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By Allan E. Martin

As part of a comprehensive investigation of tae mechanism of desulfurization of iron and steel by slags, the Blast Furnace Studies Section, Metallurgical Division, Bureau of :lines, in cooperation with the Institute of Technology., University of Minnesota, has made a study of the forms in which sulfur occurs in blast-furnace slag. This report presents data on the three sulfides most important in iron smelting, namely, ferrous sulfide, manganous sulfide, and calcium sulfide. The tendency of these sulfides to form colloids in the molten slag was determined by an examination of quenched samples with an ultramicroscope. Vogt5/ conducted experiments on sulfide silicate melts and examined synthetic blast-furnace slags in a partly crystallized condition. His conclusions were that FeS, CaS, and MnS, or isomorphous compounds, such as (FeXCay)S and (MnxCay)S, were precipitated from the melt, depending on the composition of the slag. In all specimens sulfides were visible and were spherical.

Jan 1, 1941

By R. W. Schultz

Mineral exploration carried out in Ireland since the mid-1950s has resulted in the discovery of ore deposits that are now in production atTynagh (Pb-Zn-Cu-Ag), Silvermines (Zn-Pb) and nearby Ballynoe (barite), and Gortdrum (Cu-Ag-Hg); a major Zn-Pb deposit at Navan that is now being drilled prior to development; potentially productive deposits at Keel (Zn-Cd-Pb), Ballinalack (Zn-Pb) and Aherlow (Cu-Ag); and a number of interesting prospects, including one of spodumene. Underground exploration of a formerly extensively mined copper deposit at Allihies has outlined new, albeit currently uneconomic, reserves at depth. The copper and pyrite deposits at Avoca have in recent years been re-explored and are now again being worked. Most Irish ore deposits are in the lower half of the Lower Carboniferous succession of limestones and subordinate shales and sandstones, and this stratigraphic zone is being most intensively explored at present. Other geological units under active exploration are Ordovician sediments-volcanics belts, Caledonian granites, and parts of the Old Red Sandstone and Dalradian series. Surface prospecting is made difficult in many places by glacial and other superficial deposits, including peat and alluvium. Geochemical prospecting methods have been outstandingly successful and primarily responsible for most new discoveries. Boulder hunting and outcrop prospecting have proved effective in detailed investigations of geochemically anomalous areas. Some parts of the country have been covered by three separate airborne geophysical surveys, albeit without success so far. The induced polarisation technique, the most widely used ground geophysical method, has contributed to several discoveries. The scope of application of electromagnetic surveys is more restricted than that of induced polarisation, but the method has been effective in a few cases and has contributed to the Tynagh discovery. To date, the resistivity and self-potential methods have found little application. Magnetic surveys are not applicable directly in the search for ore deposits of the various known types, but can be helpful in outlining geological structures in some areas. The gravity method has been used successfully in a survey over the Zn—Pb deposit at Navan ; it has also proved effective in trials over a blind sulphide deposit at Tynagh that cannot be detected with geoelectrical methods. An appendix lists summary descriptions of 15 Irish deposits and occurrences

Dec 1, 1971

By Rambabu Pothina, Rajive Ganguli

The economics of a mineral processing circuit is dependent on the numerous sensors that are critical to optimization and control systems. The sheer volume of sensors results in mines not being able to keep the sensors calibrated. When a sensor goes off calibration, it results in errors which can severely impact plant economics. Normally, these errors are not detected until the error grows and becomes a large (“gross”) error. Undetected errors are not remedied until the next calibration, which on average are a year apart Beamex (2019) [1] across all industries. Classical statistical methods that depend on linear relationships between input and response variables are typically used to find gross errors, but are not effective for highly non-linear and non-stationary operations in mining and mineral processing industries. Calibration of sensors is time-consuming and generally requires physical intervention that results in equipment downtimes causing production losses. Therefore, in situ detection methods are warranted that do not require physical removal of sensors to compare with standard measurements or well-calibrated sensors. Data-mining based techniques and algorithms have high success rate in tackling such problems. This paper presents results from a groundbreaking multi-year big data research project whose goal was to develop data-mining-based original techniques in a multi-sensor environment to identify when sensors start to stray, rather than wait for errors to grow. The carbon stripping (gold) circuit in the Pogo Mine of Alaska was selected for this project. Maintaining strip vessel temperatures at optimum levels is crucial for maximizing gold recoveries at Pogo, and hence the focus was on the temperature sensors of the two strip vessels. An automated algorithm to detect errors in strip vessel temperature sensors was developed that exploited data from multiple sensors in the strip circuit. This algorithm was able to detect with a high success rate when bias errors of magnitude as low as ± 2% were artificially induced into strip vessel temperature data streams. The detection times of about 1 month were much less than the industry average calibration frequency of 1 year. Thus, the algorithm helps detect errors early, without stopping the circuit. The algorithm alarms can serve as triggers when calibrations are done. Experimental methodology along with results, limitations of algorithms, and future research are also presented in this paper.

