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By C. W. JEFFERS

At its annual meeting on March 5, 1928, in Washington, D. C., the Joseph A. Holmes Safety Association gave to the Ford Collieries Co., Curtisville, Pa., a certificate of honor for "having worked 922,628 underground man-shifts from August 14, 1920, to December 31, 1926, producing 5,755,669 short tons of coal without a fatality." This remarkable record certainly deserved recognition. It developed that this company's freedom from fatalities continued until October 2, 1929, hence the full period during which no underground fatalities occurred was from August 14, 1920, to October 2, 1929, or 9 years, 1 month, and 18 days, the total tonnage being over 7,700,000. Table 1, shows the complete safety record of the Ford Collieries Co. since 1920 as given by the officials of the company. The first item in Table 1 shows a remarkable performance. This company since 1920 has mined 15 times more coal per fatal accident than the average pro- duction per fatal accident for the State of Pennsylvania in 1928 (255,257 tons). Excluding the two fatalities (one in 1922 and one in 1929) the severity rate for the same period has been 1.259 per thousand hours worked, a record of which the company may justly be proud. However, including the fatal accidents the rate is 2.407. This compares favorably with an average of 12.4 in 1928 for 66 mines in the National Safety Competition. The Ford Collieries Co. operates three mines located in the vicinity of Curtisville, Allegheny County, Pa. One of these mines, Benjamin No. 1, is idle at the present time. The officials are: A. R. Pollock, general manager, Curtisville, Pa., and C. W. Pollock, assistant general manager in charge of safety and operation.

Sep 1, 1930

By Christian Overhagen

In bar and wire rod mills, rolling procedures featuring three- and four-roll technologies are state-of-the-art to produce high-quality long products. While a rolling model for the three-roll process including an equivalent pass method was already presented by the author, pass design methods are dealt with in the current work. The geometry of the rolled product and roll grooves are described mathematically using functional contours, allowing geometric-numerical methods to be used for manipulation and deformation simulation of the rolled product. For a given pass, the output section is constructed using these methods. Roll force, torque and rolling power are calculated using the mathematical rolling model presented before. Interstand tensions are discussed as influencing parameters on the force, torque and power demands, as well as on the section shape. A mathematical model for the influence of interstand tensions on lateral spread is incorporated in the model. To complete the pass design model, elastic mill stand feedback is considered in terms of a fixed elastic modulus for each rolling stand, the elastic feedback and therefore cross-sectional variation due to elastic mill spring being calculated iteratively from the roll force by application of the Gagemeter equation. The interaction of section height and width faults due to elastic mill spring and spread variations is analyzed in detail and the consequences for the roll pass design are shown.

Oct 1, 2019

By H von Blottnitz, J L. Broadhurst

Eco-efficiency has been proposed by the World Business Council on Sustainable Development as an environmental performance indicator framework that contributes to sustainability by assisting corporate decision makers improve the environmental performance of their operations and processes, while also extracting additional economic value. Given that the recent engagement of the minerals industry with sustainability has highlighted the need for requisite tools and methodologies, it is therefore of interest to assess whether eco-efficiency indicators can drive sustainability performance improvement during process design within the minerals industry. Previous work indicates that the choice of sustainability performance indicators to be used for decision making needs to be governed by the decision context; ie the performance indicators need to be fit-for-purpose. Here, the strengths and weaknesses of eco-efficiency indicators are analysed using case studies. First, a more rigorous definition of eco-efficiency indicators for the minerals industry is proposed based on indicators currently offered in the literature. Two case studies are then selected to reflect typical decision situations encountered within minerals process design. For each case study, eco-efficiency indicators are computed and are compared to more traditional graphical representations of the economic and environmental performance of process design alternatives considered. The sensitivity of these indicators to various process design parameters is also investigated. Results confirm that the meaningful application of eco-efficiency indicators is strongly dependent on the decision context in which the process data is generated. Results also show that eco-efficiency indicators can be related to technical process design parameters to allow for richer communication of performance information for various decision trade-offs; however, in some cases, graphical approaches that provide more insights into the environmental-financial trade-offs should be preferred. The research thus contributes to guiding the selection of the appropriate tools for more environmentally sustainable design of minerals beneficiation processes.

