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By Guo Jun

In this study, BaTiO3 ultrafine particles surface-modified with stearic acid were synthesized by the hydrothermal method in a system of BaCl2-TiCl4-NaOH. The effects of NaOH/TiCl4 molar ratio, Ba/Ti ratio and time on structure and morphology of BaTiO3 ultrafine particles were investigated experimentally. The formation mechanism of different crystalline BaTiO3 particles was discussed, and it is considered that in a hydrothermal system, the main factors determining BaTiO3 crystalline are H+ replacement of Ba2+ causing H+ deficiency and anatase growth units involving in crystal growth, which clogs the axial channel for Ba2+ transference. By means of increasing the alkalinity of system and barium content, H+ deficiency and involvement of anatase growth units in crystal growth could be effectively controlled. The results show that when molar ratio of NaOH to TiCl4 is 9 and ratio of Ba to Ti 1.5, and time 8 hours, high purity tetragonal BaTiO3 ultrafine particles with a narrow grain-size distribution and nonpolar surface are obtained at 240oC. The particles have excellent flowability, which is ascribed that the surface polarity of barium titanium powder modified with stearic acid is changed and the interaction between the particles is weakened.

Jan 1, 2006

By E. Alan Haley

Accurate and economic control of line and grade on long tunnels, large structures, excavations and waterways has been a problem to surveyors and engineers for decades. The conventional method of surveying, incorporating a level, transit and a number of surveying technicians, has proven to be a very expensive and time-consuming operation. Now, however, engineers have adapted the laser to help ease the problems of surveying, at the same time increasing the efficiency of such operations. The laser, which projects a continuous, narrow red beam of brilliant light, provides a constant alignment reference that does not interfere with personnel or equipment. A complete laser alignment system, specifically designed for and suited to a variety of mining and tunneling operations, has been developed by the Perkin-Elmer Corp. The engineering significance of this development can be fully realized when it is noted that, aside from potentially tremendous economic advantages in terms of labor savings, the laser beam provides a system of alignment that is at least ten times more accurate than presently used optical systems. The new laser system provides accuracies within 10 microinches per foot (1 x 10-5in.) when used with an accessory centering detector. In one of its first field trials, the laser was used for alignment of a two-mile tunnel which showed a total deviation of less than 5/8 in.

Jan 4, 1968

By Theodore Nagel

Fuel-oil, natural gas and coke oven gas, producing the higher temperatures of open-hearth current practice, have been gradually displacing producer gas the lowest cost fuel for open hearth operations. The lower temperatures of combustion products from producer gas is caused by nitrogen dilution. Practical Application of Combustion Thermochemistry One pound of carbon burned to CO produces 3,960 B.T.U. and one pound of carbon burned to C02 produces 14,140 B.T.U. The second unit of oxygen uniting-with gasified car-bon (-CO) produces (14,140 - 3,960) 10,180 B.T.U. which is;(10,180 - 3,960) 6,220 B.T.U. more heat than produced by the first, unit of oxygen forming CO by uniting with solid carbon. A review of the relative combustion heating values of commercial gaseous fuels reveals CO requires a minimum of air for combustion, and because of minimum nitrogen dilution and the high thermal release from CO higher temperature combustion products are produced from CO than from natural gas or from coke-oven gas under similar combustion conditions. Inert nitrogen diluent lowers the calorific value of fuel gas and its diluting effect is cumulative in lowering the temperature of the products of total, combustion. It is not only logical but, practical in partial combustion, converting bituminous coal to gas, to generate the gas, with reduced nitrogen dilution.

Jan 1, 1936

By Theodore Nagel

Fuel-oil, natural gas and coke oven gas, producing the higher temperatures of open-hearth current practice, have been gradually displacing producer gas the lowest cost fuel for open hearth operations. The lower temperatures of combusts on products from producer gas is caused by nitrogen dilution. Practical Application of Combustion Thermochemistry One pound of carbon burned to CO produces 3,960 B.T.U. and one pound of carbon burned to C02 produces 14,140 B.T.U. The second unit of oxygen uniting with gasified carbon (CO) produces (14,140 - 3,960) 10,180 B.T.U. which is (10,180 - 3,960) 6,220 B.T.U. more heat than produced by the first unit of oxygen forming CO by uniting with solid carbon. A review of the relative combustion heating values of commercial gaseous fuels reveals CO requires a minimum of air for combustion and because of minimum nitrogen dilution and the high thermal release from CO higher temperature combustion products are produced from CO than from natural gas or from coke-oven gas under similar combustion conditions. Inert nitrogen diluent lowers the calorific value of fuel gas and its diluting effect is cumulative in lowering the temperature of the products of total combustion. It is not only logical but practical in partial combustion, converting bituminous coal to gas, to generate the gas with reduced nitrogen dilution.

