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By E. Oraby, S. Garcia, A. Thurgood, D. Bertoldi, G. O’Malley

Mining and Process Solutions (MPS) most advanced process, GlyCatTM is the only process that can be easily adapted to existing cyanidation plants in the market today whose real advantages over cyanidation are when treating copper containing ores, concentrates or tailings. With such complex material, GlyCatTM requires 70-90% less cyanide addition to achieve the same precious metal extraction. However, GlyCatTM is not simply cyanidation with added glycine. It is a completely different process where the solution chemistry and conditions needed to effectively leach the precious metals are quite different. Downstream however, the process is largely unchanged as the recovery of the leached gold and silver uses existing known processes such as conventional activated carbon or zinc cementation (Merrill-Crowe process). Another advantage is lower SCN, OCN, WAD and no free cyanide in the effluent which can substantially reduce cyanide detoxification requirements and decrease the OHS and ESG risk of the operation. This paper outline some of these differences and presents testwork, piloting and process examples to highlight the advantageous of this new process over conventional cyanidation.

Feb 1, 2023

By C. Ciriello

Six Sigma methodology, as applied within Xstrata (formerly Falconbridge and Noranda), involves a disciplined approach to managing projects, solving problems, improving performance, and leveraging information. The four (4) cornerstones of Six Sigma are the use of Philosophy (customer driven, desire to improve and discipline), Metrics (measurement systems), Methodology (scientific method and sequence of deliverables), and Tools (such as statistics, change management, and root cause analysis). This paper will outline the general steps of the Six Sigma methodology and demonstrate how each phase directly applies to a real plant metallurgical project aimed at reducing nickel losses of the rougher flotation circuit at Raglan. The main concepts of Six Sigma are described, along with the specific challenges, successes, and deliverables related to the project. It is also the authors' aim to demystify the basic Six Sigma principles.

Jan 1, 2007

By Patrick Moore

In 1971 the government of British Columbia issued a permit for the Island Copper Mine to commence disposal of 33,000 tons per day of mine tailings into Rupert Inlet, a marine fjord on the northwest coast of Vancouver Island. There was considerable controversy surrounding the development, public hearings were held, and as a requirement of the permit the company was obliged to carry out a comprehensive environmental monitoring program. The results of this program provide a thorough assessment of the environmental impact of submarine tailings disposal over the 24-year life of the mine. Following closure in December, 1995, the monitoring program continued for three years to determine the extent of marine ecosystem recovery and re-colonization. It is apparent from the findings of the monitoring program that the mine tailings were dispersed more widely than was originally predicted. It is also clear that widespread heavy metal contamination has not materialized. In retrospect it appears that submarine tailings disposal has resulted in far less severe environmental impacts than if the alternative of land disposal had been adopted. This review highlights significant aspects of public policy decision-making, design of environmental monitoring programs, and questions of interpretation of monitoring program data.

May 1, 2002

By H. C. Howarth

THIS paper gives observations on ground movement and subsidence resulting from pillar drawing in the Lick Run section of Montour No. 10 mine of the Pittsburgh Coal Co. adjacent to solid coal owned by the U. S. Bureau of Mines at its Experimental mine in Snowden Township, Allegheny County, Pennsylvania. The investigation was planned by George S. Rice, chief mining engineer of the Bureau, who arranged the necessary cooperation with Dr. L. E. Young, vice president of the Pittsburgh Coal Co. Engineers of that company placed permanent monuments on the surface to establish the boundaries of the coal owned by the Bureau and to furnish fixed points to which all levels were referred. Engineers of the Experimental mine staff then covered the ground under observation with a checkerwork of monuments made of oak pegs set into the ground at 50-ft. intervals in two directions at right angles to each other. The level of these pegs was determined first from Dec. 16 to 30, 1929; again from May 25 to June 5, 1930, and finally from July 7 to 15, 1931. Observations were then discontinued because work had been stopped temporarily in this part on Montour 10 mine.

