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By Mine F. J, Woods P. H

Waste waters from mine sites may be screened for all constituents of significance as a first step in establishing water quality criteria for protection of aquatic ecosystems. Inductively-coupled plasma mass spectrometry (ICP-MS) offers the capability to screen water samples and digest solutions for virtually all elements in the periodic table. This technique is therefore able to identify elements whose concentrations are elevated in waste waters and may be rarely present in background surface or ground waters. Such elements may be present in waters at only a few ¦g/L. ICP-MS has sufficient sensitivity to detect sub-¦g/L or even ng/L levels of many elements. Waste waters from most mining activities in the Northern Territory have been examined by ICP-MS. The concentration data provide the basis of a contaminant data base. The data can show specific tracers in the ore or mineral itself, subsequently found in waste water. An example is the presence of rhenium in uranium ore. Such trace elements may be present in soluble or insoluble chemical forms and are more useful as indicators when soluble and exemplifying conservative chemical behaviour. The approach described, based on ICP-MS screening of mine site waste waters, together with general physico-chemical variables, provides the most comprehensive means yet available of selecting variables for monitoring programs and ensures that key elements and/or their chemical species are not excluded from monitoring programs.

Jan 1, 1994

By Michael E. Stout

M.A. Industries, Inc. has developed and is now offering on a commercially available basis, complete systems to recover and recycle lead from spent SLI batteries. The system begins with the breaking and separation of the component parts of the batteries and subsequent treatment of the effluent water produced by this operation. The recyclable materials recovered from this process are metallic lead, lead paste and polypropylene. The lead paste is introduced into a process to convert it from a lead sulfate to a lead carbonate. The process also regenerates the salt solutions into reusable carbonate. The lead carbonate is then leached into an acid bath where it is later recovered by a proprietary electrolytic process. The metallic lead is recovered in a short rotary furnace producing metal for further refining and alloying. The polypropylene is further washed and then introduced to a reclaim extruder along with the proper modifiers and additives. The resulting resin can then be sold on the open market to injection molding processors. This complete system greatly reduces the amount of waste to be disposed of and completely complies with all applicable EPA guidelines.

Jan 1, 1993

By PHILIP A. ZANG

The rapidly increasing use of motor vehicles in the United States has introduced an entirely new problem in the proper ventilation oftunnels , subways , and other confined spaces through which such machines must pass . This problem was brought to the attention of the Bureau of Mines by the New York and New Jersey State Bridge and Tunnel Commissions with reference to the ventilation of the proposed vehicular tunnel under the Hudson River . This tunnel , consisting of twin tubes 29 feet in diameter and 8500 feet long between entrance and exit , presented an unprecedented problem in ventilation both on account of its length and on account of the traffic density , which is expected to reach a maximum of 1900 vehicles per hour . An exhaustive study by the tunnel engineers of all available data on the amount and composition of automobile exhaust gas disclosed very little information on the percentage of carbon monoxide in motor exhaust gas from the average run of automobiles and trucks under actual operating conditions on the road. It was well known that carburetor adjustment and other operating factors changed the percentage of the poisonous constituent , carbon monoxide , from practically 0 to 12 or 13 per cent ; but no safe estimate could be made of the most probable figure without further investigation .

Mar 1, 1921

By C. T. Holland

Coal mining has been an important industry in the Appalachian area for many years. This is particularly true in the northern part of the area, namely, in Pennsylvania, West Virginia, and Ohio. Also, in the south a great deal of mining activity has been carried on in Alabama, Kentucky, and southwest Virginia. Some of the by-products of this activity has been the production of mineralized water from the mines in copious quantitites. The southern Appalachians have been somewhat more fortunate in that the water there has had a considerable amount of alkalinity in it, which has to a large extent eliminated some of the more undesirable aspects of mine drainage. Northern Appalachia, including central and western Pennsylvania, the Monongahela basin in West Virginia, and the Appalachian area in eastern Ohio have not been so fortunate in that coals in those areas and the top and bottom rock have, in many cases, shown considerable quantities of pyrite, and the water does not carry the carbonates found farther south.

