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By E. M. Tignor

A research program to aid development of improved methods for increased production of petroleum from partly depleted reservoirs is a vital part of the Bureau of Mines effort to effect true conservation of that mineral resource. This report presents results of an investigation to identify the clay minerals within some Appalachian petroleum-reservoir sands, the effect of clay content on the fluid-flow behavior of those sands, and the use of brines in water-flooding operations. Permeability measurements using kerosine, calcium chloride brine, simulated oilfield brine, potassium chloride brine, sodium chloride brine, and distilled water were made on reservoir-rock cores. Clay fractions were separated from sand grains of disaggregated portions of each core sample, and the clay minerals were identified by the differential thermal analysis method. Relations of the permeability to various fluids were developed.

Jan 1, 1957

By J. Richard Tonry

In portland cement manufacturing, the raw materials axe changed to clinker in the burning operation. Generally the rotary kiln is used for this purpose and involves many processes, including pelletizing and nodelizing. This transformation is called clinkering, and is analyzed as now generally practiced in cement making, from the raw material to the resulting clinker.

Jan 1, 1963

By Tainan Ferreira Muniz

O presente trabalho estudou a influência de alguns tratamentos térmicos sobre a microestrutura e as propriedades mecânicas de um aço microligado visando à adequação de parâmetros que o classifiquem como um ao do tipo API X65 paraaplicação na prospecção e condução de óleo e gás. Diferentes ciclos de tratamentos térmicos envolvendo normalização, têmpera e revenimento foram aplicados a amostras deste aço. Estas foram submetidas a ensaios de tração, dureza Vickers e impacto Charpy, além de terem sido microestruturalmente caracterizadas com o auxílio de microscopia ótica e eletrônica de varredura. Observou-se que as microestruturas e propriedades mecânicas foram fortemente influenciadas pelos tratamentos estudados. Entretanto, apenas a amostra temperada e revenida atendeu integralmente aosrequisitos para o grau API X65no que diz respeito às propriedades mecânicas.Estaamostratambémapresentou maior a tenacidade ao impacto, o que está associado ao alívio de tensões e à decomposição da martensitae da bainita em carbonetos de ferro e ferrita. A amostra normalizada apresentou microestrutura constituída por perlita e ferrita, possuindo assim os menores limites de resistência mecânica e a maior ductilidade. Já nas espécies normalizada-temperada, assim como na simplesmente temperada, observou-semartensita e bainitacomo principais constituintes, supondo-se a presença de uma pequena fração de constituinte MA.

Aug 16, 2017

By Ross W. Whipple

Applying geophysical techniques in potential geothermal areas has received: little attention in the United States, though it is widely used and accepted in New Zealand and Italy. In those countries it has been demonstrated that geophysical surveys can be useful in locating new geothermal areas and in directing test drilling programs. Geophysical studies in a thermal region can provide structural information and, if conditions are right directly; locate subsurface hot waters. They can give indications of sub-alluvial rock types and of the thickness of alluvial cover. In certain cases they can be used to estimate the power potential of a hydrothermal system.

Jan 1, 1963

By O. Terichow

A pendulum sclerometer designed by the Bureau of Mines is described. Its method of operation is given, along with the results of tests made on representative mineral samples of Mohs' hardness scale to determine the applicability of the device for research on rock testing. The sclerometer hardness values obtained from the tests indicated that reproducibility and accuracy were good. A quantitative comparison of the pendulum hardness values with microhardness and surface energy values published by other investigators showed good agreement on minerals with Mohs' hardness numbers of 2 to 9.

Jan 1, 1967

By R. H. Lien

The Bureau of Mines investigated nitrous oxide (N20) stability when used as a solvent for organic removal from metal powder surfaces. Both supercritical and subcritical conditions were studied. This investigation was prompted by the occurrence of a violent reaction when supercritical N20 was being used to deoil a metal powder grinding waste sample that contained 20 to 25 wt pct cutting oil. Tests were conducted to determine the cause of the reaction and to define stability limits. Test data showed that the waste's oil fraction reacted violently with N20 acting as an oxidizer; the metal powder acted as a promoter to reduce the ignition temperature. Although the data were scattered, this temperature appeared to reach a minimum at a certain pressure (dependent on vessel and sample size). The minimum ignition temperature for a 0.64-g sample in a 72-cm3 vessel was 360° C at 200 psig. As the sample size increased, the ignition temperature decreased. For example, when the sample size was increased to 10 g, a reaction occurred at 240° C and 600 psig. Because of the variability of ignition temperature with pressure and sample size, safe operating conditions were not established. Overall, this research showed that extreme caution should be exercised when using N20 in an organic or organic-metal system.