Jan 1, 2009

By Ma Keyi, Yang Xianwan, Zhu Xiaoyun, Guo Zhongcheng, Zheng Yanping

"The oxidation of the Multifunctional Electrodeposited RE-Ni-WP- SiC Composites at high temperature is investigated. The results show that during high temperature oxidation the relationship between the mass change of pure Ni , Ni-W-P, Ni-W-P-SiC or RE-Ni-W-P-SiC coating and the oxidation time follows a mixed curve, i.e. it is approximately a linear relationship when the oxidation time is less than 60 mins while it is a power function relationship when the oxidation time is over 60 mins. The order for the oxidation rate of the four coatings is Ni> Ni-W-P> Ni-WP- SiC>RE-Ni-W-P-SiC. The mass change of Ni-W-P, Ni-W-PSiC or RE-Ni-W-P-SiC coating increases exponentially with a rise of oxidation temperature. The high temperature-oxidation resistance of RE-Ni-W-P-SiC composite coating is 3-4 times that ofNi-W-P alloy coating. The cross section morphologies and Xray diffraction patterns indicate that the high temperature oxidation resistance of RE-Ni-W-P-SiC composite coating is better than any other coatings.1. IntroductionWith the rapid development of modem industries the products in engineering industry are continually challenged by the requirements of long-term and stable working at higher temperature, pressure, speed and under adverse conditions. Consequently, the surface properties of the products, such as the resistance to oxidation at high temperature, the resistance to wear and the resistance to corrosion, should be improved continually."

Jan 1, 2000

By O. J. Malacarne

The use of a series of thickeners for-washing of the slime fraction of a leached ore is not uncommon in the uranium industry; however, few ore processing mills have used a thickener circuit for washing leached total ore. The, common, practice is to wash the sand fraction in classifiers and, the slime fraction only in thickeners. At the Uravan mill of Union Carbide Nuclear, Company, a total ore' acid leach is employed to extract uranium values from sandstone ores. These leached ores are then washed at a nominal rate of from 1,000 to 1,300 tons per day in a series of washing thickeners. A typical screen. analysis of the ore being washed in these thickeners, is 25 percent -200 mesh, 3 percent +35 mesh and about, one' percent +l4 mesh., The amount of slimes (-200 mesh) will vary from 20 to 30 percent s the mill receives ore from 150 different mines The washing liquor is acidic, from a pH of about 2 in the first thickener to 0.6 pH in the last thickener and of course ally acid duty equipment must be used. The Uravan mill of Union Carbide Nuclear Company is located in Montrose County, Colorado and is physically located on a canyon wall along the San Miguel river. The thickeners referred to in this, paper are located on top of the mesa above the canyon. For purposes of identification, these thickeners are numbered 1 through 8 from south to north.

Jan 1, 1962

By Neusa Alonso-Falleiros, Aristeu Braz da Veiga, Marcelo B. Mourão, Adriano Pescarmona, Antonio Alberto Froes Schettino, Cyro Takano, Carlos A. S. Giraldo

