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By Bora Derin

The partial pressure ratios of sulfur and oxygen for several copper flash smelting plants were derived using the Reddy-Blander (RB) model and predicted dissolved sulfur contents available in the literature. The sulfide capacities (Cs) of six different flash smelting plants (FeO-CuO0.5- CaO-MgO-FeOwAIOl.s?SiO2) slags were calculated. The log (Po2/PS2) versus matte grades of various industrial processes was determined. The PoiPS2 ratio increased with an increase of copper grade. The calculated partial pressure ratios for the copper flash smelting are in good agreement with those of the experimental data.

Jan 1, 2003

By AIME AIME

SHORTLY after he started his professional career, the subject of this sketch acquired the sobriquet "Moose" Allen. At the time he was engaged in geological exploration it1 the Canadian wilds. The nickname was given .him because of the wide, straight trail that he broke with unusual speed when going through the bush. Like a moose he was strong, energetic, and determined. To a considerable degree, Rolland Craten Allen today displays the same characteristics in larger affairs-business, civic, and professional. It is his habit to study a problem thoroughly, to decide u11on the best course of action, and then to pursue that course with vigor and

Jan 1, 1936

By C. B. Daellenbach

The influence of reduction roasting and thermal shock on the grindability of a refractory low-grade Michigan iron ore was examined in bench scale tests. The quantitative effects of the various treatments were evaluated at three sieve levels: 48, 100, and 400 mesh, using ball mill grindability and work index parameters as response indicators. Data from the testing program were analyzed statistically as a means of isolating the effects of cooling rate, roasting temperature, and ore chemical condition. All three variables were found to have an important influence on the grindability of the treated ore; ore chemical condition and roasting temperature had the most pronounced effects.

Jan 1, 1970

By P. Wells, P. Quinn

"A moveable flotation miniplant was designed and constructed at the research laboratory of Inco Technical Services Ltd. to address the need for flowsheet development with a limited amount of ore (such as drill cores). It consists of one rod mill, two regrind ball mills, one vibratory screen, 24 flotation cells of various sizes and two Venturi aerated flotation columns. The setup has continuous monitoring capability for pH, dissolved oxygen, oxidation-reduction potential, conductivity and temperature in conditioning tanks and flotation cells. Various options regarding flotation reagents, circuit configurations, and fineness of primary grind and regrind can be readily evaluated. The throughput of the miniplant is 20 – 30 kg/hour ore.Unit operations such as flash flotation, magnetic separation and gravity concentration can also be evaluated as an integral part of an entire flowsheet development.This communication describes the basic design features of the miniplant and some examples of applications are given.INTRODUCTIONInco operates numerous mines in Sudbury and Thompson and will shortly bring the Voisey’s Bay mine into production. It has long been recognized that the ores from different mines or from different depths of the same mine can give different responses in flotation. There is a growing need to properly evaluate the ores before feeding the mill to maximize the return of the mine/mill operation. Inco Technical Services Limited at Sheridan Park, Mississauga, Ontario has developed a batch laboratory procedure to address this issue. The results are considered in the overall economical assessment of new mine operations.For ores that cannot be processed by the existing mill operations or that will be processed by a new mill, it is necessary to develop a flowsheet that can maximize the economical return of the mine/mill operation. While recognizing the importance and contribution of the laboratory batch flotation procedure, it does not generate reliable data for flowsheet simulation and design. A full-scale pilot plant campaign is normally required to obtain the design data but often this is not possible due to a limited amount of ore obtainable from the drill core. A small-scale pilot plant (mini pilot plant or miniplant) capable of processing 20-30 kg/h ore can provide this data prior to a full-scale pilot plant campaign. A miniplant can also be used to optimize the circuit configurations, reagent additions and recycle options of process water before pilot plant work and can be used to test a different flowsheet configuration for an existing mill before re-piping a plant circuit."

Jan 1, 2003

By Raja V. Ramani

In many instances, the actual production from a longwall face does not equal the planned capacity. General problem areas which have been identified include face length and panel depth, face area and gate entry roof support, face conveyor and shearer wear, outby haulage system failures, number of entries in longwall gate development and longwall move time. The performance of a longwall face is totally dependent on the interaction of these and many other factors. To explore fully these interactions, a systems analysis of longwalls has been performed. In this paper, the systems approach, the factors considered in the analysis, and the results of the analysis are presented.

