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By Kazuteru Tozcwa

The oxidation of several sulfide minerals in aqueous ammoniacal solution is discussed thermodynamically. The region in which Cu(NH3)2 4+ is stable has been estimated as a function of pH and concentration of total ammonia, {[NH3) + [NH4)}. In ammonia leaching when copper in sulfides is assumed to be extracted in the form of Cu(NH3)2 which will be rapidly converted to cupric ammine, thermodynamic data predict that such minerals are oxidized readily in the following order, CuS, Cu2S, CuFeS2, ZnS, NiS, Ag2S. This agrees with investigations on ammonia leaching of sulfide minerals, reported previously. The leaching of copper sulfide concentrate has been examined experimentally. Copper in a copper sulfide concentrate, in which the main constituents were chalcopyrite and pyrite, was effective¬ly extracted. The copper extraction was affected by factors such as (1) agitation intensity, (2) oxygen partial pressure, (3) NH3/Cu molar ratio, (4) leaching temperature and (5) addition of ammonium sulfate. From the results obtained in this work, it is concluded that mass transfer of oxygen plays the most important role in ammonia leaching of copper sulfide minerals.

Jan 1, 1976

By C. Pritchard

John Marks said in his acceptance of the Hartman Award in 2008, "I guess that without the occasional complaint, your mine is probably over-ventilated" (Marks, 2008). Miners are seldom in this situation and spend much of the time trying to find enough air to keep an operation running. With examination, there are usually changes that can be made to increase the efficiency of ventilation systems. Mine ventilation air is a costly commodity, especially by the time it has been heated or cooled and moved to the bottom of the shaft and through the mine airways. Modifications that result in surplus mine ventilation air could bring financial and environmental benefits. Some issues mine operators have needed to address recently are increased airflow requirements to dilute diesel particulates in metal and nonmetal mines, to ventilate reserves that are deeper, hotter, and further away from fans and shafts, and to meet demands from increased production. This paper discusses successful methods to find additional usable air when there is no extra ventilation capacity. Most of the options presented in this paper are useful for metal/ nonmetal operations but some may be applicable to coal as well.

Jan 1, 2010

By J. Jankovic

Numerous advantages have been recognized for solid oxide fuel cells (SOFCs) operating at temperatures of 500-700°C. However, there are several issues related to low temperature SOFCs, such as high electrolyte resistance and high electrode polarization. One of the routes to enhance the electrode performance, particularly for the cathode, is to use new materials with optimized microstructure. In this work, the plasma-spraying technique, recognized to have several advantages over presently used deposition techniques, was used to deposit cathode materials onto ceramic and stainless steel substrates to obtain highly porous structures. Cathode materials with composition of Lao 6Sr0.4Co02Fe0 8O3 (LSCF) were employed in the powder form. The LSCF was prepared from powder precursors with different pore formers and binder levels, or from already produced, single-phase LSCF. The (La0.8Sr0.2)0.98MnO3 (LSM) cathode material was also processed for comparison purposes. The deposition process was developed to obtain coatings with good bond strength, porosity, film thickness and residual stresses. The phase and microstructure of deposited materials were characterized using XRD and SEM.

Jan 1, 2005

By C. Pritchard

John Marks said in his acceptance of the Hartman Award in 2008, “I guess that without the occasional complaint, your mine is probably over-ventilated” (Marks, 2008). Miners are seldom in this situation and spend much of the time trying to find enough air to keep an operation running. With examination, there are usually changes that can be made to increase the efficiency of ventilation systems. Mine ventilation air is a costly commodity, especially by the time it has been heated or cooled and moved to the bottom of the shaft and through the mine airways. Modifications that result in surplus mine ventilation air could bring financial and environmental benefits. Some issues mine operators have needed to address recently are increased airflow requirements to dilute diesel particulates in metal and nonmetal mines, to ventilate reserves that are deeper, hotter, and further away from fans and shafts, and to meet demands from increased production. This paper discusses successful methods to find additional usable air when there is no extra ventilation capacity. Most of the options presented in this paper are useful for metal/ nonmetal operations but some may be applicable to coal as well.

