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By J Holdsworth, L Sutton, A Lavrinec, D Ilic

Air quality is a big topic of discussion in regional mining communities as well as urban environments situated close to port terminals handling bulk solids. Community perception of poor air quality can significantly affect the reputation of the mining operation and handling facilities. Dust monitoring for regulatory compliance relies on using a handful of accurate but very expensive sensors, usually situated at the boundary, relatively far from the activities that generate the airborne dust. These reference monitors measure dust leaving the site but dust mitigation and management on-site largely relies on operator judgement. At a fraction of the cost, small wireless solar powered units can be used to supplement reference monitors in real-time. Due to their compact nature, portability and low price, these units can be implemented on a mass scale to increase spatial resolution of dust measurements and, more importantly, in much closer proximity to both the dust generating activity and the sources of dust. This can provide valuable insights into the origins and timing of dust generation thus producing datadriven decision-making while minimising subjectivity. Similarly, light detection and ranging (LiDAR) is another supplemental technology that can be used to increase the spatial resolution of dust measurements in near real-time, however, the cost of commercial systems even exceeds that of regulatory monitors. LiDAR also presents difficulties in quantifying dust plume concentrations. This study presents learnings of implementing both technologies for dust emissions management. Several low-cost sensor units and a fast-scanning custom-built 3D LiDAR system operating at a range of 1.5 km with a resolution of 1.5 m were deployed on a surface mine to monitor dust emissions from different activities. The project explores the use of real-time sensor data to quantify LiDAR measurements in parallel with integration into mine planning. The approach can assist in prioritising dust mitigation activities thereby reducing instances of emissions exceedance and minimising water use through databased and targeted application. Demonstrated is an opportunity for a step-change in industry best practice as well as commercialisation and operationalisation of the method across different industries, including future mineral extraction.

Sep 18, 2023

Project delivery in our current market is not as efficient as it could be. Industry at large (both client and consultant), is diligently following the engineer, procure, construct, manage (EPCM) or engineer, procure, construct (EPC) delivery models and not necessarily appreciating the underlying principles that make them the effective tools they were to start with. We often misinterpret project management with EPCM and end up with a literal and superficial interpretation instead of the disciplined risk reduction and business value capture exercise it is intended to be. One of these underlying principles is the project team as resource or commodity depending on which perspective we follow. Some of us understand this principle only too well and succumb to the temptation to take advantage of the imbalance in the understanding of EPCM by selling bodies and hours. Value and return on investment do not always come into the equation. The latecomers and aspirants are struggling with this as a barrier of entry into this lucrative market, since as we all know - people as commodity was becoming and still is a scarce resource. Clients are also waking up and asking why 1000 engineers on the floor are better than 100, when engineering design in all aspects of industry, new technology aside, is mature. Why is it that we start with a clean sheet of paper with every project or that neighbours in the same industry segment and location just happen to have completely unique conditions and circumstances that require totally original design (Local conditions aside)? The answers to this question appear when we explore the role of the project team and how it is structured. We will need to investigate team culture and levers for success. Then we will formulate a business case for a team to be able to follow traditional project management practices with EPCM delivery models but yet end up with an alternative look, feel and result. An outcome where more input is not necessarily better and the client and consultant both are aligned with success measured in dollars and a win-win outcome for both parties.

Jan 1, 2009

By Ahmad Ghahreman, Denver Cowan, Yeonuk Choi

"Testwork was conducted in order to compare the effectiveness of carbon based catalysts while oxidizing a gold-bearing pyrite concentrate under atmospheric conditions. Without the use of a catalyst the oxidation of pyrite was incomplete after 96 hours, resulting in roughly 60% pyrite oxidation. Furthermore the resulting sulphate yield from unassisted pyrite oxidation ranged between 72 and 84%. It is evident that atmospheric oxidation of pyrite is not viable due to slow oxidation kinetics and high sulphuric acid production when using a ferric sulphate media without a catalyst. The effect of two different carbon based catalysts, one Lewatit® AF 5 a new microporous carbonaceous bead, and the second a granular coconut shell based activated carbon, were tested under the same oxidation conditions as the unassisted pyrite tests. After 96 hours, Lewatit® AF 5 assisted oxidation showed approximately 96% pyrite oxidation with a sulphate yield ranging between 26 and 35%, while the activated carbon assisted oxidation reached approximately 100% pyrite oxidation with a sulphate yield between 36 and 37%. Testwork indicated that not only does the addition of a carbon based catalyst greatly improve the oxidation kinetics and lead to almost complete oxidation, the sulphate yield is also drastically reduced, resulting in very high elemental sulphur yields.INTRODUCTION Pyrite is an important sulphide mineral due to its ability to contain invisible gold concentrations up to 132 g/t (Chryssoulis & Cabri, 1990). As a result, ores composed of only a small amount of pyrite still have the ability to contain high gold grades. This refractory gold cannot be accessed via conventional gold leaching processes, such as cyanidation, and additional oxidative pre-treatment is required to liberate the gold, making it more amenable to extraction (Marsden & House, 2006). Current oxidative pre-treatments do exist consisting of both pyrometallurgical and hydrometallurgical processes including high temperature and high pressure leaching within autoclaves, biological atmospheric leaching and roasting. Autoclaves are a proven process reaching desirable recoveries within approximately a 1–2 hour retention time, due to the increased temperatures and pressures, allowing for an increase in dissolved oxygen (Marsden & House, 2006). The typical reaction for pyrite oxidation within autoclaves is presented in Equations 1, 2 and 3."

