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By Jr. Driscoll

The thermoelectric properties of yttrium monoarsenide, yttrium monoanti-monide) and ternary materials from the Y-As-Se and Y-Sb-Te systems were investigated by the Bureau of Mines from room temperature to 1,000° C. The maximum calculated figure of merit for yttrium monoarsenide and yttrium monoantimonide was 2 x 10-5 ° C-1. YAs and YSb were semimetallic conductors with low Seebeck coefficients and electrical resistivities. The values of the Seebeck coefficient and electrical resistivity of the Y-As-Se and Y-Sb-Te materials were between those of the yttrium selenides and tellurides and of YAs and YSb, respectively. The maximum power factor calculated for the Y-As-Se materials was 2 X 10-5 watt/cm ° C2 which yielded an estimated figure of merit of 6 X 10-4 0 C-1. Most of the Y-As-Se compounds had high Seebeck coefficients and moderately low electrical resistivities. The Y-Sb-Te materials were degenerate semiconductors with power factors of 6 X 10-8 watt/cm ° C2.

Jan 1, 1967

By Walter Miller

DURING the second year of America's active participation in the war the main objectives of the petroleum refining industry were again to provide the four most important product needs for war: 100-octane aviation gasoline, toluene for TNT production, high-quality lubricating oils for the needs of aviation and the armed forces, and petroleum chemicals for synthetic rubber manufacture. All other materials supplied by the petroleum industry took an inferior priority ranking, depending on the degree of essentiality. To accomplish the above objectives the industry initiated and carried on a building program during 1942 and 1943 which will put those two years down in petroleum refining history as the greatest construction years of all time, a record which will hold for decades to come. Led by an estimated total of $900,000,000 going into 100octane and contributory plant investment, it is easy to picture a total of two billion dollars and more going into additional refining-industry plant investment during 1942 and 1943, most of it privately paid for, but a substantial part covered by R.F.C. Government money financing.

Jan 1, 1944

By Felipe Henríquez, Daniel Silva

"Traditionally, the implementation of an automated advanced process controller in any mineral processing complex is a challenge, mainly due to the quality of resources and technologies required, the uniqueness of each control solution and the uncertainty of the engineering hours needed to complete the task. Thus, the use of advanced and proven control technology becomes a key factor when deploying the control strategy. However, success would still not be possible without the presence of common sense, process knowledge and fundamental process data. Minera Los Pelambres, taking advantage of such factors and its accumulated process experience, implemented a novel and successful combination of MPC (Multivariable Predictive Control) and advanced control for secondary grinding and regrinding stages at its copper concentrator plant. In both cases, the control objectives are: being capable of processing a variable feed from the upstream process while at the same time avoiding to become a process bottle neck and yet, maintaining an adequate product quality (in terms of size distribution) to the process downstream. Additionally, for the case of the vertical regrinding mill (vertimill), the control system should also be capable of keeping an adequate circulation load and making an efficient use of the available grinding power. In either case, extending hidrocyclones availability while maintaining their performance is a must, since both factors are required for process and maintenance purposes. Thus, the process control problem becomes one with a multi-variable type of process with multiple control objectives to satisfy simultaneously. In trying to solve it, many mineral processing operations have implemented basic or conventional control or even better yet, expert systems. Minera Los Pelambres believes that better and faster results can be achieved using a combination of MPC and advanced control. Such strategy was successfully implemented, reducing considerably process variability while maintaining high throughput and keeping the process well within constraints limits. Their control philosophy, implementation process, main results and their key performance indicators are discussed here."

Jan 1, 2014

Four taconite plants were studied to establish the extent of hazard to plant personnel which exists based on long-term exposure to noise. The criteria for evaluation include the 90 dBA and 85 dBA summations of partial exposures. Data from extensive interviews were used to determine all work stations or locations which employees occupied and how much time they spent in ach location in a typical working day. Noise level measurements at every designated location were then made. By means of a computer program, these time and noise level data were us d to find the optimum noise reductions which would be required throughout each plant to meet both noise criteria. Subsequently, each plant was examined in detail so that the apparent sources of noise for each of the locations requiring noise reduction could be delineated. In tabular form, this report presents the hazardous locations for each plant, the existing noise level, the optimum noise reduction which would be required to meet the current and proposed laws, and the sources of noise which produce the existing noise level.