Jan 1, 1936

By S. S. Klima, A. L. Mazzella, J. S. Driscoll, T. W. Beck

Previous testing was performed by researchers at the National Institute for Occupational Safety and Health (NIOSH) to improve longwall dust control using underside shield sprays with a longwall directional spray system. This testing provided encouraging results toward respirable dust exposure reductions for longwall personnel, achieving as high as 99% dust reduction at some sampling locations along the longwall personnel walkway. Additional laboratory testing was conducted to test these underside shield sprays in conjunction with a shearer-clearer spray system located on the longwall shearer body. The purpose of this testing was to determine if the underside shield sprays interacted positively or negatively with the shearerclearer sprays. Results from this testing indicate that while the shearerclearer system influences where the respirable dust particles are directed, underside shield sprays can still lower respirable dust exposure for longwall personnel.

Mar 2, 2022

By J. E. Nesset, F. Rosenblum, J. A. Finch, R. Payant

ABSTRACT Under certain conditions of moisture and oxygen, sulphides can spontaneously self-heat. We tested a hypothesis that galvanic interaction between some sulphides can promote self-heating. Galvanic interaction is controlled by the rest potential difference between sulphides and particle size. A series of binary sulphide mixtures was tested. Individual sulphides and mixtures with low rest potential difference did not self-heat, but mixtures of high rest potential difference did. When testing pyrite-sphalerite mixtures, self-heating increased inversely with particle size, with the fineness of the pyrite governing self-heating, indicating the rate-limiting step is the reduction reaction. The results support the hypothesis that galvanic interaction contributes to sulphide self-heating. A possible mechanism based on hydrogen sulphide as an intermediate product is proposed. The understanding gained will be of interest to those involved in storage, shipping, and disposal of sulphides.

Jan 1, 2012

By Mitchell M. A

The steeply dipping Mammoth orebody is mined by Gunpowder Copper Limited using a sub- level uphole bench stoping method at a mining rate of 350 000 tonnes per year. of three per cent copper ore. Access to the mine, is provided by 1 in 9 decline which spirals in the footwall connect-, ing all the sublevels, thus maximising mobility and accessibility of trackless mining equipment Sublevels are driven in ore off cross- cuts from the decline every 15 metres vertic- ally. Sublevel drives are stripped out to widths up to 18 metres before cutoff slots are mined at each end. A two boom fan drilling jumbo is used to drill inclined rows of holes to the floor of the sublevel above. Two or three rows are fired at a time which allows broken ore and remnants from the level above to be mucked out by rubber tyred LHD equipment to the brow. Ore widths of up to 80 metres are en- countered at lower levels where ring drilling from longitudinal drill drives will break ore to a draw point system below. Development is carried out with three boom rubber tyred jumbos. All haulage from the mine is in 20 and 35 tonne rear dump trucks. All aspects of the mining operation are discussed including ventilation, pumping and drainage, services and future planning.

Jan 1, 1974

By Harry M. Edenborn, Richard W. Hammack

Experiments were done to determine if a mushroom compost-based sulfate reduction system could be used to treat nickel-contaminated mine waters. Sulfate reduction systems were established in columns containing acid-washed mushroom compost. Simulated mine waters containing 2000 mg/L sulfate and 50 to 1000 mg/L nickel were adjusted to pH 4.5 and pumped through the columns at flow rates between 15 and 25 mL/hr. During the first nine days of operation, virtually all influent nickel was removed in the columns by sorption and ion exchange mechanisms. The nickel removal rate then dropped to 18 to 30 mg Ni/day (7.8 to 12.8 nmol/ g-substrate/day), probably due to low sulfate reduction rates. When sodium lactate was added to the inflow, a sustained and seven-fold increase in the nickel removal rate was observed. Bacterial sulfate reduction rates measured in mushroom compost-based wetlands exposed to coal mine drainage are 2 to 20 times faster than the rates observed in this study. Low sulfate reduction rates in the columns may have been due to the inhibition of microbial activity by high nickel concentrations and the removal of labile organic compounds from the mushroom compost substrate during acid-washing. Results of this study indicate that bacterial sulfate reduction can effectively treat nickel concentrations up to 500 mg/L if labile carbon is nonlimiting.

