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By A Rantala, J Timperi and J Kaartinen, T Maksimainen, O Haavisto

"X-ray fluorescence (XRF) is the most common technique used for online slurry assaying in base metal flotation applications. Typically, assays from feed, concentrate and tailings slurries are used to monitor and control the flotation circuit, with possible additional sampling locations in other main slurry flows inside the circuit. The elemental content detection from the XRF spectrum is relatively straightforward as the spectrum contains element-specific peaks whose height corresponds to the element concentration in the sample. However, centralised XRF analysers measure the elemental concentrations line-by-line, which may increase the sampling interval for an individual line and cause unnecessary response delays, especially in large flotation plants. Reflectance spectroscopy is an emerging technique that can be used to obtain more frequent measurements from slurries. The measurement is based on the mineral-specific absorbance of light in the visible and near-infrared (VNIR) wavelength range. Due to this relatively inexpensive and simple measurement system, it is possible to conduct the measurement simultaneously in several slurry lines. However, the information contained in the VNIR spectra is more difficult to interpret as concentrations of all the minerals in the sample contribute to the measured spectrum and changes in solids content, particle size and mineralogy disturb the elemental content estimation. Therefore, frequent calibration of the measurement is required. This study presents the application of combined reflectance spectrum and XRF measurements for rapid online slurry assaying in a copper-nickel flotation plant. The XRF assays are utilised as calibration samples for the reflectance spectrum measurement, keeping the calibration model up-to-date. The rapid reflectance spectrum analysis is then used to provide an almost continuous estimate of the slurry contents, enabling further improved process monitoring and control.Citation:Haavisto, O, Maksimainen, T, Rantala, A, Timperi, J and Kaartinen, J, 2016. Reflectance Spectroscopy with X-ray Fluorescence for Rapid Online Assaying in a Copper-nickel Flotation Plant, in Proceedings 13th AusIMM Mill Operators’ Conference 2016, pp 85–92 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Oct 10, 2016

By R. H. Sailors

During the last 15 years, the North American Mining Industry has experienced increasing usage of cast high chromium white iron grinding media in wet grinding applications. First introduced into the cement industry (klinker grinding) where wear rate reductions of four or five times have been realized compared to steel balls, this same grinding media serve the iron, copper, and phosphate markets by resisting not only impacts and abrasion, but also corrosion which occurs in wet grinding. In these markets, single mills containing 250,000 kg of grinding balls are not un-common and hence the economic potential with respect to lower wear rates can be significant. Add to reduced wear rate the increased production efficiency that is possible and it is readily understood why much of the mining industry uses cast high chromium grinding media. Metallurgically, the alloys used consist of a martensitic matrix containing hard M7C3 eutectic carbides. Carbon (2.0 to 3.5%) and chromium (12 to 277.) are characteristically used to arrive at the desired properties.

Jan 1, 1989

By J. W. Stewart

ONE of the postwar problems posed for mineral engineering educators is the desire of some mature student veterans to finish their college education under the G. I. Bill of Rights as quickly as possible, a desire that is quite understandable. Not only have they lost several years of education, which they wish to make up as quickly as possible, but many are married and have families and want to become productive as soon as possible in order to support their families properly. The obvious solution to this problem, if it really is serious, would appear to be a continuation of the wartime Accelerated Program, as it was carried on in most colleges and universities. As a matter of fact some schools are known to have continued their wartime programs in one or another form. To ascertain just what our mineral engineering schools generally are doing to meet this postwar problem, last April a questionnaire was sent to administrative officers at colleges and universities

Jan 1, 1946

By I. A. H. Schneiderl

Eichhornia crassipes approaches being a scourge in many parts of the world, .choking waterways and hindering transport upon them. At the same time it is known to readily abstract heavy metal ions from water and, thus, aids in the removal of heavy metals found in such waters. This paper considers the possibility of using specific parts of the plant as an inexpensive adsorbent for the removal of heavy metals from contaminated chemical and mining industry waste waters. In particular the root of the plant was found to be an excellent accumulator of 'heavy metal ions including uranium from solution. It is. also suggested that dried roots of the plant ?might be placed in simple bags and used in a very low cost metal ion removal system.