"The Caron process of nickel extraction from lateritic ores produces a fair amount of an inert residue, the so-called “black sludge”, that is disposed in a dam according to the required environmental regulations. On the other hand, it represents an opportunity to resource recovery. This work presents the characterization of the residue, discusses some possible ways to recover the valuables, and presents experimental results of pyrometallurgical runs aimed at recover nickel as an iron-nickel alloy. It has been shown that the residue contains large amounts of silicon, iron, aluminum and magnesium, in the form of oxides and silicates, and small quantities of nickel, cooper and cobalt, besides several other elements. It has also been shown that gravimetric or magnetic concentration methods do not present promising results. On the other hand, it is possible to obtain iron-nickel alloys by high-temperature carbothermic reduction of the “black sludge”.IntroductionThe Caron process consists of a combined pyro-hydrometallurgical process to extract nickel from high iron limonitic lateritic ores, recovering also the cobalt present in the ore. The main steps are the reduction roasting of the ore, aiming at a selective reduction of nickel and cobalt to the metallic state, avoiding as much as possible iron reduction, followed by leaching with ammonium carbonate solution and the recovery of metal from the pregnant liquor [1,2]. As a result, significant amount of tailings are generated, that are disposed in appropriate dams. This residue, called “black sludge”, contains significant proportion of silica and iron, and also small amounts of nickel, cobalt, cooper and some other elements. Due to diminishing deposits of nickel ore, high metal prices and a significant amount of “black sludge “ available after several years of operation of the plant, Votorantim Metais, who operates a facility in Brazil that uses the Caron process, decided to explore the possibility of recover nickel from the residue. This paper presents the characterization of the residue, and the results of experimental work aiming recovery of nickel from it."

Jan 1, 2008

By William Gleason

"More than 6,300 people converged on the Colorado Convention Center for the 2017 SME Annual Conference and Expo and 119th National Western Mining Conference in Denver, CO on Feb. 19-22. Many of them crammed in to hear Douglas Silver deliver the keynote address to the conference.Silver is a portfolio manager for Orion Mine Finance, a private-equity fund focused on providing funding to advanced-stage base and precious metal projects and is one of the most respected voices in the field of mineral economics. Prior to joining Orion, he served as chief executive officer and chairman of International Royalty Corp., a global mineral royalty company, which he founded in 2003 and sold in 2011.Those who were hoping that Silver would deliver at least a bit of optimism during his 90-minute presentation got what they came for from the talk titled, “When are commodity prices going to rebound?”It marked the second time Silver has presented the keynote address to SME, the first was in 2008 and was delivered during the height of mining’s super cycle (ME, June 2008). In his 2017 address, Silver looked back on the previous 10 years and the massive contraction of the global economy that resulted from the great recession that began near the end of 2008.It has been a challenging time for the mining industry. About US$1.4 trillion was lost in the global mining stocks from 2011 to Jan. 6, 2016. Major mining companies exceeded $60 billion in write downs between 2012 and 2013 and investors lost confidence in the sector, putting the global mining industry into a bear market that has taken mining equities to historic lows.However, that was then and this is now.Using numerous examples, including rising commodity prices, a steady decline in the U.S. unemployment rate, increases in discretionary income and the Dow Jones Industrial Average, which topped the 20,000 mark for the first time ever in February, Silver theorized the current down cycle is near its end and the demand for metals and other commodities will see a sharp increase by 2025. He also noted that investors are beginning to rotate back into mining equities."

Apr 1, 2017

By R. L. Peyton

Risk analysis is used extensively in many engineering applications. Although its use in the field of dam safety has been limited in practice, it has received considerable attention in recent years in the dam safety literature. Thus far, it has been shown that risk analysis in the evaluation of existing dams has the potential for providing a more rational basis for decision- making because of its focus on the direct issues--likelihood of failure, likelihood of loss of life, and risk cost of damages. It provides for a logical balance between the risk a dam imposes and the degree to which rehabilitation is required, compared to traditional evaluations based on somewhat arbitrarily chosen design events applied to large classes of dams. Dam owners could benefit by optimizing the cost of remedial measures. Downstream landowners could benefit by minimizing the likelihood of flood damages. However, it is also clear that significant technical and policy issues remain to be resolved before risk analysis in dam safety is accepted and routinely implemented in engineering practice. An obvious and important potential application of risk analysis is its use by the state regulatory agency as an in-house evaluation tool, or even as part of regulatory policy, in the implementation of its state dam safety program. Adoption of such a policy would have an important impact on the mining industry. .Although no state dam safety programs are known by the writers to have officially incorporated risk analysis into their regulations, there appears to be considerable interest in the concept. In recent surveys 47 states agreed that the development and promotion of a risk assessment methodology for state dam safety programs should be encouraged (Tschantz, 1983; Tschantz, 1984). The issue has also received important attention within the Association of State Dam Safety Officials (1986). One state-Illinois-proposed regulations during 1986 to allow risk analysis to justify lower spillway requirements for existing dams (Illinois Department of Transportation, 1986). At the Federal level, the National Research Council has found risk analysis especially appropriate for assessing dam safety at high-hazard dams (National Research Council, 19851, the Bureau of Reclamation has published guidelines for incorporating risk analysis into their dam safety grogram (U.S. Department of the Interior, 1986), and the Federal Emergency Management Agency has recently sponsored workshops and supported research related to risk analysis in dam safety (Federal Emergency Management Agency, 1985a ; Federal Emergency Management Agency, 1985b; - - McCann, et. al., 1985a, 1985b).

