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By R. A. Meussner, R. J. Goode

Six intermediate phases occur in the Nb-Zn sysThese phases form by peritectic reactions at 1120°, spectively. The Nb Zn 15 phase appears as the minor phase in the eutectic structure, and the terminal phases remain nearly pure niobium and zinc even at high temperature. Vapor -pressure measurements on the four high-temperature phases (Nb Zn to Nb Zn 3) permitted estimates of the composition limits of these phases and the calculation of approximate values of AFO, AH°, and AS°. 1 HE present study of the constitution of the binary Nb-Zn system was a part of an analysis of the mechanism by which coatings of the Nb-Zn intermediate phases protect niobium against oxidation at high temperature.' Since the primary interest in these phases was in coating service, attention in this study was given principally to the four phases stable at high temperature with only cursory attention to the two low-temperature phases. The solubility studies of niobium in zinc by Martin, Knighton, and Feder2 and the reports from the present study of the Nb-Zn coating represent the only published data pertaining to this system. Previously Hodge, Evans, and Hoskins, in an experimental survey, had noted that niobium was not resistant to attack by molten zinc, but no further observations were reported. EXPERIMENTAL PROCEDURES a) General. The nature of the binary Nb-Zn system precluded the use of more conventional methods of determining the phase equilibria such as thermal analyses of a series of cast alloys. An extrapolation of the liquidus data of Martin, Knighton, and Feder2 to higher temperatures suggested that the solubility of niobium in zinc would remain low in the entire temperature range of interest. The preliminary results of the present studies showed that all of the high-temperature intermediate phases form by peritectic reactions. Thus the sluggish nature of this type of reaction and the steepness of the liquidus indicated that thermal analyses would not yield reliable data. The peritectic reactions, of course, precluded the direct formation of samples of the individual phases from the melt. b) Materials. The niobium and zinc used in the present studies were of high purity. The niobium, in the form of 0.1-in.-diameter rods, contained 30 ppm 0, 30 ppm N, and 15 ppm C. Aside from 0.05 pct Ta, the metallic impurities (iron, titanium,

Jan 1, 1965

By Erwin Stötzer, Renato Fiorotto, Wolfgang G. Brunner, Manfred Schöpf

"Deep mixing methods can be used economically for the construction of cut-off or excavation support walls where other systems such as traditional soldier beams and lagging walls would yie ld unsatisfactory performance, where the installation of vibrated or driven sheet piles could cause vibration induced settlements and where concrete diaphragm walls would be time consuming and expensive. The new CSM method can largely replace the more conventional single or multiple auger methods of soil mixing or jet grouting. The cutter tool is similar to a cutter used in diaphragm walls or cut-off walls and is operated with a Kelly mounted on a drill rig. With this system much deeper walls can be installed and even hard soil layers can be penetrated. CONVENTIONAL SOIL MIXINGIn 1962 Norman Liver patented an auger-based soil mixing technique that has become the basis for the world's current technology.The deep mixing method (DMM), as it is known today, is an in situ soil treatment and improvement technology where the soil is blended with binders and/or other materials that are introduced in a slurry or dry form.Typically one or more hollow, rotating mixing shafts tipped with some type of cutting tool are mounted vertically to the mast of a base carrier and are driven into the ground by hydraulic or electrically powered rotary heads. The shafts above the cutting tool may be further equipped with discontinuous auger flights and/or mixing paddles. The binder is injected through the hollow shafts to nozzles located near the cutting tool where it is mixed with the ground to form columns of treated soil.Individual column diameters range from 0,6m to 1,5m and may extend to 40 m in depth. They can be arranged individually or in contiguous or secant patterns to produce a wide range of treated soil structures on both land and marine projects. Typical configurations are: Single elements, rows of overlapping (secant) elements, grids, lattices and blocks (Fig. 1 )."

Jan 1, 2005

By Y. Guan

The dissolution behavior of silver and copper from silver/copper alloys in ammoniacal solutions has been investigated using a rotating disc. Oxygen was used as an oxidant. The effect of composition of alloys, concentration of lixiviants, stirring speed and temperature on the overall dissolution kinetics has been studied. Silver / copper alloys of three compositions were used in this study. The atomic percents of silver in these alloys were 76.9, 46.9 and 24.1. The results on the rate of dissolution obtained for these alloys have been compared with that of pure silver and copper under the same testing conditions. A particular emphasis has been given to the galvanic effect on the overall dissolution rates.

