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By R. Woods

INTRODUCTION Gaudin (1), considered that "the mechanism of mineral collection is the central problem of flotation theory". From their work on adsorption phenomena in flotation for more than fifty years (2), Gaudin and his co-workers have made major contributions to the elucidation of this mechanism, a fact acknowledged by their contemporaries in the field (e.g. (3)). Their investigations in a number of areas, e. g. demonstrating that submonolayer quantities of adsorbed collector species can induce flotation, or identifying the influence of substances which can activate or depress (1), have helped to provide the basis for and the development of a theory to account for the interaction between mineral and collector. It was established in the late fifties (4) that the presence of oxygen is a prerequisite for the flotation of metal sulfides with thiol collectors. This fact rendered inadequate the concept of simple ion adsorption being responsible for rendering these minerals hydrophobic. The requirement for oxygen has been explained (1) in terms of this species being a component in chemical reactions between the sulfide surface and the collector. Gaudin has been instrumental in identifying the products of chemical reactions at sulfide minerals (1, 5), a line of work which has been continued particularly by Finkelstein and co-workers in South Africa (6). In presenting a detailed mechanism of the mineral-collector- oxygen interaction, it has often been considered that the mineral surface [must] first be oxidized to a metal oxy-sulfur species which

Jan 1, 1976

By Alan Morris

IMPINGEMENT attack, as one of the types of corrosion suffered by condenser tubes, has been given a prominent place in corrosion literature of recent years. It has been reproduced and studied in carefully controlled laboratory tests. Much has been learned of its mechanism, and of the effects of variables such as temperature, amount of air, size of bubble and water velocity. Incidentally the technical public has been given comparisons between the behavior of some few metals under various conditions of impingement attack. The tests recorded here were undertaken in an effort to find at least some sort of qualitative answer to questions which arose occasionally as to the relative resistance of various alloys to impingement attack, and which could not be answered by reference to the literature. The final decision to start work on the problem was influenced in large measure by the nature of the water available in this particular place. The mill of the Bridgeport Brass Co. is located on the Pequonnock River at Bridgeport, Conn., within two miles of its mouth. The water is much like many other estuarine sources which are used in condensers, and which cause particularly severe corrosion. It seemed a most suitable water to use in such tests. As the work progressed an important seasonal variation was noted. The purpose of this note is to record this seasonal effect. The results of individual tests are given only incidentally.

Jan 1, 1931

By R. Woods

INTRODUCTION Gaudin (1), considered that "the mechanism of mineral collection is the central problem of flotation theory". From their work on adsorption phenomena in flotation for more than fifty years (2), Gaudin and his co-workers have made major contributions to the elucidation of this mechanism, a fact acknowledged by their contemporaries in the field (e.g. (3)). Their investigations in a number of areas, e.g. demonstrating that submonolayer quantities of adsorbed collector species can induce flotation, or identifying the influence of substances which can activate or depress (1), have helped to provide the basis for and the development of a theory to account for the interaction between mineral and collector. It was established in the late fifties (4) that the presence of oxygen is a prerequisite for the flotation of metal sulfides with thiol collectors. This fact rendered inadequate the concept of simple ion adsorption being responsible for rendering these minerals hydrophobic. The requirement for oxygen has been explained (1) in terms of this species being a component in chemical reactions between the sulfide surface and the collector. Gaudin has been instrumental in identifying the products of chemical reactions at sulfide minerals (1.5), a line of work which has been continued particularly by Finkelstein and co-workers in South Africa (6). In presenting a detailed mechanism of the mineral-collector- oxygen interaction, it has often been considered that the mineral surface - must first be oxidized to a metal oxy-sulfur species which

