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Although forty-seven years have passed since the by-product coke oven made its successful commercial appearance, it is only during the past fifteen or twenty years that this system of coal carbonisation has advanced rapidly to its present position ofabsolute supremacy.Early designs of by-product ovens proved more or less faulty, and the coke produced was so inferior to coke made in beehive ovens that there was a natural hesitancy on the part of coke producers to invest large sums of money in installations of by-productovens of doubtful utility-more especially in view of the fact that beehive ovens could be erected cheaply and operated by non technical labour for the production of high-grade coke under the most variable conditions of trade.Surely and steadily designers brought forward by-product ovens of improved type, coupled with more efficient apparatus for the recovery of by-products, but still the industry lagged, due almost entirely to the insistence on the part of coke users that the qualityof ordinary beehive coke was vastly superior for metallurgical operations to the best coke produced from by-product ovens. So deep rooted was this prejudice that only the passage of time could eradicate it. That it has successfully done so is strikingly illustratedin the following statistics:

Jan 1, 1928

By Michael H. Kuryla, Galen H. Clevenger

Some years after Nobel made his epoch-making contribution to the knowledge of high explosives, Sprengell described a new class of detonating explosives consisting of mixtures, made immediately before use, of an oxidizing agent and a combustible substance.2 The novel feature of the Sprengel explosives is that the constituents alone are non-explosive during manufacture, storage and transport. Despite this advantage, and although some of these have been used in important work, they are now little used, possibly on account of the greater inconvenience to the user, compared with explosives supplied by the manufacturer in final form. Liquid-oxygen explosives are a type of Sprengel explosive in that the oxidizing agent (liquid oxygen) and the combustible substance or substances (solid carbonaceous matter alone or in combination with liquid hydrocarbons or even metallic powders and, at times inert absorbents) are brought together immediately before use. The components separately are non-explosive. The possibility of using liquid oxygen as one of the components of an explosive was perhaps first suggested by Sprengel, who stated that the beau ideal of a detonating explosive was a mixture of eight parts of liquid oxygen with one part of liquid hydrogen. Although the liquefaction of air3 had been accomplished in the laboratory as early

Jan 1, 1923

By John H. Schloen

"The object of this paper is to review electrolytic copper refining as it was in 1954(1), as it is now in 1984, and to comment on the many improvements which have been made in the last thirty years.In 1954, and even in 1984, the ASTM specification B 115 for cathode copper was 99.90% minimum copper plus silver content and 100% minimum electrical conductivity, IACS standard. However, to meet competition and to satisfy the requirements of the fabricators and the electrical industry, the electrolytic refinery must supply a product of 99.95% to 99.96% minimum copper content, and 101fJlo minimum electrical conductivity.The range of cathode impurities reported by 20 major copper refineries in 1954 are given in Table I.The much more rigid British Specification, DD 78, for high-purity cathode copper, specifies individual elements, as well as groups of elements, as shown in Table 2.The Svenska test has been replaced by a similar procedure which uses 2.r mm diameter wire. The ISO test is the one listed in the DD 78 specification. In Table 3, corresponding values for the Svenska and ISO test s are given for various wire bar coppers."

Jan 1, 1986

By Michael H. Kuryla, Galen H. Clevenger

Some years after Nobel made his epoch-making contribution to the knowledge of high explosives, Sprengell described a new class of detonating explosives consisting of mixtures, made immediately before use, of an oxidizing agent and a combustible substance.2 The novel feature of the Sprengel explosives is that the constituents alone are non-explosive during manufacture, storage and transport. Despite this advantage, and although some of these have been used in important work, they are now little used, possibly on account of the greater inconvenience to the user, compared with explosives supplied by the manufacturer in final form. Liquid-oxygen explosives are a type of Sprengel explosive in that the oxidizing agent (liquid oxygen) and the combustible substance or substances (solid carbonaceous matter alone or in combination with liquid hydrocarbons or even metallic powders and, at times inert absorbents) are brought together immediately before use. The components separately are non-explosive. The possibility of using liquid oxygen as one of the components of an explosive was perhaps first suggested by Sprengel, who stated that the beau ideal of a detonating explosive was a mixture of eight parts of liquid oxygen with one part of liquid hydrogen. Although the liquefaction of air3 had been accomplished in the laboratory as early

