Search Documents

By B. Dubreuil

Arsenical bearing deposits are posing an increasing challenge for the mining industry. In particular, mineral processing of arsenical sulfidic ores for base and precious metals recovery tend to produce problematic arsenical tailings. This arsenic being present as sulphide or oxide, tends to dissolve, contaminating surface and underground waters. To meet the environmental regulations, it is often required to stabilize the arsenic in a more insoluble form. Nichromet has developed a new patented technology using vitrification of the arsenic oxide in an economical way, giving a stable solid, well below the environmental regulations upon leaching. This technology involves oxidation of As (III) to As (V), by using a low cost natural oxidizer and transformation of the produced arsenic oxide into calcium arsenate, which is not volatile at the melting temperature of the glass. This technology would be advantageously applied on most cases around the world where sulphide concentrates are oxidized in a fluidized bed or smelted.

Aug 1, 2013

ecent work on decoppering lead is reviewed; CuS is formed rapidly even from dilute solutions of copper in lead. he mechanism of decoppering is discussed, and an explanation for the retention of metals such as silver in lead is dvanced. As decoppering tin appears to be an analogous process, the Cu-Sn-S system is studied at 300¦C. CuS, hich is not, an equilibrium product, is found in decoppering drosses. In the removal of nickel from lead, Ni3pb2S2 formed; preliminary measurements show the equilibrium nickel content to be greater than that obtained by tirring in sulphur. Decoppering bismuth is thermodynamically favoured, but is complicated by the occurrence of uBiS2. The Cu-Pb-S system is the only one of the four studied where the equilibrium can be calculated simply, as ' resence of ternary sulphide or other phases invalidates calculations based on binary data.

Jan 1, 1970

By William M. Kester

INTRODUCTION The Coal Research Bureau of the School of Mines at West Virginia University is presently conducting laboratory-scale tests to determine the technical feasibility of beneficiating pulverized coal and coal fines with high-intensity electromagnetic fields. Interest in magnetic processes for cleaning fine coals was stimulated by results obtained by Yurovsky, et a1 in 1958.1 This work, while not new in concept,2,3 indicated that pulverized coal which had been thermally treated in a rotary drum in the presence of superheated steam and air underwent thermo- chemical reactions. Films of the ferromagnetic minerals magnetite (Fe2O3), hematite (Fe3O4), and pyrrhotite (FeS[3]) were reported to be formed on the surfaces of the pyrite grains associated with fine coal during the foregoing treatment at temperatures ranging from 120 to 360°C. After thermal treatment the coal was magnetically separated in an experimental magnetic device having a field strength of 10,000 oersteds.

Jan 5, 1965

By R. Kanniganti, M. Karmis, C. Haycocks

An extensive review of multi-seam under-mining literature was conducted and a data base of case studies was assembled . A critical review of the design principles outlined in this literature resulted in the compilation of specific design criteria for the design of lower seam mines. Analysis of this criteria demonstrated the necessity for a protocol for the design of unsymmetrically loaded pillars. Such a design criteria was developed using finite element methods for a wide range of possible loading conditions. This design criteria can be utilized for underlying pillar design when the loading conditions can be determined. To facilitate using all the under-mining research results by field/planning engineers a Windows TM based software package was developed. This software package contains a multi-seam tutorial, analytical tools and a case history database. The package is user friendly and fully interactive and supported with extensive on-line help. The package contains numerous case studies of multi-seam mines that can be reviewed to facilitate analyses.

Jan 1, 1996

By John Kemeny

There are many methods used to predict blast fragmentation, including empirical and numerical models, field trials, and experience from ongoing blasting. All of these methods require an accurate measurement or prediction of the rock mass properties. These properties include the characteristics of the rock fractures, including fracture density, friction angle, orientation, length, roughness, fill, etc. They also include the hardness of the intact rock, water content, and other parameters. This paper describes three new technologies that can be used to automatically or semi-automatically obtain rock mass properties: digital image processing, 3D laserscanners, and drill monitoring systems. Each of these technologies is described, including the current state of the art, current limitations, and their future potential. Each of these three technologies has advantages and disadvantages. These new technologies, however, have the potential for providing accurate rock mass information in an automated and real time fashion. This information can then form the basis for a new generation of real-time, database driven blast fragmentation models.