Jan 1, 1995

By A. Ligorio Pires de Carvalho

The main potash deposit at Taquari-Vassouras is contained in cycle VII, and consists of several sylvinite bodies. Cycle VII belongs to a sequence of nine cycles defined by Szatmari (1974) in the Sergipe-Alagoas basin. The sylvinite layers are separated by halite beds. They are seated on or may be laterally in discordant contact with other lithologies such as the tachyhydrites at the base, and the limestone breccia at the top. The main structural features in the deposit include numerous synclines and anticlines, salt dissolution phenomena, and open fractures associated with the axes of the anticlines.

Jan 1, 1995

By A. Cordonnier, Ch. Obry, R. Evrard

In spite of the large annual expenditures and the vast field of activity covered, it cannot be said that many new grinding machines have actually come to light and modified the existing market for more than half a century. Manufacturers have mainly made advances in increasing machine sizes, efficiency and reliability, and in machine automation. The relatively recent emergence of roller presses is the only exception to this homogenisation of machine ranges. The development of roller presses in pregrinding has shown the advantages of compression grinding over the ball mill from the power consumption point of view. But classical roller presses still have maintenance problems due to the high grinding pressure. The FCB Research Centre has carried out much work in this field and in particular has studied the advantages of this process in pregrinding and integral grinding. These researches lead to the development of two new compression grinding machines. The first one, HOROMILL®, presented for the first time on the 8th European symposium on comminution at Stockholm, finds its application in the field of fine to very fine grinding in dry process. The second one, RHODAX®, presented at INTERMAT in Paris, covers the field of secondary and tertiary crushing and the first stage of grinding for most of the minerals in dry or wet process. Its high reduction factor permits to do with only one machine the work realised today with two or three crushing/milling stages. These two complementary machines offer a wide range of combination summarised on [Figure 1].

Jan 1, 1995

By C A. Foss, K Leslie, C Arnold

Magnetic susceptibility measurements provide rapid, non-destructive testing of drill core, but cannot directly map magnetite and/or hematite content. Combined magnetic susceptibility and magnetisation measurements provide much more diagnostic information and, with sparse calibration constraints, are able to quantify magnetite and hematite concentrations and potentially map differences in grain size and texture. We have developed a travelling three-component vector magnetometer that can be run alongside core to map its external magnetic field. The logger has been designed to operate in core sheds and at remote drill sites. It is used to rapidly scan a length of core, with each core being scanned in different rotations. The magnetic field contributions from any remanent magnetisation rotates with the core and cause differences between successive measurements, while the field contributions from any induced magnetisations with isotropic magnetic susceptibility remain constant. Deconvolution of the magnetic field data with simultaneous three-channel inversions of the multirotation data separates remanent and induced components. Interpretation of this data provides estimates of the intensities of induced and remanent magnetisations, the orientation of the remanent magnetisations and the ratios of the induced and remanent magnetisation strengths. We expect these magnetisation parameters to correlate with stratigraphy through a banded-iron formation. Furthermore, we anticipate that we will be able to use this information to map zones of oxidation and other changes along the core. This novel instrument is one component of an integrated CSIRO program to provide new capabilities for iron ore exploration and development based on studies of magnetic fields and magnetisations at scales ranging from centimetres for these core investigations to tens of kilometres for formation studies.CITATION:Foss, C A, Leslie, K and Arnold, C, 2015. Rapid logging of different magnetic phases in banded ironstones using a travelling three-component vector magnetometer, in Proceedings Iron Ore 2015, pp 271–276 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 13, 2015