Jan 1, 1923

By Robert B. Parsons

"On February 15, 1984 Finance Minister Lalonde presented to Parliament a budget heavily flavoured with the current consultative mood of the Government. Notably absent from the budget was the typically long list of tax changes of immediate effect. Instead, the bulk of the budget papers consisted of a wide variety of white papers on significant topics that would have a far reaching impact on the future of all Canadians.This month. Tax Notes examines the highlights of Mr. Lalonde's budget.IntroductionThe mining industry need not feel slighted in Finance Minister Lalonde's budget of February 15, 1984: the budget offered very little that would have an immediate impact of significance on any sector of the economy. Apart from some welcome announcements for the oil and gas industry to postpone the implementation of certain negative tax changes, the budget was surprisingly scant in terms of definitive tax proposals.While massive revisions in the rules relating to pensions, small businesses, commodity taxation and profit-sharing were brought forward, many of these proposals are set out in White Papers or other documents to be implemented into legislation only after further consultation. Canadians will accordingly have to wait for such promised benefits as increased RRSP and other pension contribution limits."

Jan 1, 1984

By A. Yamik

This research study includes studies carried out on the recovery of unburned carbon in the ashes of Tuncbilek Thermal Power Plant. Bottom ashes have been identified by X-ray diffraction and X-ray fluorescence. These samples are potentially of class F type and have significant amounts of unburned coal. According to the ash amount that units in the thermal power plant produce, and the analyses of the samples mixed, which used certain amounts in flotation tests, it was found that the bottom ash includes 91.47% ash in dry form and 8.53% combustible matter, and the lower calorific value is 491 kcal/kg. Optimum flotation conditions to get the unburned carbon were subsequently determined by examination of the optimum flotation grain size, pulp density, collector type and amount, depressant type and amount, frother type and amount, agitation speed, and froth-taking time. While the lower calorific value of the thermal power plant bottom ashes of the 3rd , 4th and 5th units and the mixed bottom ash sample was, respectively, 959, 469, 279 and 491 kcal/kg in dry form, it increased to 2490, 1312, 786 and 1348 kcal/kg in the product obtained as a result of flotation in optimum conditions. Key words: ash, conventional flotation, unburned carbon

Jan 1, 2008

By I. Liebman

The Bureau of Mines conducted experiments on coal dust explosion suppression. The investigation took place on a beltway in the double-entry of the Bureau's Experimental Mine. Using conditions that simulate those in a working mine, the investigation showed that a coal dust explosion can be readily initiated in a conveyor belt entry. Also, the explosion can spread into adjacent entries through opened crosscuts (stopping destroyed by explosion) to propagate for long distances even though the adjacent entries are rock dusted in compliance with regulations. Passive water barriers (water-filled tubs) were found to be effective in suppressing explosions on a beltway; however, barrier efficiency was reduced by opened crosscuts. The study indicated that the beltway barrier should be the distributed type consisting of continuous rows of water-filled tubs covering long distances along the entry. A plan is outlined for the installation of a water barrier system in a working coal mine for the protection of a beltway.

Jan 1, 1981

By Mazin Adnan

The 80m high dam at the Peribonka river in the Canadian province of Quebec was designed for the generation of 385 MW of hydro electrical power (Fig.1). The complex ground conditions required the employment of a variety of geotechnical construction methods stretched to limits never experienced before. Innovative grouting and trenching techniques were used for the construction of a plastic concrete cut-off wall down to a depth of about 116m, to cut hydraulic seepage through alluvial deposits forming the dam foundation. The bedrock where the cut-off wall is embedded forms a glacial gully with steeply sloped flanks, which created further challenging conditions. [ ]

Jan 1, 2008

By T. A. Sullivan

Refining in a molten salt electrolyte was investigated as a means of recovering nickel containing less than 1 percent and preferably less than 0.2 percent cobalt from nickel products containing up to 5 percent cobalt. Electrolytic separation of nick and cobalt was accomplished in a molten KCl-LiCl-NiCl2 electrolyte. Nickel containing less than 0.10 percent cobalt was routinely prepared. Factors that influenced the transfer of cobalt to the refined product were the nickel concentration of the electrolyte, the cobalt concentration of the electrolyte, the ratio of nickel to cobalt in the electrolyte, and cathode current densities. A method of recovering the cobalt from the electrolyte was developed. The possibility of preparing high-purity nickel by this process was shown, as well as the preparation of various cobalt-nickel-tungsten alloys.