Jan 1, 1933

By K. C. Corin, M. Tadie, N. Ndamase

Fresh water conservation efforts and strict environmental regulations have forced the mining industry to reduce freshwater consumption and effluent discharge. This is achieved by recycling process water back to mining processes. The performance of flotation circuits depends on the pulp chemistry. When process water is recycled to flotation cells, organic and inorganic species that have accumulated over time alter the pulp chemistry. The presence of accumulating ionic species such as SO4 2- and S2O3 2- has been found to hinder the adsorption of collector ions onto mineral surfaces. Sulphide minerals are semi-conductors; electrochemical reactions take place on their surfaces. The adsorption of collectors onto mineral surfaces takes place via electrochemical reactions. This study, therefore, aims to investigate how the presence of accumulating ionic species at varying ionic strengths affects the adsorption of sodium ethyl xanthate onto chalcopyrite from an electrochemical perspective. Synthetic plant water comprised of single salts with varying ionic strengths was used. Rest potential measurements were conducted to investigate collector-mineral interactions in the presence of these ionic species. Microflotation tests were performed to determine whether the presence of these ionic species affects mineral floatability. Higher chalcopyrite recoveries were achieved in the presence of SO4 2- than in the presence of S2O3 2-. Rest potential measurements were found to successfully predict microflotation performance in the presence of the ions of interest. Keywords: Flotation water quality, electrochemical adsorption; xanthate collectors

Jan 1, 2020

By Raj P. Singh Gaur

Due to high concentration of NaOH in the digested slurry after scheelite digestion, it is diluted to about 4N before filtration to separate sodium tungstate solution from the sludge (residue). However, in practice there may be deviations in the normality of NaOH present in the slurry. There may also be variations in the temperature of the slurry and filtration time. Slight variations in these parameters could cause tungsten losses in the sludge via the back reaction: Ca(OH)2 + Na2WO4? CaWO4 + 2NaOH This paper pertains to the effect of normality, temperature and time on the tungsten losses in the sludge that is separated from ?diluted-scheelite-slurry-in-NaOH? via filtration. Results indicated that tungsten losses in the filtered residue (sludge) were quite significant when the slurry temperature was kept at 70°C or higher. The effect of high temperature was less significant at the slurry normality of 3.6 or higher. Combination of low slurry normality (<3.6) and high temperature (>60°C) resulted into large W-losses in the sludge.

Jan 1, 2006

By Giulio Antunes de Medeiros, Leonardo Martins Silva, Giselle de Mattos Araújo, Rayla de Souza Caldas

To analyze the direct reduction of self-reducting briquettes producted with different electric arc furnace dust contents, three sets of homogeneous mixtures were produced with elephant grass biomass, iron ore, cement and furnace dust in increasing levels, which were submitted to thermogravimetric tests in muffle furnace and TGA furnace at variable temperatures and times. The curves of degree of reduction were obtained and the reduced briquettes were analyzed by scanning electron microscopy (SEM) and X-ray diffraction (XRD). The results showed that the reducibility of the agglomerates is diminished by the increase of furnace dust, with variations of this result at higher temperatures. The observed microstructures were spherical particles, porous structure or whiskers. Based on XRD results, it was considered probable that the decrease of the degree of reduction with the increase of furnace dust content is related to the reaction between hematite and zincite, which is expected to be controlled by zinc diffusion.

Oct 1, 2019

Ten years ago we surveyed in "Uspekhi Khimii" the mechanism of the synthesis of hydrocarbons from CO and H2 (1).5 With new data obtained since then, mostly by Soviet researchers, our previous work (2), dealing with new forms and catalysts of the synthesis, is brought up to elate by reviewing research in this field. FORMATION OF CARBIDES The hypothesis that carbides are intermecliates in the synthesis assumes that carbon monoxide reacts with the metals of the eighth group and that this reaction is connected with the reversible reaction 2CO[=]C +CO2 (1) in a certain range of temperatures (3).

