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By Samuel B. Christy

The present paper is a continuation of a study of the reductionworks of New Almaden, the first part of which was published under the title " Quicksilver-Reduction at New Almaden," in the Transactions of this Society, vol. xiii., p. 547.* Frequent reference will be made to some of the data there given. The following is an outline of the contents of this paper: I. Condensing appliances used at New Almaden: a. Brick condensers, b. Iron condensers—flues and " water-backs," c. Glass and wood condensers, d. Friction-coudensers—filters and revolving screens, e. Flues, towers, and chimneys. II. Analysis of condensing-systems. III. Temperature of condeusers. IV. Product of condensers. V. Treatment of soot. VI. Losses of treatment: a. Nature of losses, b. Composition, weight, and volume of dry gases, c. Volume of wet gases, d. Specific weight of quicksilver vapor, e. Vapor-loss at various temperatures. VII. Comparison with New Almaden practice. VIII. Comparison with results at Idria, Austria. IX. Comparison with results at Almaden, Spain. X. Future improvements in quicksilver-condensation. I. Condensing Appliances. The complete condensation of mercurial fumes in a large way presents numerous practical difficulties, familiar to all who have had to retort amalgams. In condensing the quicksilver-fumes discharged

Jan 1, 1886

By Gordon Revey

The challenge of managing blasting risk, types of risk, public perception, and a system for managing risk were covered in the first part of this article in the May/June 2000 issue of the Journal of Explosives Engineering. This final part of this two-part series provides a method for identifying specific blasting risks and reviews the importance of community relations.

Jan 1, 2001

By J. I. Schoenherr, G. Schubert, T. A. Baloun

The currently known and used plastics and rubber recycling or sorting processes cannot be applied efficiently and economically due to large amounts and different numbers of plastics types as well as of fine bulky materials (<4mm). These wastes are mostly given to land-fill sites. Thermal adhesion seems to be a great means to efficiently separate plastics mixes. Tests carried out at a special lab-scale testing unit (TaA1) confirm the effectiveness and feasibility of the separating mechanism. The thermal properties of the individual types of plastics differ from each other to a sufficient degree so that special products or product mixes of high material purity can be obtained according to the respective requirements. For this reason, plastics mixes such as PE and PP can be sorted with very good results. The separation efficiency is influenced only by different contact surfaces. The contact period can be adjusted to a short period of time so that sorting large amounts of fine dispersed plastics seems feasible. Sorting processes in feed streams were shown to be technologically effective when applying appropriate technologies. For the time being, the technological application of a thermal adhesion drum separator (TaTr1) is suitable. First tests on such a pilot-scale unit provided good separation results.

Jan 1, 2004

A revolutionary development in blasting materials has occurred in the past 5 years. Ammonium nitrate, sensitized by the addition of a few percent of No. (class) 2 diesel fuel or other suitable petroleum product, has been adopted as a low-cost, efficient blasting agent2/ by a wide variety of mining and heavy construction operations. Moreover, ready availability of the component supplies throughout the Nation and ease of their formulation into effective blasting agents have made it possible for the blaster himself to pre-pare the mixes at the site of use. Although these field-mixed products have partly or wholly displaced explosives such as dynamites in some applications, there are other blasting operations where the fuel-sensitized ammonium nitrate agents do not appear to be well adapted. Important safety characteristics are inherent in ammonium nitrate-based blasting agents prepared under competent factory control, or when field mixed under equivalent close control--as long as the hazards they present are clearly understood and respected. This publication attempts to summarize knowledge of those hazards and to incorporate practical ways to cope with them. A series of safety recommendations thus is presented. These recommendations cover the preparation, storage, transportation, and use of field-mixed ammonium nitrate blasting agents.