Jan 1, 2017

By B. Abedian, L. M. Racz, S. R. Berry, R. W. Hyers

"The presented work represents an effort to improve understanding and prediction of turbulent flow inside electromagnetically-levitated droplets. We show that the flow field in a test case, a nickel droplet levitated under microgravity conditions, is a low Reynolds number turbulent flow, i.e. in the transitional regime between laminar and turbulent. Past research efforts have used laminar, enhanced viscosity, and k - E turbulence models to describe these flows. In our study, we compare the RNG algorithm to laminar and k - E turbulence model results. We show that accurate description of the turbulent eddy viscosity µr is critical in order to obtain realistic velocity fields, and that µr cannot be uniform in levitated droplets. In the RNG method there are no characteristic length or time scales associated with the flow, thus allowing such anisotropic features to be captured. We perform calculations and analyses for two cases (1) a small, non-deforming, spherical nickel droplet and (2) a deforming, oscillating droplet. In addition to flow field calculations, we compare numerically-obtained surface tension and viscosity values to those obtained experimentally by the oscillating drop technique.IntroductionElectromagnetic levitation (EML) is a containerless processing technique for conductive materials. Its advantages are the avoidance of contamination or chemical reaction at container walls and the ability to perform long-term experiments in a metastable state. Because of its current limitation to small sample sizes, its primary use is in the laboratory. One application of interest is the measurement of thermophysical properties of undercooled liquid metals [1, 2, 3, 4]. In EML, a sample weighing approximately 1 gram is positioned inside an electromagnetic field generated by alternating currents flowing through an axisymmetric water-cooled copper coil. The coil must be designed appropriately so that thesample levitates in a stable manner.Traditionally, mathematical modeling has been performed in tandem with both earth-and spacebound electromagnetic levitation experiments, in order to determine the effect of the magnetic field on material and flow characteristics [5, 6, 7, 8]. These calculations are important because they allow design, planning, and correct interpretation of experiments. In addition, the calculations are of fundamental scientific interest, as they can be applied to other electromagnetic materials processing applications [9]."

Jan 1, 1999

By S T. L Harrison, J-P Franzidis, M Becker, N Dyantyi, J L. Broadhurst

Gold mining is a major contributor to the South African economy, but is associated with several environmental issues such as acid rock drainage (ARD). ARD is due to the oxidation of sulfides in gold tailings and is characterised by low pH, high sulfate content and elevated concentrations of heavy metals that contaminates scarce water resources and subsequently limits the use of such waters without treatment. Treatment strategies can only be implemented if the acid-generating potential of mine wastes is effectively predicted using common static and kinetic acid prediction tests. The choice of test performed is usually a trade-off between the number of samples, speed of the test, cost of the analysis and level of information obtained. Often the results of these various tests are not consistent with one another. This study uses mineralogy to analyse biokinetic test results of a Witwatersrand gold sample in order to improve the understanding of behaviour of mine wastes under different ARD prediction test conditions.All ARD prediction testing methods investigated in this study showed that the gold sample is considered to be potentially acid forming with net acid generation (NAG) pH of 2.5 and net acid producing potential (NAPP) of 36 kg H2SO4/t. Results of biokinetic test showed that ANC was consumed within four days confirming acid producing potential of the sample with low neutralising potential as observed from acid base accounting (ABA) (4.7 kg H2SO4/t) and mineralogy (4.9 kg H2SO4/t). Results generated in this study demonstrated importance of mineralogy in both understanding the controlling reaction mechanisms playing key role in ARD formation and its capability as a prediction technique. Future work will focus on the application of mineralogy in interpreting the behaviour of mine waste under different static test conditions with a view to assessing their applicability and reliability in estimating potential acid generating characteristics of gold tailings.CITATION:Dyantyi, N, Becker, M, Broadhurst, J L, Harrison, S T L and Franzidis, J-P, 2013. Use of mineralogy to interpret laboratory-scale acid rock drainage prediction tests - a gold case study, in Proceedings World Gold 2013, pp 519-526 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 26, 2013

