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FOR some years past it has been usual to specify high-grade copper for use for many purposes, but the practice of specifying zinc of a high degree of purity for certain purposes is of comparatively recent origin. It is a practice, however, which is extending ag the effect of the impurities in zinc on products manufactured therefrom becomes widely recognized.The notes hereunder are intended to briefly survey the principal uses to which high-gr.ade zinc is being put, and, wherever possible, to indicate the effect of the impurities normally present in the lower grades of zinc.In the United States zinc is graded into five divisions, known respectively as "High-grade" "Intermediate" "Brass Special" "Selected," and "Prime Western." The maximum amounts of impurities allowed in the various grades are indicated in Table I,which is compiled from data published by the American Society of Testing Materials:In addition, it is specified in an cases that the slabs shall be reasonably free from surface corrosion or adhering foreign matter. Although zinc used in Europe has in many cases been sold on analysis it is only recently that any attempt has been made to grade...

Jan 1, 1923

By Edward A. Barrett, Roberta A. Calhoun

Introduction This Instructor’s Copy contains most of the materials trainers will need in order to use Drill Rig Incident (DRI). It includes suggestions for using the exercise, performance objectives for the training, master answer sheets, a scoring key, and a set of discussion notes that provides additional subject information. Four appendices are also included. Appendix A is the complete exercise problem booklet. It may be reproduced so that every person in the training class has one. Appendix B contains answer sheet blanks. The blanks are furnished if you choose to have the invisible ink answers that appear in appendix C printed on them at your location.3 Answer sheets are consumable. One is needed for each group of three to five persons who work the exercise together. An alternative is for each individual trainee to have his/her own answer sheet. Appendix D contains the 24-question pretest / posttest that was used in the field evaluation of the DRI exercise. Acknowledgment The authors thank Linda J. McWilliams, Statistician, NIOSH Pittsburgh Research Laboratory, for her assistance in analyzing the experimental data in this document.

Jan 2, 2005

By Glenn Keep

THIS paper is not an announcement of the successful conclusion of the Cerro de Pasco Copper Corporation's pacos-pyrite problems, but merely a description of the commercial-scale, intermittent-roasting operations conducted by the writer, J. H. Lucas and others of the staff. It was prepared by request, for presentation at the February meeting of the Institute. The results obtained in Peru confirm the 1-ton-a-day experiments completed about three years ago at Kearny, N. J. by C. C. Gordon and Mr. Lucas, where it was first demonstrated that a mixture of about 80 per cent. pacos ore with 10 per cent. pyrite ore and 10 per cent. salt could be roasted intermittently in a small 1-ton-a-day Holt-Dern furnace without extraneous fuel, producing porous calcine that could be leached rapidly. Mr. Keep and his staff, by successfully introducing improvements in the construction of the commercial furnace and in their handling of material, have established beyond doubt a low cost for roasting. The other steps in the process of treating pacos and pyrite ores have not as yet been demonstrated as sufficiently conclusive to warrant their acceptance for a permanent plant.

Jan 1, 1929

By J. A. Frew, R. M. Glen

Recovery of galena and sphalerite from fine grained lead-zinc ores by flotation normally requires re-grinding to achieve economic recoveries at acceptable concentrate grades. Re-grinding aims to reduce the coarse valuable mineral particles to a size where they float more readily and to liberate the composite valuable particles so that the gangue in these composites does not dilute the concentrate. Besides changing particle size and liberation, re-grinding changes the surfaces of the minerals and thus may alter the rate that mineral particles of a given size and liberation float. A method was developed to apportion the total change in recovery after re-grinding between changes in size and liberation and changes in flotation rates. The flotation behaviour of minerals, before and after re-grinding, was measured by floating samples of plant streams under controlled conditions in a laboratory cell. Results from several industrial lead-zinc circuits indicated that the change in behaviour observed fell into three different categories. It is concluded that the method will indicate whether the focus for optimization of existing plant should be on comminution or flotation, and it will help determine the path for laboratory testing in designing new regrind circuits.