Jan 1, 1960

By R. F. Campbell, R. F. Miller

SIXTEEN steels containing different combinations of chromium and molybdenum, in amounts up to 5 per cent of each element, were examined for microstructure and hardness after air cooling and after furnace cooling from suitable austenitizing temper- [ ] atures. Diagrams summarizing the structures and hardness resulting from these two cooling rates are presented (Figs. 3, 4, 7).† Data were also obtained on the influence of these two elements, individually and in combination, on the depth 0f decarburization observed after furnace cooling (Fig. 8). COMPOSITION OF MATERIAL The chemical composition of the steels investigated is given in Table I. The plain carbon steel was made in a 25-ton Heroult electric-arc furnace, while the alloy steels were made in a 4.5-ton Ajax-Northrup elec- [ ] tric induction furnace. The cast ingots were hot-rolled to I.75-in. bars. AIR-COOLED SERIES The I.75-in. bars were forged to flat plates, 0.25 in. thick, from which specimens 0.5 in. wide by 2 in. long were cut. The specimens were pretreated to improve their homogeneity by heating to I830°F. (1000°C.) for 20 min. and oil quenching. They were then reheated to I740°F. (950°C.) for one hour and air-cooled, after

Jan 1, 1941

By J. W. Walkiewicz

The Bureau of Mines investigated alloys containing mischmetal (MM), cobalt, copper, magnesium, and iron for use in permanent magnets in place of the scarce samarium-cobalt alloys. The magnetic properties of MM-Co, MM-Co-Cu, MM-Co-Cu-Mg, and MM-Co-Cu-Fe-Mg alloys were evaluated. Magnets were fabricated by powder metallurgy consisting of arc-melting the metals, crushing and grinding the resultant alloys, alining and compacting the powder, and sintering the compacts. Magnetic values of MHc = 4.7 kOe, BHc = 4.07 kOe, Br = 6.81 kG, and (BH)max = 10.0 MGOe were obtained with a MM-Co alloy containing 36±0.5 wt-pct MM. By substituting copper and magnesium for part of the cobalt, the values for MHc and BHc were increased to 29.0 kOe and 5.89 kOe, respectively. This intrinsic coercivity value exceeded that of Sm-Co alloy obtained in our laboratory. The addition of iron to MM-Co-Cu-Mg alloys resulted in an increase of Br to 6.90 kG and (BH)max to 10.3 MGOe. Copper and magnesium contents of these alloys were optimized to obtain maximum values of MHc.

Jan 1, 1981

By Donald K. Grubbs, Frederick B. Henderson, Glen T. Penfield

The technically troubled new LANDSAT-4/Thematic Mapper (TM) land observational satellite remote sensing system has provided dramatically new and important short wave infrared (SWIR) data, which combined with Landsat&apos;s Multi-Spectral Scanner (MSS) visible (VIS), very near infrared (VNIR), and thermal infrared (TI) data will greatly improve regional geological mapping on a global scale. The TM will significantly improve clay, iron oxide, bauxite, and nickel laterite mapping capabilities over large areas of the world. It will also improve the ability to discriminate vegetation stress and species distribution associated with lateritic environments. Examples of the application of remote sensing for nickeliferous and aluminous laterites are illustrated. Nickel laterites on Gag Island, Indonesia are defined by MSS imagery. Satellite imagery of the Weipa, Cape Bougainville, and the Darling Range, Australia bauxite deposits show the potential use of MSS data for exploration and mining applications. Examples of satellite and airborne synthetic aperture radar (SAR) for Jamaica and West Kalimantan, Indonesia document the use of this method for bauxite exploration. Thematic Mapper data will be combined with the French SPOT satellite&apos;s high spatial resolution and stereoscopic digital data, and U.S., Japanese, European, and Canadian Synthetic Aperture Radar (SAR) data to assist with logistics, mine development, and environmental concerns associated with bauxite and other lateritic deposits worldwide.

