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By S. Castro

Molybdenite flotation is strongly depressed at pH higher than 9.5 in the flotation of Cu-Mo ores in sea water. Chemically sea water contains mainly Na+ and Cl- ions, but also some secondary ions, such as SO42-, Mg2+; Ca2+, HCO3-; etc., which are not necessarily indifferent for the flotation of molybdenite. The natural floatability of molybdenite in sea water and in NaCl solutions containing different secondary ions is investigated by micro-flotation tests. The tests indicate that the floatability of molybdenite in alkaline media in 0.6 M NaCl solutions is not affected by the presence of anions, such as, SO42- and HCO3-, at concentrations similar to those occurring in sea water. However, a strong depression of molybdenite at pH ranging from 9.5-10.0, is produced by the alkaline earth metal cations (Ca2+ and Mg2+ ions), dissolved in distilled water or in 0.6M NaCl solutions. It was found that effect of Mg2+ions is significantly stronger than Ca2+ ions. Effect of both ions is attributed to hydrolysis and adsorption of MOH+ hydroxy-complexes. This is followed by subsequent precipitation of hydrophilic colloidal hydroxides at the molybdenite/solution interface, and in bulk solution.

Sep 1, 2012

By R. R. Beebe

"Laboratory and pilot-scale tests are almost invariably required before metallurgical development can proceed. Difficulties with sampling, as well as with classical chemical and physical scaleups, are normally anticipated and relatively well-understood, but more subjective factors also come into play, including misunderstandings of the operating scheme chosen, wrong ""lessons"" learned from similar operations, failures to handle data appropriately, and even arbitrary intervention by management. The paper examines some of these subjective factors and suggests ways to guard against them. Several anecdotal case studies are used as examples, including when and where to heap leach or to mill specific types of gold ore.When the Romans first exploited the gold-rich gossans at Rio Tinto, they were guided by analyses and tests that delineated the ore deposits, identified the richer portions, and measured the gold recoveries achieved. There is little evidence, however, to suggest that test data were used to develop improved methods of metallurgical extraction. Indeed, it is likely that ores too difficult to treat were simply passed by, at least until improvements in full-scale operations could deal with them. For example, it is not difficult to imagine that an early metallurgist might test a tin ore by placing some in a fire; a smallscale emulation of the method actually used in practice."

Jan 1, 1997

By P. Chris Pistorius, Johannes Sono, Rossouw Sono, J. J. Kobus

Different coal properties are important in SL/RN (coal-based rotary kiln) direct reduction of iron ore, and in electrical smelting of prereduced iron ore. These differences were highlighted when a plant which processes titaniferous magnetite had to change to different coal types after decades of operation. Laboratory simulation was used to evaluate two candidate coals, which were similar in volatile content and rank, but differed in reactive maceral content. Direct reduction was evaluated by isothermal experiments using a packed bed of ore and coal, measuring the off-gas composition to determine reaction rates and departure from equilibrium. These indicated reduction to be under mixed control, and quite sensitive to temperature (confirming that the coal reactivity is of importance). An aspect of electrical smelting was assessed by determining dissolution rates of the coal in molten iron at 1550°C. Dissolution rates did correlate with differences in coal structure, as determined by X-ray diffraction, with the more ordered ("more crystalline") coal dissolving faster. The conclusion is that the coal which is more reactive during direct reduction is less reactive during dissolution. However, it is concluded that controlling the temperature during direct reduction offers a feasible method to reconcile the two process steps.

Jan 1, 2003

By C Harwood

Underground coal mines in the United States are in the process of completing installations for tracking and communication systems, mandated by Congress after a number of recent coal mine disasters. Yet, evaluation, modelling and testing of such systems has lagged due to legislated changes, abruptly introduced into the coal mining industry. System installation in a wide array of mine types, configurations, layouts and characteristics has provided a wealth of information regarding their potential in underground environments. Data collected from numerous installations for a variety of systems can be used to further define true capability and accuracy of communication and tracking packages. This paper describes a uniform means of evaluating the performance of a communication and tracking system. Several performance measures are proposed and described. These measures can also be predicted using an interactive software program. This program predicts the signal propagation, given the input mine characteristics and layout, with numerical and visual feedback. New or alternative system installations can also be more accurately designed to potentially minimise initial system cost and time required for trial and error installs. The focus of this research is to develop tools and protocols that can evaluate and measure the effectiveness of installed underground communication and tracking systems.