By Patrick J. Hannigan, Alex Ryberg, Rozbeh B. Moghaddam

Driven piles are widely used for foundation support. In the vast majority of cases, an increase in pile capacity occurs with time which is referred to as “set-up.” However, in a very limited number of cases, a decrease in capacity with time can occur. This phenomenon is referred to as “relaxation.” This paper will provide a brief review of the relaxation phenomenon, as well as pile driving information and dynamic test data on cases where relaxation has occurred. The pile types in the presented relaxation cases include H-piles, open-end and closed-end pipe piles, prestressed concrete piles, and prestressed concrete piles with H-pile stingers. The soil conditions where relaxation occurred includes dense to very dense fine sands, heavily over consolidated clays, and weak laminated rocks. Relaxation information from 36 piles at 26 sites is assessed. The collected data will assist foundation designers by identifying the subsurface conditions where relaxation has occurred, as well as by documenting the corresponding relaxation magnitude. One method of addressing relaxation when it is encountered is to drive the foundation piles to a greater end of initial driving capacity than required long-term. Hence, the identification and quantification of the relaxation magnitude will be beneficial to foundation designers installing similar pile types in similar subsurface conditions. The paper will also present pertinent observations and recommendations on mitigating relaxation when encountered. INTRODUCTION One of the earliest observations of a decrease in redriving resistance following initial driving was reported by Miller (1937). He reported that piles driven into a saturated, coarse grained soil could lose 40 to 50% of their resistance when redriven 24 hours after initial driving. Yang (1956) similarly reported that after a break in driving, a decrease in driving resistance could be encountered for piles driven in dense fine sand, inorganic silt, or stiff fissured clay. Parsons (1966) in his paper that described piling difficulties in the New York City metropolitan area termed this phenomenon “relaxation”. In this time period, pile capacity was most often evaluated from a pile driving formula frequently checked by a static load test. Hence, the true magnitude of the capacity decrease on a given pile was often poorly quantified. Furthermore, dynamic measurements that could determine what influence driving system performance variation had on the observed redriving resistance were not yet readily available.

Jan 1, 2019

By T. Brozell

"Communities near sand mines and processing facilities in Wisconsin have raised concerns regarding possible exposure to ambient respirable (PM4) crystalline silica. Fenceline PM4 (particulate matter captured with a 50 percent cut size of 4 micrometers aerodynamic diameter) crystalline silica concentration data were compiled at Fairmount Santrol Inc., Mathy Construction Inc. and U.S. Silica facilities. The long-term average PM4 crystalline silica concentrations ranged from 0.05 to 0.45 micrograms/m3 when sample values below the limit of quantification were treated as zeros. All of the long-term average concentrations were less than 20 percent of the Minnesota Department of Health’s and California Office of Environmental Health Hazard Assessment’s PM4 crystalline silica chronic reference exposure level of 3.0 micrograms/m3. The measured concentrations were consistently within the local background concentration range.Air Control Techniques P.C. compiled the sampling data using Thermo Fisher Scientific Inc. Partisol 2000i PM2.5 samplers meeting the requirements of 40 CFR Part 50, Appendix L. These samplers were adapted to capture particulate matter with a 50 percent cut size of 4 micrometers. The use of polyvinyl chloride filters allowed for crystalline silica X-ray diffraction analysis by NIOSH Method 7500. The combined use of adjusted PM2.5 filter-based samplers with Method 7500 crystalline silica analyses provided for a highly sensitive limit of quantification of 0.31 micrograms/m3 of PM4 crystalline silica.BackgroundIn 2005, the California Office of Environmental Health Hazard Assessment (OEHHA, 2005) adopted a 70-year chronic reference exposure level (REL) for PM4 (particulate matter having aerodynamic diameter of 4 micrometers or less) crystalline silica. The REL was extrapolated from occupational hygiene epidemiological studies, essentially all of which were based on in-plant PM4 crystalline silica measurements. No well-established ambient sampling technique for PM4 crystalline silica was available at the time that OEHHA adopted its REL. The personal samplers used for the National Institute for Occupational Safety and Health (NIOSH) Method 0600 in-plant sampling of employee exposure were designed for concentrations higher than ambient levels. The limit of quantification (LOQ) of PM4 crystalline silica on NIOSH 0600 filters was too high for the effective sampling of ambient air."

Jan 1, 2015

By Gregory A. Stephan

A case history of design, prediction, instrumented static load tests on probe piles, installation monitoring, and integrity testing of production piles is presented. Based upon project-specific subsoil conditions, as obtained from several 60 to 80 ft (18.3 to 24.4 m) deep test borings, deep foundation system alternatives included driven concrete and steel pipe piles as well as augered cast-in-place (ACIP) piles. High structural loads, site-specific constraints, and the production time frame mandated by the project owner led to the selection of an ACIP pile foundation system that was designed for a pile capacity of 75 tons (667 kN) in compression and 35 tons (309 kN) in tension. Site-specific concerns were raised about the highly porous nature of fragmented and decomposed sandy limestone as well as the high grout intake during construction that could result in increased foundation cost as well as interconnecting of the piles in the rock layer. Consequentially, a multi-phase ACIP pile evaluation program consisting of instrumented compression pile load tests, in conjunction with single-hole ultrasonic pile testing, pile echo testing (sonic testing), as well as full-time production pile monitoring by an experienced geotechnician was specified. As a result of this testing and evaluation program, while grout usage was determined to be within an acceptable range, the instrumented compression load tests yielded data that allowed use of 55 ft (16.8 m) long ACIP piles in lieu of the original plans to use 70 ft (21.3 m) long precast concrete piles. This information was effectively utilized as part of the overall quality control program to install a total of 268, 14 in. (356 mm) diameter ACIP piles within the building footprint to depths of 55 ft (16.8 m) below the pile cut-off elevation as part of the foundation support system. Information recorded during installation included rate of insertion/extraction of the auger, grout pump strokes and pressure, total grout volume, and grout factors, as well as quality and strength of grout. Additionally, many pre-selected installed piles were tested for integrity with a Pile Integrity Sonic Analyzer (PISA) using both sonic and ultrasonic methods. This engineered, monitored, and tested foundation solution provided an effective and quality intensive basis for completion and approval of the foundation work for the building that resulted in cost savings over other foundation alternatives for the owner.

