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By C. E. Reinhard

A USEFUL accelerated weathering test should be capable of placing any series of metals quantitatively in the same order of endurance as that noted under a particular set of actual exposure conditions. The development of such a test must necessarily depend to a considerable extent upon data obtained from a wide variety of exposures. This paper offers preliminary data from exposure tests on nine metals placed in 11 locations in the Lehigh Valley, within a radius of 20 miles from Palmerton. The exposure conditions vary from a severe industrial atmosphere to a pure rural atmosphere. The data are offered as evidence of the necessity for the identification and evaluation of the variables of corrosion and as illustration of some of the variations to be considered in the development of a useful accelerated test. It is quite clear, from this evidence, that a useful accelerated test must be versatile to the extent of showing the probable variations of corrosion resulting from differences in atmosphere as well as from differences in the metals. The paper is presented solely with the object of pointing out the wide variations in relative merits of several common metals in resisting corrosion and without any thought of initiating controversy regarding the, merits of particular metals. For this reason the metals are designated only by symbols in the tables and no key is given to these symbols.

Jan 1, 1929

Traditional vat leaching has been done on a batch basis, which involves loading the vats, leaching, drainage, washing, draining again, and unloading. As a result of these many steps and the attendent cost of labor, vat leaching is generally not an economic proposition. Also, like heap leaching, there is a tendency for channeling to occur within the bed, whether the leach solution flow is by percolation upwards or downwards. No doubt experimenters over the decades have been enticed by the idea of fluidization induced by upward flow through the ore bed. If the bed could be fluidized, then a continuous flow of material could be set up, dispensing with the high cost of loading and unloading the vat. A quick calculation of solution flow requirements, however, soon reveals that the volume of constant liquid movement necessary to sustain fluidization is prohibitive from a power and cost standpoint. The premise of the Mackie Vat Leaching Jig (MVLT) concept was that the large volume of liquid flow required for fluidization could be achieved instantaneously, and that during this small element of time, the solids would flow under the influence of the hydraulic gradient in the vat. If this procedure could be repeated in a cyclic manner, then a steady-state condition could be set up. Experiments in the laboratory demonstrated that solids flow could be achieved in this manner.

Jan 1, 1991

By R. H. Mozley

It is not my intention in this paper to review recent developments in the mineral processing industry which might fall under the above heading, but to refer to some of the research that I have done over the past 25 years or so. To begin with then, my student days at the Camborne School of Mines, the year 1952. Equipment from the last century was still in everyday use at the local tin mines. At South Crofty Ltd a steam beam engine 100 years old was pumping mine water from 2000 feet, the motive force being conveyed from surface to the pump at the bottom of the mine by a 14 inch square pitch pine rod joined with forged iron straps, steam winders were still in use, and in the mills, stamps ground the ore, and the cassiterite was recovered by equipment with exotic names like "buddies, kievs, and round frames." And to equip us students for the brave new world, we included in our practical mineral dressing a day's test programme with a Californian stamp -- experience that I am still waiting to put to good use!

Jan 1, 1984

By Pedro Sanchez-Mejorada

Laguna del Rey is the name of a dry lake bed located in the State of Coahuila, Mexico in a semi-desertic terrain typical of the basin and range physiography. Química del Rey, S.A., a subsidiary of Industrias Peñoles, has been producing sodium sulphate since 20 years ago, from brines pumped from the sub-surface of the present playa. The spent brine is used as raw material for the production of magnesium oxide. An extensive, lenticular deposit is found just below the playa. It consists mostly of glauberite (sodium-calcium sulphate) and blöedite (sodium-magnesium sulphate). The glauberite occurs as thin crystals oriented at random and leave many void spaces among them. These intercrystalline spaces are partly filled with mud, but the whole mass of the evaporite is still very porous. A brine that contains in solution ions of sodium, magnesium, sulphate and chlorine occupies the voids of the sponge-like evaporite body.