Jan 1, 2004

By Z. M. Zavodni

The stability of waste dumps depends to a great extent on the physical properties of the underlying foundation. These physical properties are evaluated through surface geotechnical surveys, subsurface exploration, and field and laboratory testing. Sufficient information must be obtained to define and assess the strength, consolidation, distribution, topographic and hydrogeologic properties for these materials. Important foundation data collected in the field include: surface infiltration rates, downhole hydraulic conductivities, ground water levels, bedrock structural parameters, soil types and soil thickness. Laboratory testing should identify the classification, strength, moisture content, hydraulic conductivity, attenuation and consolidation characteristics. Summarized in this paper are procedures and typical results of porphyry copper leach dump foundation investigations. Laboratory properties and design recommendations for potenia1 foundation liner materials are described. Back analysis and laboratory foundation strengths are compared. The topographic effect of the foundation on dump behavior is discussed and a foundation pore pressure monitoring experiment at the toe of an active waste dump is described.

Jan 1, 1985

By R. F. Kovar, R. N. Torbin

Foster-Miller has recently developed a new concept for a highly specialized shaft lining system. This innovative shaft lining system uses a continuous slip forming placement technique, lining the shaft from the bottom up such as in a raised bored shaft. Although this part is not unique, the concept is designed to use polyurethane foam instead of concrete for the liner material. Furthermore, the concept is designed to attain rates of advance of 30 m/h (98 fph). The polyurethane foam liner is designed to be thinner (100 mm or 4 in.) than a conventional concrete liner (300 mm or 12 in.). It will eliminate the high cost associated with the erection and operation of an on-site concrete batch plant. The system will be designed to operate remotely, requiring few personnel for its operation. This system (or parts of it) may be appropriate where fast construction speed is required or where a jointless liner is needed.

Jan 1, 1990

By R. Bhaskar, H. Xie

Fractal theory was horn in the mid-1970s. Since then, its application has been spreading day by day, from mathematics and geology to areas such as geophysics, physics and material sciences. In this paper, fractal models are developed to characterize particle size distribution and surface area. Theoretical formulas are derived for the computation of fractal dimensions D (size) and D[s] (surface area). The models developed are applied using experimental data of particle size distribution and surface area obtained from the Microtrac Particle Size Analyzer for dust processed by several size reduction devices. The theoretical models and the experimental data are found in good agreement. The fractal dimensions obtained are D = 1.350 to 1.770 and D[s] = 2.058 to 2.584 for fine coal dust particles (< 15 µm) produced by various size reduction mechanisms. The physical meaning of these fractal dimensions is also related to the dust generation processes.

Jan 1, 1994

By M Scoble, R A. Hall

The mining industry has aggressively sought competitiveness through increased productivity and return on investment. A primary strategy has been the pursuit of economies of scale. This has also been dependent upon the implementation of new technology and systems integration. System integration has been accomplished through the implementation of mine dispatch, global positioning and mine wide communication technologies. These technologies have tended to advance at different rates of development and implementation. The result has been that across the industry, and even within companies, mines are at various stages of operational system re-engineering in these areas, driven by improvements in productivity and operational efficiency. Although this strategy has been successful, little effort has been made to analyse change in operational performance in order to understand and model the effects of scale in a quantitative manner. This paper considers the particular impact of equipment scale, together with potential future trends. It then presents and demonstrates a preliminary method to quantify through simulation the anticipated benefits of economies of scale.

Jan 1, 2003

By W. A. Foster

NINETY years after the Riddle nickel deposit N was discovered in Oregon in 1864, Hanna Coal & Ore Corp. began mining operations. Until 1954 much prospecting and preliminary development work had been done on the property, but no ore had been shipped other than for metallurgical testing. The deposit is being explored by churn drilling and trenching, and a few test shafts have been put down for the purpose of studying the ore in place, determining volume and moisture factors, and gathering bulk samples for pilot plant and smelter tests. In churn drilling, 6-in. casing is driven down 2 or 3 ft behind the drill bit and bottomed at each 5-ft interval. All the sludge for each cased 5-ft interval is dumped through a splitter and one eighth is saved and analyzed. Drillholes are stopped after going through the ore zone and penetrating fresh peridotite in which the nickel content is less than 0.5 pct.

