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By L. Escudero-Castejon, S. Sanchez-Segado, A. Jha, Y. Hara, S. Parirenyatwa

In a world where declining ore grades are increasingly common, it has become necessary to process low-grade feedstock. Carbothermic reduction in the presence of alkali (Na2CO3) has been adapted to beneficiate waste that contains titaniferous minerals (TiO2 ca. 12 wt%), in order to recover valuable constituents such as TiO2, Fe and V2O5. The waste from vanadium metal processing has environmental legacy as it leaves nearly 1 wt% V2O5 process waste, which is environmentally problematic due to V5+ ions in contact with water and soil. This investigation focuses on the kinetics and mechanism for alkali reduction of mineral waste bearing 10–12 wt% TiO2, which we studied in the 1073–1323 K range. The thermogravimetric analysis (TGA) technique was used to record weight loss data. Two distinct regimes demonstrated mixed-control kinetics: (1) at low temperatures the activation energy was found to be 199 kJ mol−1, which corresponds to the outward diffusion of O2− ions; and (2) at high temperatures the calculated value was 130 kJ mol−1, which is consistent with the activation energy for the outward diffusion of Fe2+ ions. The metallic iron, sodium titanate and sodium aluminosilicate phases that formed were characterised using X-ray powder diffraction (XPRD) and scanning electron microscopy (SEM) techniques, and their significance for metal recovery is explained.

Mar 1, 2017

Throughout the 1970s, the US Bureau of Mines rode an ebb tide in Washington political circles. In rapid fire succession, the agency lost its mine health and safety enforcement responsibility (1973), a large portion of its energy research responsibility (1975), and then its fuel statistics functions plus a sizable portion of its coal R&D (1977). By 1978, johnny-come-latelies in the Energy, Labor, and Interior Departments had siphoned away from the Bureau some $125 million in program responsibilities as well as 900 of its employees. The bruising decade came to a close with a Department of Natural Resources proposal that, in its original form, would have scattered the Bureau's responsibilities to the winds. "There is no doubt in my wind," said Lindsay Norman, acting director of the Bureau of Mines (see box), "that were the Bureau to continue down the path it was on, the next step was closing the doors and going out of business." The doors are still open, but erosion of responsibilities had a devastating effect on the resources available to fulfill the Bureau's mission. Devastating, too, in terms of internal morale, considering the Bureau had six directors in a 10-year span. "When the troops are in the trenches and are being shot at," Norman said, "they need a leader-hopefully, a permanent one- that can get them advancing. This is something the Bureau did not consistently have in the 1970s." In September 1978, Roger Markle climbed aboard as director of the Bureau to rejuvenate the 70-year-old agency. He resigned only six months later* but the program Markle set in motion is being carried through by Lindsay Norman. Since Norman's appointment as acting director, he has spent considerable time on the road explaining his agency's redefined goals. At one such stop in Duluth, Norman and his two deputy directors, Charles Kenahan and Mike Kaas, answered the following questions. Lindsay, you were the principal architect in the Bureau's 1979 reorganization. How about a glimpse of what that entailed? Toward the end of the 1970s, after almost a decade of steady dismemberment, we reached what we felt was a critical point in the Bureau's history-we had the choice of redefining and strengthening our organization to meet the mineral challenges ahead, or continuing down the path toward the agency's eventual demise. We felt the Bureau's mission too important to abandon, so in 1978 with Roger Markle as director we initiated a six-month, no-holds-barred intro spection of just what the Bureau should be doing, why, and toward what ultimate national needs. And what did this self-reflection reveal? That there is, indeed, a unique federal role for the Bureau of Mines-that of a lead agency for influencing mineral decisions and pioneering tomorrow's technologic advances. Don't confuse us with policymakers, we're not. But we are policy analysts; we're scientists, engineers, and mineral professionals who can offer a sorely needed source of objective, accurate information to decision makers in both the public and private sectors. I feel there is no better brain trust in government than the Bureau when it comes to mineral expertise-of course, I'm biased. Do I understand you to say the Bureau of Mines is an advocate agency for the minerals industry? We plead no parochial interests, nor ought we, but from our viewpoint a sound minerals industry is extremely important to the broader national goals of security and a healthy economy. US dependence on foreign sources for critical minerals, the increasing noncompetitiveness of some US mineral sectors, and the array of land use issues surrounding mineral-rich lands all have much more serious implications than many otherwise informed people seem to recognize. In your estimation, how vulnerable is the US to foreign mineral suppliers? Let me make a distinction between dependency and vulnerability. The