Jan 1, 2011

By J. B. Newkirk, A. H. Geisler

The alloy Cu4Pd has a disordered face-centered-cubic structure when quenched from temperatures between 478ºC and the melting point (about 1100°C). Below 478ºC an ordered phase is stable. The results of a Debye-Scherrer X-ray analysis indicate that the ordered phase has a tetragonal unit cell described by the space group C24h — P42/mt with 2 Cu in 2a, 2 Cu in 2f, 4 Cu in 4j (x = 0.2, y = 0.6), 4Pd in 4j (x = 0.4, y = 0.2), and 8 Cu in 8k (x = 0.1, y = 0.3). The orientation relationship between the face-centered-cubic phase and the ordered tetragonal phase is given by: [100],,. // [130]al,. COO1Ia.d.//COO1I,,.. • The behavior of Cu,Pd is typical of ordering alloys except that the transformation is very sluggish. The increase in hardness and the microstructural and X-ray diffraction effects are interpreted in terms of coherency strains caused by the ordering. AN anomalous construction in the Cu-Pd phase diagram (Fig. 1) was reported in 1939 and has been allowed to stand without further published attention since that time. The odd figuration about the composition 10 to 27 atomic pct Pd is derived mostly from the work of Jones and Sykes.1 Evidently several features of this binary system require further study if the constitutional forms are to be well understood. The present paper includes a study of one of these features, that is, the crystal structure of a single ordered alloy containing nominally 20 atomic pct Pd. This choice of composition was suggested by the work of Harker and associates who determined the structure of Ni4Mo2 and Ni4W.3 The nature of the ordering process in Cu4Pd was studied also by observing the hardness, microstructure, and Debye-Scherrer patterns of specimens which had been aged at various temperatures after quenching from an initial disordering treatment. Experimental Methods A 20 gram ingot of Cu4Pd was made by melting spectrographically standardized copper from Johnson, Matthey, and Co., and commercially pure (99.5 + ) palladium in an argon-filled quartz tube. Chemical analysis showed that the ingot contained 80.0 atomic pct Cu. The ingot was rolled about 60 pct to a strip 0.060 in. thick and was homogenized for 16 hr at 950°C in low pressure argon. Rods cut from the rolled strip were worked into wire 0.015 in. in diameter, and specimens for hardness and microscopic examination were cut from the remaining strip. All specimens, with the exception of some of the wire, were given an initial disordering treatment by heating for 16 hr at 950°C, followed by water quenching. A 10 cm length of as-drawn wire was water quenched after being held in a temperature-gradient furnace4 for 89 days. Room-temperature Debye-Scherrer photograms were then made at points along the wire to determine the temperature below which the ordered phase was stable. Although the accuracy of temperature determination in the gradient was only about ±10 °C, the temperature gradient was sufficiently gradual that the sensitivity was much better and locations which had differed by as little as 1°C could be distinguished. An analysis of the crystal structure of the well ordered alloy was made by X-ray diffraction using a specimen cut from this wire. The change of Debye-Scherrer pattern as ordering progressed was studied by using isothermally aged samples of initially disordered wires. The wires were sealed under low-pressure argon in small quartz tubes for heat treatment. After the aging treatment, the tubes were quenched in water and photograms were made at room temperature in a 10 cm diam camera using filtered Cu kX. (A = 1.540511) Hardness was measured on a Vickers hardness tester using a 10 kg load and 2/3 in. objective lens. Reported values are the average of at least three impressions made on flat specimens 0.060 in. thick. After the hardness of a heat-treated sample had been measured, it was resealed in low-pressure argon and returned to the furnace for continued aging at the same temperature. In this way, two samples served for all aging times at each temperature. Hardness specimens which had been aged 500 hr or more were used for metallographic examination after the final aging treatment. A dilute potassium-dichromate etching solution was used.