Jan 1, 1999

By W. A. Backofen, M. L. Ebner

SINCE the early work of Gough with Hanson and Wright,l-3 the study of fatigue has been characterized by experiments on single crystals only in recent times.9-10 Now, increasing attention is given to this aspect of fatigue research for the insight that it may provide into details of mechanism. The investigations have concentrated to a large extent on the development of deformation markings on fatigued crystals, and have shown the cracks to originate in slip bands possibly preceded or accompanied by slip-band extrusions. Experiments of special interest to the present work were conducted by paterson5 on copper crystals and involved both metallographic examination and measurement of change in flow stress. Crystals were cycled in alternating tens ion-compress ion with a constant plastic shear-strain amplitude of approximately 0.8 pct, and were particularly revealing for their demonstration of hardening with accumulated strain similar to that in unidirectional straining, through an easy-glide stage I followed by a stage II of rapid hardening; deformation was not continued beyond 40 cycles, however, so that the eventual course of the hardening curve could not be decided. For the conditions used by Paterson, surface slip markings were similar to those observed in unidirectional straining, but there were no X-ray asterisms and no deformation bands on the surface. In current thinking about the nature of fracture in fatigue, two views relative to mechanism are generally acknowledged, with the reservation that both could apply simultaneously in some measure. As one possibility, fracturing across a slip plane is regarded as a result of loss of cohesion from the creation of many point defects by dislocation movement under the cyclic loading.'' On the other hand, fracture has also been taken to follow as a consequence only of the geometry of slip at a free surface, consisting of offsets and crevices which eventually become fatigue cracks.12, l3 The work of McCammon and Rosenbergl4 showing fatigue in polycrystals at 4.2oK makes clear that any long-range diffusion of point defects is unnecessary, yet studies such as those of Forsyth and stubington15 show that accelerated diffusion may be a characteristic of deformation under fatigue loading. Interest in obtaining data of possible use for resolving such questions led to the experiments described below. Copper crystals were conveniently loaded in alternating four-point bending at constant deflection, a test condition shown to approximate a constant plastic strain amplitude for a wide range of axial orientations. The method of testing was not readily adapted to extensive study of temperature effects, but an investigation of the geometry of crack formation could simply be made by orienting,the slip direction at different angles to the surface. EXPERIMENTAL PROCEDURES Single crystals were grown by a modified Bridgman method in a stationary gradient furnace under an atmosphere of purified dry nitrogen. Purity of as-grown crystals was 99.999 pct as determined by spectrographic analysis plus vacuum fusion and gravimetric analyses for oxygen and sulfur, respectively. Crystals were of reasonable perfection as evidenced by a critical resolved shear stress at 10 deg from (110) of 60 g per sq mm and half-width of a (400) X-ray diffraction line from one crystal of

Jan 1, 1960

In looking to the future of mineral processing the focus is typically on improved processing units. Basically it is a search for an elusive wonder machine that could revolutionise the economy of mining: the sorter that strips 50% of the ore with only a few % loss of value; the comminution device that uses 5% of the energy while producing fully liberated particles; or the recovery device capable of producing a 99% recovery at 99% grade. These aspirations are propounded against a reality backdrop of sorters rusting in back yards, mill throughputs below design and varying by 30%, cyclones flaring and cut-sizes fluctuating, mediocre recoveries and soaring processing costs. This disconnect between aspiration and reality appears, to these authors at least, to be a mighty chasm. Moreover, it remains one over which we are expected to magically leap rather than methodically bridge. Indeed one may be forgiven for thinking that should such a wonder machine come along, taking advantage of it would be highly improbable. Questions would inevitably emerge on how to feed the correct material, how to cope with the wide variability of feeds, how to control such advanced equipment and how to handle the new product from such a machine. It is likely these questions might lie unanswered, or more regrettably, unasked. It is generally accepted that as an industry we are exceedingly unlikely to teleport from the current status quo to an entirely new reality in a single flash. It is our thesis that the probability of these magical machines materialising is remote, and even if they miraculously appeared, we simply wouldn?t know what to do with them. Rather, it is our contention, that a step change will only arise through a staircase rather than from a single giant leap. We should focus on building those steps and linking them together into a firm structure ? a workable mineral processing circuit. This paper addresses the alternative of a coherent set of modest but significant improvements, integrated to produce the step change we desire: essentially, a reduction of processing energy to below 40%, which we believe is achievable without recourse to any mystical machines. A key underlying capability to designing these dramatically improved processes, is the weaving of independent process models into a coherent circuit simulation, in order to design the new generation of mineral processing circuits. Keywords: step change, circuit design, circuit simulation, energy reduction

Sep 1, 2012

By R. V. Ramani, W. Miola, R. Srikanth, S. C. Soboleski

"Dust control in high-production longwalls requires attention to operating practices and ventilation schemes. Several studies have shown that the shearer is the major source of dust on a longwall face. Support movement has not been regarded as a major source of dust in US longwalls. Yet, under certain conditions, 31% of the shearer operator's dust exposure can be due to support movement.Several methods have been developed for the control of shield-generated dust. But the need for better methods is apparent. In this paper, the amount of airborne, respirable dust generated per shield move is estimated from specially designed experiments on longwall faces. Ten experiments were conducted on five longwall faces in four mines. Each experiment involved one face visit and lasted three to six hours. The contribution of shield movement to the airborne, respirable dust concentration immediately downwind of the shield move varied between 0.12 and 1.75 mg/m3 in the five longwall faces. The mass of airborne, respirable dust gener-ated by shield movement was found to vary between 39 and 386 mg per shield move. The results from this study reveal that control of dust from longwall shields requires a combi-nation of approaches involving alternative operating prac-tices, reducing shield dust generation rate, increasing face air flow and decreasing personnel exposure.IntroductionIn 1992, longwall mining accounted for about 36% of US underground coal production, a 240% increase from a decade ago. The absolute longwall tonnages were 46 and 133 Mt (51 and 146 million st), respectively. Compared with room-and¬pillar mining systems, the longwall mining system is charac¬terized by higher recovery, enhanced safety and higher pro¬ductivity.However, personnel dust exposure on a longwall face is higher than in other types of mining. According to Mine Safety and Health Administration (MSHA) data, fewer longwalls were in continuous compliance with the applicable dust standard in 1992 than in 1989.Controlling shearer-generated dust and reduction of per-sonnel exposure to airborne dust have commanded attention in the design of longwall faces, operational practices and ventilation schemes. Studies in the United States and abroad have revealed that support-generated dust can be a major obstacle to compliance under certain conditions (Becker et al., 1989; Bradley et al., 1983; Jankowski and Organiscak, 1983; Jankowski et al., 1990; Organiscak et al., 1985)."