Albin, B. R. Billings, Mont. 28 Amster, Nathan L 25 Broad St., New York, N. Y. '28 Bache, Jules S. 42 Broadway, New York, N. Y. 28 Barrett, C. P. 5338 Harper Ave., Chicago, 111. '28 Baum, Frank G., Cons. Hydro-Electric Engr Cassel, Shasta Co., Cal. '28 Bayless, William S. Russ Bldg., San Francisco, Cal. '28 Bean, Louis H.60 E. 42nd St., New York, N. Y. '28 Beatty, Roes J. 1105 First National Bank Bldg., Chicago, Ill. '28 Benwell, Oswald F. Hold Mags. '28 Beymer, Albert S., V.P., Keystone National Bank Pittsburgh, Pa. '28 Blumenthal, Hugo 44 Pine St., New York, N. Y. '28 Boettcher, Charles Ideal Cement Bldg., Denver, Colo. '28 Bowlus, Thomas H. Iola, Kan. '28 Brown, Colvin B. Chamber of Commerce, Washington, D. C. '28 Bart, Maxwell Struthers Southern Pines, N. C. '28

Jan 1, 1932

Albin, B. R Billings, Mont. '28 Amster, Nathan L 25 Broad St., New York, N. Y. '28 Bache, Jules S. 42 Broadway, New York, N. Y. '28 Barrett C. P. 5338 Harper Ave., Chicago, Ill. '28 Baum, Frank G., Cons. Hydro-Electric Engr Cassel, Shasta Co., Cal. '28 Bayless, William S. Russ Bldg., San Francisco, Cal. '28 Bean, Louis H. 60 E. 42nd St., New York, N. Y. '28 Beatty, Ross J. Room 604, 6 N. Clark St., Chicago, Ill. '28 Benwell, Oswald F. Hold Mags. '28 Beymer, Albert S., V.-P., Keystone National BankPittsburgh, Pa. '28 Blumenthal, Hugo. 44 Pine St., New York, N. Y. '28 Boettcher, Charles Ideal Cement Bldg., Denver, Colo. '28 Bowlus. Thomas H. Iola, Ken. '28 Brown, Colvin B. Chamber of Commerce Washington, D. C. '28 Burt, Maxwell Struthers Southern Pines, N. C. '28

Jan 1, 1932

By Steve Kral

The Society for Mining, Metallurgy and Exploration’s origins can be traced back to 1871. This was when 22 Pennsylvania coal mining engineers founded the American Institute of Mining Engineers (AIME). The organization’s objective was to “promote the arts and sciences connected with economic production of the useful minerals and metals, and the welfare of those employed in those industries by all lawful means.” Metallurgy and Petroleum were added to the AIME name in 1919 and 1956, respectively. Divisions of AIME were formed throughout the following years in recognition of the increasing trend toward specialization among mineral industry engineers. At the time, SME’s divisions consisted of the Coal Division (1930, now known as the Coal and Energy Division), the Industrial Minerals Division (1935), the Mineral and Metallurgical Processing Division (1948) and the Mining and Exploration Division (1949). The Environmental Division was created in 1997.

Jan 1, 2007

By C. W. Sherman, J. Chipman, H. I. Elvander

J. F. Elliott—This is an excellent piece of work and makes a chemical metallurgist more enthusiastic than ever about what can be done with multicomponent systems, if we have satisfactory data. I have a remark to make on the interpretation of fig. 5. First, I will comment on the problem of activities in solutions. The iron-sulphur system has in its phase diagram an intermediate solid phase FeS. The occurrence of an intermediate phase is normally associated with negative departures from Raoult's law over a portion of the activity curves in the liquid. (Perhaps it would be better to reserve the phrase "departure from ideality" to departures from Raoult's law line rather than to departures from Henry's law line). Fig. 5 indicates that the deviation of the sulphur activity curve from the Henry's law line is negative;