Jan 1, 1969

By Nieves Iglesias

The removal of the refractoriness of a gold bearing pyrite- arsenopyrite ore is studied. Flotation concentrates were prepared and leached with a dilute acidic ferric sulfate solution. The elemental sulfur film which forms on arsenopyrite in the oxidation process is not responsible for the low rate of the arsenic dissolution observed. A positive effect on the leaching rate is observed when Ag' is added. This pretreatment eliminates the refractory nature of concentrates.

Jan 1, 1993

By A. G. McGregor

IN THE Southwest a number of large steel chimneys discharge the gases from the copper smelting furnaces. Some of these chimneys show no deterioration after twenty years, others show serious deterioration after tour years service. A steel stack 20 ft. 7 ½ in. (6.3 m.) in diameter by 279 ft. (85 m.) high, Fig. 1, used for roaster gases only at the Calumet & Arizona Mining Co.'s plant at Douglas, Ariz., was lined to the top of the bell, 40 ft. (12 m.) from the base, with common brick placed on end, lime and cement mortar being used. Above the bell, the stack was lined with 4 by 4 by 8 in. (10 by 10 by 20 cm.) building tile, placed on end, making a lining 4 in. thick. The tiles were supported on angle-iron rings, riveted to the inside of the chimney shell about 15 ft. apart. The chimney was put into use in the latter part of 1913. Four years later, considerable of the tile lining had fallen out of place and mixed with the flue dust at the bottom of the chimney. About a year later, several . flattened and distorted sheets were noticed about 70 ft. below the top. An investigation showed that the thickness of these distorted sheets, which was originally ¼ in., had been reduced one half. One year later, or six years after the chimney went into use, several holes, a square foot and smaller in area, appeared near the flat spots mentioned. Soon afterwards, when the chimney was shut down for repairs, it was found that most of the tile lining for 125 ft. from the top had fallen out and that the steel shell was badly corroded; but where the lining remained in place the shell was undamaged. Many of the tile which had fallen out of place had become soft or flaky and crumbling, others were as hard as when placed. An analysis of the hard and soft tile is shown on p. 2. These tile were of a fireclay mixture, and were used instead of common brick on account of lower cost. The steel forming the upper 125 ft. (38 m.) was replaced, and a 4 ¼ -in. (11-cm.) lining of firebrick was laid from the bell to the top of the chimney. The brick were placed on end, wedges and keys being used. After each 8-in. course was set, keyed, and wedged tight, thin mortar -water, sodium silicate, and finely ground silica-was worked into the joints. The brick are supported on angle-iron rings, every 15 ft., in the same way as the tile.

Jan 1, 1921

By R. S. Dean, John Gross

"In a preliminary report made a year ago it was shown that certain minerals when subjected to heating with water under high pressure and temperature were shattered upon the sudden release of that pressure. The main feature in which the results of this method differ from those of conventional grinding is in the differential effect obtained. The more metallic minerals, and hence the valuable minerals, are shattered more readily than are the gangue minerals. In other words, explosive shattering is unique among possible methods for comminuting an ore in that it wastes the least energy on the useless part of the ore. Explosive shattering, therefore, offers possibilities as a means for reducing grinding costs, arid it is this potential advantage of the process that makes it worthy of further experimental study. The first part of this paper is devoted to a study of the mechanism of the process; the, second part reports results obtained in toots on a selected list of ores to exhibit some of the advantages of explosive shattering."

Feb 1, 1933

By Robert K. Koch

The Bureau of Mines investigated separating HF from HF-SiF4-H2O mixtures by passing the mixed gases through a sodium fluoride slurry in an airlift scrubber and forming a mixed precipitate of NaHF2 and Na2SiF6. The oven-dried precipitate was thermally dissociated in two stages. The first stage was carried out at 400° C and dissociated NaHF2 to NaF and HF. Condensation and analysis of the evolved HF proved it to be 97 to 99 weight-percent HF containing 0.79 to 0.99 weight-percent H2O and 10 to 93 ppm silicon. The second stage was carried out at 700° C and dissociated Na2SiF6 to NaF (for recycle) and SiF4. The quantity of HF recovered from gaseous HF-H2O-air mixtures decreased with increasing relative H2O concentrations. Air was beneficial when scrubbing extremely dilute wet HF gases. At HF partial pressures of 0.24 and 0.013 mm Hg in the scrubber entrance gases, HF partial pressures of 6.2 x 10-4 and 9 x 10-6 mm Hg were obtained, respectively, in the scrubber exit gases. Scrubber efficiencies were 99.7 and 99.3 percent.