Jan 1, 1992

Diffusion in Solid Metals. BY ROBERT F MEHL (Institute of Metals Division Lecture Tech Pub 726 in Metals Tech, Aug , also Trans, vol 122 22,500 words ) Diffusion in solid metals constitutes one of the important fundamental phenomena in metallurgical behavior Apart from its obvious importance in processes such as chromizing, carburizing, nitriding and calorizing, it plays an important part in the processes of homogenization, age-hardening, and transformations in steel, its scientific importance is no less great Diffusion may occur within a grain, along a grain boundary, or upon a surface, though the exact and even the relative values of these separate processes are known for only a very few cases The requirement of solid solution formation presents the possibility of identifying solid solution phases by a study of diffusion layers Some distortion accompanies diffusion, leading to little¬ understood grain-size changes Distortion assists diffusion though usually it dis¬appears before diffusion has become extensive In a binary system the rate of diffusion is the more rapid in the lower melting metal Many of the published data are too qualitative to permit sound scientific conclusions Age-hardening data may be treated as diffusion data and rates of reaction in steel could profitably be studied from this point of view Studies on diffusion are of great importance to the develop-

Jan 1, 1937

By E. L. Litchfield

Spark ignition of combustible-gas mixtures is a relatively old subject of investigation and has been treated both experimentally and analytically by many people. Elements of static and current electricity are almost always present in mining and industrial operations, and the spark can be an extremely efficient source of ignition. Thus the practical interest of such problems as the "intrinsic safety" of electrical apparatus is obvious. Ignition and quenching phenomena are the primary laboratory representatives of combustion phenomena that are dynamically nonsteady, and such nonsteady phenomena playa considerable part both in industrial processes and in safety matters, although they are of less immediate practical interest. Considerable effort has been expended by the Federal Bureau of Mines in investigations of spark ignition.5 6 7 8/ Primarily, this work has established the significance of several of the parameters involved. Although the

Jan 1, 1959

By R. Harris

Blister copper melts of 800 g to 1000 g containing less than 1 wt % S and up to 3 wt % Ni were desulfurized at 1523 K in air or by a pure oxygen jet blown at 75,500 and 1000 cm3/min, from 1 cm above the melt. Rates of desulfurization and oxygen pickup were measured and visible surface phenomena were photographed and videotaped. It was observed that SO2 was evolved from Cu-S melts in a manner reminiscent of the effervescence seen in carbonated drinks. The effervescence lasted up to 20 minutes and resulted in the ejection of material up to a height 50 cm above the melt surface. Sporadic discharge of large bubbles was also observed in a Ni containing melt top-blown with oxygen at 1000 cm3/min. The Cu-S melts top-blown with oxygen experienced faster sulfur elimination as compared to stagnant melts exposed to air and experienced only a single period of turbulent SO2 evolution, which occurred almost immediately after oxygen injection commenced. The Cu-S melts exposed to air experienced multiple episodes of effervescence. The stagnant blister copper melt containing nickel did not exhibit effervescent behaviour and experienced a lower rate of sulfur elimination compared to Cu-S melts tested under similar conditions. The present article examines the role of surface phenomena in determining the observed behaviour.

Jan 1, 1999

By A. Unal, H. Sevim

The utilization of high-sulfur Illinois coal by utility plants has been decreasing since the enactment of the 1990 Clean Coal Air Act Amendment. Illinois coal producers can make their coal more attractive by offering the choice of taking the coal combustion and flue-gas desu furization products from the utility plants and placing them in the abandoned sections of their mines To be competitive, however, coal producers need to select an environmentally acceptable transportation-handling-placement system through which the cost-per-ton of product disposed of can be minimized In this paper, several such systems are presented The favorable operating conditions of each system are determined in terms of distance and tonnage ranges. For a 90 kt/year (100 thousand stpy) operation, it is found that, up to a distance of 150 km (93 miles), transporting products by truck would be less expensive than using rail cars and intermodal containers. Also, a case study is given in which a cost analysis is conducted for an underground coal mine receiving products from two Illinois utility plants. At 90 kt/year (100 thousand stpy) and a distance of 40 km (25 miles) between the power plant and the mine, it is found that truck transportation and under ground placement would cost $0.090/tkm ($0.131/st-mile) and $2.98/t ($2.70/ st), respectively.