Dec 1, 1996

By J. R. Schafler, J. L. Brinkman

"The US coal mining industry has suffered a recent decline in profits caused by a combination of decline in commodity demand and more restrictive government regulation, forcing coal mining companies to cease production in numerous mines. A 40% decrease in the total number of coal mines occurred from 1994 to 2000. The number of mines remained relatively constant until 2008 when a change of government sparked a series of new environmental regulations which have contributed to another 15% decrease from 2008 to 2016. In contrast, production has only decreased by 3%, increasing from 1994 to 2008, and then decreasing since 2008. However, this value is skewed by large increases in sub-bituminous coal production and decreases in other coal ranks. Several aspects assist in executive decisions on mine longevity and economic worth. Studies of open source mine data collected by mandated government surveys coupled with commodity history can be used to find relationships between mine closures and these elements, which include statistics on production tonnage, seam height, coal rank, etc. This paper looks at coal mining trends since 1994 by comparing mine, market, and regulation factors that may influence mine closure. INTRODUCTION The US coal mining industry is currently experiencing a decline in both demand and commodity price while facing implementation of more stringent air and water pollution regulations. Company profits have decreased significantly, forcing several major companies to declare bankruptcy. The industry was required to adapt to survive. Many of these companies have adjusted by abandoning mines; the last two decades have seen a drastic decrease in the number of mines. To discover the primary causes of this downturn, three major aspects must be studied: properties of abandoned mines, commodity history, and regulatory impact. TRENDS SINCE 1994 Each year, US coal mines are required to submit data on a wide variety of categories to the Mine Safety and Health Administration (MSHA) and the US Energy Information Administration (EIA). This data includes administrative records, production values, and information regarding the attributes of the mined material and the mine itself. Each year since 1996, EIA has released a report summarizing the data from two years prior. Additionally, MSHA maintains a database containing a collection of all the most current data. These resources are the primary sources for the following figures."

Jan 1, 2017

By Ricardo Dobry, Alain Pecker, George E. Leventis, Ralph B. Peck

"This year’s DFI Outstanding Project Award is for the design and construction of the foundation scheme for the largest cable-stayed bridge in the world. In 1993, Gefyra, SA (a French/Greek consortium led by VINCI of Paris, France) was awarded a €750 million ($1billion+ USD) Concession Contract to design, build, fi nance, operate and maintain a three-span cable-stayed suspension bridge connecting the Peloponnese, Greece’s southernmost peninsula, with the mainland across the Gulf of Corinth. The contract extends over a 42-year period, 7 years for design and construction and 35 years for operation. The project was fi nanced through a combination of public funds, private equity and bank loans. Alternative foundation concepts that were considered included traditional driven piles, deeply embedded caissons and soil improvement. PROJECT CHALLENGESThe extreme technical challenges faced included:??Weak foundation soils composed of soft alluvial deposits consisting of interbedded layers of granular and cohesive materials with thin layers and lenses of gravel and liquefi able sand pockets; rock is believed to be at a depth of 1,000 m (3,500 ft) or more.??A very deep seabed exceeding 60 m (200 ft).??The requirement to withstand the collision of 180,000-ton tankers traveling at 16 knots.??Maximum wind forces of 250 km/hour (155 mi/hour).??Design seismic forces corresponding to Richter magnitudes of 7.0+ with peak ground accelerations of 0.48 g at seabed.??Design tectonic movements of 2 m (7 ft) in any direction between any two adjacent bridge pier foundations/pylons.Considering subsurface conditions and local seismicity and water depths, foundation design and construction methods were the key drivers for this project. In large part, the success of the project is owed to the unprecedented partnering and collaboration between all partners involved fostered under the leadership of Jean Paul Teyssandier and Gilles De Maublanc of VINCI Group (France) who served as lead Concessionaire and General Contractor. The joint venture’s lead Greek partners were Elliniki Technodomiki/AKTOR and J&P/AVAX. Alain Pecker of Geodynamique et Structure (France) served as lead Geotechnical Consultant/ Designer while Buckland and Taylor (Canada) served as Design Checkers with Ralph Peck and Ricardo Dobry (U.S.) as Special Advisors on foundation issues, Langan International/Langan Engineering and Environmental Services P.C. (George E. Leventis, Gregory Biesiadecki and Diane Fiorelli) served as Technical Advisor on geotechnical, geodynamic and foundation/marine construction issues."