Jan 4, 1980

By Shao Li, Chen Zhiming, Wu Jihong

In this paper,powder emulsion explosives,which have high sensitivity and strong detonation force,have been studied by applying emulsion technology to the production of the present powder ones.Under the condition of #8 industrial detonator initiation,the distance of air gap propagation is 110~180mm,brisance !3.5mm, lead block test value 325ml and detonation velocity 3000~4000m/s for small diameter (35mm) explosive cartridges.In addition to these,the factors effect on are investigated by experimental study and theoretical analysis.

Jan 1, 1991

By Douglas H. Bolton

In recent years, equipment manufacturers have been busy developing remote control systems to catch up with the sophistication and efficiency of continuous miners. Now the tables are turned, and manufacturers are undertaking the new challenge of upgrading, refining and equipping continuous miners to take full advantage of the capabilities made possible by modern, successful remote control systems. Because the operator can safely advance the miner farther without pulling out for roof bolting, continuous miners now need to be equipped with means of complying with correct face ventilation, dust suppression, methane detection, diffusion and improved lighting. Some of the exciting possibilities being developed to catch up with remote control include feedback controls using laser beams as datum points, coal sensing devices with feedback signals to show the operator what the machine is doing, show where it is relative to the coal seam, how hard it is working, and more sophisticated use of cyclic control. Mining machinery manufacturers have accepted the new challenges, and faster, safer mining procedures are already in sight.

Jan 1, 1975

By Rainer Kahrger, Guenter Ewald

The topic of this paper is to demonstrate the development of mobile crushing installations from throughput capacities of 200 tons per hour, to mobile and semi-mobile large- scale crushing installations with throughput capacities of 3,500 up to 10,000 tons per hour. Basis are approximately 140 mobile and semi-mobile crushing installations which have been built since 1956 or were on order in 1987. [FIGURE 1. Total Number of Mobile or Semi-mobile Crushing Plants] Sixteen of these approximate 140 mobile and semi-mobile crushing installations have a throughput higher than 3,500 metric tons per hour. Mobile crushers were developed more than 25 years ago in Europe for the quarry industry, which had special requirements - fairly low capacity, mostly softer and less abrasive material (limestone) and full mobility. So the majority of the units up to about 1980 were fully mobile, having a fairly small capacity and utilizing mainly hammermills, double roll and impact crushers. It was only when the mining industry and large quarries picked up the concept in the early 1980's that a drastic increase in capacity took place. Even though the first mobile crusher in a true mining application went into service in 1971, it took another 10 years before it proceeded in a larger scale. This trend was obviously supported by the drastic fuel price and energy cost increase in the mid 70's. Since the cost of conveying material is substantially cheaper than trucking it, the increase in energy cost, combined with increasing haulage distances provided a strong incentive. Figure 1 shows clearly the throughput distribution of all crushing installations and it also shows the sharp increase in the throughput capacities within the last few years.