Jan 1, 1986

By David Wright, Jerome Chamfray, Anthony Harding, Brian Boye

Conway’s Law states that unless we intentionally design automation tools around what we need, we will simply replicate our existing processes. While we may achieve some savings this way, there is an opportunity for greater benefits if we re-imagine the way we, as an industry, perform design. This paper examines current technology and shows how even small departures from merely encoding what we currently do could reap significant benefits. From these examples a framework is developed for a new and innovative approach tvo automation that will allow us to design more quickly, to a higher quality, and communicate outcomes more effectively.

Dec 1, 2022

By W. I. Enderlin, P. O. Jackson, J. A. Glissmeyer, K. B. Olsen

A reliable estimate of radon emissions to the environment from underground uranium mines was obtained through measurements of radon in ventilation air at 24 mines and from estimates of radon release from other mine sources. The total production of U308 from the mines sampled represents about 63% of the total U.S. production from underground mines (1978 statistics). Wide variation in the radon emission rate per unit of production was found from mine to mine. Using the total radon emitted and U308 produced by all mines sampled, an average of 26.7 Ci of radon was emitted per ton of U309 produced. The investigation includes a brief study of the sources of variation of the emission rates. A statistically significant relationship was found between the measured radon release rate and the cumulative ore production at several mines.

Jan 1, 1981

By Mostafa Maazouz, Jeff Blackwood, Mauricio Gordillo, Sang Hoon Lee, Micah Ledoux, Liang Zhang

To meet rising requirements for the low-damage ultra-fine process with the focused ion beam (FIB) in the materials science and semiconductor industry, the advanced ion column and corresponding advanced applications as a solution are developed and demonstrated. Novel high-speed high kV milling, low kV cleaning and imaging capabilities have enabled the creation of impeccable ultra-thin structures such as TEM samples and nanometer scale structures. Minimizing Ga+ induced sample damage is achieved through the optimized final cleaning at 500 eV ion landing energy with the new ion optics, which utilizes close control of the ion dose, beam incidence angle, spot size, pattern algorithm and imaging performance. Newly introduced process solutions achieve the improved process throughput. Initial demonstration is performed on the latest 14 and 10 nm scale FinFET device. Validation of the thinnest <0.8 nm thick ion damage layer on the <7 nm thick lamella structure was confirmed through TEM analysis.

