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By E. Dernedde

A few studies have suggested that the rate of adsorption of hydrogen fluoride on smelter grade alumina is determined by kinetic factors. However, no performance equation for dry scrubbers has appeared in the literature so far. Experimental data from a pilot dry scrubber with co-current flow were compared with results of kinetic models of adsorption, film diffusion and pore diffusion. The pore diffusion model was deemed the most appropriate. It was transformed into a performance equation for steady-state operations of dry scrubbers by the inclusion of the alumina recirculation. Operating results of industrial dry scrubbers with co-current flow were successfully evaluated by means of the performance equation. The average fluoride content of the alumina was also estimated by using the pore diffusion model.

Jan 1, 2011

By Abhishek Asthana

The incineration of Municipal Solid Wastes (MSW) is an attractive process for reducing the volume of the wastes and recovering their energetic value, which, however, requires to be strictly controlled in order to limit its impact on the environment. In this context, we have undertaken the mathematical modeling of the different sections of a typical incineration plant. The combustion of the waste bed, usually carried out on a moving grate, is at the core of the process. This paper presents the 2-dimensional, steady-state model that we have developed for simulating the MSW combustion. The model describes gas flow through the porous waste particle bed, the gas-solid reactions, conductive and radiative heat transfers, drying of the feed, its pyrolysis and the emission of volatile species, combustion of the pyrolysis gases, the formation of char and its gasification by water vapor and carbon dioxide, and the consequent reduction of the bed volume. Pyrolysis kinetics distinguish between cellulosic and non-cellulosic materials and are experimentally derived from our laboratory measurements. The calculated results give a deep insight into the various involved phenomena, an example being the complete consumption of oxygen in a large zone of the bed and the related appearance of a char gasification zone. The influence of various operating parameters, like the temperature and flow rate of primary air, is presented and explained. Finally, the effect of stirring the waste bed on the moving grate is also analyzed.

Jan 1, 2006

By C. A. Summers

The U.S. Bureau of Mines applied process mineralogy to investigate a lead and zinc deposit located near Story Creek, Colville Mining District, Alaska. Mineralization is hosted by the Kayak Shale in veins, veinlets, and breccia. Sphalerite and galena, with supergene anglesite, occur in symmetrical quartz veins and between breccia clasts. The study sample analyzed 2.11 percent Pb, 5.37 percent Zn, 0.014 percent Cu, and 1.2 oz/ton Ag. Analyses of crushed products showed that 33 percent of the sample weight, and more than 50 percent of the Pb and 65 percent of the Zn, are in the minus 850 um fraction. Liberated grains of sphalerite and galena were found in crushed products finer than 300 um. Beneficiation tests indicate the material is amenable to processing by traditional gravity and flotation techniques.

Jan 1, 1991

By Pieter Barendsen, Olivier Dubugnon

INTRODUCTION There are three fronts on which development efforts are being concentrated to extend the application domain of Tunnel Boring Machines (TBM), which is potentially very large - Assessment of a reliable prediction method, including machine-rock interaction and geological characterisation, so that the boring system can be designed properly and the costs remain in the predicted range for each given tunnel project. - Development of lighter, more flexible and more controllable machines to be applied in shorter, deeper tunnels or roadways, such as required in mining. - Reduction of cutter and machine costs when excavating hard rocks or difficult grounds, in developing improved tool materials, cutting geometries and tunnelling systems. The above three lines of development have a common, critical requirement: to have a reliable set of design rules to optimize the machine specifications from the knowledge of rock and geological parameters and working requirements. This optimization can only be done if a model sufficiently sophisticated is made available, able to take into account the numerous factors influencing the TBM advance , and being interactive enough to achieve the optimization.