Jan 1, 1993

By Jae-Ho. Lee

Mercury is a toxic contaminant encountered in the extraction of gold from mercury-containing ores. It is found in the leach solution of CIP circuits and in the cathodes of the electrolyte cells used to electrodeposit the gold. The research conducted has examined the potential for selective removal of mercury from synthetic Au-Hg-CN electrolytes containing only gold, only mercury, and both gold and mercury. Cyclic voltammograms were obtained for mercury- coated copper electrodes with these cyanide electrolytes. Exchange current densities were determined from the voltammograms in the low overpotential region. Laboratory scale batch- electrolysis at constant current was also conducted for the electrolytes containing only mercury and both mercury and gold, at 20 and 50°C and from which the kinetic behavior associated with the process was analyzed. The surface of cathode before and after electrolysis was also characterized and a copper mercury intermetallic (CyHg,) was identified. Gold codeposited with mercury during the later stages of electrolysis. The results of this work corroborate that the mercury-amalgam copper electrode offers a viable electrochemical technique for the selective removal of mercury, however a high-surface-area cathode-cell would have to be utilized to provide for the desired selectivity.

Jan 1, 1994

By Hayes K. M, Ostwald J

Compacted tablets of hematite ore (containing clay and quartz gangue) and limestone were heated in air in an ULVAC-RIKO rapid heating furnace to maximum temperatures in the range 1200-1350°C.The resulting sintered products were examined in terms of mineralogy, texture, strength and reducibility. The sintered tablets are a good analogue of normal plant sinters. These investigations have shown that sinters of optimum reducibility are produced in the narrow temperature range 1250-l275°C. Conditions for the production of such highly reducible sinters under plant conditions are discussed.

Jan 1, 1984

By Rebecca Hope, Derick Moolman, Frikkie Malan

"Despite the lip service that has been paid to pro-active plant maintenance processes over recent years, a significant portion of maintenance in industry is still reactive. The business driving force to prevent expensive production opportunity costs arising from “break-down maintenance” is obvious. Various benefits can be derived from successfully deploying remote equipment diagnosis technology and associated business processes.From an end-client’s viewpoint these include the ability to predict and take actions to prevent equipment breakdowns, increasing the lifetime of equipment by responding to appropriate operating instructions and therefore improving the return on capital expenditure. Better planning and scheduling of maintenance priorities and resources with performance measures like an Equipment Health Index are also possible. The knowledge that a qualified supplier engineer is constantly in touch with the operating conditions of their equipment, albeit remotely, is more than a comfort, and can be translated into quantifiable cost savings and improved supplier service levels."

Jan 1, 2003

The initiation of a panel cave is an extremely important and infrequent event in the life of a large underground caving operation. A new cave was initiated at the Henderson Mine in 1991, 15 years after its first cave had been developed in 1976. The original cave was started after a half billion dollars had been invested in the development of the mine, mill and 23 km haulage system. Many things had changed since 1976, the most significant of these being much lower realizations for molybdenum. In 1976 the high demand for molybdenum and uncertainty of caving characteristics, formed the basis for a very conservative cave initiation sequence with miles of boundary weakening and inspection drifting. In 1991 the highly competitive molybdenum market in conjunction with 15 years of caving experience made for a very different mining climate.

Jan 1, 1994

By H. V. Alminas

The U.S. Virgin Islands consist of three major islands (St. Thomas, St. John, and St. Croix) and some 50 smaller islands that are located primarily along the coasts of St. Thomas and St. John. St. Croix, the largest of the islands, is located approximately 160 km south-southeast of San Juan, Puerto Rico and is about 218 km in area (Fig. 1). St. Thomas, the second largest island is located 64 km east of Puerto Rico and incorporates approximately 77 km2. St. John is located immediately to the east of St. Thomas and incorporates approximately 49 km2. The climate in the U.S. Virgin Islands is maritime tropical. The average annual rainfall at higher elevations is 127-152 cm and at lower elevations 51-76 cm. There is no well-defined wet or dry season. Temperatures generally average in the 80's (F°) with only a 5°-7° F variation throughout the year.