Jan 1, 1995

By I. Iwasaki

As the world tension relaxes and as the interest and taste for consumer products change, complacency is beginning to prevail over the needs of minerals and primary metals. The current trend towards resources and energy conservation calls for miniaturization of consumer goods, and lowers the demand for virgin materials to produce goods and services. Challenged by the third world countries with high grade ores and low labor costs, industrialized nations with lower grade ores are being pressed into more efficient operation through technological innovation, while protecting the environment. In many countries, domestic mines were forced to close since the oil crises due to rapidly rising energy and labor costs. Research in conventional mineral processing needs to be directed towards breakthrough technologies in order to maintain the competitive edge in the global marketplace. Research activities will provide new challenges in the processing of solid waste and waste water for environmental remediation as well as for resource conservation, in the preparation of new functional materials of extreme purity and/or unique properties for high technology applications and in the development of such future resources as deep sea minerals and extraterrestrial materials.

Jan 1, 1995

By Hae-Moon Choi, Sang-Don Lee, Hee Soon Shin, Choon Sunwo, Chang-Ha Ryu, Hyun-Koo Lee

Building tunnels means dealing with what rock is encountered. Relocation of the site of the underground structure is rarely possible. Tunneling engineers and miners have to cope with the quality of the rock mass as it is. Different tunneling philosophies and different rock classification methods have been developed in various countries. Most of the rock classification methods are based on the response of the rock mass to the excavation. Tunnel support requirements could be assessed analytically, supplemented by rock mass classification predictions, and verified by measurements during construction. Rock mass classifications on their own should only be used for preliminary, planning purposes and not for final tunnel support. Design of blast pattern in tunneling projects in Korea is also for the most part prepared according to the general rock classification methods such as RMR or Q. It, however, does not take into account the blast performance, and as a consequence, produce poor blasting results. In this paper, the methods of general rock classification and blast design for tunnel excavation in Korea are reviewed, and efforts to develop a new classification method, reflecting the blasting performance, are presented. Copyright ©

Jan 1, 2004

By J. T. Shapland

When externally mounted sliding-gate valves are used to control the flow of metal from ladles, none of the valve components are immersed in steel. In general, the refractories used to date in sliding-gate valves have been made of a high-alumina composition. Because these refractories replace the fireclay sleeves and clay-graphite heads used to construct conventional stopper rods, they represent a major change in the use of pouring-pit refractories, Changes in the well and lining of the ladle as a result of conversion to external flow control probably will not be as severe; however, the sliding-gate valve makes it possible to preheat to a higher temperature and to decrease the turnaround time, and materials more refractory than those currently employed, such as basic brick, might be used in these areas. Another area of pouring-pit refractories that has became quite important is the tundish used with continuous casters. The use of external flow-control devices on tundishes makes it possible to use the tundish for prolonged periods of time and makes the use of better refractories necessary. In this application, high-alumina and zirconia are finding acceptance.

Jan 1, 1972

By Jakub Nalaskowski, Vamsi K. Paruchuri, Marcin Niewiadomski, Jan D. Miller

Spherical oxide particles can be used as mineral fillers, paint pigments, polishing materials and catalysts. They can be prepared using various techniques involving precipitation and spray drying. Melting of particles in a high-temperature flame is a simple technique which produces particles with a high degree of sphericity and high smoothness from non-spherical feed material. In current research the preparation of alumina particles by melting the feed material in a hydrogen- oxygen flame is described. The spherical particles obtained were characterized using scanning electron microscopy, atomic force microscopy, energy dispersive spectroscopy, X-ray difiaction, Fourier transform infrared spectroscopy and electrokinetic measurements. The particles pre- pared exhibit a high degree of sphericity and a low level of roughness. The chemical composition of the material after preparation is unchanged, however the crystallographic structure is different. It is suggested that alumina changes from pure a-alumina to a mixture of different transitional forms. Changes in the electrokinetic behavior were also observed for alumina which can be attributed to the strong dehydration of the oxide surface and/or change in the crystallographic structure. Also, the possible accommodation of trace amount of impurities in the surface zone during melting cannot be ignored.

