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By H. H. Uhlig

Soon after general use of stainless steels began, it was observed in practice that certain combinations of factors tended to induce corrosion by pitting. For most applications this was a serious drawback, not so much because the structural properties of the metal were impaired but because of the rapidity with which heavy sections of the alloys were penetrated by small elongated pits. These pits seemed to initiate readily in oxidizing metal salt solutions like ferric chloride and in chloride solu-tions like sea water. It was observed that in sea water pitting was more frequent in stagnant or polluted waters than in highly aerated, moving waters. The steels in these chloride solutions were observed to be sensi-tive to long contact with material such as sand grains or attached bar-nacles. At points of attachment or contact it was not uncommon to discover initiation of corrosion. Pits once begun at contact faces were observed to grow rapidly, usually elongating phenomenally in the direc-tion of gravity until the metal was perforated. Hydrochloric acid and other nonoxidizing acids, on the other hand, were observed to corrode stainless steels generally; the weight losses often were higher, but the penetration less than for the pitting type of corrosion. The causes of pitting, a type of corrosion recognized as character-istic not only of stainless steels but of many additional metals and alloys, are important in corrosion studies. A possible explanation bears prac-tical significance, for once it is known why pits begin where they do and continue to grow after initiation, intelligent direction can be given to diminishing corrosion. This can be done either by some alteration in the composition and treatment of the alloy or by some alteration in the environment. It appears foremost in importance to discover the nature of pit foci, for if initiation of pits can be discouraged their growth will be no longer a factor to be considered. In a multi-component alloy containing many impurities normal to production of such an alloy, each of which may play a part in pitting, and whose corrosion resistance is sensitive to heat-

Jan 1, 1940

By F. Goodarzi

"The nature and distribution of the inorganic components and the concentration of certain environmentally sensitive elements, such as, As, Sb, B, Hr, Cd, CI, F, Mo, Pb, S, and Se, or elements detrimental to the utilization by industry such as B, Na, P and S are very important in determining coal quality. The concentration of elements in coal is controlled by the following factors: (1) frequency of occurrence of partings; (2) nature and habit of occurrence of minerals in coal; (3) environment of coal deposition; (4)rank; (5) geological setting; and (6) weathering.Selective mining of coal can reduce the input of undesirable elements such as As and S by eliminating the part of the seam which is enriched in these elements. IntroductionCoal is a sedimentary rock of plant origin and consists of two components: an inorganic component (minerals) which is formed by influx of clastic sediments into the coal-forming environment and also by activities of groundwater, and an organic component (macerals) which is formed from plant debris deposited in the original coal-forming environment. However, coal is a generic term with a broad range of utilization characteristics. A coal that is attractive for use in one market - such as generation of electricity (combustion) - may not necessarily be acceptable for use in another, such as for production of coke (Davis, 1978).The elements in coal are associated with both macerals and minerals. The elements associated with coal macerals, such as C, H and N are termed elements with organic affInities. The concentration of elements with organic affmities (including B, Br, CI, F, I, S, and Mg) often decrease with increasing ash content of coal (Nicholls, 1968; and Finkehnan,1982). FIgure 1 shows such a trend for chlorine. Some of these elements may also be incorporated in coal maceral as very fine mineral grains (Finkelman, 1982). The elements with organic affmities are often volatilized during combustion and carbonization of coal and emitted in the vapour phase. Emission of some of these elements (C, 0, Br, N and S) is of major environmental concern (Lim, 1979)."