Jan 1, 1989

By M. Minagawa, G. Granata, C. Tokoro, T. Kato

"In this work, we studied the mechanochemical activation of chalcopyrite by vertically stirred ball milling (VSBM) to enhance the dissolution of copper. By using x-ray diffraction (XRD) and laser diffraction particle size analysis, we investigated the effect of milling and milling conditions on particle size and phase composition of the chalcopyrite concentrate. To elucidate the efficiency of VSBM towards the mechanochemical activation of chalcopyrite, we also conducted leaching experiments in sulfuric acid-ferric sulfate media. Under all investigated milling conditions, the VSBM determined a dramatic decrease of particle size from over 100 µm of P80% up to about 13 µm. Furthermore, the XRD of the ground chalcopyrite specimens highlighted a partial oxidation of the mineral. In leaching, upon grinding by VSBM, the increase of copper extraction ranged from a minimum of +10% to a maximum of +40%, depending on the grinding conditions. In order to elucidate whether the dissolution enhancement was a consequence of the decreased particle size or of an induced mechanochemical reaction, we performed leaching experiments on activated and non-activated chalcopyrite sample having the same particle size. In addition, we determined the activation energy of leaching before and after vertically stirred ball milling. The leaching results on samples with the same particle size highlighted a greater copper extraction and higher dissolution rates upon mechanochemical activation. Whether performing grinding by VSBM or not, the leaching kinetics was found to be controlled by the chemical reaction on the surface of the chalcopyrite particle. By grinding the chalcopyrite concentrate by VSBM, the activation energy of leaching slightly decreased from 66 to 58 kJ/mol. INTRODUCTION Due to the increasing demand of copper, low grade ores and refractory minerals like chalcopyrite are expected to become the main copper source in the next years (Klauber, 2008). As a low-grade sulfide, chalcopyrite shall be processed hydrometallurgically. However, due to the formation of a protective layer of elemental sulfur during the oxidizing leaching, the dissolution of copper is slow and/or incomplete (De Bernardi and Carlesi, 2013). Therefore, the development of new technologies to enhance the extraction of copper from chalcopyrite is highly required."

Jan 1, 2018

By D. H. Diering

The paper takes the reader into the depths of a modern ultra-deep South African gold mine and gives a perspective on the vertical and horizontal extent of the tunnel networks in such a mine. Depending on the mine design layout employed, tunnels once excavated are subjected to various levels of stress change over their life time, and the support requirements are explained. It is suggested that shotcreting is the only viable ultra-deep level support medium, and after looking at the latest developments, the logistical problems are put forward. In an effort to overcome most of these problems, the South African ultra-deep mining industry embarked on a collaborative research programme in 1998. The importance of tunnelling and in particular tunnel support as a critical technology for future successful ultra-deep level mining is stressed. While not yet fully ?on top of? these problems and challenges, our industry is now fully addressing them and we expect to make significant progress during the next 4 to 5 years.

Jan 1, 2000

By Hugo A. Carrillo F

Los campos petrolíferos de Brea y Pariñas son reservorios del tipo "impulsión de gas", cuya recuperación por métodos normales de producción es ínfima del 30% del aceite original. Por ello, el objetivo del trabajo, propone la inyección de gas o agua, como método principal de recuperación artificial para dichos yacimientos. Este sistema comprende dos tipos de inyección: mantenimiento de presión y circulación, cuya ventaja radica en la estabilización de la producción, elimina el tiempo para agotar el reservorio, reduce los costos de producción, y permite un mayor rendimiento de la gasolina natural.

