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By Zhang Hanbo, Niu Liping, Zhang Zhiqi, He Jicheng, Dou Zhihe

"Rutile, ilmenite and Al-Ca complex reducer were used to prepare high titanium ferrous alloy by enhanced reduction-SHS method. The effects of the complex reducer compositions and slag types on the enhanced reduction-SHS process were investigated. The high titanium ferrous alloys were characterized by XRD and SEM. The results indicate that the high titanium ferrous alloys consist mainly of TiFe2, AlTi3 and Al2O3. The oxide inclusions exist resulting in directly the high oxygen content and micro-structural defects in the alloys. The titanium and oxygen contents decrease, but the aluminum content in the alloy increases while the mass ratio of calcium in the Al-Ca complex reducers increases. When the mass ratio of Al/Ca in the Al-Ca complex reducer is 6:1, titanium, oxygen and aluminum contents are 63.75%, 3.01% and 10.72% respectively. When the mass ratio of Al/Ca is 5:1 titanium content is 55.00% nearly and aluminum content is higher than 14.00%, but oxygen content is lower than 2.0%.1. IntroductionThe high titanium ferroalloys with 65%~75% titanium have the advantages of low melting point and high titanium content. They are widely used in special steel refining, while they are also a kind of very important quality orientation alloys in the rage of aviation and aerospace. At present, the methods of preparing high titanium ferroalloy include vacuum remelting and thermit reduction. The alloys prepared by the vacuum remelting method have good qualities and low oxygen content, so it is widely used in Russia, Western Europe and other developed countries. In China, there are abundant rutile resources, but waste titanium is lack, therefore, the preparation method is the thermit reduction. But there are many quality defects in the high ferrotitanium alloy, including high oxygen content, unstable quality and so on. In order to improve the qualities of the high titanium ferroalloy, especially to reduce oxygen content, the domestic and overseas have done a lot of further researches. For example, Sichuan E-mei ferroalloy plant and Beijing Nonferrous Metal Research Institute have prepared high titanium ferrous with 73.77% titanium with natural rutile, but the oxygen content is high. Through controlling the quality of raw material, they obtained the better qualities, but the oxygen content is still very high. South Africa Mintek company have prepared high titanium ferrous alloy with low nitrate by plasma heating under the isolation air conditions, but they couldn’t also remove effectively oxygen in the alloy. The oxygen exists in the form of Al2O3 and titanium protoxide. So it can be speculated that except TiO2 not being fully reduced, the no-sufficient alloy-slag separation is the direct reason resulting in high oxygen and poor microstructure. In view of present technical difficulties during preparing high titanium ferroalloy by thermit reduction, this paper proposed a new method of preparing high titanium ferrous with low oxygen by enhanced reduction-SHS with Al-Ca complex reducer. Ca in Al-Ca complex reducer has stronger reductive ability, it can effectively strengthen the reductive degree of TiO2. The slagging agent CaO CaF2 and MgO can effectively reduce the viscosity of Al2O3 slag to improve its liquidities to strengthen alloy-slag separation effects so that to remove inclusions and oxygen. In this paper, effects of slagging agent type on the reduction and the qualities of high-titanium ferroalloy were studied."

Jan 1, 2012

By John Birkinbine

Secretary's Note.—In printing this paper in the present volume, the figures given in the pamphlet edition have been brought more nearly up to date, the product of 1899 being in many instances inserted. Iron-Ore Resources. In a paper presented to the Institute in 1897,* I discussed the iron-resources of the United States as then developed, calling attention to some principal sources upon which other countries depended. The following statement will give a general idea of the amounts, as compiled from the latest official records, of ores won, and metal produced, in the nations which are important contributors to the world's output. Unfortunately these are not all contemporaneous, since in some countries the statistics do not appear until after one or more years. The statement covers not only pig-iron and iron-ore, but also manganese-ore —the manganese mined being principally used in the production of spiegeleisen or ferro-manganese, and these alloys being generally included in the pig-iron output. Table I, which epitomizes the present situation, shows respectively the countries and the quantities of iron-ore and man-