Jan 1, 1958

By Fred W. Stuart

Microprocessor technology has revolutionized the business community by placing tremendous computing power in the hands of the end-user for a very inexpensive price tag. The range of applications covers process control, to office automation, to personal computing capabilities. With the influx of this new technology, which these systems have to offer, also comes some unique operational and control considerations. But before we address these items, let us lay a foundation of common terms to be used throughout this presentation. Due to the rapid advances in microprocessor technology, where a new generation of computers is announced every two or three years, it becomes difficult to define a microprocessor system and have it valid for an extended period of time! Therefore, for this presentation, we will be dealing with a subset of microprocessors called Personal Computers or PC&apos;s. At the heart of a PC is a Central Processing Unit or CPU. The CPU performs the actual program and command execution. The programs dealing with driving the various peripheral equipment is referred to as the Operating System (for example: DOS : Disk Operating System, CP/M - Control Program/Microcomputers, etc.). The CPU is normally housed in an enclosure which contains power regulators, peripheral equipment interfacing &apos;cards&apos;, and expansion &apos;slots&apos; to enlarge the capabilities of the PC system.

Jan 1, 1989

By Ruschitzka C

The productivity and economic success of a German hard coal mine is attributed to the high productivity of a small number of operation points; however high rates of production are associated with increased gas emission at the working sites. Therefore modem high technology is required in order to reach the planned production rate, since high methane concentrations often cause unplanned breakdowns in operation. The optimised simulation of gas emission is a fundamental planning tool for mine design as well as for determining the potential of a coal deposit and has increased in significance over the last years. Methane-INFO enables the three-dimensional, graphical simulation of a working site taking account of different aspects such as the mine design, ventilation, production rate, geology, seam quality, gas exhaustion, etc. The following paper gives a short overview over the benefits of the discussed system.

Jan 1, 1995

By Øystein Sture, Kurt Aasly, Ben Snook, Sigurd A. Sørum

INTRODUCTION Efficient exploration methodologies for base metal deposits have huge benefits for future deep sea mining endeavours, and underwater hyperspectral imaging (UHI) has been variably demonstrated to have applications in the identification and characterisation of mineralisation on the seafloor for both nodules and seafloor massive sulphides (SMS) (Dumke et al., 2018 and 2017 respectively). Due to growing resource requirements (Singer, 2017), SMS deposits are considered to be increasingly significant sources of copper and zinc, as well as silver and gold. This style of mineralisation is currently occurring at active hydrothermal vents (black and white smokers) but now-inactive sites also have the potential to be large mineral deposits. As such, the development of novel methodologies to detect both on-going and extinct mineralisations are of high importance. Geological setting During the MarMine cruise (Ludvigsen et al., 2016), non-mineralised host rock, low grade ore and high grade ore grab samples (Snook et al., 2018) was collected by ROV from the Loki’s Castle deposit (Pedersen et al., 2010), located on the Mohn’s/Knipovich junction on the ultra-slow spreading Arctic Mid-Ocean Ridge (AMOR), at a depth of approximately 2300 m. This material has been characterised as part of the MarMine project (e.g. Snook et al., 2017), and, by imaging compositionally constrained material, the measured hyperspectral responses can be used to generate a library for identification of deposits on the ocean floor. UHI technology Remote sensing with hyperspectral and multispectral technologies has seen wide use in prospecting for ores and hydrocarbons on land (Van der Meer et al., 2012). Iron oxides and sulphides have low blue reflectance and high red reflectance in the visible spectrum. The ratio between these two pairs has been used in exploration for terrestrial deposits of hydrothermal origin (Sabins, 1999). This discrimination typically also includes wavelengths exceeding the visible spectrum (1.5µm – 2.5µm). These wavelengths are typically not utilised underwater because infrared wavelengths and higher are rapidly attenuated in water. However, discrimination based on the full shape of the spectral response in the visible light (350nm – 800nm) may still be possible (Bolin and Moon, 2003). Resolving the endmembers from the spectral responses requires prior knowledge about the optical properties of the materials, i.e. their reflectance. These reflectances can be obtained in a controlled environment, where the spectra of the lamps, wavelength- dependent attenuation in water and scattering of light can be accounted for (Johnsen, 2013).