Jan 1, 1994

By E. W. Engle

For several years the Fansteel Products Co. has been engaged in e production and development of various of the rarer metals. It is at present engaged in the commercial production of tantalum, tungsten, and molybdenum in a very high state of purity. The information contained in this paper is partly a general compilation from various sources and partly information obtained as a result of recent years of work in the laboratory of this company. Tantalum, tungsten, and molybdenum form a group peculiar to themselves among the commercially available metals. Their very high melting points (tantalum 2770' C., tungsten 3350' C., and molybdenum 2550" C.) set them apart so far as the metallurgical processes for their production are concerned. Further, when properly prepared and treated they will stand a somewhat unusual degree of cold work, that is work below the temperature at which marked crystal growth takes place. Such cold-worked metal may show a high tensile strength; tantalum to 130,000 lb. per sq. in., tungsten to 490,000 lb., and molybdenum to 260,000 lb., in the form of fine wire. In physical appearance, these metals are not unlike some steels; they may be better described by saying that polished tantalum somewhat resembles lead; polished tungsten, iron; and polished molybdenum, nickel. The polished surfaces of all three remain untarnished in ordinary air. Air containing corrosion-producing impurities will, in general, show molybdenum the least resistant to corrosion and tantalum the most resistant. Molybdenum has, however, a high degree of resistance to corrosion by hydrochloric acid, a property that should render it of commercial interest. On the other hand, it is markedly attacked by some of the weaker organic acids. The three metals oxidize rapidly when heated at or above a dull red in air. This feature limits their use in many applications where their high melting point and strength make them appear usable. Tungsten and molybdenum, at red heat, are quite inert to hydrogen and nitrogen; while tantalum has a rather remarkable affinity for all the ordinary gases, which results in its becoming embrittled in their presence. This

Jan 1, 1925

By L. A. Melis, A. R. Marchbank, S. A. Webster

"Certain northern Saskatchewan uranium ores have a high content of nickel and cobalt which offer the potential for recovery as a by-product to uranium. A nickel/cobalt recovery process has been developed as a viable method of recovering a marketable concentrate from typical uranium raffinate solution.Impurities are first removed from the raffinate and the pure solution is then treated with sodium carbonate to recover a bulk nickel/cobalt carbonate precipitate for sale to a primary nickel producer. All contaminants of concern are removed to very low levels and the product is free of radioactive contamination with gamma emissions significantly below natural background. Cost estimates have shown that installation of a nickel/cobalt recovery circuit within a uranium process plant is economically feasible.The testwork that led up to the selected process is described along with recommendations for further investigations such as additional testing of hydroxide precipitation as a possible viable alternative to carbonate. The selected process is described and project economics are briefly reviewed.PROCESS TEST PROGRAMBackgroundExtensive metallurgical research has been performed over the years to develop a process for recovering uranium from the Midwest deposit in northern Saskatchewan. During the course of this research, a certain amount of information became available which suggested that recovery of nickel and cobalt from uranium raffinate could be economically feasible. It was decided to undertake a test program which would investigate methods of separating nickel and cobalt from radioactive and other metal contamination to permit production of a saleable product.Available technology suggested that three general approaches could be taken to recover nickel and cobalt. The first and simplest approach would be to selectively precipitate the impurities of concern, primarily arsenic, iron and radium, and then recover a bulk concentrate from the purified raffinate. The second approach would be to purify the raffinate and then remove cobalt from solution by solvent extraction producing pure nickel and cobalt solutions for further treatment. The third approach would be to precipitate all metals from solution and then selectively re-dissolve nickel and cobalt in ammoniac solution which would be further treated by solvent extraction for nickel recovery, leaving cobalt for further treatment."

Jan 1, 1993

By N. I. Aziz

The importance of using disc cutters for rock excavation is reflected by their wide application in hard rock cutting machines such as tunnel boring machines and raise borers. The forces involved in the cutting process are those due mainly to thrust and rolling forces and are greater than that required by cutting picks. An interesting feature of cutting with discs is the formation of surface crushing, surface and sub-surface chipping and primary crack formation. Experimental, as well as analytical, work has been carried out to determine the optimum spacing between the disc cutters to control primary crack orientation. Wedge bit indenters were used to simulate disc cutters. The paper concludes by proposing a new approach to rock excavation by hybrid cutting based on controlling the primary crack orientation.