Jul 20, 1955

By K. A. Svanstrom, W. R. Opie

Problems associated with deposition of titanium infused chloride baths using TiCl4 as a feed material are reviewed. A potentially workable cell design using Alumdum diaphragms is discussed. Problems inherent to diaphragm-type cells are emphasized and experiments described which led to the development of a cell without a diaphragm. INVESTIGATORS assigned the problem of developing a commercial electrolytic process for making titanium metal have found that they are faced with the difficulty of overtaking rapidly improving magnesium and -sodium reduction processes. The ultimate goal must be a simple process that can be conducted with low-cost raw materials in equipment that is inexpensive to build and operate. This paper deals with some work of a preliminary nature conducted by personnel of the Research Laboratories, National Lead Co., Titanium Division. Many others have reported on the general subject of depositing titanium from fused salt electrolytes. A partial bibliography is attached. PRIMARY CONCEPTS Anyone attempting to deposit titanium metal from fused chloride electrolytes using TiC14 as a source material is faced with at least the following problems: 1) Getting the titanium into solution in the bath. 2) Controlling oxidation and reduction reactions associated with multiple valency of titanium, which result in low electrical efficiency. a) Prevention of dichloride oxidizing to trichloride and trichloride to tetrachloride at the anode. b) Prevention of trichloride from being reduced only to dichloride at the cathode. 3) Prevention of metal formation away from the cathode thru disproportionation of titanium dichloride to satisfy the equilibrium. 3 TiCl2 == 2 TiCl3 Ti [I] 4) Protection of reduced chlorides in the bath from reaction with oxygen from the bath container or air. 5) Removing from the bath the deposited metal formed without allowing it to become contaminated with oxygen or nitrogen. 6) Selecting cell materials of construction which will not contaminate the metal product or cause cell inefficiencies. EARLY EXPERIMENTS The initial attempts made to electrodeposit titanium from fused chloride baths using TiCl4 as a source material indicated that TiCl4 was essentially insoluble in molten chlorides of alkali and alkaline earth metals. If, however, the TiCl4 was introduced close to a nickel cathode some metal could be formed and appreciable quantities of reduced chlorides would be present. These reduced chlorides reacted with any oxygen present in the atmosphere above the bath and would also diffuse quickly to the anode (graphite) where they would react with chlorine and be evolved as TiCl4. The net electrolytic efficiency of such a cell is essentially nil. The TiCl4 evolves from the anode at almost the same rate that it is introduced in the vicinity of the cathode although a small amount of titanium metal can be formed on the walls of the cathodic pipe. It becomes apparent from the operation of such a cell that: metal can be deposited on the cathode, although of small particle size and a nonadherent nature, and when reduced chlorides are present in the electrolyte, TiCl4 can be absorbed, probably by the following reactions: TiCl4 + TiC12 - 2 TiCl3 [21 2 TiCl3 + 2 faradays - 2 TiC12 + C12 [31 DIAPHRAGM CELLS These facts encouraged the development of cells containing diaphragms to prevent migration of reduced chlorides from the cathode area to the anode. Small-scale cells for process development are described by Alpert, Schultz, and Sullivan.20 A larger brick-lined cell incorporating internal heating by passing ac through the bath is shown in

Jan 1, 1960

By A. D. Mutch

This contribution is prompted by the fact that the writer has recently published an article" which has in part the same general conclusions as B. S. Butler's, namely, the form of the standard mineral paragenesis in hypogene deposits and the parallel transition from early high temperature acid to late low temperature alkaline or neutral solutions. Since the writer also recognizes that he is not fully qualified to discuss the formation of ore deposits as a chemical problem, this discussion will be limited to summarizing other observations and will suggest how Butler's Table II might be made more effective. The form of Butler's table is not unlike that widely used by European geologists30 in which the various minerals are related to the types of ore fluids-pegmatitic, pneumatolic and hydrothermal. Thus the decrease in temperature and change in pH of the ore- bearing fluids as recognized by Butler may also be paralleled by perhaps even greater changes in composition, density, and character.

Jan 5, 1958

By J. R. Welty

High-temperature thermodynamic data have, in recent years, become increasingly important for the extractive metallurgist. The extraction of metals from their ores previously was based on trial and error methods, involving hours of testing and often costly equipment fabrication. Using thermodynamic data it is frequently possible to predict the feasibility of a proposed metallurgical process as well as the optimum operating conditions for the process with reasonable accuracy. Such predictions can save consider-able tim~ and expense. Widespread use of thermodynamic analyses has been handicapped by lack of dependable experimental data. Investigators, notably K. K. Kelley (4)4. have devoted many years to determining and compiling such data. These investigators, although prolific in their production of thermodynamic values, have been unable to meet all the needs of industry and other branches of science. This becomes obvious when one considers the aeronautical and nuclear fields, in which previously unimportant, therefore uninvestigated, substances have become of prime importance.