Jan 1, 2007

INTRODUCTION Trade financing is a particularly important component of short-term financing for a minerals company since errors, extra costs, or payment delays/defaults can easily wipe out the profit margin on a particular shipment or can cause problems when arranging purchases of e.g. reagents. It is required to make any minerals operation function and does not have to be cross-border to require proper management. Sources of working capital are as follows: 1. Extended credit terms from suppliers 2. Inventory loans from banks, finance companies 3. Accounts receivable financing or factoring 4. Credit lines or overdraft facilities from banks. TRADE CREDITS These are provided under the familiar terms "net 10 days" or payment due by the "10th day of the following month." Thirty days for payment is usual but longer periods can be negotiated with regular suppliers. Shipment may be made on open account with specified periods for settlement. In the mining industry, a custom smelter gains trade credit by paying for concentrates three months after the month of shipment. INVENTORY LOANS Various forms of inventory finance are provided via "floor-plan" or warehouse financing. A set percentage, usually 60%-80%, of a good-quality, readily saleable inventory item (e.g. bullion, concentrates, ingots) will be provided by a bank or finance company which will usually have security over these products and has a right to inspect the goods from time to time. Legal security will he achieved by warehouse receipts, floating liens, chattel mortgages, trust receipts, or through collateral management service companies. The latter certify control over stock or distribution outlets and often carry insurance against fraud. Costs range around 1.5% - 2.0% p.a. or more plus some fees to cover out-of-pockets or other costs. ACCOUNTS RECEIVABLES Accounts receivable financing is based on the company's generation of satisfactory receivables which are continuously assigned to a bank or finance company ("factoring"). Because of the risks in being able to collect receivables, such as payments to a smelter for its blister copper shipments to a refinery, this form of financing costs as much as 3% - 5% of the debt amount purchased plus an additional charge for processing paperwork. Receivables can be purchased with or without recourse and on a notification or non-notification basis to the client's customer to, respectively, pay the invoice directly to the bank or not. LETTERS OF CREDIT Letters of Credit ("L/C's") are a common feature of international trade finance whereby a bank, at the request of the buyer, issues a written undertaking to an exporter to pay a specified sum of money within a set time on presentation of previously specified documents. This undertaking means that the exporter is no longer relying on the credit standing and integrity of the foreign importer. A dispute about shipment does not otherwise affect the obligation to pay upon presentation of a "clean" set of documents. These documents include the hill of lading and other documentation, often on standard "form" bases. There are a number of conventions and techniques in L/C's such as irrevocable/revocable L/C's, time L/C's, confirmation/advising L/C's and transferable L/C's. These are tools to adjust for the varying risks that the importer will not pay. Other routes where one is comfortable with an importer include documentary sight hills (D/P hill), documentary term bills (D/A bill), and, of course, open account.

Jan 1, 1985

By Keith P. Bingham

A total transportation system providing for delivery of finished products to customers and raw materials to the plant is one of the key elements contributing to Dravo Lime Co.'s success. Dravo Lime operates one of the largest noncaptive lime and limestone plants in the US at Maysville, KY, where products produced can cost as much to deliver as they do to manufacture, depending on the product itself, its destination, and mode of transportation. With delivery costs comprising a significant portion of total costs for its products, Dravo Lime has made total transportation services an integral part of its business strategy. Prices for most products produced at Maysville are quoted f.o.b. destination. In short, Dravo Lime's Distribution Department relies on the approach that says to customers: "Leave the delivery to us." The 0.9-Mt/a (1-million stpy) Maysville facility, located about 121 km (75 miles) east of Cincinnati, OH, on the Ohio River, primarily produces sulfur-absorbing Thiosorbic lime used by coal-fired electric utilities as a scrubber reagent to remove SO2 from stack gases. The product is currently supplied to eight power plants in the Ohio River valley region which extends through portions of Kentucky, Indiana, Ohio, West Virginia, and Pennsylvania. The plant ships approximately 907 kt (1 million st) of lime and a comparable amount of limestone fines each year. In addition, it arranges for delivery of about 181 kt (200,000 st) of coal to the plant. Lime is transported by covered hopper barges, covered rail cars, covered dump trucks, and pneumatic trucks. It is transferred from barges to storage silos and trucks at a terminal on the Ohio River near Marietta, OH. At another terminal near Aliquippa, PA, lime is transferred from barges to silos, trucks, and rail cars. Future plans call for rail-truck transfer terminals. To produce lime from limestone at the Maysville plant, about 181 kt (200,000 st) of coal is burned annually in three coal-fired kilns. In transporting this coal from the mine to Maysville, Dravo takes maximum advantage of opportunities for reloading carriers with limestone for outbound backhaul movement. Coal, shipped from southeastern Kentucky mines in rail cars, is transferred to barges at a river terminal in West Virginia. After it is unloaded at Maysville, the barges are cleaned with a front-end loader and then reloaded with limestone. Limestone also is backhauled in connection with truck deliveries of coal. The economics of using backhaul shipments has permitted Dravo to enter into markets in which Maysville limestone otherwise would not be competitive. The company plans to backhaul limestone in empty open hopper cars in the future. As part of its ongoing assessment of the distribution system that supports the Maysville operation, Dravo Lime recognizes that a new environment has developed between shippers and carriers because of regulatory changes in the railroad and trucking industries. Although dry bulk shipments by barge to and from Maysville have always been unregulated, other forms of transportation have not. With railroads and motor carriers now approaching varying degrees of deregulation, contracts and agreements are replacing tariffs, and rate negotiations are becoming a daily activity. Dravo Lime plans to take advantage of these transportation changes, all of which may be beneficial to both its plant and its customers.

Jan 10, 1982

By S. I. Anufrieva, N. A. Permyakova, E. G. Likhnikeevich

"Russia’s rare metal reserves are composed of compositionally and structurally complex ores and are characterized by an increased content of natural radionuclides due to their geochemical similarity with rare metals. For instance, concentrates of Zashikhinsky daeposit are characterized by an increased content of uranium (0,06%) and thorium (0,59%); Beloziminsky deposit holds pyrochlore-apatite-magnetite-carbonate ores characterized by increased radioactivity (130 mkR/h) and containing 0,0016-0,0025% of uranium; Etykinsky deposit is characterized by columbite-pyrochlore-microlith mineralization with an average ore grade of 0,013% of uranium and 0,0020% of thorium; eudialyte concentrate of Lovozero deposit (Alluaiv area) belongs to Class II of mineral reserves. Industrial development of these mineral reserves involves the need to comply with environmental standards, public health requirements applicable to finished core and by-products, to take into account the amount and class of the generated radioactive waste, the possibility of disposal or recycling of the radioactive production waste. Concentration processes of radioactive rare metal feeds most often lead to a concentration of natural radionuclides and their accumulation in concentrates. Comprehensive hydrometallurgical processes are currently under development for such concentrates, aimed at producing salable products compliant with the radiation safety standards. The choice of the hydrometallurgical processing method for radioactive rare metal concentrates is based on the mineralogical component of the concentrate, textural and structural features, the distribution of valuable components and impurities, and the content of radionuclides. A systemic approach to the selection of processing methods, in particular integrating several methods, is an effective solution. Methods may not only be combined, but also inextricably linked with each other. Hydrometallurgical processing methods include leaching by acidic and alkaline agents; sulfatization for selectively decomposing the minerals and moving the bulk of U and Th into solution; fluorine extraction process. Methods of precipitation and co-precipitation, extraction (by liquid and solid extractants), sorption, and ion exchange are used to decontaminate the solutions by removing thorium, mezathorium, uranium, and their radioactive decay products. Agents used in hydrometallurgical processing of radioactive rare metal ores include sulfuric, nitric, hydrochloric, hydrofluoric acid, alkali (NaOH, KOH), sorbents (for example, AB-17) for sorption of uranium and extractants (mono- and bidentate organophosphorus compounds, diamides, etc.) for the extraction separation of rare, rare-earth, and radioactive elements."