Jan 1, 2003

By V. F. Hollister

The South American porphyry copper province includes most of the Andean orogen, excepting the tin province of Bolivia. Porphyry coppers have not been commonly found within the tin belt, though copper-tin deposits in San Rafael, Peru and copper-tungsten deposits in Llamuco, Chile, are known. James" shows the depth to the Moho to appreciably thicken where the tin belt exists, but disclaims any genetic significance from this coincidence. Table I gives some of the most important porphyry copper deposits explored to date, but does not include Antaminas, Peru, nor a number of other large skarn deposits associated with intrusions. V. D. Perry* points out that porphyry copper mineralization does occur to some extent in the intrusion associated with many of these skarn deposits. Also not included are the suspected possible porphyry type occurrences, such as, for example, quartz-sericitically altered lower levels of the Casapalca mine, Peru. Many deposits not well enough documented to list in a summary paper are also excluded. Should anyone care to tabulate all other large copper de- posits in South America, they could demonstrate that a tremendous potential awaits the proper political and economic climate in the future.

Jan 8, 1973

By A. Probst, N. Moores, J. A. Finch

In 1994, McGill University and INCO Ltd. (Sudbury operation) initiated the transfer of technology originally developed to detect levels in equipment ranging from flotation columns to thickeners. A conductivity probe was installed in a concentrate thickener to monitor the mud line and the solids load. The probe consisted of a vertical tube with 32 equally spaced electrode rings connected in pairs to give 31 conductivity cells. Conductivity was measured as a function of depth to produce a conductivity profile. From the conductivity profile, the mud line and the percent solids can be inferred. The probe was installed in October 1994, and it has been successfully detecting profiles since then. This paper includes a description of the incidents that occurred and the experiences gained during this technology-transfer process. Discussed is probe installation and startup; software modifications to accommodate both operating conditions and the needs of the operators; and calibration procedures to adjust to changes in performance as a consequence of long-term use. Also included are preliminary observations of the still-in-progress last stage, i.e., signal interpretation and use to facilitate operation, particularly by providing early reaction to upstream disturbances.

Jan 1, 1999

By Dale Preece, Stephen Chung, D. Scott Scovira

The DMC_BLAST (Distinct Motion Code) has been developed to model rock motion and displacement during the gas expansion phase after the detonation of an explosive in a borehole. Recently, a designated delay firing order algorithm was written into the DMC_BLAST code. The model can now be used to analyze rock mass displacement for a V-cut, center opening, or sinking cut initiation sequences. This new feature allows the investigation of the effects of delay firing order on rock displacement when blasting complex inter-bedded and ore-waste structures. The model provides important ground movement and mixing indicators for dilution control in surface gold mining relative to the initiation sequences employed. Echelon blasts as compared to center opening type blasts show differences in their internal muckpile displacement. These displacement differences can be important to operations that mine narrow strike driven ore bodies. The model also has applications to through coal seam blasting and demonstrates that down-dip blasting is a better alternative than up-dip blasting. There is less disturbance to the dipping coal seam and less mixing of the rock and the coal.

Jan 1, 2000

By Dan White

Stress measurements taken at Climax, El Teniente, Henderson, Lakeshore and Urad mines indicate that the deposits cited are generally subject to an inclined stress field that can be highly anisotropic. The horizontal stresses vary significantly between deposits and exceed the measured vertical stresses at Henderson and El Teniente mines. Experience at Henderson, Lakeshore and Urad mines is used to suggest a relationship between cavability and the premining stress. In poorly fractured, high strength rock masses, high stresses can assist the caving process. In well fractured, low strength rock masses, caving is ensured by breakage along fracture planes. The relationship between ground weight and the premining stress is also investigated. Ground weight problems appear to be most related to the competence of the ground rather than the magnitude of the premining stress as supported by experience at Climax and El Teniente mines. Recent developments in block caving favor the extraction of poorly fractured, high stressed rock. Accompanying the development of these deposits are new problems such as rock bursts. These pose particular problems to mine designers in that no experience currently exists in combatting rock burst problems at block caving mines.

