Search Documents

By D. J. MacDonald

The Bureau of Mines has conducted bench-scale investigations leading to the design of an integrated process for producing reactor-grade zir-conium oxide (Zr02) from zircon sand, which avoids the air pollution, water pollution, fire hazard, and odor problems associated with the hexone-thiocyanate process. The integrated process consists of three steps: production of crude zirconyl sulfate solution, solvent extraction, and production of Zr02 from strip liquor. This report describes the solvent extraction step. Multistage, countercurrent liquid-liquid extraction with a tertiary amine in kerosine was used to separate zirconium from a dilute H2S04 solution containing hafnium and other impurities. Process steps de-scribed include extraction from an aqueous feed solution to form a hafnium-contaminated, zirconium-bearing organic-phase solution, scrubbing to separate zirconium from coextracted hafnium, stripping to transfer hafnium-free zirconium into an aqueous strip liquor, chloride-loading to produce a chloride-bearing organic solution, scrubbing with the chloride-loaded organic solution to remove traces of uranium impur-ity from the zirconium-bearing strip liquor, and regeneration to pre-pare the organic solution for reuse. These steps were performed simul-taneously in steady-state, bench-scale experiments. Zirconium recovery of up to 93 pct was achieved. Results of an economic evaluation are included.

Jan 1, 1984

By Rebecca Hope, Derick Moolman, Frikkie Malan

"Despite the lip service that has been paid to pro-active plant maintenance processes over recent years, a significant portion of maintenance in industry is still reactive. The business driving force to prevent expensive production opportunity costs arising from “break-down maintenance” is obvious. Various benefits can be derived from successfully deploying remote equipment diagnosis technology and associated business processes.From an end-client’s viewpoint these include the ability to predict and take actions to prevent equipment breakdowns, increasing the lifetime of equipment by responding to appropriate operating instructions and therefore improving the return on capital expenditure. Better planning and scheduling of maintenance priorities and resources with performance measures like an Equipment Health Index are also possible. The knowledge that a qualified supplier engineer is constantly in touch with the operating conditions of their equipment, albeit remotely, is more than a comfort, and can be translated into quantifiable cost savings and improved supplier service levels.This paper analyses the reasons for the inadequate level of pro-active plant maintenance practice in industry today, and presents a number of important criteria in selecting appropriate solutions to this problem. A case study of a specific real-time, remote equipment management application is presented."

Jan 1, 2003

By Abolfazl Eslami, Fatemeh Rostami, Sara Heidarie Golafzani, Mohammad Arabameri

Collapsible loess is classified as problematic soil found in most continents. The loess immediately collapses under stresses induced by axial compressive loading or the soil weight when exposed to moisture. In Iran, vast areas of the Golestan province are covered with aeolian loess deposits. This paper investigates whether the simultaneous effect of inundation and pre-loading in helical pile installation are operative and effective in improvement of Golestan loess. The effect of installation conditions on loess collapsibility is studied via two main approaches, i.e., field investigations and physical modelling. The experimental studies include installation of eight single helix piles in the Amirkabir University of Technology Frustum Confining Vessel, i.e., FCV-AUT. Also, four single helix piles with embedment depth of 3 m and diameter of 250 mm were installed in Golestan province and full-scale pile static loading tests were performed. The results indicated that the simultaneous application of crowd loading and water pressure during installation of helical piles results in better soil shear strength parameters. Moreover, high crowd stresses or low crowd stresses accompanied by water pressure during pile installation brings about similar load-displacement behavior of model piles installed in FCV-AUT and full-scale helical piles.

