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By H. S. Baloyi, J. J. Rust

Spiral concentrators are widely applied to beneficiate commodities such as Cr2O3, mineral sands, and ferrochrome. The application of spirals for heavy minerals has been limited to a feed top size of 1 mm. At particle sizes larger than this, friction retards heavy particles and the particles' primary velocity approaches zero, resulting in a solids build-up, therefore inhibiting further separation. Recently, a new Multotec SC25 spiral model was introduced to the industry, which aids in beneficiating particles of up to 3 mm, with successes having been demonstrated in ferrochrome slag and titanium-bearing minerals. This spiral also has potential in electronic waste applications. This paper examines the applicability of the SC25 spiral in coarse Cr2O3 recovery. This stems from the fact that junior chrome miners tend to discard particles larger than 1 mm as they neither have milling nor dense media circuits. Also, alluvial chrome miners discard +1 mm even though this size fraction contains recoverable and liberated Cr2O3. The SC25 spiral has shown better Cr2O3 separation efficiencies than the SC21 model and with higher SiO2 rejection at saleable grades, thus providing an additional revenue stream specifically for the coarser (+820 μm) size fractions. Keywords: Spiral concentrators, chromite recovery, specific gravity, SC25 spiral, coarse spiral

Jan 1, 2020

By Raymond W. Hiteshue, Sam Friedman, Martin D. Schlesinger

The Bureau of Mines in cooperation with the El Paso Natural Gas Co. investigated the effect of high temperature and pressure at short residence times on the hydrogenation of a New Mexico coal to gaseous and liquid hydrocarbons . The study was made in a bench - scale semicontinuous unit at pressures of 500 to 6,000 psig , 480 ° to 1,000 ° C , and residence times of less than 1 minute to 15 minutes . Ammonium heptamolybdate was impregnated on the coal to furnish 1 percent molybdenum based on maf coal . Coal could be rapidly hydrogenated at elevated temperatures and pressures to yield large quantities of gaseous hydrocarbons and small quantities of lowboiling oils , high in single - ring aromatics . At 800 ° C and 6,000 psig and a residence time of 1 minute , the yield of hydrocarbon gas was 43 percent and of liquid hydrocarbons 9 percent , based on maf coal . With a 15 - minute residence time , the yield of gaseous hydrocarbons increased to 68 percent with a decrease in yield of oil to 6 percent . At higher hydrogen velocities , the yields of oil were much greater but contained large quantities of asphaltene . Low concentrations of molybdenum (0.01 and 0.1 percent ) or a high concentration of iron ( 1 percent ) were ineffective at 800 ° C , 6,000 psig , and short residence time .

Jan 1, 1964

By H. Itou

A mechanism of scorodite formation at ambient pressure was investigated using transmission electron microscopy (TEM). Several types of iron arsenate were obtained from Fe/As solutions (Fe/As = 1.0 and 1.5) at pH values of 1.0, 1.25 and 1.5 at 95°C. Amorphous FeAsO4.xH2O was precipitated from solutions having a higher mole ratio of Fe/As at pH l.5, even after 9 hours. A few micron sized particles were observed by SEM, but these proved to be agglomerates of 10-50 nm amorphous FeAsarxH2O particles when observed by TEM. This means that supersaturation of the solution causes the acceleration of nucleation of iron arsenate hydrate. Crystalline scorodite was obtained from a solution in which the Fe/As mole ratio was unity, at pH l.0 and pH 1.5, after 3 hours. Almond-type crystalline scorodite particles were observed by TEM and most of them showed high crystallinity. The addition of scorodite seed material enhanced the crystallization. Amorphous FeAsO4.xH2O, however, was observed at the surface of the seeds during the early stages of precipitation. It is postulated that crystalline scorodite is not directly precipitated even on crystalline scorodite seeds, but requires a certain time to crystallize on the seed material.