Jan 1, 1983

By R. R. Faddick

Properties of coal-water slurries were studied in two separate phases: a rheological phase and a pipeline phase. The purpose of the study was to investigate the rheology of fine coal slurries to determine the effect of fine particles in a coal-water mixture on the economic and operational aspects of a slurry pipeline. The slurries consisted of 6x10, 100x200, and 200x0 mesh coal in water. A fourth slurry consisted of a mixture of the 6x10 and 200x0 mesh coal. Brookfield and Stormer rotational viscometers were used to obtain or simulate rheograms for a range of fine coal concentrations, temperatures, and particle sizes. All the slurries were pumped through a 1-inch diameter acrylic pipe. The fine coal slurries were found to encompass four distinct rheological models. The narrow size distribution of the coal slurries was apparently responsible for the high pipewall friction losses, more so than the particle size. A scale-up method applicable to Bingham plastics was found satisfactory for predicting pipeline headlosses of fine coal slurries from rheology data.

Jan 1, 1974

By S Jahanshahi, D R. Swinbourne

A knowledge of the value of the activity coefficient of cobalt oxide in slag as a function of composition and temperature is necessary if effective strategies are to be devised to maximise the recovery of cobalt in nonferrous smelting processes. This work reviews previous studies and shows that comparison and evaluation of the results is hampered by variations in the choice of standard states for the species. Published results have been recalculated to a common set of standard states with a preferred value for the Gibbs free energy of formation of cobalt oxide. It has been shown that the value of the activity coefficient of cobalt oxide referred to the solid standard state in iron silicate slags is approximately two, at temperatures from 1523 to 1623¦K. It is suggested that some contradictory results are most likely due to errors in the measured partial pressure of oxygen.

Jan 1, 1998

By L. A. Readdy

Defining classes of ore using geostatistical methods that match historical classifications has presented problems in the past. A simplistic and practical approach to this problem is presented. An example of the approach is presented using a porphyry type system as a case study. The technique described uses area of drill hole influence and known conditions from similar deposits, or the production history of the deposit being studied. It provides a practical bridging mechanism for defining the class of ore on a block-by-block basis using .the error of estimation value developed during kreiging. The approach provides a filtering method that refocuses attention on the adequacy of drill hole spacing.

Jan 1, 1985

By Eric W. Johnson

In the late 1950's a low-grade copper ore zone was outlined at the fifty-year-old McIntyre Porcupine Mine in Northern Ontario. Following this an independent copper circuit was installed in the existing gold mill. The nature of the operation decreed that capital expenditure be a minimum. To this end, in order to resolve the problem of storing and grinding two separate ores, it was decided to install a divider in the existing 4000 ton capacity fine ore storage bin and to replace ten conventional feeders with sixteen Mexican feeders. The article describes a successful application of the Mexican type feeder.

Jan 1, 1968

By C. A. Ozturk

The compressive strength of rock (sc) has an important effect on design of structures in rock engineering. Compressive strength can be determined in the laboratory using the uniaxial compressive strength (UCS) test. Some other index tests, such as the point load test, are also used, particularly when suitable samples for UCS are not available. The quantification of rock texture has introduced a new method in rock engineering for estimating the mechanical and physical properties of rock materials from microscopic investigations. The aim of this study is to quantify rock texture to estimate rock strength from the texture coefficient (TC), which is determined from a statistical assessment of thin section images. Rock texture is quantified by twelve different images from a single thin section to increase the reliability of texture analysis. A data-set is prepared to investigate correlations between TC and sc. The statistical correlations are computed after classifying of the rock samples based on their lithology as well as grain features. Equations derived based on the results of this study are used to predict the approximate value of compressive strength from the texture coefficient. This method is particularly useful for preliminary studies in rock engineering projects prior to detailed site investigation.

Jan 1, 2014

By Atmesh K. Sinha

The market for thermal coal has recently been growing rapidly and it is projected to continue to do so in the foreseeable future. Both the national and international markets often demand high Btu low sulfur thermal coal in order to minimize the cost of utilization and meet the environmental restrictions. High quality thermal coal can be prepared to compete in the utility market by desulfurizing the high Btu midwestern coal and blending it with low sulfur western coal which is usually low in Btu content. The methods that can be used for optimizing the coal preparation plant operating parameters for physically desulfurizing coal is presented.