Jan 1, 1984

By Jon C. Volkwein

Advances in mining technology have enabled deeper seams of coal to be mined from the surface. Highwall mining is frequently used to mine areas at the perimeters of a surface mine when removal of the overburden becomes uneconomical or threatens environmentally sensitive surface features. At the same time, advances in materials and technology have enabled highwall mining of coal that create blind headings over 300 meters in length. Deeper surface mining and deeper highwall penetration depths have lead to more frequent encounters with methane gas. While this coal is remotely mined from the surface, underground ignitions of methane have propagated to the surface and injured miners. Methods described in this paper show how this hazard can be correctly monitored and controlled for auger type highwall mining machines. Research indicates that small quantities of gas liberated during mining migrate to the face, creating higher gas concentrations than would otherwise be expected. Using the same principles that cause the gas to migrate to the face, researchers have shown that inert gas introduced at the collar of the hole can inert the entire hole, thus ensuring safe conditions for mining.

By Yi-jun Cao, Jin-cai Ran, Guo-sheng Li, Jiong-tian Liu, Li-jun Deng, Shu-lei Li

A fly ash sample from a power station in Guangdong province has been characterized by size separation, X-ray diffraction, contact angle measurements and X-ray Fluorescence. The ash sample had a loss-on-ignition (LOI) (%) of 15.54% and a large proportion of the unburned carbon was distributed in the +74 µm and -20 µm fractions. Contact angle measurements suggested that the removal of unburned carbon from the fly ash using flotation would present some challenges. The effects of various operating variables on the removal rate of unburned carbon (RUC) (%) and (LOI) (%) were determined using a cyclonic-static micro bubble flotation column (FCSMC). Within the range studied, the optimum diesel oil dosage was 1200 g/t, abies oil (frother) dosage was 600 g/t, pulp density was 20%, superficial gas velocity was 1.4 cm/s and circulating pressure was 0.20Mpa. Column flotation tests indicated that the FCSMC method a viable and effective separation process for removing the unburned carbon from the fly ash. Under the optimized conditions, a clean ash with 2.13% LOI and 94.21% RUC was obtained.

Jan 1, 2014

By J. Trouw, W. de Bruijn, A. van Sandwijk, R. H. Heerema

Differential reduction and expansion or shrinkage of hematite under the influence of intimately associated foreign oxides may be a source of stress formation and sinter degradation during blast furnace reduction. To study specific effects, synthetically prepared hematite powder evenly doped with 1 % by weight of several elements present as oxides, was pressed into tablets and sintered at high temperature prior to reduction. Continuous theimogravimetric and dilatometric analyses were performed on the sintered tablets as these were being subjected to reduction under simulated blast furnace time/temperature/gas composition conditions up to 1183 K. These findings were coupled with observations on the microstructure of tablets removed from various stages of the reduction process. The results indicate that the degree of expansion or shrinkage of hematite during reduction is highly dependent upon impurities associated with the original material; marked differences in reduction rate and microstructure were observed as well. An important finding is that the influence of a particular additive can also strongly vary from one reduction stage to the next. The reduction behavior appears to be affected by the physical and chemical nature of the associations formed by the added elements.

Jan 1, 1990

By E. G. Valdez

Iron foundries that melt automobile scrap produce flue dusts averaging about 32 percent zinc and 6 percent lead. Some is sold to smelters, but because of the meager return and difficulty in handling, most of the dust is discarded. As part of the Bureau of Mines program to find uses for mineral wastes, research was initiated to develop an economical process to recover zinc and lead from the flue dust. Research encompassed the extraction of zinc and lead by fuming, leaching, and agglomeration. Controlled vacuum fuming of zinc to produce Prime Western zinc and a lead-rich residue was the most effective method for treating the dust. This process involved two distillations, or fumings, with carbon and methane as reductants, and resulted in recovery of 91.4 percent of the zinc in a Prime Western grade product, and 98 percent of the lead. Hydrometallurgical techniques involved several leaching methods, but the simultaneous extraction of iron, manganese, and copper resulted in contamination of the solution and made the zinc recovery processes too complicated. Agglomeration was done by pelletizing or briquetting the dust for possible use as feed to a zinc smelter.