By C. F. Feng, L. Froyen

"In-situ processes have emerged as new and promising techniques for metal matrix composite fabrication. They offer significant technical and economic advantages over conventional processing. One of the in-situ processing routes that have been used is reactive free sintering of a mixture of powder reactants. However, materials synthesised via this route are always porous because of density differences between reactants and products. An example are the porous Al/(TiB2+Ah03) MMCs obtained by heating powder mixtures of Al+ Ti02+B with Ti02 and B in stoichiometric ratios for forming TiB2• In this study, porous Al/(TiB2+Ah03) composites were further processed by hot-pressing at temperatures above 600°C. This processing cycle was designed so that the composites could be densified. Furthermore, the reaction kinetics of the in-situ processing are studied by means of DSC analysis measured at different heating rates. The activation energies of the three intermediate steps that are involved in the reactive processing for preparing AV(TiB2+Alz03) MMCs are determined to be 923 kJ/mole, 241 kJ/mole and 235 kJ/mole respectively.XRD proved that the hot-pressed products consist of Al, TiB2 and Al203- Properties of the products are assessed by microstructural characterisation (LOM, SEM and EDS), microhardness, Young's modulus and bending tests. The results show that good microstructures, elastic properties and strengths, as well as acceptable ductilities were achieved. For the composition 79.74wt% Al-15.95wt% Ti0z-4.31wt% B, after the reactive free-sintering and hot-pressing cycles, Young's modulus is 105 GPa, bending strength is 509 MPa and maximum strain is 5.0%; for composition 88.73wt% Al-8.87wt% Ti0z-2.40wt% B, they are 89 GPa, 311 MPa and 8.2% respectively. It can be seen that the properties of products can be tailored by adjusting the relative amounts of reactants in green samples. Furthermore, for comparison reasons, Al and a binary system Al-Ti02 were identically processed as the ternary systems. Their microstructures and properties were studied."

Jan 1, 1998

By J M. F Clout

Geological, textural and mineralogical classification of iron ores is routinely conducted by mine and exploration geologists on reverse circulation percussion, blasthole cone and bulk samples for grade control, defining ore and waste, determining lump:fines ratio and predicting downstream processing characteristics. Classification is based on physical hardness, colour, streak and other visual characteristics. However, logging is generally restricted to the five to 20 per cent of chips above about 2 mm. This means that most of the sample is too fine to be reliably logged for anything but colour or streak and the textural types must be inferred from other information. A recently developed software package called æRecognitionÆ allows automated identification and classification of iron ore textural types and gangue on a particle basis in polished section down to 0.01 mm using processed digital images. It is not designed to be used as a routine logging tool, but is applicable where higher definition is required at the resource evaluation stage on selected percussion, drill core or bulk samples. æRecognitionÆ processes data obtained after optical image analysis of fine iron ore samples. It contains several parts, like æRecognitionÆ, æCompositionÆ, æLiberation by Total IronÆ, æLiberation by PhasesÆ and æStatisticsÆ, which allow vast and diverse information to be obtained about the iron ore samples being studied. Identification and classification of the textural type of each particle is performed according to the CSIRO-Hamersley Iron Ore Group Classification Scheme. The recognition procedure encompasses a good knowledge of different ore types and a logical knowledge tree, managing fuzzy boundary problems and the potential for a few different ore types in the same particle to be considered. This new technology introduces strict criteria to make the process of identifying particles more objective. Automated recognition standardises the identification procedure and significantly saves time. It enables users without a strong background in mineralogy to perform accurate texture identification. The æRecognitionÆ package has a modern user-friendly interface and Word compatible output. The combination of all the features mentioned makes the package a convenient tool for detailed studies of fine iron ores.

Jan 1, 2005

By C Rizos

Many of the ‘new paradigms in mining’ and notions of ‘sustainable mining’ have at their core the requirement for reliable, continuous centimetre-level positioning accuracy to enable increased automation of mining operations. The deployment of precision systems for navigating, controlling and monitoring machinery such as drills, dozers, draglines and shovels with real time position information increase their operational efficiency, and reduce the need for humans to be exposed to hazardous conditions. The Global Positioning System (GPS) is the best known, and only currently fully operational, Global Navigation Satellite System (GNSS) providing positioning capability anywhere in the globe, on a continuous 24/7 basis, with accuracies ranging from the dekametre-level to the sub-centimetre-level depending on hardware and operational configuration. Despite this versatility, GNSS cannot satisfy the high accuracy positioning requirements for many applications in mine surveying, and mine machine guidance and control. The reason is that increasingly open cut mines are getting deeper, resulting in a reduction of the ‘sky-view’ necessary for GNSS systems to operate satisfactorily. Yet, to date there have been no viable alternatives to GNSS that can be deployed in mine environments that can meet the challenging requirements in open cut mines.Locata Corporation, a Canberra-based company, has invented a terrestrial high accuracy positioning system known as ‘Locata’ that can augment GNSS with extra terrestrial signals to permit cm-level positioning accuracy even when there are insufficient GNSS satellite signals for reliable positioning and navigation. Locata relies on a network of synchronised ground-based transceivers that transmit positioning signals that can be tracked by suitably equipped user receivers. Hence Locata can be considered a new type of ‘local constellation’, able to provide high accuracy positioning coverage where GNSS fails. This paper introduces some of the technical aspects of this Australian technology and describes tests conducted by Leica Geosystems over the last few years at Newmont Boddington Gold in Western Australia. A recent news announcement by Leica Geosystems (12 January 2011) has confirmed that their new mine management system will have combined GNSS + Locata positioning capability – the first commercial product that integrates GNSS and Locata capabilities into a single high accuracy and high availability navigation device for open cut mine machine automation applications.