Jan 1, 1976

By Robert Corcoran, George Wiener

A study of the orientations and microstructure of 3 pct Si Fe alloys after deformation and recrystallization has been made. The components found after deformation agreed with recently published work on single crystals, being primarily (001) [110], (111) [110], and (111) {112}. A pronounced effect of temperature of recrystalliza-tion was found on microstructure and orientation. Low temperature recrystallization was interpreted in terms of low angle boundaries which resulted in the retention of a large amount of the deformation texture. High temperature recrystallization was interpreted in terms of high angle boundaries which gave rise to new components. No simple angular relation between the deformation and high temperature recrystalliza-tion textures could be detected. DEFORMATION and recrystallization behavior of 3 pct Si-Fe has been the subject of scientific investigation for many years. The fact that it is a single phase body-centered-cubic alloy from room temperature to the melting point permits study over a wide range of temperature without the complications of phase transformations. There is an important commercial interest in this material as well, since it is widely used in the electrical industry. In the present work the deformation and recrystallization behavior of poly crystal line silicon iron has been studied with the primary purpose of evaluating the effect of a second phase impurity on both processes as well as the effect of temperature on the recrystallization characteristics. With regard to deformation, the emphasis has been placed on a study of the crys-

Jan 1, 1957

By Alan T. Gorton, T. L. Joseph, Gust Bitsianes

High-temperature X-ray diffraction techniques were used to determine thermal expansion coefficients of iron and its oxides. Lattice parameters of a and iron, wiistite, magnetite, hematite, and goethite were determined and plotted as a function of temperature. From these results, the true and mean linear thermal expansion coefficients were calculated. In the case of noncubic crystals, the expansion coefficients were determined along each of the crystallographic axes. The effect of the magnetic transformation on lattice parameter was measured for a iron and magnetite at their respective curie temperatures. COEFFICIENTS of expansion for iron and its oxides were determined from the temperature dependence of their lattice parameters. From these data, the true linear coefficients were derived by means of the formula: at =[(l/ao )(dao/dt)] [1] where at is the true linear coefficient of expansion, a, is the lattice parameter in angstrom units, and all variables are referred to the temperature, t, in OC. Thus the true expansion coefficient represents the instantaneous change in lattice parameter on a unit basis and at a particular temperature. A second expansion coefficient is also often used. It is termed the mean linear coefficient and is defined in the following way: am = [ao(t) - ao(O)]/ao(0) l [21 This coefficient represents the average change in lattice parameter on a unit basis but at a specified parameter length, ao at O°C, and over a specified temperature range,1 to 0°C. Generally the true co-

Jan 1, 1965

By Stanko Nikolic

Ferrous calcium silicate slags are potentially important for future practice in copper converting operations and processes and can be described by the ?Cu2O?-FeO-Fe2O3-CaO-SiO2 system. Despite its industrial importance the phase equilibria in this system have not been fully investigated. Characterization of this slag system is necessary to improve the design and optimization parameters of new processes, including fluxing and operating temperatures. Experimental methods have been developed to investigate the phase equilibria of these slags at copper saturation and without copper. This technique involved equilibration of samples at a fixed oxygen partial pressure, rapid quenching, and analysis of the compositions of phases using electron probe x-ray microanalysis (EPMA). Liquidus and solidus data are reported for the primary phase fields of spinel, wollastonite and tridymite at 1250oC and an oxygen partial pressure of 10-6atm. The resulting data has been used to construct liquidus isotherms in the ?FeO?-CaO-SiO2 system both in equilibrium with and without molten copper. The experimental results were compared with the predictions of a thermodynamic computer package utilizing a self consistent thermodynamic database. The predictions of the model were in good agreement with the experimental isotherms when projected onto the FeO-CaO-SiO2 section, however the copper concentrations in the liquid phase at copper saturation were lower than predicted using the current database of the model.

Jan 1, 2006

A new porphyry copper gold district has been discovered at Goonumbla near Parkes in central New South Wales. Endeavour 26 North is the largest deposit known to date with a possible resource of 166.4 million tonnes at 0.74% copper, 0.12g/tonne gold and 1.7g/tonne silver, using a cut-off grade 0.3% copper. Mineralisation is primarily bornite in the higher grade zones and chalcopyrite in the peripheral lower grade zones. Most of the copper, gold mineralisation is associated with potassic alteration. Two mineralised quartz monzonite porphyry intrusive stages have been identified and these are related at depth to a large monz- onite stock which may have been the source of some of the mineralisation. On the basis of detailed paragenesis studies, the potassic zone can be divided into three symmetric subzones. The low grade inner potassium feldspar subzone is confined to the later intrusive porphyry. The outer potassium feldspar subzone is the most highly mineralised alteration halo due to the focussed superimposition of two hydrothermal cycles which have overprinted intrusive and volcanic rocks. The fringing biotite potassium feldspar subzone reveals alteration minerals which are developed early in the paragenesis. Fracture controlled quartz sericite alteration with low sulphide content, fringes and, in part overprints the potassic zone. The restricted pipe-like nature of the alteration zones and related mineralisation suggests that Endeavour 26 North is repres- entative of a multiphase focussed porphyry copper gold system.