Jan 1, 1901

By Herman L. Bauer

The Robinson Mining District near Ely, Nevada, is one of the major porphyry copper districts in the world. Within the district is an east-trending zone of altered porphyry, metamorphosed sedimentary rocks, and sulphide mineralization surrounded by Paleozoic limestone, dolomite, shale and sandstone, Tertiary volcanics, and Quaternary alluvium. Six major disseminated ore deposits have been exploited in this eight-mile zone. About 20% of the district production has come from disseminated ore in metamorphosed sedimentary rocks found adjacent to altered quartz-monzonite porphyry. The following brief statements summarize the inter-relationship of porphyry, alteration, metamorphism, and mineralization: 1. Disseminated copper ore does not occur in unaltered porphyry or in unmetamorphosed sedimentary rocks 2. Sedimentary rocks have been only weakly metamorphosed where intruded, by unaltered porphyry. 3. Intensely metamorphosed sedimentary rocks are found only adjacent to, altered porphyry. 4. Many hydrothermal minerals are common to both altered porphyry and adjacent metamorphosed sediments. 5. Disseminated ore is found in altered porphyry and adjacent meta¬morphosed sedimentary rocks. 6. In general, there is a direct correlation between grade of ore in porphyry and copper content in the adjacent rocks. 7. Chemical changes in the altered porphyry facies and metamorphosed rock facies appear to be related:

Jan 1, 1963

By Maria Salazar-Villalpando, Todd H. Gardner

"Efficient utilization of CO2 can help to decrease global warming. Methane reforming using carbon dioxide has been of interest for many years, but recently that interest has experienced a rapid increase for both environmental and commercial reasons. The use of CO2 provides a source of clean oxygen, which eliminates the need for costly oxygen separation plants. The product of dry reforming is useful syn-gas, which can be used to generate electrical power in a SOFC or in the production of synthetic fuels (hydrocarbons and alcohols). Hexaaluminate catalysts prepared at NETL may represent a product that can be utilized for the conversion of CO2 to syn-gas. In this work, transition metals dispersed in barium hexaaluminate have shown to be promising new catalysts for dry methane reforming. In this investigation, a series of BaNixAl12-yO19-d catalysts with varying Ni content were prepared by co-precipitation followed by calcination at 1400°C. CO2 reduction by dry methane reforming was carried out to determine catalyst performance as a function of temperature and carbon formation was also quantified after the reforming tests. Results of catalysts characterization, dispersion and surface area, were correlated to catalytic performance.IntroductionEfficient utilization of CO2 can help to decrease global warming. Methane reforming using carbon dioxide has been of interest for many years, but recently that interest has experienced a rapid increase for both environmental and commercial reasons. The use of CO2 provides a source of clean oxygen, which eliminates the need for costly oxygen separation plants. The product of dry reforming is useful syn-gas, which can be used to generate electrical power in a SOFC or in the production of synthetic fuels (hydrocarbons and alcohols). The dry reforming reaction has been known for a long time. Recent publications have reported studies over several catalysts. For example, the CO2 reforming of CH4 over mesoporous nanocrystalline zirconium powders (ZrO2–3%M2Ox; M: Ce, La and K) at 700ºC have shown methane conversion up to 60% (1). Similarly, the effect of Ni content (1–12 wt%) on the surface and catalytic behavior of bimetallic PtNi catalysts supported on ZSM-5 for reforming of methane with CO2 has been studied and report shows a maximum conversion of 16% and catalyst deactivation was observed during the first hour of time on stream (2). In another report, (3) Ni/a-Al2O3 catalyst was tested for syn-gas generation at 750ºC. The maximum methane conversion was 25%."