Jan 1, 1987

By J. F. Hutwelker

A pilot plant was constructed and operated to investigate the column flotation of 20 x 200 mesh North Carolina phosphate ore, using high throughput, high solids operating conditions developed at the NCSU Minerals Research Laboratory. Flotation was performed at 45% solids in a 9.5 cm (3.75 in.) diameter by 2.26 m (7.4 ft.) tall column at throughputs of 19.1 t/hr/m2 (2.0 stph/ft2) and 31.7 t/hr/m2 (3.3 stph/ft2). Recoveries in excess of 98% of the phosphate value were obtained at the lower throughput -- while obtaining concentrate grades containing over 28% P205 (61.2% BPL) at that recovery. Recoveries of about 95% of the phosphate value were obtained at the higher throughput, while making a concentrate averaging 27.6% P209 (60.3% BPL). In addition, a better understanding of the variables governing the column flotation of coarse nonmetallic minerals was gained. Low air flow rates adversely affected concentrate grade at the lower throughput. At the higher throughput, phosphate recovery decreased at an elevated air flow rate. An unexpected result of the study was the effect that frother type had upon phosphate metallurgy. Use of Nottingham Econofroth 925 provided better flotation selectivity than American Cyanamid F-65 at the low throughput. This is significant since the high' throughput tests were conducted with F-65 exclusively. It is reasonable to expect further improvement in high throughput performance when the optimal frother type and dosage are determined.

Jan 1, 1993

By M. M. Botz

There are currently more that 460 mines worldwide that utilize cyanide for gold and silver extraction. Despite this large number of cyanide-related mining operations, there have been no published accounts during the previous 25 years of the death of humans due to cyanide as a direct consequence of major mining-related environmental incidents. All published accounts of human deaths due to mining-related environmental incidents have been the result of physical inundation with tailings or waste rock materials. It appears that major mining-related environmental incidents have not been concentrated in any geographic location, are likely to occur regardless of the size of the mining company and do not occur more frequently with a specific type of mining activity. Several cyanide treatment and recovery technologies have been widely demonstrated to reliably control cyanide levels in mining solutions. With proper use of these technologies, tailings cyanide concentrations can be maintained at levels protective of wildlife while reducing the potential for adverse environmental incidents. The development of an international cyanide code of practice or management plan is recommended and should take into consideration the adoption of a weak-acid-dissociable (WAD) cyanide standard that maintains the levels entering a tailings impoundment below 50 mg/L.

Jan 1, 2001

By ROBERT E. CROCKETT

MAGNETITE mining and milling in New York, New Jersey and Pennsylvania continued to remain comparatively inactive during 1933, owing to the low rate of output of the steel industry and also to unrestricted importation of foreign ores. However, some improvement over conditions existing in 1932 was noticeable, particularly in New Jersey, where one plant, that of the Washington mine of the Alan Wood Mining Co., at Oxford, went on full production in August. At Lyon Mountain, N. Y., the Chateaugay Ore and Iron Co. resumed mining and milling operations in October, on a reduced scale, principally to provide employment during the winter months. The Chateaugay company produces a special low-phosphorus pig iron. During the year they obtained a contract to supply their product for use in the manufacture of the suspension cables of the New. Golden Gate Bridge.