Jan 1, 1984

By Stephen Taber

INTRODUCTION THE term asbestos, as commonly used, includes half a dozen minerals all having a well-developed fibrous structure, but differing in chemical composition and in some of their physical, properties. In its strict application the name is limited to the fibrous varieties of the monoclinic amphiboles. Commercially, however, the most important of the asbestiform minerals is chrysotile, a fibrous variety of serpentine. About 95 per cent. of the asbestos used in manufacturing is chrysotile, and it commands a much higher price than any of the other fibrous minerals now on the market. Although the production of asbestos has increased rapidly in recent years, comparatively little has been published concerning its origin. The present paper is preliminary in its nature, and therefore does not pretend to exhaust the subject. The ideas herein developed are the result of field investigation, laboratory experiments in the growth of fibrous

Jan 10, 1916

By Gerhard Heinrich

"The composition and the possible utilization of a slag sample from a nickel smelter operation in the Sudbury district were investigated. The sample containing 0.136% Ni, 0.10% Co and 0.29% Cu could be characterized as a fayalit e slag with a sulphide bearing glass matrix. While the fayalite contains most of the Co, Ni is enriched within both sulphides and fayalite. Cu is only present in higher amounts in sulphides or metallic droplets. This, as well as the small grain sizes of the mineral phases, inhibits significant enrichment by mechanical methods. However preconcentration is possible by means of magnetic separation. An effective hydro metallurgical approach proved to be oxygen pressure leaching with sulphuric acid. Accordingly, the method proposed for processing the investigated slags is to combine the normal utilization as coarse construction material with pressure leaching of the fines and the ground upgraded magnetic fraction. Besides the recovery of base metals, the leaching process yields fine-grained residues, which, after addition of CaD, will set to a cement-like material, or can be used as a pozzolanic cement colour. INTRODUCTIONDuring the pyro metallurgical processing of nickel ores, the valuable metals nickel, cobalt and copper are enriched within the sulphide matte, similar to the smelting of copper ores. The resulting waste materials are slags, which may still contain valuable metal contents of up to 0.5% or above . These contents are close to the cut-off grades of some nickel-cop per-cobalt deposits. The methods that are used to recover copper from slags comprise in general further pyro metallurgical treatment, often after enrichment by flotation. Another area of application for such slags is their use as construction material. However, this might cause environmental problems if nickel containing dusts are produced.Based on one example, the characerization and a possible way of complete utilization of nickel smelter slag s as construction materials in combination with partial base metal recovery are described in this paper. The investigated slag sample was obtained from a dump site in the Sudbury district, Ontario. Detailed test series for process optimization were not possible during this study due to the limited available sample size."

Jan 1, 1989

By N. Saracoglu, J. P. Golightly, R. H. Wallis, J. J. Brummer

"In January 1974, the Minerals Division of Canadian Occidental Petroleum Ltd. made the strategic decision to add uranium to its active exploration commodities and through compilation studies selected northern Saskatchewan as the most attractive and cost-effective exploration area in Canada. In August 1974, 100 sq. miles were staked adjacent to Gulf Minerals' Rabbit Lake deposit and east of the Esso Minerals Midwest boulder train. Initial exploration was based on geologic models of the Rabbit Lake deposit.In the summer of 1975, surface surveys delineated radon anomalies which were drilled that winter and found to overlie anomalous concentrations of uranium in the regolith which forms the upper unit of the crystalline basement. Within the crystalline basement, one hole intersected graphite and pyrite with anomalous nickel-cobalt-arsenic. Geochemical and radiometric surveys followed in the summer of 1976. Drilling in the winter of 1977 intersected several zones of graphite and also anomalous, but uneconomic, uranium abundances. Also in 1977, Dahlkamp and Tan (1977) described the coincidence of graphite and uranium at Key Lake and ground EM surveys on CanadianOxy claims detected graphite conductors beneath 250 ft of Athabasca sandstone. Inco Limited joined the project in April 1977 as a 50% partner. The project area was then surveyed using the airborne INPUT EM method, which detected 84 miles of conductors, with associated graphitic metasediments. On the ground these were located with MaxMin surveys, and follow-up drilling located the ""Tent"" Lake uranium zone.In 1978, the Midwest and Dawn Lake discoveries were announced, 7 miles and 2 miles west of the Joint Venture (J.V.) claims; and, in part for this reason, the 1979 winter drilling was concentrated on the deeper west side of the property. Exploration hole 102-79 intersected altered and uraniferous rocks, but stepout holes were barren. Drill hole 153-79 tested an under-snow three-station radon anomaly east of hole 102-79 and intersected 33 feet of 7.51 % U3O8, confirming the disco very of the McClean North zone. The geophysical grid of the McClean North conductor system was extended and detailed a strong, continous conductor to the south, called McClean South. This was drilled in January 1980and hole 1004-80intersected 22 feet of 2.95% U3O8."