Mar 1, 2017

By Joerg Hammerschmidt, Marcus Runkel, Steffen Haus

Given the limited number of new plant construction, focus is turning to the optimization of existing metallurgical roasting plants. To meet the goals of high process efficiency with limited capital expenditure, plant owners are looking for new strategies, including digitization and expert support. As a supplier for numerous roasting, gas cleaning and sulfuric acid plants, Outotec has intensified its effort in recent years to develop solutions to accommodate increasing customer need. This article presents a short review on how Outotec is applying advanced control tools for the fluidized bed industry. Focus will be given on how to transfer the existing technology (used in selected Zinc roasting plants for over a year now) to copper roasting. Outotec has developed the Pretium Roaster Optimizer, a system based on heat and mass-balanced simulation models. Direct experience with this technology will be shared and will highlight similarities to the Partial and Sulfate Copper roasting processes. Pretium detects equipment and plant bottlenecks and provides consistency in process development. The Pretium program combines 24/7 advanced online digitalization tools, along with expert personal support when required. INTRODUCTION Fluidized bed reactors have been used for commercial-scale zinc and copper roasting since the 1950s. While the principles of roasting remain unchanged, over time, the technology has advanced to improve process control of roasting plants. In the past, environmental and safety standards were the driving forces for improvement of equipment and plant design. Today, the emphasis is on plant efficiency and optimization. Another change has come in process control philosophy. While plant control and operation have traditionally been the responsibility of owner/operators, they have now shifted to include both integrated digital tools and specific know-how from engineering companies. This can be seen from the earliest design stages through commissioning and into production, as evidenced by zinc roasting plants in Mexico, Brazil and Turkey.

Jan 1, 2019

By John J. Sammarco

The functional safety of programmable electronic (PE) mining systems is an international issue and concern. From 1995 to 2001, 11 PE-related mining incidents in the U.S. were reported by the Mine Safety and Health Administration (MSHA); 71 PE-related mining incidents were reported in Australia. MSHA does not have regulations for formal evaluations of the functional safety of PE mining systems. Hence, the National Institute for Occupational Safety and Health (NIOSH), in partnership with MSHA and the industry, generated the NIOSH safety framework for functional safety of PE mining systems. An overview of the NIOSH framework is given; the key framework elements, the safety life cycle and safety integrity levels are detailed. The safety framework approach has impacted the national and Australian mining industries by enabling the industries to advance from an ad-hoc approach to a formalized and systematic functional safety process. In retrospect, valuable lessons were learned for addressing functional safety and for changing industry perspectives and practices. These lessons continue to benefit mining and are applicable to other industries as well.

By J. W. Devon

The coal mining industry is divided into two distinct economic segments based on Coal Supply Agreements. Coal supply agreements generally fall into two categories, spot or long-term, with the selected contract term being driven by the buyer&apos;s market expectations, security of supply considerations, fuel tonnage and quality requirements, and economics. Short-term or spot coal purchases are generally market driven and are highly competitive in today&apos;s marketplace. Long-term contracts, particularly those involving captive mines and mine-mouth power plants, are commonly driven by considerations other than economics. These other considerations, such as Reserve Conservation and Resource Recovery, Security of Supply, and Maintenance of Levelized Costs may increase the cost of coal, often needlessly and without benefit to the buyer or seller. The basic economic principles which guide the market driven metals industry and generally guide the spot coal sector of the coal industry should apply equally well to the long-term coal supply contract. The artificial constraints imposed as a result of regulated rates of return should be re-examined and in most cases, abandoned. There are many methods of surface and underground coal mining being used today such as, open-pit, contour, mountaintop, and area mining for surface mineable reserves; conventional, standard continuous and super-section continuous miners, and longwalls for deep reserves; and highwall miners, thin seam miners and augers in between. This discussion is primarily directed to surface mining, however the same principles of least cost mining on a Net Present Value basis must be considered in all cases.

Jan 1, 1994

By M. Bueno, T. Chavez Matus, M. S. Powell, S. Michaux, S. Luukkanen

Comminution tests are an essential element in the design of ore beneficiation plants. Many methods have been developed to assess the breakage characteristics of rocks to generate parameters for modelling. However, most of the existing methods are laborious, expensive and require large samples. Consequently, test work has been traditionally conducted with a few representative reference samples. On the other hand, geometallurgical modelling programs require an extensive amount of test work to allow understanding the variability of ore properties within the deposit and establish spatial geometallurgical domains that show the differential responses to mineral processing. Therefore, comminution tests for geometallurgy need to be more efficient in terms of time, cost and sample size. This paper introduces a new testing device (Geopyörä) which is capable of measuring forces and energy applied to rock particles during the breakage process. The new testing method uses smaller samples and can be up to 50 times faster than other commonly used tests in the industry. This paper presents the concept prototype and the preliminary test work results, which have been benchmarked against some of the industry standard tests, such as the JK Drop Weight Test (JKDWT), the SMC Test® and the Bond ball mill test. Keywords: Geometallurgy, comminution, ore breakage characterization, variability.