Jan 1, 2009

By M. Aatach, St. Gaydardzhiev, M. Kadiyski, E. Visariev, V. Stoilov

Detailed process oriented characterisation on representative samples from plant survey of the slag flotation plant belonging to Aurubis, Bulgaria has been realised in order to evaluate the mineralogical occurrences of Cu, Ni, Mo and Co bearing phases. The slag subjected to flotation consisted in majority of fayalite, magnetite-iron oxides and a glass-like phase. Ni and Mo have been found to be closely associated to magnetite and fayalite. The tailing from the slag flotation has been subjected to sulphation roasting followed by water leaching as a hydrometallurgical means to recover the remaining Cu, Mo, Ni and Co. Based on the various sulphation roasting conditions (acid dosage, duration, temperature) copper, nickel and cobalt were brought to solution to a different extent. Molybdenum was the most difficult to be rendered soluble due to its close association with iron, suspected to form an insoluble compound with it. Sulphation roasting performed at 350ºC has secured the best extraction degree for Cu, Mo and Co, while maximum recovery of Ni has been documented when roasting was done at 150°C. Keywords: Copper slag; characterisation; SEM; roasting; metals leaching, hydrometallurgy 16(2), 153–65.

Jan 1, 2020

By Oliver Bowles

THE ADVERSE CONDITIONS that have gripped industry during recent years have to some extent submerged technical developments under the more pressing demands of economic problems. Progressive operators, nevertheless, have given attention to improvements in processes and equipment even when sales were at a low ebb. The array of facts relating to technical advancement here presented, although doubtless incomplete, is sufficient to indicate that the spirit of inquiry and research has not been quenched by adversity. During the latter part of 1933 a new element has focused interest more fully on improved methods of quarrying, mining, and preparation of nonmetallic minerals. Codes established under the NRA have fixed minimum wages, reduced working hours, and tended to establish selling prices .on a basis of reasonable profit. Labor adjustments will in many instances increase the cost of production, and stabilization of selling prices will tend to emphasize quality and service rather than price as sales arguments. These new conditions point to a growing necessity for improving technique in the interest of reducing cost of production and improving the quality of products. Thus, technology is linked with economics more firmly than ever.

Jan 1, 1934

By Barbara J. Arnold

The Electric Power Research Institute (EPRI) and six EPRI-member utilities are sponsoring research to define relationships between coal properties and coal handling behavior. Deratings and outages caused by plugged chutes or bunkers or frozen coal can cost utilities millions of dollars annually in lost energy production as well as in manpower to restore coal flow. There is also the added expense of maintaining redundant equipment to assure a continuous coal feed to the boiler, a common practice for utilities. Over the past two years, researchers at CQ Inc. and Iowa state university have collected and analyzed coal samples to develop a coal handleability index for utilities to use when specifying coals for their power plants. These coal samples cover ranges in ash content, rank, grindability, size distribution, and moisture content--properties that affect the handling behavior of coals. Other properties, such as the washability and ash composition, are measured as well. Over the remaining two years of the project, all of these analyses will be correlated to handling behavior, measured using a triaxial shear tester that determines the strength of a coal under compression. An index will be developed and validated at host utility power plants.

Jan 1, 1991

By M. M. Fan

In Florida?s phosphate industrial practice, the most favorable upper size limit of froth flotation is 1.18 mm which corresponds to particle weight of about 2.8 mg. Conventional froth flotation is not efficient in upgrading coarse particles (+0.425-1.18 mm). A limited number of studies have been devoted to understanding and improving coarse particle flotation. We have shown that the coarse particle flotation performance can be significantly improved by the presence of picobubbles generated by hydrodynamic cavitation. In this study, the size of picobubbles produced under certain hydrodynamic conditions was measured by a laser particle size analyzer. A size-by-size flotation performance analysis of coarse phosphate froth flotation in the presence of picobubbles is conducted in terms of flotation kinetics, selectivity and recovery. It was found that picobubbles doubled the flota-tion rate, increased the P2O5 recovery more significantly for +0.85-1.18 mm particles than +0.425- 0.6 mm and +0.60-0.85 mm particles. At a given acid insolubles (A.I.) rejection, the presence of picobubbles increased the P2O5 recovery by up to about 25%.

