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By S. W. Ihle, L. J. Warren

A sample of garnet from the scheelite ore body on King Island, Tasmania, Australia, was upgraded and ground to produce an ultrafine portion suitable for micro-electrophoresis. X-ray and chemical analysis identified the garnet as andradite with some admixed grossular. At neutral pH the garnet particles were negatively charged, their zeta potential becoming rapidly more negative with increasing pH. An iso-electric point was found at pH 3.5. The effects on the zeta-potential of various electrolytes, hydrolyzable metal ions, and flotation collectors were also studied.

Jan 1, 1976

By Richard J. Mainiero, T S. Bajpayee

The U.S. Bureau of Mines (Bureau) has conducted research to evaluate the firing accuracy of electric delay detonators used in surface blasting operations. Over four billion pounds of explosives and blasting agents are used every year in surface blasting in coal, metal and non-metal mines. In a typical large-scale surface blast, several thousand pounds of explosives are fired in a timed sequence using delay detonators. The delayed firing of explosive charges allows time for the fragmented rock to move out before the next charge is fired.

Jan 1, 1990

By Rick Lamkie

When investigating citizen complaints about blast vibration and airblast, it is important to be able to establish the spatial relationships between blasts, blasting seismographs monitoring the events, and complainant structures to assess any directional impacts. The Pennsylvania Department of Environmental Protection (DEP) routinely uses hand-held GPS receivers to document these relationships. The waypoint (structures and seismograph monitoring locations) and tracking (blasting and permit areas) features are used to map a site. These data are imported into the software for editing and conversion to GPS Exchange (.gpx) format.

Jan 1, 2008

By Charles A. Edwards, Kenneth D. Merrill

The Construction of the Northeast Extension of the Baltimore Metro involved soft ground, compressed air tunneling. During the tunneling, gasoline and dry cleaning fluid contamination were encountered. Innovative approaches and solutions were developed to address these problems. Special emphasis was on the problem of compressed air pushing gasoline vapors into surrounding communities, resulting in an extremely dangerous situation and a public relations nightmare. Guidelines and standards were established for working in this contaminated environment. Also, through a proactive approach by all parties, all claims and disputes have been resolved.

Jan 1, 1995

By H. K. Livingston

A TECHNIQUE has been developed which makes it possible to determine the spreading pressure of liquids and solids, for simple systems. Data for surface tensions, interfacial tensions, spreading pressures, and contact angles for water, heptane, and silica are tabulated. These results can be applied to the evaluation of capillary rise and displacement pressure in a petroleum reservoir. Appropriate equations are presented and the application of these equations is discussed. The presence of surface-active components affects both capillary rise and displacement pressure and also seems to influence the rate of fluid flow.

Jan 1, 1942

By S. Behl, S. Mathur

The viability of physico-chemical purification methods such as selective, flocculation for the separation of two components having similar chemical compositions and the same crystal structure but different surface properties is demonstrated. A loss of selectivity was observed in a dolomite-dolomite mixture when polyethylene oxide (PEO) (five million molecular weight) was used us the flocculant. Heteroflocculation was minimized using a low molecular weight PEO (MW =105) as a site blocking agent (SBA). Near complete separation was achieved at pH 10.5 at the 100% recovery level

Jan 1, 1996

By D. A. R. Kay

Phase stability diagrams are used to predict the abilities of lanthanum and cerium oxides to desulfurize coal gasification products in the temperature range 800-1000 C. Results of desulfurization studies in laboratory fixed bed reactors illustrate the effects of i) sorbent preparation, ii) input gas quality and iii) temperature, on the desulfurization reaction. 2CeO(2-x)(s) + H2S(g) + (1-2x)H2 = Ce2O2S(s) + 2(1x)H2O(g) The results of desulfurization/oxidation regeneration cycles are also reported.

Jan 1, 1989

By M. Dubrovsky, J. W. Evans

A laboratory scale cell (approximately 50 amps current) equipped with a fluidized bed cathode was used in a study of the electrodeposition of cobalt from acidified aqueous sulfate solutions The effect of current density (in the range 0.1 to 1 amp/cm2 of diaphragm), cobalt concentration (4 8 to 100 glliter) and catholyte pH (1 35 to 6 2) on current efficiency and energy consumption were determined. Generally the current efficiency increased with increasing current density and cobalt concentration Current efficiencies were comparable to those reported in the literature for conventional electrowinning

Jan 1, 1981

By J. Iannicelli

A variety of domestic bauxites have been beneficiated to meet refractory grade standards by use of high intensity, high gradient, wet magnetic separation. Besides reducing the iron content to less than 2%, the Ti02 content of the bauxite was also reduced. The beneficiation can be accomplished by means of a simplified wet process flow sheet with an estimated cost comparable to that of water washed, filler grade kaolin. The process has been carried out on a small pilot plant and then scaled to produce 25 tonnes of calcined refractory bauxite meeting National Stockpile Specifications.