Jan 1, 2008

By Paul Summers, Kevin Richardson, Willem (Billy) Villet, Paul J. Sabatini, Edward C. Clukey

"Between 2008 and 2009, more than 6,000, 23-m long deep mixing method (DMM) elements were constructed to support 124 concrete mats comprising the foundations for the process trains for an LNG facility. The Owner requested first-of-its-kind analyses and assessments to confirm the quality and reliability of the DMM foundation. This paper provides information on these assessments and the procedures used to ultimately conclude that a fit-for-purpose foundation system was constructed.During early phases of construction, several DMM test cores revealed nodules of unmixed clay in upper core samples. A comprehensive review of available DMM core information was undertaken. It was concluded that the amount of coring being conducted as part of the contractor’s QA/QC program should be increased to achieve a foundation system with the required level of reliability.Three-dimensional finite element analyses were completed considering various distributions of defects in the DMM elements and the effects of potential downdrag on DMM elements. Calculated mat settlements and mat stresses were compared to cases without defects in the DMM elements. Various distributions of loaded and unloaded mat areas and number and position (both in the subsurface and laterally) of defects were considered. Four (of the 124) mats were identified as potentially “at-risk”. The settlement performance of these mats is currently being monitored and, to date, performance has been acceptable.IntroductionThe foundation support system for the process train at a major LNG facility comprises more than 6,000, 23-m long DMM elements. The general subsurface stratigraphy at the project site comprises (from the ground surface): (i) up to 8 m of fill sand initially placed underwater building to a stable construction platform; (ii) up to 12 m of soft organic clay (Unit II clay); and (iii) clayey sand and sand layers becoming progressively denser with depth (Unit III sands). Each DMM element comprised two secant 1.5-m diameter DMM columns. DMM elements were typically arranged as cells enclosing one, two, or three DMM elements."

Jan 1, 2017

By Jiang Su, Alan Bloodworth

"Composite sprayed concrete lining (SCL), consisting of two layers of permanent sprayed concrete separated by a layer of spray-applied waterproofing membrane, represents the latest development in SCL tunneling, but presents several challenges to designers. This paper aims to address the following issues: (1) how to simulate composite action, (2) behavior of a composite SCL tunnel, and (3) how to utilize composite action to achieve lining thickness efficiency. It firstly sets out the background to the composite SCL concept, and then presents a strategy for numerical investigation. The main part of the paper is the presentation and discussion of the simulation results, focusing on the lining deformation, load sharing and the safety margin of both linings. Interface stresses are also examined. It is found that significant secondary lining thickness reduction may be achieved by utilizing composite action. Challenges for the design of composite SCL tunnels are briefly discussed at the end. INTRODUCTION Sprayed concrete lined (SCL) tunnelling has seen rapid development over the last twenty years in the UK (Su 2013). One of these developments has been the replacement of traditional sheet membrane and cast in situ secondary lining with innovative spray applied waterproofing membrane and sprayed secondary lining system, which has been adopted in recent major projects, such as Crossrail (Pickett 2013), and brings many benefits to the construction (Dimmock et al. 2013). The combination of sprayed primary lining, spray applied waterproofing membrane and sprayed secondary lining is perceived to provide a structurally efficient lining system that outperforms the traditional lining system, which consists of sacrificial primary lining, sheet waterproofing membrane and cast in situ secondary lining. The claimed benefits in structural performance arises from the composite action between the sprayed primary and secondary linings via the spray applied waterproofing membrane, which produces a much stiffer cross-section and therefore a more efficient use of materials. Early investigations on the design of composite SCL tunnels were carried out without (1) definite and reliable long-term interface parameters, (2) a verified numerical modelling technique, or (3) consideration of different stress histories between primary and secondary linings (Thomas and Pickett 2011, Marcher et al. 2011). This paper reports the findings from a numerical parametric study on a typical composite SCL tunnel with varied secondary lining thickness. The results show that the true benefit of composite lining arises from the optimisation of the lining thickness (stiffness) ratio between the primary and secondary linings to achieve secondary lining safety and thickness efficiency at the same time."

Jan 1, 2016

By John A. Church

IN May, 1878, I had the honor of presenting to the Institute, at the Chattanooga meeting, some observations upon the heat of the Comstock Lode, and since then the subject has attracted some attention and criticism, in the course of which, I have observed errors of apprehension which I beg leave to correct now. Mr. John Arthur Phillips discussed it before the Geological Society, his paper being printed in the Quarterly Journal for August, 1879.* His criticism is based upon that part of my paper in which I quote a number of analyses of the mine waters, to illustrate the fact that the heat does not come from the oxidation of pyrite. I pointed out that these waters contain only an insignificant proportion of sulphuric acid, and not enough to account for even one per cent. Of * A Contribution to the History of Mineral Veins. By J. Arthur Phillips, Esq., F.G.S. Quarterly Journal of the Geological Society for August, 1879.

