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By R. B. G. Yeo

The effects of alloy additions on the M, and A, temperatures of an Fe-22.5 pct Ni alloy have been determined. Increasing amounts of titanium, colum-bium, vanadium, and silicon raise and then lower M,while raising A, cmtinuously. Cobalt raises both M, and A,. Aluminum has little effect on Ms but raises A,. Chromium md nickel lower M, and A,. It is proposed that elements raise M, in accordance with their effect on the Ae3 temperature of iron until the lattice becomes stiffened against the shear transformation so that M, is then lowered. An anomaly, first pointed out by Zener,1 arises in steels when the addition of elements, such as molybdenum and tungsten, which raise the Ae3 temperature, also lower the M, temperature.2'3 During the development of a series of martensitic precipitation-hardening (maraging) steels, the effect of several elements on the transformation of austenite to martensite was studied. The results show that under suitable conditions several elements which raise Ae3 also raise the M, and A, temperatures. PREPARATION OF MATERIALS STUDIED A series of alloys was made in which cobalt, titanium, columbium, vanadium, silicon, aluminum, molybdenum, chromium, and nickel were added to an iron base containing 22.5 pct Ni. The compositions of the alloys prepared are given in Table I. The residual manganese contents of the heats were in the range of 0.030 to 0.35 pct, silicon 0.05 to 0.1 pct, carbon 0.0008 to 0.009 pct, and nitrogen from 0 to 0.004 uct. The allois were made as 50-lb induction heats starting with electro-iron and electro-nickel, melted in air to oxidize impurities. Additions of silico-manganese and ferro-silicon were made after which the power was turned off to allow the products of deoxidation to rise and be skimmed from the surface of the melt. The furnace chamber was pumped down to a pressure of 5 p and the charge was heated to 2900°F for the addition of other alloying elements. The heats were poured into five 10-lb ingots, making successive alloy additions to each. The ingots were soaked for 2 hr at 2300°F and hot-worked to 3/4-in.-diam bars. This stock was heated to 1500°F for 1

Jan 1, 1963

By Charles Willis

THE problem of the curtailment of forces in large numbers does not often come to employment departments and is, therefore, a problem that many departments are not prepared to handle intelligently. Those companies that are able to measure the individual efficiency of each man would probably lay off men according to their individual ability, irrespective of dependents, citizenship, or other considerations. During the war when labor was scarce, the business of the employment manager in industry was hiring men and carefully placing them where they were best fitted to work. The careful selection of employees had developed to a considerable extent before the war, and was becoming a recognized science. In the last few months, however, the cancellation of copper contracts, the accumulation of large stocks, the necessary curtailment of production because the copper could not be sold, and lack of any immediate prospects of the copper market opening, have led to a universal reduction of forces; and the problem that industry now confronts is that of discharging rather than employing. The problem has been aggravated by the cancelation of contracts in many war industries with the consequent turning loose of hundreds of thousands of men, a great amount of unemployment, and the return of the soldiers and sailors. The problem has now become one of reduction of working force with the least hardship and the least injustice, and yet caring for the returning soldiers, sailors, and marines who have been in the service of the government for nearly 2 years, and who have offered the supreme sacrifice. The Copper Queen Branch of the Phelps Dodge Corpn., operating at Bisbee, Ariz., found it necessary, along with all of the-other copper companies of the country, to reduce its force materially. In making this reduction it was, after due consideration, decided to classify employees with respect to dependents, length of service, and citizenship. The question of individual efficiency or workmanship was not considered. Copper