Jan 1, 2014

By I Douglas, L Allen

Localised indicator kriging was developed following a similar approach used by Marat Abzalov (2006) in his paper titled æLocalised uniform conditioning (LUC): A new approach for direct modelling of small blocksÆ. Abzalov introduced the idea of mapping panel distributions from uniform conditioning onto selective mining unit-sized blocks that were created using ordinary kriging. This concept of remapping panel distributions was applied to multiple indicator kriging histograms.At Newmont a program was developed that made the remapping of MIK histograms to SMU sized blocks extremely efficient and was subsequently tested on several gold deposits. The results have been encouraging as the localised indicator kriging (LIK) method has eliminated many issues that have plagued both ordinary kriging and multiple indicator kriging. Use of localised indicator kriging methodology limits the smearing of high-grade and the over-smoothing of grade that is common and difficult to control in OK but retains the ability for localising grades. LIK also simplifies change-of-support corrections, eliminates un-mineable slivers of low or high-grade when dealing with small tonnages, and allows for the mapping of linear and non-linear estimates into the same block.

Sep 26, 2011

By Scott Burchmore, Jason Emery, Michael Melville

This paper presents best practice data management for monitoring of extensometers in Australian underground coal mines. This work is based on the combined experience of the authors and the available literature. The information and ideas presented herein are a culmination of many years of database development founded from mine site-based ground support design, underground inspections, extensometer data management and data analysis. Each author has more than ten years’ experience as a practicing geotechnical engineer at several operating industry wide research project focused on utilizing mechanical extensometer data for data analytics and machine learning. Principal hazard ground control management plans, stipulated in Australian coal mining legislation, outline the mandatory installation of ground monitoring devices during routine mining activities. After 20+ years of data gathering the barrier to implementing modern data analytics remains the challenges imposed by inconsistent data structure and data quality. This inconsistency is still routinely found between sites, companies and mining regions. Through the relatively simple application of a standardized database structure, the potential to shift from simplistic tracking of trigger levels, siloed at individual sites, to an industry standard method for compilation & comparison of monitoring data is enabled.

Jun 25, 2024

By P. M. Gruzensky

In view of some of the outstanding properties of chromium, considerable effort has been made in recent years to prepare the high-purity metal in ductile form. The object of this investigation was to obtain such metal by electrolysis of chromic acid solutions and to determine the conditions that yield optimum results. The apparatus is described, as well as the parameters that received consideration. Ion-exchange resins were employed to remove cation impurities from the electrolyte. Tensile specimens prepared from the electrodeposits by arc melting, press forging, swaging, and drawing, were ductile at room temperature. INTRODUCTION Metallic chromium displays an exceptionally high resistance to corrosion, oxidation, and wear at elevated temperatures. Although these properties are utilized to some extent when chromium is alloyed with other metals, such as in stainless steels, high-chromium alloys and pure chromium are not employed as engineering materials because of a serious lack of ductility and impact resistance at room temperature. Because high-chromium alloys appear promising as refractory metals for applications such as in gas turbines, much interest has been shown recently in the preparation of uniformly ductile chromium and in determining which factors contribute to its brittleness.

Jan 1, 1957

By P. C. Dagneau

QUEBEC CARTIER MINING COMPANY was incorporated in 1957 to explore and develop low grade iron are deposits in Northeastern Quebec. Four separate deposits were located and identified as being of ore quality and size to support commercial development. Said deposits were located at Lac Jeannine, Mount-Wright, Fire Lake and Mount-Reed. In 1970, in preparation for the replacement of the depleting Lac Jeannine are reserves, construction of an SS-mile railway extension was initiated, towards the newly selected mine site at Mount-Wright. This orebody was selected because the physical and chemical characteristics of the ore were very much similar to those of Lac Jeannine, as well as its huge reserves, estimated at more than one billion tons. In addition to the railroad extension, a mine, concentrator and related facilities were constructed and the new town of Fermont was created. Total investment for the Mount-Wright project exceeded $700 million and initial production commenced in 1976. Quebec Cartier is presently (1992) the leading producer and seller of iron ore in North America at 15,5 million tons and employs some 2,300 people.