Nov 22, 2011

By F. Qunfei, W. Laijun, X. Lyu, A. Cosmos, L Huijuan, Z. Jinggang, G. Yao

In this paper, four cyanide-utilising bacteria strains were isolated from a gold mine tailings pond, in the Hexi gold mine (Shandong), China. Based on the analysis of 16S rRNA gene sequence, four strains were identified as Aeromonas hydrophila strain C1, Bacillus mojavensis strain C3, Shewanella oneidensis strain C2, and Aeromonas media strain C4. Based on the cyanide detoxification efficiencies results of the four strains, Bacillus mojavensis C3 had the highest detoxification rate and was selected to assess its efficiency to detoxify cyanide in gold mine tailings at different pH (9.5, 10.5, and 11.6) using cyanide as the sole carbon and nitrogen sources. Strain C3 was capable of detoxifying 46.5mg/L of cyanide-containing gold mine tailings at all tested pH ranges at 30oC, 196 rpm after 15 d. The amounts of cyanide detoxified were 87.5%, 84.1%, and 73.5% at initial pH 9.5, 10.5, and 11.6, respectively. The highest cyanide detoxification was observed at pH 9.5. The viable cells growths in the samples were 5.7E+09CFU/mL, 4.9E+09CFU/mL, and 2.7E+09CFU/mL at pH 9.5, 10.5, and 11.6, respectively. Free ammonia concentrations were observed as a byproduct of the biodetoxification process. The residual ammonia concentration in the sample was observed at 0.35 mg/L, 0.33 mg/L, and 0.62 mg/L at pH 9.5, 10.5, and 11.6, respectively. The highest residual ammonia concentration was noticed at pH 11.6. The amount of cyanide removed by mixed culture strains C3 and C4 was 94.6% and showed a residual free ammonia concentration of 2.6mg/L, as biodetoxification byproduct after 120 h. The pure culture Bacillus mojavensis strain C3 and its mixed culture strains exhibited higher potential to detoxify cyanide-containing gold mine tailings at alkaline pH values and could be cultivated to detoxify gold mine effluents at large-scale. Keywords: Bacteria strain, cyanide, detoxification efficiency, gold mine tailings

Jan 1, 2020

By J. H. East, D. Harrington

Fires in metal mines have resulted in some of the worst disasters in American mining history insofar as loss of life is concerned. One fire caused the death of 163 miners and individual less spectacular fires have cost the lives of scores of workers. Metal mines are often very deep, and the men working on numerous levels far removed from direct communication with the surface. In many instances they cannot be warned quickly of an emergency or a mine fire by telephone or other usual method of communication, or by messenger, flashing lights, gongs, sirens, or whistles. Telephones are not paricularly effective as a means of warning unless placed at all strategic points and with attendants always on duty; though telephones well placed have a definite value in any well-pla.mied emergency procedure in mines of all kinds. Messengers are slow and men working in remote parts of a mine would not receive a warning quickly enough. Most metal mines are not electrically lighted, except at or adjacent to shaft stations and in principal haulageways, and this limits the effectiveness of flashing lights. Electric gongs and sirens or whistles have been tried as warning signals, but the sound is quickly deadened and does not travel upward into the stopes, especially those of an extensive volume. Shutting off the compressed air is by no means satisfactory as a warning, as not infrequently it is stopped accidently, so that it loses its value as an alarm. The introduction of water into compressed air lines is undesirable as a fire warning and necessitates considerable care, especially in deep mines; pressure-reducing valves must be provided to reduce pressure that otherwise would break connections or split the pipe. A quick, effective method of warning miners underground of the existence of an emergency requiring them to leave the mine immediately, such as a fire on the surface or underground, is provided by the introduction of stenches in the compressed-air lines. This method of warning is by no means experimental, inasmuch as it has been used successfully for many years in