Jan 1, 2006

By Gino Palarchio

Dofasco is Canada?s 2nd largest steel manufacturer producing 4.5 million tons of flat rolled steel per year. They have revenues of over $3 billion and employ 7,000 people in their Hamilton, ON plant. Dofasco is North America?s most profitable steel producer and were recently ranked as the #1 steel maker in the world by Dow Jones. Motivation to Improve In the 1980?s the steel business was good. However, in the late 80?s and early 90?s things began to change. Globalization was beginning to influence the market, imports started arriving at lower prices and higher quality, hangover from the 1970?s inflation saw costs rising and prices dropping, there was a shift from a sellers to a buyers market, and shareholder returns were beginning to erode. Dofasco took a step back and evaluated their maintenance performance and found that they were operating in an environment where 70% of their work was reactive and only 30% was proactive. They also found that the rate of product quality improvement was flat and their average equipment availability was only 78%. At that point they realized that Equipment Reliability was key to improving product quality, production output, costs and shareholder return. They initiated a project to research, develop, and implement the most advanced maintenance practices and information technologies to achieve maximum equipment reliability.

May 1, 2001

Optimal gold recoveries largely depend on efficient liberation of the gold or gold-bearing minerals as well as on maximum access for the lixiviant. Thus, crushing and grinding may become the most costly part of gold ore processing. It may, in fact, represent 50% to 70% of a plant's operating costs (Michaelis, 1989). The increasing significance of refractory gold will require even more cost-efficient comminution of ultrafine sulfides and/or native gold. Transitional ore zones with semi refractory gold may respond to direct leaching if better particle fracturing is being achieved (Baum, 1991, 1993a). Many oxide ores have been left in the ground because they were unsuitable for heap leaching since conventional comminution could not facilitate economic gold extraction. Also, the costs of conventional bal1 mill operations did not permit the recovery of gold from many ultrafine, low-grade refractory ores. As shown by Marsden et al. (1993), the trend to treat ores with progressively lower grades will involve power-and leach-efficient grinding applications. Our current laboratory work shows that high-pressure grinding roll (HPGR) Polycom grinding may enable many mining companies to add large amounts of these "non-leachable" ores to their current heap or mill leach feeds. This finding may dramatically change the economics of many oxide gold ore operations and may add significant reserves to ores amenable to direct cyanidation.

Jan 1, 1994

By G. L. Zhu, Y. F. Wu, H. Nagaumi

A novel eutectic-type alloy Al12Si-HTC with high thermal conductivity has been developed by strict chemical composition control and heat treatment. The thermal conductivity of the alloy is about 30 % higher than that of current commercial Al12Si alloy. The Al12Si-HTC alloy has a silicon content of 10~12 wt.%, which provides excellent castability. Trace element strontium or calcium is added to modify eutectic silicon, and contents of transition elements such as copper, manganese are controlled in a low level. By appropriate heat treatment, thermal conductivity of the castings increases by 7.5 % and finally reaches 172 W/(m·K). It is found that eutectic silicon modification which makes average particle size finer than 2µm plays a dominant role in improving thermal conductivity, as well as further spheroidization of eutectic silicon and reduction of lattice defects in a-Al microstructure in subsequent heat treatment process. The alloy is successfully applied to produce a certain communication enclosure with complex finned structure by die casting process in industrial scale. The results of numerical simulation and thermal analysis experiments show that when manufactured by Al12Si-HTC alloy, the surface temperature of chips in the enclosure is reduced by 2.0~4.5 ? and the temperature distribution is more homogeneous compared with traditional Al12Si alloy.

Jan 1, 2015

As part of a continuing program of evaluating the Nation's crude-oil resource, this report presents information pertaining to resource, primary reserve, and potential waterflood reserve for 3,209 selected reservoirs contained in 24 oil-producing States, as of January 1, 1968. To that date the selected reservoirs had not been subjected to pressure-maintenance or secondary-recovery operations. These reservoirs also met the following parameters: (1) a minimum of five oil-producing wells on January 1, 1968, (2) a minimum of 50 acres areal extent, (3) a minimum of 50,000 bbl of oil ultimate primary recovery, and (4) the principal reservoir energy was other than active water encroachment. The selected 3,209 reservoirs produced 527 million bbl of oil in 1967, about 17 pct of U.S, total production. Primary oil reserve was 4,983 million stb; in addition, there was 6,043 million stb of potential water- flood oil reserve. Oil resource in the selected reservoirs was 59,547 million stb. A brief history and outlook of waterflooding are presented for each State. Depth and producing rate statistics and geologic distributions of production, resource, reserve, and potential waterflood reserve for the selected reservoirs are presented by States in the appendix. Also included in the appendix are description, history, and technique modifications of waterflooding, and a preliminary cost estimate of a closed-system water-injection project.