Jan 1, 1985

By I. Hague

Support liners for underground applications include steel and timber sets, meshing and lacing, screen/mesh, shotcrete and thin support liners (superskins). Over the past few years, major advances have been made in the design and application of liners; especially shotcrete and thin support liners. For shotcrete in mines these advances include the common use of slick-lines to solve logistics problems, the design of alkali free accelerators, the use of synthetic fibres and the new generation application equipment. The field of thin support liners is a new one but advances have been dramatic. This paper discusses the progress made and the need for standardization in definitions and testing for thin support liners. It concludes that the newer technologies have a huge potential positive impact on the industries, from both safety and cost points of view. Le chemisage de soutènement pour extraction souterraine comprend des cadres d’acier ou de boisage, mailles et chapeau, cribles/mailles, béton projeté et des chemisages minces de soutènement (super-peaux). Dans les dernières années, des progrès considérables ont été fait dans la conception et application des chemisages, en particulier les chemisages de soutènement en béton projeté et les chemisages minces. Pour le béton projeté dans les mines, ces progrès comprennent l’utilisation courante de lignes de minerais broyés fin pour résoudre des problèmes de logistique, la création d’accélérateurs sans alcali, l’usage de fibres synthétiques et d’une nouvelle génération d’outillage. Le domaine des chemisages minces de soutènement est très récent mais les progrès ont été rapides. Cette étude présente les progrès accomplis et discute du besoin de standardisation dans les définitions et les tests pour chemisages minces de soutènement. La conclusion est que les technologies nouvelles présentent un énorme impact potentiel positif sur les industries, du point de vue à la fois de la sécurité et de la rentabilité. Unterstützungsverkleidungen für Untertaganwendungen inkludieren Flecht und Seilwerk, Gitter/Geflecht, Spritzbeton und dünne Unterstützungsverkleidungen (superskins). Während der letzten Jahre wurden grosse Fortschritte im Design und in der Anwendung der Verkleidungen gemacht; besonders bei Spritzbeton und dünnen Unterstützungsverkleidungen. In Bezug auf Spritzbeton in den Gruben schließen diese Fortschritte den allgemeinen Gebrauch von Rutschbahnen ein um Logistikprobleme zu lösen, das Design von alkalifreien Akzeleratoren, den Gebrauch von synthetischen Fasern und die neue Generation von Anwendungsausrüstung. Der Bereich der dünnen Unterstützungsverkleidungen ist neu, aber die Fortschritte sind drastisch gewesen. Diese Arbeit behandelt den erzielten Fortschritt, die Notwendigkeit der Normierung in den Definitionen und in der Prüfung dünner Unterstützungsverkleidungen. Sie kommt zum Schluß, daß die neueren Technologien, sowohl vom Gesichtspunkt der Sicherheit als auch der Kosten, eine sehr große potentielle positive Auswirkung auf die Industrien haben.

Jan 1, 2003

By Jesús Ortíz V

Si bien en 1974, las reservas del mineral duro y semiduro del yacimiento minero Cerro de Pasco resultaron apropiadas para el método Arch Bach, en cambio, sus niveles de producción no alcanzaron un mayor desarrollo. Es por ello que se optó por explotar los cuerpos de mineral suave a través del método de corte y relleno descendente (undercut and fill) cuya aplicación en la recuperación de pilares tuvo buena recepción. En este sentido, el objetivo del trabajo es mostrar las soluciones adoptadas en la mina de Cerro de Pasco al mecanizar el método de corte y relleno, con el fin de optimizar el método de minado, mejorar la eficiencia, recuperar los rangos de producción y reducir los costos.

Nov 20, 1978

By Aysan Molaei, Kristian E. Waters

"Solvent extraction is the one of the most common techniques for recovering metal ions from aqueous systems. However, it is not efficient in the extraction of low concentration metal ions from aqueous solutions. Predispersed solvent extraction (PDSE) is an alternative method for solvent extraction which implies colloidal liquid aphrons as extracting agents in order to reach higher interfacial area and lower reagent consumption. This work investigated important parameters in PDSE of nickel ions from dilute aqueous solutions by fractional factorial design of experiments. Four experimental parameters, the initial extractant concentration, initial surfactant concentration, equilibrium pH and phase volume ratio (organic to aqueous ratio) were investigated. The important parameters were determined as well as important interactions between these parameters. It was found that extractant concentration, phase volume ratio, and equilibrium pH are the most significant experimental parameters. However, the interaction between surfactant concentration and other parameters was determined as significant interactions.INTRODUCTIONNickel is one of the key components found in cars, mobile phones, rechargeable batteries, kitchen appliances, and steel industry (Anyadike, 2002). It is one of the most important metals produced by Canada which is in the five top nickel producers in the world. Despite a 24% decrease in the nickel prices from 2011 to 2014 the nickel global mine production increased by 36% between these years (U.S. Geological Survey, 2015; Nickel - Statista Dossier, 2015), which shows the increasing demand for nickel. This high demand leads producers to consider the production of nickel from low grade ores and other secondary sources such as process wastewaters. The removal of nickel ions from process wastewater is also important due to environmental considerations. Nickel is known to be a human carcinogen and it may cause serious lung and kidney problems, pulmonary fibrosis, gastrointestinal distress, and skin dermatitis if it exceeds the critical level (Borba et al., 2006; Fu & Wang, 2011)."