Jan 1, 1984

By Don Deardorff, Ke Yang, Yingcai Han, Ken Sorensen, Robert Kruger, Mark Petersen, Diane Fiorelli, Larry Goldfarb, Kathryn Petek, Kwabena Ofori-Awuah

Design of deep foundations for lateral loads requires an understanding of soil-foundation-structure response during loading. Lateral loads on a deep foundation (piles) could be due to earthquakes, winds, waves, and/or machine vibrations. Over the years, analysis of response of piles due to lateral loads evolved from closed-form solutions to p-y methods to strain wedge to finite element/finite difference modeling. Although analysis of lateral response of piles and shafts is routinely performed, there is no single guidance document and/or standard for design and testing. Several different analytical methods are available for the analysis, and the resulting design can result in significantly different responses which can create confusion. This is especially true for analyzing and designing piles in potentially liquefiable soils with lateral spread issues under seismic conditions.This guidance document is intended to assist geotechnical engineers, pile designers, and contractors in analysis, design, and testing of piles and drilled shafts for lateral loads. This document discusses the background of different analytical and testing procedures and presents the recommended methods for analysis, design and testing of piles for lateral loads.Chapter 1 defines the different kinds of lateral loads to which a single pile or pile group may be subjected. This first chapter also presents different types of piles used to resist lateral loads.Chapter 2 discusses geotechnical issues related to lateral pile design such as liquefaction and lateral spreading and other non-seismic issues. Also addressed in Chapter 2 is geotechnical site characterization (as related to lateral loads) in terms of site investigation, in-situ testing, geophysical testing, laboratory testing, and estimation of soil/rock properties.Chapter 3 discusses the background and available analytical methods and tools for the analysis and design of single piles and drilled shafts. Several methods of analyses from closed-form elastic solutions to the finite element/finite difference solutions and their applicability are discussed. Available commercial computer software packages for analyzing single piles and drilled shafts are also presented.Chapter 4 expands the discussion of single piles and drilled shafts into the analysis and design of pile groups. In addition, group effects, resistance of pile caps, results of previous experimental and analytical studies, and available analysis tools and software for pile groups are discussed.Chapter 5 presents the issue of lateral resistance of piles and drilled shafts as discussed in different national and international building and non-building codes. A summary of extensive research on several codes are presented to facilitate the compliance with different codes.Chapter 6 discusses structural design issues of individual piles and drilled shafts such as depth of fixity.Chapter 7 discusses soil structure interaction issues related to kinematic and inertial effects due to seismic loading and available methods of analyses.Chapter 8 discusses and presents the typical procedures for the lateral load testing of piles. This guideline was developed as an aid to the practicing engineer in providing information, direction and commentary on the lateral design of deep foundations. Although all reasonable effort has been made to accurately compile the material and information contained herein, no warranty is made with regard to any such material or information and the Deep Foundation Institute assumes no responsibility for any possible errors or any direct or indirect result of the use of any such material or information. It is not intended that this document address every factor affecting lateral design for every situation. Therefore it is the responsibility of the person utilizing information from this document to confirm that it is appropriate and correct for their situation as well as to understand and properly apply

Jan 1, 2012

By Ehsan Alavi Gharahbagh

Tool and cutterhead wear is a crucial issue in soft ground tunneling, especially because tool inspection, maintenance, and replacement are done under difficult conditions, and often under pressurized faces or under ?hyperbaric interventions?. Overall, tool inspection and changing is a time consuming and costly step, which needs to be quantified and the related costs accounted for in any construction contract for scheduling and costing of the tunnels at design stage or bid preparation. However, lack of a universally accepted index or measure for soil abrasivity in the geotechnical reports has made it difficult, if not impossible, to define cutter wear for this purpose. Soil abrasion and its impact on cutting tools for tunneling machines under dry or wet conditions have recently been under spot light due to construction claims in several of the recent tunneling projects. The objective of this paper is to examine soil?s physical, mechanical and tribological properties related to the interface of the soil and excavation tools and discuss ways to measure soil abrasivity in a quantitative and repeatable manner. The paper will discuss the efforts that are underway to develop a new soil abrasivity index and the fabrication of a new testing device for this purpose.