Jan 1, 1880

By Pengfei Wang, Guorui Feng

With increase of cover depth, dynamic incidents, such as large gateroad convergences and coal bursts, are frequently encountered when mining deep longwall panels. It would be more adverse due to large inclination of the coal bed. Because of the shearer and armored face conveyor (AFC) sliding downhill, toppling of shields, disconnection of AFC to the stage loader are related to it. Tangshan coal mine is a typical deep, inclined coal mine situated in the east of China. The split-level longwall panel layout is being adopted for mitigating problems above, where tailgate entries of longwall panels are driven below gob edge and along the floor, while headgate entries are driven along the roof. Wire mesh and steel sets have been used empirically for support for tailgates for about a decade, which reduces the tunneling speed. In view of this fact, the paper serves to investigate the proper adjustment of the tailgate locations and to analyze the resulting stress and yield conditions according to support strategy. First, field measurements and observations were carried out. Stress data distributed within surrounding rock mass were obtained, especially within the roof since the roof consists of only a coal sheet with a thickness of 2–4 m. Roof pressure of the tailgate represents the pressure at the gob edge since it is below the gob edge. The convergence data were also collected. Numerical modelling using FLAC3D™ was conducted and validated by side abutment stress data. The double-yield constitutive model was used to simulate the gob. The finalized tailgate layout and design were determined through comparison of three scenarios. The research in this paper can help engineers choose the proper tailgate layout and support strategies for coal mines that are going to adopt a split-level longwall panel layout for mining deep, inclined longwall panels.

Jan 1, 2018

By Zay, Jeffries

THE effect of thoria (ThO2) on grain growth in tungsten was discussed in some detail in a paper presented before this Institute by one, of the authors in 1918.1 In that paper it " was assumed that the, thoria was present in the tungsten entirely as a mechanical mixture. There was no indication in the experiments described that even a trace of the thoria was in solid solution in the tungsten. Langmuir,2 however, observed that thoriated-tungsten filaments under certain conditions showed electron emissions many thousand times greater than unthoriated tungsten at the same temperature. He concluded from his studies that a slight amount of the thoria had dissociated on heating the filament to a temperature near 220°. C. At this temperature and higher, part of the thorium diffuses to the surface of the filament where it evaporates at. a much faster rate relatively, than the tungsten, and also at a rate, nearly as fast as it is brought to the surface by diffusion: If the temperature is lowered to say 1800°,. C., diffusion of the thorium atoms to the surface is more rapid than evaporation, sown adsorbed film of thorium atoms is produced on the surface of the tungsten filament. The electron emission is governed by the outside layer of atoms so the emission from such a filament might be expected to approxi¬mate that of a thorium filament at the same temperature. PRESENCE OF METALLIC THORIUM IN THORIATED TUNGSTEN If the filament containing the adsorbed film of thorium. is heated to a sufficiently high temperature, the thorium atoms evaporate: rapidly and the electron emission becomes more nearly that of tungsten. On cooling again to 1800° C., or thereabouts, the emission 'builds up gradually to a maximum. The filament containing the adsorbed layer of thorium atoms is said to be "activated." By studying the rates of activation under different conditions of prior thermal treatment and at different temperatures, Langmuir was able to arrive at an estimate of the