Jan 1, 1984

By Edwin B. Cook

This report presents the results of calculations of the equilibrium composition of the products of combustion with air of six different mixtures of octane CgH18, plus PbEt4 and halogen-bearing scavengers at three air-fuel ratios, at pressures of 5 and 30 atm., and at temperatures of 350°, 1,000°, 1,800°, and 2,000° K. The air-fuel weight ratio has the values 12, 15:12, and 18. The concentration of PbEt4, M, in milliliters per gallon of iso-octane, has the value 1 or 3. The word "case" is used to designate the halogen concentration. Three cases have been considered [ ]

Jan 1, 1953

By Nathan C. Rockwood

THE title of this paper, I understand, was suggested by professional mining engineers as an opportunity for someone to pose problems rather than to offer solutions for them, but the paper will merely attempt to pose some of the production problems of the mineral aggregates industry in such manner as to create professional interest in their solution by the mining engineer, geologist, geochemist and the metallurgical engineer versed in mineral-dressing technique. DEFINITION OF MINERAL AGGREGATES "Mineral aggregates" may be defined as fragments of any rock or mineral used to supply bulk or volume or substance for a given purpose. For example, mineral aggregates are used in portland-cement concrete to provide bulk with the expenditure of the least feasible amount of cement binder. Mineral aggregates are used without portland cement or bituminous binder in highway and railway roadbeds to provide substance, to carry loads. Mineral aggregates are used in filters for water and sewage, to provide substance for the liquid to trickle through. These are only a few typical uses of mineral aggregates. For all these uses, strength, toughness, resistance to abrasion, and durability are usually prime requisites; so, while theoretically mineral aggregates may be of any mineral composition, what really is desired is a mineral composition as nearly inert under the conditions of use as anything of earthly origin can be. EXPLORATION AND POSSIBILITIES OF DEVELOPMENT The distribution of deposits of mineral aggregate is universal, since almost any part of the earth's crust can be used; even the top soil is sometimes used in stabilized surfacing for highways or airport runways. Nevertheless there is ample opportunity for exercise of the talents of the mining engineer and the geologist in finding the particular deposit that will be most economical to develop, keeping in mind such considerations as: (1) quality and mineralogical characteristics of the material; (2) size and permanency of the market; (3) final cost of opening and development of the deposit; (4) selection of location of plant; (5) methods and costs of distribution of the product in comparison with both present and possible future competition; (6) selection of the proper type of operating equipment; (7) estimation of probable waste products and their disposal. These are typical but there are other considerations also. Because profit margins are far smaller than in any comparable mining operation, it is all the more logical to assume that a higher degree of expert knowledge is desirable to make a success of a mineral-aggregates business. The industry has much engineering talent in its operating branch, but it lacks, to a considerable

Jan 1, 1943

By Patrick M. Y. Waye

As mines utilise more automation in mining operations to improve efficiency and safety, a corresponding increasing demand is placed on the transport of information. Some of the recent technological advances in underground telecommunications are described for various data, voice and video applications. In particular, two new innovative underground communication systems are described, one with high speed data at 30 Mbps and the other for mine wide evacuation and safety applications. The high speed data system incorporates stateof- the-art data networking technologies and the existing leaky cable narrow band radio channels. The new system provides over the same basic infrastructure the high speed data network at 30 Mbps TCP/IP Ethernet with 100 Base-T interconnection, plus 32 narrow band radio channels. The second system is a system for mine wide evacuation with "through the earth" communication infrastructure. Emergency situation can be communicated to and from all the miners within seconds through a central control location. The technology involved does not require leaky cable or any other similar transmission media installation. Many applications are possible, including warning miners of emergency situations, mine rescue operation to communicate with trapped miners, regular reporting from miners working alone.

May 1, 2001

By P. K. Narasimharaghavan

The major threat to the sustainability of Aluminium Industry is its significant contribution to global warming by way of generation of non eco-friendly gases during its production cycle from Bauxite to the finished product. Though reduction measures are taken in control and effective recovery of values from pot room gases, efforts in use of environment friendly additives in the final products production line is warranted. In this line, the present paper describes our efforts in the use of a new generation refining flux which apart from helping in effective removal of alkali metals, reduction in inclusions and ensure a better metal cleanliness shall also aide in reduction of obnoxious gases generated during the metal refining process prior to casting. The aim of the current work was to reconcile the practical results with the old generation fluxes used. Further improvements to bring in a better metal cleanliness will also be discussed.