Jan 1, 1993

By T. F. Tomb

on' January 6, ,1992, the Mine Safety and Health Administration (MSHA) issued an Advanced Notice of Proposed Rule Making (ANPRM) for diesel particulate (DP). The ANPRM identified five areas where the Agency was seeking additional information to assist in the rule making process. These areas were exposure 'limits, risk assessment, consideration of other information, sampling and monitoring methods, and feasibility. The period for submitting information relative to the ANPRM closed July 10, 1992. Prior to issuance of the ANPRM, the agency was involved in conducting studies to evaluate sampling and control technologies and to gather information with respect to occupational exposures to diesel particulate in underground mining operations employing diesel-powered equipment. Since issuance of the notice, additional studies have been conducted to provide supplementary information in these specific areas. Results of these additional studies indicate that average DP levels in coal mines not using aftertreatment range from 0.9 to 2.1 mg/m3. Aftertreatment devices can reduce these levels by approximately 50 to 90 percent. Studies conducted in metal and nonmetal mines showed average DP levels ranging from 0.3 to 1.6 mg/m3.

Jan 1, 1994

By P. T. Bissert, J. P. Ducarme, J. L. Carr, A. K. Smith

The continuous mining machine is a key piece of equipment used in underground coal mining operations. Over the past several decades these machines have been involved in a number of mine worker fatalities. Proximity detection systems have been developed to avert hazards associated with operating continuous mining machines. Incorporating intelligent design into proximity detection systems allows workers greater freedom to position themselves to see visual cues or avoid other hazards such as haulage equipment or unsupported roof or ribs. However, intelligent systems must be as safe as conventional proximity detection systems. An evaluation of the 39 fatal accidents for which the Mine Safety and Health Administration has published fatality investigation reports was conducted to determine whether the accident may have been prevented by conventional or intelligent proximity. Multiple zone configurations for the intelligent systems were studied to determine how system performance might be affected by the zone configuration. Researchers found that 32 of the 39 fatalities, or 82 percent, may have been prevented by both conventional and intelligent proximity systems. These results indicate that, by properly configuring the zones of an intelligent proximity detection system, equivalent protection to a conventional system is possible.

Jan 1, 2016

By Stanislas Mauuary

Price pressure is a real challenge on the stainless steel market. With market globalization, increase production capacity and exorbitant raw material, the margins are squeezing for stainless strip producers. Primetals Technologies offers a wide range of advanced technological solutions to secure the margins of our customers. Our solutions, implemented with professional project management, allow an optimum coil to market time, securing then the return on investment for the investor. Among the possible lever used to optimize the production route, one drastic step can be made to cut rolling time and cost by replacing the common 20-Hi mill stand reversing process by state of art high capacity X-HI® stands in continuous rolling line. Other source of savings can be implemented by integrated several process steps together (rolling, annealing, pickling, skin passing), achieving then savings on stocks and logistics while coil processing is reduced to fraction of hour. Additional solutions can also be implemented on the new, as well as existing line, like maintenance free solid state laser welder, skin-pass and tension levelers, in-line inspection system coupled with process and quality management system.

Aug 17, 2017

By Jorge D. Vier, Raúl B. Rebak, Alicia E. Ares, Natalia S. Zadorozne

Recent worldwide demand has driven nickel and molybdenum prices to record high values. Alloys containing significant amounts of nickel and molybde- num, such as the austenitic and duplex grades, have experienced significant price increases and some spot shortages have resulted in some regions. With low or no nickel content and reasonable molybdenum content, super-ferritic stainless steels are now proving to be the most cost effective corrosion resistant materials. The electrochemical behavior APMT® (Fe–21Cr–5Al–3Mo–0.04C) and 4C54® (Fe–26.5Cr–0.8Mn–0.5Si) super-ferritic stainless steel in NaCl solutions has been studied using open circuit potential measurements, potentiodynamic polarization curves, and electrochemical impedance spectroscopy. The aim is to compare the behavior of these materials with austenitic stainless steel alloy 316 (Fe–18Cr–10Ni– 2.5Mo). The results indicate that the APMT alloy presents a better performance than the AISI 316 stainless steel, while 4C54® does not, especially at anodic potentials. The good behavior of APMT® may be attributed to Al and Mo content in its composition.