Jan 1, 1986

By J. L. Bray

IT is well known that iron markedly improves the physical properties and casting characteristics of aluminum bronzes. The use of 1 to 4 per cent iron as the principal modifying addition has become common practice in many foundries melting aluminum bronzes. Although the beneficial effects of iron are unquestioned, there is some uncertainty regarding the structural changes caused by it in the basic copper-alumi-num system. It is agreed that a new constituent appears in abundance when the iron content reaches 2 to 4 per cent. This constituent, which frequently occurs in shapes resembling clover leaves, is sometimes assumed to be an aluminum-iron intermetallic compound. If this were correct we might expect a change in the structural relationships of the matrix in the direction of decreased aluminum content. On the other hand, it has been reported that iron has a negligible effect in altering the fundamental relationships of copper-aluminum alloys1. Others2,3 have reported an additive coefficient. Apparently it will be necessary to know the equilibrium relationships between the phases of the copper-aluminum-iron alloy system to establish any such theory as fact. When this has been done it may very well be that a further revision in the structural relationships may be necessary to describe the changes to be expected in commercial cast alloys. It was with this latter problem before them that the authors attempted to

Jan 1, 1936

By H. H. Fields, Stephen Krickovic, M. G. Zabetakis, Albert Sainato

The Bureau of Mines is in the process of degasifying a virgin area in northern West Virginia from the base of an 839-foot -deep vertical borehole. An in situ gas pressure hole 199 feet long, and seven degasification holes ranging in depth from 500 to 850 feet (average 618 feet) were drilled in an 8-foot-thick virgin Pittsburgh coalbed from the enlarged (14-foot-diameter) bottom of this borehole. The in situ pressure at the back end of the hole and the range of gas and water flows from degasification holes as they were completed and closed off were 203 psi, 79,000 to 257,000 cfd (average 160,000 cfd), and 5 to 8 gpm per hole (average 6.8 gpm), respectively. Twenty-four hours after the seven holes were connected through individual water traps to a common collector for natural venting of the gas through pipes to the atmosphere, the total gas and water flows and the in situ pressure dropped, respectively, to 971,000 cfd, 1.3 gpm, and 18 psi. Eighty days later the corresponding values dropped to 529,000 cfd, 0.50 gpm, and 13 psi. After 180 days of degasification, 91 million cubic feet of gas had been removed from the affected virgin area. This represents 60 to 70 percent of the gas calculated to be contained in the area of coal affected by the holes.

Jan 1, 1973

By George S. Kalamaras

Coal strata strength is included as a vague term in most of the pillar design formulas, either as a questionable fraction of the intact coal strength or a size-dependent relationship for scaling down a laboratory value to the in situ strength. In order to introduce a coal mass strength criterion which would be compatible with current design trends, the Rock Mass Rating (RMR) system was revised to incorporate factors governing coal seam behavior under load. A number of adjustment factors have been proposed but, the most significant change, is the introduction of a parameter representing the heterogeneity of the seam. When developing a rock mass strength criterion, it is necessary to find the constants of appropriate intact rock strength criteria and to establish a correlation to scale down these constants as a function of the RMR. For four intact rock strength criteria, the constants for coal were found using the Nelder-Mead method. To correlate the constants of the strength criteria with the coal seam quality values (RMR), a procedure was developed based on finite element modeling of in situ large scale tests for which the RMR was known. A new coal strata strength criterion is proposed, in a principal stress formulation, for modeling coal pillar behavior when the stress field in a pillar is known. A linear relationship is also given, to be used when empirical pillar strength formulas are used to design pillars. The proposed criteria have been evaluated in a case study.