Jan 1, 2010

In the interest of safety in metal mining, the Bureau of Mines recommends: That underground metal mines be equipped with a main fan in a fireproof housing, located preferably on the surface. The fan installation should be designed to ventilate the mine adequately throughout and to permit prompt reversal of direction of air flow. Many metal mines depend for ventilation upon natural flow of air, assisted by the exhaust from pneumatic drills and by compressed air blown into the workings. Others also ventilate separate headings or sections with fans and blowers. Relatively few have o mechanical ventilating system that controls the coursing of air throughout the mine.

Jan 1, 1939

By M Passmore, N Poznik

Olympic Dam is a world-class deposit and is unquestionably one of the most geologically, structurally and texturally complex orebodies in the world. As development advances into the Southern Mine Area (SMA) the geological understanding is rapidly evolving as underground drill rigs are prioritised to provide the additional data necessary to convert Indicated and Inferred Resources into Measured Resources. The SMA represents approximately 70 per cent of Olympic Dam’s total resource and is significantly more complex when compared to the Northern Mine Area with respect to the diverse nature and origin of lithotypes, rock mass characteristics and the extent of major structures controlling primary mineralisation trends.Recent mine development into the central SMA has been impacted by a major structural gouge zone. Sound geological interpretation allowed mine geologists to successfully integrate their local understanding of the distribution of lithotypes with critical geotechnical data, chiefly rock quality designation (RQD), to delineate and better predict this major structural gouge zone. As a direct result, development rates improved whilst also increasing awareness for the importance of sound geological interpretation utilising all available data. In order to maximise predictability across all systems in place through the mining geology value chain, the integration of geological and geotechnical data in a geotechnical RQD block model provides an additional tool to assist in preventative solutions for complex problems to achieve a proactive mining environment.This paper details the methods used to build the RQD block model, the geostatistical estimation parameters, 3D geotechnical domain wireframes, challenges regarding legacy approaches, and collection of geotechnical information and incorporating/linking geotechnical data with geological features, including the use of grade and lithotype domains. Although the geotechnical block model proved difficult and complex to construct, the resultant product has seen successful integration of geological and geotechnical data into mine planning providing higher resolution of critical parameters for local mining areas.CITATION:Clark, J M, Passmore, M and Poznik, N, 2017. Olympic Dam rock quality designation model – an integrated approach, in Proceedings Tenth International Mining Geology Conference 2017, pp 27–36 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 20, 2017

By D. Gearhart

Full-scale tests are conducted on mine roof supports using protocols developed by the National Institute for Occupational Safety and Health (NIOSH) using the unique capabilities of the Mine Roof Simulator (MRS). These protocols simulate the loading conditions that the support will be exposed to in an underground mine to determine the performance capabilities and limitations of the support. Some tests are conducted with rigid boundary conditions, creating uniform contact and near ideal axial loading conditions. These tests are used to determine the ultimate performance potential of a support, including the strength, stiffness, and stability. For prop supports where stability is a critical design issue, tests are implemented to induce buckling by a modified end condition, eccentric contact, or biaxial loading. It is important to determine the cpacity of the support design when the support is subjected to unpredictable loading conditions. This paper examines the effect of end conditions and load profiles on prop support performance and applies a new analysis methodology based on eccentric loading to determine a factor of safety for load capacity. Recommendations for installation practices that minimize eccentricity and therefore preserve capacity are also provided.