Jan 1, 1977

By R. F. Stevens

A laboratory method for examining crude shale oil is described. The method uses only about 500 ml. of sample and a limited number of analytical determinations. Results provide information on the general characteristics and composition of an oil and serve as a basis for comparing different oils. However, the method does not provide for direct estimates of yields of commercial products. Analyses of 10 oils produced in the United States by different methods of retorting and of 10 shale oils from commercial-scale operations in 6 foreign countries are given. The shale-oil-analysis method presented in this paper is based on and employs the same equipment as the Bureau of Mines routine method for analyzing crude petroleum. As shale oil contains groups of compounds not generally found in petroleum, several modifications of the petroleum method that might increase its suitability for application to shale oil were investigated. The modifications included in the present method take into account the apparent poor heat stability of shale oil and the presence of large quantities of olefins and nitrogen compounds.

Jan 1, 1952

By G. R. Waters

NMR360 is developing a suite of chloride-based metals extraction processes, with the first commercial operation scheduled for commissioning late in 2018. It is critical, therefore, that with the introduction of any new technology, that the circuits do not suffer from mechanical failures which will compromise the operation. Although chloride leaching is at atmospheric pressure and relatively low temperature, the main challenge is preventing corrosion, since the high proton activity makes even a small amount of acid behaves as though it were concentrated. An additional challenge in concentrated chloride circuits is the potential for solids precipitation. In this context, therefore, correct valve selection is crucial, and NMR360 has partnered with CGIS to ensure that the Severe Service Valves (SSVs) needed will perform over and above the definitions of the Manufacturers Standardization Society (MSS) of the Valve and Fittings Industry. This paper outlines what the minimum requirements are for SSVs in chloride leaching applications, drawing on five decades of industry experience from one of Canada’s leading valve experts.

By Leslie C. Taylor, Anthony L. Kee

Computational modeling of explosively loaded saturated sand on a suspended plate is an inherently complex problem. In this study a computational method is used to predict the dynamic pressure load/impulse from a buried charge. A fully coupled code modeling the explosive charge, sand and air with a Eulerian mesh and the plate structure with Lagrange elements, such as Gemini-Dyna, is an appropriate computational tool. In water-saturated sand, the loadings are soil and water-transmitted shock and bubble or blast effects depending on the depth and the charge size. The computations provide the capability to determine the total impulse load placed on a horizontal plate on or above the soil due to an explosion in the saturated sand for different burial depths in saturated sand and different plate stand off distances. The following test case will be presented: (a) 4.5 Kg (10 lbs) TNT, 10.16 cm (4 in) depth of burial to top of charge, and 20.32 cm (8 inch) stand off distance (Test 4).

Jan 1, 2005

By K. Rainer Massarsch

"Part 1 of 2 By K. Rainer Massarsch, Geo Engineering AB, Stockholm, SwedenINTRODUCTIONConstruction activities, such as driving of piles and sheet piles, soil compaction or excavation generate noise and vibrations. In populated areas these can have a negative impact on the environment, disturb inhabitants and, under unfavorable conditions, cause damage to buildings and installations. This condition is aggravated by the growing public awareness of environmental issues and the increasing use of vibration-sensitive electronic equipment and machinery in industry. In many countries, environmental regulations are enforced more stringently and limit or even prohibit the use of impact or vibratory hammers. This development has restricted the use of cost-effective foundation methods, such as driven and vibrated piles and sheet piles.Vibration problems are gaining importance in many European countries and extensive research has been performed during the past decade, especially with respect to traffic vibrations (Massarsch, 2004). Significant progress has been made owing to the availability of high-quality field measurements and an improved theoretical understanding of how vibrations are generated and transmitted through soil layers. These findings can also be applied to vibration problems associated with construction activities. However, this information is not yet appreciated by the geotechnical profession and even less by the construction industry.This paper discusses the effects of ground vibrations on the surrounding soil and on buildings, with particular emphasis on the different mechanisms of damage that may occur. Guidance is given on the elements which should be taken into account in an assessment of risks associated with piling projects. A simplified method is proposed for assessing the risk of settlements or strength loss in soil deposits. Limiting vibration levels are presented, based on the Swedish standard, which can be used to assess the risk of damage to buildings. Aconcept to predict ground vibrations caused by pile driving and the mechanisms which control the propagation of ground vibrations, will be presented in the second part of this paper."