Jan 1, 1992

By R. L. Templin

The increasing use of aluminum and its alloys in commercial fields tias demanded a better understanding of their machining properties. This fact is exemplified by problems that have arisen in the automotive and airplane industries, but many in other fields might be cited. As pure alunlinum and its alloys in their various commercial conditions show appreciable differences in their machining properties, it is not surprising that quite divergent solutions have been offered for the machining problems encountered. However, if the fundamental requirements of the most suitable cutting tools for these metals are understood, these machining problems lend themselves more readily to satisfactory solutions. Since the machining of free cutting brass and mild steel is understood by most persons accustomed to working these metals, it may serve our purpose better to first make a general comparison of the tools more commonly used in machining these metals with the tools most suitable for machining aluminum, then proceed to a more specific discussion of the individual tools. Comparison oF Cutting Tools Cutting tools commonly used for machining free cutting brass usually have little, if any, top and side rake; they are ground on a medium to coarse abrasive wheel and used without any cutting compound or with a cutting compound that has a paraffin base. Those ordinarily used for steel have some top and side rake, are usually ground on a medium to fine abrasive wheel, and are often used with soluble-oil cutting compounds. The proper tools for aluminum and its alloys should have appreciably more side and top rake than the tools for cutting steel; should have very keen edges obtained by grinding with fine or very fine abrasive wheels supplemented in many cases by hand stoning with an oil-stone; and should be used with suitable cutting compounds whenever possible. In many cases, tools suitable for machining aluminum and its alloys are not appreciably different from tools commonly used for cutting hardwoods. The front clearance of a tool most suitable for machining aluminum and its alloys should be about 6°, the top rake from 30" to 50°, making the total angle of the cutting edge of the tool from 35' to 55". A side

By R. L. Templin

THE increasing use of aluminum and its alloys in commercial fields has demanded a better understanding of their machining properties. This fact is exemplified by problems that have arisen in the automotive and airplane industries, but many in other fields might be cited. As pure aluminum and its alloys in their various commercial conditions show appreciable differences in their machining properties, it is not surprising that quite divergent solutions have been offered for the machining problems encountered. However, if the fundamental requirements of the most suitable cutting tools for these metals are understood, these machining problems lend themselves more readily to satisfactory solutions. Since the machining of free cutting brass and mild steel is understood by most persons accustomed to working these metals, it may serve our purpose better to first make a general comparison of the tools more commonly used in machining these metals with the tools most suitable for machining aluminum, then proceed to a more specific discussion of the individual tools. COMPARISON OF CUTTING TOOLS Cutting tools commonly used for machining free cutting brass usually have little, if any, top and side rake; they are ground on a medium to coarse abrasive wheel and used without any cutting compound or with a cutting compound that has a paraffin base. Those ordinarily used for steel have some top and side rake, are usually ground on a medium to fine abrasive wheel, and are often used with soluble-oil cutting compounds. The proper tools for aluminum and its alloys should have appreciably more side and top rake than the tools for cutting steel; should have very keen edges obtained by grinding with fine or very fine abrasive wheels supplemented in many cases by hand stoning with an oil-stone; and should be used with suitable cutting compounds whenever possible. In many cases, tools suitable for machining aluminum and its alloys are not appreciably different from tools commonly used for cutting hardwoods. The front clearance of a tool most suitable for machining aluminum and its alloys should be about 6°, the top rake from 30° to 50°, making the total angle of the cutting edge of the tool from 35° to 55°. A side