Jan 1, 1955

By Eleazar Salinas R., Miguel Perez L., J. Cesar Juarez T., Martin Reyes P., Eduardo Cerecedo S., Isauro Rivera L., Francisco Patino C., Juan Hernández A.

"A complete characterization of burrows from Mining district of Pachuca - Real del Monte, in Hidalgo state Mexico, was done. These kind of residues had not been formally characterized, founding an average chemical composition of 70.43 % wt. of Si02, 7.032 % wt. of Ah03, 2.69 % wt. of Fe20 3, 0.70 % wt. of Mn, 3.98 % wt. ofK20, 3.34 % wt. of CaO, 2.50 % wt. ofNa20, 1.01 % wt. of MgO, 0.26 % wt. of Ti02, 0.04 % wt. of Zn, 0.026 % wt. of Pb, 56 g/ton of Ag and 0.6 g/ton of Au; In the same way, the residues present as majority mineralogical phases the following: Quartz, Berlinite, Orthoclase, Feldspar, Anorthoclase and Calcite. By the other hand, joint with the big volume that present these residues and the chemical and mineralogical characteristics, these materials or sub - products can be used for production of ceramics, into mixes forming some materials for architecture (bricks, blocks, and tiles), refractory bricks, in the production of cement and to get some metallic values such as gold and silver involved in these residues.IntroductionActually the mining residues in Hidalgo State, Mexico are the result of more tan 500 years of mining, leading so a great volume of deposits, which we can classify in different types, among the most communes we have: Acid Mining Waters, Waters of solid transport and elements in the form of radicals, deposits of abandoned minerals without processing, and mining wastes of processed minerals known as burrows or dumps, being these the most abundant in the Hidalgo State [1-4].Form the metallurgical point of view, it is known that a characterization study if fundamental to find the viability of reuse of these kind of residues, leading so an additional use and the opportunity of get an alternative use into several industrial processes, due to its contents of oxides of silicon, iron, aluminum, calcium, sodium and potassium, principally, besides of its mineralogy and distribution of chemical elements into its primary and secondary phases [ 1-2, 5- 6]."

Jan 1, 2011

By L. M. . Chia

The successful treatment of waste materials to recover metals with acceptable purity is often hampered by the presence of undesirable impurities. The problem is further complicated by the need to insure that any residues or solutions generated are environmentally acceptable. Hydrometallurgical processes involving leaching- solvent extraction-electrowinning offer some attractive features which address many of these problems. However, in certain instances trace impurities that contaminate the organics are difficult to chemically strip and interfere with the overall process efficiency. A new processing scheme has been developed which appears to provide some attractive alternatives for impurity removal from organics. It has been shown that many ionic impurities can be electrochemically removed from the organic by spontaneous direct reduction using solid metals. A variety of metal ion impurities have been removed from selected common organic extractants such as D2EHPA and TBP using different metals as the reducing agents. The results and probable mechanisms involved in the reactions are discussed.

Jan 1, 1994

By R. Luchese de Moraes, J. A. Matthews, C. Feliciano Bruzual

The role of biomass char in blast furnaces has been re-examined by scientists worldwide, as a feasible option to reduce the carbon intensity of ironmaking. This contribution makes a technical and economic analysis of the ferro gusa industry in Brazil, with the last 172 charcoal-Blast Furnaces operating in the world. A key strategic question is presented: what is the current status and future prospects of biomass use in Blast Furnaces? Findings provide significant implications to metallurgists: while ferro gusa from charcoal is regarded as carbon neutral iron with low impurities, there are limiting factors that hinder the further proliferation of charcoal-BFs: biomass generation requires vast extensions of arable land and aggregates have low production capacity. Additionally, most of the charcoal is presently generated in beehive kilns with low yields. These elements combined make charcoal-hot metal expensive in price. With respect to the future prospects of biomass, the injection of small biochar particles through the PCI rigs in BFs (here coined Bio-PCI) and iron ore sintering may offer a practical alternative to significantly reduce the CO2 emissions in the ironmaking process.