Jan 1, 2004

By E. P. Youngman

A new mining law for the Recublic of Polend was promulgated by presiden- tial decree dated November 29, 1930, published in the Journal of Lews (Dzienni stex) No. E, text 654, December E, 1530, and wes to become effective January 1, 1932, in all Polend except Silesie. Its adoption in Silesia wes dependent pon the action of the Silesian Diet. As the new law is considered an im- provement over the old Austrian Mining Lew, which is operative in the Silesian districts of Bielsk and Cieszyn, and the Prussian Kining Law, which is opera- tive in Upper Silesia, no delay in its adoption for Silesin was looked for. This new law codifies the various juridical regulations pertaining to ines existing in different parts of the Polish Republic but does not include legislation with respect to the extraction of minerel oil, especially crude oil. Petroleum legislation was postponed to a later date in order to facili- tate codification in other fields. Koreover, as the oil industry exists in Galicia elone, deley will not be detrimental.

May 1, 1932

By P. G. Comba

Many gold producing states are requiring rinsing of spent heaps to render the leached ore compatible with the environment and are placing restrictions on effluent pa, cyanide, and metals concentrations. Parameters which may affect efficient rinsing of heaps have been investigated by the U.S. Bureau of Mines in laboratory column studies. Rinse profiles for cyanide, metals, and pH as a function of the volume of water passed through the spent ore are presented. Fresh water rinsing of spent ore in columns showed that rinsing of cyanide was not affected by the rinse solution application rate. Interrupted rinsing with a rest period between applications reduced the volume of water required to meet effluent cyanide concentrations. chemical oxidation of the effluent with recycle of the rinse solutions reduced effluent cyanide concentrations and the volume of waste solution generated. Water rinsing was not successful in reducing the alkalinity of the cement agglomerated ore. A dilute acid solution had to be applied after cyanide removal to reduce effluent pa levels to specified limits.

Jan 1, 1992

By R. L. Hopkins, H. T. Rall, H. J. Coleman, C. J. Thompson

Two methods were tested for separating sulfur compounds in certain petroleum fractions into types . Such separation is preliminary to identifying the compounds . Each method involved extraction of sulfides from petroleum sulfur concentrates . In the first method , the sulfur concentrate was reacted with methyl - ptoluenesulfonate to form sulfonium compounds from which unreacted portions of the sample were removed by washing with solvent . The sulfides then were recovered by heating the sulfonium compounds with anhydrous triethanolamine . The second method consisted of passing anhydrous hydrogen iodide into a n-butane solution of the sample cooled in dry ice , whereupon the hydrogen iodide adducted with the sulfides to form sulfonium compounds . These adducts separated as crystalline solids or , more frequently , as glassy viscous liquids . The sulfide was regenerated by adding water to the filtered sulfonium compound and was recovered by steam distillation or by extraction with pentane . These methods have been evaluated , using individual pure sulfur compounds and blends of sulfur compounds . They also have been applied successfully to separating sulfides from sulfur concentrates derived from petroleum fractions .

Jan 1, 1964

By Dave M. Jakelski, Gerhard W. Heinrich, Peter F. Wells, Daniel F. Suarez, Jamie B. Beauchamp

"A need for increased copper concentrate production and for less nickel contamination in that concentrate at Falconbridge's Strathcona Concentrator during 1993 required the installation of a third flotation column and improvements in the operation of the existing circuit. Innovations in wash water distributor and launder design were fundamental in achieving objectives on a new 3 meter diameter column. Minnovex plug-type spargers were tested on a 2.1 meter diameter column in order to reduce maintenance requirements. The paper details the measures taken to enhance column flotation circuit performance and the results obtained.IntroductionFalconbridge's Strathcona Mill receives 10% of the ore feed from a rich copper zone in the Strathcona mine. This ore typically grades 7% copper and 1 % nickel and, because of its high copper content, it is processed in a separate circuit ('C' circuit) which consists of conventional grinding, rougher flotation with the concentrate being treated with lime to pH 12.3 and cyanide followed by column flotation. The columns are operated with mechanical flotation scavengers and the scavenger concentrate is returned to the column feed. Testwork conducted in 1991 showed that the original flotation column (Column 2) could only produce 5.5 mtph of concentrate with less than 0.5% nickel (Figure 1).Between 1991 and spring of 1993, production was increased at times by open circuiting the scavengers. Metallurgical improvements were obtained by improving the wash water distributor of Column 2 and by wash water sprays in conventional cells (1 ). However, the scavenger concentrate assayed 0. 7 -0.8% nickel and was not acceptable for long term operation. When Copper ore production targets were significantly increased for 1993, it became clear that an additional flotation column was required. The new flowsheet employs mechanical scavenger cells on the column tails as in Column 2 circuit (Figure 2). A -parallel configuration was chosen as pulp solids fraction has been shown to be a critical variable and the second column in series would receive a lower density feed."