Jan 1, 1966

By Leonhard Weixler, Alexander Blatt, Franz-Werner Gerressen

Diaphragm wall technique is usually used to construct structural elements in the ground, commonly used for retention systems, permanent foundation elements or deep ground-water barriers, named Cut-Off-Walls (COW). It can be anticipated that global urbanization and increasing demands on environmental considerations will need to be accommodated in underground space in the future. These trends show an increasing requirement for diaphragm walling in even more complex conditions, especially in inner-city applications with limited space. Therefore, there is the demand to minimize the size of equipment to accommodate such projects. Following this demand, a new trench cutter system, the so-called CUBE System, was recently developed. The complete trench cutter system has been fit into container size dimensions so that it can work in very limited space conditions. In addition, complex conditions in terms of space limitations require specifically adapted solutions for slurry, spoil, reinforcement and concrete handling and the related logistics to ensure smooth production. Due to the limited space requirements, the impact on the surrounding environment is limited. As the system is electric driven, an additional reduction of carbon footprint can be expected. First tests of the system have been carried out and the results will be shared. The paper will explain the construction process and the specific challenges and experiences made for these extreme conditions.

Oct 1, 2022

By Travis A. Davidsavor, Charles Dowding, David A. Provost, Yonggang Gou

This paper compares measured blast induced strains on operating, full scale, buried pipelines with three similar past studies. The recently performed study represents realistic and modern pipeline blasting techniques combined with modern data acquisition. The evaluation compares measured PPV and strain, as well as calculated stress, at equivalent scaled distances.

Feb 1, 2020

By W. P. Yant, R. R. Sayers

The rather sudden increase in the use of methanol as an antifreeze for automobile radiators has caused considerable comment , with some anxiety to persons interested in industrial and public health , regarding the possible health hazard in dispensing and using the product . In view of this , the chemical industry interested in the manufacture and marketing of methanol requested the Bureau of Mines to make an impartial and extensive investigation of the hazard involved . With the assistance of the industry this investigation is now in progress and will extend throughout the present winter . When these observations are finished a complete report will be made . At present , however , the acute interest in the problem and the many inquiries that have been received from manufacturers of methanol , garage owners , the automotive industry , public health officials , and private persons demands a brief statement relative to the reasons for the recent availability of methanol for antifreeze purposes , the plan of the bureau's investigation , and the trend of the results of the investigation obtained to date .

Dec 1, 1930

By AIME AIME

C. H. BENEDICT, chief metallurgist of the Calumet and Hecla Consolidated Copper Co., has pioneered for nearly half a century. Noted for his ammonia leaching process, lie has Iong been responsible for all Calumet and Hecla mill, concentrator, and reclaination plant flowsheets. His influence has spread far beyond his own organization. lie is dean of Lake Superior metallurgists and has contributed greatly toward raising his specialty-the country over-to an honored profession; not merely an honored profession but a profitable one for industry and the public. The leaching process which he developed in 1912 has, since 1915, produced for Calumet and Hecla 250,000 tons of copper from waste tailings at a cost per pound, in 1929, below five cents. It has yielded profits of $35,000,000. In the war just ended, this process proved the only one adaptable to the recovery of copper from gilding-metal¬clad steel strip, and Calumet and Hecla treated more than 50,000 tons of such scrap for the Government.