Jan 1, 1927

By LJ Aspinall, Paulo Sérgio Soares Santiago

Monitorar adequadamente a qualidade da água em sistemas de resfriamento é fundamental para assegurar um bom condicionamento de seus indicadores chave de desempenho: a corrosão, a incrustação, a formação de depósitos e a atividade microbiológica, de forma que as unidades operacionais possam atingir suas metas com relação aos seus respectivos índices chaves de performance do processo industrial. Enquanto a confiabilidade deste monitoramento em antever problemas assume, então, elevada importância, os métodos utilizados até o presente na indústria não têm efetivamente fornecido resultados realísticos pela ausência de troca térmica nos dispositivos usados. A Knew Value desenvolveu e patenteou uma nova tecnologia, o Sentinel, que permite aplicar métodos inovadores de monitoramento on-line, permitindo realizar simulações em condições críticas de velocidade de escoamento e temperatura de película e atingindo excelência em monitoramento de indicadores chaves de desempenho do tratamento químico aplicado em sistemas de resfriamento. O objetivo deste trabalho é apresentar esta tecnologia e casos históricos de desempenho.

Aug 1, 2019

By T. Shi, Q. Yuan, S. P. Vanka, B. G. Thomas

"The quality of continuous cast steel is greatly affected by fluid flow in the mold region, especially involving transient phenomena. Mathematical models are being applied to investigate many different aspects of these phenomena, but their accuracy must be validated before they can be applied with confidence. As part of a long-term effort to develop and apply comprehensive models of the continuous casting process, this work evaluates the relative accuracy of models of three different fluid flow phenomena in continuous casting through comparison with measurements.Firstly, transient flow simulations of velocities in the mold region are compared with digital particle image velocimetry (PIV) measurements in a single phase water model. Large-eddy simulations (LES) are found to reasonably match the flow measurements, including transient flow variations, except at long time scales, which could not be modeled owing to the excessive computation costs. The standard K-e model produced very good agreement with time-averaged velocities for relatively little computation time, although it is inaccurate at predicting the transient variations. Secondly, particle trajectory calculations are compared with water model measurements to study the distribution and flotation removal of inclusion particles. The LES model was able to match the measurements both qualitatively and quantitatively. Thirdly, steady, multi phase flow computations are compared with flow patterns observed in both a water model and an operating steel caster with argon gas injection. For the same conditions, the water model and steel caster produced very different flow behavior. The computational model was able to match the measured flow patterns in both cases.This work suggests that computational flow modeling has the potential to match real processes as well or better than water models, especially when complex related phenomena such as particle motion and multiphase flow are involved. Much work is still needed to further improve the models and to apply them in parametric studies."

Jan 1, 2001

Exxaro installed their first ultra fines treatment plant at Leeuwpan Coal mine. The plant is now fully operational and results already show that the plant has great potential. The plant was designed and installed by DRA. Several challenges were faced during the installation due to the space constraints in the Leeuwpan plant. Efficiency tests were conducted on both modules after commissioning and showed very promising results. A lower ash product with a higher yield can be produced with the fine coal dense medium cyclones compared to the spirals previously employed.

Jan 1, 2010

By E. D. Musin, S. S. Gudkov, A. V. Epiforov, S. V. Balikov

The standard technology for processing of gold-bearing sulfide raw material has many problems associated with the use of cyanide as a gold lixiviant. Therefore, many tests to find alternative gold recovery methods are being undertaken. This paper describes some technological solutions, which can become alternatives to cyanide technology in the future. Pressure oxidation (POX) of refractory gold-bearing sulfide concentrates from five different Russian gold deposits were investigated. Concentrate 1 was gold-copper concentrate. Concentrate 2 was gold-pyrite concentrate. Concentrates 3-5 were pyrite-arsenopyrite double refractory concentrates. The POX tests were at temperatures of 110, 200 and 220 °C and oxygen pressures of 1.5, 2.4 and 3.0 MPa were carried out. Gold lixiviants, such as chloride, thiosulfate, sulfite and thiocyanate were tested. The recovery of gold from sulfide gold-bearing concentrates by non-cyanide methods was 97- 99%, and from double refractory concentrates, 86-93%. The tested reagents are less toxic than cyanide, and their use will reduce of the cost of gold production. These methods make it possible to recover gold in acidic media, and eliminate the washing operation and POX slurry neutralisation. In addition, precious metals recovery from POX cakes using lead reduction smelting was investigated. It was shown that the “POX-pyrometallurgical” technology for double refractory concentrates processing could be used with recoveries of gold and silver of 97 and 96%, respectively. Keywords: Recovery of gold, refractory sulfide gold-bearing concentrates, double refractory concentrates, pressure oxidation, non-cyanide lixiviants of gold, chloride autoclave leaching, thiosulfate leaching, thiocyanate leaching, sulfite leaching, reduction smelting, POX-pyrometallurgical technology