Jan 1, 2020

By R Strand, L Reading, G Keir

A major challenge in managing coal seam gas (CSG) water is predicting how much water will be produced as the industry develops. Klohn Crippen Berger Ltd (KCB) was commissioned by the Queensland Department of Natural Resources and Mines (DNRM) to develop a tool to forecast where, when and how much CSG water will be produced in the Surat and Southern Bowen Basins under various industry expansion scenarios.The water production tool (WPT) uses the Theis equation, a non-equilibrium groundwater flow equation that accounts for the effect of pumping time on well yield in confined aquifers, to predict water production volumes. Where multiple pumping wells are in close proximity, the required pumping rates for coal seam depressurisation are reduced. Therefore, pumping effects are projected spatially to assess interference effects between wells. Water production is then upscaled to the projected scale of the CSG industry within the Surat and Southern Bowen Basins.Two modifications were made to address the dual phase nature of CSG extraction (a transmissivity reduction factor) and the impact of weathering at the eastern margin of the Surat Basin (a ænear edge effectÆ factor). These factors modify relevant hydrogeological parameters in a consistent and defensible manner to more closely match observed water production.The WPT was verified by comparing results to equivalent Theis equation calculations and to type curves provided by CSG proponents. Calibration was achieved by varying the spatial distribution and intensity of the near edge effect factor in conjunction with a chi-squared analysis of residuals.The tool, which is now being maintained and further developed by the Centre for Water in the Minerals Industry (CWiMI), was built to balance numerical complexity against relative flexibility and simulation speed. The result is a tool that can produce statistically relevant results of prescribed scenarios to plan water handling and treatment requirements in discrete zones of operation.CITATION:Strand, R, Reading, L and Keir, G, 2013. Water production simulation tool for coal seam gas operations in Bowen and Surat basins, in Proceedings Water in Mining 2013 , pp 311-320 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 26, 2013

By William Kent

In a paper by Mr. Frank Firmstone, published in vol. iv, of the Transactions of the Institute, on " Comparison of Results from Open-topped and Closed-topped Furnaces," the regularity of the average grade of pig iron procluced by the furnace under different conditions is expressed by means of a curve or diagram. The object of this note is to show that the graphic method, or that of representing variations by plotted curves or diagrams, is capable of a much more extended application to blast-furnace records, making a valuable auxiliary to the " furnace hook," and that by it the practical metallurgist may obtain at a glance information concerning the variations of the furnace during long periods, which could be found in the furnace book only after a tedious search. Plate XII is a graphic record of an anthracite blast furnace for one month. The table on page 554 gives the figures obtained from the furnace book, together with a record of temperature of the atmosphere, barometric pressure, and moisture in the air, which was obtained from a meteorological observatory not far from the furnace. In the records of a furnace, two of the variable qualities are final results, viz., the quantity of pig iron produced, and its grade; all the other variables are antecedent causes which produce the final results. Of these variable callses which contribute to the quantity of product and its grade, some are partially under the control of the furnace manager, others depend upon the state of the atmosphere, and still others are accidental. Of the first class are the character of the materials charged, and their relative proportions, their mechanical conditions, as wetor dry, large or small pieces, etc., the revolutions of the engine, the heat and pressure of blast, and the distribution of the charge. Of the second class are the number of pounds of air blown into the furnace for each stroke of the engine, the amount of moisture in the air, and the condition of the chimney draughts. These vary largely with the season of the year. Of the third class is the leaking of a tuyere or a temporary stoppage. To keep a record of this kind for a whole year, it is only necessary to procure a sheet of common profile or cross section paper, about 38 inches long and 8 or 10 inches wide, with cross lines ruled about 0.1 of an inch apart. The vertical lines, or those in direction of the