Jan 1, 1945

By D Teyhan, J Kirsch

Traditionally, most Australian iron ore mining operations have been surface-based. Processing plants were designed to handle dry ores. In recent years mining operations in the Pilbara have progressively moved below the water table exposing wet, sticky ores which have caused lost efficiency in screening operations as particles tend to agglomerate and adhere, blinding screening media. Miners and vibrating screen manufacturers have experimented with a shift from linear motion to elliptical motion screens. Elliptical motion conveys and lifts particles. Effective on flat deck (horizontal and inclined) or sloping decks it can be configured to provide a controlled transport rate, applying pressure in all directions to maximise screening efficiency. In practice, elliptical motion screens have proven to be effective in dislodging sticky particles from screening media, reducing blinding rates and improving screen efficiency. Moisture and clay content change during the life of a mine. These changes are sometimes the effect of seasonal rainfall, in other cases due to increased groundwater and clay content as mining operations go deeper. To compensate for such changes and optimise screen efficiency, changing the ‘shape’ of elliptical screen motion is required. This has traditionally required shutting down processing plants and making mechanical screen adjustments. Plant downtime is costly and machine adjustment has been a ‘trial and error’ practice. This paper will explore the results of a field trial that is currently underway in Brazil of a next generation elliptical motion screen design that allows operators to make changes to exciter rotational direction, speed and screen stroke angle, through electronic drive phase control. The machine’s electronic drive system synchronisation is enhanced for stability with a unique mechanical timing system. Operating at up to 6 g, screen adjustments can be made on the fly without stopping production. Early trial results are showing up to 50 per cent improvement in screen efficiency compared with traditional elliptical motion machines under certain feed conditions.

Nov 8, 2021

By B. W. Gandrud

This is the first report published by the Bureau of Mines on washability characteristics of coal from beds in Tennessee. It is based principally upon screen-sizing and float-and-sink tests of raw coal from a bed on the Cumberland Plateau. Stripping operations were undertaken recently on this bed by the Cumberland Collieries, Inc., near Chalybeate,Van Buren County, Tenn. The bed has not been definitely correlated, but it may be an extension of the Sewanee bed, which has been mined extensively in the Tracy City district to the south-vest and at points near Dunlap and Pikeville to the southeast and east. It was spoken of by officials of the Cumberland Collieries as the Sewanee bed at the time of sampling for this study. In a letter dated October 16, 1948, W. D. Hardeman, geologist of the Department of Conservation, Nashville, Tenn., states: "The stripping operations of the Cumberland Collieries near the old postoffice at Chalybeate are, I am fairly certain, in the upper part of the Whitwell shale, which carries the Sewanee coal. This coal may be a stray seam, but it probably can be correlated with the Sewanee coal, which is mined farther east. "There are no detailed geologic maps or reports covering the area, and this opinion is based on what was observed in visiting the strip mines in that general vicinity." The laboratory work upon which this report is based was done at the Southern Experiment Station of the Bureau of Mines, United States Department of the Interior, in cooperation with the University of Alabama and the Cumberland Collieries, Inc.

Jan 1, 1949

By E. L. Howard, R. S. Barney back

E. L. Howard (Chief Testing Engineer, Pacific Cement & Aggregates, Inc., San Francisco, Calif.) We have made concrete with all the materials mentioned by Mr. Barneyback, including sawdust. He has highlighted the principal problems and effects found when these light materials are used as concrete aggregate. We can only agree with the inter-relationship he has emphasized between grading, specific gravity and unit weight. Uniformity in these characteristics helps to assure good concrete. Mr. Barneyback says the design of lightweight concrete mixtures "is a complete mystery to most engineers". He is wholly right in his evaluation of our ability generally to put together a concrete using lightweight aggregate. A study of the references he has appended will yield little comfort in the matter of proportioning. Much remains to be done in this area of concrete. We believe Mr. Barneyback has treated the subject, though briefly, in an excellent manner.