Jan 9, 1919

By G. B. Gould

THE softening temperature of coal ash, as determined in the labora-tory, has been used for years as an indication of the tendency of coal to form clinker and slag. It has not, however, provided an index of unfail-ing and complete reliability for forecasting the relative performance of different coals, even in the same plant and under the same conditions of operation. A large amount of investigation has been done in attempts to account for this, but practically all of this has been in the direction of studying the chemical constitution of coal ash. Much has been learned, but without much progress toward a better practical application of knowledge to the selection of coal. There has always seemed to be an important factor that eluded discovery. It has long been recognized that the ash-softening temperature as determined in the laboratory had one weakness, in that it represented the temperature at which a thorough mixture of the whole ash of the coal would melt, the mixing having taken place before the heat was applied. This does not, of course, simulate what takes place in practice. With certain exceptions, which will be noted later, almost all of the investiga-tions that have been made, especially the chemical studies of coal ash, have likewise dealt with a mixture of the whole ash in the coal. The present investigation differs from these fundamentally in its approach to the problem. It started from the observation that some clinkering and slagging obviously takes place in a boiler furnace at tem-peratures below the laboratory-determined ash-softening temperature of the coal. Knowing that coal as it is shipped to market is a hetero-geneous mixture of diverse mineral substances, each of which may act independently of the others in the initial stages of clinker and slag formation, it seemed logical to investigate separately the softening tem-perature of the ash in physically separable portions of the coal, and to determine the relative quantities of ash contributed by each portion.

Jan 1, 1940

By D. Bhattacharyya

The adsorption and desorption of gold cyanide by activated carbon is significantly influenced by particle size of the activated carbon particles and the chemical environment. A series of adsorption and elution experiments have been performed with ten different particle size fractions. The tests indicate that although the ultimate adsorption capacity is independent of the activated carbon particle size, the adsorption rate is strongly affected by the particle size. Further, desorption characteristics using traditional Mintek and atmospheric Zadra procedures reveal interesting trends with variation in particle size and will be discussed in this paper.

Feb 23, 2014

By E L. Kotova

Completeness of extraction of a mineral from ore depends on many reasons. First of all it is a function of quality of disintegration of ore. It is supposed that two basic factors: character of structure and texture of the ore aggregate and a disintegration technique influence the quality of the mineral aggregate destruction, æopeningÆ of its internal boundaries. In this paper, the problem of technological mineralogy from the point of view of genesis of the mineral aggregate, its typomorphical features and methods of their quantitative description are discussed. The purpose of this research is to provide information for technologists. It should enable the development of a rational flexible scheme of disintegration of ore with full extraction of a useful component, without its losses and without unnecessary expenses of energy. For achievement of this purpose the mineralogical information should have ½number and a measure+. By the authors, the technique of the quantitative analysis of fabric of the mineral aggregate based on several models û thermodynamic, crystallographic and geometrical is offered and discussed. The leading role in the quantitative analysis of a fabric of ore belongs to internal bounders. But internal bounders of the mineral aggregate by bounders or faces of the mineral individuals or mineral grains are formed. Their geometry, orientation concerning own (mineral grain) crystallographic lattices, orientation and distribution in space of the ore aggregate are proportional to the energy accumulated at origin and the further growth. These characteristics of mineral individuals are consequences of conditions of their formation. That is why the named triad of models is used. From crystallography it is known that faces of different stability and mobility form borders of crystals. They also contain different quantity of energy. Mineral grains also are faceted by different energy borders. They form intergrowths with each other according to a principle of balance or unbalance. That is why in addition to traditional parameters of the description of a fabric of the mineral aggregate (mode and grainmetrical composition) it is necessary to add new. For example, length and the square of intergrowthing bounders of mineral individuals differentiated (in couples), crystallographic symbols of borders, their roughness and so forth. Consequently, solving a problem of the geometrical characteristic of borders, we define also its power characteristic. In this paper experience of application of our technology in studying ores of one of deposits of Urals Mountains is presented. For realisation of these types of the analysis technologies of measurement, the program of calculation and the devices, which are carrying out the analysis in a semi-automatic mode, are possessed. Structure and texture of rock or ore aggregate reflect its formation and transformation conditions. It is important to understand that disintegration energy cannot be more than aggregation energy, the energy of intergrowths formation. The square and orientation of mineral individuals borders vary at pressures or stresses of mineral aggregate evolution. These phenomena often cause selective increase in the square of borders at constant average grain size, ie the granulation. Granulation presents the increase in quantity of mineral individuals while their modal share remains constant. At the same time their average mineral grains size. Some mineral individuals increase in size at increased pressure. When lithostatic or lateral pressure drops the majority of mineral grains increases in volume at the cost of intersticial or film solutions or fine grains. These are only special examples of the ontogenesis of the mineral aggregate. They illustrate our statement that all changes in fabric of the mineral aggregate are a reaction on varying external (ie geological) conditions. It is possible to consider that structurisation of totality of mineral individuals as a whole is a process of adaptation of the mineral aggregate, which forms and exists in varying force and energy fields. Differential and integrated geometry of total internal boundaries of the mineral aggregate serves as adaptation mechanism of the mineral grains system. Boundaries form intergrowths of the mineral aggregate. Thus, it is possible to consider that the most informative parameters of the stereometric analysis for restoration of the ontogenesis of the mineral aggregate are the following. First of all, it is a quantitative estimation of the volumetric shape of the ore mineral in crystallographic coordinates, a total area of borders of all mineral grains in the aggregate, the specific square of their boundaries, the specific square of intergrowth boundaries of the ore mineral separately with grains of each minerals of the matrix of the mineral aggregate as well as traditional grainsmetric and modal composition. For realisation of these types of the analysis technologies of measurement, the program of calculation and the devices that are carrying out the analysis in a semi-automatic mode are possessed.