Jan 1, 1879

By I. Iwasaki

In recent years the rapid depletion of high-grade iron ores and the demand by blast furnace operators for increasingly low-silica ores have stimulated interest in flotation studies of low-grade iron ores, such as wash-ore tailings and oxidized taconites. Four processes have been reported for the flotation separation of these iron ores--anionic and cationic collection of the iron oxides, cationic collection of siliceous gangue, and anionic collection of activated siliceous gangue (5).5/ The effectiveness of any one method, however, depends largely on the mineralogical composition and on the physical structure of the sample; hence, a comprehensive study of the floatability of the individual minerals occurring in these materials is essential. A review of the literature shows that the floatability of hematite and magnetite has been frequently investigated, whereas very little corresponding information is available for goethite, or for its more earthy form, limonite, both of which are abundant in the Mesabi and Cuyuna ores (19). The purpose of this investigation was to formulate general information on the floatability of goethite. Vacuum flotation, contact angle measurement, and simplified flotation tests using a modified Hallimond tube were used. The experimental results were correlated with the electrokinetic properties of goethite as determined by streaming potential measurement. The results were used to interpret the batch flotation tests made on an artificial mixture of quartz and goethite.

Jan 1, 1960

By AIME AIME

THE revised program for the San Francisco meeting, with assignment of the various papers to the several sessions is now available and is printed below : MONDAY, OCT. 7 . General Meeting, 11-12 A.M. Chairmen: Frederick W. Bradley and E. A. Hersam. Opening of the session by the Chairman of the San Francisco Section-E. A. Heraam. Address of welcome by the President of the Institute- Frederick W. Bradley. Address: The Mining problems of the West--Charles W. Merrill.

Jan 1, 1929

By C. J. Osborn

The temperature dependence of the free energies of formation of metallurgically important oxides, sulphides, chlorides, carbonates and sulphates is presented graphically, whereby the task of deriving practical metallurgical information is greatly simplified. The diagrams have been revised according to the latest available thermodynamic data. WHILE it is true that much careful investiga-tional work remains to be done, there are already available in the literature sufficient thermo-dynamic data to enable the metallurgist to predict with reasonable confidence the equilibrium conditions to be expected in most important, and potentially important, metallurgical reactions. In this connection, the careful, critical compilations of K. K. Kelley and his collaborators in numerous U. S. Bureau of Mines Bulletins are particularly valuable. However, the translation of reliable thermo-dynamic data into metallurgical language unfortunately involves lengthy manipulations of the cumbersome formulas which can be set up from heat of formation, entropy, and heat capacity data. Many years ago, Kelley20 predicted that thermo-dynamic calculations would be made in the future "with the aid of free energy, heat content, and entropy tables, rather than by means of the algebraic methods employed at present", and where such tables are available they greatly simplify the task of deriving practical metallurgical information. However, in addition to these tables, there are also available one or two reliable graphical presentations, particularly of free energy data, which may be used in the same way as the tables, but which have the added advantages that interpolation is never necessary, and that the behavior of different metals or compounds may be compared at a glance. Some years ago Professor Robert Lepsoe, Head of the Department of Metallurgy at Norways Institute of Technology (N.T.H.), began a compilation of curves showing the temperature dependence of the heat contents of the elements, and the heat contents and heats and free energies of formation of the common metallurgical compounds. With such a compilation, the thermal and free energy requirements of a reaction may be read from curves in a matter of seconds; and this statement applies not only to the formation of compounds from their elements, and to the reverse dissociation, but to any reaction involving substances whose thermodynamic properties are available. This follows from the fact that heats and free energies of formation are completely additive. For example, the free energy change associated with the chlorination of a metallic oxide at any temperature, T, is given by the free energy of formation of the chloride at temperature T minus that of the oxide also at T; both of these quantities may be read directly from curves of the type suggested above. Since this early, unpublished work of Lepsoe, both Ellingham7 and Richardson and Jeffes46 have

Jan 1, 1951