Jan 1, 2020

By E. V. Konopleva, H. J. McQueen

"The isothermal bainite transformation kinetics of low- and medium-carbon alloy steels after hot deformation and the rmocycling treatment (TC) has been studied by the magneto - metric method. Deformation was produced by rolling at 800°C-1000°C. TC included three cycles of rapid (30°C/s) electro-heating up to 900°C-1000°C followed by quenching.Hot deformation retards bainite transformation in the lower part of bainite range (<400°C) and accelerates it in the upper part (>400°C). The effect is greater for higher strain and lower deformation temperature. Deformation also diminishes the overall bainite fraction below 400°C and increases the completeness of reaction above 400°C.Thermocycling provides more uniform ultrafine austenite grains with average size of 3 µm -4 µm compared to 12 µm -14 µm after conventional heating. The transformation rate after TC was almost the same as after conventional heating in low-carbon steel but was faster in medium-carbon with no change in the completeness of reaction. The degree of acceleration increased with rise of transformation temperature.There are a number of factors which are responsible for a change in bainite transformation kinetics in austenite deformed at high temperatures or subjected to TC. One of the most important factors is the refinement of structure, another one is structural and chemical inhomogenity of austenite due to deformation or to rapid heating. To estimate the contribution of these factors, ?-transformation was studied after different austenitizing conditions (low-temperature heating at 850°C- 950°C; high-temperature heating at 1100°C; step treatment – austenitizing at 1100°C, then cooling to 950°C-850°C). The results obtained make it possible to conclude that the structural and chemical inhomogeneity of austenite activate the bainite reaction while the grain refinement retards it. Intensity of the effect produced by each factor depends strongly on the steel composition."

Jan 1, 1997

By Diego Moisés Maciel Vieira

Aços resistentes à abrasão possuem alta dureza, sendo largamente utilizados em aplicações nas quais o componente é submetido a situações em que é exigida alta resistência mecânica e resistência ao desgaste. Podem ser empregados para fabricação de implementos rodoviários, implementos agrícolas e na indústria de mineração. O presente trabalho visa analisar a influência da espessura dos corpos de prova de Charpy-V na energia de impacto absorvido em amostras de aço resistente à abrasão da série 450HB. Os corpos de prova foram usinados com as dimensões padronizadas pela norma ASTM E23 [1]. Os resultados obtidos demonstram uma redução nos valores de tenacidade ao impacto com a redução da espessura, explicitando a importância do método da energia relativa absorvida para análise dos resultados dos ensaios que abordam variação de espessura.

Aug 16, 2017

By A. V. Corlett

THE use of the diamond-drill hole as a means of breaking clown ore and waste is not new. Years ago, the method was adopted in mines in northern Ontario and in the western United States to reach out to bad pillars, or to remnants of ore left on walls, the winning of which by any other method might be dangerous or too expensive. The practice is still in vogue and has generally proved a success. Of the known mineral deposits in Canada and elsewhere, many are of very low grade. Some are marginal and not even worthy of being classed as &apos;ore&apos; until some means is found and proved of exploiting them economically. Other conditions being favourable, if a mining method could be found that would give a large &apos;bulk break&apos; with a sufficiently low cost of development and a low cast of mining per ton, mineral deposits of this latter type might be brought into the classification of ore. We know that any block-craving system whereby the ore may be undercut and allowed to crush and cave will give a very high breakage and low costs. In some cases, however, the physical characteristics of the ore do not lend themselves to this method. In such ore-bodies, the alternative system of &apos;bulk-breaking&apos; might be aided by long diamond-drill blast holes. We could obtain this &apos;bulk breaking&apos; by the use of long diamond-drill holes in conjunction with a sub-level system using extremely thick benches, or possibly by the adaption of modified open-pit methods to underground mining. ln fact, if conditions are favourable, the idea would be simply ta open up a slot or free face and break into it on a larger scale with longer holes. The use of deeper benches-that is, using each level as a sub-level and thereby eliminating much development footage, slashing, setting up, and mucking time-would naturally be expected to lead to cheaper mining.