Jan 1, 1983

By R. W. Ruddle

The advent of new methods of roasting, “flash roasting and fluidisation”, which are now under development, combined with the use of oxygen-enriched air, may markedly increase the SO2 content of roaster smokes. Skogmo suggests that the production of smokes containing as much as 50 per cent SO2 should be feasible. The use of flash smelting processes may well enable a similar increase in the SO2 content of smelter smokes to be made. In this event the recovery of sulphur would be greatly cheapened and the process might well be much more economic, even if allowance is made for the cost of generating the oxygen

Jan 1, 1953

By K J. Riihioja, E Nozawa

SmartTag is a radio frequency identification (RFID) based technology designed to allow tracking of ore from its source through blasting, run-of-mine (ROM) pads, crushers, intermediate stockpiles and finally into the concentrator. This paper presents current developments and the future direction of the SmartTagÖ ore tracking system, as well as presenting some case studies. Successful applications of the SmartTag system have encouraged development to allow the system to be used in a wider variety of plants, in particular plants with finer crushing and screening stages. This presented Metso with a number of technological challenges, including RFID tag and antenna design. By reducing the traditional RFID tag diameter from 60 mm to 20 mm the RFID tags can now successfully pass through a secondary crusher. The new smaller RFID tags (referred to as mini RFID tags) have been used in some Process Integration and Optimisation projects with very promising results. The results indicate that the miniature RFID tags have a higher survivability to blasting and through secondary crushing stages. Extending ore tracking further through the process allows more reliable linking of spatial data with time based process performance. Metso is looking at developing even smaller micro RFID tags, and is also investigating other applications for the SmartTag system, including ore tracking from the original source to the final destination (ie from the mine, through the plant and ports to the customer).

Sep 26, 2011

By Lawson F

Chrome chemicals are commercially produced by the alkali roasting of the chrome-bearing ore chromite with sodium carbonate. In order to ascertain the influence on the extent of reaction of the replacement of Mg(II) for Fe(II) in the chromite spinel structure and the presence of acidic oxides in the gangue material, a series of roasting experiments was conducted using chromite materials from a number of different locations. The roast feeds and products were chemically analysed and the major compounds identified using X-ray diffraction and scanning electron microscope techniques.Mg(II) replacement for Fe(II) in the chromite structure does not appear to restrict the amount of "available" chromium for reaction.Under the test conditions, namely an atmosphere of pure oxygen, finely ground chrome-bearing material, a roast temperature of 950°C and the stoichiometric amount of sodium carbonate to react with the chromite, the yield of water-soluble sodium chromate was able to be expressed as %yield = 104.5 -1.58 × %AI2O3 - 2.23 × %SiO2 for chromite samples containing alumina in the range 7.8 to 27.8 per cent and silica in the range 2.9 to 7.4 per cent.