Nov 22, 2011

By A Dal-Corobbo

Traditional acid and metalliferous drainage (AMD) wastewater treatment focuses on the iron co-precipitation/adsorption process as this is a very effective method of reducing heavy metals, including copper, lead, zinc, arsenic, etc, to parts per billion (ppb) levels in AMD wastewater streams. One of the drawbacks to this method however is the large volume of sludge produced and subsequent disposal costs for the mine site concerned.A proprietary metals treatment system called high density sludge (denoted HDS) which significantly reduces the quantity of waste generated is described in this paper. This process generates a dewatered sludge that contains in the order of 50 to 55 per cent solids. This sludge is denser than conventionally dewatered sludge, which typically contains only 20 to 30 per cent solids. This advanced process has a wide range of applications and can be easily retrofitted into existing AMD treatment systems. It has been successfully installed at several mine sites to treat AMD wastewaters. This paper discusses the high density sludge process, its benefits and provides data and operating results from pilot test installations.CITATION:Dal-Corobbo, A, 2013. High-density sludge process for treating metal bearing acid and metalliferous drainage wastewaters, in Proceedings Water in Mining 2013 , pp 217-220 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 26, 2013

By Bryan Ulrich

Knight Piésold and Co. hosted its annual roundtable discussion on March 17, 2011 at the Stockman Hotel and Casino in Elko, NV. The theme for Roundtable 2011 was, ?High density tailings, paste, and filtered tailings,? although the topic may well have been subtitled, ?Don?t prematurely rule out any technologies before they are given their day in court.? Bryan Ulrich, Knight Piésold?s local representative, as well as Tom Kerr from Knight Piésold?s office in Denver, CO, were on hand to help facilitate the discussion. Ulrich and Kerr are senior vice president and president of Knight Piésold?s U.S. practice, respectively. The event played host to more than 30 attendees from several western states. Attendees included personnel from a dozen mining properties and various corporate offices. There were also attendees from manufacturing and specialist consulting firms who have been providing services to various high-density tailings, paste and filtered tailings operations worldwide. It may be noted that the term ?filtered tailings? is used in this discussion. Alternative terms, such as ?dry stack? or ?dewatered tailings,? should be avoided whenever possible, as such terms tend to give a false sense about the nature of the material since these materials typically still retain a significant amount of moisture.

Jan 1, 2011

By P. L. Swanson

Over a recent 20-month observation period, the U.S. Bureau of Mines obtained seismogram records from a single vertical-component, short-period seismometer installed at the surface of a metal mine in northern Idaho. The seismic events were analyzed for local (Richter) magnitude (M), time of occurrence, location, and relation to rock bursting and production blasting. Approximately 150 seismic events with -0.5 = M = 2.9 were located within the mine, yielding a b value (slope of the logarithm of the number of events with magnitude greater than M versus M) of 0.5. Event locations were constrained using a dense underground array of high-frequency accelerometers. Twenty of the surface-recorded events, with 0.5 = M = 2.9, were associated with rock bursts that produced damage requiring at least 1/2 day of cleanup and/or repair. Other possibly hazardous rock bursts, with magnitudes as small as -1.1, were numerous but were not associated with significant structural damage. Approximately 60 pct of the seismic events with M > -0.5 and 75 pct of damaging rock bursts occurred within 45 min of blasting. Estimates of characteristic rupture dimensions for rock bursts with -1.1 = M = 2.9, based on a conventional dislocation shear-slip model of failure, range from 3 to 300 m.

Jan 1, 2010

By R. R. Wells, G. M. Potter, A. O. Ipsen

This paper gives results of laboratory and pilot - plant investigations of concentration of western manganese ores during the Bureau of mines manganese-development program initiated in December 1940. The data summarize results obtained from laboratory investigation of concentration of ores from three properties in southeastern Arizona . The high - grade Gray - claims lot B ore , a product of hand sorting , is marketable directly or after sintering treatment . Intermediate - grade lot A selectively mined ore would be marketable after sintering as a plus 35 percent manganese produce , but gravity concentration methods were employed effectively to produce high - grade manganese concentrates with over 80 percent recoveries . Complex association of fine - grained manganese oxides , calcite , and fluorite in a siliceous ground mass limited the recovery of high-grade manganese concentrates obtainable from the low-grade Pyrolusite -group ore . A recovery of 63.7 percent of the manganese was made by flotation in a concentrate that sintered to plus 48 percent manganese grade . The low-grade Davis ore contains iron and manganese oxides too intimately associated to permit production of marketable manganese products . However , good rejection of calcite gangue was obtained by flotation , and the enriched manganese - iron product might have value as a spiegeleisen ore .