Jan 1, 1994

By R. Moreau, V. Uspenski, K. Messadek, Y. Delannoy

Experiments and numerical simulations have been carried out to investigate the properties of quasi-2D turbulence. A new mercury model experiment has been built and tested in a uniform magnetic field up to 6T, (Ha~ 1000), ensuring a better two-dimensional behaviour than earlier versions (Alboussiere et al., 1997), limited to 0.2T. The quality of the experimental results has been improved in order to get wave number spectra (instead of frequency spectra) and higher signal over noise ratio (due to the higher magnetic fields). In parallel, some two-dimensional "direct" numerical simulations were performed using a commercially available code to solve a 2-D motion equation involving a source term to model the Hartmann layer. This term is derived from the condition of closure of the electric current, which allows to transfer the Hartmann effect into the 2D-core flow without simulating the layer itself (Sommeria & Moreau, 1982). No subgrid scale modelling is needed in such a two-dimensional situation where most of the energy is carried by the large scales.

Jan 1, 1999

By C. F. McCarroll

[Laboratory research and, control in the production an. utilization of petroleum and it 3 products have expanded greatly during the past decade, and much of the routine control and experimental equipment now rewires the constant daily use of liquid mercury. In spite of this ;;renter use, very little consideration has been given to the hazard that might be occasioned by the toxic vapors of mercury unavoidably spilled' of otherwise exposed to the atmosphere during the normal procedure of laboratory open at ions. A simple visual examination ).'.' son-,, r° the laboratories reveal the presence of a considerable quantity of mercury in the cracks of floors, on work tables, and on ark, around equipment stands. Usually this mercury is contaminated with oil3/ and dirt so that it remaining in a finely divided state and a ;mall amount pre presents a relatively large surface for evaporation. Since :mercury shows measurable volatility at a temperature v,.^ lo.! 5o F., mercury vapor will be present in, the mercury _3 exposed promiscuously.]

Jan 1, 1939

By Stanton L. Tainter

When the disruption of gold mining stopped the usual source of siliceous flux needed by copper smelters , sandstone copper deposits in northern Arizona offered possibilities as a source of the flux during the war emergency . The Federal Geological Survey , while making a comprehensive survey of sandstone copper deposits , investigated the Warm Springs mining district in northcentral Coconino County in August 1943. A month later , J. H. Hedges , chief of the Tucson Division , Mining Branch , Bureau of Mines , examined the operations in connection with an application for an access road . Both investigations concluded that the district , as an emergency source of copper-bearing siliceous flux , had considerable merit , provided high prices for copper continued in effect . Early in 1944 , V. M. Ryan and S. B. Atherley requested assistance from the Bureau in exploring various deposits on their property . The Bureau / drilled 152 holes , aggregating 3,756 feet , on the Petoskey and Mackin groups of claims . This report is based upon churn drilling done under contract from October 7 to November 25 , 1944 .

Feb 1, 1947

By Robert J. Anderso

Few elements have received more attention and developed greater interest in the last ten years than titanium. The substantially pure metal has been din...ie. cult to isolate, and so far has been little employed oommercially, but the use af alloys and chemical compounds of titanium has increased markedly in recent years. The earlier attempts at preparing pure titanium resulted in various impure forme which, from their metallic appearance, were always mistaken for the metal. Hunter in 1910 isolated pure titanium by the reduction of titanium tetrachloride with sodium. This brief statement is issued by the Bureau of Mines in response to numerous inquiries which have been received concerning titanium. More complete in. formation on the metal may be had by consulting the referenpes appended. The Literature is voluminous and only the more important references are Riven. It has been drawn upon freely in preparing this report; also information was supplied by M. g. Hunter, Arthur Braid, M 1. Schmid, C. M. Johnson, N. B. Hoffman, and de Courny Browne. The pioneer investigator in titanium is A. IL Rossi.