Oct 1, 2022

The ever increasing demand for energy and the progressive depletion of crude oil resources, have renewed interest in oil shale as an alternative fuel resource. Weathered oil shale samples were assembled from El-Nakheil phosphate mine in Quseir area, Eastern desert, Egypt. The oil shale samples were prepared and analyzed by XRD (X-ray diffraction), XRF (X-ray fluorescence spectrometry), and optical microscopic techniques. Rock-Eval pyrolysis and total organic carbon were used to study shale hydrocarbon potential. A leaching procedure using inorganic and organic acids was used to selectively dissolve the oil shale associated ash forming minerals. XRD results showed that calcite is the dominant carbonate mineral, whereas primary silicate minerals are quartz and montmorillonite. SEM (Scanning Electron Microscopy) observations indicated that the organic matter is dispersed throughout the rock matrix. The acid soluble fraction upon leaching was determined to be 37.59 and 42.74 wt% by using 5% HCl and 10% HCl, respectively. The TOC was increased from 20.78 to 29.88 and 34.09 wt% by using 5% HCl and 10% HCl, respectively. Keywords: el nakheil oil shale, characterization, xrd, xrf, sem, elemental analysis, proximate analysis, ultimate analysis, thin section, rock eval pyrolysis, acid leaching

Sep 1, 2012

By Gregory J. Chekan

The Bureau of Mines, in an effort to improve planning and development in coal mining, is investigating strata interactions associated with mining of multiple coalbeds. Two common interactions that occur between adjacent coalbeds are subsidence and pillar load transfer. The study described involves underground observations and measurements conducted at two Pennsylvania mines, each affected by one of these interactions. At the mine affected by subsidence, measurements show that undermining had little effect on upper mine pillar stability, but had a more severe effect on the development and maintenance of entries. Roof-to-floor measurements recorded over four times more convergence in entries developed over gob as compared with entries developed over support pillars in the lower mine. At the mine affected by pillar load transfer, Initial in situ measurements have shown the existence of a pressure arch in the lower workings. Prior research has shown that arch interaction between two adjacent openings can create stress concentrations in the in-nerburden. Underground measurements and results obtained from both mine sites correlate with theoretical and photoelastic multiple-seam models, and eventually these field data will serve to refine model accuracy. Further study of multiple-seam interaction mechanisms will lead to improved mine planning, increased resource conservation, and a safer working environment.

Jan 1, 1986

By Troy Boisjoli, Sean Hillacre, Matt Batty

Discovered in 2014, the Arrow Uranium Deposit has undergone rapid development through successive drilling programs informed by geostatistical drill hole spacing studies. An independent third-party geostatistical drill hole spacing study was completed by Clayton V. Deutsch Consultants Inc. in 2017, evaluating the uncertainty of thickness, grade, density, and areal limit of the Arrow Deposit to determine a drill hole spacing suitable for Indicated Mineral Resources. Indicated spacing was defined to be 24 to 32 metres (“m”) to be within 15% of predicted for a nominal quarterly production volume with a probabilistic tolerance between 75 and 90%. The study not only defined the Indicated Mineral Resource resultant from the 2016 drill program, but also provided drill hole targeting criteria for subsequent drill programs aiming to convert Inferred to Indicated Mineral Resources. A subsequent geostatistical drill hole spacing study on the Arrow Deposit was completed by Clayton V. Deutsch with Resource Modeling Solutions in December 2018 to define Measured Mineral Resource spacing in support of the 2019 drill campaign. The study resulted in a drill hole spacing of 9 to 17 m to be within 15% of predicted for monthly and quarterly production volumes using an accepted industry probabilistic tolerance of 90%.

Jan 1, 2020

By Neville Jordison

Indirect, gravity flow, heat exchangers have become a well established technology in mineral and metallurgical process plants. The technology is a conventional heat exchanger using high efficiency plates, with a free flowing bulk solid on one side of the exchanger and a fluid on the other side. This simple concept leads to many opportunities for achieving greater energy efficiencies in process plants. Indirect heat exchange is much more efficient than direct heat exchange using air such as in a fluid bed or rotary device. When air is used directly, large fans are required, it may also be necessary to chill the air, both high consumers of energy. By contrast, using water as the cooling medium requires only low horsepower pumps, typically only 10% of fan HP. Furthermore there are no stack emissions with the requirement for removal of dust or emissions. Indirect heat exchange also creates the opportunity to recover energy. This can work in two ways: energy can be recovered from a hot bulk solid, to heat pressurized hot water for steam generation or preheat air. Alternatively recovered energy from elsewhere in the plant in the form of hot water, steam, air or thermal oil can be used to preheat a bulk solid.