Jan 1, 1970

By Michael Magerstädt

Material loss by abrasion of contact surfaces of pipes, chutes, pumps, and other equipment in contact with ore is one of the main reasons for downtime of mining operations. Abrasion protection materials in use range from expensive tungsten carbide overlay to hardened steels, ceramics, as well as polymers, particularly polyurethanes (PUR). This paper describes abrasion protection products made from High Performance Polyurethane Elastomers. An interior pipe coating was developed that exhibited outstanding abrasion resistance and an extremely high adhesion to steel. Years of field testing in oil sands tailings as well as applications in slurry lines (e.g., phosphate slurries) have proven the performance of this material. A proprietary field joining process was developed and successfully applied in the field. This joining process requires only one field weld per joint very similar to the joining of uncoated pipe. No internal re-coating is necessary adding savings during pipe laying to the significant savings of reduced down time. Using the building-kit chemistry of polyurethane synthesis, similar high performance elastomers were used to extend the life time of ball mills. An intelligent system was developed in which wear parts contain sensors reporting the actual wear thereby optimizing maintenance interval leading to significant cost savings for the operator. Test data as well as field experience with High Performance PUR Elastomers for abrasion protection in mining are presented.

Aug 1, 2013

By R. C. FLEMING

MINING rock asphalt for use as a paving material is an industry which has grown with the spread of the good roads movement. "Mineral Industry During 1930" reports asphaltic pavements constructed, including maintenance and repair but excluding pavement constructed with road-oil, cut-back or emulsified asphalt, as grown from 23 million square yards in 1911 to a high of 144 million in 1927. In 1930 the same source reports 106 million square yards of such paving laid and, in that year, 664,871 tons of native rock asphalt were so utilized. Many states contain rock asphalt deposits of greater or less importance but in only a few places are the de¬posits being mined commercially. In the year cited Ken¬tucky produced 305,024 tons of bituminous sandstone, Texas 270,138 tons, mostly bituminous limestone, while Alabama, Oklahoma, California and Utah produced 89,709 tons of bituminous rock for road construction. In addition Utah produced 37,906 tons of the purer asphaltic products, gilsonite, wurtzilite and ozokerite, for other uses. Speaking generally, the rock asphalt is a sandstone or limestone naturally impregnated with asphalt to an extent that makes it an ideal road surfacing material without mixing or treatment other than crushing. The asphalt content of the commercial product runs 8 to 12 per cent.

Jan 1, 1933

By Yury V. Kulikov, Rakan Rahbani, Arkady Y. Senchenko

"The relevancy of complex minerals treatment is constantly increasing taking into account mineral resources depletion. Different refractory ores and concentrates, oxidized and polymetallic ores, as well as metallurgical products (slags) can be assigned to such mineral type. The treatment of such products via conventional flowsheets requires considerable capital and operational costs and does not always provide high recovery level of valuable components into a saleable product. Therefore, considerable amount of ores and metallurgical products are not treated, or treated inefficiently. One of the most promising approaches that allows economic treatment of refractory products is their ultrafine grinding down to 5-20 µm with subsequent processing or hydrometallurgy. Horizontal bead mills - the IsaMillTM, developed by Xstrata Technology, received their wide application in mining industry. Standard testing is performed under laboratory conditions in an M4 IsaMillTM (volume - 4 liters) to define the parameters of fine grinding. This mill completely simulates the operation of full scale industrial mills up to 50 m3 in volume (up to 8000 kW motor). The paper describes fine grinding technology performed in bead mills, and the importance of testing according to a certified method for industrial equipment selection. The paper contains description of promising directions of fine grinding technology application for several projects in Russia and Kazakhstan."