Jan 1, 2018

By A D. Price, W J. Germs, O Patterson, T R. Weaver

"Understanding controls on groundwater and surface water flow and quality at mine sites throughout all mine stages is critical to effectively manage environmental impacts over the entire mine life. Monitoring forms is an essential component of this proof of understanding. Typically, monitoring programs at mine sites have been developed in the framework of existing conditions. However; recognition of the challenges of climate change and the performance of mines during recent extreme events in Australia has highlighted the need to develop monitoring programs that are resilient and responsive to changing environmental conditions. Water monitoring programs need to be effective under a range of environmental conditions, potentially not historically experienced.This emerging challenge requires cross-disciplinary teams to work together to understand issues including: representativeness of background conditions to longer-term conditions at the mine site sensitivity of mine and closure designs to changing climate and hydrologic conditions methods of performance (eg water quality or quantity) failure during extreme climate events such as flood or extended drought.These understandings come together in a detailed conceptual and, in many cases, numerical hydrologic model that considers the mine-water environment under a range of conditions. The groundwater, surface water and water quality monitoring programs that are developed from the conceptual model need to be sufficiently responsive to be effective in the face of such changing conditions, with results in turn informing the conceptual model. Extended drought, major floods and changing weather patterns can alter recharge and discharge areas, oxidation profiles and ultimately, the contaminant flux estimates that would have contributed to mine design parameters and performance. Unless these effects are considered in the spatial and temporal design of the monitoring program and within the parameters monitored, the resultant program may fail to capture data that are critical to evaluating environmental impacts from mine sites.Developing and implementing a water monitoring program that considers these issues can build confidence in mine performance under a range of conditions, leading to increased confidence by all stakeholders in long-term mine performance during and after closure.CITATION:Weaver, T R, Price, A D, Patterson, O and Germs, W J, 2013. Developing resilient water monitoring programs in changing climate conditions, in Proceedings Water in Mining 2013, pp 109-114 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Nov 26, 2013

By Marcel Vallée

"Abstract - Traditionally, the emphasis in ore and reserve inventory has been to provide fairly simple definitions and presentations for reporting to shareholders and the investing public. The recent introduction of the mineral resource category aims to take into account the "part of the deposit that cannot yet be produced or extracted legally and profitably." Recent proposals still place insufficient emphasis on relating resource/reserve reporting definitions more closely to the needs of mining and exploration operators for the estimation and inventory of these basic material assets.In most schemes, significant ambiguities and shortcomings remain. These concern the potential economic interest of resources, the concept of continuity which is fundamental to the estimation of volumes, mass and grades, the objectives of the production feasibility study and the requirements of the geology, engineering and economic appraisals leading to it, and the "availability" of the permits required to start mine development. Up to now, no industry-wide formal consensus has yet been reached for any of these steps, nor for reconciliation between successive statements.A resource/reserve inventory scheme is presented here that is based on ISO 9000 principles and the Australasian system. Explicit criteria and transition points are proposed to define resource and reserve. Similarly, appropriate criteria are proposed to classify the three mineral resource and two ore reserve categories, based on geological and value continuity and on the objectives of the feasibility study. This scheme offers a way to develop ISO 9001 certification of resource/reserve estimation procedures for mining operations and supply exploration companies with an appropriate inventory system, to allow better information for the shareholders and the investing public.Résumé - L’objectif des inventaires des minerais et des réserves est, depuis le début du siècle, de fournir des définitions simples et d’ordre général visant les actionnaires et le public investisseur. L’introduction d’une catégorie de « ressources minérales » fournira un cadre tenant compte de la "portion d’un gisement qui ne peut encore être extraite ou exploitée légalement et à profit." Cependant, les propositions récentes de systèmes d’inventaires ne comportent pas des définitions des ressources et réserves qui tiennent compte suffisamment des besoins des opérateurs en exploitation et en exploration minière.La plupart des systèmes comportent des ambiguïtés et des carences. Citons la susceptibilité d’exploitation commerciale des ressources, la continuité qui est au centre de l’estimation des volumes, masses et teneurs, les objectifs de l’étude de la faisabilité de la mise en production, le niveau requis des travaux de géologie, d’ingénierie et d’économique qui y mènent, ainsi que la disponibilité des permis dont dépend la mise en production. Il n’y a jusqu’à maintenant aucun consensus dans l’industrie sur ces points, ni sur des procédures de réconciliation entre les estimations successives.Le système d’inventaire des ressources/réserves proposé ici s’appuie sur la structure ISO 9000 et le système australien. Des critères et des points tournants explicites sont établis pour définir les ressources et les réserves. De même, les définitions des trois catégories de ressources et deux catégories de réserves, s’apparent sur la continuité de la géologie et des teneurs et sur les objectifs de l’étude de la faisabilité. Ce projet offre une voie pour développer les critères de la certification ISO 9001 pour les opérations minières, tout en fournissant un système approprié d’inventaire aux compagnies d’exploration, pour mieux informer les actionnaires et les investisseurs potentiels."