Jan 1, 2011

By M. A. Golozar

Partially stabilized zirconia (PSZ) has been proven to be an excellent candidate as a thermal barrier coating (TBC) for hot sections in, for instance, heat or internal engines and gas turbine parts. The main functions of these coatings are reduction of heat losses, reduction of fuel consumption, increasing efficiency, and extending durability and life. One of the main problems involved is wear behavior in the development of such coatings for these applications. Using air plasma spraying (APS) technique, conventional and nanostructured 8 wt % yttria partially stabilized zirconia (Y-PSZ) coatings were deposited on austenitic stainless steel (AISI 304) disc-shaped substrates. The coated substrates were subjected to pin-on-disc wear tests, using 10 mm silicon nitride and zirconia balls as the pin. The coefficient of friction was recorded in real time. The weight loss of coated substrates was measured. Coatings were characterized before and after being subjected to wear testing by various techniques including optical microscopy, scanning electron microscopy (SEM), energy dispersive X-ray spectrometry (EDX) and X-ray diffraction (XRD). Effects of various experimental parameters such as wear distance, test temperature, and counterface material were also investigated. Results obtained revealed that, regardless of experimental conditions applied, the nanostructured zirconia coating shows better wear and tribological properties than those of the conventional one.

Jan 1, 2005

By L. E. Djingheuzian

IN 1953, Lewis (1) published an article which brought forth a great amount of discussion by grinding engineers. In his contribution to discussion the present writer (2) suggested that, for the most efficient performance of a ball mill, there must be a .definite relationship between Cn, per cent critical speed, and V p, per cent mill volume occupied by the ball charge. Later, he ( 3) was able to publish some grinding data from Wright-Hargreaves milly which appeared to bear out this contention. It is with this view to establishing a fundamental relationship between Cn and Vp that the idea of this Forum was conceived. Accordingly, a questionnaire was prepared and copies of it were mailed to over eighty Canadian mill operators. This questionnaire did not include a question on dilution on the assumption that each mill operator was using the most efficient dilution for his operation, nor was a question on efficiency of classification included since it was thought that the inclusion of efficiency of dassification in the questionnaire at this preliminary stage might render the forum discussion,. while everybody was trying to find his bearings, too unwieldy. However, it is evident that, as discussions develop, this forum will have to define a uniform method for establishing most efficient classification in grinding circuits

Jan 1, 1957

By J. W. Craig

THERE are, broadly speaking, three classes of refractories: acid, basic, and neutral. Fireclay, diaspore, silica, and the sillimanite group of minerals are included in the acid class, which for the most part are not very resistant to basic slags. The neutra! class includes chrome, graphite, and silicon carbide, while most important in the basic class are magnesite and dolomite. Although chrome is a neutral refractory, it has no sharp distinction from magnesitic refractoriness. The two are mineralogically (1) and chemically related, and there is available on the market a complete range of brick from straight chrome to straight magnesite. In many indus trial applications, one. type may be replaced by another. The present paper is confined entirely to such refractories. The following types of basic and neutra! brick, each sold under sorne special trade name, are available for use in Canada: (1) Burned chrome from crude ores (2) Burned chrome from treated ores (3) Chemically bonded (unburned) chrome-magnesite ( 4) Burned chrome-magnesite (5) Chemically bonded ( unburned) magnesite-chrome (6) Chemically bonded (unburned) high-iron magnesite (7) Burned high-iron magnesite (Regular) (8) Burned low-iron magnesite (9) Burned olivine-magnesite (10) Burned magnesitic dolomite-chrome (Magnecon) (11) Chemically bonded magnesitic dolomite-chrome (Magmecom) (12) Dolomitic brick