Jan 8, 1957

By W. M. Tuddenham, R. J. P. Lyon

In many areas surrounding the orebodies in mining districts rocks have been bleached and altered by the ore-forming solutions and have been oxidized during later weathering processes. A number of the rock-forming silic-ates have been broken down to clay, sericitic micas and chlorites have been developed, and pyrite may be found hundreds of feet outside the economic limits of the orebody. These halos of altered ground are prime targets used by geologists in many districts to delineate promising sites for drilling. Both in the field and in the laboratory it is often difficult to map these mineralogical changes in the halos in detail without numerous petrologic examinations. The secondary minerals are generally fine-grained, and since conversion of one mineral to another is often progressive, many alteration processes have not proceeded to completion (feldspars to clay to sericite mica). Qualitative detection of these minerals is difficult; quantitative determination is frequently impossible.

Jan 1, 1960

Over the years, numerous hydrometallurgical processes have been proposed as an alternative or complement to smelters for the treatment of copper concentrates. Most of these initiatives met with limited success. Bioleaching is applied commercially for secondary copper minerals heaps and dumps, and bacterial leaching processes are being developed for copper concentrates, although industrial application is still years away. More recently developed processes usually include pressure leaching and/or ultrafine grinding. This paper proposes a new leach process to treat copper sulphide ores or concentrates: the process operates under atmospheric pressure and uses limited concentrations of ferric sulphate as oxidant; the key to the process is the regeneration of the ferric ion, which can be effected in-situ (direct process) or ex-situ (indirect process) using SO2/O2. Examples are presented for the treatment of copper concentrates by agitation leach and of copper ores by heap leaching. Application of the process to copper gold ores and chalcopyrite concentrates is also discussed.

Jan 1, 1999

By Smith P

The past 20 years have seen the replacement of hydraulic control of longwall mining systems by the neater. smaller and better controlled electronic units.Early problems of moisture and other effects on reliability were overcome to see electronically controlled supports chosen for Corrimal Colliery ten years ago. Lessons from Corrimal and elsewhere, with following improvements and sophistication led to wider use as exemplified by Meco and other electronically controlled supports used in more recent installations in New South Wales, Queensland, USA and Czechoslovakia of the total of over 80 electronically controlled support installations worldwide in the past decade. Present work is toward a fully "integrated face" of British Coal by 1993, incorporating the Meco automatic face straightening system already due for practical use in the UK later this year. However the manless face still appears to be some way off although the present minimum crews and close monitoring, including early warning, are promising stages.

Jan 1, 1991

By John Sherbourne

Much valuable scientific research has been performed in recent years on the subject of phase behavior of hydrocarbons. ? 1-11 Engineers employed in petroleum production are interesting themselves in this work as well as in methods of applying the fundamental data available to the solution of their various problems. Recently a number of papers have been published in which applica-tions of phase behavior have been made to specific cases pertaining to critical phenomena.)12-16 Little effort, however, has been made in the literature to show the relation between changes occurring in the critical region and the more common phase behavior, therefore it is believed that a presentation of the fundamentals of phase behavior with reference to hydrocarbons is timely. Study of phase behavior is not new. In the metallurgical field, knowledge of heterogeneous equilibria has advanced tremendously, particularly with reference to solid-solid and solid-liquid behavior. Much is known about vapor-liquid equilibria too, but few engineers are familiar with this subject. ?

Jan 1, 1940

By Wei Yun-Jie

Columnar jointed basalt is a fractured rock, with a lot of small spacing structural planes and poor integrity of the rock mass. On the basis of the comprehensive study of the columnar shape of Columnar joints, rugosity of the fracture surface and the chemical composition of basalt, columnar joints of Bai hetan dam area were formed as a result of the cooling and shrinkage effect of magma. Columnar joints basalt are mainly chlorite, kaolinite, epidote, tremolite chemical reactions and the content of columnar joints are mainly chlorite by slice identification and chemical analysis. Columnar joints basalt showed high uniaxial tension test, low coefficient of friction and high cohesion by indoor physical and mechanical test. Columnar joints rock mass showed high strength and large deformation by field shear test and deformation test. Columnar joints basalt can be used directly as a foundation of dam as long as we follow the rules and reduce disturbance strictly.