Jan 1, 2015

By F. S. Crawford

Interesting data on electric blasting and sinking of the Montreal No. 5 shaft of the Montreal Mining Co., Montreal, Wis., were obtained during the sinking of the last 877 feet of this shaft. Several unusual features and safety practices are also to be found in the Montreal mine. The Montreal shaft was sunk 2,156 feet from August 16, 1921, to May 1, 1924, and 877 feet from October, 1927, to June, 1928. The first section of the shaft was supported with steel sets spaced 5 feet on centers; and instead of lagging the walls were covered with three-eighths of an inch of gunite where Greenstone was encountered, and where quartz-slate was found (from the surface to the 12th level) the walls were lagged with tamarack lath treated with carbolineum, a preservative.

Jan 1, 1929

By Tuncel M. Yegulalp

This article summarizes some of the results of the continuing research activity at the Henry Krumb School of Mines, Columbia University, directed towards a better understanding of the stochastic behavior of slurry flows in underground coal-slurry pipeline systems. The slurry system under consideration here replaces all conventional haulage systems between the coal face and the coal preparation plant on the surface. At the beginning of the pipeline system, flow rate and frequency of coal slurry is very closely related to the activities of production equipment at the coal face. Due to several scheduled and unscheduled interruptions in continuous miner's coal mining activity, resulting slurry flows possess stochastic characteristics. Proper understanding of these characteristics is believed to lead to a more realissic and economic design of slurry handling equipment. Fundamental ideas supported by field observations are presented and a Semi-Markov model of the slurry flows is developed. As a result of this formulation, behavior of combined slurry flows from N independent coal faces can be expressed in analytical form. The contents of a slurry surge tank receiving slurry flows with certain stochastic characteristics is investigated as a function of discharge pump characteristics and time.

Jan 1, 1981

By A. M. Raichur, S. P. Vijayalakshmi

Fine coal dewatering is a major problem in the coal industry because the fines hold significant amounts of water and account for two-thirds of the product surface moisture. Present methods include flocculation using polymeric flocculants followed by filtration. But the kinetics of filtration are not favorable with such flocculants. In this study, a novel method involving flocculation with microorganisms for improving the settling rates and dewatering kinetics has been investigated. Two Gram-positive microorganisms, Mycobacterium phlei and Bacillus subtilis were used as bioflocculants. The effect of time, pH and ionic strength of the electrolyte used on adhesion and flocculation were studied. Adhesion tests showed that maximum adsorption occurred in 20 minutes in the pH range of 2-7 and the total amount of bacteria adsorbed was almost the same with both the flocculants. Nearly 98% of the coal flocculated with both the microorganisms in about 5 minutes. The filtration rate of fine coal almost doubled with addition of bacteria and electrolyte and maximum filtration occurred near the point-of-zero-charge of the bacteria.

Jan 1, 2003

By M. G. Stamatakis, C. Zagouroglou, C. Helvaci, J. Kanaris

"Abstract -Borate minerals, such as colemanite, ulexite and borax, have been reported in Tertiary continental basins of West Anatolia, Turkey, and Samos Island, Greece.Tuffaceous rocks interbedded with the borates are rich in authigenic silicate minerals such as zeolites, potassium feldspar and opal-CT, all of which have a genetic association with the borates. Chemical analyses of the tuffaceous rocks show variation in major elements due to the varying percentage of carbonaceous, detrital, and volcanic derived material.The volcanic activity in the vicinity of each particular lacustrine basin created ion-rich fluids from which a series of borates were precipitated under arid climate. Additionally, the saline-alkaline character of these fluids was responsible for the diagenesis of the silicic glass of the tuffaceous rocks, altering them to silicates and silica polymorphs."