The November General Meeting of the Institute was held in Kelvin House, Johannesburg, on Wednesday, 18th November, 1970, at 4.00 p.m. V. C. Robinson (President) was in the Chair. There were also present 30 Fellows, including J. K. E. Douglas, R. C. J. Goode, Dr J. P. Hugo, Prof J. de V. Lambrechts, D. G. Maxwell, Prof R. P. Plewman, Dr M. D. G. Salamon, P. W. J. van Rensburg, L. W. P. van den Bosch (Council Members), R. E. Burnton, S. Craib, D. de Villiers Oxford, J. C. Fritz, G. W. Gray, G. H. Henderson, S. D. Hill, C. H. Kruger, B. Leach, C. S. MacPhail, D. J. Molony, W. G. Fyne Mercier, R. A. Scott, M. v. R. Steyn, I. E. van Aswegan, A. D. Vos, J. M. Vosloo and N. Zolezzi. Four Members, including I. G. Evans, R. W. Shearer, W. Wilson. One Associate: P. M. C. Wilson. Four Students: H. G. Albertyn, J. T. Davies, P. G. Henderson and P. J. Pretorius. Fourteen Visitors, including S. R. Barker, F. H. Deist, Dr de Jager, L. F. Duvel, P. du P. Kruger, B. D. Maree, B. R. Meyer, R. Redmond, J. Rietief, A. W. S. Schumann, Mrs A. W. S. Schumann, T. S. Stoffberg, C. A. Visser and R. van der Wait. Secretary, D. C. Visser. Total present 55. The President: "Gentlemen, I would like to welcome all members of the Institute who are present, and visitors, and I would like specially to welcome any members of the Suid-Afrikaanse Akademie who are present this afternoon." OBITUARIES The President: "Before starting on the agenda the first item, of course, is unfortunately obituaries and it is my sad duty to announce the death of the following: I would like to start with a person who is not actually a member of the Institute but who, in his capacity as President of the Chamber of Mines, was Honorary President of this Institute three times and I refer, of course, to Mr Herman Calderwood Koch who passed away last Saturday. Then I would refer to Richard Beaumont Tasker, Life Fellow, who joined this Institute in 1932, and who died on the 22nd of October, 1970. Then, lastly, Mr Jean Francois du Plessis, a student, who joined the Institute on the 19th June, 1968, and passed away on the 11th of November, 1970, as the result of an accident. Mr du Plessis was to have received a Student Prize today for his paper entitled, Displacements and stresses in the vicinity of a horizontal long-wall'. We were all most upset to learn of his death last week, and we are now going to make arrangements to hand his prize to his widow on a suitable special occasion. As a mark of respect to the memory of the deceased, and in sympathy with the bereaved, I would ask you all to stand and observe a few moments' silence. Thank you." CONFIRMATION OF MINUTES The President: "May we confirm the minutes of the monthly general meeting which was held on 16th September, 1970, as published in the November Journal?" Agreed. MEMBERSHIP The President: "I have much pleasure in announcing that the names of the undermentioned candidates having been published in accordance with By-Law 5.2.2, Council has elected them to membership of the Institute in the following grades: Fellow: Ronald White Ballantine. Members: Jan Johannes Hertzog Viljoen, Agge Petrus Rutgerus van der Meer, Peter Anthony Reynolds, Ernest Esdaile Leyde Hans Lutz Klingmann, Ronald Archer.' Graduates: Trevor Stanley Schultz, Thomas Cochrane Meiklejohn, Leslie Harold Heyman, Dennis William Bosch, Sydney Stuart Absolom. Associates:Roderick James.Vermaak, Theodorus Daniel van Wyk, Michael Osmond Savignac Stedman, Leslie Owen Raymer, Bryan Arthur McKay, Leon Ellis Finlay Leask, Dudley Graham Lovedren Hall, John Arthur Gibbon, Richard Reginald de Villiers, Carel Frederik Boshoff. Students: Frederik Wilhelm Christian Coetzer, Phillippus Johannes de Wit, Jan van der Merwe Grimes, Davood Khareghani, Jan Wolvaardt Oberholzer, Johannes Lodewikus Pretorius Pieter Jacobus Strobos, Herbert Gerald Waldeck.' MEMBERS TRANSFERRED TO A HIGHER GRADE From Associate to Fellow: Howard Mitchell Wells. From Associate to Member: Ernest John Dominy. "I welcome the newly elected members to the Institute and congratulate the members who have been transferred to a higher grade." AWARDS The President: "It is with very great pleasure that I can announce that Council has agreed to make the following awards for papers presented to the Institute during the year ended July, 1970. Gold Medals to Prof Plewman and W. D. Ortlepp for their paper entitled 'The development and application of a digital computer method for the solution of strata control problems' written jointly with F. H. Deist (Visitor) and presented in September, 1969. A Silver Medal to Dr Finkelstein for his paper entitled 'The Influence of sulphydryl and cationic flotation reagents on cyanidation of native gold' written jointly with Dr K. G. Ashurst (Visitor), and presented in June 1969 at the Symposium on the Recovery of Pyrite. ' May I congratulate these gentlemen on the high honour they have won with their papers. As new medals are in the process of being designed the actual awards will be made at a later date to be announced to members.