Jan 1, 1968

By V. R. Spironello

One of the primary objectives of the Bureau of Mines solid waste utilization program is the recycling of the magnetic fraction of municipal solid waste called raw refuse scrap. In this investigation, several types of scrap of differing quality, including refuse and turnings, were melted in a 1-ton electric-arc furnace in various combinations to produce steel in noncritical (construction) grades. In-formation on furnace operation and on the behavior of tramp and alloying elements was obtained. The research showed that it is possible to produce acceptable steel from a variety of steel scrap. Although some scrap is routinely used in steelmaking, it was found that up to 50 to 55 pct of the scrap charge can be ref-use, provided it is combined with higher quality scrap. The chemistry of the steels was generally acceptable, and all of them were rolled without difficulty. The specification (ASTM 615) for the steels produced was grade 40 or grade 60, containing 0.30 or 0.40 pct C, with mini-mum yield strengths of 40,000 or 60,000-psi, respectively. Most of the steels met the specification requirements. In-formation on typical microstructures of some of the steels is included. The composition of some furnace dusts showed high levels of Sn, Pb, and Zn.

Jan 1, 1981

By Robert C. Steckley

The Bureau of Mines performed a fragmentation experiment in cooperation with Duval Corporation in a porphyry copper-molybdenum deposit near the Sierrita pit south of Tucson, Ariz. This experiment evaluated the fragmentation created in a 10-hole test blast having blasthole spacings of 25, 20, and 15 feet. The 10 blastholes were 9 inches in diameter and contained a total of 17,400 pounds of aluminized slurry blasting agent in 50-foot columns with 60 feet of stemming. Diamond drill core examination was the primary method used to determine the condition of the rock before and after blasting. These core examinations included study of length recovery, rock quality designation (RQD), weight recovery, and size distribution. Topographic surveys were used to measure the rock swell produced by the blast and a fragment size distribution was obtained for the broken material on the surface. Fragmentation to depths of 110 feet was excellent from the 15-to 20-foot blasthole spacing patterns. Good breakage was also produced by the 25-foot pattern although the effects of the blast were not so obvious. In situ leaching tests were not conducted. However, based only on size consideration, all three blasting patterns produced adequate breakage for successful leaching.

Jan 1, 1975

By Robert W. Gordon

This report describes the results and conclusions of the further development of a lightweight probe drill for use in anthracite mines. Improvements to the drill previously developed under Contract H0282044 were made and tested at an Eastern Pennsylvania mine. These improvements were: 1. Better hole cleaning due to the development of an air-water mist flushing system. 2. The application of roof drill bits to allow drilling through rock seams and lenses. 3. The development of a quick coupling drill system which reduced total steel change time. 4. Adaptation of a swivel to the drill anchoring system which greatly reduced set-up time between holes. With these improvements the probe drill demonstrated its ability to drill the required 11 holes in one shift. It also gained miner acceptance as a viable underground working tool. The probe drill proved to meet all of the design requirements of portability, low weight drilling controllability, structural integrity and reliability. In addition to its ability to drill the required probe pattern, the probe drill has the capability of drilling long holes. By drilling several holes over 80 feet deep the probe drill has demonstrated a potential for use in robbing pillars and for methane drainage.

Jan 1, 1981

By Frank C. Appleyard

As the environmental movement gained force during the past few years, it was inevitable that attention would be focused on surface mining, and we have seen this method of extracting minerals from the ground come under heavy attack by conservation groups, the press and television, legislators at all levels of government,, and the public at large. It is difficult, and in some situations, perhaps impossible, to measure either the need for, or the results of, land reclamation in absolute terms. Therefore, much of the criticism of surface mining has been based upon subjective analysis rather than hard data, with the result that discussion of the subject often includes a fair amount of emotional response. To be fair, this reaction is not limited to just our critics; even we hard headed engineers sometimes respond in the same way, an observation with which you may agree when I finish this talk. This leads to the thought that whether you are for it, or against it, land reclamation in many respects is a state of mind. That is, our reaction to it can vary considerably, depending on how far we have thought it through. And think it through we must, because the pressures being brought to bear need to be met with positive actions if the problem is to be brought under control, and in the next few minutes I would like to discuss from a management point of view some ideas which might aid in this thinking process. It would be a mistake, I believe, to think that the current energy crisis will suddenly bring the environmental movement to a stop, and therefore, we can relax and go back to running our busi¬ness the way we used to. This is not realistic; on the contrary the energy crisis is focusing attention on the limitations of our natural resources as nothing else could, and with respect to land