Jan 1, 1984

By Isiah M. Warner, Philip Oldham, John Kennedy, Bennett D. Lass

A new method for determination of residual flotation oils on beneficiated kaolin clays has been developed The method, which yields qualitative information, is based on fluorescence measurements employing a spatially resolved, polychromatic illumination source for excitation, and a two-dimensional detection scheme using a silicon-intensified, video imaging device The method was used to identify residual oils on a beneficiated, Washington County, Georgia, crude clay The results were compared to a similar qualitative analysis performed via capillary column gas chromatography using a flame ionization detector The video fluorometry was the preferred method of analysis

Jan 1, 1983

By Robert M. Rowe

Among the increasing operating costs affecting today' s processing facilities are those necessary in meeting the continually growing requirement for safe and environmentally sound materials- control and handling procedures. Of particular interest are materials listed as hazardous, the need to maintain accurate records of their acquisition, consumption and disposal, and the obligation to employees and the community to have information available regarding such materials. Some requirements affecting modern operating facilities are reviewed in this paper, and potential methods for dealing with complex handling and documentation requirements, including computer automation, are discussed.

Jan 1, 1991

By Arthur E. Goddard

Radio propagation measurements were conducted in a coal mine at UHF (200 to 1000 MHz) and VLF (1 to 50 kHz) to characterize the transmission loss of intra-mine paths. The basic experimental parameters included frequency, polarization, path orientation and distance. Further tests evaluated the performance of roof-bolt vs. loop antennas at VLF and parasitic reflectors at UHF. Measurement results are summarized in a series of transmission loss curves. Examples are presented to show the use of these curves in predicting the performance of radio communication systems in mines.

Jan 1, 1973

By Qiang Ji, Richard L. Sanford

A laboratory-scale microcomputer-based autonomous excavation system has been developed that moves a pile of fragmented rock to a designated location using a shovel attachment on a robot arm. Navigation and excavation sub- systems interactively direct a robot excavator to move the shovel to the rock pile, intelligently load its bucket using a video camera, and dump the rocks to a designated area. Although research was conducted on a laboratory scale model, the system can serve as the basis for further work on a full-scale, robust excavation system.

Jan 1, 1993

By N. M. Grant, W. G. Prast

Jamaica has extensive deposits of marble, gypsum, and limestone, offering prospects for commercial sales to nearby US markets, notably the Gulf Coast and Southeast. Stare-owned and private Jamaican industrial minerals producers have made limited sales to date but expect to increase exports during the balance of the 1980s. Restraints include Jamaican government controls on access to essential foreign exchange for new capital investments and distribution of profits. Jamaican efforts to identify market opportunities in the US are reviewed, and the outlook for further exports of carbonates is discussed.

Jan 1, 1987

By Robert C. Bates

Published information on costs of radon daughter control in uranium mines was analyzed to develop estimates of the cost per ton for any level of radiation exposure control. All data were converted to 1967 cost of living index to provide a common analysis base. Re- of the analysis show that the cost per ton increases exponentially as the radiation level is lowered. A linear relationship with the cost of living index is assumed, and equations and graphs are provided to estimate control cost per ton for any exposure control level and cost of living index.

Jan 1, 1982

By G. W. Dopson, P. A. Korpi

The angular spiral lining system reduces energy consumption and grinding media consumption in grate discharge ball milk. This paper discusses the effect of this lining system on mill product size distribution. Performance comparison of a grinding circuit outfitted with angular spiral liners in ball mills are made with respect to standard double wave-liner installations. The angular spiral lining system was developed by Waagner-Biro of Austria. The installation of this lining system at Magma Copper Co. is the first of its kind in a grate discharge ball mill used for wet grinding.

Jan 1, 1983

By Bob de Raadt

After a review of the general principles for blasting stacks, the stagnations of two stack demolitions are investigated. The author concludes and demonstrates that MS-delay blasting can be risky under certain circumstances. How this initiation device can still be applied safely to the demolition of stacks is shown in an account of a blasting operation, in which two 106-m (350 ft) -high concrete stacks were involved. The recent discovery of a possible hazard of MS initiation in this field of blasting is an essential contribution to increased safety in blasting tall structures.

Jan 1, 1982

By Robert J. McNally

There are three primary plant nutrients-nitrogen, phosphorus, and potassium--expressed in any fertilizer compound as percent N, percent P2O5, and percent K20, in that order. This article will be concerned with the first two. The chief source of P205 is phosphate rock. As found in the western states phosphate rock is essentially tricalcium phosphate-calcium fluoride (fluorpatite). As such, it is quite water insoluble. The principal phosphate fertilizer used is single superphosphate, produced by reacting sulfuric acid with phosphate rock in the proper proportions.

Oct 1, 1956

By E. Jannoulakis

This paper introduces a practical methodology for analyzing vi¬bration records in view of improv¬ing blast designs and preempting anomalous vibrations. This technique, which is based on empirical data, uses a blasting-efficiency determinator (BED) as an indicator of vibration-energy transmission. The method was tested using data from a blasting event at an open-cast coal mine in the province of New Brunswick, Canada. The results derived from the BED values showed that geology and delay timing were probably the principal factors that induced high-intensity vibration propagation.

Jan 1, 2000

By R. J. Shaffer

Hydraulic fracturing in rock masses involves complex and coupled processes of fractures propagating in discontinuous media and of fluid flow in discrete channels. The Unconventional Gas Program at LLNL is actively developing numerical models to gain insight in the physics of these coupled processes. This paper describes the current status of the FEFFLAP code, which models fluid-driven discrete fracture propagation in jointed media. We also discuss the results of a preliminary series of physical tests in which hydrofractures were driven across slanted interfaces between dissimilar materials, in blocks loaded in biaxial compression.

Jan 1, 1984