Jan 1, 2014

By Kenneth Holmnerg

About 100 million terajoule is used annually worldwide to overcome friction and that is one fifth of all energy produced. The largest quantities of energy are used by industry (29%) and in transportation (27%). Based on our recent studies on energy use in passenger cars, trucks and buses, we concluded that it is possible to save as much as 17.5% of the energy use in road transports in the short term (5-9 years) by effective implementation of new tribological solutions. This equals to annual energy savings of 11.6 exajoules, fuel savings of 330 billion liters and reduction in CO2 emission by 860 million tonnes. In a paper mill, 15-25% of the energy used is spent to overcome friction. The electrical energy used by a paper machine is distributed as 32% to overcome friction, 36% for the paper production and mass transportation, and 32% is other losses. In paper machines, 11% of the total energy used to overcome friction can be saved by the implementation of new tribological technologies. This would result in electrical energy savings worldwide of 130,000 terajoule, economic cost savings of 2 billion euros and CO2 emission reduction of 11 million tonnes annually. An overview of the total energy saving potential by improved tribology in transportation and industry is presented.

Jul 31, 2018

By R. Karl Zipf

A fatal explosion in a sealed area at the Sago Mine in 2006 prompted researchers and regulators in the United States to re-examine the requirements for explosion-resistant mine seals. Seals are used in underground coal mines to isolate abandoned mining areas from active workings. Prior to the Sago disaster, mining regulations required seals to withstand a 140 kPa explosion pressure. Recent research at the National Institute for Occupational Safety and Health (NIOSH)Pittsburgh Research Laboratory showed that pressures from explosions can far exceed this pressure. U.S. mining regulations now require much stronger seals. Current research focuses on understanding the science, engineering and management of sealed areas of coal mines. Scientific efforts seek understanding of how explosive methane-air mixtures accumulate using measurements and models of the sealed area atmosphere. Additional scientific efforts aim to understand the explosion pressures that can develop using a combination of numerical modeling and experiments. Engineering efforts aim to produce design guidelines for seals that can resist the new higher pressure design criteria. NIOSH researchers are also developing guidance for monitoring of sealed area atmospheres and inertization of potentially explosive gas mixtures within sealed areas. This paper seeks to encourage scientific discussion among international peers since preventing explosions within sealed areas is of interest to underground coal operators and regulators.

Jan 1, 2009

By James O'Brien, Lyman Frost, S. Elangovan, J. Stephen Herring, Joseph Hartvigsen, Carl Stoots, Anthony Nickens

"Carbon dioxide recovered from concentrated sources, such as metallurgical reduction furnaces, cement kilns and fossil power plants can provide a valuable feedstock for a synthetic fuels industry based on energy from nuclear, solar, wind and hydropower sources. High temperature co-electrolysis of CO2 and steam to produce synthesis gas has been demonstrated using reversible solid oxide fuel cell technology. Where a source of high temperature process heat is available, such as from an advanced high temperature nuclear reactor or solar dish concentrator, the endothermic electrolysis reactions can utilize both thermal and electrical inputs in such a way that the conversion efficiency within the cell is 100%. Synthesis gas produced in a coelectrolysis cell has been further reacted over a catalyst to produce conventional hydrocarbon fuels. Widespread implementation of synfuel production from CO2 will enable a much larger reliance on intermittent renewable energy than can be accommodated by conventional electric demand profiles.IntroductionFor the past several years, Ceramatec, Inc and the Idaho National Laboratory (INL), have been studying the feasibility of high temperature solid oxide electrolysis for large-scale, nuclearpowered hydrogen production under the U.S. DOE’s nuclear hydrogen initiative (NHI) as an alternative to the thermochemical process. Parallel to this effort, the INL and Ceramatec have been researching high temperature co-electrolysis of mixtures of steam and CO2 to produce syngas:"