Jan 1, 1936

By P. C. M. Knops, K. Rijnsburger, R. M. Santos

To overcome the challenges of mineral CO2 sequestration, this work utilizes a unique proprietary Gravity Pressure Vessel (GPV) reactor technology, and focuses on reaction products of high economic value. The GPV provides intense process conditions through hydrostatic pressurization and heat exchange integration that harvests exothermic reaction energy. Here, laboratory-scale tests of the envisioned process was performed in tubular and continuously stirred tank reactor (CSTR) autoclave reactors. The mineral used was Olivine (~Mg1.6Fe2+0.4(SiO4) + ppm Ni/Cr), although asbestos, steel slags and oil shale residues are also under investigation. The effect of several process parameters on reaction extent and product properties was tested: CO2 pressure, temperature, residence time, additives (buffers, lixiviants, chelators, oxidizers), solids loading, and mixing rate. The products (carbonates, amorphous silica and Chromite) were physically separated (based on size, density and magnetic properties), characterized (for chemistry, mineralogy and morphology) and tested in intended applications (e.g. as pozzolanic carbon-negative building material). Economically, it is found that product value is the main driver for mineral carbonation, rather than, or in addition to, the sequestered CO2. The approach of using a GPV and focusing on valuable reaction products could thus make CO2 mineralization a feasible and sustainable hydrometallurgical process.

Jan 1, 2015

By Henrique Lacerda Eleutério, Aldo Henrique de Almeida Barbosa, Vicente Tadeu Lopes Buono

The automotive industry’s interest in galvannealed (GA) boron steel for hot forming processes application has been steadily increasing due to its excellent surface quality, galvanic protection provided to the parts, good paint adhesion and better weldability in relation to other coatings for this application. In this study, samples of 22MnB5 galvannealed steel were heat treated and hot stamped on a water cooled die in laboratory scale. The influence of heat treatment on stability of coating and steel was assessed by using initial heating rates 11.0ºC/s and 15.0ºC/s. Microstructural evolution of galvannealed coating and structural integrity of steel during hot forming were investigated by scanning electron microscopy with energy dispersive spectroscopy analysis (SEM/EDS/Line scan), X-ray diffraction (XRD) and optical microscopy (OM). It was possible to quantify the Fe-Zn phase evolution during hot forming, to understand the effect of these heating rates on the product properties and to establish an optimized heat treatment for hot forming of these steel. The heat treatment with the heating rate of 15.0ºC/s presented greater operational flexibility and final products free from surface defects or cracks in the substrate.

Oct 1, 2019

By G. J. S. Govett

Dwindling near-surface mineral reserves emphasize the need for the development of exploration techniques capable of greater depth penetration; geochemical techniques tradition- ally have been restricted to the search for deposits having at least a sub-outcrop expression. Rock geochemical techniques developed in Cyprus in 1967-1968 recognized anomalous conditions in volcanic rocks up to one mile from an ore de- posit. Research by the Exploration Geochemistry Group at the University of New Brunswick has shown that some massive sulphide deposits in New Brunswick have well-defined halos of major, minor, and trace elements in the host rocks extending up to 1,200 metres (4,000 feet) laterally along the same stratigraphic horizon, and up to 450 metres (1,500 feet) vertically in hanging wall rocks which apparently post-date mineralization; well-defined halos have also been found in foot- wall rocks. Some of these halos are readily identified as individual elements or as element pairs; others are so subtle as to be recognizable only through computer-calculated multivariate analysis. Research continues to extend the dimension of rock geochemical halos for regional exploration and for identification of more restrictive anomalous conditions which may closely define the location and extent of buried sulphide deposits.