Jan 1, 1934

By J. P. Ducarme, J. L. Carr, C. C. Jobes

"An average of 1.2 fatalities occur per year in underground coal mines in the United States when a miner is struck or pinned by a remote-controlled continuous mining machine. Proximity detection technology provides a means to prevent these types of accidents by disabling all machine motion when a miner is in close proximity. Researchers at the National Institute for Occupational Safety and Health (NIOSH) have developed the intelligent Proximity Detection (iPD) system, which continuously tracks the position of miners near the machine and disables only those machine motions that could cause a pinning accident. This system, previously demonstrated using non-permissible proximity detection hardware, has now been shown to be effective when implemented using an MSHA-approved system as a platform. Performance tests have shown accuracy, repeatability, and stop zone identification to be comparable to or better than the system demonstrated with non-permissible hardware. INTRODUCTION Underground coal mining room-and-pillar operations typically use Continuous Mining Machines (CMMs), such as the one shown in Figure 1. When CMMs first became available, they were operated from an on-board operator’s compartment that protected operators from roof falls and other hazards but severely restricted visibility and subjected them to machine vibration and high levels of dust and noise. To solve these problems, remote controls were developed to operate CMMs. Now CMM operators are free to position themselves for best visibility of each mining task and are no longer subjected to the rough motion of the CMM during mining operations or the dust and noise generated by the machine. However, this technological advance removed operators from the protection afforded by the operator’s compartment and exposed them to the hazard of being struck or pinned by the CMM or other large moving machines."

Jan 1, 2015

By John J. Van den Broek

As the established tailings disposal techniques do not meet the requirements of today, alternative methods of disposal are explored. McIntyre Mines Ltd., Coal Div. found a solution in the construction and operation of a tailings dewatering plant. The solids are recovered from the tailings slurry by means of mechanical dewatering equipment and are then dried in a unique drying system to provide an excellent thermal fuel for a power generating station.

Jan 1, 1983

By D Clarke, I Minniakhmetov

The Olympic Dam deposit is truly a world-class IOCG-Ag deposit, the world’s fourth largest deposit of copper and the world’s largest known single uranium deposit. Traditional and non-traditional methods have been used to accurately model the geology and mineralisation of the Olympic Dam deposit. Conditional simulation models have long been used as the most robust method for estimating risk and uncertainty in mine planning decisions at other mines around Australia and the world. There are many challenges associated with simulating the Olympic Dam deposit at a selective mining unit size sufficient for underground mine planning purposes. These include the size of the deposit, resulting in hundreds of millions of grid blocks; the disseminated nature of the zoned sulfide mineralisation. And lastly the direct relationship of the relative abundances of the sulfide mineral species that are crucial to the Olympic Dam smelter performance. Several geostatistical techniques have been utilised in the workflow for the Olympic Dam Conditional Simulation model to address these challenges. The key techniques are: • Projection Pursuit Multivariate Transform to de-correlate the main elements before simulation. • Pluri-Gaussian implicit boundary simulation method to simulate the mineralisation domains. • Spectral simulation method of de-trended and de-correlated attributes with account of local varying variance. The resulting conditional simulation models have been validated against histograms, grade-tonnage curves, cross-plots and assessed for variogram reproduction. This paper presents how the final conditional simulation models compare to benchmarking models created using alternate estimation techniques of ordinary kriging and local uniform conditioning. It also presents a validation process using historical samples to test final estimate accuracy of the simulation models.

May 24, 2023

By L. Tapia

The main disturbance for stability in primary grinding using SAG mills is related to continuous changes in the ore being fed to the plant, such as size and hardness. Searching for stability is the first step to accomplish, before trying to maximize the mill throughput. The time variability in the characteristics of the ore being fed from the mine to the plant must be known or inferred to perform adaptive changes in the grinding process control. In day to day operation, such information is not available in real time. Transport times and inventories between the mine and the plant complicate the situation. Under this scenario, Minera Los Pelambres implemented a grinding optimization strategy, based on the real time analysis of certain process variables, such as ore size, mill current consumption, pebble generation and throughput. As a result, both grindability and stability indexes are inferred. This is equivalent to inferring the ore characteristics by knowing its effect on the grinding behavior. These two indexes permit control of the SAG mill total charge level and hence, allow optimization of throughput by means of an expert control system.

Jan 1, 2007

By Heikki K. Jalkanen

Thermodynamic properties of copper-iron mattes and slag-matte distribution of copper and some minor matte constituents (Ni, Co, Mo, As, Sb and Bi) are discussed on? the basis of equilibrium measurements: a change from. oxidic to sulfidic solubility as the predominant form of dissolution of copper takes place as matte grade decreases. Distribution coefficients of minor matte constituents are complex functions of sulfur and/or oxygen potentials?. The distribution behaviour of different? metals can be qualitatively derived from their affinities to copper and stabilities. of their sulfides and oxides. The equilibrium results are compared with commercially observed values. from Outokumpu.Oy flash smelting furnace.