Jan 1, 1928

By P. O. Rag, Daniel E. Walsh

"Gravity concentrators are evaluated either in closed or open circuit. The process developed by MIRL employs the use of neutron activated gold (/98Au) and radiation detection circuits which monitor the concentrator's product pulp streams. Concentrator recovery is determined from the ratio of the number of gold particles detected as passing into the concentrate to the total number of gold particles detected over all monitored pulp streams. This system eliminates the experimental errors introduced by sampling, sample reduction, and assaying and allows recovery to be evaluated for gold particles of specific sizes, shapes, and flatness. In addition to allowing for a more accurate and detailed recovery analysis, this process significantly reduces the time and cost required for unit evaluation when compared to other gold recovery analysis procedures. This system enjoys its greatest utility where a large number of tests are to be run in order to evaluate a concentrator over a variety of operational settings, i.e. factorial designs, and allows accurate testing of concentrators operated in closed circuit systems.IntroductionThe surge in gold prices of the late 1970s and early 1980s was followed closely by a renewed interest in gravity concentration processes, especially in concentrators claiming efficient recovery of fine placer gold. Cones, spirals, spinning bowls, jigs and cyclones are all considered potential fine gold concentrators. Fine gold, in this context, is defined as not only that gold finer than 250 um (60 mesh""), but also coarser gold, whose low shape factor may decrease its recovery by conventional, large-scale sluicing operations.Adoption of fine gold concentrators by the Alaskan placer milling industry was retarded by the lack of reliable, accurate, and reproducible data on concentrator efficiency with respect to fine placer gold recovery. In most cases, concentrator performance was based on a limited number of tests run on placer material, about which only slight knowledge of gold size and shape characteristics existed. In order to be prepared for the resurgence of interest in fine gold concentrators, which will follow the next upturn in gold prices, a detailed study of the fine gold recovery characteristics of gravity concentrators needs to be conducted."

Jan 1, 1986

By A. Ouchi

This paper presents ground control best practices in weak rock environments including the "Unsupported" Weak Rock Updated Span Design Curve and awareness pertaining to the potentially detrimental effects of using resin grouted rebar in weak rock masses and the false sense of security that the use of resin grouted rebar may instill. Ground support is almost always used in weak rock environments, though the type of support used can vary widely. The development of the Weak Rock Updated Span Design Curve by the addition of 463 case histories of RMR76 values ranging from 25 to 60, has also been calibrated to four different support categories; Category A: Pattern Friction Sets, Category B: Pattern Friction Sets with Spot Bolting of Rebar, Category C: Pattern Friction Sets with Pattern Rebar Bolts and Category D: Cablebolting, Shotcrete, Spiling, Timber Sets or Underhand Cut and Fill. Design of underground man-entry type excavations in North America relies heavily upon empirical analysis. This design requires a higher Factor of Safety than other non-man entry type excavations. A comparison of the calculated ½ span failure Factor of Safety between all the categories is also presented.

May 1, 2009

By L. D. Tracy

This paper represents work conducted by the Bureau of Mines in cooperation with the Illinois Geological Survey and the Engineering Experiment Station of the University of Illinois.

Jan 1, 1926

By Pierre Filiatreault, Brian Straight, Stephanie Thibeault, Devin Castendyk, Londie Cameron

"Working on or near water at active, closed or abandoned mine sites is inherently dangerous. Between 1996 and 1999, the U.S. Mine Safety and Health Administration (MSHA) reported 17 fatalities involving drowning at U.S. metal, non metal and coal mines (MSHA, 2000). Openpit mines which fill with water following mine closure, called pit lakes, present numerous risks to environmental monitoring teams including: a) drowning, b) hypothermia, c) falls to the ground from the top of high walls, d) collapse of unstable access roads, e) rock falls and avalanches from pit walls, f) avalanchegenerated tsunamis traveling across the lake surface and g) rapid degassing events.Some pit lakes are simply not safely or easily accessible for ongoing monitoring. However, the routine collection of water samples from the entire water column on a regular basis is needed to monitor the evolution of water quality over time, verify the accuracy of numerical predictions and, ultimately, manage lake water chemistry and ecological risks. For pit lakes with surface water discharge, regular monitoring is used to appropriately design and adjust water treatment plants in order to produce acceptable site discharge water quality.As a product of these risks and the need for water samples, mining companies spend considerable expense on pit lake safety as part of monitoring programs. This includes training personnel for on water duties and hazards, purchasing or hiring specialized equipment and personnel (such as boats, boat operators, personal floatation devices and cold-water clothing called mustang suits), stabilizing pit walls and maintaining safe access roads to the lake surface and employing spotters who can directly communicate with emergency medical services to watch sampling activities because cell phones and radio signals can be blocked by pit walls. Some sites utilize redundancy to prepare for unexpected incidents and accidents. For example, one Canadian mining company requires two boats on the water during pit lake sampling events, with a third boat on the shoreline, gassed and ready to go. In addition, water samplers are required to hold Marine Emergency Duties training to ensure the entire boat crew is sufficient and competent for the safe operation of the vessel in the event of an accident."