Jan 1, 2008

By T. Tamagawa

A gaseous chlorination process for hydrometallurgical treatment of a chalcopyrite concentrate was investigated. The overall process is visualized to consist of low temperature chlorination-selective oxidation, followed by aqueous chloride leaching and SX-EW for producing electrolytic copper, elemental sulfur and ferric oxide. In this article, the chlorination phase of the processes is described. Initially, the chlorination behavior of chalcopyrite-concentrate micro-pellets was investigated using a small batch-type fluidized bed reactor. The optimum conditions thereby established was used in continuous chlorination tests. The chlorinated products thus prepared were used in the selective oxidation phase of the investigation.

Jan 1, 1999

By K. T. Cunningham

The Oakfield, New York Hine of the United States Gypsum Company is a shallow, room and pillar mine developed in the Camillus Formation of Silurian Age on the up-dip edge of the northern Appalachian Basin. The gypsum comes to subcrop beneath a variety of glacial materials and is subject to solution activity by groundwater. A geologic environment unfavorable to mining activity is thus created. Since 1978 seismic studies have been used to supplement core drilling to determine a conservative boundary between normal and questionable mining environments. A single channel seismograph, originally in use, is now replaced by a twelve-channel unit and is used to determine bulk material velocity which is the basis for defining the mining limit.

Jan 1, 1987

By H. E. Powell

The magnetic susceptibilities of 57 minerals containing titanium, zirconium, vanadium, columbium, tantalum, chromium, molybdenum, and tungsten were determined. The source and petrographic analysis of each sample are given. Included are values for isomorphous series of minerals showing wide ranges of composition and for a few high-purity synthetic minerals.

Jan 1, 1968

By R. E. Sundell, S. M. Correa

"A mathematical model is developed for the fluid flow in tungsten-inert gas weld pools. The fluid is taken to be incompressible, viscous, electrically conducting, and confined within a pool of specified shape. The flow is driven by surface-tension gradient (thermocapillary), electromagnetic, and buoyancy forces generally in this order of importance. Analysis indicates that the electromagnetic field may be calculated a priori and so decoupled from the nonlinear fluid mechanics and heat-transfer problem. The resulting set of equations is solved numerically by a line relaxation process. Computational errors caused by truncation in finite-difference schemes and by inadequate grid distributions are considered. The model is used to study several cases of differing heat and current input to the pool with and without surfactant-induced thermocapillary forces. The principal conclusions are that the thermocapillary flow, when present, is dominant with surface velocities on the order of 1 m/s. The heat transfer, as deduced from isotherms within the pool, is crucially dependent on the flow. Also, flow velocities and weld-pool surface temperatures were measuredand agree well with the model.2. IntroductionThe requirements of improved control and of automation in the TIG (tungsten-inert gas) welding process have led to the development of mathematical models for the heat transfer to the workpiece. It is now widely recognized that the fluid flow in weld pools sufficiently distorts the conduction heat transfer pattern to warrant inclusion in a process model. The experiments of Woods and Milner (1), among others, demonstrated that TIG weld pools could be driven by the electromagnetic J x B body forces present, J being the current distribution and B the induced magnetic field. Atthey (2) calculated that in typical pools the buoyancy force was about an order of magnitude less important - despite the large temperature gradients present - and neglected it in a computational study of the magnetohydrodynamic (MHD) flow. This work also reviewed many earlier studies of MHD flow caused by a source of current at a fluid surface, including analytical studies by Shercliffe (3), Sozou (4), and Sozou and Pickering (5), and a numerical study by Andrews and Craine (6). These works establish the importance of the electromagnetic force in the weld-pool flow."