Jan 1, 1984

By E. Gervais

"In today's marketplace, heavy competition between materials is the norm. This is particularly true f or the base metals, which are being increasingly challenged by new or improved materials in all traditional applications. Current usage of base metals results from a combination of a metal's intrinsic properties, and technology. The future of the base metal industry rests with innovative, high-quality product development, its ability to take advantage of the results of worldwide, massive material R&D investments, and with the dynamism and effectiveness of its market development programs.The ZA casting alloys program is an illustration of the zinc industry’s efforts to protect and expand its market position in the casting field through state-of -the-art technological developments. The market potential f or these advanced engineering alloys is substantial, and their impact on traditional zinc die casting alloy consumption is particuarly important. The ZA alloys, in offering increased performance through zinc castings produced at low cost and by a wide range of moulding processes, have unlocked a multitude of new end-use applications.Following a review of the development of ZA alloys, of their key properties and of their performance characteristics, the numerous challenges that the alloys present to the zinc industry and to the R&D community are discussed.IntroductionZinc is anodic to steel and has a low, uniform rat e of corrosion; it has a low melting point, can be cast with precision , and is readily finished. In addition to its use in protecting steel and in the production of a wide range of castings, zinc is employed : (1) to produce brass, high-strength aluminum alloys and magnesium die casting alloys, (2) in the wrought state for coinage and in building products, particularly as roofing materials , and (3) as an oxide, in the rubber industry, in ceramics, glass, cosmetics, pharmaceutical products and as the starting materials for many chemicals.Zinc die castings are produced with accuracy at high speed, at low cost, are easily finished and have excel1ent mechnical properties . Car fuel economy, changes in automobile styling, competition from other materials, increased sophistication of design and miniaturization have all led to a dramatic change in the volume of zinc consumed for die-casting applications. This has been particularly notable in the United States. Throughout the 19505 and the I960s, casting was the fastest growing major use of zinc; it was firmly established, accounting for 35% of the total zinc consumption(1), By 1983, the volume of zinc being purchased for casting applications had dropped to less than 20% of all zinc consumed in the United States. In the western world(2), consumption for zinc casting application s is currently at about 15%; being nearly equal to the zinc consumed by the brass industry. Coating applications dominate with a consumption of more than 40% of the total market."

Jan 1, 1987

By Weller KR

Completely dry or completely wet materials are comparatively easy to screen, but materials with moisture contents between these two extremes can present varying degrees of difficulty. The presence of moisture can impair the performance of a dry screening plant in a number of ways: ò agglomeration of fine undersize particles onto larger oversize particles, resulting in the fine particles being misplaced to the oversize; ò increasing attractive forces between particles that hinder stratification and particle presentation to the screen; and ò blinding of the screen apertures caused by fine moist particles clinging to the screen which reduces the effective aperture size and the open area of the screen. Test work on full-scale screens has shown that the agglomeration of fine particles onto larger particles only occurs once the equilibrium moisture content of the ore is exceeded, and that the quantity of adhering fines present is proportional to the surface area of the larger particles. An -adhering fines screen model has been developed from this work, and by using relationships derived between the model parameters and feed moisture content, the effect of changes in feed moisture on both product quality and operation of iron ore dry screening plants is predicted.

Jan 1, 1993

By D Connelly

Quartz deposits are common in nature but the presence of quartz suitable for yielding high purity quartz is exceedingly rare. This paper describes a test work study on producing high purity quartz (HPQ) product to meet the tight product specifications of greater than 99.97per cent, including four and even five nines, for uses including, lighting and fibre optics and modern-day high efficiency solar panels. Due to demand in renewable energy applications the market for high purity silica solar panels known for their increasing efficiency and durability is rapidly growing. Demand continues to rise for the use of high purity quartz in semiconductors, electronics, imaging and sensor markets. Microelectronic components are created by chemically fabricating wafers of semiconductors such as silicon to obtain the desired transport of electrical charge and control of the current. The production of silicon metal from high purity quartz has been designated a Strategic Mineral by the European Commission and by the US Department of Justice due to the growing significance of this metal in various industries. The subsequent processing of quartz is the key step to adding value and aiding technological advances. Overall, the high purity quartz market is a highly secretive, specialised market with increasing opportunities for stakeholders. The attempt to produce HPQ in this work was carried out using an Australian quartz ore following a typical HPQ process flow sheet. The unit processes included primary crushing, scrubbing, magnetic separation, flotation, acid leaching followed by hot chlorination. The results indicate that grinding of quartz requires specialist equipment due to the hardness and extreme abrasiveness of the ore leading to additional iron contamination in the ground ore. The critical impurities were aluminium, iron, sodium, potassium, lithium, titanium, zircon, calcium and magnesium. The chemical refining was found effective. The hot chlorination process needed to be done at 1200°C in a chlorine – hydrogen chloride gas atmosphere. The risk of any gas being released during this stage is very serious and only specialist companies should and can carry out this step. More recent studies reported many new options that appear to facilitate the production of HPQ with the requisite purities more easily, but costly equipment along with highly trained operators are required and hence unlikely to become available in standard metallurgical laboratories any time soon.