Jan 1, 1974

By V. A. Temeng, M. Owusu-Tweneboah, K. Awuah-Offei

The mining industry has long recognized the value of dispatch systems in open pit mines as they reduce load and haul costs. Over the years, researchers have proposed many dispatch systems with various limitations and advantages. The simplest dispatch algorithms are the so called 1-truck-for-N-shovels dispatch strategy. These algorithms are limited by the fact that their objective functions do not consider all the objectives of a mine and cannot be applied to all possible truck-shovel configurations. They are also myopic in nature. However, they are simple and computationally efficient and do not require occasional updates of the upper stage problem as required in multi-stage dispatch algorithms. In this work, an agent-based truck dispatch algorithm that conceptualizes trucks as intelligent agents that make autonomous dispatching decisions to maximize their utility is proposed. The advantages of this algorithm includes utility functions that encapsulate all of management’s objectives and agent’s with broad situational awareness. They are also more suitable for autonomous trucks. We evaluate the new algorithm against a simple 1-truck-for-N-shovels dispatch strategies using discrete event simulation. The simulation results show that the new utility function has significant advantages over 1-truck-for-N-shovels inspired utility functions. Future work will incorporate adaptive behavior into the model via reinforcement learning algorithm. INTRODUCTION In an attempt to optimize truck shovel operations in open pit mines in order to reduce the cost of haulage operation, which according to (Alarie and Gamache, 2002) is estimated to be about 50-60% of the total cost of mining, several effective and efficient strategies have been developed. Optimizing truck haulage systems in an open pit mine is one of the greatest challenges of mining engineering and has been the subject of many research projects. It is important that haulage systems are designed to be efficient, in order to minimise haulage cost, improve profitability and increase the total mine value. Although optimizing the number of trucks required in the operation of open pit mines can help reduce the cost, an effective and efficient truck dispatching system add value by ensuring that the available trucks are used efficiently. With truck dispatching systems, the trucks are normally dispatched between the crusher and dumping station (e.g. waste dumps and stockpiles), and the shovels in order to maximize the total output, obtain grades targets, reduce fuel consumptions and other objectives. Truck dispatching, which can have one or more objectives, is typically subjected to certain operational constraints such as truck and shovel capacities, empty and loaded trucks speed, among others. The problems associated with truck dispatching was first mentioned by Dantzig and Ramser (1959) after they made an attempt to determine the optimum routes of a fleet of delivery trucks between bulk terminals and a service stations. The problem occurs in several industrial systems besides mining (Alarie and Gamache, 2002; Gendreau et al., 2006; Rego and Roucariol, 1995). The dispatching problem, also referred in literature as the vehicle routing problem, has seen a number of modifications and extensions with Bertsimas and Ryzin (1991) presenting a dynamic and stochastic vehicle routing problem, and Ralphs et al. (2003) also adding to the original concept, the concept of vehicle capacity routing.

Jan 1, 2019

By Charles L. Kimbell

World political events that occurred subsequent to yearend 1989 but that bear heavily on the global mineral industry have been of such significance that they cannot be disregarded, and certainly they contribute to any type of "outlook?. However, to write of them simply as "forecasts" in an "outlook" section of this study would be to unjustly pretend to status as prophets. Thus, this section covers events that have occurred not as predictions but rather as history. The section also includes an element with some broad statistical information, but this is included last rather than first for two reasons: the information is subject to considerable re- vision as additional data become available and as preliminary returns are corrected; and the authors view it as less important than the events that govern the statistics. The Near East and the Crisis There.- Of all 1990 political events influencing the world's mineral industry, the Iraqi invasion of Kuwait and the remarkable events that followed this aggression must head the list. The almost immediate imposition of economic sanctions, involving embargoes on shipment of virtually all goods into and out of Iraq, caused severe dislocations in the production and trade of mineral commodities, not only within the region itself, but with a ripple effect, into other world areas as well.