Jan 1, 2008

By R. T. Seaman

Pressure oxidative treatment of whole ores and/or mineral concentrates is used to leach or liberate metals of value for downstream recovery. Silver, when present, is often lost in processing, precipitating as a cyanide-insoluble jarosite in the residue. Depending on pressure oxidation conditions, the degree of silver loss to jarosite can vary dramatically. Batch bench-scale testwork is often performed to define that loss, and then assess the implications in continuous operations. This paper focusses specifically on the impact of CESL pressure oxidation conditions on silver recovery, and discusses limitations of batch bench-scale testing as well as means of overcoming these limitations to better predict silver recovery in the scale up from bench-scale to continuous operations. Since silver is only partially soluble in both sulphate and chloride media, it will gradually leach and deport to a jarosite as oxidation progresses. When a silver-insoluble anion, for example iodide, is dosed prior to oxidation, there is a marked improvement in silver recovery from batchgenerated residue; however, that benefit is not consistently seen in continuous operations. The difference has been attributed to the dynamic solution conditions in the batch test, specifically the first few moments of oxidation. Using these principles, a predictive correlation has been established between initial leach concentrations of iron and acid and ultimate silver recovery with iodide addition.

By L. G. Wilson

In our comparison of California and Turkish colemanites, we should first place the discussion in context. In order to exclude technical considerations, which are not germane to this paper, we must make the manifest and basic observation that if colemanite were not acceptable for the production of glass products it would not be used, and we would not be interested in this comparison at all. Suffice it to say that the colemanites, being calcium borates, provide a necessary flux in glass manu¬facture, together with the requisite degree of physical strength and chemical durability which can be achieved only by the use in glass of a. flux substanti¬ally free from alkali; so the sodium borates are automatically excluded from the production of textile fibers. Thus we have today under consideration only California colemanite, Turkish cole mite, and, because it provides a degree of competition to both, ABA, or anhy¬drous boric acid, which, although it is a refined intermediate and of much higher cost, it is also of a much higher degree of purity, and its characteristics can easily be modified to produce a desired end product, so we must include it in any consideration of high quality borates. [Calcim Borate Pentahydrate] Colemanite is a [calcium pentahydrate,] with the formula Ca2B6011.5H20. It has a theoretical B203 content of 50.8%.

Jan 1, 1973

By James C. Barker

Yttrium and rare-earth element. pegmatite dikes are associated with a peralkaline granitic and nephelene syenite complex near Dora Bay on southern Prince of Wales Island. Mineralized dikes were mapped and sampled during USBM investigations in 1987 and 1988. Coarse-grained pegmatite dikes, which emanated as late-stage magmatic fluids from the intrusion, further evolved into vein-dikes and ultimately silica-rich veins. The dikes can be traced up to two miles along a north-south zone. Lithophile elements exhibit a pronounced zonation in vein-dikes and veins that are distal to the Dora Bay complex with increasing values correlating with increasing distance from the complex. The pattern of mineralization suggests very late stage magmatic fluids containing the incompatable lithophile elements were injected into a preexisting north-south fracture zone. REE mineralogy exhibit fine-grained intergrowths of principally thalenite and bastnaesite with lessor monazite and eudialyte. Euxenite contains most of the columbium values and zircon is commonly associated with the dikes. Estimates of inferred and hypothetical resource tonnage range from 1.7 X 1C6 to 8.5 X 106 st for two deposits. Contained RED (including yttrium) averages 0.5 pct and ranges up to 2.0 pct. Deposits are of polymineralic composition and about half of this resource comprises the heavy yttrium subgroup.

Jan 1, 2011

By Sergey S. Gudkov

In the current climate of changing the approach to mining and treatment of mineral resources, processing technologies are being developed that require little maintenance and are economically as well as ecologically sustainable. This may also involve the development of entirely new ways of ore processing. One promising approach is to use bioleaching for the pretreatment of gold refractory ores to cyanidation. Capital costs for vat bioleaching of concentrates and ores are very high and cannot be applied for small or medium-size deposits. IRGIREDMET JSC carried out bio heap leaching test work on refractory ore samples from three Russian deposits. Following this biological treatment a combination of flotation, vat bioleaching, and cyanidation are used to recover gold. After heap bioleaching, gold recovery was 75-80 per cent. It was found that efficiency of heap bioleaching process depends on ore feed size. High duration of this process is another feature and it lasts for about a year. This process can be also used for carbonates in the combination with other process during which acid generation occurs. The results of our studies have shown that this technology is amenable for refractory gold ores. Its introduction allows an increase gold recovery and to solve a number of environmental problems. Keywords: heap biooxidaton, the refractory of the ores, the degree of oxidation, arsenopyrite, pyrite, CIL