Feb 1, 1946

By D. Harrington

More or less unconsciously and from sheer force of habit human beings do many things they probably would not do if the possible consequences of their acts were fully recognized and appreciated. Such carelessness ordinarily could be condoned if human life were not at stake, but it is difficult to understand why intelligent men engaged in the hazardous occupation of mining indulge with the utmost indifference in some habit or continue some custom in violation of State leas and company regulations and under circumstances that may jeopardize not only their own lives but those of scores, even of hundreds, of their fellow workers as well. The old adage that stolen sweets are the best may or nay not have some foundation, but when applied to the practice of smoking surreptitiously in a coal mine, more especially a gassy mine, it is without even remote justification. Although a relatively harmless habit in the proper environment, smoking has been the cause or suspected cause of many gas explosions and black-powder ignitions and has resulted in numerous instances of bodily injury, loss of life, and destruction of property. Likewise, many fires in both coal and metal nines, causing loss of life, have been started by smoking.

Jan 1, 1941

More and more coal in Australia is extracted by underground mining methods especially by longwall mining. These methods can be particularly sensitive to relatively small-scale structural discontinuities and variations in roof and floor rock character. Traditionally, information on these features has been obtained through drilling. However, this is an expensive process and its relevance is limited to the immediate neighbourhood of the boreholes. The geological uncertainty remains. Seismic surveying, especially by 3D seismic, is an alternative tool for geological structure delineation with growing credibility. In fact, it is one of the most effective geophysical methods available for identification of geological structures such as faults, folds, washouts, seam splits and thickness changes which are normally associated with potential mining hazards. Seismic data even can be used for stratigraphic identification. The information extracted from seismic data then can be integrated into mine planning and design. In this paper, we demonstrate computer aided interpretation techniques for maximising the information from seismic data and illustrate the ability of seismic reflection methods to resolve localised geological features. Both synthetic and real seismic data obtained in recent 2D and 3D seismic surveys from Australian coal mines will be used. Compared with results obtained with drilling programs, the structural definitions from seismic are of unprecedented quality.

Jan 1, 2002

By S. Aram

Concrete reinforcing requires coordination among many roles: structural engineer, estimator, detailer, fabricator, installer and others. The methods used to define and represent concrete reinforcement elements and assemblies in building information models is crucial in determining the efficiency of sharing data among BIM platforms and the effectiveness of using the carried data in production planning, fabrication and site work activities. Starting from the information items that are required to be provided by BIM platforms, as defined in earlier work, we have developed the Industry Foundation Classes (IFC) bound Concepts and Model View Definitions (MVDs) for concrete reinforcement. Furthermore, in coordination with software developers, we propose guidelines for best practices for concrete reinforcement modeling. Implementing these guidelines by software providers will improve reinforcement modeling with regard to various aspects of reinforcement products like geometric representation, placement, and property specifications. The proposed approach is selected as a way to improve functionality of the shared data for production planning, fabrication, project management, and site activities. Guidelines for assigning information to rebar type and instance definitions as well as to rebar elements and assemblies are provided. An efficient method of sharing geometry and property sets among rebar instances of a rebar array is also defined.

Aug 1, 2013

By J. H. van Laar, L. J. van der Walt, P. L. Crouse, H. Bissett, G. J. Puts

"SynopsisSilicon carbide nanopowders were produced using a microwave-induced plasma process operating at 15 kPa absolute and at atmospheric pressure. Methyltrichlorosilane (MTS) served as precursor, due to its advantageous stoichiometric silicon-to-carbon ratio of unity, allowing it to act as both carbon and silicon source. Argon served as carrier gas, and an additional hydrogen feed helped ensure a fully reducing reaction environment. The parameters under investigation were the H2:MTS molar ratio and the total enthalpy. The particle size distribution ranged from 20 nm upwards, as determined by SEM and TEM micrographs. It was found that an increase in enthalpy and a higher H2:MTS ratio resulted in smaller SiC particle sizes. The adhesion of particles was a common occurrence during the process, resulting in larger agglomerate sizes. SiC layers were deposited at 15 kPa with thicknesses ranging from 5.8 to 15 µm.IntroductionIt is well known that methyltrichlorosilane (CH3SiCl3 or MTS) decomposes to form silicon carbide (SiC) and hydrogen chloride (HCl) as shown in Equation [1]. The reaction kinetics and mechanisms for this reaction are thoroughly reported in the literature (Sone et al., 2000; Papasouliotis and Sotirchos, 1999; Kaneko et al., 2002; Wang et al., 2011)."