Jan 1, 1993

By Charles Fettke

IN THE present day manufacture of glass nearly pure quartz sands are used almost exclusively as the source of the silica, which is the major constituent of all common varieties of glass. Ordinary soda-lime, such as bottle, common tableware, plate, and window glasses, contain from 65 to 75 per cent. of silica. OCCURRENCE Glass sands occur in nature either in the form of loose, unconsolidated sediments or in deposits in which the individual grains have been more or less thoroughly bound together by some cementing agent so as to form sandstones. While deposits of sand and sandstones occur both widely and abundantly distributed, deposits that are sufficiently free from other constituents than quartz grains, so that they can be employed in the manufacture of the better grades of glass, are, comparatively speaking, of rare occurrence. The major portion of the glass sand produced in the United States comes from sandstones. In order to be suitable for glass sand, they should be rather friable. The rock should break down readily along the cementing material between the grains and should not break across the grains rather than along the bond. Some of the sandstones used are so friable that only light shots of slow-burning dynamite are necessary to disintegrate them sufficiently for hydraulic mining, while others have to be passed through crushers in order to disintegrate the rock into its individual grains.

Jan 2, 1926

By W. L. Dennen, V. H. Wilson

THIS paper is a description of the opera¬tion and results of a Humphreys Spiral Silt Cleaning Plant at the Powderly Colliery of The Hudson Coal Co. during the first nine months of operation and follows a pre¬liminary description given at the Anthracite Institute in May, 1947, in a paper titled "Preparation of Anthracite Sift for Boiler Fuel in a Humphreys Spiral Test Plant" by H. H. Otto, V. H. Wilson and W. L. Dennen. This plant is considered a full size operating test plant and, like all new plants, numerous minor changes in the methods of operation have been made from time to time to secure the results desired. Views of the silt preparation plant and of the screening house are given in Fig 1 and 2. This plant consists of 48 spirals in 8 batteries of 6 spirals each, 36 of which were to be operated as primary spirals and the remaining 12 as secondary spirals. A brief description of the plant and its operation follows. The only material cleaned at the plant during 1947 was that carried in the underflow from the Thickener which handles the Breaker waste water. This underflow, amounting to approximately 2000 gpm of water and containing 12.6 pct of solids, is pumped .to vibrating screens where the plus 316-in. material is removed. (Fig 3). This oversize material drops into a pocket from which it is trucked to the run-of-mine

Jan 1, 1948

The objective of extensive underground experimentation on three longwall coal faces was to improve the stability of mechanised longwall faces through investigation of the relations between support resistance and convergence and resultant deformation of roof and face strata. In particular the influence of high setting and yield pressures on several strata and support parameters was studied in great depth. Increased setting pressures resulting in an increase in setting load densities from 0.15 MN/m2 to O.45 MN/m2 were shown to reduce convergence, face spalling roof flaking, lateral movement of roof and floor, extrusion of the face wall and progressive failure of the coal wall ahead of the face. This was shown to result mainly from the change in roof strata deformation from a wedge shaped compression zone with tension at the face edge to an even beam shaped compression zone over the face area. Debris thickness above the support canopy and below the base was observed to be the one of the most variable parameters which influenced the support characteristics particularly the rate of load acceptance by supports and the roof to floor convergence. A setting load density of 0.4 MN/m2 to 0.5 MN/m2 was found to be optimum under soft to moderately strong sandstone roofs. The authors demonstrated that use of guaranteed set valves with powered supports contribute to good strata control, reduce face down-time and increase face productivity.