Jul 1, 1943

By A. Thatcher, C. Day, C. Meyer

The purpose of this paper is to provide general information about the bioaccessibility of metals and specific information about the use of bioaccessibility in risk assessments (human health risk assessments [HHRA] or ecological risk assessments [ERA]) and a list of sites where regulatory agencies have approved the use of bioaccessibility data in risk assessment. The memorandum also cites current U.S. Environmental Protection Agency (USEPA) guidance as well as state specific guidance where applicable. BRIEF HISTORY OF METAL BIOACCESSIBILITY TESTING AND METHODS The bioaccessible fraction of a constituent is that fraction that dissolves or desorbs from its matrix (e.g., soil) in the gastrointestinal tract and is available for absorption (USEPA 2007a; ITRC 2011; ITRC 2017). This is different from the bioavailable fraction, which is the percentage of the amount of an element that an organism is exposed to that is absorbed by that organism during a given time under defined conditions (USEPA 2007a). The bioaccessibility factor is the percentage of a metal that is potentially available for absorption and, therefore, is a conservative estimate of the bioavailable fraction since all that is available for absorption may not ultimately be absorbed into the organism’s system. Currently, there are two main techniques for estimating bioavailability of metals within a medium: in vivo animal studies (time-consuming and often cost-prohibitive), and in vitro tests that simulate human, or animal digestion in a laboratory setting. In vitro and in vivo test methods and protocols have been extensively evaluated by numerous researchers (Ruby et al. 1996; Rodriguez and Basta 1999; Sips et al. 1998; Sips et al. 2001; Molly et al 1993; Oomen et al 2002; Kelley et al. 2002; Oomen et al. 2003; Furman et al. 2006; Drexler and Brattin 2007; Basta et al. 2007; Wragg et al. 2009; Wragg et al. 2011; Chaney et al. 2011; Bradham et al. 2015; Bradham et al. 2018). The most recent scientific literature demonstrates that protocols used to estimate the bioavailability of metals to mammals also predict bioavailability of metals to birds as well (Beyer et al., 2016).

Jan 1, 2019

By Jingwei Lou, Bing Li, Suzhen Li, Miao Shen, Jianguo Yu

"As a main impurity in primary lithium metal, magnesium is difficult to remove because of the very close relative volatility of the two metals. Electrochemical refining provides a possibility to completely remove Mg in the LiCl-KCl melt prior to Li reduction. MgCl2 reduction processes in LiCl-KCl- MgCl2 melt were investigated by cyclic voltammetry (CV), square wave voltammetry (SWV), chronoamperometry and chronopotentiometry. Then potentiostatic electrolysis was carried out and Mg (II) ion was reduced onto a liquid lead cathode from the LiCl-KCl-MgCl2 melt at the Mg deposition potential. The results show that Mg ( II ) is reduced in one step with two-electron transfer. The reduction potential of Mg ( II ) was well defined. The reduction of Mg( II) results in Li ( I ) underpotential deposition at 0.2V more negative potential than that of Mg( II) reduction. Therefore, in order to prevent Li ( I ) from codeposition with Mg, accurately controlling Mg ( II) reduction potential during the potentiostatic electrolysis was necessary. Ninety three to 99 % removal rate of MgCl2 was achieved after 8-12 h electrolysis when liquid lead was used as cathode.IntroductionMetallic Li has been widely used in batteries, light weight alloys and in fusion reactors because of its excellent properties. Currently, the only way in industry to produce metallic Li is by electrowinning from molten LiCl-KCl at about 450 °C [l-5]. LiCl-KCl is the only electrolyte used, because they presents a lower eutectic temperature and KCl shows a slightly higher theoretical decomposition voltage than LiCl, as shown in Table l .The produced metallic Li generally contains 1-2 wt% impurities including Na, K, Al, Ca, Mg, Si, etc. [6l, which are derived from the corresponding metal chloride compounds or metal oxide compounds existing in the LiCl and/or KCl raw materials. These impurities have to be removed by subsequent vacuum distillation at high temperatures to meet the requirements for metal Li purity in the final products. Separation of Mg from Li by vacuum distillation is difficult because their relative volatilities are very close, as shown in Table 2."

Jan 1, 2011

By Kuniaki Murase, Tetsuji Hirato, Yasuhiro Awakura

"Electrodeposition of CdTe was studied using aqueous ammonia-alkaline electrolytic baths in which Cd11-and Te1V-ions are dissolving as Cd11(NH3)/+ and Te1vol-ions, respectively. Ca-thodic polarization curves of the baths suggest the presence of strong interaction between the Cd11-and Te1V-ions; electrodeposition of tellurium is inhibited by the presence of Cd(NH3)/+ ions. The interaction makes it possible to electrodeposit CdTe films with stoichiometric composition. Polycrystalline CdTe thin film of about 1 µm thickness was electrodeposited at 343 K from ammonia-alkaline solutions (pH= 10.7) containing TeO32-(<20 mmol dm-3) and Cd(NH3)/+ ( < 60 mmol dm-3) ions. Increasing Cd(NH3)/42+/TeO32- mole ratio or decreasing total concentration of ammonia/ammonium-ion gave flat and smooth crystalline CdTe deposits at constant cathode potential-0.70 to -0.30 V vs SHE at 343 K.IntroductionCadmium telluride (CdTe) is well-known as a compound semiconductor whose band gap, i.e. 1.44 eV, is suitable for solar energy conversion with a photovoltaic cell. Various methods, such as CVD (chemical vapor deposition) and electrodeposition, of preparing CdTe thin films for solar cells have been investigated.Acidic sulfate solutions with a pH of 1-2 are usually employed for CdTe processing by electrodeposition.1-3) The electrodeposition of compound semiconductors is usually achieved (i) at a higher cathode potential than the redox potential of less-noble species, can in this case, and (ii) under the condition of diffusion-limiting current of a more noble species, Te1Y.4) There-fore, a suitable CdII/TeIV concentration ratio in the acidic electrolytic baths, resulting in the deposition of stoichiometric CdTe, is determined by the diffusion-limiting current density of TeIV- reduction, i.e. the concentration of HTeIVO2+ · Since the solubility ofTe1v species HTeIVO2+ in the acidic solutions is quite low, the rate at which CdTe is deposited from the acidic solutions is extremely slow."

