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By B. B. Wood, M. J. Rzasa, E. W. Hough

An apparatus for the determination of fluid-fluid interfacial tension by the pendant drop method has been constructed. The apparatus is refined beyond those previously described in that the samples are introduced into an evacuated windowed cell without contacting air or mercury. Interfacial tension data are reported for the water-methane system between 74 and 280°F and 15 and 15,000 psi. The variation of wettability of the stainless-steel dropper tip with pressure and temperature was observed incidentally to the measurements. INTRODUCTION The most refined previous apparatus --for the determination of fluid-fluid interfacial tension at reservoir conditions was built by Hauser and Michaels.' These authors used the pendant drop method, previously investigated by Andreas, Hauser, and Tucker.' Recently, Fordham3 has made the pendant drop method an absolute one by numerical integration of the differential equation of drop shape. It is necessary to know the difference in density of the two fluids and the acceleration due to gravity in order to evaluate the interfacial tension from measurements of drop dimensions. Contact angle is not involved in the measurements by this method. Some precise tests of the method have been made at atmospheric pressure and 77°F by Douglas," who found agreement with established values to within about 0.1 per cent for water and air, cyclohexane and air, benzene and air, and benzene and water. No values of interfacial tension from the recent pendant drop apparatusJ have been published by Hauser and Michaels. However, values for the water-benzene and water-decane systems are given in Michaels' thesis5 or Dressures from 15 .to 10,000 psi and temperatures from 73 to 268ºF. Some determinations on gas-oil and gas-water systems in the range of 15 to 4,000 psi and 78 to 178°F have been made by Hozott,' by the drop-volume method. The capillary rise method has been used to investigate the interfacial tension in gas-oil systems at 88°F to several thousand psi by Swartz.7 Other determinations in gas-oil systems at pressures under 1,000 psia have been made by Jones: and Beecher and Parkhurst.9 The scarcity of data for pressures above 5.000 psi is apparent. APPARATUS An assembly drawing of the working section of the interfacial tenqion apparatus is given in Fig. 2. 'The endanant drop (A) is housed in a pressure chamber having glass windows (B). An agitator (6) is provided. The metal parts of the apparatus coming into contact with the sample are made of AISI: Type 316 steel. Drain grooves are provided around the whdows so that the sample in contact with the O-rings is not returned to the working section when the pressure is reduced. A schematic arrangement of the apparatus is given in Fig. 3. The working section containing the pendant drop (A) is filled by samples from bombs (B) with the aid of the vacuum system (C). The O-ring sealed pistons (D) used to separate the sample from the hydraulic fluid are shown together with the pressure production and measurement system (E). A front view of the apparatus is shown in Fig. 1. Most of the hydraulic system is at the top of the panel. The pump and displacement piston are at the lower right. The Variacs for the air bath heaters. the camera. and the vacuum gauge are a1so visible on the panel. The working section together with a window closure and a drop-forming tip closure are shown in Fig. 9. The carbon arc light source with filter is visible in the upper part of the picture. Two sides of the air bath with the impeller and a part of the convection shield can also be seen. The assembled air bath is shown in Fig. 10.