Jan 1, 1983

By V Malysiak, N J. Shackleton

In the flotation of platinum group minerals pyroxene is a major gangue mineral. This study shows using zeta potential and ToF-SIMS analyses that when pyroxene is exposed to copper, nickel and/or calcium ions in solution at alkaline pHs a surface reaction occurs between the hydroxy species, in the case of copper and nickel, or divalent calcium ions and the pyroxene surface which influences the floatability of the pyroxene. Following exposure to copper and nickel ions at pH 9 addition of SIBX resulted in the pyroxene floating readily. It is also shown, in the case of copper, that the activating effect of the adsorbed copper hydroxy species can be reduced by the addition of complexing amines prior to SIBX. Proposals are made to explain these observations.

Jan 1, 2005

By Fernando Henrique Gomes de Souza

Techniques which use a spring to supply the bias force to actuator are well adopted since they are inexpensive and simple to construct. In this work it was design an actuator concept using bias-type device technique, which comprises two coils that mutually push against each other to supply the stroke. For the coils springs, it was used a wire of NiTi shape memory alloys (SMA) and a wire of 400 grade maraging steel as construction materials.

Aug 8, 2018

By Jim Bruce, Naresh Gurpersaud

"The West Toronto Diamond project, under construction since 2006 and due to be complete in 2015, is a rail-to-rail grade separation project in the heart of urban Toronto. Once complete, a depressed corridor over 1000 metres long will take the CN tracks beneath the CPR tracks. An interlocking steel pile wall serves to retain ground and cut off groundwater. Remedial measures, constructed using jet grouting, were required at several locations within and behind the steel piles.At mechanical interlock joints damaged or suspected of being damaged, jet grouting was used to improve native soils on the retained side of the wall to reduce permeability of the soil mass in intimate contact with the joints to 10-7 cm/s. At a number of steel piles where groundwater and soil type combined to cause basal instability inside the pipes during the interim between excavation and concreting, jet grouting was used to construct temporary bottom seals. At locations near adjacent structures where the steel pile installation process resulted in disturbed ground on the retained side of the wall, jet grouting was used to strengthen and stabilize ground.This paper outlines the details of the various jet grouting applications, the respective testing programs implemented to demonstrate in situ permeability and strength of the soil-grout matrix, and performance of the constructed system.INTRODUCTIONThe West Toronto Diamond (WTD) is a junction of several railway lines, all intersecting at the same grade (Figure 1). A major grade separation project at this site commenced in 2006 and is scheduled to be completed in 2015. The whole of the work is comprised of multiple contracts, completed and/or ongoing, by different constructors. Once completed, a depressed corridor over 1000 metres long with over 23,500 m2 (face area) of retained earth will bring the CN tracks beneath the CPR tracks and eliminate a major bottleneck at the most heavily used rail crossing in Canada."

Jan 1, 2017

By D. C. Shumway

Mining in Cushenbury Canyon began in 1860 when John Cushenbury left his Holcomb Valley gold prospect and discovered a silver vein in the limestones of the present day Cushenbury Mine. Cushenbury Canyon is located along the western boundary of the Mojave Desert in Southern California and on the north slope of the San Bernardino Mountains. The Holcomb Valley, immediately southeast of Cushenbury Canyon was the most prolific gold producer in Southern California. Gold mining dominated the area until World War II when interest in the Lucerne Valley Limestone deposits was peaked by the construction of the Kaiser Steel Plant in Fontana, California. The steel making process required large amounts of metallurgical grade limestone and Kaiser geologists located claims in most of the limestone deposits. Kaiser Cement constructed a cement plant and limestone mine in Cushenbury Canyon in 1956. Kaiser Cement modernized the facility in 1982 to a four stage preheater-precalciner system. Mitsubishi Cement Corp. purchased the property in April, 1988, and through further system modifications have created the most efficient and modern cement plant in the United States.

Jan 1, 1992