Jan 1, 1962

By Yong-neng Feng, Xiao-ping Chen, Wei Guo

"While the uniaxial compressive strength of rock has been extensively investigated, the relation between the saturation and natural compressive strength is relatively unexplored. This paper studies on 1865 statistical data of Chongqing Rail Transit Line 1 and Line 6, which located in the Middle Jurassic of Shaximiao formation. The research focuses on the relation between the saturation and natural compressive strength. The statistical data are categorized and quantified in order to ascertain the softening properties of sandstone and sandy mudstone. The findings suggest that the saturation compressive strength is significant effected by its natural compressive strength, and an empirical formula is introduced to explain the relation. These findings have implications for researchers and engineer who concerned with Chongqing rail transit construction.INTRODUCTIONIn the engineering construction and surrounding rock classification, the uniaxial compressive strength index (Ministry of Water Conservancy, 1995; Ministry of Railways, 1999) is one of the essential parameters of rock mass. Usually, there are two types of the uniaxial compressive strength index, natural and saturation compressive strength, and the ratio of them is the softening coefficient. Most of the previous studies on rock strength had focused on the influence factors (Liu et al., 2008; Liu et al., 1998; Liu et al., 2013; Wang, 2013; Zhang et al., 2008; Zhang et al., 2010; Zeng & Lin, 2003) with experiment and in-situ tests. But few publications that reports a long and formal research project on the relationship between natural and saturation compressive strength. In order to figure out this issue, this study investigated the distribution of Solidity Classification of Rock Mass and softening coefficient based on the statistical data of Chongqing Rail Transit Line 1 and Line 6. Based on the analysis, an empirical formula was proposed to explain the relationship."

Jan 1, 2015

By A. J. Jager, N. C. Joughin

The effects of extensive solid-waste packing as a support medium are described. It is shown that the waste packing resulted in excellent hangingwall conditions with only minor deleterious effects.

Jan 1, 1979

By T. J. Williams

Researchers at the U.S. Bureau of Mines monitored rock mass response to mining of an experimental underhand longwall stope in Hecla Mining Co.'s LUCKY Friday Mine, Mullan, ID. This stope design, the Lucky Friday underhand longwall (LFUL), was proposed as a means of controlling rock bursting while also allowing increased mechanization of mining operations. Instruments were specifically manufactured to monitor three geomechanical factors (backfill performance, ramp stability, and rock mass response) that directly affect the success of stope design. Despite considerable difficulties with instrument installation and survival in the harsh mine environment, especially within the stope fill, sufficient information was collected to suggest that the LFUL method was successful in achieving project goals. This conclusion, in addition to favorable economic and operational evidence, led the mine to adopt the method throughout the mine. Indeed, this study and mining experience suggest that underhand longwall mining could be considered a feasible mining method for rock-burst-prone ground throughout the Coeur d'Alene District. Further Reports of Investigations (RI) in this series present in-depth analyses of the effects of backfill on rock bursting and calibration of a stope numerical model.

Jan 1, 2010

By Tooley S. M

An experimental investigation of the hydraulic cuttability of coal from the Theiss Dampier Mitsui mine near Moura, Central Queen land illustrated the ability of established cutting equations to describe the behaviour of the coal during cutting. The experimental equipment developed for the work proved reliable. The results of the experimental programme are consistent with accumulated experience from overseas.