Jan 1, 2018

By P. L. M. Wong, N. W. Johnson

Surface analysis by X-Ray Photoelectron Spectroscopy (XPS) of samples taken from the galena flotation section of the Hilton Concentrator of Mount Isa Mines Limited are presented. Flotation rate and pulp chemical data taken during the sampling period are also presented and discussed. Surface analysis suggested that, under normal operating conditions, an overlayer of precipitated calcium sulfate existed at the surface of the sulfide minerals. In particular, there was a decrease in the surface concentration of calcium sulfate for the concentrate samples relative to that occurring on the tailing samples. This suggests that the flotation process was selective against minerals which have calcium sulfate predominating at the surface. Heterocoagulation of hydrophilic calcium sulfate on to the galena surface considerably reduced galena flotation rate. Methods to control calcium sulfate precipitation, which include sodium carbonate treatment of the pulp, are also discussed. Sur- face analysis results of samples taken from the Hilton Concentrator during sodium carbonate addition to the grinding circuit are also presented. This shows clear evidence for the removal of calcium sulfate from the mineral surfaces without concomitant surface precipitation of calcium carbonate. Reasons for the apparent dispersion of precipitated calcium carbonate are discussed. Galena flotation rate was increased by the addition of sodium carbonate apparently due to the removal of interfering calcium sulfate.

Jan 1, 1995

The discovery of copper and nickel sulphides in the Riwaka Complex in 1967 led to considerable exploration activity by a number of companies. Various exploration techniques used by these companies are summarised and discussed. Activity of these companies shows that mineralisation is mainly confined to the southern, ultramafic section of the Riwaka Complex where geological mapping recognised sixteen units within, or associated with the Riwaka Complex. Significant pyrrhotite, pentlandite chalcopyrite mineralisation is restricted to biotite feldspar pyroxenites and to clinopyroxenite units. Lesser and more erratically distributed pyrite chalcopyrite pyrrhotite mineralisation occurs in poikilitic pyroxene hornblendites, melanocratic gabbros, and in marginal diorite lenses. It is suggested that a linear belt of layered ultramafic and mafic rocks described in Fiordland by Williams (1974) may be a southern extension of the Riwaka Complex. The Riwaka Complex has been classified as belonging to the Picritic subtype, (Tholeiitic suite), of Naldrett and Cabri, (1976), and as such it is concluded that it exhibits substantial potential for the discovery of economic copper and nickel deposits. It is considered that the complex is a multiphase differentiated intrusion emplaced in a major tensional fracture zone that developed in a relatively stable tectonic environment, namely a succession of middle Paleozoic shallow water shelf sediments. Based on sparse available evidence it is suggested that the Riwaka Complex was intruded in the lower to middle Permian. It is further suggested that the tensional fracturing was initiated by the onset of subduction process which were responsible for the development of the Permian volcanic arcs and ophiolite belt in the north west Nelson area.