Jan 1, 2016

By S. Skowronski

The melting of cathode copper, ususally containing 95.98+ per cent. • Cu, would appear to be a simple matter. Owing to the well known affinity of copper for sulfur, however, so much sulfur is absorbed by the copper during the operation that a long and expensive refining process is required to remove it, and the final product is inferior in purity and lower in electrical conductivity than the original cathode copper. The furnace operation, as now conducted, includes the following stages: 1. Charging the cathodes into the furnace. 2. Melting the cathodes. 3. Oxidizing period—saturating the copper with cuprous sub-oxide and bringing the metal to the condition known as "set copper;'' this is now done by blowing air into the molten bath of metal. 4. Reduction period, otherwise known as "poling," whereby the oxygen previously added is removed by covering the molten bath completely with coke or charcoal and introducing large poles of green wood; this reduces the cuprous sub-oxide, bringing the copper to the "tough pitch" stage ready for casting. 5. Casting Period. Many experiments have been made to obviate the long periods of oxidation and subsequent reduction, with no success. While the copper first cast will be good, as indicated by the set surface of the bars, it is impossible to hold it to the "tough pitch" condition, and long before the whole charge has been poured the copper will become "overpoled," entailing numerous difficulties. Sulfur has always been blamed by the furnace men as the reason why this refining process is necessary, yet the literature on the subject does not sufficiently emphasize how small a proportion of sulfur will ruin copper for practical purposes. The sulfur absorbed by copper during the melting period comes from two sources: (1) the sulfate left on the cathode sheets in the tank houses; (2) the fuel. The percentage of sulfates on the cathodes is variable, and depends on the care taken in washing the cathodes after removing

Jan 1, 1919

By W. F. Wyman, S. F. Ravitz

"INTRODUCTION By far the greater part of the high-grade manganese ore used in the United States is imported from overseas. During the early part of the recent World War importations of manganese ore were seriously threated, and it appeared that it would be necessary to utilize low-grade domestic ores to the fullest possible extent. Among the processes that appeared to offer the best possibilities for beneficating low-grade domestic oxide manganese ores, which ordinarily are net readily amenable concentration by ore-dressing methods, were those involving leaching with sulfur dioxide. The Bureau of Mines therefore investigated the amenability of a large number of such ores to sulfur dioxide leaching.Several sulfur dioxide processes for beneficiating low-grade oxide manganese ores have been proposed. 3/ One of these, based on a patent by Van Arsdale and Maier, 4/ was used recently in a plant constructed to treat 1,000 tons per day of 20-percent manganese ore from the Three Kids deposit near Las Vegas, Nev. 5/ In this process the ore slurry is leached with sulfur dioxide gas, the resulting solution is evaporated to crystallize the manganese sulfate, the crystals are decomposed thermally to produce high-grade manganese oxide and regenerate sulfur dioxide, and the manganese oxide product is nodulized. The Bureau of Mines has recently developed a process 6/ in which a suspension of the ore in calcium dithionate solution is leached with dilute S02 gas, the manganese is recovered from the resulting solution by a simple lime precipitation, and the precipitate is nodulized or sintered to form a high-grade manga¬nese oxide product."

Jun 1, 1947

By E. J. Yoder, N. B. Aughenbaugh, R. B. Johnson

Mineral aggregates experience degradation during field and laboratory compaction. Reduction in the aggregate size is accomplished by abrasion of the particle edges and fracturing of individual pieces which have become overstressed. Little is known of the factors that govern the amount of breakdown experienced for a given situation. A field study was made of the factors affecting aggregate breakdown under compaction using three carbonate aggregates of different physical properties. The preliminary results indicate that rock type, compactive effort, gradation, and thickness of compactive layer are factors which exert the greatest influence. Mineral aggregates experience a mechanical breakdown of some of the aggregate pieces into smaller fragments during any compaction process, whether in the field or laboratory. This phenomenon occurs as abrasion of the sharp edges during movement and reorientation of the particles in densifying and/or as granulation and fracturing of those pieces which have become overstressed. Two types of aggregate breakdown occur in the field. These may be classed in a general category of aggregate degradation.* One occurs during the con- * Aggregate degradation has been defined in many different ways. For this paper it is considered as any breakdown of larger particles into smaller ones, whether mechanical or chemical. struction period and is related to the densification of the aggregate body from a loose state to a relatively dense mass by heavy compaction equipment. This type is almost entirely a mechanical action. The other occurs after the construction period when the roadway has been put into use. This in-service breakdown is; a different phenomenon from the breakdown during construction in the sense that it combines mechanical with chemical changes. Time becomes an important consideration that may cause subordinate factors in construction degradation to develop into principal ones for in-service breakdown. Breakdown of aggregates in service has been extensively studied by investigators from the northwestern