Jan 1, 1998

By B C Tanda, E A. Oraby, J J. Eksteen

"Base metal and precious metal deposits are well known for their significant geometallurgical variation throughout the volume of the proven resource. At the metallurgical level, the plant normally processes an upper oxidised layer, a transition zone and a sulfide zone, often leading to different processing techniques for the different zones. A novel processing approach is presented whereby alkaline leaching with glycine is used to leach base and precious metals, using a copper-gold ore deposit as a case study. Glycine is a cheap, non-toxic, non-volatile, highly water-soluble crystalline solid produced industrially in bulk quantities. As a chelating ligand it forms a number of stable glycinate complexes with Ni, Co, Cu, platinum group metals (PGMs), Au, Ag, Zn, Pb, Hg and Cd, with broad stability regions over an extended temperature-pH-Eh range, allowing dissolution of these metals in the neutral and alkaline regions (pH 7–13). It has been shown that this lixiviant system can leach the metals from their oxide, oxy-halide, basic sulfate, carbonate, native and various sulfide forms, including refractory sulfides such as chalcopyrite. Extraction of the metals from their soluble glycinates is easily achieved using a range of solvent extraction and precipitation processes, and the glycine remains stable in aqueous solution for recycle and reuse. Minerals bearing metals in Groups 1 to 8 of the periodic table are normally unaltered. This technology therefore provides a highly selective leaching environment for the extraction of numerous scarce metals of economic interest, with minimal interaction with gangue minerals, whilst using environmentally benign reagents. Problematic leach residues such as jarosites, elemental sulfur and silica gels are averted through this processing approach. This technology allows hydrometallurgical processing that is much less domain-sensitive in the geometallurgical sense, and utilises essentially the same key reagents for the whole deposit.CITATION:Eksteen, J J, Oraby, E A and Tanda, B C, 2016. Developing Robust Hydrometallurgical Processes to Recover Metals from Deposits with Large Geometallurgical Variation, in Proceedings The Third AusIMM International Geometallurgy Conference (GeoMet) 2016, pp 15–20 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Jun 15, 2016

By Jozef Zmik, Sergey Dobatkin, Martin Fujda, George Raab, Libor Kraus

"The present work, likewise, deals with grain refinement of medium carbon steel AISI 1045 having different initial microstructure resulting from thermal and/or thermomechanical treatment (TM) applied prior severe plastic deformation. In case of TM treated steel, structure refinement was conducted in two steps. Preliminary structure refinement has been achieved due to multistep open die forging process which provided total strain Eef ~ 3. Uniform and fine recrystallized ferrite structure with grain size of the order of 2-5 µm and with nest-like pearlite colonies was obtained. The further grain refinement of steel samples having different initial structure was accomplished during warm Equal Channel Angular Pressing (ECAP) at 400°C. The microstructure development was analyzed in dependence of effective strain introduced ( Eef ~ 2.5 - 4). Employment of this processing route resulted in extensive deformation of ferrite grains where mixture of subgrains and ultrafine grain was found regardless the preliminary treatment of steel. As straining increases the dynamic polygonization and recrystallization became active to form mixture of polygonized subgrains and submicrocrystalline grains having high angle boundaries. The intensive straining and moderate ECAP temperature caused the partial cementite lamellae fragmentation and spheroidization as straining increased. The lamellae cementite spheroidization was more extensive in TM treated steel samples. The deformation behavior of for both steel structural state confirm the strength increase; however the work hardening behavior was modified with respect to initial structure of steel prior SPD processing.IntroductionIn the last years, ultrafine grained materials have attracted considerable research interest because they tend to possess high strength without sacrificing toughness and ductility. Microstructural refinement of steel is usually achieved by alloying and/or by thermomechanical treatment process, which modifies phase transformation. Recently, advancement of severe plastic deformation (SPD) techniques provides another efficient access for grain refinement of metals and alloys. The fabrication of bulk materials with ultrafine grain sizes has attracted a great deal of attention over the past two decades because of the materials' enhanced properties [ 1, 2]. In last decade a worldwide effort in manufacturing process to obtain ultrafine grain structures in steels is persisting."