Jan 1, 1977

The Warraua and Mount Poole Inliers form part of a discontinuous series of basement complexes in the northwestern corner of New South Wales. The Inliers comprise mainly clastic sediments of low metamorphic grade (Wonominta Beds) and minor sills, dykes and intrusives, particularly within the Mount Poole lnJier. The Warratta rnlier has received attention due to the occurrence of auriferous quartz-veins where reef mining activities havetaken place.The deformational history of the Warratta and Mount Poole Inljers is characterised by a continuous subhorizontally WSW-ENE directed compression. Deformation was associated with the development of NNW-trending and steeply west-dipping major faults, which bound or biscct the inliers. Chevron folds and a penetrative axial planar cleavage characterise the deformational architecture and document crustal shorterung of at least 40 per cent. In zones adjacent to the major faults and within pelitic and semi-pelitic uruts, a multiple deformational evolution becomes apparent, comprising two events (D1 and D2). Deformational structures considered significant in this study were the result of D1. Tight, northeast-vergent fold patterns FI&apos; and associated axjal plane cleavage SI&apos; and reverse dip-slip movements at major faults indicate early northeast-directed thrusting during D1. This was followed by dextral strike-slip deformation displayed by tight, recumbent folds, en-echelon fold patterns (F2&apos;), a northeast trending crenulation cleavage (52&apos;), and two sets of second order faults, the latter showing high angular relationship to the major faults. A final stage of the deformational history (D2) is represented by WSW-ENE trending kink folds (F2).Auriferous quartz veins, predominantly occurring within pelitic and semi-pelitic units, were generated syntectorucally during the early deformational event (D1) in the course of commencing development of cleavage (S2&apos;). Vein textures point towards vein formation by repeated hydrauJjc fracturing and fracture healing (crack-seal process), and by simple accretionary vein growth. Folded pelite-dominated horizons, considered as low permeability units, are suggested preferential sites where migrating metamorphic Ouids pooled and were trapped, causing high fluid pressure.Hydraulic fracturing and vein precipitation was controlled by lithology and structural constraints such as cleavage.K-Ar dates of approximately 440 Ma (Benambran Orogeny) marking the peak of metamorphism, and coinciding with the development of cleavage S1&apos;, also indicate the time of auriferous quartz-vein formation. A period of deformation of at least 30 Ma is proposed for the development of cleavage S1&apos;, as constrained by K-Ar dating and the intrusion of a syntectonic granitoid, the Tibooburra Granodiorite.

Jan 1, 1992

By Drummond Earley III

The hydrology of in situ leach mining operations is being studied by the U.S. Bureau of Mines using a variety of techniques, and the Bureau has made significant advances in tracking and modeling the flow of leach solutions in rock formations. However, the influence that leach solution composition has on the hydrology of these systems is poorly understood, and geochemically-controlled changes in the hydrologic characteristic of ore deposits during in situ leach mining of porphyry-hosted, copper oxide ores have not been previously studied. The Cyprus Casa Grande in situ leach mining operation mines fracture-hosted and disseminated copper oxides (predominantly chrysocolla) hosted by granodiorite porphyry using a pattern of underground wells. The injection solution consists of sulfuric acid raffinate from a solvent extraction-electrowinning plant. Chemical analysis of representative injection and recovery solutions reveals that gangue cation concentrations in these solutions are high, and geochemical modeling shows that the solutions are saturated or nearly saturated with respect to gypsum, jarosite, and various amorphous oxides. Precipitation of these solids is evoked by calcium-exchange reactions, rising pH, and perhaps locally rising redox potential, as the leach solution reacts with the ore minerals, host rocks, and the atmosphere. Mass and volume balance calculations show that approximately 25 cm of precipitates are formed per gram of copper recovered at Cyprus Casa Grande. The results of geochemical modeling agree with petrologic examination of pre-and post-leach core samples from the leached horizon. Moreover, hydrochemical modeling and hydrologic field data suggests that chemical precipitation causes significant decreases in porosity and permeability during in situ leach mining of porphyry-hosted, copper oxide ore.

Jan 1, 1992

Three separate and unconfined aquifers occur in the Hilton area, named relative to position in relation to ore horizons: Footwall Aquifer in the east; Ore-Zone Aquifer within the ore-bearing Urquhart Shales; and the Hangingwall Aquifer in the west.It is the on-going strategy it Hilton to drain the Ore-Zone Aquifer which occupies structurally- and sulphide-controlled leached zones in the steeply west dipping strata. The aquifer affects considerable ore reserves to 480 m below the surface. Dewatering began in 1976, and is essentially completed to 4 level (240 m below surface). Dewatering efforts are now based on 8 level (480 m below surface).