Jan 1, 1951

By J Zanganeh, M Ajrash, B Moghtaderi

Application of thermal oxidation is considered a promising technique in reducing fugitive methane gas from ventilation air methane (VAM). A typical thermal oxidiser operates with diluted methane and converts it to less potent greenhouse gases. However, having a thermal oxidiser in the vicinity of the coalmine exhaust shaft is a major safety concern as its high operation temperature increases the likelihood of accidental fire and explosion. The aim of this study is to investigate the application and effectiveness of side venting technique in reduction of deflagration consequences caused by methane gas. To address this importance a series of experiments were conducted on a detonation tube designed and fabricated as part of larger scale VAM Abatement safety project. The experimental work was carried out into two stages: examine the flame and explosion properties in a large-scale detonation tube to get reliable data; and then design and employ a venting system into the detonation tube to verify the effectiveness and performance of the venting against the flame and explosion.Results corresponding to this study show that the side vent duct with venting coefficient magnitude of 37 had a significant influence on methane flame deflagration and the explosion characteristics. The maximum pressure rise at the detonation tube reduced approximately 20 per cent to 32 per cent by applying the side venting duct. Also, the data shows that the venting damped the pressure oscillation after the flame deflagration which eventually reduced the system instability. Finally, by applying the venting technique the expected level of damage due to the dynamic pressure reduced to the level of limited building damage.CITATION:Ajrash, M, Zanganeh, J and Moghtaderi, B, 2017. Application of side venting technique in mitigation of methane – air explosion and flame deflagration in ventilation air methane, in Proceedings Australian Mine Vent Conference 2017, pp 153–258 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 28, 2017

By Ian Hutchison, Ted Sluder, Jack Caldwell, Don Moore

Introduction The Cannon mine at Wenatchee, WA has recently been brought into operation to recover gold from the sandstones of the Swauk formation. The mine is a joint venture between Asamera Minerals (US) Inc. and Breakwater Resources. A tailings impoundment was constructed to impound 2.7 to 3.6 Mt (3 to 4 million st) of tailings at 1.8 kt/a (2000 stpd) over about five years. This paper describes the design and construction of the impoundment. In particular, it describes the 100 m (300 ft) high earthfill embankment that is the main feature of the facility. Project environment The project is located on the outskirts of Wenatchee, a town of about 40,000 people. The town is situated on the flat alluvial terraces beside the Columbia River. The Cascade Mountains rise from the terraces in a series of ridges and valleys. The mine is at the foot of the Cascades. The tailings impoundment is in one of the steep valleys. The climate is mild and dry (Table 1). Site selection Twelve alternative sites within a 16-km (10-mile) radius of the mine were examined. Decision making theory was used to select the most suitable site. Advantages of the chosen site include its proximity to the mine and its low visibility from points of common public access. Also, the area was already heavily impacted by an existing silica quarry. The major disadvantage of the site is the need to pump tailings over a distance of 1.5 km (1 mile) and against a static head of 200 m (655 ft). Also, it is located in a gulch just upstream from the town of Wenatchee. Site geology The impoundment is generally underlain by interbedded sandstones and siltstones. The siltstones are often shattered. The sandstones are often friable. Both rock types are extensively jointed. Some isolated faulting of the sediments occurred before the area was covered with basalt flows. About 10,000 years ago, at the end of the ice age, the basalts were covered by 3 to 10 m (10 to 33 ft) of wind blown loess - a fine sandy clay and silt. River deposits filled the base of the valley to depths between 5 and 25 m (16 and 82 ft). Under the main part of the embankment, these materials were removed to expose bedrock. Ground water flow is generally through the more permeable layers. The permanent water table is about 5 m (16 ft) beneath the ground surface. Project and impoundment layout Figure 1 shows the layout of the mine, the mill, and the tailings impoundment. The tailings deliv-