Jan 7, 2017

By N. Niemuth

Strong demand for copper in developing nations such as China and India, plus the additional demand for industrial minerals to supply the Arizona construction market, brought about a record-setting year for the state?s mining industry. The value of Arizona?s copper production set a new high of $5.5 billion and pushed the total value of mineral production to $7.58 billion. This was also a record. As it has for many years, Arizona ranked first in nonfuel mineral production in the U.S. In addition to leading the nation in copper, Arizona ranked in the top five in molybdenum, sand and gravel, gemstones, perlite, silver, zeolites and pumice. Generally strong and rising prices, especially toward year?s end, fostered a bullish atmosphere that encouraged significant levels of acquisition and exploration. This activity has spread beyond the normal commodities to include some, such as manganese and fluorspar, that have not been mined in Arizona for decades.

Jan 1, 2008

By S. Caron, P. Radziszewski

Industrial practice in mineral processing shows that an important problem in understanding and monitoring in-mill parameters is due to the lack of fundamental knowledge and appropriate sensors. However, over the last decade, Discrete Element Method (DEM) modelling has shown an interesting potential in describing the fundamentals of grinding mill behaviour, in improving the understanding of internal grinding mill dynamics, and in developing solutions to industrial practice. With the objective of bringing this modelling technology into the concentrator control room to assist operators, this paper aims to describe the main elements needed to apply this emerging and developing technology to on-line mill performance monitoring.

Jan 1, 2004

By A. J. Partos

One Liberty Place, at 315 m is the tallest building in Philadelphia, PA USA. It is supported on drilled piers socketed in heterogeneous rock. 3832 kN/m2 end bearing and 383 to 766 kN/m2 shaft resistances were selected. Design load distribution was 40% on the base and 60% by shaft resistance. The maximum compression on the corner core columns is supported by clusters of 3 drilled piers. In order to confirm load distributions along shaft and at the base, Drilled Pier G-10 supporting T13-A type outrigger column was instrumented. This column supports 53,849 kN compressive load which includes 13,440 kN windload. This paper reveals details about the process to select the final design for One Liberty Place together with pertinent Information about site geology, foundation construction, quality control, and methods of steel erection. It also presents detailed Information on the type of Instruments, their calibrations, field fabrication, and installation in the shaft of Pier G-10. Readings of concrete temperatures, computed loads, and load distributions are presented for a period from October 1985 through May 1988. The building was completed in 1987.

Jan 1, 1989

By D. Tao, R. Honakey, B. K. Parekh

The dewatering of stable phosphatic clay suspensions generated from phosphate beneficiation in the central Florida is an issue of practical and theoretical importance. Because of its tiny particle size and surface charge, the phosphatic clay takes up to 20-30 years to settle in water and causes environmental, aesthetic, economic, and handling problems. An efficient and cost-effective dewatering/consolidation process for phosphatic clay is of great interest to the phosphate industry in Florida. In this paper, the consolidation and dewatering behavior of phosphatic clay was studied by use of anionic flocculants with and without sand addition. The effects of pH, initial polymer concentration, polymer dosage, polymer addition steps, and metal cations (K+, Ca2+, and Al3+) on the flocculation of phosphatic clay have been studied. Experimental results indicated that clay suspensions were well flocculated at pH 10.5 by DPW-1-1355 and Magnafloc 5250 flocculants acquired from Ciba Specialty Chemicals. Sand particles from phosphate flotation added to the clay slurry promoted flocculation and increased clay consolidation. K+ showed good performance to improve the flocculation characteristics by neutralizing clay surface charge. The adsorption mechanisms of flocculants on clay particles were also discussed in this paper.