Jan 1, 1965

By A Tsang, D La Rosa, L Julian, W Hunt, R Pratama

Mineral extraction is facing the twin challenges of finite resources and increasing environmental and economic costs. Society’s growth is matched by an increase in demand for the earth’s resources. It is incumbent on us as contemporary mining professionals to promote and facilitate ethical and efficient practices. Technological developments have and will continue to allow a decrease in viable cut-off grades, creating new economic opportunities from deposits that were previously uneconomic. Mining low-grade deposits however, even with perfect recoveries, will have a significant environmental cost for the metal won. The greatest opportunity to increase metal with the least environmental cost is to increase the metal yield from existing mines. The determination of mining polygons is a critical juncture where rock is typically subjected to the binary grading of either ore or waste. This is undertaken using a number of factors, such as the mining equipment being used and the recovery in the processing plant. Traditionally, mining polygons were generated on the in situ grade control model. This ignores the complex differential blast dynamics that occur during blasting. Two opportunities exist to improve metal yields: optimise the blast design to achieve the post-blast muck pile that will support the greatest outcome; and generate optimised polygons on the post-blast muck pile. A data set from a Canadian Gold deposit is used to demonstrate the potential benefit of iterative blast movement modelling and grade control polygon optimisation on metal yield. The impact of blasting on the total recoverable metal is presented, highlighting blast design as a critical process in the mining value chain.

Sep 1, 2024

By J. H. Tylczak

The Bureau of Mines studied the effect of alloy additions on abrasive wear of low-alloy steels. A dry-sand, rubber-wheel abrasion test appa-ratus using ASTM G65-Sl procedure B was used for the abrasive wear tests. Eighty-six material heat-treatment combinations were abrasion tested. Results of these tests were analyzed statistically using regression analysis to see if additions of Cr, Mn, Mo, Ni, Si, AI, Cu, and S were significant in affecting the abrasive wear rate of low-alloy steels. Regression analysis was also used to confirm hardness and C affect on the abrasive wear rate of these steels. It was found that for all the steels taken as a group, increased amounts of Mn significantly reduced the wear rate, while increased amounts of Mo and S1 increased the wear rate. Analysis also confirmed previous research done by others, that increasing hardness and amounts of C reduced the wear rate. For the hardened steels taken as a class, only increasing amounts of C and Mn reduced the wear rate, while increases in Si increased the wear rate. In the class of unhardened steels, increases in C, Mn, and S re-duced the wear rate, whereas increases in Mo increased the wear rate. The steels with the best resistance to wear were two hardened experimen-tal steels similar to AISI 1055 and AISI 107S.

Jan 1, 1986

By Marling J. Ankeny

MINING research in the U. S. today is indeed complex, whether it involves the Government, a small private concern, or a large one. And it promises to become more so, despite great advances already made in developing equipment and technology. The U. S. Bureau of Mines is committed to place greater emphasis on mining research as expressed in a recent policy statement to Congress on the "Long Range Minerals Program," by Secretary Fred A. Seaton, quoted above.

Jan 1, 1958

By J. F. McIlwain

The Bureau of Mines investigated fumes generated by selected welding materials used in mines in order to help determine their relative hazard potential. The initial phases of the study have been completed. A welding-fume generation and collection apparatus was designed, assembled, and calibrated. Five brands of coated, AWS-type E308-16 stainless steel electrodes were tested. Total fume generation rates of 0.39 to 0.51 g/min were measured. Quantitative chemical analyses were conducted for all of the principal firms constituents. Two analytical schemes were used to determine levels of the Cr6+ and Cr3+ species contained in the welding fumes; comparable results were obtained. The Cr6+ was found to be the most hazardous constituent, leading to a maximum allowable total fume exposure of 1 mg/m3. Fume generation rates and fume constituent analyses will be derived for other groups of welding electrodes using similar procedures.

Jan 1, 1983

The leaching of gold and silver by ammonium thiosulfate solutions in the presence of copper has been actively studied in recent years. Newmont Gold Company has successfully tested the ammonium thiosulfate for gold extraction following biooxidation pretreatment of low grade refractory carbonaceous/sulfidic ores. In this paper, the chemistry of the copper catalyzed leaching process is reviewed. Factors affecting both the leaching reactions and the stability of the lixiviants are reviewed and discussed from a solution chemistry perspective.

Jan 1, 1996