Jan 1, 1986

By F. Reich, S. L. Chryssoulis, K. G. Stowe

The surface chemistry of particulates from mineral processing streams can be determined by laser-probe microanalysis. The small area of analysis (2-30 micrometres) enables the surfaces of individual grains to be characterised. Conclusions are based on data acquired from a statistically significant number of grains of a given type. Maps showing the distribution of elements on the surface of mineral particulates can be obtained by time-of-flight secondary ion mass spectrometry. The importance of such analyses in understanding the response of minerals to beneficiation practices is discussed with reference to three examples. The first relates to the loss of selectivity in the differential flotation of a base-metal ore, the second to the different flotabilities of coarse- and fine-grained pentlandite from a Cu-Ni ore and the third concerns the preg-robbing effects of organic matter in a carbonaceous gold ore.

Jan 4, 1992

By Seung Han Kim, Andrew Yu, Carlos Jaramillo, Chu-Chieh Jay Lin

The Penstock Access Tunnel (PAT) concrete plug is a reinforced concrete plug separating the pressure tunnels from the personnel accessible tunnels and has leaked since the first filling at the Helms Pumped Storage Plant located in Fresno County, California. A grouting program was successfully implemented in 2009 to reduce the leakage from PAT concrete plug from over 1,000 gpm to 25 gpm. Recent observations indicated increasing water leakage through new pathways, leading to a decision to execute a high-pressure grouting and waterproof membrane installation program in 2017. The high-pressure grouting and membrane installation program was successfully executed in the areas adjacent to the PAT concrete plug where most of the inflows originated and the largest hydraulic gradients are suspected to present. It reduced the leakage from over 300 gpm of inflow to less than 20 gpm.

Jun 13, 2021

By R. L. Smith, J. L. Rutherford

ALTHOUGH considerable effort has been devoted toward the determination of the mechanical properties of pure metals, it is extremely difficult to compare the results of such work. This is because of differences in method and type of test, grain size, heat treatment, and purity of material. There is very little information on the properties of most of the high melting point reactive metals with purities greater than 99.9 pct. Previous evidence concerning the tensile properties of unalloyed metals show that: body-centered-cubic metals are brittle at low temperatures; face-centered-cubic metals remain ductile; some hexagonal metals remain ductile, others become brittle. It may be that traces of impurities decrease the low temperature ductility of the body-centered-cubic lattice. This would suppose that a body-centered-cubic lattice free from impurities would exhibit nearly the same ductility as a face-centered-cubic structure. The present investigation has been an evaluation of the tensile properties of zone refined iron in order to determine whether higher purity material than that previously evaluated behaves differently. Experimental Procedure In this investigation, high purity iron was zone purified using the floating zone method.' The starting stock was obtained from two sources. The first,

Jan 1, 1958

By R. David Prenganan

RSR has developed a new environmentally superior process to recover lead as high purity electn:1o'i0!1 cathode from battery scrap. The process involves crushing the batteries, separating the lead bearing material from the plastic, ebonite and separators, and separating the active material (paste) from the metallic lead fraction. The paste is desulfurized using Na2C03 to convert the PbS04 to PbC03 and produce a sodium sulfate solution. The paste is further treated to decompose the PbO2 and PbC03 to Pbo. The PbO from the treated paste is easily leached, using H2SiF6 and electrown from solution using Pbo2?coated graphite anodes. The electrown lead has a purity exceeding 99.99%. RSR is in the final design stages of a plant to produce 36,000 tons per year of electrcwon cathode from battery paste in a new plant adjacent to the present Indianapolis refinery. This paper describes the work of a pilot facility operated in the early 1980's. The paper describes the patented process in detail and compares the newly designed environmentally clean electrolytic plant to present recycling plants.