Jan 1, 1992

By M Rauer

With a worldwide growing population the demand for higher living standards, food and the development of new technology is rapidly rising. To allow for a continuous growth, larger quantities of minerals and raw materials are needed at a faster pace. Different methods have been developed to access or tap ore more quickly, such as improved drill and blast operations, mechanical mining methods using equipment such as roadheaders (RH), longwall miners and other technical equipment. Another possibility to access and develop mines faster is the use of a tunnel boring machine (TBM).The historical usage of TBMs is surprisingly long, but the opportunity for technology adoption by the majority of worldwide mining companies remains largely untapped. Dozens of full face TBMs have been used by mines around the world, including two that will begin operation soon in Australia. TBMs have been used to safely and rapidly gain access to the orebody, or to expand access to the orebody to increase output by running a TBM along the edge of the orebody for several kilometres. These machines have also been used for ventilation and for conveyor tunnels for ore removal. They have been used to quickly excavate long and winding declines giving access to an orebody at several levels in a short period of time.Tunnel boring technology can be used for mine declines, mine access tunnels and all sorts of different mine designs and set-ups. TBM technology simply needs to be adapted to the mine conditions and, if manufacturers are involved early on in the planning process for mine development, the operation can be very successful. In some cases, historically typical mine designs may need to be re-thought.One mine, the Stillwater Platinum mine in Nye, Montana, is currently employing its fourth TBM in 25 years. Two were used to create tunnels running alongside the orebody, rapidly expanding access to the orebody in many locations for increased output. Two were used to create parallel access tunnels to a mine expansion at the East Boulder orebody; one tunnel is for conveyor haulage and the other for vehicular access. TBMs have been employed successfully many times to rapidly drive vehicular decline tunnels to multiple mine levels, such as at the San Manuel – Magma Copper mine in the USA. While TBM technology may not seem to be optimal for every mine, these success stories show that the method can provide vast benefits for the right projects.Early use of TBMs in extremely hard rock metal mines, in the 1960s and 1970s, had limited success since performance was low. However there have been great improvements made over the years in the strength of rock which can be excavated by TBMs with high performance. Other important improvements involve the provision of a safe work environment, safely and rapidly supporting the rock and predicting geology ahead of the TBM.This paper will briefly note the more than 20 TBM mining projects and highlight some notable successes. It will then go on to give a status report on the two active TBM mining projects in Australia and the difference between a TBM operation versus other excavation methods such as drill and blast (D&B) or RH excavation.CITATION:Rauer, M, 2014. Tunnel boring machines in mines – a?brief review of past use with a status report on use today in Australia, in Proceedings 15th Australasian Tunnelling Conference 2014 , pp 663–670 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 17, 2014

By Z. Zhang, R. G. Reddy

Viscosities of industrial lead slags with various compositions were measured as a function of temperature using a Brookfield viscometer. Based on the experimental data from this study and other investigations reported in the literature, an expression has been developed to correlate the viscosities of lead silicate slags as functions of composition and temperature. The effect of each individual slag component on the variation of the slag viscosity is identified. The composition dependency of viscosity of lead silicate slags is discussed. The calculated results using this viscosity expression are in good agreement with the measured data.