Sep 1, 2024

By Luis Elek

DEVELOPMENT of the cement industry in Mexico began some 40 years ago. It has gradually reached great importance in the economic life of the country and has contributed greatly to the technical and economical advances which have been so noteworthy, particularly during the last 15 years. From a modest start, the industry now comprises 18 cement-producing plants having a potential annual capacity of approximately 14 million bbl. About half the plants were built and equipped with secondhand machinery during the last world war when no new machinery could be procured. They will hardly attain full production before being modernized and reconditioned, a job now under way in several of the plants. At present, the yearly consumption is only about 8 to 9 million bbl but is steadily increasing. This is only a fraction of the cement consumed in the U.S.A., which is about 250 million bbl per year, although on the basis of consumption per capita per year, the figure is 1/3 bbl for Mexico and 1 2/3 bbl for the U.S.A. Cement consumption in Mexico is well above the average of all other Latin American countries, with the exception of the Argentine, and considering the potentialities and undeveloped riches of Mexico, the road construction and irrigation works, it is fair to assume that the Mexican cement industry will still prosper and expand in spite of temporary setbacks in the future caused by local events of economic or political nature. Portland cement is manufactured by burning a mixture of raw materials, one of which is mainly composed of calcium carbonates and the other of aluminum silicates. The most typical materials answering this description are limestone and clay, both of which occur in Mexico in many varieties. To be usable for cement manufacture limestone should contain at least 77 to 80 pct calcium carbonate. Lower grade limestone can be used for cement manufacture only if the lime content is increased by the beneficiation process, which has not yet been adopted by the Mexican cement industry. Most of the limestone used by Mexican cement plants has a calcium carbonate content of 90 to 95 pct and therefore requires addition of one or several correction materials. A typical composition of raw mix for cement manufacture is 85 pct limestone and 15 pct shale, clay or volcanic materials. Occasionally it is necessary to add a smaller amount of sand or other siliceous material to increase the silica ratio in the raw mix. Likewise, it is sometimes necessary to add 1 or 2 pct iron ore to facilitate fusion in the kiln and to obtain proper relation between alumina and iron oxide. After calcining and

Jan 1, 1953

By Terry A. Lee

The grade of mineral resource estimates underpin all major economic considerations of mining prospects. While there are reporting requirements to satisfy when stating a mineral resource estimate, an examination of NI 43-101 style reports suggests that authors believe that there are a number of ways of addressing these requirements. As a reader of these reports, some processes are helpful and others are not so in getting a real appreciation of how realistic is the mineral resource estimate. Critical to the quality of the mineral resource estimate is how realistic is the economic mineral concentration component. In many cases, this parameter is called grade. The industry experiences increased difficulty in achieving realistic grade estimates as the sample grade variability increases. The level of transparency in a mineral resource estimate is very much a function of the competence of the author. An objective presentation of the critical data, such as grade sampling variability can assist a reader in determining if the geology of the mineral concentration is adequately understood and how realistic is mineral resource grade estimate. This paper has considered 75 NI 43-101 style reports released in the past 2 years. The review demonstrates features that were helpful in determining how realistic the mineral resource grade estimate is. If there is insufficient transparency in a report, there is a high probability that the mineral resource grade estimate will not be realistic.