Jan 1, 1951

By E. W. Hough, B. B. Wood, M. J. Rzasa

An apparatus for the determination of fluid-fluid interfacial tension by the pendant drop method has been constructed. The apparatus is refined beyond those previously described in that the samples are introduced into an evacuated windowed cell without contacting air or mercury. Interfacial tension data are reported for the water-methane system between 74 and 280°F and 15 and 15,000 psi. The variation of wettability of the stainless-steel dropper tip with pressure and temperature was observed incidentally to the measurements. INTRODUCTION The most refined previous apparatus --for the determination of fluid-fluid interfacial tension at reservoir conditions was built by Hauser and Michaels.' These authors used the pendant drop method, previously investigated by Andreas, Hauser, and Tucker.' Recently, Fordham3 has made the pendant drop method an absolute one by numerical integration of the differential equation of drop shape. It is necessary to know the difference in density of the two fluids and the acceleration due to gravity in order to evaluate the interfacial tension from measurements of drop dimensions. Contact angle is not involved in the measurements by this method. Some precise tests of the method have been made at atmospheric pressure and 77°F by Douglas," who found agreement with established values to within about 0.1 per cent for water and air, cyclohexane and air, benzene and air, and benzene and water. No values of interfacial tension from the recent pendant drop apparatusJ have been published by Hauser and Michaels. However, values for the water-benzene and water-decane systems are given in Michaels' thesis5 or Dressures from 15 .to 10,000 psi and temperatures from 73 to 268ºF. Some determinations on gas-oil and gas-water systems in the range of 15 to 4,000 psi and 78 to 178°F have been made by Hozott,' by the drop-volume method. The capillary rise method has been used to investigate the interfacial tension in gas-oil systems at 88°F to several thousand psi by Swartz.7 Other determinations in gas-oil systems at pressures under 1,000 psia have been made by Jones: and Beecher and Parkhurst.9 The scarcity of data for pressures above 5.000 psi is apparent. APPARATUS An assembly drawing of the working section of the interfacial tenqion apparatus is given in Fig. 2. 'The endanant drop (A) is housed in a pressure chamber having glass windows (B). An agitator (6) is provided. The metal parts of the apparatus coming into contact with the sample are made of AISI: Type 316 steel. Drain grooves are provided around the whdows so that the sample in contact with the O-rings is not returned to the working section when the pressure is reduced. A schematic arrangement of the apparatus is given in Fig. 3. The working section containing the pendant drop (A) is filled by samples from bombs (B) with the aid of the vacuum system (C). The O-ring sealed pistons (D) used to separate the sample from the hydraulic fluid are shown together with the pressure production and measurement system (E). A front view of the apparatus is shown in Fig. 1. Most of the hydraulic system is at the top of the panel. The pump and displacement piston are at the lower right. The Variacs for the air bath heaters. the camera. and the vacuum gauge are a1so visible on the panel. The working section together with a window closure and a drop-forming tip closure are shown in Fig. 9. The carbon arc light source with filter is visible in the upper part of the picture. Two sides of the air bath with the impeller and a part of the convection shield can also be seen. The assembled air bath is shown in Fig. 10.

Jan 1, 1951

By J. Chia, M. H. Kobler, J. Cheung, M. J. Robison

INTRODUCTION The Lake Merced Transport is being constructed as part of San Francisco's Clean Water Program. The Clean Water Program, which began in the early 1970's, is designed to control wet weather, storm sewage overflows into the Pacific Ocean and San Francisco Bay. To accomplish this goal, a system of large underground storage and transport facilities, pump stations, modernized treatment plants, and outfalls is being built. By 1991, eighty percent of the system had been completed and was in operation. One of the remaining projects for the Clean Water Program is the Lake Merced Transport. The Lake Merced Transport is located in the extreme southwestern portion of San Francisco, as shown in Figure 1, Project Location. The transport will convey dry weather flow from the existing Lake Merced Pump Station to the Westside Pump Station. During wet weather, the transport will fill with sewage and runoff, with a storage capacity of 36 million liters. The Lake Merced Transport was expected to be excavated entirely within the Colma Formation, an alluvial deposit consisting of weakly cemented sand. Once excavation of the access portal at the Sloat/Great Highway parking lot began, it became evident that a portion of the tunnel would be excavated through beach/dune sand. Based upon the expectations of the Geotechnical Design Summary Report (GDSR), encountering beach/