Jan 1, 1984

By George S. Martin, Michael D. Winship

"Placer Dome Inc. is the operator of the Musselwhite project located 100km north of Pickle Lake, Ontario. J.S. Redpath Limited was contracted to conduct an underground exploration program using shaft access.During the winter of1988, the shaft collar was established in 16 metres of water bearing sand and till overburden. This paper will illustrates the engineering techniques used to overcome the obstacles to installing a shaft collar in deep overburden. Specialized dewatering and piling procedures were employed.INTRODUCTIONHarold and Allan Musselwhite discovered gold in the Opapimiskan Lake area, north of Pickle Lake, in 1962. The prospectors were grubstaked by ten companies in 1973.A diamond drill program was initiated shortly thereafter.In 1983an underground ramp exploration program was carried out on the West Anticline portion of the property. The program was unsuccessful in establishing an ore reserve so surface exploration continued. In 1986the ""T"" zone was discovered. Further surface drilling was done and an over-all drill-indicated reserve of 6 million tonnes at 7 grams per tonne was outlined. The gold mineralization occurs in several vertical tabular deposits within the iron formation. In late 1987the joint venture partnership, now consisting of Placer Dome Inc., Inco Gold Co., Corona Corporation and Esso Minerals Canada, contracted J.S. Redpath Limited to conduct an underground exploration program on the ""T"" Zone.The scope of work for the project was to: 1. establish a 45 km winter road in 1988 and 1989;"

Jan 1, 1989

ATTENTION has recently been directed to the subject of dust production and methods of allaying same in the Broken Hill mines, so that the time would seem opportune for the local branch of the Institute to discuss certain features of an important phase of the health question in connection with underground work. Tests conducted in the Broken Hill South mine and at other mines at Broken Hill have shown that the ordinary operatioils of mining, such as boring, blasting, and shovelling, may be accompanied by the production of considerable dust unless water is judiciously used.In South Africa·dust particles under 5 microns size are regarded as dangerous, becailse they are so small as to be invisible to the naked eye, and wm esc'ape the protections set up by nature in the nose and throat, and thus may be inhaled in large quantity. A micron is 1 25000th part of an inch. This paper contains an account of the work done on the Broken Hill South mine chiefly, though some tests were done on other local mines.An acknowledgment is due to Mr. T. A. Reid, of the Broken Hill South mine, who conducted some of the tests herein mentioned, and under whose supervision most dust counts were made. Numerous dust samples have been taken by means of thekonimeter, an instrument designed by Dr. Kotze, the Government mining engineer of the Union of South Africa, and fully described...

Jan 1, 1921

By Michael W. Oakland

Weidlinger Associates was retained to evaluate the foundations supporting ten oil storage tanks at a tank farm on the east coast. The tanks were constructed over the site of a landfill which was underlain by deep organic deposits. The tanks were typically 48 ft. in height and ranged in diameter from 60 to 150 ft. The tanks were supported on both wood and steel pipe piles. After more than 35 years of service, an inspection found that up to 25 percent of the piles had separated from the mat foundation. The operations at the facility were temporarily stopped pending further investigation. Weidlinger developed comprehensive finite element models of the foundations for each tank and used random generators to conduct Monte Carlo simulations the range of scenarios of detached support conditions since it was not possible to survey all the piles below the tanks. To confirm the modeled performance and verify stability, each tank was also load tested using water with electronic instrumentation installed by Geo-Instruments. The instrumentation provided real time, web based monitoring during testing in areas which would otherwise be inaccessible during loading. Through inspection, complex modeling and sophisticated load testing, Weidlinger and Geo-Instruments were able to show that all but one of the tanks could safely be put back into service. This paper details the analysis, Monte Carlo simulations and instrumentation and load testing performed for this unique project.

Jan 1, 2009

By Dennis V. Woods, J. Duncan Crone

"In order to determine its capabilities and to aid in the interpretation of fie ld results, a scale model study and field tests were carried out on the Crone borehole pulse electromagnetic (PEM) system. The model results indicate that if a borehole passes in the vicinity of a tabular conductive body, the system will not only detect the presence of the body, but will also return information as to its conductivity-thickness product, size, altitude and position.The effect of variation of these electromagnetic and geometric factors on the shape of the response curve from a borehole PEM survey is displayed by a number of suites of scale-model response curves. These model curves can be used directly as type curves in the interpretation of field results. Field tests of a prototype PEM system provide a check on the scale-model results and also summarize the procedure of interpreting field data using the model type curves.The borehole pulse EM system can be effectively used as a follow-up geophysical instrument for locating and delineating known conductive bodies. It can also be profitably utilized as a primary geophysical exploration tool in areas of deep mineralization below the depth limit of conventional airborne and ground geophysical systems. The probed area of a diamond drill hole in these cases is increased from a 1- inch drill core to a zone extending hundreds of feet from the hole."