Jan 1, 2006

By F. Khorram

Image processing is a technique that simulates the human vision system. This technique enables applying every statistical or intelligent operation to recognize differences. In this way this new technique is used in quality control systems in most industries. Studying sedimentary rocks is very important from the economic point of view. Some units of sedimentary sequences involve different mineral deposits, hydrocarbon and water resources. Therefore it is important to identify and classify different sedimentary rocks. Descriptive classification of sedimentary rocks is usually based on visual and textural features and chemical composition of a sample. In this paper different samples of a limestone mine in central part of Iran are classified. The samples were collected from different parts of the mine and crushed down in size from 2.58 cm to 3.58 cm. The rock samples were labeled based on percentage of chemical and lithological compositions. Each sample was assigned to one of the distinguished groups. The images of the samples were taken in appropriate environment and processed. A total of 74 features were extracted from the identified rock samples in all images. In order to feature dimensional decrease, principal component analysis method was used. Then Bayesian statistical algorithm was used as a useful tool for classification. Classification Correctness Rate (CCR), calculated for the test data sets are %88, %68, %61 and %72 for the first to fourth class respectively. Therefore it can be inferred that the extracted features of images are appropriate indicators for different samples identification. These precise results besides the advantages of image processing technique, which are increasing speed of operation and decreasing cost, appears to be a desirable success.

Jan 1, 2012

By Anthony H. Tawil

Modern, high-speed machines used in the manufacture of paper require foundations with stringent settlement constraints. To fulfill this requirement, caisson piles, extending into bedrock, were selected to support a paper machine in Baie Comeau for the Quebec North Shore Paper Company (QNSPCo.). This was the fourth machine in an existing paper mill, and its construction was part of an expansion program which included the building of associated structures such as a wood room and chip storage building, and other facilities, Figure 1. The paper mill in Baie Comeau, Quebec, is located in an area which has extensive deposits of sensitive marine clay which are transformed into a viscous liquid when disturbed by external forces such as the driving of piles. Loss of ground and soil disturbance as affected by piling activity assumed considerable importance in the design and construction of the caissons particularly in view of the proximity of existing plant facilities, including another paper machine.

Jan 1, 1987

By I. R. Firth, D. L. Taylor

Metal mining operations, in particular gold mining operations, use intensive ore control procedures in order to manage the extraction of ore zones from benches containing both ore and waste material. Typical grade control procedures rely on blast hole samples to indicate ore grade. Statistical techniques and geological controls are then used to create two-dimensional polygons, which indicate zones of material designated as ore. These ore-polygons are calculated using pre-blast material locations and are generally not corrected for rock movement caused by blasting. This lack of correction appears to exacerbate the material mischaracterization problem of sending ore to the waste dump and/or waste to the mill. One Nevada gold mining company has estimated that this could be a $10 million per year problem for their operations. Using a simplified vector field algorithm, a method of taking point movement data and interpolating post-blast positions for all nodes in a polygon has been developed. Currently working in 2-dimentions (X-Y), this algorithm utilizes the movement vectors calculated from pre-and post-blast positions of targets placed in a blast, to generate a spatial transformation function for any point on the bench. This transformation is then applied to the nodes of the ore-polygons to produce modified dig lines ore polygons reflecting distortion and movement resulting from the blast. The method as implemented uses common mine planning routines and is performed using the Surpac software suite. The method may be adapted to use any pre-and post-blast point movement data available, and most mine planning suites include the simple interpolation algorithms used. Keywords: Blast movement; Ore control; Open pit blasting; Grade control

Jan 1, 2003

By August J. Kwitowski

This Bureau of Mines report summarizes the development of a protective operator compartment for a new generation thin-seam mobile bridge carrier. The developed compartment is commercially available and is currently employed on approximately 15 bridge carriers used in the mining industry. The design of the compartment, which employed human factors engineering and small- and full-scale mockup models, is fully described. Details of the compartment's fabrication, evaluation, and demonstration in a commercial low-seam coal mine are also provided.

Jan 1, 1986

Research workers From the Bureau of Mines and industry met with other government and industry representatives in Pittsburgh, Pa., on January 22, 1975, to discuss the results of research under the Bureau of Mines Noise Control Program. The program, aimed at reducing noise in mines, is functionally divided into three major areas: Instrumentation, personal protection, and noise abatement. This proceedings contains the opening remarks to the seminar and seven technical presentations based on various aspects of noise abatement and control.

Jan 1, 1975