Jan 1, 1993

Australia as a leading producer of mineral sands has also occupied a leading position in many areas of research'in the processing and applications of these minerals. Research in upgrading ilmenite to produce synthetic rutile has resulted in the develop- ment of many processes, e.g,., Becher, Murso, Chlorine Technology, and ICI processes. Studies on the reducibility of ilmenites, aqueous leaching of reduced ilmenites, Fe-Ti-O system, leachability of natural and treated ilmenites in hydrochloric acid and selective chlorination of iron from ilmenites have been carried out in order to develop and improve the efficiency of the above processes. While research on the processing of zircon sand to produce high purity (99.99% ZrO2 zirconia powder and zirconium chemicals started only recently, research by CSIRO in the early 1970s led to the discovery of the phenomenon of transformation toughening in partially stabilized zirconia (PSZ) ceramics. Australia, with very significant resources of lanthanide-containing ores, pro- duces substantial quantities of monazite each year but research in processing and appli- cations of rare earths was neglected in recent years in this country. However, research to improve processes for the recovery of rare earths is now under way and studies on the production and testing of Nd-B-Fe magnets which are 1.5-2 times stronger than the strongest magnets (Sm-Co) currently available, have also commenced.' An overview of the research in the pro- cessing and applications of mineral sands during the last two decades in Australia and its implications for the industry are pre- sented in the paper.

Jan 1, 1986

By Louis D. Huntoon

(New Haven Meeting, February, 1909.) THE Hammond Mining and Metallurgical Laboratory is the gift of Prof. John Hays Hammond to the Sheffield Scientific School of Yale University. Professor Hammond was graduated from this school in the class of 1876, and has always shown great interest in its welfare and progress. In 1903, he offered to build and equip for it a mining and metallurgical laboratory. This offer was gratefully accepted by the trustees; and in October of the same year the architect, W. Gedney Beatty, and the writer were employed to draw up plans for the building, which is the largest of its kind in this country. The Treasurer's report shows the total gift of Professor Hammond, including land, building, and equipment, to have been $128,741.53. This does not include $5,000 given by Professor Hammond to defray incidental expenses. The detailed cost of the machinery and installation, included in the above sum, is as follows: Machinery, $9,846.00 Pipe and fittings, 925.05 Hangers, shafting, pulleys, belts, etc., . 357.83 Steel-work, tanks, launders, etc., . 272.19 Screens for sizing ore, 411.37 Lumber, 1,896.36 General Supplies Hardware, . $135.96 Tools, 263.66 Paints, . 04.63 Electric and incidental, . 439.57 - 1,043.82 Machine-shop material, 259.44 Labor, 722.29 - 981.73

Mar 1, 1909

By Miroslaw M. Hajdasinski

A project's rate of return (ROR) [The list of all the acronyms used in his text is provided at its end.], be it an internal or external one, usually needs to be approximated. The success and efficiency of an approximation procedure depend on the quality of the initiating parameters such as bounds or seed values (guesses). Current approximation procedures commonly use bounds and guesses dictated by intuition rather then by mathematical consideration. The paper presents three ROR-bounding and six ROR-guessing approaches and examines their suitability on the examples of the typical project cash flow patterns.

Jan 1, 1996

By L. Martins Demuner, D. Burzic, V. Cunha Aranda, F. L. Lourenço, G. Romeu Trindade dos Santos, F. Ramstorfer

For many years, Dynamic Soft Reduction has been regarded as a proper method in improving internal quality of slabs. Even though processes models improved significantly over the past years, the efficiency of Soft Reduction was always limited by the discretization error, which inherently exists if segment rollers cannot be positioned individually. The recently developed SRD segment type allows for an individual roller positioning within the mushy zone by avoiding any discretization deviation from the optimal gap. This paper provides a detailed technological overview of the SRD segments as well as operational results at their very first implementation at Ternium Brazil.

Oct 1, 2019

By AIME AIME

THE 1941 fall meeting of the Iron and Steel and the Institute- of Metal, Division held at the Ritz-Carlton Hotel, Philadelphia, during the first three days (Oct. 20-22) of the National Metal Congress was well attended as usual, and the seven technical sessions and the joint round table on order-disorder transformations were this year of considerably more than routine interest. Despite unseasonably warm weather, a scarcity of hotels (there were rumors, apparently well-founded, that , some of the metal man attending the Congress had to stay in tourist camp), and a multiplicity of technical and other ions of the co-operating societies that gave the Congress this year the general air of a three-ring circus the A.I.M.E. sessions attracted audiences that ragged from seventy or eighty up to 350