Jan 1, 2001

By P Mulvey, M Stuckey

"Inter-aquifer leakage due to fractures caused by coal seam gas extractions or longwall mining is an important issue for both the gas and coal industries. Currently, predicting stress induced macro-porosity associated with hydraulic fracturing, depressurisation via dewatering or collapse of overlying seams to infill a void left by longwall mining, is problematic. If fractures can be located the fracture can be sealed. Locating fractures is difficult. The non-geophysical approaches to locate fractures has been to consider the mixing of different waters, particularly that of more recent shallower groundwater with older deeper groundwater, via differences in radio-isotopes integrated with geochemical models to predict likely mixing of waters. This approach is applicable under appropriately complex settings; however, it is an expensive technique and is based on the assumption that the daughter isotopes are equally non-reactive which may not always be the case.Potentially a cheaper and faster technique is to consider integrating geochemistry (mineral weathering) and hydrogeology. The chemistry of groundwater, controlled by the weathering of primary rock?minerals and?formation of secondary minerals, can not only be differentiated between geological strata but also within strata as different stages in weathering results in differing impacts on water quality (ie different reactants).Field analysis of pH, electrolytic conductivity (EC), oxidation reduction potential (ORP) and dissolved carbon dioxide together with laboratory analysis of dissolved constituents characterise the chemistry of the water. Collection of rock samples at the time of drilling for bore installation can provide the (only) opportunity to assess the media in which the groundwater resides and migrates through. An assessment of aquifer matrix chemical makeup, via bulk sample chemical analysis, X-ray diffraction (XRD) and petrographic analysis can achieve this.The chemistry of groundwater is dependent on the water velocity. Water at deposition and post-diagenesis dissolution of minerals by hydrolysis and oxidation will result in equilibria of the dissolved phase with the solid phase. Post-depositional fractures caused by either tectonic activity or weathering alter the rate of weathering and thereby the geochemistry. Slow water flow in microfractures results in water in equilibrium with the rock minerals. Faster flow in larger fractures results in water being in disequilibria with rock minerals.Fractures can alter groundwater chemistry by two pathways: changing groundwater velocity, which changes the rate of hydrolysis or oxidation mixing water from different geological strata.Both pathways cause subtle changes in the water chemistry.It is however, the dissolved phase chemical data, which can be observed over time at individual locations and/or at a point in time along a flow path, which allows the hydrogeologist to ælook up-gradientÆ and locate the zone of leakage. Hence, influences on rock/groundwater chemistry, from anthropogenic sources to natural mixing of waters, can be assessed via appropriate interpretation of geochemistry, hydrogeochemistry and flow data.This paper will use the example of the geochemical and hydrogeological characterisation of aquifers within the Hawkesbury and Bulgo Sandstone of the Southern Coalfields to the south of Sydney in New South Wales to demonstrate this approach.CITATION:Stuckey, M and Mulvey, P, 2013. Looking for fractures - integrating geochemistry with hydrogeology to find inter-aquifer leakage above dewatered or collapsed coal seams, in Proceedings Water in Mining 2013, pp 99-108 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Nov 26, 2013

By Y. Jiang, B. Li, R. Liu

"In this study, laboratory flow tests were conducted on 2-D artificial rock fracture network models containing a single intersection constituted by two inlet and two outlet branches. Three models with different intersecting angles of 60°, 90° and 120° were tested using both dye solution and distilled water. Constant flow rates were imposed on one inlet, and the flow patterns in the fracture intersections were captured by using a CCD camera. The test results were compared with the predictions made by numerical simulations that solved the Navier-Stokes equations. The results revealed that when Reynolds number (Re) is as low as less than 1, the intersecting angle has negligible influence on the flow rate of each branch and the flow patterns within a fracture intersection. As the interesting angle ? and Re (e.g., from 10 to 200) change, the normalized flow rates of different outlet branches change significantly, due to the inertial effect of fluid flow. These changes could be represented by a series of mathematical expressions involving Re and ?, which could be applied to fracture network models to improve their prediction accuracy on hydraulic properties (e.g., permeability and breakthrough curves of particles) of rock masses. INTRODUCTIONCoupled stress, flow, heat and mass transport are the corner stone subjects for many geoscience and geo-engineering disciplines, such as geological disposal of radioactive waste and geothermal energy exploitation. Many outstanding issues need to be investigated to enhance the knowledge on these subjects, and specifically more in-depth research in testing and modeling of the fluid flow in fractured rock masses is needed. In recent years, discrete fracture network (DFN) models have been extensively used to study the fluid flow and mass transport behaviors of fractured rock masses (e.g., Min et al., 2004; Zhao et al., 2011). In these models, each fracture is usually represented by a parallel-plate model, in which fluid flow exactly follows the cubic law. Therefore, comparative flow rate in each outlet branch of an intersection in these models only depends on its aperture. In reality, due to the surface roughness of fractures, the magnitude of mechanical aperture is usually larger than that of the hydraulic aperture of each fracture (Li et al., 2008; Xiong et al., 2011), and abundant flow patterns could exist in an intersection, influenced by its geometry, varying with changing Reynolds number (Re) (Kosakoswski & Berkowitz, 1999). Recent studies have also revealed that different mixing patterns might exist at a fracture intersection, bounded between streamline routing model and complete mixing model, that determine the final distribution of solutes in fractured rock masses (Johnson and Brown, 2001; Park et al., 2001). Numerical simulation has been the principal method adopted in previous studies, and the studies conducting flow tests on intersected fractures are less reported (Wilson & Witherspoon, 1976; Johnson and Brown, 2001). In this study, laboratory flow tests and numerical simulations by solving the Navier-Stokes equations were conducted on 2-D models containing a single intersection constituted by two inlet and two outlet branches, intersected at different angles. The main objective is to study the influence of intersecting angle on the flow behavior of the intersected fractures and the variations of flow patterns and fluid redistribution in each model along with the changes of the Re and the intersecting angle ?. The influence of surface roughness was not considered."