Jan 1, 2010

By R. G. Gillies, C. A. Shook, W. H. W. Husband

"The current state of knowledge concerning pipeline transport of coal in water slurry form is summarized for the four categories: coal-water fuels, conventional fine coal slurries, coarse coals and stabilized mixtures of coarse and fine particles. Surface chemistry is of dominant importance for coal-water fuels and considerable progress in understanding the role of surfactants has been achieved in recent years. Little generalized research on the flow of conventional fine coal slurries has been done in the past 17years, although innumerable conceptual designs and feasibility studies have been undertaken. Coarse coal slurries are fairly well understood but the model which explains their flow requires more data to be established fully. Stabilized flow mixtures should probably obey the same model as coarse coal slurries but experimental results for stabilized mixtures have not yet been incorporated in a comprehensive theory.IntroductionPipeline transportation of coal in a water vehicle has been employed for many years in coal washeries. It has been used less frequently in hydraulic mining and thermal power station fuel supply systems. The suitability of coal for pipeline transport arises from its moderate specific gravity relative to the carrier fluid and the fact that throughputs are often large and steady over long periods of time."

Jan 1, 1990

By Luckie. Peter T., Deurbouck. A. W., Harold L. Lovell, E. R. Palowitch, James K. Kindig

PART 1: DENSE MEDIUM SEPARATION by E. R. PALOWITCH and A. W. DEURBROUK INTRODUCTION During 1974, 43.9% of the 603,406,000 tons (549,099,000 mt) of bituminous coal and lignite produced was cleaned mechanically, of which 82,280,000 tons (74,875,000 mt) was cleaned by dense medium processes.l The percentage of bituminous coal and lignite cleaned mechanically by dense medium processes increased from 7 to 31 % between 1938 and 1974. Dense medium separations include those coal preparation processes which clean raw coal by immersing it in a fluid having a density inter- mediate between clean coal and reject. As there is a general correlation between ash content and specific gravity, it is possible to achieve the required degree of removal of ash-forming impurities from a raw coal by regulating the specific gravity of the separating fluid. Dense medium processes offer the following advantages over other coal cleaning processes: 1) Ability to make sharp separations at any specific gravity within the range normally required even in the presence of high percentages of the feed in the range of 2 0.1 sp gr units. 2) Ability to maintain a separating gravity that can be controlled with ± 0.005 sp gr units.

Jan 1, 1979

By A. Suarez, M. Menendez, M. R. Gent, P. Riesgo

"Recent requirements to reduce thermal coal plant emissions, and ultrafine coal's tendency to produce these emissions due to its typically high ash and moisture contents have limited the use of ultrafine coal. Ultrafine coal in beneficiation plants are usually either disposed of in tailing ponds at a loss in combustible material or disposed of by blending with coarser higher-grade products, resulting in a reduction in marketed product quality. A study of the options for processing ultrafine coal, consisting of < 200 µm hydrocyclone overflow, with 38.8 percent ash content is presented here. Ultrafine coal was processed based on 200-µm sieve bend and 10-µm hydrocyclone classifications, enhanced gravity separation (EGS) and froth flotation concentration as well as combinations of these. Yield, combustible material recovery (CMR) and product humidity were evaluated as test results.Depending on the processing applied, product ash content could be reduced up to 49.7 percent, and up to 95.8 percent CMR of the actual run of mill feed could be attained. All of the processing options analyzed could reduce produced thermal electric plant emissions due to ash and moisture from 22 to 38 percent of the actual unprocessed ultrafine coal product.Froth flotation was found to be the optimal process, yielding a product with the lowest ash content attained of 19.5 percent and CMR of 92.3 percent. Being the most versatile of the processes evaluated, it is capable of producing coal with varied ash contents but is subject to potential variations in coal flotability. The most complicated of the processing options, a combined sieve bend recovery of the > 200 µm fraction and EGS processing of the 10 to 200 µm fraction was found to be the next best option, attaining a combined 90.1 percent CMR and 25.0 percent ash content. IntroductionMunicipal, regional and national objectives to reduce fossil fuel combustion emissions and their effects on air quality and global weather changes are affecting thermal electric plant operations. Plans and regulations such as President Obama's Clean Power Plan (U.S. Environmental Protection Agency, 2015), the European Directive 2010/75/EU (European Commission, 2010) and China’s proposed Enhanced Actions on Climate Change (Wei, 2015) are of major significance to thermal electric plant operations. Although thermal plant efficiencies depend in large part on the losses of heat by plant components, the ash and humidity contents of thermal coal invariably reduce plant efficiencies and increase emissions of carbon dioxide (CO2), nitrogen oxides (NOx) and dust.Any noncombustible material present in thermal coal will result in higher CO2 emissions per unit of energy produced. Since no particle emission control can be totally effective, it is to be anticipated that any reduction in coal ash content will also result in reduced particle emissions. Kurose, Ikeda and Makino (2001) reported that NOx emissions also increase with coal ash content. The effect of coal moisture content during combustion is complex. Kurose, Ikeda and Makino (2001) showed that an increase in coal moisture content significantly reduces thermal NOx to total NOx production, and Bosoaga et al. (2006) showed that it tends to reduce NOx emissions. Since the humidity, pyrite and ash content of thermal coals directly affect thermal electric plant efficiencies and emissions, minimizing these factors should facilitate, at least in part, compliance with thermal electric plant emission limits. This, in turn, would affect the specifications and prices of the coal preparation plant products."