Jan 1, 1941

By B. P. Spigarelli

To meet the growing need for CO2 capture and storage technology, Michigan Technological University is researching CO2 capture and storage using carbonate solutions. The objective of the present study was to increase the absorption rate of CO2 into the carbonate solution without reducing the absorption capacity of the solution. This approach used a polypropylene glycol methyl ether (PPGME) as a surfactant to chemically alter the gas bubble size. Experiments were conducted to study the absorption rate of CO2 at varying surfactant concentrations of 0, 0.12, 0.24, 0.36 and 0.48 g/L. Results showed that as the concentration of surfactant increased in solution, the absorption rate also increased. The CO2 absorption rate increased from 3.45 mmol/min CO2 at 0 g/L PPGME to 3.92 mmol/min CO2 at 0.48 g/L PPGME. This amounted to a 14% increase in the CO2 absorption rate with no decrease in absorption capacity of the solution.

By M. E. Orman

Many factors must be considered when designing a heap leach pad. Geotechnical properties of the ore, can and will affect how well an ore leaches, the solution recovery, stability of the heap, and settlement. As a heap is stacked some of these properties will change due to the increased load. In order to properly design a heap these properties should be determined beforehand so that the heap performs as intended.

Jan 1, 1997

By A. Rod Kern, Michael A. McNicholas, Yaser Taheri

Deep foundations were required for construction of an 18,000 ft2 (1,672 m2) 4-story office building and an adjacent 23,750 ft2 (2,206 m2) 5-story parking garage in Queens, New York due to an existing uncontrolled fill layer ranging from 15-20 ft (4.6 - 6.1 m) in thickness beneath the building footprint. The geotechnical engineers for the project initially selected auger cast-in-place (ACIP) piles over driven piles to limit the impact of noise and vibrations on the surrounding neighborhood. Ultimately, drilled displacement piles (DDP) were installed since this method offered a more economical solution that would generate the required pile capacity with shorter drill depths and would also mitigate spoils volume. During installation of test piles by the geotechnical contractor retained for the foundation work, multiple unanticipated soil conditions were encountered that would adversely affect the constructability of the piles. The existing fill contained significantly more natural and manmade obstructions than expected and the underlying glacial soil became too dense to penetrate at shallower depths than anticipated. This paper discusses how these issues were overcome through pre-drilling and the use of detailed instrumented test pile data coupled with in-house engineering capability to proactively re-evaluate minimum pile lengths at any given location and keep the project on track. INTRODUCTION Geotechnical work in the New York City market presents soil conditions that can be highly variable and challenging due to the presence of uncontrolled urban fill placed over the native soils. Construction in this area can therefore pose many unforeseen challenges, even with detailed geotechnical analysis being performed at project sites. A case in point is a construction site in Queens, New York. The proposed site development consisted of construction of a 4-story office building with a footprint of 18,000 ft2 (1672 m2) and a stand-alone 5-level parking garage with a footprint of 23,750 ft2 (2206 m2), together with associated new pavements and utilities. The site is bordered by a mix of commercial buildings and residential properties on all sides. Depth of the uncontrolled nature of the fill extended up to 20 ft (6.1 m) below street grade. Given the significant cost associated with removal and replacement, deep foundations were recommended to bypass the unsuitable soils and support the structures at depth where good bearing material existed.

Jan 1, 2019

By J. B. Webster

Health and Safety in the work place is of primary concern to the underground coal industry. Control of dust in the underground environment is of major importance in this concern. Utah Power and Light Mining Division has undertaken extensive studies to determine and control the various sources of respirable dust in underground high production sections. Determination of dust sources has been achieved by real-time aerosol sampling and standard gravimetric sampling on individuals and in various suspect locations. Some sources are diesel roadway dust, outby crushing, and handling equipment, face sloughing, water spray roll-back, and mining equipment. Once identified, the dust sources are suppressed or controlled and/or the workers are directed from areas of greatest potential exposure.