Jan 1, 2015

By V. Castranova, T-M. Ong, V. Vallyathan, M. J. Keane, W. E. Wallace Jr.

"Inhalation of certain forms of silica, asbestos and some other respirable dusts can result in pulmonary fibrosis, characterized by destruction of the surfaces of alveoli and respiratory bronchioles. Fibrous thickening of the alveolar septa decreases the lung's capacity for gas exchange.Pulmonary macrophage damage by respired dust may initiate the fibrotic response.In one proposed mechanism, dust particles interact with the plasma membrane of a macrophage. This damages the cell or induces some hyperactivity of the cell, resulting in excessive release of lysosomal enzymes and reactive forms of oxygen (1). These reactive enzymes or radicals then damage the alveolar surface epithelial cells. A second mechanism has also been pro¬posed (2,3) in which dust damage to the macrophage causes the release of mediator substances which induce pulmonary fibroblast cell proliferation and increased collagen synthesis. This produces fibrous tissue in the terminal air spaces (4,5).Mineral surface interactions with plasma membrane lipoproteins have been proposed as a mechanism of lytic damage of pulmonary cells by silica dust in numerous models (6,7). The significance of dust surface proper¬ties has been further revealed in studies showing significant changes in dust induced cytotoxicity as a function of dust surface crystallinity and organic or inorganic contamination or coating of mineral surfaces (8,9). Such modification of the mineral surface might interfere with surface sites responsible for the toxicity of dusts for pulmonary macrophages, thus interrupting the early stages of the process of fibrosis.In vitro cellular assay systems using erythrocyte hemolysis or the release of macrophage cytosolic or lysosomal enzymes following dust challenge, have been used to analyze the initial mechanism of dust damage to cells. However the ability of these assays to predict the pulmonary disease producing potential of various dusts is imperfect owing to some ""false positive"" results. These assays as performed are therefore questionable models for the initial lesion in pneumoconiosis or silicosis. In particular, kaolin frequently is found to have comparable biological activity to silica quartz in these assays (10,11).Silica and kaolin have distinctly different fibrogenic potentials. Silica is highly fibrogenic, resulting in both acute and chronic silicosis (12). Some epidemiological data and animal experimentation data have indicated that long term exposure to kaolin can result in pneumoconiosis; however, kaolin is relatively benign as compared to silica (13-18). Kaolin is also of interest because it is one of the major mineral inclusions in Eastern U.S. bituminous coals. We have observed that exposing respirable sized native silica or kaolin for two hours to pulmonary macrophages results in a greater enzyme release for kaolin exposures, on a dust mass basis. Exposure of erythrocytes to the dusts also results in greater levels of hemolysis by kaolin for equal mass respirable dust doses. Therefore, these results do not correlate positively with known disease inducing potentials of the two dusts.Characterization of physical and chemical surface properties of dusts involved in occupational exposures, and characterization of the alteration of those surface properties which are likely to occur upon deposition of the dust in the lung, should improve the identification of respiratory disease hazards.Inhaled dust particles deposited in the lower respiratory tract will come in contact with pulmonary surfactant. This surfactant forms a surface film on and emulsion in the liquid hypophase coating of the alveoli and respiratory bronchioles. The primary constituent of this pulmonary surfactant is the lipid diacyl glycerophosphorylcholine, lecithin (19). Because this lipid is also a major component of cell membranes, it is possible that surfactant can interact with mineral dust to alter its Interaction with macrophages and other pulmonary cells and, thus, it"

Jan 1, 1988