Jan 8, 1986

By R. S. Shoemaker, F. W. McQuiston

The principle of cyanide recovery or regeneration of cyanide from solution, be it a weak wash or a foul solution, is by acidulation. All or part of the cyanogen is converted thereby into hydrogen cyanide which is fixed by an alkali (generally lime) and returned to the cyaniding system (the Mills- Crowe process). The solution is made acid by bringing it into contact with sulfur dioxide. The acidified solution is stripped in a packed tower by a counter flow stream of air in which the air and the solution are brought into intimate contact. The air leaving the tank charged with hydrogen cyanide is then passed to another tank in which it is mixed with an alkaline solution, the latter absorbing the HCN and leaving the accompanying air clean for reuse in removing more HCN from the acidified solutions. Of the recoverable cyanide, 9770 is usually recovered in a three-unit disperser tower system. When there is a considerable content of copper, the solution is made acid following standard procedure; however, the HCN is not removed until the copper is reduced by regeneration. Copper removal at this point may be as high as 90%. After reduction of the copper, the acidified solution then is contacted with a lime solution which brings down calcium sulfate as a second step. The silver, gold, and copper are recovered in the form of a precipitate which can be shipped to a smelter. At the Hudson Bay Mining and Smelting Company, Ltd., most of the precious metals have been recovered in the copper and lead concentrates, but it has been found profitable to submit the flotation tailings to a scavenger cyanide treatment for the recovery of exposed gold contained in pyrite rejected during flotation. Due to the fine particle size, maximum dissolution is achieved in a four-hour contact period. In the cyanidation plant, the thickened flotation tailing at 70% solids is given a four-hour agitation in weak calcium cyanide solution and filtered. Filter cake is repulped and discharged either to the tailing storage area or to the mine as backfill. Clarification, de-aeration and precipitation of pregnant solutions are carried out in a standard Merrill-Crowe unit. Typical analysis of precipitate is as follows: Au, 0.47%, Ag, 4. 88%; Cu, 46.0%; Zn, 13. 8%. Cyanicides in the form of copper minerals limit the reuse of barren solution. To recover the substantial quantities of cyanogen chemically combined with base metals in this solution, a cyanide regeneration plant is in operation. The barren solution is acidified with sulfuric acid in a spray tower where an upward current of air from a blower sweeps the liberated hydrocyanic acid gas to an adsorption unit where it meets a fine rain of lime suspended in plant solution with which it combines to form calcium cyanide. The lime--water solution carrying calcium cyanide is reused in the cyanide circuit. The return gases are drawn into the blower and back to the disperser tower thus

Jan 1, 1975

By T. Rockley, J. Brune

"The mining of tabular deposits accounts for a significant portion of modern production in both underground hard rock and especially, soft rock mining. There is a large discrepancy between the availability of tabular reserves and the amount of development of these deposits, particularly when the deposit has a dip of around 25-50 degrees. This project studied the technical and practical barriers to the mining of these deposits through modern and historical case studies. The primary technical barriers to the development of these deposits are material movement and roof support. The study of historical attempts overcome these barriers and why they failed allowed us to research the possibility of implementing modern technology on previously unsuccessful methods. By modifying some common mining methods, some of these deposits can be mined at only a marginal increase in cost and using readily available equipment. These modified mining methods could make previously underdeveloped deposits to become viable. INTRODUCTION Tabular deposits are defined as orebodies that extend at least hundreds of meters along two dimensions, and a substantially smaller amount along another [1]. Moderately bedded tabular deposits are mined less often than their more horizontal counterparts due to the technical issues they present. These issues often cause lower productivity, higher cost, and more frequent accidents. Moderate dip is a less well defined term; but in this case, it will refer to any deposit which has a dip of at least 20°. This paper will focus on deposits that dip around 25°-50° and are deep enough to require underground excavation methods. These deposits are too steep for most conventional methods yet not steep enough for gravity fed methods to work efficiently. In some cases, this dip range is also referred to as intermediate or steeply dipping. The types of deposits most likely to fall into this category are sedimentary bedded deposits such as coal, trona, evaporates, placers, and other alluvial deposits. Some other types of deposits can fall into this category as well. These include some of the metal reefs such as the Bushveld Complex in South Africa, which was deposited by lava flows, but is tabular. Some areas have dips that fall into the moderately inclined category. There are also some metamorphic deposits such as slate or marble that can have dips of more than 20°. The dip angle of these deposits can cause several challenges. Ore movement becomes more difficult as the exceeds the limits of conventional conveyors, rubber-tired, or tracked vehicles. At the same time the dip is below the angle of repose of the material. This prevents gravity assisted haulage, as the ore and waste will not run downhill by itself. Another common problem in moderately inclined underground mines is roof support. The dip angle can increase the risk of pillar and support failure. This is due to slippage between rock layers, non-perpendicular support of the vertical stresses, and slippage of standing supports. The inclination leads to stresses that are not usually found in typical horizontally bedded deposits. These stresses may require larger pillars that may reduce ore recovery below profitable levels."