May 1, 2009

By Adrian Smith, Debra W. Struhsacker

There is now overwhelming evidence that, despite concerns to the contrary, natural degradation of cyanide and cyanide attenuation by hydrogeochemical processes are capable of minimizing or eliminating potential water qua1ity impacts from heap leach systems. A1 though there was some recognition of these data by the regulatory authorities, for example the initial USEPA modification of cyanide standards to an advisory level, many states have codified standards inappropriate to the clearly site specific nature of heap leach operations. As an overview to this problem, this paper will integrate the theoretical chemical data on cyanide with the observed geochemical behavior of cyanide in the decommissioned heap leach environment. The cyanide species that are likely to exist within an abandoned heap leach system will be identified, and the relative toxicity and potential environment effect of these cyanide species will be discussed. These data will then be used to evaluate cyanide detoxification regulations for decommissioned heap leach projects in 14 states.

Jan 1, 1987

By David Burgess, Hershiel H. Hayden

Experiments at the Somerset mine, Colo., under an agreement between US. Steel Corp. and the US. Bureau of Mines are described. A test was made of the tube bundle method of mine air sampling which was developed for European longwall mines; some 300,000 running feet of tubing provided continuous monitoring at 38 locations. Carbon monoxide concentrations were obtained with standard deviations of less than 1 ppm and oxygen concentrations with standard deviations of less than 0.2%. A base level of CO index (ppm CO evolved per percent 0, removed) was determined to be zero to 20 through most of the passageways of the mine. However, in one working section where the coal was initially hot (about 180°F within a pillar) the CO index was demonstrably higher, 120 trending upward to about 60 when smoke appeared and the section was sealed. The data are discussed in terms of laboratory experiments on CO evolution from coals.

Jan 1, 1977

By Ellis WK, Greenwood-Smith R

A nuclear technique for the analysis of copper in bulk materials has been developed and successfully field tested at Mount Isa Mines Limited. The technique utilises the gamma-ray resonance scattering process. A bulk analyser based on this technique gives a rapid and accurate measurement of the percentage by weight of copper or nickel aver- aged over a large mass of sample, typically 20 kg. The only sample preparation required for accurate analysis is crushing to -2.5 cm. At Mount Isa over 100 mineral samples covering a wide range of rock types and copper contents were analysed. Bulk analyser assays and chemical laboratory assays agreed closely for underground pillar-extraction and geolog- ical chip samples, conveyor belt samples, and finely ground samples from the ore concentrator. For the concentrator samples, the root mean square deviation between bulk analyser and chem- ical laboratory assays was 0.06 wt.% copper. The chemical assay errors for these samples were about 0.06 wt.%

Jan 1, 1975

By William Petruk

Performance assessments are carried out to monitor operations, to evaluate performance and to identify processing problems. The assessment involves collecting and analyzing representative samples from critical points in a flowsheet and interpreting the data. Sample analysis techniques include chemical analyses, mineralogical investigations, mineralogical analyses, and materials balancing. Chemical analyses provide the lowest cost assessment and should be used liberally, particularly in monitoring a process. Materials balances performed on chemical assays for a suite of samples are used as a first step in evaluating a process. Mineralogical investigations are more expensive than chemical analyses but need to be used only at the beginning of mining and metallurgical operations and as a second step in assessing processing problems. Quantitative mineralogical analyses combined with materials balancing provide the most complete performance assessment, but the procedure is expensive. On the other hand, the assessment has the potential of a large payback when carried out where warranted.

Jan 1, 1991

By R. J. Lipp, I. Iwasaki, R. H. Heerema

The presence of calcium ion in iron ore pulps that are upgraded by selective desliming can result in indiscriminate flocculation of both iron oxide and siliceous gangue slimes. In order to overcome this adverse effect, deflocculation by three complexing agents, namely ethylenediaminetetzaacetate (EDTA), sodium tripolyphosphate (STPP), and sodium hexametaphosphate (SHMP), was investigated. The precipitates and complexes of these agents with calcium ion were characterized by potentiometric and conductometric titrations, and the surface properties of quartz and goethite were studied in the presence of calcium ion and of the complexing agents by means of streaming potential measurements and flotation tests. The results were then correlated with selective flocculation tests on an artificial mixture of quartz and goethite. EDTA markedly improved the selectivity of flocculation when added in near stoichiometric amounts, whereas STPP was less effective and SHMP was totally ineffective due to strong, indiscriminate dispersion. Remanent calcium polyphosphates on the goethite surface interfered with the adsorption of starch flocculant.

Jan 1, 1983