By W. W. Anderson, D. G. Girton

The photoluminescence of Pr, Nd, Ho, Er, Tm, and Yb in CdS, and Ho, Er, Tm, and Yb in ZnSe has been observed from crystals Prepared by diffusion using rare earth metals and an excess chalcogen pressure. For a given temperature, time, and chalcogen pressure the spectral characteristics were very reproducible from run to run, and the emission intensity for Nd, Er, and Yb in CdS was as high or higher than the best vapor phase doped crystals we have grown. For a few rare earths it was found that certain conditions of diffusion tend to yield optimum rare earth emission intensity with respect to the background lattice emission. Photoluminescence measwements of Yb in CdS as a function of depth gave a profile which was neither a Gaussian nor complementary error function. Part of the profile appears to arise from a fast component of the diffusion and the other part from a slow diffusing component. At 960°C and 33 atm S pressure, a com -plimentary error function approximation of the slow diffusing component gave a diffusion coefficient of D = 1.3 x 10-9 sq cm per sec. MOST of the studies of emission from rare earth ions in II-VI compounds have been reported on crystals doped during growth,1,2 although Kingsley and Aven prepared ZnSe:Er by diffusion for paramagnetic resonance and fluorescence studies. Pappalardo and Dietz prepared CdS:Yb by diffusion, but they made optical absorption measurements., We know of no study on the properties of rare earth diffusion in the II-VI compounds. To date we have diffused Pr, Nd, Ho, Er, Tm, and Yb into CdS, and Ho, Er, Tm, and Yb into ZnSe and observed the rare earth emission spectra. For a given temperature and chalcogen pressure, the emission characteristics are very reproducible from run to run and for Yb, Nd, and Er in CdS, as good as the best crystals we had prepared by doping during vapor phase growth.2 The emission of Pr, Ho, and Tm has been observed in CdS prepared by diffusion for the first time. Previous attempts2 to prepare these later three materials by vapor phase growth were unsuccessful. The problem of obtaining reproducible characteristics in II-VI semiconductor compound work is well known.5 Not only is it difficult to reproduce results from one laboratory to another but it is sometimes difficult to reproduce results from one growth run to another under ostensibly identical conditions within one laboratory. This situation has been particularly bothersome in research on the luminescence of rare earth activated ZnS1 and Cds2. Crystals from one vapor phase growth run would show very strong rare earth line emission while crystals from a nearly identical run would show no rare earth emission. It was also observed on occasion that the intensity of the rare earth emission was not constant over the entire volume of a single crystal. MATERIAL PREPARATION AND INSTRUMENTATION Vapor phase grown boules of CdS were supplied by Dow Corning. This material was characterized by a free electron concentration of n - 3.5 x 1015 cm-3 and Hall mobility of 350 sq cm per v sec at room temperature. There were microscopic voids and decorated precipitates in some samples. The precipitates annealed out at diffusion temperatures but the voids remained. Single crystal rectangular samples of mm dimensions were sawed from the boules. The ZnSe was polycrystalline, UHP grade from Eagle-Picher. Poly-crystalline samples were sawed from the ingots. The samples were lapped, polished on one side, etched in a solution of 0.5 M K2Cr2O7 in 16 N H2SO4, and thoroughly washed in distilled water. A sample, excess sulfur (or selenium), and 5 mg of rare earth metal (turnings) were sealed in a 3.6 cm3 quartz ampoule at about 2 X 10-5 torr. The high chalcogen pressure used (1 to 30 atm) prevented thermal etching of the crystals and affected the diffusivity and solubility of the rare earth ions in the crystal lattice. For meaningful or reproducible results, it is thus necessary to specify the vapor pressure at which the diffusion was carried out. It is assumed that a negligible amount of the chalcogen was used in the formation of rare earth sulfides or selenides Our sulfur vapor pressure calculations are based on data assuming S2, S6, and S, molecules only in which case the equilibrium constants are given by6 where the pressures are expressed in torr. Selenium vapor consists of a mixture of Se2, Se4, Se6, and Se6 molecules. The selenium vapor pressure was calculated using equilibrium constants given by The status of the rare earth source during diffusion is unknown, i.e., the partial pressures of the rare earth metal and of the rare earth chalcogenides has not been determined. All emission spectra were recorded at 77°K on a Perkin-Elmer model 98-G spectrometer using a 640 line per mm grating. No correction was made for the spectrometer and detector spectral sensitivity. Excitation was by means of an XBO 1600 w xenon arc

Jan 1, 1970