Jan 1, 1962

By Edward Jeffrey

THE use of coke in metallurgy, to any important degree, dates from the middle of the 18th century. Its utilization came most opportunely for European civilization. The forests of Europe, except in the most remote and inaccessible regions, had been largely fed, in the form of charcoal, into the smelting furnaces. For a hundred years-the middle of the 17th to the middle of the 18th century-there was a stationary condition of population corresponding to the exhaustion of European forests. This situation, which was particularly evident in Great Britain, was due to the fact that the forests had been depleted and the practical utilization of coke had not begun. The coking industry is essential for our metallurgical industries, which in turn are basal to healthy economic progress. But coke is of great importance, not only on its own account, but for its byproducts, which enter fundamentally into all the arts of peace and war. The dyestuff industry and the manufacture of explosives are intimately connected with one another, as was shown by the recent war. The subject of coking coal, therefore, is well worthy the serious attention both of practical industry and the scientific investigator. The most valuable coking coals, from the metallurgical standpoint, are derived from the coals of highest ranks. Coals, for example, that have a carbon ratio of from 70 to 80 per cent. yield the most valuable coke for the blast furnace. The difficulty of investigating these coals, however, is great, for they are rather friable and delicate and possess a high carbon content, which makes them difficult to manipulate. They present, on account of their high carbon content, a considerable degree of opacity when examined, in thin sections, under the microscope. The tenderness of structure and blackness of such high-grade coking coals as those of Connellsville and the Pocahontas region make them extremely difficult to investigate.

Jan 1, 1925

By Y. S. Sun, Northeastern University, W. B. Li, P. Gao, Z. Y. Zhang, J. W. Yu

"The boron-bearing iron concentrate was extracted from ludwigite ore by the process of magnetic-gravity separation. In order to fully utilize the refractory ore and meet the boron consumption of China, a novel process for separation of boron from iron in boron-bearing iron concentrate was proposed in this paper. In particular, laboratory scale experiments of improving boron reactivity were performed. Fine boron-bearing iron concentrate briquettes were reduced by bituminous coal completely at 1125 °C for 150 min. The effect of sodium carbonate, which was used as an additive in the roasting process, was investigated. The addition of sodium carbonate decreased the boron reactivity and facilitated the volatilization of boron. The influence of diverse cooling methods of the reduced samples on the boron reactivity was studied. The results indicated that boron reactivity could reach up to 80.76% when the reduced samples were cooled by rapid water quenching. In addition, the magnetic material containing 92.71 % Fe with a recovery of 95.11 % and boron-rich non-magnetic material containing 14.51% B2O3 with a recovery 88.85% could be obtained by low-intensity magnetic separation. The magnetic material and boron-rich non-magnetic material were good raw materials for steel-making and borax production, respectively.INTRODUCTION Ludwigite ore is abundant in Liaoning province of China, with 28.43 Mt B2O3 accounting for 57% of the boron resources of the country (Liu et al., 2006). However, it has not yet been utilized on an industrial scale due to its complex mineralogy and fine mineral dissemination (Wang, Wang, Ding, Ma & Xue, 2012). At present, boron-bearing iron concentrate and boron concentrate can be obtained from ludwigite ore using magnetic-gravity separation. The boron concentrate contains B2O3 12%~16%, which can be used as a high-quality raw material for the boron chemical industry after activated roasting, but the B2O3 content in the iron concentrate reaches up to 4%~6%. In order to further separate boron and iron from boron-bearing iron concentrate, a blast furnace and a solid pre-reduction followed by electric arc furnace melting have been proposed (Liu, Cui & Zhang, 1998; Wang et al., 2012). However, both of these two current routes face the same crucial problem that molten boron-rich slag has to be cooled slowly to obtain the alkali-dissolution activity of boron, which affects the yield of boron resource."