Jan 1, 1993

By Harry J. Cain

Introduction The property of Pioneer Gold Mines of B. C., Limited, is located in the Lillooet mining district of British Columbia, on Cadwallader creek, 54 miles distant by motor road from Shalalth, a station on the Pacific Great Eastern railway. Milling by the present Company was commenced in 1924, a small amalgamation plant, consisting of a crusher, Bryan mill, and plates being operated until 1928. Tailing from this plant was impounded and later treated in the 100-ton continuous counter-current decantation cyanide plant which was erected during 1927-28 and placed in operation during May of 1928. A second cyanide plant, employing continuous counter-current decantation, having a nominal capacity of 200 tons, has been erected during the past few months and was put into operation during September of the present year. The ultimate capacity of the combined units of the present mill has not been determined, but it is expected to be much in excess of the rated capacity. The Ore The ore, as received at the mill, consists chiefly of quartz carrying free gold, with small amounts of pyrite, arsenopyrite, and pyrrhotite in evidence, though probably amounting to less than one per cent of the total. Some gold is very closely associated with the sulphides. The country rock is a basic igneous rock, probably an augite diorite. Near the vein it is highly altered to sericite, which slimes readily on grinding, and does not settle very well. The quartz is of two types, clear and ribbon. In the latter, the ribbons, which are not much thicker than paper, consist of shattered sulphides. In crushing this ribbon quartz, breakage is often along the streaks, exposing these shattered faces to advantage in subsequent treatment. While gold is the metal for which the ore is mined, some silver is also present and is paid for by the mint. It is, however, unimportant from a commercial viewpoint. From the standpoint of crushing and grinding, the ore might be termed 'medium 'hard'.

Jan 1, 1932

By William C. Marshall, Frank G. Norris

THE term "total operation" is meant to include problems that cannot be answered from the standpoint of either the blast furnace or the open hearth separately but must be studied by considering the interrelations of these two processes. There are other ways of expressing this idea, such as reference to the blast furnace and the open hearth as an integrated process or by emphasizing the interrelation and interaction of the two processes. Much progress has been made in metallurgy and other fields by breaking complicated processes and reactions into simpler parts and studying each of these intensively. This intensive study frequently is done under the controlled conditions of the laboratory experiment. The entire process is understood better by this specialized study of each of its parts. This procedure is so satisfactory that an understanding of unit operations is a fundamental requirement of chemical engineering. Much discussion of the open-hearth process is in terms of one heat or one furnace. By this is meant that the conclusions apply to one furnace, wherever it may be. Furnaces seldom occur singly; they are located in groups and these groups are located in steel plants having characteristic blast-furnace equipment. Problems that are affected by the number of furnaces operating, by the number of blast furnaces in the plant and by the fact that the open hearth shop is dependent on the blast-furnace capacity rather than on its own needs for the amount of iron available are among those which, in contrast to "unit operations," we have chosen to call "total operations," Many of these problems, such as charging delays and the general mechanical problem of material handling, are so familiar that merely to define "total operations" brings them to mind. These problems are of such importance that already they have received careful thought and study and probably will merit further study. As will be shown later, these mechanical problems are so intimately related to metallurgical problems of total operations that the effect of certain changes cannot be ascribed with certainty to either a mechanical or a metallurgical cause entirely. Although the problems coming under the general term of "railroading" are included in the problems of total operations, two others are selected for the discussion of this paper. One of these is strictly a problem of composition; the other is strictly a problem of tonnage production. The problem of phosphorus is present whenever basic open-hearth slag is used in the blast-furnace burden. This practice has not secured universal acceptance chiefly because of difference in preference for high-manganese or low-manganese pig iron. If high-manganese (2.00 per cent) iron is to be made, open-hearth slag as a source of manganese is usually cheaper than man

Jan 1, 1943

By BARRY BANNATYNE

Gypsum in Manitoba is quarried from the Jurassic Amaranth Formation a1 Gypsumville and Harcus; it has been mined near Amaranth and Silver Plains. At Gypsumville, gypsum is carbonate- free but has thin clay laminae between gypsum layers; the rock is folded in places, and some anhydrite is present. At Harcus, gypsum contains scattered dolomite, both as patches in a penemosaic pattern and as thin layers; small chalcedonic concretions also can be found. The quarry at Harcus was opened late in 1978 and currently produces about 100,000 tonnes annually. The two inactive mines near Amaranth operated from 1932 lo 1963 and from 1967 to 1970, and contain a central anhydrite layer. The mine near Silver Plains was flooded from an underlying artesian aquifer in 1975 and has not been reopened. Manitoba gypsum is used in cemem plants in Mani1oba and Saskatchewan and in wallboard plants in the three Prairie Provinces.