Jan 1, 2015

By D Giurco

This paper presents the results from research undertaken in the CSIRO-funded Mineral Futures Collaboration Cluster on developing a future vision for the mining and minerals industry – Vision 2040 – in which the industry proactively contributes to long-term benefit for communities and the nation. Our research finds that Australia is currently experiencing mining-led prosperity due to high commodity prices, yet underlying this are challenges for maintaining market share due to lower productivity from extracting lower grade, more remote and complex ores. Whilst much focus has been on developing new technologies for finding and processing such ores, this paper assesses these activities, together with policy and market innovations in the context of needing to strengthen social, environmental and financial capital for long-term benefit. Vision 2010 sees mining activities linked to systems that are net providers of clean water, energy and ecosystem services, rather than minimising negative impacts alone; sovereign wealth funds are used to harness current prosperity for future innovation. Using a case study in lithium and comparisons to iron/steel, coal and copper – we illustrate the opportunities for new technology, policy and market innovations to link the mining and minerals sector in Australia to more sustainable patterns of production, consumption and prosperity.

Nov 22, 2011

By B Mack

The cost of water treatment is now more than ever a major consideration for maintaining an environmentally and economically sustainable mining operation. As an industry, we often have to consider water sources that are highly impure and difficult to treat. We are also discovering the value of our waste waters in this regard and using new and improved methods and technology to reclaim and reuse water. In many instances, the water or waste water to be treated is highly acidic and saturated in sparingly soluble salts. Conventional systems used to liberate this type of water typically involve high doses of lime with large volumes of waste sludge produced, and are comparatively complex to operate, to pretreat the water in order to reduce scaling tendency on the reverse osmosis stage. However, if the water is considered valuable for reuse, then why not avoid difficult and cumbersome pretreatment processes and treat the water at low pH to keep the sparingly soluble salts, metals and other dissolved species in solution. This paper describes a patented technology that uses and successfully proves this concept as a cost effective option for certain situations. Results from a treatability study on an Australian groundwater are discussed, along with an economic comparison to a conventional method and discussion on full-scale potential.

Jan 1, 2009

By Xue Yang

Even though many approaches have been proposed for automated fault detection and diagnosis of Heating Ventilation and Air Conditioning (HVAC) systems, and advanced maintenance programs, such as preventive and predictive maintenance have been applied for the systems, issuing work orders for corrective maintenance is still a reality. Currently corrective maintenance still accounts for more than 55% of all maintenance programs in average facilities in the US (DoE, 2010). Indoor air related problems are especially important among corrective maintenance work orders. This paper provides details of a case study conducted to capture the workflow that HVAC mechanics follow, their rationale in diagnosis process and the information they typically refer to while responding to indoor air related corrective maintenance work orders. The general workflow for HVAC mechanics to complete such types of work orders was summarized into 5 stages, and generic information requirements recorded from the case study were synthesized. Initial findings show two main challenges in the industry for HVAC mechanics to get access to required information, which highlights the need for a systematic approach that would enable identification of such information applicable to a given context under which a work order has been generated and provide values of required information for HVAC mechanics to do sound diagnosis through integrated data repositories.

Aug 1, 2013

By H. J. McQueen

Before 1950, hot working was simply deforming above the recrystallization point and gave a soft product compared to cold working. From 1960 onwards, improved testing in compression and torsion (stress, strain rate, temperature, quenching) provided valid specimens for microstructural analysis by polarized optical and transmission electron microscopy (TEM). Indeed, TEM was essential to uncovering the hot working mechanisms because it could distinguish between cold and hot substructures (dynamic recovery) in either initial or new grains (dynamic recrystallization). Over the years, teams at Concordia, McGill and UBC obtained NSERC support for students and equipment. CANMET built up a hot forming group having capabilities from high-rate cam-plastometer compression to rolling of experimental alloy billets; this was combined with latest metallographic instruments for fundamental research. Al alloys of every class (2000, 3000, 5000, 7000, 8000) were studied to understand the effects of solutes, precipitates, dispersoids and composites. The complex flow patterns in extrusion were clarified and modeled by finite element methods. Physical simulations of rolling schedules (up to 20 passes and reductions of 98%) by torsion provided evidence of microstructure development during both the passes and the softening intervals, thus clarifying development of texture in different alloys. The results frequently appeared in proceedings of Light Metals symposia and Canadian Metallurgical Quarterly