Jan 1, 1940

By L. H. Adami

The heats of formation of anhydrous cadmium sulfate, cobalt sulfate, copper sulfate, nickel sulfate, and zinc sulfate were determined by hydrochloric acid solution calorimetry. The values at 298.15° K for formation from the metal, rhombic sulfur, and oxygen gas follow (cal/mole): CdS04J -222.0 ± 0.3; CoS04, -212.0 ± 0.4; CuS04) -183.4 ± 0.6; NiS04, -208.1 ± 0.2; and ZnS04, -233.1 ± 0.2. Corresponding heats of decomposition to form the metal oxide, sulfur dioxide, and oxygen were derived from these results; heats of decomposition to form the metal oxide and sulfur trioxide were also derived.

Jan 1, 1965

By John Gordon

Rare earth elements (REE) required in modern technological products are found in shale rocks above and below coal seams. Often during the process of mining coal, shale rock adjacent to the seam inadvertently is removed then diverted to landfill sites. Ecologically sound and potentially economic methods of extracting the REEs from these landfills are proposed. Methods include utilizing geomemembrane barrier beneath the landfill site, ion exchanging with moderate pH, slightly acidic, sodium chloride solutions. Sodium hydroxide is utilized to precipitate the REE-hydroxides subsequently converted to REE-chlorides with suitable amount of hydrochloric acid. All acid and base streams are co-produced with efficient membrane/electrolysis technology. Concentrated-REE chlorides are transported tocentralized solventextraction facilities for isolation and purification. Solvent extraction processes also employ the methodology of using co-produced acid/base streams. This paper details minimization of environmental impacts and maximizing economics to produce valuable REEs while increasing the economics of coal mining.

Mar 1, 2018

By Maria I. De Rosa

The U.S. Bureau of Mines performed experiments to determine the hydrogen cyanide (HCN) concentrations and smoke particle characteristics during the combustion of flexible polyurethane foams and other nitrogen-containing materials, for the development of a test parameter. The experiments were conducted in an approximately 2O-L furnace at set furnace temperatures of 250° and 1,000° C for a 14-min duration, with an airflow through the furnace of 10 L/min. The variables studied as a function of time were the gaseous and aerosol HCN concentrations, the smoke particles average diameter (dg) and particle concentration (no), and the product of the smoke particle diameter and concentration (dgno). Carbon monoxide, carbon dioxide, and oxygen concentrations, sample mass weight loss, and furnace temperatures were also studied; analyses of nitrogen and cyanate content of the material were carried out. Results show that dgno correlates directly with the HCN concentrations, which depend on the nitrogen and cyanate contents of the material.

Jan 1, 2010

By Lingyun Zou, Xinghai Lei, Tiezheng Li, Yifei Song, Nan Wang, Yang Li

The stability of key strata is of utmost importance in ensuring safe and effective coal seam mining operations. To minimize disturbance impacts on these strata and ensure their stability, it is crucial to assess the degree of disturbance caused by mining activities. This study proposes the evaluation index “disturbance degree of key stratum (KSDD)” and establishes a quantitative KSDD criterion to measure the degree of disturbance on key strata. To facilitate the assessment process, an intelligent calculation system for KSDD is developed. The classification criteria are derived by combining the measured three-zone heights from multiple mines. The reliability and accuracy of the KSDD quantitative criterion are validated using field measurement data. Furthermore, the KSDD quantitative criterion is applied to the Meihuajing mining area No. 23, and the distribution characteristics of KSDD are analyzed. The findings of this study can serve as a valuable reference for reducing disturbance and enhancing the stability of key strata during subsequent mining operations. Overall, this work contributes to the field of ground control in coal seam mining by providing a comprehensive approach to assess and mitigate the disturbance caused by mining activities on key strata.

Mar 8, 2024