Jan 1, 1975

By Robert K. Koch

The Bureau of Mines investigated separating HF from HF-SiF4-H2O mixtures by passing the mixed gases through a sodium fluoride slurry in an airlift scrubber and forming a mixed precipitate of NaHF2 and Na2SiF6. The oven-dried precipitate was thermally dissociated in two stages. The first stage was carried out at 400° C and dissociated NaHF2 to NaF and HF. Condensation and analysis of the evolved HF proved it to be 97 to 99 weight-percent HF containing 0.79 to 0.99 weight-percent H2O and 10 to 93 ppm silicon. The second stage was carried out at 700° C and dissociated Na2SiF6 to NaF (for recycle) and SiF4. The quantity of HF recovered from gaseous HF-H2O-air mixtures decreased with increasing relative H2O concentrations. Air was beneficial when scrubbing extremely dilute wet HF gases. At HF partial pressures of 0.24 and 0.013 mm Hg in the scrubber entrance gases, HF partial pressures of 6.2 x 10-4 and 9 x 10-6 mm Hg were obtained, respectively, in the scrubber exit gases. Scrubber efficiencies were 99.7 and 99.3 percent.

Jan 1, 1966

By W. J. Adams

It is recognized that within life cycle assessment that the eco-toxicity potentials (TPs) derived for metals require additional research to improve their reliability. Current models used to develop TPs do not include important fate process for metals such as speciation and bioavailability. Toxicity potentials are standard values used in LCA to enable a comparison of potential toxic impacts between substances. Huijbrechts (2001) calculated toxicity potentials for 181 substances utilizing the USES model for six impact categories, i.e. freshwater aquatic ecotoxicity, marine aquatic ecotoxicity, freshwater sediment ecotoxicity, marine sediment ecotoxicity, terrestrial ecotoxicity and human toxicity (not considered here). Marine ecotox potential for metals is typically high using this approach, whereas most open ocean metal concentrations are very low. A sensitivity analysis of the USES-LCA model was undertaken using copper as an example. Results indicate: fate processes on the global scale are driving the marine water and sediment TPs for copper most; the second most important fate parameter is sedimentation from the water and burial in deep sediment layers; inclusion of speciation and bio-availability processes would be very beneficial; more accurate estimates of input parameters should be used, and the PNECwater and PNECsediment and all partition coefficients for metals should be updated in the model.

Jan 1, 2007

By G Campbell-Cowan

Much has been written about the fact that most transformation efforts disappoint. This paper addresses factors that should be taken into consideration in planning and implementing transformation programs to ensure success.In 2009, St Barbara commenced a transformation program to address issues of chronic poor quarterly operational performance; financial pressure caused by the unreliable operational performance; and an inability to develop business plans with integrity and to reliably deliver on the plans. As a result of a number of years of disappointing operational performance, St BarbaraÆs culture was not conducive to business success.This paper uses lessons learnt during St BarbaraÆs transformation program to highlight key characteristics of change programs that can generate significant sustainable benefits. While there were many benefits from the transformation program, the most significant impacts of St BarbaraÆs program have been transformation of the companyÆs culture and capability of people as business leaders; the establishment of a business systems framework to guide the design and development of systems; and developing support functions, for example centralised procurement and supply chain, business improvement and technical services.CITATION:Campbell-Cowan, G, 2012. Business transformation - Lessons learnt for successful change, in Proceedings International Mine Management 2012, pp 135-142 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 20, 2012