Sep 1, 2012

By Dale E. Wittmer

Nonoxide ceramic materials could substitute for high-temperature alloy steels containing imported critical and strategic materials such as cobalt, chromium, and nickel if their high-temperature properties can be improved. An important result of this substitution would be a reduction of the Nation&apos;s need for imports of critical and strategic materials. In this Bureau of Mines investigation, the primary objective was to produce high-purity u1trafine (particles <5 ~m equivalent spherical diameter (ESD)) alpha-silicon carbide (a-SiC) powders with improved high-temperature properties using the Bureau&apos;s patented turbo-milling process. A secondary objective was to determine the feasibility of using polymer mill construction materials as a means of eliminating metal contamination from the turbomill. U1trafine a-SiC powders with BET (Brunauer-Emmett-Te11er) surface areas from 30 to 35 m2/g (~0.06 ~m particle ESD) were produced in an all-polymer turbomi11. These high-purity powders (with I-pct Band I-pct C additions) hot-pressed to greater than 99 pct of their optimal density and exhibited properties commensurate with those of commercially available a-SiC. The most promising of the construction materials tested for the major wear surfaces of the turbomi11 was u1trahigh-mo1ecu1ar-weight (UHMW) polyethylene, a polymer thermoplastic.

Jan 1, 1984

By Charles F. Stack

The A. P. Green Refractories Co. operates clay mines in ten states. Eight of these states have reclamation laws with which we have to comply and indications are that the U. S. Congress will pass a federal surface mining reclamation act in the near future. These regulations, in addition to the value of land in most areas, dictate that mining and reclamation be considered as a single operation. In many instances the land may be more valuable after properly planned mining and reclamation than before. Refractory clay, commonly called "fire clay" is defined as a siliceous clay rich in hydrous aluminum silicates, capable of withstanding high temperatures. It is deficient in iron, calcium, and alkalies and approaches kaolin on composition. Refractory clay is much more limited in occurrence and usage than common clay or shale. During 1971, common clays and shales were mined in 47 states with a total production of 45 million tons. Fire clay production was reported in 22 states with a total production of only slightly over 3 million tons.(1) Many of these producing areas are extremely limited in extent and production. Several are contained within a one or two county area. This reflects the unique geological conditions required for the formation or development of fire clay. The major fire clay producing areas in the United States are shown in Figure 1.

Jan 1, 1974

By R. Schipper

Two bench scale biochemical reactors (BCRs) were operated over a period of 3 months for the removal of uranium, radium, and selenium from mining influenced water (MIW). A BCR is an anaerobic reactor comprised of organic and inorganic substrate including woodchips, straw, sawdust, and limestone. Uranium and selenium are removed in a BCR by biological reduction of oxidized species (i.e., selenite, selenate) to less soluble forms (Pahler et al. 2007, Blumenstein et al. 2008, Rutkowski et al. 2013). It is believed that radium may be removed through absorption to the biomass in the BCR. The bench scale BCRs were constructed of 6 inch PVC columns with a top to bottom flow configuration. The bench influent water consisted of three different water ratios from two adit seeps. BCR hydraulic retention times of 24 to 36 hours were targeted during the study. Influent concentrations ranged from 19 ug/L to 1.86 mg/L for dissolved uranium, 12 ug/L to 270 ug/L for dissolved selenium, and 4.9 pCi/L to 24 pCi/L for radium 226. The average and maximum dissolved uranium removal was 93.6% and 98.5% respectively, the average and maximum dissolved selenium removal was 93.3% and 98.9% respectively, and the average and maximum radium 226 removal was 89.5% and 100% respectively.

Feb 23, 2014