Jan 1, 1993

By ZhiLong ZHAO, Lin Lin, Zhancheng Guo, Jingtao GAO, Huiqing Tang

Grain sticking often occurs in the fluidized bed reduction of f ine iron ore, which is closely related to the precipitation morphology of metallic iron on the surface of ore particles. In this work, simulating the gas-solid reduction process of iron ore, in situ observations were carried out to investigate effects of doping mineral oxides on the precipitation morphology evolution of metallic iron during reduction of iron oxides with CO. Results indicate that the precipitation morphology of metallic iron is related to the quantity of doped mineral oxides. The minimum mole fraction of doped oxide ( xyOA N ) that can inhibit the growth of iron whiskers is related to its cation radius ( Ax r ), extranuclear electronic layers ( Ax n ) and valence electrons ( Ax q ). Their relation can be expressed as:

Jan 1, 2016

By Joseph A. DeCarlo

According to the annual survey of beehive-coke plants by the Bureau of Mines, United States Department of the Interior, there were 61 plants with 9,549 ovens in the United States on December 31, 1956, This publication in¬cludes only those for which an annual report was filed with the Bureau of Mines. Not all plants listed were active, however, as nearly one-third of those canvassed were idle all year. A compilation of the returns showed that 44 plants with 6,920 ovens were active part or all year and 17 plants with 2,629 ovens were idle throughout the year. The capacity of beehive ovens has fluctuated between 6 and 14 million tons during the past decade. At the end of 1956, the annual coke capacity of beehive ovens on which reports were received amounted to 5.8 million tons. As noted in table 2, however, not all of this capacity was in operating condition, as 2,093 ovens with a capacity of 1.2 million tons were not operable on [ember] 31, 1956.

Jan 1, 1958

By Ted C. Briggs

Equations for the elastic pressure distortion of the volumes of a Burnett compressibility apparatus are developed and presented in this report for volumes under internal and external applied pressures. An experimental method for the determination of the external pressure distortion coefficients is presented. Young?s modulus and the internal-pressure distortion coefficients are computed from the experimentally determined external-pressure distortion coefficients. The temperature dependence of the pressure distortion coefficients and of Young&apos;s modulus is evaluated for the temperature range 0° to 80° C.

Jan 1, 1968

By Erwin L. Zodrow

"For 25 chemical elements in electrostatically precipitated fly ash (Lingan coal-fired power station), concentration changes are studied as a function of increasing proportions of fines (ash particle diameter less than 45 micrometres). Elements that are involved when concentrations increase as the proportions of fines increase are likely to escape into the atmosphere. These are Th, U, As, S, P, Sb, Na, Ag, Zn, Pb, Ni, Ba, Sc, AI, Mo (and Bi, Ge, Ga, F and Li), i.e., more or less highly volatilized elements. Of the less volatilized metals such as Fe, Ca, Cu, Ti, K, Co, Mn (and lanthanides), certain portions presumably also escape as stack emissions. Diadochy and spinel formation in bottom slag is presented as an emission-reducing agent for certain metals.IntroductionThe Lingan coal-fired power generation plant, owned and operated by the Nova Scotia Power Corporation, produces annually about 140,000 metric tons of ash (the residual mineral content after burning coal). The tonnage is based on a 15 per cent average ash content of Cape Breton coal.For purposes of this report, samples of the hard, fused slag (bottom slag) that is accumulated at bottoms of boilers, and electrostatically precipitated fly ash (ep ash), were collected and investigated. Bottom slag is a minor component of the produced ashes.The ashes were surveyed and the presence of over 75 major, minor and trace elements is reported. From this survey, 25 elements were selected to establish elemental enrichment/depletion trends when the proportions of the less than 45 micrometre <45µm) fractions in ep ashes increase. The results are significant in that, taking the case of elemental enrichment, the elements involved are likely to escape into the atmosphere, i.e, highly volatilized elements. Depletion trends for elements are presumably associated with less volatilized elements during coal-firing. Quantification of the emission of atmospheric pollutants is not considered part of this work. ""Igneous"" minerals generated during coal combustion include spinels (found mainly in the bottom slag), quartz, glass and mullite."

Jan 1, 1982