Jan 1, 2011

By James A. Finch, Xiang Zhou, Yue Hua Tan

Methods to determine frother functions, control of bubble size and froth properties, are now widely used. Some collectors also exhibit frother functions which are less understood. Using a water-air system in a mini-mechanical flotation cell setup, this paper determines bubble size and water overflow rate for three amine collectors: one primary amine (dodecylamine, DDA) and two commercial ether amines (Flotigam® EDA and Flotigam® 2835-2L) and their combination with two common frothers, MIBC (methyl isobutyl carbinol) and PPG 425 (polypropylene glycol, molecule weight 425). Compared to the frothers, the amines were less effective in reducing bubble size, giving larger minimum size and the two commercial amines showed evidence of coalescence at low concentration. In blends, at fixed frother dosage, frother eliminated the coalescence but as amine concentration increased the amines dominated bubble size. Water overflow was a strong function of reagent type. For fixed 1-cm froth depth, PPG 425, Flotigam® 2835-2L and to a lesser extent DDA produced overflow while MIBC and Flotigam® EDA did not. In blends with frother overflow increased except with Flotigam® EDA. Mechanisms are briefly explored. The principal benefit of blending identified is the elimination of coalescence if residual concentration of the two commercial amines is below ca. 10 ppm.

By Greg Plutko

Laboratory testing has shown that the Marsh Funnel test can be significantly impacted by long-chain polymer entanglement. In general, shorter hydration time leads to more chain entanglement which in-turn, leads to higher marsh funnel values that values seen for longer mixing. This trend makes it very difficult to predict funnel-viscosity on successive days. Data is presented which helps to explain this chain interaction effect on Marsh Funnel data and how it differs from traditional Fann viscosity. The data suggest that this long-chain polymer entanglement occurs more in samples with less hydration time and decreases as hydration time increases. There is also suggestion that higher polymer concentrations have a greater drop-off in marsh funnel viscosity for a given aging length than do lower solids slurries. Fann rheology was shown to be much less impacted by the hydration time of the PHPA polymers than was Marsh Funnel viscosity. This suggests that the Marsh Funnel viscosity is impacted by some aspect of the slurry that does not affect Fann rheology as strongly. It is known from literature that longer-chained polymers have more potential to entangle and our data support the theory that the Marsh funnel viscosity is greatly impacted by this polymer-chain ‘roping’ entanglement.

By Shiqiang (Rob) Hui, Jiaren (Jimmy) Jiang, Rees Llewellyn, Yongsong Xie

Wear has been estimated to cost the Canadian mining/mineral processing industry over $15 billion per year mainly for repair/replacement of worn parts in 2013. The associated production loss is difficult to quantify but add considerably to the problem. The Canadian oil sands sector which has to deal with extremely abrasive and erosive solids, has traditionally incurred extremely severe and often unique attack. Demonstrable progress in mitigating the wear problems has been achieved through materials development, more informed materials selections, and better component and operation condition designs. An integral contributor to these advances is a long-term collaborative research partnership between NRC and the mining/supply industry. In this paper, this continuing collaboration will be described. A main focus is to identify degradation mechanisms occurring in the most severe and important service applications and to correlate these findings with laboratory test data. Relevant abrasion and erosion (often combined with corrosion) properties have been established and correlated with composition and microstructures for all classes of resistant materials ranging from relatively soft elastomers to ultra-hard ceramics. A comprehensive wear properties database has been compiled. This capability has been instrumental in facilitating the development of improved materials, optimizing materials fitness/selection for service, wear failure analysis, and quality assurance.

Jan 1, 2015

By E Jamieson

For a number of years, Alcoa World Alumina Australia (Alcoa) has been investigating opportunities to produce economically viable products from bauxite residues. Three of these potential products are described here, being Red Sand, ALKALOAM« and REDLIMETM.Red Sand has a nominal particle size of +100 micron and is physically little different to crushed bauxite from which it is derived. In AlcoaÆs Western Australian refineries, Red Sand constitutes up to half of the residue going to impoundment areas. Initial testing indicates that this sand could be processed to provide an acceptable general landfill material, a construction back fill or a material suitable for road base construction. ALKALOAM« is the fine-grained residue often referred to as red mud. A great deal of work has been done to show the benefits of adding this material to sandy soils, which are common in coastal regions of WA. ALKALOAM« has properties that can elevate the pH of the acidic soils and also retain phosphorous, reducing overall fertiliser use and protecting sensitive waterways. REDLIMETM is a by-product of the refining process. This material has a high acid neutralising value. REDLIMETM could be more effective at pH control than most available products because of the fine particle size and sodium carbonate that remains with the product.

Jan 1, 2004