Jan 1, 1984

By Sadtler, C. B.

IT is generally assumed that in most metals and alloys a given tensile stress produces a given deformation irrespective of the length of time during which the stress is applied. This assumption is justified in most of the important engineering applications of metallic materials; however, in the case of some metals and alloys used or tested at temperatures over or slightly under that at which recrystallization can occur the assumption is not warranted.1 This paper deals with the variations of deformation produced by a constant tensile stress acting for varied lengths of time in the special case of thin aluminum alloy sheet of the duralumin type, which had been subjected to different thermal and mechanical treatments. The material investigated was in the form of a sheet approximately 0.002 in. thick, which had been cold-rolled from a thickness of 0.020 in. It has been found that at a sufficiently high constant tension such material deforms continuously with the elapse of time and that the rate at which this deformation occurs is greatly influenced by the previous thermal and mechanical treatments.

Jan 1, 1927

By Yue Tian, Shengqian Wang, Lifeng Zhang

This paper is to discuss the removal of non-metallic inclusions from molten steel using a high frequency magnetic field. In experiments, a certain amount of aluminum was added to the molten steel in a crucible to generate aluminum inclusions. A layer of aluminum clusters were observed close to the wall of the crucible after the electromagnetic (EM) field was imposed. Three dimensional EM field and fluid flow simulation were performed and showed that over 91% inclusions transported to the skin depth (2.31 mm) of the molten steel. The calculation of inclusion removal agreed well with the experimental observation. The separation mechanisms of inclusions from the molten steel by the high frequency EM field were discussed.

Jan 1, 2014

By Cooper W. C, Stokes M. A

Proterozoic gold deposits in the Pine Creek Geosyncline are at present receiving renewed attention with the opening of old mines and several new discoveries. This important polymetallic province contains occurrences of gold, base metals, tin, tungsten, tantalum, platinum, palladium and aluminium. These resources have been exploited over the past century with periods of major interest during the turn of the century and during the past 20 years. Economically viable resources of predominantly gold, eg Pine Creek, Woolwonga, Brocks Creek and Union Reefs, and Ag-Pb-Zn, eg Woodcutters are currently in development or being mined. A variety of genetic models, ranging from magmatic through hydrothermal to syngenetic, have been postulated in the past for the formation of gold deposits in the Pine Creek Geosyncline. The first discussion on the regional geological factors that control ore deposition in the Brocks Creek-Howley District was by Sullivan and Iten (1952). They recognised that the most important ore deposits are associated with anticlinal and domal structures and that granites may be a controlling factor in the localisation of the mineralisation. More recently a group of authors, Needham and Roarty (1980), Goulevitch (1980), Nicholson and Eupene (1984), Sanger-Von Oepen, Friedrich and Kater, (1988), Nicholson and Eupene (1990) and Kruse, Whitehead and Mulder (1990) have suggested an exhalitive syngenetic origin, or remobilised syngenetic during dolerite intrusion and/or regional deformation, for gold mineralisation, especially those associated with South Alligator Group lithologies (eg Bridge Creek, Mt Bonnie group of mines and Cosmopolitan Howley). Studies carried out at the Bridge Creek and Western Arm Prospects over the last three years suggest that syngenetic models for gold mineralisation are less relevant to gold mineralisation in the Howley District than first thought (Wall, 1989; Partington, 1990). The Bridge Creek prospect has been cited as an example of a syngenetic-syngenetic remobilised deposit (Oepen, Friedrich and Kater, 1988) while the Western Arm prospect is more clearly a vein hosted epigenetic deposit and a comparison of the styles of mineralisation at both prospects will be made. The nature of the gold mineralisation at both prospects will be described and compared, and possible genetic models for gold mineralisation and their relevance to regional exploration discussed.

Jan 1, 1994