Jan 1, 2017

By D. Goossens

Quality control is a system which should guarantee that quality is achieved. It is the execution and verification of a project in an organised way, in order to obtain the maximum of certainty that the results meet the requirements. This concerns all stages of the project, from the soil investigation, over the design, to the execution. Quality control can and has been successfully realised for important projects by means of a quality plan. A quality plan is based on a number of general considerations, but should certainly be focussed on the particularities of a specific project. Practical examples of quality plans, which have been realised on sites in Belgium, are developed and the advantage of the system is shown by concrete case studies.

Jan 1, 1996

By H. O. Hofman

THE leading antimony mineral is stibnite. In smelting stibnite ore two processes are available, precipitation and roasting-reduction. The former is suited only for high-grade ores. As low-grade ores are more common than high-grade, roasting-reduction is of greater importance than precipitation. In the roasting process the aim may be to leave the oxidized antimony in the ore, or it may be to volatilize as much of the antimony as possible, collect the volatilized oxide as a rich intermediary product and smelt it for antimony, leaving the gangue poor enough to be considered a waste product. Whichever way the roast is conducted certain difficulties inherent in stibnite are encountered. These are: 1. The low melting point of stibnite which; according to Pelabon,1 is 550°C., according to Wagemann2 540°C., and according to Borgström3 546°C. 2. The ignition temperature: According to Friedrich,4 stibnite, if heated in air, begins to oxidize at 290°C. if the size of a grain is 0.1 mm. in diameter; at 343°, if 0.1 to 0.2 mm.; and 430° if 0.2 mm. 3. The fusibility of a mixture of Sb2S3 and Sb203 which in the form of kermesite (Sb2S3)2.Sb203 melts at 517°C.5 4. The volatility of Sb2S3 and Sb203, for which no numerical data appear to exist, although practical experience has shown that they are volatile at low temperatures.

Jan 1, 1916

By Nasri Munfah, Steffen Matthei, Vojtech Gall

"Conventional tunneling as defined by ITA WG19 is also known as the New Austrian Tunneling Method (NATM) or Sequential Excavation Method (SEM) was transformed in the US to deal with challenging tunneling conditions as an alternative to the more traditional tunneling methods. It is being used more often in urban areas, under difficult ground and ground water conditions, and with limited cover. Often the tunnel is of a large and non-uniform cross section in soft soils or weak rocks. The intent of using this tunneling method is to minimize impact on traffic and utilities and reduce disruption of everyday life of people and businesses. To meet these challenges, the industry developed technical approaches and implementation techniques and established sophisticated contractual relationships and collaboration in the field among various parties for successful implementation. This paper examines the development of conventional tunneling (NATM/SEM) in the US to deal with these challenges using recent examples such as Russia Wharf in Boston, Northern Boulevard Crossing, in New York, and Chinatown Station in San Francisco. INTRODUCTION / HISTORY Conventional tunneling or NATM/SEM is a concept that is based on the understanding of the behavior of the ground as it reacts to the creation of an underground opening. In its classic form the SEM/NATM attempts to mobilize the self-supporting capability of the ground to an optimum thus achieving economy in ground support. Initially formulated for application in rock tunneling in the early 1960’s, NATM has found application in soft ground in urban tunneling in the late 60’s and has since then enjoyed a broad, international utilization in both rural and urban settings. In the US the NATM/SEM tunneling method has been used successfully to address challenging tunneling conditions in urban areas. A large number of tunnels have been built around the world using a construction approach which was loosely termed NATM. During the years of discussions and the application of NATM a variety of terms have been used for the same construction approach. These terms were primarily aimed at describing the construction approach rather than the region of its reported origin."