Jan 1, 1990

By S. K. Kawatra

Many mineral oxide and multi-component oxide (basalt) specimens break down into powders upon expo-sure to sodium vapor at elevated temperatures for extended times. This paper examines several possible mechanisms of oxide breakage by sodium vapor, both experimentally and from a thermodynamic viewpoint. The oxides for which reduction by sodium was thermo-dynamically favorable all exhibited some degree of fragmentation. The oxides which were not favorable for reduction by sodium did not exhibit fragmentation, with the exception of rutile, a titanium oxide. The rutile fragmentation was caused by the reduction of iron that was in solid solution in the rutile crystal structure.

Jan 1, 1995

By Y, Li Jianxiong, Hu Hua, Gu Desheng

After having briefed the technical and economical advantages of continuous mass mining in underground metal mines, the authors discuss the four stages of research and development of continuous mass mining in China. The four stages are: vibrating ore drawing in a stope, continuous mass mining in a stope continuous mass mining without rib pillars in an area and continuous mass mining in whole mine. The authors briefly review the research achievements of the first and the second stage; Combining the key national research project of the æNinth Five Year PlanÆ ù æThe experiment and research of continuous mass mining without rib pillarÆ, the authors introduce in detail the technological condition of mining, the design ideas of continuous mass mining, the design scheme of mining, the technology of mining. the equipment of mass mining, the chief research achievements and so on. The success of research of continuous mass mining without rib pillar indicates the arrival of the third stage of research. The introduction of continuous mass mining will promote the technology revolution of mining in China remarkably. The authors also point out that the development direction of continuous mass mining of the 21 century is continuous mass mining in whole mine, which is the fourth stage of research.

Jan 1, 2000

By Alan Rice

Abstract-The mechanism by which stratiform ore deposits of PGE (platinum-group elements) are laid down in ultramafic igneous complexes is not completely clear. Early studies by the author and coworkers on numerical analyses of the convective cooling of low-Rayleigh-number magma chambers examined the effect of suspended crystal load on fluid density, and raised the possibility that the growth of the suspended crystal load during cooling could split a magma chamber into several convecting layers. The lower layers would have a higher content of refractory phases than the upper layers, which would consist of more evolved melt. This paper considers numerical modelling, as well as theoretical and experimental work in other fields dealing with suspended loads in fluids. The calculations, which are based on the physics of convecting magmas, yield quantitative relationships consistent with the observation that economically interesting stratiform PGE deposits are restricted to large magma bodies, and also yield estimation of the depth in a magma chamber at which certain grades of mineralization may occur.

Jan 1, 1997

By Alan Rice

The mechanism by which stratiform ore deposits of PGE (platinum-group elements) are laid down in ultrama?c igneous complexes is not completely clear. Early studies by the author and coworkers on numerical analyses of the convective cooling of low-Rayleigh-number magma chambers examined the effect of suspended crystal load on ?uid density, and raised the possibility that the growth of the suspended crystal load during cooling could split a magma chamber into several convecting layers. The lower layers would have a higher content of refractory phases than the upper layers, which would consist of more evolved melt. This paper considers numerical modelling, as well as theoretical and experimental work in other ?elds dealing with suspended loads in ?uids. The calculations, which are based on the physics of convecting magmas, yield quantitative relationships consistent with the observation that economically interesting stratiform PGE deposits are restricted to large magma bodies, and also yield estimation of the depth in a magma chamber at which certain grades of mineralization may occur.