Jan 1, 2016

By J. Helton, J. L. Bellanca, M. McNinch, L. R. Swanson

DISCLAIMER The findings and conclusions in this paper are those of the authors and do not necessarily represent the official position of the National Institute for Occupational Safety and Health, Centers for Disease Control and Prevention. Mention of company names or products does not constitute endorsement by NIOSH. ABSTRACT Accident data indicates that mobile haulage poses a significant pinning, crushing, and striking risk. Proximity detection systems (PDSs) have the potential to protect mineworkers from these risks. However, unintended consequences of mobile PDSs can undermine the safety benefit they provide. Soliciting iterative user input can improve the design process. Users help provide a critical understanding of how mobile PDSs may hinder normal operation and endanger mineworkers. Researchers explored users’ perspectives by conducting interviews with mineworkers from seven mines that have installed mobile PDSs on some of their haulage equipment. Mineworkers reported that mobile PDSs affect loading, tramming, section setup, maintenance, and general work on the section. Mineworkers discussed the operational effects and increased burden, exposure, and risk. Mineworkers also suggested that improved task compatibility, training, logistics, and PDS performance might help address some of these identified issues. This paper also gives additional insights into mobile PDS design and implementation. INTRODUCTION Pinning, crushing, and striking accidents are a large problem in underground coal mines, especially for mobile haulage. Between 1984 and 2014 there were 179 non-fatal and 42 fatal pinning, crushing, and striking accidents involving mobile haulage vehicles, including coal hauling machines and scoops [1]. Proximity detection systems (PDSs)—automated systems that decelerate and stop a vehicle in order to prevent a collision—have the potential to protect mineworkers in these situations. In fact, PDSs are now required on all place change continuous mining machines as of March 16, 2018, as a result of the final rule published in January 2015 (30 CFR 75.1732) [2]. To address mobile haulage, later in 2015 the Mine Safety and Health Administration (MSHA) also proposed a new rule that would require PDSs on mobile haulage vehicles [3]. Though there has been no additional actions related to the proposed rule and it is not currently required, mobile PDS can still help to save lives. MSHA estimates that the adoption of mobile PDSs could prevent approximately 70 injuries and 15 fatalities over the next 10 years [4]. As of June 2015, the underground coal industry had already equipped 155 of the 2,116 mobile haulage vehicles in use [1]. In order to capitalize on the projected safety gains afforded by PDSs, it is important that the systems are designed and implemented effectively. Along with others, researchers at the National Institute for Occupational Safety and Health (NIOSH) have been exploring PDSs for more than two decades [5-7]. Throughout this time, NIOSH has also held several stakeholder meetings (2010, 2014, 2016, and 2017) in order to disseminate information and provide an opportunity to discuss on ongoing issues and concerns. Despite some progress, human factors remain a key concern. Previous research examined mineworkers’ attitudes towards PDSs on continuous mining machines [8] as well as how continuous miner operators’ perceptions of risk have changed as a result of PDSs [7]. However, stakeholders have still expressed a need to better understand how mobile PDSs affect the mining process, the mineworker, and whether and how they may present previously unidentified risks.