Jan 1, 1975

By R. W. Stahl

Increasing use of continuous miners, especially the boring type, has focused attention on the inadequacy of face ventilation in coal mines. The bulk of the machine, the rapid advance of working faces, and the increased liberation of methane from the larger expanse of freshly exposed coal surfaces have created ventilation problems that were unknown with conventional mining equipment. Ignition of gas, especially that caused by machine bits striking hard rock or pyritic inclusions, have increased at an alarming rate. As the mines penetrate beds under thicker cover at an ever-increasing rate of face advance, this problem will probably increase unless face ventilation is improved. A previous survey, described in Bureau of Mines Report of Investigations 5414, Auxiliary Ventilation of Continuous Miner Places, disclosed that auxiliary fans with tubing generally improved circulation of air and removal of gas at the face. The study here reported attempts to examine, face ventilation at various mines and to note any plan or innovation of. air coursing that industry might adopt to reduce the danger of gas ignition. ACKNOWLEDGMENT The mines visited were very cooperative in the study-and-generously supplied any data requested.

Jan 1, 1960

By Dhaval Patel, Kim Witte, Charles Vaught, Michael T. Stephenson, Steve Booth-Butterfield, Cynthia Zuckerman, Brian L. Quick

This longitudinal field study was designed to encourage Appalachian coal miners in West Virginia and Pennsylvania to engage in hearing-protection behaviors. Method: Participants were mailed postcards that featured either a positive, negative, or neutral message on the outside of the postcard and a message encouraging hearing protection behaviors on the inside. The first posttest measurement of the effectiveness of the persuasive messages was conducted about a week after the postcards were mailed. The delayed posttest measurement was conducted six weeks later. Results: Responses from 307 coal miners revealed that the positive or neutral messages generated significantly more self-reported hearing protection behaviors than the negative message. Identical results were obtained in a delayed posttest assessment of miners' self-reported hearing protection behaviors. The positive message was also more effective than either the neutral or negative message in preventing defensive mechanisms from emerging over time. Impact on Industry: Positive and neutral messages were convincingly more than negative messages in facilitating self-reported hearing protection behaviors among coal miners. Similarly, the positive messages kept defensive processes at bay. Keywords: Hearing protection; Hearing loss; Coal miners; Campaign; Messages

By E. C. Robertson

Observations of faults in mines, at outcrops, and in the laboratory lead to the conclusion that the displacement d of a fault increases irregularly but monotonically with the thickness t of its associated fault gouge and breccia, not including adjacent undisplaced jointed rock. The general trend of data points has a slope d/t of about 100. (The correlation coefficient of a logarithmic regression line is r = 0.94.) The rather wide scatter of the points can be accounted for by inaccuracies in measurement of d and t, and by variation in the conditions at faulting of confining pressure, rock type, water pressure, and deformation history. Limestone is an exception to the relation. Until the data can be corrected and refined, the relation should be used only qualitatively for estimating displacement of ore bodies in mines. The suggested relation is based on observations of 48 steeply- dipping normal and reverse faults and nine small flat-dipping thrust faults, with displacement less than 5 km (3 miles). It does not apply to large strike-slip and low-angle overthrust faults because their large displacements are poorly determined and their breccia thicknesses are widely variable.

Jan 1, 1984

By John R. M. Hill

The Bureau of Mines performed elastic-plastic, finite-element analyses to investigate the support performance of hydraulic backfill. A mathematical model was developed for two vertically adjacent stopes separated by a sill pillar. An exact duplicate of a working stope was not intended; however, the model did simulate a working stope to the extent that field measurements from an active stope could be used for comparative purposes. Using a predetermined mining sequence, the computer analysis simulated the mining operation as a series of incremental cut-and-fill steps. Computer results included a complete history of stope closure and pillar stresses throughout the mining sequence. With the mining sequence and rock properties held constant, three separate analyses were made using varying backfill properties. These cases included no fill,-low-to-medium-quality fill, and medium-to-high-quality fill. Results of these analyses show decreases in stope closure and pillar stresses as the backfill quality increases, thus reducing the possible occurrence of rock bursts. Predicted stresses within the backfill compare favorably with field measurements. A relationship between maximum stress normal to the stope wall and the ratio of relative fill stiffness to relative rock stiffness was also indicated.

Jan 1, 1974