Jan 1, 1990

By Eugene R. Rice

There are many methods for determining the meridian, but all of those in common use involve at least two separate observations, one for latitude and one for azimuth. Such observations made upon a south star at any hour are open to the objection of possible inaccuracy due to ignorance of the absolute refraction, and also to slow change in the altitude of the star when near the meridian. The method of observing a circum-polar star at elongation. besides requiring a separate observation for latitude, is open to the serious objection that clouds may obscure the star at the critical moment. Moreover, a tedious wait for the star to come to elongation is sometimes necessary. Many of us can recall 'long, cold, weary vigils, waiting for Polaris to reach elongation. For observing a circumpolar star at any hour, not only the latitude, but also the true time, must be known. This it is practically impossible to obtain, except in regions reached by the telegraph, and usually then one has to know the longitude also, in order to reduce " standard time" to " local time." The results obtained by this method, when the star is at culmination, are not very good, unless the true local time is absolutely known. The methods of obtaining the nleridian from the sun, by means of a solar attachment, or by direct observation, while good, are not absolute, by reason of refraction, change in declination of the sun, and small change in vertical angle, when the sun is near the meridian. For these two methods, latitude, time, and approximate longitude have to be known. In the method here described, only one observation is needed, and from it are computed azimuth, latitude, aud sidereal time. In other words, one call observe a circumpolar star—Polaris

Jan 1, 1911

By Neil Smith

Mineral processing plants typically procure a range of industrial services from contractors. Their satisfaction and value received is directly affected by how the services are procured, rationalized and delivered. Conventional purchasing strategies often focus on price rather than on optimizing the service relationship between supplier and customer. The nature of this relationship may have the greatest potential to reduce costs and enhance production. It has been documented that a service involves simultaneous production and consumption. A high degree of customer involvement is often necessary for a successful outcome and the expectations and attitudes of the customer can positively or negatively affect delivery of the service. This indicates that the customer can enhance or diminish their own satisfaction and value received and the supplier cannot act alone for best results. The Optimax? Program for industrial services is a service delivery framework whereby a customer and supplier work together to raise the efficiency of the service exchange. The Optimax? Program is intended to help the customer optimize costs and maximize production by connecting the customer and supplier through shared information and objectives. This paper will review the basic nature of services, provide a couple of examples of conventional procurement strategies for services and outline the features of the Optimax? Program. A Case Study showing recent results from implementing the Optimax? Program will be included.

Jan 1, 2006

By Raymond A. Binns

Exploration for undersea polymetallic sulfide mineral resources with high economic potential would be more effective given an ability to predict sites with particularly high gold contents (averaging say > 10 ppm Au). Herzig et al (1993) addressed this issue shortly after recognition that deposits in the back-arc Lau Basin (average 3.8 ppm Au) were enriched in gold relative to mid-ocean ridge sites (average 1.2 ppm Au). Small but significant numbers of hydrothermal sites with massive sulfide deposits averaging >10 ppm Au have since been discovered. The principal genetic factors underlying gold enrichment include depositional processes at and below the seabed, and the source of gold. It is timely to consider whether resolution of their relative importance can be translated into practical criteria for exploration strategies focused on especially gold-rich deposits. Comparing the ?grade? of seafloor deposits using analyses cited in research papers is fraught with difficulty, but there is no alternative at present to assuming that such averages provide an initial tenor guide. On this basis, four known polymetallic hydrothermal sites from convergent plate margins fit the exceptional-gold category with >10 ppm ?average? Au, while one from a divergent margin comes close: Sunrise (Myojin Knolls; 20 ppm ?average? Au) and Suiyo Seamount (28 ppm Au) in the Izu-Bonin Arc are frontal arc volcanoes dominated by rhyolite and dacite respectively, contrasting with more common mafic neighbor edifices (Iizasa et al., 1999). In both cases gold-rich massive sulfides occur in summit calderas with significant development of pumiceous volcaniclastic rocks, at depths around 1300 and 1370 m respectively. In the Eastern Manus Basin, PACMANUS (~1700 m; 14 ppm Au) and Suzette (~1550 m; 22 ppm Au) occur along the crests of volcanic ridges dominated by dacite/rhyodacite and andesite/mafic dacite respectively (Binns, 2004). Caldera structures are lacking. Although the Eastern Manus Basin is tectonically a rifted back-arc, its submarine volcanic edifices (picritic basalt to rhyodacite) have distinctly arc-style geochemical and isotopic affinities, differing from more typical back-arc basin basalts at the spreading axis further west (central Manus Basin). Probably as a consequence of transpression and a marked rupture in the New Britain subduction zone, submarine arc volcanism has here extended into the rifted back-arc region.