Jan 1, 1998

By L. A. Roe, John Jan

Iodine is a soft, lustrous, grayish-black nonmetallic element with a density of 4.9. It is the least active of the four members of the halogen family. The other members are, in order of increasing activity, bromine, chlorine, and fluorine. Iodine is a solid at ordinary temperatures, while bromine is a liquid and chlorine and fluorine are gases. Iodine melts at 113°C and volatilizes at 184.4°C to a blue-violet gas with an irritating odor. It occurs in nature only as iodates and iodides or other combined forms. It was discovered by Bernard Courtois in France in 1811, who noticed its presence as an unknown substance in crude soda ash obtained from burning seaweed. Gay-Lussac recognized it as a new element and named it iode, from the Greek word "ioeides or iodes" for violet color (MacMillan, 1970). The world production is not known with any great certainty, but it is probably between 25 and 35 million lb per year, of which about 30% is consumed in the United States. Geology and Mineralogy Iodine compounds occur as a minor constituent as a mineral in the Chilean nitrate deposits and in solution in brines and seawater. According to the US Geological Survey, it is the 47th most abundant element in the earth's crust. The minerals lautarite, Ca (I03)3 (calcium iodate), and dietzeite, Cat (103)2 (CrO4), (calcium iodate-chromate) are found in Chilean nitrate deposits which are located in Antofagasta and Tarapaca provinces on the eastern slope of the coast range in a desert area. Various brines contain iodine compounds. Seawater contains about 0.05 ppm of iodine and some seaweeds will extract and accumulate it up to 0.45% on a dry basis. Some coals in West Germany also contain iodine compounds. The known and potential sources of iodine reported in 1968 are given in Table 1. Table 2 lists estimated world iodine reserves. Iodine has been recovered from brines in Java, Indonesia, France, England, and the USSR. Iodine has also been recovered from seaweed in Ireland, Scotland, France, Japan, Norway, and the USSR. The indicated reserves and future resources of iodine are large but have never been adequately measured. Analysis Iodine as the free element can be detected by the characteristic blue color it gives to a starch solution. Quantitatively it is determined as the free element by titration with standard thiosulfate solutions using starch as an indicator. Colorimetric methods are also applicable. Markets and Prices Iodine and its compounds are generally marketed in the form of: iodine, crude; iodine, resublimed; calcium iodates; calcium iodide; potassium iodide, sodium iodide, and numerous organic compounds. Product Specifications Crude iodine, World market: 99-99.5% 12. Crude iodine, US produced, average: 99.8% 12. Crude iodine, USP XVII Specs: not less than 99.8% percent I2. Resublimed iodine is usually 99.9% and ACS specifications call for not over 0.005% total bromine and 0.020% nonvolatile materials (Anon., 1971). Prices, c.i.f. United States, for iodine have been steadily increasing from $1.18 per lb of crude in 1967 to $6.37-7.27 in January 1981 (Anon., 1981). In 1980 the price of iodine increased by 50%.

Jan 1, 1983

A banquet, attended by 467 members and visitors, was held at the Wanderers Club, Johannesburg, at 8 p.m. on Friday, 21st March, 1969, to celebrate the 75th Anniversary of the founding of the Institute. Introduction of Dr Carel de Wet R. C. J. Goode (President) Dames en here: Ons het 'n aantal vooraanstaande gaste in ons midde vanaand en mnr Maxwell sal u later meer van hulle vertel. Dit is my aangename plig om u voor te stel aan sy Edele, die Minister van Mynwese, van Beplanning, en van Gesondheid, Dr de Wet en sy gade, mev de Wet. Sy Edele Dr de Wet het geen bekendstelling nodig nie-alhoewel hy ons minister vir slegs die afgelope twee jaar is, het hy reeds talle funksies van ons Mynbedryf bygewoon en het baie vriende gemaak onder ons. Hy het homself baie bemind onder ons gemaak toe hy Wes-Driefontein onlangs besoek het om hulle ondersteuning en aanmoediging aan te bied in hulle uur van nood. The Honourable Dr de Wet was born in the Free State. He is a grandson of that very famous general Christiaan de Wet, who caused so much pain to the British forces and for so many months so successfully eluded them in the Transvaal and Orange Free State. He was educated at both the Pretoria and Witwatersrand Universities. He first practised medicine at Boksburg and then moved to Vanderbijlpark, so you see he has an early association with gold mining on the Witwatersrand, and in moving to the Vereeniging-Vanderbijlpark district he became closely involved in our coal mining and metallurgical industries. South Africa's first steel was poured from a l0-ton open hearth furnace belonging to the Union Steel Corporation in Vereeniging in 1913. Dr de Wet has been mayor of Vanderbijlpark and for several years has been their member of parliament. More recently, the Honourable Dr de Wet has filled with great honour that most important office of Ambassador for the Republic of South Africa in London. At present he wears two hats, in that he is Minister of Planning and of Health, but more important is his cloak, that of Minister of Mines, which I trust offers him the greatest comfort. To fulfill these three arduous tasks must demand of him a terrific devotion to duty, and in doing this he carries on that loyal tradition of service to his fatherland so evident in his grandfather. Dames en here, dit is vir my 'n groot genoeë om Sy Edele Dr de Wette vra om 'n heildronk in te stel op die Instituut vir Mynwese en Metallurgie. Toast to the Institute of Mining and Metallurgy Dr the Honourable C. de Wet (Minister of Mines): Mr President, ladies and gentlemen, Mr President you have introduced me gracefully to this distinguished company and I am appreciative of your remarks. I am fully conscious of the responsibilities that devolve upon me as Minister of Mines in a country where mining makes so vital a contribution to economic progress and development and has, in fact, laid much of the foundation on which our present proud edifice is built. The achievements of the mining and metallurgical industry in its diversified activities arouse feelings equivalent to paternal pride, but let me speedily add that in considering any family relationship that may exist, the Minister of Mines should not be regarded in the role either of a fairy godmother or an indulgent father.