Jan 1, 2016

By Charles H. Behre

This paper deals with recent geologic studies in the slate belt of Northampton, Lehigh and Berks counties, Pennsylvania. The work was conducted under the auspices of the Pennsylvania Topographic and Geologic Survey. Three years have now been spent in detailed consideration of the economic geology of this region. In the field, particular attention was paid to the bearing of geology on quarry development and property valuation and the object of this paper is to summarize the results from that viewpoint. Excellent studies of a somewhat similar nature have already been carried out by Bowles,' but with the emphasis upon the details of quarrying and fabricating methods, rather than upon the geologic relations. The Northampton-Lehigh-BeRks District Location The region here discussed lies in east-central Pennsylvania and extends southwestward from Delaware River, on the New Jersey line, to the Schuylkill in north-central Berks County. It is an elongated belt occupying the northern sections of the three counties mentioned and lying along the southern edge of Blue Mountain. Its length is about 50 miles and its average width five or six, though in places it attains a maximum of 10 miles. There are no large cities in the region, but about 10 miles south are Reading, Allentown, Bethlehem and Easton. Railroads serving the slate belt are the Delaware, Lackawanna and Western, and the Pennsylvania along the Delaware River, the Lehigh Valley and Central of New Jersey along the Lehigh, and the Pennsylvania and Philadelphia and Reading on the Schuylkill. In addition, two railroads—the Philadelphia and Reading and the Lehigh and New England—cut obliquely through the slate region to reach the more isolated communities. Transportation facilities are thus excellent. The slate deposits of these three counties are conspicuously unified, both economically and geologically. In general type of marketable

Jan 1, 1928

By G. Stuart Littlejohn

In spite of recent concerns in certain European countries, I believe that silicate-ester grouts will continue to be employed in practice, unless more cost-effective inorganic grouts are developed for the treatment of fine sands. It is also noteworthy that over the past 40 years, there has been a record of good experience where silicate-ester grouts have been used in ground improvement. Nevertheless, there is now a need via the European Standard EN 12715 (2000) "to assess the environmental impact, particularly the toxicity of the grout and grout components, and their effect on ground and drinking water should be considered before grouting." "When testing the grouting material for environmental impact, the following aspects should be considered: ? Whether during processing, transport or grouting, substance can be generated or released which could be hazardous to the environment or the grouting crew; ? Whether noxious substances can spread upon mixing with ground water; ? Whether reaction products can be produced or released which influence the water quality; ? The type of particles eroded from hardened grout; ? Chemical reactions between hardened grout and the ground water."

Feb 10, 2003

By S J. Schafrik, M Long

There are several factors that are increasing the need for new graduates to be ready to design and manage more autonomous operations at mines. Autonomous controls and systems range from the start-up, control, and shutdown of processing plants to the autonomous operation of vehicles. These operations require the workers, engineers, and management to have additional skills for programming, debugging, tasking, and maintaining the equipment. The future survivability of many mining operations will be influenced by a company’s willingness and ability to understand, accept, and utilise this technology for safe and productive operations. This is an educational opportunity and challenge that needs to be addressed throughout the student’s experience, from first year to graduate level. This paper discusses the lessons learned from a decade of multidepartment effort at all student levels and many courses that are able to incorporate data science, controls, and autonomous design into the already topic-rich national curriculum. This approach also exposes other engineering disciplines to the mining industry which is a valuable recruiting tool for talent outside of the mining engineering departments.

Sep 1, 2024

By Julio C. Martinez, Jeffrey L. Rice, Hayden Weschler

This paper details the extensive underpinning required to hold up the 39th street Bridge while demolishing its massive support piers and building a 30ft deep Cut/ Cover RR tunnel beneath it. The underpinning/SOE support required the construction of 16 large hand dug pits 36ft deep that were reinforced and concrete filled. In addition, an extensive steel support system was tied into the bridge super structure. All of the underpinning/tunnel construction was done while a 110ton crane sat directly atop the heavily trafficked – 66 ft. wide bridge. The tunnel excavation, concrete lining and final bridge pier support work will also be presented. All work was done within 5ft of active mainline tracks and that required tight grouting behind all lagging to eliminate any track settlement.