Jan 1, 2011

By G. J. Simandl

"Since the 1980s, China has become the predominant producer of REEs. Recently, it introduced REE export quotas and this started a world-scale REE exploration rush. REE resources are concentrated in carbonatite-related deposits, peralkaline igneous rocks, pegmatites, REE ± P veins, ion adsorption clays, placers, and some deep ocean sediments. REEs could also be derived as a by-product of phosphate fertilizer, U processing, Ti-Zr-bearing placers, and exploitation of Olympic Dam-type sub-type of IOCG deposits. The ideal REE development target would be located in a politically stable jurisdiction such as Canada. REE grade and tonnage, mineralogy, and permissive metallurgy are some of the key technical factors that could be used to screen projects. INTRODUCTIONAccording to the International Union of Pure and Applied Chemistry (IUPAC), the term “rare earth elements” (REEs) encompasses yttrium (Y), scandium (Sc), and the lanthanide series: lanthanum (La), cerium (Ce), praseodymium (Pr), neodymium (Nd), promethium (Pm), samarium (Sm), europium (Eu), gadolinium (Gd), terbium (Tb), dysprosium (Dy), holmium (Ho), erbium (Er), thulium (Tm), ytterbium (Yb), and lutetium (Lu). This definition is used throughout this paper.REEs are subdivided into light (LREE) and heavy (HREE) categories. LREEs include, Sc, La, Ce, Pr, Nd, Sm, Eu, and Gd and HREE include Tb, Dy, Ho, Er, Tm, Yb, Lu, and Y. Promethium (Pm) does not occur in nature. Concentrations of individual LREEs in the upper crust of the Earth are comparable to those of base metals. Even the least abundant REE (Lu) is about 200 times more abundant than gold.The production of REEs, reported in the form of oxides (REOs), for 2011 is estimated at 140 000 t (Figure 1a). Although high technology industries can substitute several REEs with other materials, these substitutes are typically more expensive or less effective than the REEs they replace. A number of countries, including the United States, consider several REEs essential for national security, their economy, and a general reduction in green house gas emissions. The forecasted demand for individual LREOs is much higher than that of HREOs (Figure 2). Dy, Eu, Tb, Nd, and Y are essential for the US economy and subject to predicted supply disruptions (U.S. Department of Energy, 2010)."

Jan 1, 2012

By H Kurth

"The focus of this paper is on measuring the composition to improve mill feed quality to minimise the processing of waste, optimise process performance, reduce processing costs and minimise the generation of tailings.Technologies used since the 1990s in the cement and coal industries for measuring conveyed materials have been operationally proven and effectively derisked. Despite this the acceptance by the minerals industry has been very slow except in iron ore. Real-time penetrative full stream measurement using prompt gamma neutron activation analysis (PGNAA) for multielemental analysis and microwave transmission for real-time moisture analysis provide representative, tonnage weighted dry weight per cent results on a minute by minute basis. Analysis is unaffected by particle size, dust, layering/segregation, mineralogy and belt speed. The technologies are explained and performance examples given. The benefits derived from real-time compositional analysis are predicated upon a good understanding of deposit geology, mineralogical associations, waste to ore interfaces, amenability to mining, metallurgical processes and downstream customer requirements. Processing may include basic preparation in the case of direct shipping ores, minor beneficiation using simple upgrading methods, or concentration using more complex processing systems such as flotation, leaching or many others. The value of real-time data from primary crushed conveyed flows, using analysis of increments smaller than a single haul truck’s load, is very beneficial in process plants aiming to reduce waste processing, increasing feed grades and increasing metal recoveries. Grade variability can be utilised to divert conveyed increments of waste, direct shipping ore (DSO) quality material bypassing beneficiation, and subeconomic material amenable to upgrading diverted for further preconcentration by particle separation (sorting, heavy medium etc). Paybacks of a few months have been commonly achieved where the real-time technologies have been applied in the minerals sector. The paper outlines proven applications and case studies and proposes some innovative applications.Citation:Kurth, H, 2016. Measuring and Utilising Ore Quality Variability Using Real-time On-belt Elemental Analysis to Improve Mill Feed Quality, in Proceedings 13th AusIMM Mill Operators’ Conference 2016, pp 239&ndash;244 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Oct 10, 2016

By A. H. Onur

Spontaneous combustion of coal is a significant hazard in underground coal mines. It causes serious problems for miners for many years after the fact. It threatens workers? lives and causes economic losses for companies. It disrupts coal production and makes it necessary to abandon the main drift where the spontaneous combustion occurred. Coal fires have to be prevented before they occur; otherwise they are very hard to control. Precautions thus have to be taken in potentially risky areas. For coal to spontaneously combust, it needs 3 elements: fuel, oxygen and heat. If one of them is missing, the fire cannot occur. The best way to prevent spontaneous combustion is to prevent contact between coal and air. Coating of the coal surface with an air-proof lining material would be a practical and useful solution to prevent spontaneous combustion of coal. In the scope of this study, a lining material for coating the coal surface was designed at laboratory conditions. Lining material to be used for preventing coal fires should be airproof, cheap, sufficiently strong, have low rebound, be water- and heat-resistant, and easily obtained and applied. It should also be safe for human health when in contact with mine ventilation. By considering these obligations, 3 kinds of gypsum (plaster, satin plaster, molding plaster), as well as lime, cement and fly ash and different mixtures of these materials were applied in laboratory conditions to form a lining material. Samples of lining material were subjected to uniaxial compressive strength tests to determine their behavior against roof loads. Although there is no need to carry any roof load, the lining material has to be sufficiently strong to stay in place on the applied surface. If the lining material is broken, coal and oxygen can react again. Air permeability and curing time of the mixtures were also tested in laboratory conditions. Then the tested mixtures were applied on a wall with a pump to test the applicability of mixtures. After all tests were performed in laboratory, the most suitable mixture was determined as the optimal lining material to prevent coal fires.