Jan 1, 2019

Callie underground gold mine is part of the Newmont Tanami Operations, and is now the primary provider of ore to the Granites processing Mill. The Callie underground mine has produced in excess of 7.6 million tonnes (Mtpa) of ore, since production began in 1998, with a current production rate of 1.9 Mtpa. Callie underground uses sublevel open stoping with extraction through a combination of primary and secondary stopes. The primary stope filling strategy utilises cement aggregate fill (CAF) to allow full recovery of secondary stopes. The Callie backfill operation has had a continuous testing program in place during this time, which has resulted in a great deal of information available for post fill analysis. All CAF placement into primary stopes for Callie has been via surface boreholes and this has given Callie mine an understanding of some of the issues related to borehole design, type of linings to use depending on angle, depth and quantity of fill into stopes. Finally backfill barricades at Callie have undergone a number of changes during the time to optimise the design based on whether CAF or sand fill is used. This paper discusses the CAF backfill practices and testing methods used for backfilling operations at Callie.

Jan 1, 2005

By K. Madhusudan Reddy

"Pile response under combined uplift and lateral load is very important and it is imperative to evaluate the effect of combined loading and only few studies were reported on pile behavior under combined uplift and lateral loads. Model pile made-up of aluminum having an outer and inner diameter of 25.4 mm and 19.4 mm respectively is used. Dimensions of the model steel tank are fixed as 1.0 m x1.0 m x 1.2 m (depth) to avoid the boundary effects under combined lateral and uplift loads. Experiments were carried out on single piles at isolated uplift, isolated lateral loading and combined lateral and uplift loading, embedded in sandy soil. Results indicate that load–deflection behavior is nonlinear for isolated uplift and lateral load tests as well as in case of combined loadings. It is also observed that the behavior of piles under isolated loadings is substantially different when compared to combined loading.INTRODUCTIONPile foundations are generally used to support compressive loads from superstructures. Some structures, like transmission towers, mooring systems for ocean surface or submerged platforms, tall chimneys, jetty structures, etc. are constructed on pile foundations, which have to resist large lateral and uplift loads and moments. The various loads (compressive, lateral and uplift) and moments act on the piles simultaneously rather than isolated manner. There are well-established theoretical methods present to evaluate the pile behaviour under different isolated loadings namely, verticalcompressive, vertical-uplift and lateral (Poulos and Davis, 1980), but there are very limited studies focused on pile behaviour under combined loadings. Though there is good number of studies reported on pile behaviour under combined compressive-lateral and compressive-uplift loadings (Ramasamy, 1974; Jain et al. 1987; Zhang and Small, 1999; Dash and Pise, 2003; Karthigeyan et al. 2006 & 2007; , there are only very few studies reported on pile behaviour under combined uplift and lateral loads. Darr et al. (1990) described an approach to a rational solution of the interaction of pile to combined uplift and lateral loads based on analytical and experimental studies. Influence of cyclic loading was also considered. Narasimha Rao and Prasad (1993) investigated the uplift behaviour of pile anchors subjected to lateral cyclic loading. There were many onshore and offshore situations where lateral cyclic loading may affect both the pullout and lateral loading capacity of pile anchors. Jetty and wharf structures are usually subjected to lateral forces from wave and wind action. If these cyclic lateral loads are acting on the supporting piles, the resulting movement of the upper part of the embedded length of pile may reduce the skin friction. This progressive deterioration in pullout resistance may not be reflected by a pullout test made soon after the installation. Hence, Tomlinson and Woodward (2008) pointed out that a generous safety factor on the ultimate pullout load should be adopted for piles in such situations. Mroueh and Shahrour (2007, 2008) presented a threedimensional finite element analysis of the response of battered piles to the combined lateral and vertical pullout loads. Nevertheless, the model is not validated well due to lack of good experimental data based on rigorous experiments. Thus there is a scope for investigating the effect of lateral load on pile behaviour under uplift load and vice versa based on carefully designed experiments, which is main focus of the present investigation."