Jan 1, 1985

By V. ?. Chanturiya, I. Zh. Bunin, M. V. Ryazantseva

"Surface changes in naturally occurring metal sulfides (pyrite, arsenopyrite, sphalerite, chalcopyrite, galena, and molybdenite) due to treatments from high-power electromagnetic pulses (HPEMP) at varying times were studied using X-ray photoelectron spectroscopy. Analysis of the obtained results revealed common patterns and differences in surface transformations. The transformations were found to include two main stages. The first stage was observed at low treatment intensities (up to n ~103 pulses). At this stage, formation and accumulation in the surface layer of the nonstoichiometric sulfide phase, oxides and hydroxides, as well as elemental (polysulfide) sulfur and/or metastable sulfur species (thiosulfate, sulfite) was observed. The second stage (N = 3·103 pulses) is characterized by thermal removal of sulfur species and renewal of the mineral surface (sulfidization).It was found that the chemical changes of the sulfur on the surface layer of pyrite, arsenopyrite, chalcopyrite included accumulation/formation of S0 (Sn 2-) at the first stage of the transformation, followed by its removal. An increase in the surface concentration of elemental sulfur for pyrite and chalcopyrite was 10–12% while arsenopyrite was approximately 5%. A more complicated chemical change was observed for sphalerite and galena, that included formation/accumulation of metastable sulfur species (thiosulfate, sulfate) at the initial stage (up to 103 pulses) and during longer treatment times, the sulphur is reduced back to its initial state (sulfide or disulfide). The increased concentration of S0 sulfur, compared to the original sample, was only 3% in galena and sphalerite.The application of HPEMP treatment to improve flotation selectivity is supported by singlemineral flotation tests. Changes in flotability as a result of HPEMP treatment are principally explained by surface phase changes that resulted in higher adsorption activity."

Jan 1, 2016

By Juan L. Yarmuch, Hyam Rubinstein

Open-pit mine planning is a key process in the definition of mineral reserves and their efficient removal. Ore in open-pit mines is extracted bymining sequential pits called pushbacks. Pushbacks need to satisfy complex geometrical constraints to ensure the efficient usage of equipment. To date, no algorithms that both account for those constraints and maximizeNPV, are commercially available. Therefore, pushback design is done by engineers relying on their expertise to incorporate practical features intothe output of commercial tools. In this article, we present a new algorithm that produces close to optimal practical pushbacks and we illustrate its performance in real mines.

Jun 25, 2023

By G. X. Du

Reaction kinetics of serpentine and hydrochloric acid is theoretical basis for optimizing reaction process conditions of serpentine and hydrochloric acid. Kinetics of serpentine and hydrochloric acid was studied in this paper. The results indicated that apparent reaction order to hydrochloric acid was two and reaction kinetic equation could be expressed as: 2HClHCl,ddtckct-=·. The diffusion rates of hydrogen ions in liquid film on surface of serpentine particle and in amorphous silica layer generated in the reaction and chemical reaction velocity during the reaction had important effects on to-tal reaction velocity. And chemical reaction velocity had the most significant influence. The relation of conversion rate of magnesia xMgO with reaction time could be expressed as: 1(1)xkt--=·.

Jan 1, 2014

Underground coal mining continues to evolve in the U.S., and more reserves are being mined under deeper cover, with worse roof, or with interactions from previous workings. At the same time, the mining community is responding to higher safety standards and intense competitive pressures. The need for effective ground control design has never been greater. Ground control safety issues that have been addressed by recent the National Institute for Occupational Safety and Health (NIOSH) research include: Improving roof support performance; Maintaining safe tailgate escapeways from longwalls; Optimizing pillar design for retreat mining; Controlling multiple seam interactions; Predicting roof conditions during extended cuts, and; Preventing massive pillar collapses. As funding from both government and the private sector has diminished, the emphasis in research has focused on providing the mining community with practical techniques for improved ground control design. Many projects have successfully employed empirical methods that emphasize the statistical analysis of case histories from underground mines. Other projects have employed numerical models and large-scale laboratory testing of roof support elements. Using these data, NIOSH has developed an entire toolbox of computer programs that have been effectively transferred to the mining community.

By J. F. Edwards

In situ extraction of copper through borehole injection presents a new technology for the mining of copper. For the successful application of this technology, copper recovery at the surface must be specifically designed for borehole injection and the general conditions of the well field. This paper describes the design of a solvent extraction / electrowinning facility specifically designed for in situ leaching of copper. This design is based on commercial solvent extraction / electro-winning with considerations of the requirements of this specific application.

Jan 1, 1988