Aug 1, 2013

By W. E. Wallace, C. A. Hill, M. J. Keane

"Diesel exhaust particulate material from exhaust pipe scrapings of two trucks, diluted automobile diesel exhaust particulate material collected on filters, and two oil shale ores were prepared for the Ames mutagenrcity assay by dichloromethane OOP ex¬traction, by dispersion into 0.85% saline, or by dispersion into dipalmitoyl lecithin (DPL) emulsion in saline. Salmonella typhimunum TA98 was used to detect frameshift mutagens in the samples. Samples of diesel soot gave positive mutagenic responses with both DCM extraction and DPL dispersion, with the DPL dispersion giving higher results in some cases. The results suggest that possible mutagens associated with inhaled particles may be dispersed or solubilized into the phospholipid component of pulmonary surfactant and become active in such a phase.INTRODUCTIONThe Ames Salmonella/microsome assay (Ames et al., 1975) has been shown to be a useful test for detecting genotoxic properties of various agents. Hundreds of specific chemicals have been screened (McCann et al., 1975), and the test has been applied for many types of environmental samples. Airborne mutagenic agents, for example, have been found in urban air (Chrisp and Fisher, 1980; Hughes et al., 1980; Ro· senkranz et al., 1978), in diesel engine exhausts (Huisingh et al., 1978), and in the by-products of coal combustion processes (Chrisp et al., 1978).Samples of airborne particles are typically collected on membrane filters, and undergo a rigorous extraction procedure with organic solvents and/or ultrasonic agitation (Clark and Hobbs, 1980). Often extracts are transferred to another solvent that is compatible with the assay system. These extraction procedures, while efficient from an analytical perspective, are not physiologically plausible. The questions that present themselves are whether a demonstrated mutagen can be taken up in vivo and whether the process is quantitatively or qualitatively different from the above laboratory procedure (Wallace et al., 1984).When a particle of respirable size is inhaled to the alveolar region of the lung, its first physiological contact is with pulmonary surfactant that lines the inner surfaces of the alveoli. This surfactant is an aqueous fluid containing proteins, phospholipids, and other components (R. J. King, 1982). The principal phospholipid constituent is L·alpha-phosphatidylcholine, beta,gamma-dipalmitoyl, or dipalmitoyl lecithin (OPL) (l. C. King et al., 1981)."

Jan 1, 1989

By K. J. G Hedges

"Once a health based guidance limits for exposure to diesel exhaust have been established, and as part of a multi-disciplinary team, the program for exposure reduction should incorporate the plan-do-check-adjust cycle. Setting a suitably protective (health based) occupational exposure limit (OEL) for diesel particulate matter (DPM) and nitrogen dioxide is a key driver to reduce exposure. It is important to go beyond regulations and reduce exposure to diesel exhaust, DPM, as low as reasonably achievable (ALARA) such as that prescribed under the Australia, Queensland Mining and Quarrying Safety and Health Regulation 2017 where under section 135 Limiting workers exposure, the workers exposure must not exceed the exposure limit applying to the worker for the hazard; and is ALARA. It appears that previously acceptable OELs are no longer safe. Therefore it is important that the internal responsibility system be implemented and the precautionary principle approach be followed, especially as it may be some time before a suitably protective OEL specifically for DPM is in place. One leading multi-national mining company BHP Billiton has acknowledged a significant lag that exists between regulatory action and the level of science that informs health risk. This company is managing exposure to diesel exhaust to as low as technically feasible. This same company that has set an interim target for managing diesel exhaust to 0.03 mg/m3 is achieving these levels which paves the way for other mining companies and general industry including construction. The Occupational Cancer Research Centre 2017 recommends reducing personal exposure to within 0.02 mg/m3 (EC) for underground mining and 0.005 mg/m3 for other workplaces. Controlling DPM is important to prevent cancer however it is also important that that nitrogen dioxide (NO2) be reduced (ALARA) and that careful selection of control technology be considered such as the proper selection of a diesel oxidation catalyst so that the level of NO2 does not in fact increase. The example from BHP Billiton provides a leading practice including using a multi-disciplinary approach and the importance of controlling emission at source and having an auditable diesel emissions based monitoring program in place."

Jan 1, 2019