Jan 1, 1999

Australia, with its fast-growing economy and high standard of a~ living, has a high and rapidly increasing per capita consumption of energyIn total terms, Australia's energy requirements are doubling every 15 years, and among mature Western economies Australia ranks behind only Italy-and Japan in the rate of increase of energy consumption.The use of energy is often accepted as a yardstick of development and on this basis Australia might well congratulate itself on its high energy consumption. However, it is less well recognised that the resources absorbed in the production of energy represent a real cost to the* community, and that just as we strive for industrial efficiency or farm productivity we should strive for economy in the use of energy fuels.Australians spend annually an estimated ú500 million.on all forms of energy, a sum which represents about seven per cent of the Gross National Product. In all, energy production and distribution absorb the employment of more than 100,000 persons. In addition, the annual capital investment by.the oil industry amounts to some E55 millions, by the coal industry about ú12 millions, and by electrical and gas authorities some E108 millions, in total representing more than ten per cent of annual investment in other than private motor cars and housing,

Jan 1, 1962

By Thomas P. Meloy, Duane T. Eppler

The science of particle shape analysis has expanded rapidly in the decade since precise numerical-statistical techniques were developed for use in characterizing the shape of closed forms. Use of Fourier descriptors permits shape to be quantified to whatever degree of precision is required. With this technique, particles and particle systems can be compared either on the basis of shape characteristics displayed by individual particles, or on the basis of aggregate shape characteristics representative of large samples of particles. Shape characterization work completed to date has shown that the physical characteristics of particle systems (porosity, permeability, strength, mechanical stability, chemical reactivity, and flow characteristics (viscosity)) are related directly to particle shape. Furthermore, it has been shown that particle shape is a function of chemical composition, process of formation, and post-formational history of the particle. In this light, particle shape analysis has potential applicability to a host of engineering and industrial problems encountered in processing particulate material. It can be used to optimize the efficiency of separation processes and particle feed systems, to trace particle pathways through processing systems, and to monitor the operation of specific processes, the wear of critical machine parts, and the quality of end products in processing systems. In this paper we discuss these specific applications of shape characterization to particle processing.

Jan 1, 1980

Here, published for the first time, is the group of Anaconda officials (New York office) concerned with the planning and operations of the company's copper properties in Chile.

Jan 1, 1952

By J. E. Murphy

A method is being developed by the Federal Bureau of Mines for recovering lead metal from galena without the generation of SO2. Lead chloride is obtained by leaching lead concentrate at a temperature of approximately 100° C with FeCl3 solution: PbS + 2FeCl. " PbC1 2 + 2FeC1 2 + S. Electrolysis of the PbCI 2 product in a fused-salt bath results in deposition of molten lead metal at the cathode and evolution of chlorine at the anode. The chlorine can then be absorbed in the spent leach solution to regenerate FeCl3 for recycling. Optimum electrolyte composition was a PbC12-LiCl eutectic containing 7.6 wt-pct LiCl. The PbCl2-NaCl eutectic also proved satisfactory. Electrolysis in the PbCl2-LiCl bath at 450° C yielded 99 pct current efficiency at a current density of 5 amp/in2 with an energy requirement of only 0.24 kW-hr/lb metal produced. This compares with 98 pct current effi¬ciency and 0.26 kW-hr/lb metal produced for the PbCI2-NaCI bath. A typical lead deposit contained less than 100 ppm total detectable metallic impurities. At the low temperature employed for electrolysis, there was essentially no vaporization of Pb or FbC12.