Jun 13, 2021

By M Hood, X S. L, W J. T Daniel, H Gurgenci

It is believed that disc cutter shape affects rock fracture and therefore cutter performance and cutter life. However, the current generation of disc cutters is made of hardened steel and these cutters wear rapidly and consequently they are unable to maintain their original shape in strong and abrasive rock. This wear problem could be reduced if the cutter was made from a harder material. Unfortunately as material hardness increases so does the propensity for brittle failure. In this study the optimum cutter shapes were identified by studying the mechanics of rock/tool interaction. The results showed that bevel and wedge cutters are better than cutters with dome and flat edges. A new cutter was designed, based on this result, using a harder material to increase the life by a factor of 20.

Jan 1, 1998

By L. Don Leet

Abstract Earthborne vibrations from blasting and other sources, including rock bursts, can now be recorded effectively. The nature and magnitude of vibrations from various sources have been investigated and certain applications of the knowledge thus gained have been made. Vibrations from blasting have been measured on special equipment over a range from an electric blasting cap at a few feet, through the largest quarry shot in history to date ( 1,-362,985 lb.), to the first atomic bomb, in uew Mexico on July 16th, 1945. Laws relating amount of explosive to amount of vibration at different distances have been developed and tested. Special studies have been made of the effects of vibrations on buildings, particularly from the standpoint of possible structural damage. Recorded vibrations are used to study the effects of modern short-period delay shooting. It ?has been found that short-period delay firing is extremely effective in reducing vibrations under the right conditions, but with certain limitations. In quarry shooting, there appears to be a minimum number of holes below which vibrations are not appreciably reduced by short-period delay firing. In several instances this minimum has been near 7. Vibrations in the ground from rock bursts and the effects of mining in stresesd ground have been studied both underground and on the surface in a search for a rock burst warning system. Introduction Earthborne vibrations from blasting and other sources, including rock bursts, can now be recorded effectively. Analyses of blasting records have been yielding increasing funds of information of practical as well as theoretical interest. The nature and magnitude of the vibrations have been investigated with special reference to their effects on structures.

Jan 1, 1951

By Uday Kumar

This paper presents details of an availability study for a fleet of diesel engine operated load-haul-dump (LHD) machines used in a Swedish mine. For the purpose of this study, the LHD machines have been considered as a system comprised of many subsystems like engine, brake, transmission, etc., in series. As availability is dependent on both the reliability and maintainability characteristics of the system, together with reliability, the concepts of maintainability are also discussed. The need for exploring the data for the presence of any structure, which is very common in repairable system data sets, is emphasized with suitable examples. Simple graphical techniques are used for verifying the independent and identically distributed (IID) assumption for the data set. The error introduced due to the use of the exponential distribution in place of more appropriate distributions in estimation of availability and reliability characteristics is analysed.

Jan 1, 1989

By A. Idegami, M. Imamura, S. Heguri, Y. Ozaki

"Nickel powder can be produced by the reduction of a nickel ammine complex solution by hydrogen at high temperature and pressure. To minimize the deposition of fine nickel on the surface of the reactor and other equipment, seed crystals are added to the initial solution to promote nucleation of the nickel powder. Such seed crystals catalyze the precipitation of the nickel particles on the surface of the seed and enhance grain growth. In this study, nickel nuclei were precipitated by the addition of a polymer to the nickel ammine complex solution, resulting in the production of nickel powder. Thus, we herein propose a model that explains the effect of the polymer in the precipitation of nickel nuclei.INTRODUCTIONNickel powder is commonly produced via a hydrometallurgical process from the hydrogen reduction of a solution containing a nickel ammine complex at high temperatures and pressures, and this process was commercialized in the 1950s by Sherritt Gordon (Sherritt International, Canada, Benson & Colvin,1973; The Staff, Research and Development Division, Sherritt Gordon Mines, Ltd., 1958).In the above transformation, upon the injection of hydrogen gas into the solution, nickel is reduced as outlined in Equation(1), ultimately resulting in the production of nickel powder.Ni(NH3)nSO4+ H2?Ni+ (NH4)2SO4+ (n-2)NH3(n:2–6)(1)In this process, seed crystals are added to the reactor to suppress the precipitation of fine nickel (scaling) and to enhance nickel reduction (Benson & Colvin, 1973; Mackiw, Lin & Kunda, 1957). More specifically, iron sulfate and a small amount of dispersant polymer are added, which leads to the formation of nuclei. Upon subsequent hydrogen reduction, the reduced nickel can then be deposited on the nuclei, allowing nickel particle growth to take place. However, this results in iron contamination in the final nickel product, and so the use of pure nickel as a seed crystal is desirable to produce high quality nickel powders."

Jan 1, 2017