volume of projects in the previously traditional areas such as North America and Western Europe and an increase in Asia (Hong Kong, Indonesia, China, Korea etc). As a consequence less experienced contractors are acquiring the latest ultra high power equipment, without the knowledge necessary to achieve optimum performance. The interdependence of TBM and muck removal systems has been assessed with emphasis on the emergence of the continuously extending conveyor technology, as a means of achieving dramatic productivity increases. The Australian system assessed here at the time of drafting this paper holds the world record tunnel excavation production of 2,166 metres. A little considered aspect of the adoption of conveyors is the associated improvement in safety.

Jan 1, 1995

By R. Venugopal, T. C. Rao, J. P. Barnwal, K. Udaya Bhaskar

The performance characteristics of a multigravity separator for the recovery of heavy minerals of lead, zinc, copper and silver from a lead rougher-flotation concentrate were studied. Factorially designed experiments were carried out on three operating variables, i.e., the amount of wash water, the drum inclination and the drum rpm, of a multigravity separator. The experiments were carried out at two levels of each variable. With the experimental data, regression equations were developed for different metal grades and recoveries. The analysis revealed that drum speed has a major influence in determining the heavy-metal grade and recovery. Drum inclination is the next most important variable, with the amount of wash water being the least important. A concentrate containing 40% lead, 9.4% zinc, 1.5% copper and 1,400ppm silver was obtained with recoveries of 74.8%, 65.9%, 64.1% and 53.2%, respectively. Finally, the predicted values of grades and recoveries at intermediate levels are compared to actual experimental data to test the validity of the equations developed.

Jan 1, 2000

By John McDonald

THIS report is a continuation of an earlier one with a similar title,1 to which the reader is referred for such details of procedure as do not appear here. A brief summary will be given of the objects and methods of the research at this time. It was pointed out in the previous paper that properties of magnesium alloys, as re-ported by different workers, often differ. This was thought to be due to differences in the preparation of the specimens tested. The ideal way to compare alloys would be to prepare each of them in so many ways that reasonable assurance would exist that the best properties of each alloy had been developed. The alloys would then be com-pared on the basis of these properties. The treatment actually given the alloys of these studies is necessarily a compromise with completeness. Nevertheless, enough treatments have been given so that a con-siderable degree of assurance exists that the properties obtained are representative of the alloy as such, and not merely of the manner in which it was worked and heat-treated.

Jan 1, 1940

By C. L. Jiang, B. K. Parekh, X. Shao

Among the impurities present in phosphate ore, dolomite is the most difficult to remove. This is because dolomite and phosphate have similar chemical compositions and because the dissolved species of dolomite is adsorbed on the surface of the phosphate mineral. A new amphoteric surfactant was found to be a suitable collector for the separation of dolomite and phosphate. Flotation results showed that the new amphoteric collector had a high flotation selectivity for dolomite over a wide pH range. studies on the flotation of francolite and dolomite in each other's supernatant demonstrated that the dissolved ions had little effect on the selectivity of the new collector. It was found, however, that the dissolved ions were detrimental to the flotation separation using sodium oleate as collector. From a mixture offrancolite and dolomite containing 26.2% P2O5, a phosphate concentrate containing 35.2% P205 with a 90% recovery was obtained using 290 g/t of the amphoteric collector. The rejection of MgO was 81.41 %.

Jan 1, 1999

By M. C. Mulligan

Counter current decantation (CCD) thickener circuits are used to recover soluble metal as pregnant liquor solution from ore leach residue. The basis of CCD operation is to concentrate suspended solids thereby minimizing liquor content in underflow slurry that flow in one direction. Then the underflow slurry liquor is diluted with wash liquor that flows in the opposite direction and the suspended solids are concentrated again and again. The amount of liquor in the thickener underflow contributes to determining the number of CCD stages required to recover the desired amount of soluble metal. Furthermore, similar results could be achieved at a lower wash quantity, reducing the size of downstream equipment. High density thickeners (HDT) are designed to use gravity and compression, and minimize the amount of liquor in the underflow thus minimizing the number of CCD stages. This paper reviews the process used to select HDTs rather than high rate thickeners (HRT) for the Ruashi II copper-cobalt hydrometallurgical process in the Democratic Republic of Congo (DRC), using laboratory HDT simulations, to CCD simulations and thickener design details.

Jan 1, 2009

By W. R. Ingalls

SOME months ago, I had occasion to make an investigation that introduced the subject of blue powder that is produced as a byproduct in zinc dis-tillation. Although every zinc smelter is aware that more or less blue powder production is inevitable and there is a common practice as regards the treatment of it, the specific and quantitative data respecting the subject were more imperfect than would have been expected. I had reports from eight important works. Some of the data were especially determined for my investigation. Speaking generally, there is a good deal of uniformity in the figures, all of which show that the blue powder product, bears a large proportion to the ore originally charged into the retorts; that a large proportion of the retort capacity is devoted to the redistillation of blue powder; and that of the spelter product of a furnace about 30 per cent. is derived from blue powder, i.e., it is zinc that has been distilled twice. The figures from the works are given in the following table:

Jan 4, 1922

By Leonard Waldo

(New York Meeting, February, 1911.) THE recent and rapid development of the physics of engineering materials at temperatures as low as that of liquid air and as high is that of the electric are, has drawn renewed attention to the absence of tables, properly printed and spaced, for the convenient and accurate translation of temperature from centigrade to Fahrenheit scales and vice versa. It is to be noted that the Fahrenheit scale is the almost universal usage in foundries and shops in the United States, though the laboratories of the same works employ the centigrade notation. The growing use of the electric furnace in Germany and France calls for much American citation all in centigrade high temperatures, and while the arithmetical calculation is simple, it becomes burdensome when often repeated. I have been surprised at the numerous reprints of Table I. from centigrade to Fahrenheit degrees, first privately printed for personal use, which have been made by works, blue-prints, test-books, and technical journals, and I hope that Table II., from Fahrenheit to centigrade degrees, will be equally useful.

Jan 4, 1913