Jan 1, 2005

Scattered north and south along a 161-km (100-mile) stretch of Interstate 80, Newmont Min¬ing Corp. owns four active mining properties in Nevada?s northern high desert ? Carlin Trend Operations, Midas, Twin Creeks and Phoenix. Among the four, there are nine openpits, five underground mines and 14 processing facilities. While gold is the predominant ore, silver and copper are also produced. And in a move to hold down energy costs, Newmont built and owns the 200-MW (net), coal-fired TS power plant. This plant provides about 65 percent of the power used for Newmont?s own operations, while the rest is sold to NV Energy, which services Nevada and northeastern California. Bringing the Phoenix Mine ? Newmont?s newest in Nevada ? on-line presented many developmental and operational challenges. Located about 19 km (12 miles) southwest of the town of Battle Mountain, the general area had been home to prospectors and other mining companies since the 1860s. But any profitability in developing the lower grade gold, copper and silver deposit at Phoenix proved elusive, with Battle Mountain Gold being the last company to make an attempt. When Newmont acquired Battle Mountain Gold and its Phoenix reserves in 2001, the lower grade of ore was not a deterrent. Newmont found Nevada-wide cost savings synergies for maximizing profit during the depressed gold market of the late 1990s. The new property was aptly renamed the Phoenix Mine, a nod to its rising from the ashes of the dreams and efforts of previous mine owners.

Jan 2, 2010

By R. Frank Chiappetta

A new blasting technique has been developed by International Technologies, LLC. to eliminate subgrade drilling, lower ground vibrations, improve fragmentation and reduce explosive consumption. The new technique utilizes a uniquely designed borehole plug, with a bottom hole air deck and a predetermined stemming mass on top of the plug. This combination is referred to as the Power Deck?. Single holes and full scale tests were conducted by Blasting Analysis International, Inc. (BAI) to determine how the system works, the mechanisms behind its success and the best design parameters to use for the given rock conditions. Results have shown reduced or eliminated subgrade drilling, ground vibration reductions of up to 33%, reduced explosive consumption by 16 to 25%, and improved fragmentation by up to 25%. This paper summarizes the methodology, field test setups, analyzes procedures and results for one series of single hole and full-scale tests which were performed in a Pennsylvania, USA quarry.

Jan 1, 2004

By David Dardick

Tround International Inc. is developing rock excavation and drilling devices which utilize a simple patented mechanism for firing frangible projectiles. This system launches a salvo of three projectiles with every shot in automatic sequence. Studies conducted by Physics International Inc. have demonstrated that firing projectiles into hard rock such as granite creates fragmentation which is much faster and cheaper than conventional drilling and blasting. The Tround salvo approach enhances this further by a controlled stresswave interaction created by a slight time difference during impact of the individual projectiles. The University of Maryland is conducting additional studies to optimize these parameters.

Jan 1, 1981

By Wen-Ming Chien

Keywords: AN-KN Phase Transition, Lattice Parameters of AN-KN, X-ray Diffraction The lattice parameters of the low and high temperature phase of KNO3-rich (in NH4NO3) solid solutions have been determined by the X-ray diffraction method. The low temperature single KNO3 phase (KN II) are from 92%-100% KNO3 in NH4NO3 composition range and from room temperature to 393 K showing in X-ray diffraction patterns. The high temperature KNO3 phase (KN I) showed very broad composition range between 20% to 100% KNO3. The lattice parameters of KNO3-rich (KN II and KN I) solid solutions have been calculated at different temperature range. The volumes of orthorhombic KN II phase decrease from 0.3208(3) to 0.3195(3) nm³ at the room temperature as the compositions increase from 95% to 100% KNO3. The lattice constants of the hexagonal KN I phase show that there is no significant change in a-direction when the temperature increases. Details X-ray results and lattice expansion equations during heating will be presented.

Jan 1, 2005