Jan 1, 2017

By S. Ralph Austin

This Bureau of Mines investigation determined the effects of so-called annealing at high temperatures on radon-222 emanation from domestic uranium ores. Concurrently, a method was developed for closely estimating the emanation coefficients of hot samples from measurements of their gamma activity after cooling. Emanation coefficients of 102 samples from 14 domestic areas of past, present, and possible future uranium production were investigated using modifications of the closed-can, gamma-only assay method at and after cooling from 100° to 1,000° C. True annealing probably does not occur below 500° C. In limited investigations at 500° C and above, effects of annealing are masked by the effects of other parameters. Emanation is commonly less at one or more of the steps investigated in the 100° to 500° C range than before heating. This decrease is tentatively attributed to water loss at temperatures dependent upon the minerals present. The average sample emanates least at 300° C; emanation increases with higher temperatures to at least 900° C. Emanation decreases sharply on cooling, but it is partially restored by prolonged exposure to the atmosphere at room temperature. Higher than average emanation of coffinite ores at 500° C and above may be related to destruction of the coffinite crystal structure.

Jan 1, 1979

By Anne Kvithyld

Silicon solar cells, that convert the energy of sunlight into electric energy, are attractive sources of energy. In the production line wafers of solar cells are sliced from a multicrystaline ingot solidified unidirectionally. Recycling scrap from top and sides of such ingots is addressed. SiC and Si3N4 inclusions are a major problem. Scrap from Scan Wafer ASA is melted in a high vacuum furnace at around 1500ºC. The filters, from commercial producers, are C and SiC with 10, 20 and 30 ppi. Characterisation of inclusions before and after filtration, and in the filter itself, is performed by microscopy. Dissolution of silicon in acid and counting of the un-dissolved inclusions is also carried out. In the filter Si3N4 needles and SiC inclusions were identified. The amount of these inclusions in the filtered silicon is much less than in the input. In conclusion, filtration using SiC and C filters in vacuum system in argon atmosphere removes SiC and Si3N4 inclusions from solar cell scrap. Flow of metal through the filters is not a problem. These results are promising with scale-up to industrial application in mind.

Jan 1, 2006

By Khamis Y. Haramy

This Bureau of Mines paper describes the use of the borehole shear tester (BST) In mines. Assembly and procedure sections explain how the equipment is assembled and used properly. Schematics of the BST, limitations, test hole specifications, data recording and calculations are all explained briefly, and an example of the data collecting and calculations is given to assist understanding.