Jan 1, 2016

By P. Berendsen

Structures along the rift were subjected to episodic reactivation. Major north-northeast-trending high-angle normal or reverse faults and northwest-trending trans-current fault systems, may exercise control over ore-forming processes. Gabbro and basalt are the dominant igneous rock types. Carbonatite and kimberlite occur in Nebraska and Kansas. Concentrations of Cu, Ni, Co, Ti, Au, Ag and PG-minerals are known to occur in this setting Arkosic sandstone, siltstone, shale and minor carbonate units occur on top of the rift basalts and in flanking basins where they may reach thicknesses of 10 km. The potential for stratiform or unconformity-related metal liferous deposits must be considered.

Jan 1, 1986

By S. T. Wlodek, John Wulff

Dense, adherent, and ductile coatings of chromium can be applied to Molybdenum by selectively freezing out the chromium solute from a supersaturated copper-or tin-rich liquid alloy. The successful exploitation of this technique depends on the control of variables common to any freezing process. Under the most favorable combimtion of supersaturation, nucleation, and mass-transfey, coatings as thick as 0.004 in. can be obtained. In exploratory experiments it was found that a coating of chromium may be applied to molybdenum by immersing the molybdenum body in a supercooled copper-chromium or tin-chromium melt and selectively freezing out the contained chromium onto the molybdenum body. Supercooling of the liquid metal plating bath can be achieved by cooling, or the maintenance of thermal or concentration gradients in the melt. The technique is similar to conventional dip-plating procedures where the sample is immersed in a molten bath of the pure plating medium, except that in these studies, the plating medium consisted of a dilute solution of chromium in liquid tin or copper. The success of this method requires that the base material to be plated be isomorphous with the coating and insoluble in the plating bath. In addition, the plating bath, while having an appreciable solubility for the coating component, must have negligible solid solubility in the solid plate. Such relationships exist in the molybdenum-chromium, chromium-tin, and chromium-copper systems. Liquid tin and copper are satisfactory as the plating solvent, because although chromium is appreciably soluble in both of these liquid metals, solid inter-solubility is almost negligible, and no compound formation occurs. The same relationships exist between molybdenum and copper or tin except that the solubility of molybdenum in liquid tin or copper is insignificant. It is this combination of solubility relationships, as well as the completely isomorphous nature of the molybdenum-chromium system, which allows the formation of a chromium coating on molybdenum by the selective freezing mechanism. Since the main deterrent to the widespread use of molybdenum for high-temperature structural applications is its poor oxidation resistance, the formation of a dense and ductile chromium coating on molybdenum may well be of commercial significance. In addition, the basic principle of coating formation by selective freezing should be applicable to other metallic or even nonmetallic systems. The precipitation of the solute from a liquid metallic solution, for the formation of a protective coating, has not been previously considered in the literature. Frequently, however, a similar phenomenon has been described in the corrosion of metallic heat exchangers by liquid metals1 wherein temperature gradients in the liquid metal heat-transfer medium result in the formation of layers or deposits of metallic residue2 in the cooler portions of the system. Impregnating techniques using liquid baths have been tried as a plating process. Semchyshen and Barr, for instance, have successfully diffused chromium into molybdenum by immersing the molybdenum specimen in a liquid tin-chromium or copper-chromium alloy. This simple holding technique fails to produce a layer of pure chromium and requires prolonged immersion to allow for the diffusion-activated enrichment of the molybdenum. During the course of this investigation, most of the phase relations published for the copper-chromium4 and molybdenum-chromium4 systems, were found reliable. It was necessary, however, to investigate the solubilities of chromium and molybdenum in liquid tin as well as the solubility of molybdenum in liquid copper. These determinations were made by a simpie weight loss technique on materials of the same purity as used in the plating studies. The results of these solubility studies are given in Tables I and I1 and indicate that although the solubility of molybdenum in liquid

Jan 1, 1961