Jan 1, 1980

By J. W. Bolton

THIS paper discusses some fundamental metallurgical principles involved in production of sound cast bronze. In a previous paper the writers advanced the theory that "oxidation" in bronze castings is due to incipient shrinkage, and showed the effect of reducing melting atmospheres. In the present paper the effects of certain impurities and of actual oxidizing conditions are shown. The appendix deals with the appearance of various inclusions. For many years the prevailing opinion has been that unsoundness, dark colored fractures and other phenomena accompanying porosity and weakness in bronzes are due to oxidation. The actual troubles are caused by fissures of intercrystalline type, which are often mistaken for intercrystalline films. These weaken the metal and make it porous. Grave doubt regarding the accuracy of the oxidation theory appears when several research papers presented within the last 10 years are reviewed critically. In 1919, Comstock conducted metallographic researches, attempting to identify "oxides" in synthetically prepared metals. He found that oxides of tin, aluminum, zinc, etc. are different from the intercrystalline films (or cavities) to which porosity is due. Apparently he believed that these "oxide films" may be caused by volatile oxides of zinc or of phosphorus or by dissolved gases thrown out of solution during solidi-fication of the metal. In 1923, Woyski and Boeck3 definitely questioned the accuracy of the oxidation theory and indicated the danger from reducing atmospheres. They say that "oxidation, gassing and shrinkage may produce effects very similar."

Jan 1, 1930

Dr R. E. Robinson, Pr. Eng., obtained a B.sc. (Chem. Eng.) cum laude from the University of the Witwatersrand in 1950 and a Ph.D. (Eng.) from the same University in 1953, where he was awarded the Haikes Memorial Medal for Industrial Chemistry. Professor G. G. Garrett was appointed Professor of Physical and :Fabrication Metallurgy in the Department of Metallurgy at the University of the Witwatersrand in June 1980, and in January 1984 he became Head of the Department. Mr P. A. van Wielligh, Pr. Eng., climbed the mining ladder in the hard way, starting as a Mine Surveyor in 1936 and working his way up as Chief Surveyor, Underground Manager, Mine Manager, and Consulting Engineer, to Executive Director, including the intermediate steps. Mr H. E. James, Pr. Eng., is a graduate in Chemical Engineering from the University of the Witwatersrand. Both his B.sc. degree (1961) and his M.sc. degree (1964) were obtained on bursaries, the former from Gold Fields of South Africa and the latter from the Atomic Energy Board. Mr G. Pienaar, Pr. Eng., obtained a B.Eng. (Met) in 1967 and an M.Eng. in 1973, both from the University of Pretoria. Dr A. K. Haines, Pr. Eng., obtained all his degrees from the University of Natal, finishing with a. Ph.D. in 1971. Mr B. C. Alberts, Pr. Eng., obtained his academic training at the University of Pretoria, where he was awarded B.sc. degrees in both agricultural engineering (1963) and mining engineering (1965). Mr H. C. van Zyl, Pr. Eng., holds B.sc. degrees in mining engineering (1968) and civil engineering (1972), both from the University of Pretoria.

Jan 1, 1984

By Arturo Ressi di Cervia

Construction of the drilled shafts for the Brightman Street Bridge Replacement Project were not only challenging due to working over the water but were also challenged by changed soil conditions, concurrent work being performed by an adjacent contractor on the same project, environmental restrictions and severe winter conditions. A total of 36 x 8 feet diameter drilled shafts with 7.5 feet rock sockets were installed for the East and West bascule piers. This project also included Osterberg Cell load testing on two production drilled shafts at each the East and West bascule piers. The results from the load test program were used to fine tune the design of the drilled shaft rock sockets. From a constructability standpoint the reverse circulation drilling method with a pile top drill rig proved to be an excellent choice for drilling the overburden and rock sockets of the large diameter deep drilled shafts.

Jan 1, 2003