Jan 1, 1997

By Fan Jiang, Haigang Wang, Shi Liu

"This paper describes several applications of Electrical Capacitance Tomography (ECT) in gassolid two phase flows. A new image reconstruction algorithm was evaluated by both simulation and experiments. It is then applied to the online measurement of solids distributions in square circulating fluidized beds (CFBs) and good results were obtained. From the measurement of solids distributions in the bottom zone of a CFB, a bubbly fluidization pattern is identified. A cross-correlation technique was combined with the solids concentration measurements to obtain the flow rate through the dip leg of the cyclone, i.e. the circulating rate of a test CFB. The same· technique was applied in a dense phase pneumatic transport pipe provides the solids concentration, and the flow rate of a wavy gas-solids flow.IntroductionElectrical capacitance tomography (ECT) has been developed for imaging multiphase distributions in the 90's of the ·last century. It is a non-intrusive method. The principle of ECT can be firefly described as follows:Firstly ECT uses a number of electrodes to surround the measuring zone, depicted by Fig. I. The capacitances between the electrodes are measured in turn and an array C is obtained that contains a total number of m independently measured capacitances. Meanwhile the measuring zone is virtually divided into a grid of n pixels, represented by an array G, named the image vector, the gray level of each pixel represents the local value of the concentration of the material. As the material distribution will be reflected by the capacitances between each pair of electrodes, such distributions can be reconstructed according to the measured capacitance, a process called image reconstruction. A common image reconstruction method is called linear-backprojection (LBP). It linearize the relationship between the dielectric distributions in the measuring zone and the capacitances between the electrodes as the following:"

Jan 1, 2004

By George O. Lower

The use of cyanides in the extraction of gold and silver is well known.1 Such extractions employ con¬centrations of cyanide in the range of 0.02-0.25 % sodium cyanide equivalent in leaching cycles of 24-48 hours and frequently longer. Copper minerals, even though minor components of precious metal ores, dissolve in these cyanide leaching solutions, consume cyanide, cause fouling of mill solutions, and thus interfere with the precipitation and recovery of gold and silver. 2,3,4 This paper presents a summary of laboratory investigations on the use of cyanide solutions as extractants for copper from various copper-bearing ore fractions. In view of the metal contents involved, it will be apparent that larger quantities of cyanide are required to extract copper than for the extraction of precious metals. In cyanide solutions of concentrations generally favorable to copper extraction, sulfide and oxide copper minerals were found to dissolve rapidly at room temperature and atmospheric pressure. For example, on products in the flotation size range, the major portions (e.g. 65-85%) of the extractable copper frequently dissolved in 2-10 minutes. At coarser grinds, e.g. 100% minus 28 mesh and 100% minus 10 mesh, 75-85% of the total copper was extracted in 30 minutes.

Jan 1, 1966

By Andressa Alves da Silva

Nowadays, population growth and the interest of food industry, makes the research and applications of biodegradable polymers increase, because under favorable conditions its degradations may occur within weeks or in a few months, reducing the environmental impact. This work presents the processing and characterization of flexible films by the incorporation of 3 % (% wt) of modified bentonite light green clay in the Copolyester/PLA biodegradable blend. The clay incorporation was carried out by melt-mixing processing, using a twin screw extruder machine. The films were obtained by cast extrusion tape. The films obtained were submitted to tensile tests, SEM and XRD analysis, and the correlation between their properties was discussed. The XRD results of clay showed that the quaternary salt and sodium carbonate addition increased the interlayer distance of clay making it easier to intercalation of blend in the nanoclay. The XRD results of PBAT/PLA/Clay nanocomposite show no characteristic organoclay peaks. This result suggests intercalation between nanoclay and matrix (blend). The tensile test results showed an increase of around 30% in tensile strength at break of nanocomposite film when compared with blend film.

Aug 8, 2018

By V. A. Nieberlein

This paper presents the results of research undertaken to recover titanium and columbium by low-temperature chlorination of low-grade columbium-bearing ilmenite concentrates, and to simultaneously remove chlorinated impurities from the volatile chlorides without resort to distillation. Coke-reduced ilmenite was chlorinated at 400° to 500° C., and the resulting TiC14 was free of most impurities before condensation. A heated purification column was used wherein various packing materials reacted chemically or physically with the impurities which passed through them in the vapor phase. A nearly water-white TiC14 product was obtained directly. The principal impurities in the titanium tetrachloride were: 0.02 percent Fe, 0.01 percent V, 0.05 percent A1, 0.04 percent Si, and 0.07 percent Cb. This is a less pure product than commercial TiC14. Most of the columbium was recovered as crude CbC15, requiring further refining.

Jan 1, 1960