Jan 1, 1981

By M. Maeda, H. Sasaki

"Precious metals such as platinum, palladium, and rhodium are commonly used for automotive catalyst converters. To recover these metals with lower environmental load and cost, exposure to zinc vapor was proposed as a pretreatment prior to acid leaching. Alloying with zinc is expected to enhance dissolution of precious metals and reduce the amount of toxic chemical agents required for the leaching. This study examined the effect of the alloying pretreatment using model catalysts. Catalysts were immersed in leaching solutions for a predefined time with or without zinc vapor pretreatment, and the amount of dissolved metals was then evaluated. INTRODUCTIONAutomotive catalysts account for large portions of the world consumption of platinum (Pt), palladium (Pd), and rhodium (Rh) (Butler, J., 2011). Because of their limited production and high prices, recovery of the precious metals from spent catalysts is obviously an important issue. A representative structure of an automotive catalytic converter can be described as a monolithic ceramic support with a honeycomb structure which is coated with porous oxides such as those of aluminum (Al2O3), cerium (CeO2), and zirconium (ZrO2) (Heck & Farrauto, 2001; Matsumoto & Shinjoh, 2007). Small particles of precious metals, originally several nanometers or less, adhere to the oxides.Typical recovery processes for precious metals from scraps are shown in Figure 1 (a)-(c) (Habashi, 1997; Yoo, 1998; Shibata & Okuda, 2002). Precious metals can be recovered by using non-ferrous smelters as Figure 1 (a) shows. Smelted along with metals such as copper (Cu), precious metals and ceramics in the scraps are absorbed into the metal phase and slag phase, respectively. Because the metals separate from Cu as anode slime in successive electro-refining, such a process can recover precious metals as co-products of Cu. However, in order to prevent negative effects on the principal process, a specialized procedure is needed. Figure 1 (b) is a specialized approach in which scraps are melted at elevated temperature with Cu called the Rose process. Here Cu works as a collector metal, and the absorbed precious metals are then concentrated by oxidation of Cu. Such a process can separate precious metals from ceramics constituting catalyst converters. Smelting at high temperature, however, requires extensive equipment as well as a high amount of energy. On the other hand, hydrometallurgical processes may be effective to separate precious metals from ceramics into an aqueous solution, because chemical agents can act on these metals selectively (Figure 1 (c)). Leaching of precious metals, however, requires strong acid and oxidizing agents because of their corrosion resistance; this makes liquid waste disposal and the large environmental load controversial. To solve the problem, a metal vapor pretreatment was proposed (Okabe, Yamamoto, Kayanuma, & Maeda, 2003a, 2003b; Kayanuma, Okabe, Mitsuda, & Maeda., 2004; Kayanuma, Okabe, & Maeda, 2004; Itoh, Kayanuma, Miyake, Kimura, & Maeda, 2005). A flow diagram of the process using zinc (Zn) vapor is shown by Fig. 1(d). Exposed to Zn vapor, precious metals are expected to form alloys which dissolve more easily than pure precious metals, thus reducing the use of chemical agents and environmental load involved with successive leaching. In previous research (Sasaki, Miyaki, & Maeda, 2010; Sasaki & Maeda, 2010, 2012), dissolutions of precious metal alloys formed by Zn vapor treatment were examined in hydrochloric acid (HCl) using an electrochemical method, and it was confirmed that these metals dissolved at higher rates from the alloys than from their pure states (Figure 2). In this study, the availability of the alloying pretreatment was demonstrated by testing on model catalysts in leaching solutions."

Jan 1, 2012

By L. A. Neumeier

The Bureau of Mines evaluated the properties and anisotropy in properties of rolled Zn-Cu and Zn-0.12 pct Ti-Cu alloys with various copper additions to 1.25 pct. The alloys were rolled cold and at various hot-rolling temperatures to reductions as high as 92 pct after breakdown rolling. The properties are extremely sensitive to various combinations of composition, rolling temperature, and rolling reduction, Zn-Cu alloys can develop good creep resistance, but they are inferior in that respect to Zn-Ti-Cu alloys. For alloys either with or without the titanium addition, cold-rolling results in recrystallization of the matrix and rejection of copper from solution, causing poor hardness, tensile, and creep properties, but high ductility. Peak tensile strengths develop when the alloys are rolled in the range 320° to 400° F, Best creep resistance for Zn-Cu alloys requires higher rolling temperatures when copper content is increased. Creep resistance is best for Zn-Ti-Cu alloys with about 0.75 to 1.0 pct CU rolled near 480° F. Some copper is soluble in the TiZn15 phase, which forms into "stringers" during rolling. The possible contributions to creep behavior of factors such as distribution of second-phase particles, grain size, and preferred orientation are discussed.

Jan 1, 1970