By David J. Starbuck

For small precious metals mining to show a comeback a different perspective must be taken than that of larger mining companies. This perspective must be much the same as that of past successful smaller mining enterprises such as when the US had a need for Uranium. Abandoned mines and environmental concerns in older mining districts have discouraged many from entering with the attitudes of why try there if so many unsuccessful mines exist. A small mining venture can be successful there but must have a "think smart'' attitude. There must be a thorough understanding of deposits, utilization of advanced technology and a properly managed mining operation. "THINK SMART" MINING The small mine operator is usually looking for small high grade deposits, consequently, long term success depends on a series of small successful mining operations. The small miner must succeed right-off or credibility and future project funding will suffer. No veteran of even a few years in the mining industry needs to be told that a dollar spent on production today fails to yield as much as it once did. More efficient equipment and techniques have helped soften the problem, but there is little likelihood that a mining company can do much to control inflation, wages, regulations, or grade. That leaves the small miner to "think smart" as one area where operating dollars can still be stretched to produce more than they presently do (Gardner. 1981). In the planning stage of a mining venture, when most options are still open, the main controllable elements are market timing, deposit selection, cutoff grade, mining method, mine design, mining sequence, rate of production build up, process design, project financing structure, project management, and project ownership structure. During planning, optimum criteria can be established for each of these. Once a mine is in production, these options are foreclosed or at least severely constrained. The more thought given to a mining program using all information available the less the risk of encountering disabling surprises. Thus the intent of this paper is to suggest the "think smart" attitude most small mine operations use for long term success. If one looks at a number of successful mining ventures, whether large or small, there is a general logic most have followed to be successful. They have used proven exploration, mining and processing techniques along with economic evaluation and experienced personnel to improve their odds. LOGIC IN DEVELOPING A FEASIBLE VENTURE Most successful small mine ventures achieve positive cash flow as quickly as possible by seeking out those deposits which require the least time and expense on activities leading up to production. To do this they look for deposits that are the most accessible, easily investigated, mined and processed with the cheapest fundamental methods. The general sequence of events starting with district selection are deposit selection, preliminary feasibility, exploration, detailed economic feasibility, mine planning, development and production. Each successive step becomes more costly requiring intermediate decisions along the way. District Selection Small operations should look for known deposits which favor the occurrence of the type deposit sought rather than efforts in unproductive areas. Known deposits in developed areas have some advantages over remote areas: 1. More alternative methods of transportation are available. 2. A larger stable work force is available. 3. The area is usually more pro-mining. 4. Power, water, housing, technical services, skilled services, schools, recreation and shopping are available.

Jan 1, 1987

By W. C. Hagel, H. J. Beattie

Phases present at 2200° and 1500°F (1204° and 816°C) were identified in sixty wrought developmental austenitic alloys possessing wide compositional variations. The bases were iron-, cobalt-, and nickel-rich as well as a base with equal parts of each. There are only two structure types previously not found in similar alloys, viz .-the Co3 W and the Fe3Al types. A molybdenum-rich monocarbide decorates dislocations with unusual clarity. Other results provide correlations between alloy composition and phas e precipitation. Grouping intermetal -lic phases into three general classes : I) geometrically close-packed, 2) topologically close-packed, and 3) bcc derivatives, the nickel base prefers the first, the iron base the second, and the cobalt base the third—each base tending to shun the other two classes. Thus, a crystal-chemistry effect previously noted by Laves and Wallbaum can he expanded for these Group VIII elemental bases. There appear to he no quaternary or higher -order structure types requiring more than three atomic species. AFTER studying aging reactions in many diverse commercial austenitic alloys1-4 as a function of detailed time-temperature variations in heat treatment, it became apparent that matrix composition influenced structure types and morphologies to a large extent. These tendencies were related4 to a crystal-chemistry effect uncovered by Laves and Wallbaum.5,6 We have now directed our efforts to exploration of the whole ternary field, covering the standard base elements—iron, cobalt. and nickel— with 10 to 20 pct Cr and moderate amounts, up to 10 pct, of the usual alloy additions. Solutioning and aging treatments were held constant with major emphasis on X-ray identification of microconstituents. The possible existence of exceptions to the Laves-Wallbaum effect, or any new phases, was sought. Phases appearing in austenitic alloys can be classified as geometrically close-packed (gcp), octahedral or nonoctahedral interstitial compounds, topologically close-packed (tcp), semicarbides, and bcc derivatives. Crystal structures of the first four classifications can be visualized as a dense packing of semirigid spheres of different sizes, while the bcc derivatives represent a less efficient packing of spheres. The Laves-Wallbaum effect involves the gcp and tcp phases. Gcp phases possess both tetrahedral and large octahedral interstices; examples are Ni3Ti(n), NiSAl(y'), Co3W(E), and other ordered AB3 compounds where B atoms are smaller than A. Their precipitation is primarily intragranular, presumably coherent with an austenitic matrix, and a chief source of strengthening. Most octahedral interstitial compounds (e.g., CbC, Tic, TiN, Mo2C) have a gcp lattice of large metal atoms which accommodate small carbon or nitrogen atoms in the octahedral interstices. The compound Ti2SC, previously designated Y phase or T phase, can, with some reservation due to its partial co-valency, be placed in this category.7 The nonoctahedral interstitials (e.g., M7C3, Fe3C) represent close-packings of spheres in structures that provide larger triangular-prism interstices for carbon, since the octahedral interstices formed by chromium and iron atoms are too small. Tcp phases possess only tetrahedral interstices; examples are Laves (Fe2Ti, Fe2Cb, Fe2W...AB2), p(Fe7MO6, Co7W8.... A8B7), and (FeCr, Co2Cr3)

Jan 1, 1965