By D. Donald Downey

Pilot Testing Ion Exchange Resin (IEX) can go from very simple beaker testing to complicated column testing. Space velocities, regenerant quantities, loading capacities, ion leakage, are all terms that get accumulated together to prove or disprove a resin’s (or resins’) ability to load a single ion (or specific set of ions). Not getting all the resin’s operating parameters correct will disqualify (or at least skew) the results. Laboratory tests for capacity, moisture content, bead size, metals fouling, etc.—what does it all mean? At last count, there were over twenty-five separate ion exchange resin tests (analyses) that were available to end users. Standard testing procedures identify the resin properties but more specific procedures can be used to identify problems with equipment operation. Then, there are the costs to consider; simple cation resin testing (moisture content, total capacity and bead integrity) is in the $200/sample range. However, add to this Chatillon, Russian Ball Mill Test, HIAC particle size, metals and % regeneration test procedures and the lab work can increase to over $1000/sample. In this paper, the author will explain the “must-do” pilot and test procedures and why they are important and the key to understanding how resin performs ion exchange.

Electronic detonators have been in commercial use for a decade, with an excellent safety record. This paper lists known incidents involving electronic detonators. Typical standards required by regulatory bodies for static electricity and electromagnetic fields are reviewed. The performance of some detonators is compared to these standards; in general the minimum standards are easily exceeded. The general resistance of electronic detonators to extraneous electrical energy that can be derived from the body of test results is compared to danger levels for exposure of humans to these energies; it is shown that electronic detonators can safely tolerate higher electrical energies than people can. This comparison includes comparable data for electric detonators, which are shown to be more vulnerable to extraneous electrical energy than people are. Electronic detonators also bring significant safety benefits in blasting due to their testability, two-way communications, reliability, programmability and precision. The links between these attributes and enhanced safety are discussed with examples from actual blasting. Although electronic detonators are usually more vulnerable to extraneous electricity than non-electric initiation systems, the paper shows that the net safety benefit in handling and blasting is in favor of electronic detonators, which are the safest initiation system that has ever been offered to the mining industry.

Jan 1, 2010

By U. Steiner

Electronic detonators have been in commercial use for a decade, with an excellent safety record. This paper lists known incidents involving electronic detonators. Typical standards required by regulatory bodies for static electricity and electromagnetic fields are reviewed. The performance of some detonators is compared to these standards; in general the minimum standards are easily exceeded. The general resistance of electronic detonators to extraneous electrical energy that can be derived from the body of test results is compared to danger levels for exposure of humans to these energies; it is shown that electronic detonators can safely tolerate higher electrical energies than people can. This comparison includes comparable data for electric detonators, which are shown to be more vulnerable to extraneous electrical energy than people are. Electronic detonators also bring significant safety benefits in blasting due to their testability, two-way communications, reliability, programmability and precision. The links between these attributes and enhanced safety are discussed with examples from actual blasting. Although electronic detonators are usually more vulnerable to extraneous electricity than non-electric initiation systems, the paper shows that the net safety benefit in handling and blasting is in favor of electronic detonators, which are the safest initiation system that has ever been offered to the mining industry.

Jan 1, 2010

By T Raynlyn, S Hapugoda, V Nunna

The predominant phase in most Marra Mamba, channel iron deposits and detrital iron ore deposits is goethite. Goethite abundant iron ore fines tend to have complex mineralogical associations and fine dissemination of gangue material. These ores are typically challenging to process using conventional beneficiation methods. With declining ore grades, there is a need to develop new processing routes for low-grade goethitic ores/fines.Comparative process amenability studies were carried out using two different processing options to recover iron with low alumina and silica content from a low-grade goethite-abundant iron ore fines (-2 mm) sample from the Pilbara region of Western Australia. The first option involved dehydroxylation at 350°C and 400°C, followed by grinding dehydroxylated samples to 100 per cent passing 106 µm and magnetic separation. The second option was processing raw sample by gravity separation using a Floatex density separator. The performances of the two processes are discussed in terms of the iron grade-recovery responses, and an optimal processing route is proposed based on the findings from these tests.CITATION:Nunna, V, Hapugoda, S and Raynlyn, T, 2015. Process amenability studies on goethite-abundant iron ore fines, in Proceedings Iron Ore 2015, pp 165–174 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 13, 2015