Jan 1, 1974

By Dennis Dolinar, Christopher Mark, Gregory M. Molinda

In 1999, 2,087 unplanned roof falls were reported from 841 mines. Nearly 55% of all mines reported at least one roof fall, and nearly 17% of the mines reported five or more falls. In order to investigate the variables that contribute to roof falls, the National Institute for Occupational Safety and Health (NIOSH) compiled a national database of roof performance from 37 coal mines. Geotechnical factors and their effect on roof fall rates were compiled from over 1,500 miles of drivage. The factor that is the best predictor of roof fall rate is the Coal Mine Roof Rating (CMRR). For a low CMRR (#30), almost all cases have high roof fall rates. Conversely, high roof fall rates are rare for strong roof rocks (CMRR $ 60). Roof fall rates were also higher in deeper mines, probably because of greater stresses. Intersections were much more likely to fall than roadways, and four-way intersections were more prone to fall than three-way intersections. In a controlled comparison of the effect of increasing bolt length on roof fall rates, it was found that longer bolts reduced the roof fall rates in 11 of 13 cases. A relationship between the roof fall rate, the intersection span, and the CMRR was also found. Finally, a systematic method for tracking roof performance and geotechnical variables was demonstrated.

Jan 10, 2000

By Robert O. Davis, Phillip A. Abbott

The response of geologic materials subject to nuclear weapon effects is of considerable interest in the design of buried protective construction. Recently, more consideration has been given to placing such structures in rock rather than in soil. Although rock has the obvious advantages of high strength and low deformability, discontinuities such as joints and fault planes severely complicate any response analysis. Nevertheless, some knowledge of the effects of these discontinuities must be developed, even if that knowledge remains largely qualitative in nature. In this paper, we present a constitutive description of cracked rock subject to uniaxial shock loading. The constitutive equations are based on certain average response characteristics of a particular cracked rock model. Rather than attempt to represent each material discontinuity individually, we have incorporated the discontinuity effects into constitutive relationships for a continuous medium. The resulting equations are suitable for use in hydrodynamic computer codes presently used for ground motion calculations. APPROACH The continuum description which will be presented below is based on a detailed analysis of a particular cracked rock model. This model can be visualized as a sequence of plates (representing the intact rock) separated by gaps (representing the discontinuities). This so-called "plate-gap" model was first used by Thouvenin (1) in an effort to explain the behavior of porous materials at high

Jan 1, 1971

By J. Peck, M. J. Scoble, C. Hendricks

This paper is based on field studies in North American surface mines. The work involved the adaptation of microprocessor-based instrumentation to monitor various operating parameters on-board rotary blasthole drills and mining shovels. Following a review of instrumentation and monitoring methodology - drawing on experience gained under field conditions-the paper will focus on the application of monitoring technology within the framework of an Integrated Equipment Monitoring System. Such a system will permit real-time performance evaluation of key equipment involved in surface mine production. Drill performance monitoring has been demonstrated through work to date, to provide significant input into blast design, reserve estimation, mine planning and production control processes, through an improved facility for ground characterization. Monitoring excavation equipment has been proven valuable in assessing how effectively the input from drill monitored data has been used in the evolution of blast designs. This specifically refers to assessing blast efficiency through measuring associated levels of excavator performance in relation to muckpile characteristics. The medium-term goal of equipment instrumentation and monitoring has been to assist mines in optimizing the overall rock breakage and handling process. Based on the reported results, this has been accomplished. Long-term efforts now concern using a greater understanding of equipment performance and response to varying operating conditions as a foundation for the implementation of mining automation.

Jan 1, 1993

By George M. Schwartz

WHEN reviewing the progress made in mining geology for the year 1953, one might say that not much has been accomplished and, indeed, in a subject such as economic geology not much progress should be expected in the 10 months of the year which elapsed before this article was prepared. This seeming lack of progress, however, disappears when the facts are investigated a bit. There undoubtedly are more economic geologists at work than ever before. It is probably not an exaggeration to say that more geologists are now employed by a single company in the Lake Superior district than were employed in the whole district 20 years ago. In most mining districts geologists are busy with numerous problems of production, development, and exploration and some give an occasional thought to the scientific problems of the science, or rather the art, of mining geology. In fact, this very intense activity of mining geologists is one reason why progress seems slow; they do not have time to write up results of investigations. There is also a great amount of work being done which is not released because of company policy. Conditions have improved very much in recent years but mining corporations, in general, have some distance to go before attaining par with the petroleum industry in this respect.

Jan 2, 1954