Oct 1, 1922

By Merrill, Charles White

MOST extraordinary of the technical developments in placer gold mining during the last five years has been the rise of the dragline dredge, by which is meant a floating washing plant for auriferous gravel, fed by a dragline excavator. The idea originated in the fall of 1933, when Horace Onyett constructed a floating washing plant to which gravel was delivered by a dragline excavator standing on dry land. Onyett's operation near Oroville, Calif., and another started by H. F. England later on Wyandotte Creek, Butte County, Calif., yielded '75 oz. of fine gold before the end of 1933. Although the first operation was abandoned shortly as un- profitable, the dragline-dredge method of gold recovery soon began to expand at a boom rate. As a matter of interest, the Onyett operation was taken over later by Lord and Bishop, who are re- ported to have succeeded in making it the first financially successful drag- line dredge. In California alone drag- line dredges produced $3,294,970 worth of gold in 1937, and the pros-

Jan 1, 1938

By Yongyong Gong, Qijie Zhai, Zhichen Zhang, Qixin Li, Zhishuai Xu

"Microstructure of semisolid slurry of Al-4.5wt.%Cu alloy was investigated with pulse magnetooscillation (PMO) treatment, the results showed that the PMO treatment can refine the crystal structures of Al-4.5wt.%Cu alloy significantly. The discharging frequency of PMO had a great effect on the solidified structure transformation of semisolid slurry of Al-4.5wt. %Cu alloy, and the primary a-Al particles become much finer and rounder with an increase of discharging frequency. However, over a certain discharging frequency, the grains of primary a-Al become coarse.IntroductionOver the last decade, a lot of attentions have been paid on metal rheoforming process [1-4], since it has higher mechanical properties of formed components, strength to weight ratio and age hardenablity. Nevertheless, semi-solid forming is always performed at high solid fractions (40%-60%), so it has the limitation of viscosity, a tends to be difficult to pour semisolid slurry into the hole of the shot sleeve. Therefore, a series of novel semi-solid slurry preparation methods and rheoforming techniques have been invented, such as, semisolid vibration treatment [5], rheocasting [6], pulsed magnetic field process [7], annulus electromagnetic stirring [8], via ultrasonic vibration process [9], equal channel angular extrusion (ECAE) process [l0] and straininduced melt activation (SIMA) process [11].The electromagnetic field is characterized by its effective grain refinement, green, convenient manipulation and without contamination of melt. The mechanisms of dendrite was fragmentation by electromagnetic field have also been largely proposed [12-14]. The broken dendrite arms then undergo a coarsening process to provide the globular structures and obtain much finer and rounder a-Al particles. When compared with other external electromagnetic techniques, Pulse Magneto-Oscillation (PMO) has obtained more fuvors, owing to narrower pulse width and much lower energy consumption. Furthermore, the PMO treatment can reach finer grains with shorter time treatment [16, 17]. This work aims to study the effects of different discharging frequency ofPMO treatment on the microstructure transition of the semisolid slurry of Al-4.5 wt.%Cu alloy."

Jan 1, 2014

By J. L. Watson

n the U.S., lead has been produced via blast furnace processing for over a century, and the slags from that pyro-metallurgical process have been accumulating on industrial sites over that extended period. Lead blast furnace slags typically contain both lead and zinc compounds in an iron-silicate matrix, and it appears highly likely that such materials will have to be processed in the near future to meet with EPA regulations. Thus it is appropriate to investigate possible processing routes to render the slags non-hazardous and simultaneously to recover metal values to partially off-set the inherent high cost of processing such materials. There are two major processing alternatives: one being pyrometallurgical and the other hydrometallurgical. The research reported here investigates leaching/solution purification/recovery processes for lead and presents experimental data for the treatment of lead blast furnace slags from S.E. Missouri. The results of the research suggest that both lead and zinc can be removed effectively from the slag, and that metallic lead can be recovered directly from the organic extractant utilized for solution purification.

Jan 1, 1995

By J. B. Hiskey

Of the halogens, the gold iodide complexes are the most stable in aqueous solutions. A series of experiments were performed to investigate the kinetics and mechanism of the leaching reaction between gold and iodide. Using a rotation disk technique, the effects of rotation speed, iodide and iodine concentration, temperature, pH and in the presence of different electrolytes were measured. Oxygen and hydrogen peroxide were also examined as oxidants in the iodide system. The first order reaction rate was found with respect to 13 and half order reaction rate with respect to 1-. The comparison of gold leaching between iodide and cyanide is also presented, in which a rate constant of about 2.6x10-9 mol/cm2? sec for 10-2 M I- and 5x10-3 M I2 was obtained. This value is close to that -for typical cyanidation. Cyclic voltammetry experiments were also performed to examine the electrochemical nature of the reaction which will be presented in part II of this study.

Jan 1, 1990