Apr 1, 2005

By Luis Elek

DEVELOPMENT of the cement industry in Mexico began some 40 years ago. It has gradually reached great importance in the economic life of the country and has contributed greatly to the technical and economical advances which have been so noteworthy, particularly during the last 15 years. From a modest start, the industry now comprises 18 cement-producing plants having a potential annual capacity of approximately 14 million bbl. About half the plants were built and equipped with secondhand machinery during the last world war when no new machinery could be procured. They will hardly attain full production before being modernized and reconditioned, a job now under way in several of the plants. At present, the yearly consumption is only about 8 to 9 million bbl but is steadily increasing. This is only a fraction of the cement consumed in the U.S.A., which is about 250 million bbl per year, although on the basis of consumption per capita per year, the figure is 1/3 bbl for Mexico and 1 2/3 bbl for the U.S.A. Cement consumption in Mexico is well above the average of all other Latin American countries, with the exception of the Argentine, and considering the potentialities and undeveloped riches of Mexico, the road construction and irrigation works, it is fair to assume that the Mexican cement industry will still prosper and expand in spite of temporary setbacks in the future caused by local events of economic or political nature. Portland cement is manufactured by burning a mixture of raw materials, one of which is mainly composed of calcium carbonates and the other of aluminum silicates. The most typical materials answering this description are limestone and clay, both of which occur in Mexico in many varieties. To be usable for cement manufacture limestone should contain at least 77 to 80 pct calcium carbonate. Lower grade limestone can be used for cement manufacture only if the lime content is increased by the beneficiation process, which has not yet been adopted by the Mexican cement industry. Most of the limestone used by Mexican cement plants has a calcium carbonate content of 90 to 95 pct and therefore requires addition of one or several correction materials. A typical composition of raw mix for cement manufacture is 85 pct limestone and 15 pct shale, clay or volcanic materials. Occasionally it is necessary to add a smaller amount of sand or other siliceous material to increase the silica ratio in the raw mix. Likewise, it is sometimes necessary to add 1 or 2 pct iron ore to facilitate fusion in the kiln and to obtain proper relation between alumina and iron oxide. After calcining and

Jan 1, 1953

Existing fluid flow techniques may be readily applied to the design of ranges for seam gas drainage. The Reynolds number characterises the flow regime within the pipe and it can be used in conjunction with data on absolute pipe surface roughness to determine the system friction factor. The application of the solution to the isothermal compressible flow equation utili- sing Moody friction factors and the concept of equivalent length of pipe for fittings and valves provides a practical method for sizing gas ranges. The physical capacity of a range can be decreased by the existence of significant quantities of water in the range and also by the ingress of air into the system at poor pipe joints etc. Both problems can be elimin- ated by adequate attention to design detail.

Jan 1, 1982

By Stephen E. Erickson

MORE and more hydrocyclones are being installed in beneficiation plants. This recent rapid increase is of special interest in the history of beneficiation, since development of the hydro- cyclone appears to have swung in a circle. To avoid any chance of confusion, it would be well first to review the accepted definitions. The size of a cyclone is expressed as the diameter of the cylindrical section. Size of the inlet orifice- which may be circular, square, or rectangular- is expressed as a diameter, or as width and length, or as an area (in square inches). The angle of a cyclone is expressed as the total included angle. The overflow or finest classification fraction leaves the cyclone through the vortex finder. The underflow or coarsest classification fraction leaves through the apex opening.

Jan 8, 1957

By T. D. Wheelock

The effect of various flotation depressants and surface treatments on the floatability of coal derived pyrites in the presence of XIBC was investigated with a modified Hallimond tube microflotation cell. The floatability of pyrite particles which had been cleaned with hot dilute (5%) hydrochloric acid was relatively large. However, the floatability of such particles was reduced greatly by the addition of specific depressants such as calcium hydroxide and also by treating the pyrite with an aerated warm alkaline solution. Although this treatment and these depressants also had some effect on the floatability of coal particles, the effect was much less than on the pyrite particles.

Jan 1, 1979

By Horace V. Winchell

This paper, embodying information acquired by the writer in his work in connection with the Geological Survey of Minnesota, is presented by permission of the State Geologist. Historical.—On November 16, 1890, the workmen of Captain J. A. Nichols, of Duluth, Minn., encountered in a test-pit on the northwest quarter of section 3, township 58, range 18, west of the fourth principal meridian, the body of soft ore now called the Mountain Iron mine. Hard ore, chiefly magnetic, had been known for many years on the Mesabi range, and explorations made by Mr. E. W. Griffin, of Minneapolis, near the falls of Prairie river in T. 56-24 and T. 56-25, and by John Mallmann, at the Mallmann explorations, T. 59-14, had revealed some hard hematite interbedded with quartzite and low-grade soft ore; but this was the first discovery of merchantable hematite on the range. Captain Nichols had been exploring more or less along the range for some two years. To him and to the Merritt brothers, of Duluth and Oneota, who, unshaken in Faith by the discouraging reports of explorers, miners, experts, and geologists, had persevered in the search for ore, great credit is due for the final success, and large rewards have accrued to them already.

Jan 1, 1893