Mar 1, 2017

By Cheng Wei

Fly-ash was used as adsorbent to remove butyl xanthate from aqueous solution in this study. Adsorption kinetics investigation reveals that the adsorption process abides by the Lagergren-second-order Kinetic Model, and fine fly-ash prepared by grinding has a higher second-order adsorption rate as 1.25 g/mg?min and a higher saturated adsorption amount as 10.92mg/g. Four influencing factors as adsorption temperature, solution pH, consumption of fly-ash and adsorption time were investigated. Testing results indicate that butyl xanthate removal rates declines slightly with the temperature increase within the range of 15-50?, increases slightly when pH rises from 7.27 to 8.01 and then declines from 99.65% to 98.25% when pH rises from 8.01 to 11.10. An enhancement of removal rates can be observed by increasing the consumption of the adsorbing agent or prolonging the adsorption time. Thermal desorption was adopted to regenerate the used fly-ash, and test results show that fly-ash possess good regeneration performance and could be used as adsorbent repeatedly with little influence on the adsorption capacity.

Sep 1, 2012

By Paul M. Tyler

The alkali metals , sodium and potassium , and more particularly sodium , occur abundantly in chemical combination with other elements . The elements themselves are available in metallic form but are so active chemically that they oxidize rapidly in contact merely with the air . Potassium will even catch fire spontaneously in air , and both the metals will decompose water with explosive violence . Inasmuch as they are almost as soft as wax they are not suitable for the structural or other mechanical uses characteristic of ordinary metals , and consequently the uses of these elements even in the metallic condition are based upon chemical rather than physical qualities . Sodium metal is used largely as a commercial reducing agent , but potassium metal is rarely found outside of chemical laboratories . Numerous salts and other compounds of these elements enter largely into world trade and are commercially very important , but none of these compounds except sodium peroxide and sodium cyanide are made economically from the metals . Sodium is generally considered as rather an uncommon metal , but in point of annual tonnage produced it is far more important than mercury , magnesium , molybdenum , bismuth, cadmium, cobalt , gold , silver , or the various rarer metals .

Apr 1, 1932

By Francisco M. S. Garrido, Fabiano A. C. M. Passos, Carla N. Barbato, Karoline K. Ferreira, Danielle C. Castro, Adriana A. S. Felix, Luiz C. Bertolino, Fernanda A. N. G. Silva, Karla M. A. Simões

Cancrinite and sodalite are characterized by high capacity of adsorption due to its porous structure. The aim of this work was to use kaolin from Borborema-Seridó/Brazil as a source of aluminium and silicon to hydrothermal synthesis of sodalite and cancrinite and to evaluate the best conditions to the formation of these phases. Therefore, kaolin was heated at 700 and 900 °C for 2 h in order to transform kaolinite in metakaolin. Thereafter, experiments with the calcined kaolin’s were carried out between 150 and 230 °C for 30–270 min on a stainless steel pressure vessel using NaOH, Na2CO3 and H2O. The samples were characterized by X-ray diffraction, nuclear magnetic resonance, scanning electronic microscopy, thermogravimetry, and Zeta potential. The most pure sodalite phase was obtained at 230 °C, with the kaolin/NaOH ratio of 1:1, low concentration of Na2CO3 and smaller time of synthesis (30 min). On the other hand, for the synthesis of cancrinite phase at 230 °C, it was necessary to use kaolin heated at 900 °C, a longer time of synthesis (270 min) and a higher concentration of Na2CO3.

Mar 1, 2017

By G Pitkin, D Sorley

The purpose of any consultancy is to provide a superior service for their client. Organisational structure is a key element in providing this service and differentiating between consultants.In an organic organisation the emphasis is on effectiveness, problem solving, responsiveness, flexibility, adaptability, creativity and innovation. Such an organisation is able to respond in a timely manner to change because employees are empowered to be creative, to experiment and to suggest new ideas. The process of innovation is triggered by employees throughout the organisation in a collaborative manner.Problem solving becomes a core competence of the consultancy. A multidisciplined approach arrives at superior solutions that are rigorous, holistic, achievable and often novel. It allows the mining consultancy to extract the most from a very talented and experienced team.This paper highlights the advantages of an organic structure for a mining consultancy and how to implement such a structure. It draws on examples of innovative problem solving from feasibility and strategic studies carried out in Australia and Africa.CITATION:Pitkin, G and Sorley, D, 2016. Organic management structure – its advantages in a mining consultancy, in Proceedings International Mine Management Conference, pp 155-162 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jun 22, 2016